WO2020117580A1 - Membrane purge system - Google Patents

Membrane purge system Download PDF

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Publication number
WO2020117580A1
WO2020117580A1 PCT/US2019/063502 US2019063502W WO2020117580A1 WO 2020117580 A1 WO2020117580 A1 WO 2020117580A1 US 2019063502 W US2019063502 W US 2019063502W WO 2020117580 A1 WO2020117580 A1 WO 2020117580A1
Authority
WO
WIPO (PCT)
Prior art keywords
separator
separation component
turbulence
heat pump
fluid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2019/063502
Other languages
French (fr)
Inventor
Rajiv Ranjan
Yinshan Feng
Parmesh Verma
Michael A. Stark
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Carrier Corp
Original Assignee
Carrier Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carrier Corp filed Critical Carrier Corp
Priority to CN201980041015.3A priority Critical patent/CN112334656A/en
Priority to US15/734,844 priority patent/US11686515B2/en
Publication of WO2020117580A1 publication Critical patent/WO2020117580A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B43/00Arrangements for separating or purifying gases or liquids; Arrangements for vaporising the residuum of liquid refrigerant, e.g. by heat
    • F25B43/04Arrangements for separating or purifying gases or liquids; Arrangements for vaporising the residuum of liquid refrigerant, e.g. by heat for withdrawing non-condensible gases
    • F25B43/043Arrangements for separating or purifying gases or liquids; Arrangements for vaporising the residuum of liquid refrigerant, e.g. by heat for withdrawing non-condensible gases for compression type systems
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D19/00Degasification of liquids
    • B01D19/0031Degasification of liquids by filtration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02Inorganic material
    • B01D71/028Molecular sieves
    • B01D71/0281Zeolites
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B39/00Component parts, details, or accessories, of pumps or pumping systems specially adapted for elastic fluids, not otherwise provided for in, or of interest apart from, groups F04B25/00 - F04B37/00
    • F04B39/16Filtration; Moisture separation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P80/00Climate change mitigation technologies for sector-wide applications
    • Y02P80/10Efficient use of energy, e.g. using compressed air or pressurized fluid as energy carrier
    • Y02P80/15On-site combined power, heat or cool generation or distribution, e.g. combined heat and power [CHP] supply

Definitions

  • Embodiments of the present disclosure relate generally to chiller systems used in air conditioning systems, and more particularly to a purge system for removing contaminants from a refrigeration system .
  • Chiller systems such as those utilizing centrifugal compressors may include sections that operate below atmospheric pressure. As a result, leaks in the chiller system may draw air into the system, contaminating the refrigerant. This contamination degrades the performance of the chiller system .
  • existing low pressure chillers include a purge unit to remove contamination.
  • Existing purge units typically use a vapor compression cycle to separate contaminant gas from the refrigerant.
  • Existing purge units are complicated and lose refrigerant in the process of removing contamination .
  • a separator for removing contamination from a fluid of a heat pump includes a housing having a hollow in terior, a separation component mounted within the hollow interior, and at least one turbulence-generating element positioned within the hollow interior adjacent the separation component.
  • the at least one turbulence -generating element extends into a flow of the fluid adjacent to the separation component.
  • the at least one turbulence-generating element extends adjacent to an exterior surface of the separation component.
  • the at least one turbulence-generating element includes a baffle.
  • the at least one turbulence-generating element includes a turbuiator.
  • the at least one turbulence-generating element includes an e j ector.
  • the at least one turbulence-generating element includes a plurality of turbulence-generating elements spaced along a longitudinal axis of the separation component.
  • the plurality of turbulence-generating elemen ts are substantially identical.
  • a configuration of at least one of the plurality of turbulence- generating elements varies from a configuration of a remainder of the plurality of turbulence- generating elements.
  • a separator for removing contamination from a fluid of a heat pump system includes a housing having a hollow interior, a separation component mounted within the hollow interior, and at least one vibration isolator mounted at an interface of the separation component.
  • the at least one vibration isolator is positioned at an intermediate portion of the separation component.
  • the separation component is mounted within the hollow interior by at least one header plate.
  • the at least one vibration isolator is mounted between the separation component and the at least one header plate.
  • the at least one vibration isolator is mounted at a portion of the separator fluidly connectable to the heat pump system.
  • the at least one vibration isolator is tnechnica!ly connected, but not fluidly connected to the heat pump system.
  • the at least one vibration isolator is formed from a flexible material.
  • the at least one vibration isolator is a vibration dampening pad.
