WO2021059883A1 - 排ガス浄化触媒の製造方法 - Google Patents

排ガス浄化触媒の製造方法 Download PDF

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Publication number
WO2021059883A1
WO2021059883A1 PCT/JP2020/032989 JP2020032989W WO2021059883A1 WO 2021059883 A1 WO2021059883 A1 WO 2021059883A1 JP 2020032989 W JP2020032989 W JP 2020032989W WO 2021059883 A1 WO2021059883 A1 WO 2021059883A1
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Prior art keywords
exhaust gas
base material
flow type
type base
catalyst
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English (en)
French (fr)
Japanese (ja)
Inventor
大司 望月
浩幸 原
豪人 高山
禎憲 高橋
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NE Chemcat Corp
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NE Chemcat Corp
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Priority to JP2021548723A priority Critical patent/JPWO2021059883A1/ja
Priority to CN202080057067.2A priority patent/CN114222627A/zh
Priority to EP20868793.9A priority patent/EP4035774A4/en
Publication of WO2021059883A1 publication Critical patent/WO2021059883A1/ja
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0006—Honeycomb structures
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • F01N3/0222—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • F01N3/035—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1025—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/206—Rare earth metals
    • B01D2255/2063—Lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20715—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B01D2255/20—Metals or compounds thereof
    • B01D2255/209—Other metals
    • B01D2255/2092—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/915—Catalyst supported on particulate filters
    • B01D2255/9155—Wall flow filters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/92—Dimensions
    • B01D2255/9207—Specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B01D2258/012—Diesel engines and lean burn gasoline engines
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00793—Uses not provided for elsewhere in C04B2111/00 as filters or diaphragms
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0081—Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers

Definitions

  • the present invention relates to a method for producing an exhaust gas purification catalyst and the like.
  • Exhaust gas emitted from an internal combustion engine contains particulate matter (PM) mainly composed of carbon and ash composed of non-combustible components, and is known to cause air pollution.
  • PM particulate matter
  • diesel engines which emit particulate matter relatively more easily than gasoline engines, had strict restrictions on the amount of particulate matter emitted, but in recent years, gasoline engines have also tightened restrictions on the amount of particulate matter emitted. Is being done.
  • a method of providing a particulate filter for the purpose of depositing and collecting particulate matter in the exhaust gas passage of an internal combustion engine is known.
  • CO carbon monoxide
  • HC hydrocarbons
  • NOx nitrogen oxides
  • the particulate filter as described in Patent Document 1 has a wall flow type structure from the viewpoint of removing particulate matter, and is configured so that exhaust gas passes through the pores of the partition wall.
  • soot collection performance there is still room for improvement in soot collection performance.
  • the amount of particulate matter emitted by a gasoline engine and the amount of particulate matter emitted by a diesel engine are different.
  • the PM particle number regulation (6 ⁇ 10 11 / km) in the case of a gasoline engine is said to correspond to 0.4 to 0.5 mg / km in terms of PM mass.
  • the regulation value of particulate matter in diesel engines is set to 5 mg / km (0.005 g / km). In this way, even with the regulation of particulate matter, there is a difference in the required collection performance between a gasoline engine and a diesel engine.
  • the present invention has been made in view of the above problems, and an object of the present invention is an exhaust gas purification catalyst capable of easily and reproducibly producing a high-performance exhaust gas purification catalyst having excellent soot collection performance in order to comply with PN regulations.
  • Another object of the present invention is to provide a novel treated wall flow type base material suitable for use in the above-mentioned method for producing an exhaust gas purification catalyst.
  • the present invention is not limited to the purpose described here, and it is an action and effect derived by each configuration shown in the embodiment for carrying out the invention described later, and it is also possible to exert an action and effect that cannot be obtained by the conventional technique. It can be positioned as another purpose.
  • a method for manufacturing an exhaust gas purification catalyst that purifies the exhaust gas emitted from an internal combustion engine A base material preparation process for preparing a treated wall flow type base material with solid resin attached to the partition wall, It has a catalyst coating step of coating the catalyst slurry on the partition wall. The amount of the solid resin adhered is 1.50 to 9.41 g / L. Manufacturing method of exhaust gas purification catalyst.
  • the base material preparation step A step of impregnating the end portion of the wall flow type base material on the exhaust gas introduction side or the exhaust gas discharge side with a resin solution, and A step of applying the resin solution impregnated in the wall flow type base material to the porous partition wall by introducing a gas into the wall flow type base material from the end side.
  • the method for producing an exhaust gas purification catalyst comprises a step of drying the coated resin solution and adhering the solid resin to at least a part of the partition wall.
  • the resin solution contains polyvinyl alcohol and contains The concentration of the polyvinyl alcohol is 0.80 to 5.00% by mass with respect to the total amount of the resin solution.
  • the catalyst coating process A step of impregnating the end portion of the wall flow type base material on the exhaust gas introduction side or the exhaust gas discharge side with the catalyst slurry, and It comprises a step of applying the catalyst slurry impregnated in the wall flow type base material to the porous partition wall by introducing a gas into the wall flow type base material from the end side.
  • the solid resin contains polyvinyl alcohol. The treated wall flow type base material according to [7].
  • an exhaust gas purification catalyst capable of easily producing a high-performance exhaust gas purification catalyst having excellent soot collection performance with good reproducibility, and the soot produced by the production method. It is possible to realize a high-performance exhaust gas purification catalyst having excellent collection performance. Further, according to the present invention, it is possible to provide a novel treated wall flow type base material suitable for use in the above-mentioned method for producing an exhaust gas purification catalyst.
  • a gasoline particulate filter (GPF) but also a diesel particulate filter (DPF) and the like are used as means for suppressing the improvement of the soot collecting performance of the particulate filter carrying the catalyst. It can also be used in a particulate filter, and the performance of an exhaust gas treatment system equipped with such a particulate filter can be further improved.
  • the method for manufacturing the exhaust gas purification catalyst of the present embodiment is a method for manufacturing the exhaust gas purification catalyst 300 for purifying the exhaust gas discharged from the internal combustion engine, and the solid resin 21 is attached to the partition wall of the wall flow type base material 11. It has a base material preparation step (S1) for preparing the wall flow type base material 100 and a catalyst coating step (S2) for coating the catalyst slurry 31a on the partition wall, and the adhesion amount of the solid resin 21 is 1. It is characterized by having a weight of .50 to 9.41 g / L.
  • the method for producing the exhaust gas purification catalyst 300 of the present embodiment includes a heat treatment step of thermally decomposing the solid resin 21 adhering after the catalyst coating step (S2), and a heat treatment of the coated catalyst slurry 31a to heat the catalyst layer 31. May have a firing step of forming. The heat treatment step and the firing step may be performed at the same time by heating once.
  • each process will be described with reference to a process diagram schematically showing a method for producing the exhaust gas purification catalyst 300 of the present embodiment shown in FIG. 1.
  • the treated wall flow type base material 100 (hereinafter referred to as) having a wall flow type base material 11 in which a plurality of passages are defined by a porous partition wall and a solid resin 21 adhering to the partition wall is provided.
  • base material 100 the wall-flow type base material before treatment, in which the solid resin 21 is not attached to the partition wall, is referred to as the pre-treatment wall-flow type base material 11 (hereinafter, also simply referred to as “base material 11”).
  • the treated wall flow type base material on which the solid resin 21 is attached to the partition wall is referred to as a treated wall flow type base material 100 (hereinafter, also simply referred to as “base material 100”).
  • base material 100 the base material 11 having a wall flow structure (wall flow type base material 11 before treatment) constituting the skeleton of the exhaust gas purification catalyst will be described.
  • the introduction side cell in which the end on the exhaust gas introduction side is open and the discharge side cell in which the end on the exhaust gas discharge side is open adjacent to the introduction side cell are separated by a porous partition wall. It has a wall flow structure that is used.
  • the exhaust gas purification catalyst 300 using the wall flow type base material 11 having such a configuration the exhaust gas discharged from the internal combustion engine is introduced into the introduction side cell from the end (opening) on the exhaust gas introduction side, and the partition wall. It is introduced into the adjacent discharge side cell through the pores of the exhaust gas, and is discharged from the end (opening) on the exhaust gas discharge side.
  • particulate matter is difficult to pass through the pores of the partition wall, so it is generally deposited on the partition wall in the introduction side cell, and the deposited PM is generated by the catalytic function of the catalyst layer or at a predetermined temperature ( For example, it is burned at about 500 to 700 ° C. and decomposed.
  • the exhaust gas contacts the catalyst layer provided in the partition wall, which carbon monoxide (CO) and hydrocarbons (HC) contained in the exhaust gas by oxidation to such water (H 2 O) and carbon dioxide (CO 2)
  • nitrogen oxides (NOx) are reduced to nitrogen (N 2 ), and harmful components are purified (detoxified).
  • the removal of particulate matter and the purification of harmful components such as carbon monoxide (CO) are collectively referred to as "exhaust gas purification performance".