  • FIG 1 is a schematic diagram of a heat pump of a refrigerant system
  • FIG 2 is a schematic diagram of a purge system according to an embodiment
  • FIG. 3 is a perspective view' of a separator of a purge system according to an embodiment
  • FIG. 4 is a schematic cross-sectional view' of a separator of a purge system according to an embodiment
  • FIG. 5 is a schematic cross-sectional view' of a separator of a purge system according to another embodiment.
  • FIG. 6 is an end view' of a header plate of a separator of a purge system according to an embodiment
  • the terni heat pump is intended to include any system capable of heating and/or cooling, such as a vapor compression system, a sorption system, a geothermal system, a waste heat recovery system, a heat based cooling system, and a heating system.
  • the heat pump 10 includes a compressor 12, a condenser 14, an expansion valve 16, and an evaporator 18 arranged to form a fluid loop.
  • the compressor 12 pressurizes heat transfer fluid in its gaseous state, w'hich both heats the fluid and provides pressure to circulate it through the system.
  • the heat transfer fluid, or refrigerant includes an organic compound.
  • the refrigerant comprises at least one of a hydrocarbon, substituted hydrocarbon, a halogen-substituted hydrocarbon, a fluoro- substituted hydrocarbon, or a chloro-fluoro-substrtuted hydrocarbon.
  • compressor 12 flows through a conduit 20 to a heat rejection heat exchanger such as condenser 14
  • the condenser is operable to transfer heat from the heat transfer fluid to the surrounding environment resulting in condensation of the hot gaseous heat transfer fluid to a pressuri zed moderate temperature liquid.
  • the liquid heat transfer fluid exiting from the condenser 14 flows through conduit 22 to expansion valve 16, where the pressure is reduced.
  • the reduced pressure liquid heat transfer fluid exiting the expansion valve 16 flows through conduit 24 to a heat absorption heat exchanger such as evaporator 18
  • the evaporator 18 functions to absorb heat from the surrounding environment and boil the heat transfer fluid. Gaseous heat transfer fluid exiting the evaporator 18 flows through conduit 26 to the compressor 12, so that the cycle may be repeated.
  • the heat pump 10 has the effect of transferring heat from the environment surrounding the evaporator 18 to the environment surrounding the condenser 14
  • the thermodynamic properties of the heat transfer fluid must allow it to reach a high enough temperature when compressed so that it is greater than the environment surrounding the condenser 14, allowing heat to be transferred to the surrounding environment.
  • the thermodynamic properties of the heat transfer fluid must also have a boiling point at its post expansion pressure that allows the temperature surrounding the evaporator 18 to provide heat to vaporize the liquid heat transfer fluid.
  • Various types of refrigeration systems may be classified as a heat pump 10 as illustrated and described herein.
  • One such refrigeration system is a chiller system. Portions of a refrigeration system, such as the cooler of a chiller system for example, may operate at a low pressure (e.g. , less than atmosphere) which can cause contamination (e.g., ambient air) to be drawn into fluid loop of the heat pump 10 The contamination degrades performance of the refrigeration system.
  • the heat pump 10 may additionally include a purge system 30 for removing contamination from the heat transfer fluid of the heat pump 10
  • the purge system 30 includes a purge collector 32 connected to the condenser 14 of a heat pump 10 via a purge connection 34
  • the purge collector 32 receives purge gas including refrigerant gas and contaminants, such as nitrogen and oxygen for example, from the purge connection 34
  • the purge system 30 additionally includes at least one separator 36 arranged downstream from and in fluid communication with an outlet 38 of the purge collector 32.
  • the separator 36 includes at least one separating component 40, such as a membrane for example, for separating contaminants from the refrigerant gas.
  • separating component 40 such as a membrane for example
  • the membrane may includes a porous inorganic material.
  • porous inorganic material can include ceramics such as metal oxides or metal silicates, more specifically
  • aluminosilicates e.g., Chabazite Framework (CHA) zeolite, Linde type A (LTA) zeolite, porous carbon, porous glass, clays (e.g., Montmori!lonrte, Halloysite).
  • Porous inorganic materials can also include porous metals such as platinum and nickel.
  • Hybrid inorganic- organic materials such as a metal organic framework (MQF) can also be used.
  • Other materials can be present in the membrane such as a carrier in which a mieroporous material can be dispersed, which can be included for structural or process considerations.
  • Metal organic framework materials are well-known in the art, and comprise metal ions or clusters of metal ions coordinated to organic ligands to form one-, two- or three-dimensional structures.
  • a metal-organic framework can be characterized as a coordination network with organic ligands containing voids.