  • the material of the wall flow type base material 11 is exposed to high-temperature (for example, 400 ° C. or higher) exhaust gas generated when an internal combustion engine is operated under a high load condition, or particulate matter is burned and removed at a high temperature.
  • high-temperature for example, 400 ° C. or higher
  • a material made of a heat-resistant material is preferable so that it can be used in various cases.
  • the heat-resistant material include ceramics such as cordierite, mulite, aluminum titanate, and silicon carbide (SiC); alloys such as stainless steel.
  • the shape of the wall flow type base material 11 can be appropriately adjusted from the viewpoint of the ability to collect particulate matter and the suppression of the increase in pressure loss.
  • the outer shape of the wall flow type base material 11 can be a cylindrical shape, an elliptical cylinder shape, a polygonal cylinder shape, or the like.
  • the capacity (total volume of cells) of the wall flow type base material 11 is preferably 0.1 to 5 L, more preferably 0.5 to 3 L, although it depends on the space to be incorporated.
  • the total length of the wall flow type base material 11 in the stretching direction is preferably 10 to 500 mm, more preferably 50 to 300 mm.
  • the introduction-side cell and the discharge-side cell are regularly arranged along the axial direction of the tubular shape, and adjacent cells are alternately sealed with one end in the extension direction and the other end. Has been done.
  • the introduction-side cell and the discharge-side cell can be set to an appropriate shape and size in consideration of the flow rate and components of the supplied exhaust gas.
  • the shape of the introduction side cell and the discharge side cell can be a triangle; a rectangle such as a square, a parallelogram, a rectangle, and a trapezoid; another polygon such as a hexagon and an octagon; a circle.
  • HAC High Ash Capacity
  • the number of introduction-side cells and discharge-side cells can be appropriately set so as to promote the generation of turbulent flow of exhaust gas and suppress clogging due to fine particles or the like contained in the exhaust gas, and is not particularly limited. , 200 cpsi to 400 cpsi is preferable.
  • the partition wall that separates adjacent cells from each other is not particularly limited as long as it has a porous structure through which exhaust gas can pass. It can be adjusted as appropriate from the viewpoint of improving the mechanical strength. For example, when a catalyst layer is formed inside the pores of the partition wall using the catalyst slurry described later, the pore diameter (for example, the mode diameter (the pore diameter having the largest appearance ratio in the frequency distribution of the pore diameter (maximum value of the distribution))). ) Or when the pore volume is large, the pores are less likely to be clogged by the catalyst slurry, and the resulting exhaust gas purification catalyst tends to be less likely to increase the pressure loss, but the ability to collect particulate matter is reduced. Also, the mechanical strength of the substrate can be reduced.
  • the pore diameter (mode diameter) of the partition wall is preferably 8 to 25 ⁇ m, more preferably 10 to 22 ⁇ m, and further preferably 13 to 20 ⁇ m.
  • the thickness of the partition wall (the length in the thickness direction orthogonal to the stretching direction) is preferably 6 to 12 mil, more preferably 6 to 10 mil.
  • the pore volume of the partition wall by the mercury intrusion method is preferably 0.2 to 1.0 cm 3 / g, more preferably 0.25 to 0.9 cm 3 / g, and further preferably 0.3 to 0.3 to. It is 0.8 cm 3 / g.
  • the porosity of the partition wall by the mercury intrusion method is preferably 20 to 80%, more preferably 40 to 70%, and preferably 60 to 70%.
  • the pore diameter (mode diameter), pore volume, and porosity mean values calculated by the mercury intrusion method under the conditions described in the following examples.
  • the porous partition wall of the wall flow type base material 11 has a complicated pore shape.
  • the solid resin 21 is formed in the narrow portion 11c between the pores which tends to cause an increase in pressure loss. It exists in advance (S1 in FIG. 2).
  • the treated wall flow type base material 100 can be said to be a wall flow type base material in which the narrow portion 11c is masked (protected) in advance by the solid resin 21.
  • the coating of the catalyst slurry 31a may be hindered when the amount of the solid resin 21 adhered is large.
  • the collection rate of PN is improved.
  • the reason for this is not particularly limited, but as the amount of solid resin 21 adhered to the solid resin 21, the masked portion increases, and as a result, the amount of catalyst applied to the air pores increases. This is probably because the pore distribution after catalyst coating shifts to the small pore side as a whole.
  • the amount of the solid resin 21 adhered is small, such fluctuations in the base term distribution do not occur, and it is considered that there is no significant contribution to the PN collection rate.
  • the amount of the solid resin 21 adhered to the solid resin 21 in the present embodiment is 1.50 to 9.41 g / L, preferably 1.69 to 6.58 g / L with respect to the capacity of the wall flow type base material 11, and more. It is preferably 1.88 to 5.64 g / L.
  • the amount of the solid resin 21 adhered is 1.50 g / L or more, the soot collection performance of the obtained exhaust gas purification catalyst tends to be further improved. Further, when the amount of the solid resin 21 adhered is 9.41 g / L or less, the coatability of the catalyst slurry to the substrate can be ensured.
  • the amount of solid resin 21 adhered can be adjusted by adjusting the concentration of the resin in the resin solution 21a, which will be described later, the amount of the resin solution 21a to be applied, and the like.
  • the amount of the solid resin 21 adhered is determined by cutting out a sample having a predetermined volume from the treated wall flow type base material 100 and putting it into a resin solution (hot water, various solvents, etc.) to dissolve the solid resin 21. It can also be calculated by measuring the amount of the resin.
  • the samples cut out here are three points on the exhaust gas introduction side, the central part, and the exhaust gas discharge side excluding the outer peripheral portion (hereinafter, also simply referred to as “exodermis”) of the treated wall flow type base material 100, and the average value thereof is taken as the average value.
  • the amount of solid resin 21 attached is used.
  • the pre-treatment wall flow type base material 11 to which the solid resin 21 is not attached to the partition wall is prepared, and the solid resin 21 is attached to the partition wall.
  • the treatment method is not particularly limited, and examples thereof include a method in which the partition wall of the pre-treatment wall flow type base material 11 is impregnated with the resin solution 21a and dried. More specifically, the step S1a of impregnating the end portion of the exhaust gas introduction side 11a or the exhaust gas discharge side 11b of the wall flow type base material 11 with the resin solution 21a, and the gas in the wall flow type base material 11 from the end side.
  • the method of impregnating the resin solution 21a in this step S1a is not particularly limited, and examples thereof include a method of immersing the end portion of the wall flow type base material 11 in the resin solution 21a.
  • the resin solution 21a may be pulled up by discharging (sucking) gas from the opposite end.
  • the end portion to be impregnated with the resin solution 21a may be either the exhaust gas introduction side 11a or the exhaust gas discharge side 11b, but it is preferable to impregnate the end portion of the exhaust gas introduction side 11a with the resin solution 21a.
  • the gas can be introduced in the same direction as the exhaust gas introduction direction in the step S1d described later, and the resin solution 21a can be applied to the complicated pore shape along the flow of the exhaust gas. Therefore, the soot collection performance is expected to be improved, and the exhaust gas purification performance is also expected to be improved.
  • step S1d the gas F1 is introduced into the wall flow type base material 11 from the end side 1a impregnated with the resin solution 21a (FIG. 1).
  • the impregnated resin solution 21a moves from the introduction side of the wall flow type base material 11 to the back of the wall flow type base material 11 along the gas flow and reaches the end portion on the gas discharge side.
  • the resin solution 21a passes through the pores of the partition wall, so that the resin solution 21a can be applied to the inside of the pores.
  • the direction of the wall flow type base material 11 when gas is introduced into the wall flow type base material 11 from the end side impregnated with the resin solution 21a is not particularly limited, but the extending direction of the partition wall and the vertical direction are substantially parallel to each other. And, after adjusting the direction of the wall flow type base material 11 so that the end portion impregnated with the resin solution 21a faces upward in the vertical direction (S1b to S1c in FIG. 1), the direction is directed from the upper side to the lower side in the vertical direction. It is preferable to introduce the gas into the wall flow type base material 11 from the end side impregnated with the resin solution 21a (S1d in FIG. 1).
  • the flow direction of the gas to be introduced coincides with the direction of gravity (vertically below), so that when gas is introduced from below to above in the vertical direction against the direction of gravity, or when the partition wall is extended perpendicular to the direction of gravity.
  • the resin solution 21a can be uniformly applied by the partition wall.
  • the drying conditions in step S1e are not particularly limited as long as the solvent volatilizes from the resin solution 21a and the solid resin remains (adheres) to the partition wall surface.
  • the drying temperature is preferably 100 to 225 ° C, more preferably 100 to 200 ° C, and even more preferably 125 to 175 ° C.
  • the drying time is preferably 0.5 to 2 hours, preferably 0.5 to 1.5 hours.
  • the resin solution 21a contains a resin and a solvent such as water.
  • the resin is not particularly limited, but is, for example, a polyvinyl alcohol-based resin such as polyvinyl alcohol and a saponified product of polyvinyl alcohol such as polybutyral; an acrylic resin such as poly (meth) acrylic acid and poly (meth) acrylic acid ester.
  • Resin Cellulose-based resins such as methyl cellulose, ethyl cellulose, and carboxymethyl cellulose can be mentioned.
  • the water-soluble resin is preferably a polyvinyl alcohol-based resin, and more preferably polyvinyl alcohol. That is, as the resin solution 21a, a water-soluble resin-containing solution containing at least water and a water-soluble resin is preferably used.
  • the concentration of the resin is preferably 0.80 to 5.00% by mass with respect to the total amount of the resin solution. Yes, more preferably 0.85 to 4.50% by mass, still more preferably 0.90 to 4.00% by mass.
  • the resin concentration is 0.80% by mass or more, the soot collection performance of the obtained exhaust gas purification catalyst tends to be further improved. Further, when the concentration of the resin is 5.00% by mass or less, the coatability of the resin solution to the base material can be ensured.
  • the catalyst slurry 31a is further coated on the partition wall of the treated wall flow type base material 100 (FIG. 1).
  • the wall flow type base material 200 coated with the catalyst slurry is obtained, in which the catalyst slurry 31a is coated on the partition wall of the treated wall flow type base material 100.
  • the coating method of the catalyst slurry 31a is not particularly limited, and examples thereof include a method of impregnating a part of the wall flow type base material 100 with the catalyst slurry 31a and spreading it over the entire partition wall of the wall flow type base material 100. Be done.
  • step S2a of impregnating the end portion of the exhaust gas introduction side 11a or the exhaust gas discharge side 11b of the wall flow type base material 100 with the catalyst slurry 31a, and the step S2a from the end side into the wall flow type base material 100.
  • a method including a step S2d of applying the catalyst slurry 31a impregnated in the wall flow type base material 100 to the porous partition wall by introducing a gas can be mentioned.
  • the impregnation method of the catalyst slurry 31a in this step S2a is not particularly limited, and examples thereof include a method of immersing the end portion of the wall flow type base material 100 in the catalyst slurry 31a. In this method, if necessary, the catalyst slurry 31a may be pulled up by discharging (sucking) gas from the opposite end.
  • the end portion to be impregnated with the catalyst slurry 31a may be either the exhaust gas introduction side 11a or the exhaust gas discharge side 11b, but it is preferable to impregnate the end portion of the exhaust gas introduction side 11a with the catalyst slurry 31a.
  • the gas can be introduced in the step S2d described later in the same direction as the exhaust gas introduction direction, and the catalyst slurry 31a can be applied to the complicated pore shape along the flow of the exhaust gas. Therefore, the soot collection performance is further improved, and the exhaust gas purification performance is also expected to be improved.
  • the catalyst slurry 31a for forming the catalyst layer 31 provided on the surface of the pores in the partition wall will be described.
  • the catalyst slurry 31a contains a catalyst powder and a solvent such as water.
  • the catalyst powder is a group of a plurality of catalyst particles (hereinafter, may be simply referred to as “particles” or the like) including catalyst metal particles and carrier particles supporting the catalyst metal particles, and is fired to be described later. Through the steps, the catalyst layer 31 is formed.
  • the catalyst particles in the present embodiment, composite particles containing the catalyst metal particles and the carrier particles supporting the catalyst metal particles are used, but the type thereof is not particularly limited, and the catalyst particles are appropriately selected from known catalyst particles. Can be used.
  • the solid content of the catalyst slurry 31a is preferably 1 to 50% by mass, more preferably 10 to 40% by mass, and further preferably 15 to 15 to 40% by mass. It is 30% by mass.
  • the D90 particle size of the catalyst powder is preferably 1 to 7 ⁇ m, more preferably 1 to 6 ⁇ m, and further preferably 1 to 5 ⁇ m.
  • the D90 particle size is 1 ⁇ m or more, the crushing time when the catalyst powder is crushed by the milling device can be shortened, and the work efficiency tends to be further improved.
  • the D90 particle size is 7 ⁇ m or less, it is suppressed that the coarse particles block the inside of the partition wall, and the soot collection performance tends to be improved.
  • the D90 particle size means a diameter measured by a laser diffraction type particle size distribution measuring device (for example, a laser diffraction type particle size distribution measuring device SALD-3100 manufactured by Shimadzu Corporation).
  • the catalyst metal constituting the catalyst metal particles various metal species capable of functioning as an oxidation catalyst or a reduction catalyst can be used.
  • platinum group metals such as platinum (Pt), palladium (Pd), rhodium (Rh), ruthenium (Ru), iridium (Ir) and osmium (Os).
  • palladium (Pd) and platinum (Pt) are preferable from the viewpoint of oxidizing activity
  • rhodium (Rh) is preferable from the viewpoint of reducing activity.
  • These metals may be used alone or in combination of two or more. From the viewpoint of increasing the contact area with the exhaust gas, it is preferable that the average particle size of the catalyst metal particles in the catalyst slurry 31a is small.
  • the average particle size of the catalyst metal particles is preferably 1 to 15 nm, more preferably 1 to 10 nm, and even more preferably 1 to 7 nm.
  • the average particle size of the catalyst metal particles can be confirmed using, for example, a scanning transmission electron microscope (STEM) such as HD-2000 manufactured by Hitachi High-Technologies Co., Ltd.
  • STEM scanning transmission electron microscope
  • the circle-equivalent diameters of the 10 catalytic metal particles extracted at random are calculated, and the average value thereof is taken as the average particle diameter of the catalytic metal particles.
  • an inorganic compound conventionally used in this type of exhaust gas purification catalyst can be considered.
  • oxygen storage materials such as cerium oxide (Celia: CeO 2 ), ceria-zirconia composite oxide (CZ composite oxide), aluminum oxide (alumina: Al 2 O 3 ), zirconium oxide.
  • oxides such as (zirconia: ZrO 2 ), silicon oxide (silica: SiO 2 ), titanium oxide (titania: TiO 2 ), and composite oxides containing these oxides as main components.
  • the oxygen occlusion material is when the air-fuel ratio of the exhaust gas is lean (that is, the atmosphere on the oxygen excess side), the oxygen in the exhaust gas is occlusioned, and when the air-fuel ratio of the exhaust gas is rich (that is, the atmosphere on the excess oxygen side). That is, the atmosphere on the excess fuel side) is the one that releases the stored oxygen.
  • the specific surface area of the carrier particles is preferably 10 to 500 m 2 / g, more preferably 30 to 200 m 2 / g.
  • the catalyst metal support rate in the state of being supported on the wall flow type base material (amount of catalyst metal per 1 L of base material). Is preferably 0.5 to 10 g / L, more preferably 1 to 8 g / L, and even more preferably 1 to 6 g / L.
  • step S2d the gas F1 is introduced into the wall flow type base material 100 from the end side 1a impregnated with the catalyst slurry 31a (FIG. 1).
  • the impregnated catalyst slurry 31a moves from the introduction side of the wall flow type base material 100 to the back of the wall flow type base material 100 along the gas flow and reaches the end portion on the gas discharge side.
  • the catalyst slurry 31a can be applied to the inside of the pores by passing the catalyst slurry 31a through the pores of the partition wall.
  • the direction of the wall flow type base material 100 when introducing gas into the wall flow type base material 100 from the end side impregnated with the catalyst slurry 31a is not particularly limited, but the extending direction of the partition wall and the vertical direction are substantially parallel. And, after adjusting the direction of the wall flow type base material 100 so that the end portion impregnated with the catalyst slurry 31a faces upward in the vertical direction (S2b to S2c in FIG. 1), the direction is directed from the upper side to the lower side in the vertical direction. It is preferable to introduce the gas into the wall flow type base material 100 from the end side impregnated with the catalyst slurry 31a (S2d in FIG. 1).
  • the flow direction of the gas to be introduced coincides with the direction of gravity (vertically below), so that when gas is introduced from below to above in the vertical direction against the direction of gravity, or when the partition wall is extended perpendicular to the direction of gravity.
  • the catalyst slurry 31a can be uniformly applied by the partition wall.
  • the wall flow type base material 100 (wall flow type base material 200 coated with the catalyst slurry) coated with the catalyst slurry 31a is heat-treated to thermally decompose the solid resin. ..
  • the heat treatment temperature is not particularly limited, but is preferably 400 to 650 ° C, more preferably 450 to 600 ° C, and even more preferably 500 to 600 ° C.
  • the heat treatment time is preferably 0.5 to 2 hours, preferably 0.5 to 1.5 hours.
  • a drying step of drying the wall flow type base material 200 may be performed before the heat treatment step.
  • the drying temperature is not particularly limited, but is preferably 100 to 225 ° C, more preferably 100 to 200 ° C, and even more preferably 125 to 175 ° C.
  • the drying time is preferably 0.5 to 2 hours, preferably 0.5 to 1.5 hours.
  • the catalyst layer 31 is formed from the coating film of the catalyst slurry 31a by heat-treating the wall flow type base material 100 coated with the catalyst slurry 31a (wall flow type base material 200 coated with the catalyst slurry). To do.
  • the firing step may be performed at the same time as the heat treatment step.
  • the firing temperature is not particularly limited, but is preferably 400 to 650 ° C, more preferably 450 to 600 ° C, and even more preferably 500 to 600 ° C.
  • the firing time is preferably 0.5 to 2 hours, preferably 0.5 to 1.5 hours.
  • the exhaust gas purification catalyst of the present embodiment is obtained by the above-mentioned manufacturing method of the exhaust gas purification catalyst, and is used for purifying the exhaust gas discharged from the internal combustion engine.
  • the exhaust gas purification catalyst of the present embodiment is preferably used for a gasoline particulate filter (GPF) capable of collecting and removing particulate matter contained in exhaust gas.
  • GPF gasoline particulate filter
  • the exhaust system is provided with an exhaust gas purification device equipped with an exhaust gas purification catalyst, and harmful components (for example, carbon monoxide (CO), hydrocarbons (HC), nitrogen oxides (NOx) contained in the exhaust gas by the exhaust gas purification catalyst are provided. )) Is purified, and particulate matter (PM) contained in the exhaust gas is collected and removed.
  • harmful components for example, carbon monoxide (CO), hydrocarbons (HC), nitrogen oxides (NOx) contained in the exhaust gas by the exhaust gas purification catalyst are provided.
  • CO carbon monoxide
  • HC hydrocarbons
  • NOx nitrogen oxides
  • the pore diameter (mode diameter) of the partition wall obtained by the above-mentioned production method by the mercury injection method of the exhaust gas purification catalyst after the catalyst coating is preferably 8 to 23 ⁇ m, more preferably 12 to 20 ⁇ m, still more preferably. It is 14 to 18 ⁇ m.
  • the pore volume of the partition wall of the exhaust gas purification catalyst after the catalyst coating by the mercury injection method is preferably 0.2 to 1.0 cm 3 / g, more preferably 0.25 to 0.9 cm 3 / g. Yes, more preferably 0.3-0.8 cm 3 / g.
  • the porosity of the partition wall of the exhaust gas purification catalyst after the catalyst coating by the mercury injection method is preferably 20 to 80%, more preferably 30 to 70%, and preferably 35 to 60%.
  • the pore diameter (mode diameter), pore volume, and porosity mean values calculated by the mercury intrusion method under the conditions described in the following examples.
  • the treated wall flow type base material 100 of the present embodiment has a wall flow type base material 11 in which a plurality of passages are defined by a porous partition wall, and a solid resin 21 attached to the partition wall, and is a solid resin.
  • the amount of adhesion of 21 is 1.50 to 9.41 g / L.
  • the aspects of the wall flow type base material 11 and the solid resin 21 attached to the partition wall thereof are as described above. Further, the method for producing the treated wall flow type base material 100 is also as described above.
  • the solid resin 21 preferably contains a water-soluble resin and is water-soluble.
  • the resin more preferably contains polyvinyl alcohol.
  • the amount of the solid resin 21 adhered to the treated wall flow type base material 100 is 1.50 to 9.41 g / L, preferably 1.69 to 6.58 g / L, and more preferably 1.88 to 1.88 to L. It is 5.64 g / L.
  • the amount of the solid resin 21 adhered is 1.50 g / L or more, the soot collection performance tends to be further improved. Further, when the amount of the solid resin 21 adhered is 9.41 g / L or less, the coatability of the catalyst slurry to the substrate can be ensured.
  • the present invention is not limited thereto. That is, the materials, amounts used, ratios, treatment contents, treatment procedures, etc. shown in the following examples can be appropriately changed as long as they do not deviate from the gist of the present invention. Further, the values of various production conditions and evaluation results in the following examples have meanings as a preferable upper limit value or a preferable lower limit value in the embodiment of the present invention, and the preferable range is the above-mentioned upper limit value or lower limit value. And may be in the range specified by the combination of the values of the following examples or the values of the examples.
  • Example 1 Polyvinyl alcohol (hereinafter referred to as "PVA") and ion-exchanged water were mixed to prepare a 1.0 mass% PVA aqueous solution.
  • PVA Polyvinyl alcohol
  • ion-exchanged water ion-exchanged water
  • a wall flow type honeycomb base material (number of cells / mill thickness: 300 pieces / 8 mil, diameter: 118.4 mm, total length: 127 mm) made of Cordellite was prepared.
  • the end portion of the base material on the exhaust gas introduction side was immersed in the above-mentioned PVA aqueous solution and sucked under reduced pressure from the opposite end side to impregnate and hold the PVA aqueous solution in the base material.
  • Alumina powder having a D50 particle size of 28 ⁇ m and a BET specific surface area of 141 m 2 / g is impregnated with an aqueous solution of palladium nitrate and then calcined at 500 ° C. for 1 hour to obtain Pd-supported alumina powder (Pd content: 4.3 mass). %) was obtained. Further, a zirconia-lanthanate-modified alumina powder having a D50 particle size of 29 ⁇ m and a BET specific surface area of 145 m 2 / g was impregnated with an aqueous solution of rhodium nitrate, and then calcined at 500 ° C. for 1 hour to carry Rh-supported zirconia-lantern-modified alumina. A powder (Rh content: 0.7% by mass) was obtained.
  • the end portion of the base material treated with the PVA solution on the exhaust gas introduction side was immersed in the above-mentioned catalyst slurry, and the catalyst slurry was impregnated and held in the base material by suction with reduced pressure from the opposite end side.
  • the end face side impregnated and held with the catalyst slurry is turned upward in the vertical direction, and gas is introduced vertically downward into the base material from the end face side to apply the catalyst slurry to the surface inside the pores of the partition wall of the base material and gas.
  • the excess catalyst slurry was blown off from the end of the discharge side.
  • the base material coated with the catalyst slurry was dried at 150 ° C., and then calcined at 550 ° C. in an atmospheric atmosphere to prepare an exhaust gas purification catalyst.
  • the amount of catalyst applied after firing was 60.9 g / L (excluding the mass of the platinum group) per 1 L of the base material.
  • Example 2 An exhaust gas purification catalyst was prepared by the same operation as in Example 1 except that PVA and ion-exchanged water were mixed to prepare and use a 3.0 mass% PVA aqueous solution.
  • Example 3 By the same operation as in Example 1 except that the catalyst slurry was applied so that the amount of the catalyst applied after firing was 40.6 g per 1 L of the base material (excluding the mass of the platinum group metal). An exhaust gas purification catalyst was prepared.
  • Example 4 By the same operation as in Example 1 except that the catalyst slurry was applied so that the amount of the catalyst applied after firing was 76.1 g per 1 L of the base material (excluding the mass of the platinum group metal). An exhaust gas purification catalyst was prepared.
  • the particle size distribution of the catalyst slurry was measured by the laser scattering method using a laser diffraction type particle size distribution measuring device SALD-3100 manufactured by Shimadzu Corporation.
  • an exhaust gas purification catalyst having improved soot collection performance can be obtained relatively easily.
  • the exhaust gas purification catalyst produced in this way can be widely and effectively used as an exhaust gas purification catalyst for removing particulate matter contained in the exhaust gas of a gasoline engine.
  • the exhaust gas purification catalyst of the present invention can be effectively used as an exhaust gas purification catalyst because it removes particulate matter contained in exhaust gas of not only gasoline engines but also diesel engines, jet engines, boilers, gas turbines and the like. is there.

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JP2007526117A (ja) * 2004-02-27 2007-09-13 コーニング インコーポレイテッド 触媒塗膜を備えた多孔質セラミックフィルタ
JP2014510631A (ja) * 2011-03-30 2014-05-01 コーニング インコーポレイテッド セラミック製触媒担体を下塗り被膜で被覆する方法および下塗り被膜を有するセラミック製触媒担体
WO2016060048A1 (ja) 2014-10-16 2016-04-21 株式会社キャタラー 排ガス浄化用触媒
JP2019122897A (ja) * 2018-01-12 2019-07-25 エヌ・イーケムキャット株式会社 排ガス浄化触媒及びその製造方法

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JPS58109140A (ja) * 1981-12-22 1983-06-29 Nippon Shokubai Kagaku Kogyo Co Ltd ハニカム触媒の製造方法
WO2018037637A1 (ja) * 2016-08-26 2018-03-01 エヌ・イーケムキャット株式会社 ハニカム構造体、ハニカム構造型触媒および製造方法

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JP2007526117A (ja) * 2004-02-27 2007-09-13 コーニング インコーポレイテッド 触媒塗膜を備えた多孔質セラミックフィルタ
JP2014510631A (ja) * 2011-03-30 2014-05-01 コーニング インコーポレイテッド セラミック製触媒担体を下塗り被膜で被覆する方法および下塗り被膜を有するセラミック製触媒担体
WO2016060048A1 (ja) 2014-10-16 2016-04-21 株式会社キャタラー 排ガス浄化用触媒
JP2019122897A (ja) * 2018-01-12 2019-07-25 エヌ・イーケムキャット株式会社 排ガス浄化触媒及びその製造方法

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