  • the coordination network can be characterized as a coordination compound extending, through repeating coordination entities, in one dimension, but with cross-links between two or more individual chains, loops, or spiro-links, or a coordination compound extending through repeating coordination entities in tw'o or three dimensions.
  • Coordination compounds can include coordination polymers with repeating coordination entities extending in one, two, or three dimensions.
  • organic ligands include but are not limited to bidentate carboxylat.es (e.g., oxalic acid, succinic acid, phthalic acid isomers, etc.), tridentate carboxylates (e.g., citric acid, trimesic acid), azoles (e.g., 1 ,2,3-triazole), as well as other known organic ligands.
  • carboxylat.es e.g., oxalic acid, succinic acid, phthalic acid isomers, etc.
  • tridentate carboxylates e.g., citric acid, trimesic acid
  • azoles e.g., 1 ,2,3-triazole
  • metal organic framework materials include but are not limited to zeolitic imidazole framew'ork (ZIP), HKUST-1.
  • pore sizes of the material of the membrane can be characterized by a pore size distribution with an average pore size from 2.5 A to 10.0 A, and a pore size distribution of at least 0.1 A.
  • the average pore size for the porous material can be in a range with a lower end of 2.5 A to 4.0 A and an upper end of 2.6 A to 10.0 A. A .
  • the average pore size can be in a range having a lower end of 2.5 A, 3.0 A, 3.5 A, and an upper end of 3.5 A, 5.0 A, or 6.0 A.
  • range endpoints can be independently combined to form a number of different ranges, and ail ranges for each possible combination of range endpoints are hereby disclosed.
  • Porosity of the material can be in a range having a lower end of 5%, 10%, or 15%, and an upper end of 85%, 90%, or 95% (percentages by volume).
  • range endpoints can be independently combined to form a number of different ranges, and all ranges for each possible combination of range endpoints are hereby disclosed.
  • microporous materials can be synthesized by hydrothermal or solvothermal techniques (e.g., sol-gel) where crystals are slowly grown from a solution.
  • Templating for the micro structure can be provided by a secondary building unit (SBU) and the organic ligands.
  • SBU secondary building unit
  • Alternate synthesis techniques are also available, such as physical vapor deposition or chemical vapor deposition, in which metal oxide precursor layers are deposited, either as a primary microporous material, or as a precursor to an MOF structure formed by exposure of the precursor layers to sublimed ligand molecules to impart a phase
  • the above-described membrane materials can provide a technical effect of promoting separation of contaminants (e.g., nitrogen, oxygen and/or water molecules) from refrigerant gas, which is condensable.
  • contaminants e.g., nitrogen, oxygen and/or water molecules
  • Other air-permeable materials such as porous or non-porous polymers can be subject to solvent interaction with the matrix material, which can interfere with effective separation.
  • the capabilities of the materials described herein can provide a technical effect of promoting the implementation of a various example embodiments of refrigeration systems with purge, as described in more detail with reference to the example embodiments below.
  • the membrane material can be self-supporting or it can be supported, for example, as a layer on a porous support or integrated with a matrix support material.
  • thickness of a support for a supported membrane can range from 50 nm to 1000 nm, more specifically from 100 nm to 750 nm, and even more specifically from 250 nm to 500 nm.
  • fiber diameters can range from 100 nm to 2000 nm, and fiber lengths can range from 0.2 m to 2 m.
  • the microporous material can be deposited on a support as particles in a powder or dispersed in a liquid earner using various techniques such as spray coating, dip coating, solution casting, etc.
  • the dispersion can contain various additives, such as dispersing aids, rheology modifiers, etc.
  • Polymeric additives can be used; however, a polymer binder is not needed, although a polymer binder can be included and in some embodiments is included such as with a mixed matrix membrane comprising a microporous inorganic material (e.g., microporous ceramic particles) in an organic (e.g., organic polymer) matrix.
  • a polymer binder present in an amount sufficient to form a contiguous polymer phase can provide passageways in the membrane for larger molecules to bypass the molecular sieve particles. Accordingly, in some embodiments a polymer binder is excluded.
  • a polymer binder can he present in an amount below that needed to form a contiguous polymer phase, such as embodiments in which the membrane is in series with other membranes that may be more restrictive.
  • particles of the microporous material e.g., particles with sizes of 0.01 pm to 10 mm, or in some
  • tire application of solid particles of microporous material from a liquid composition to the support surface can be assisted by application of a pressure differential across the support.
  • a pressure differential across the support For example a vacuum can be applied from the opposite side of the support as the liquid composition comprising the solid microporous particles to assist in application of the solid particles to the surface of the support.
  • a coated layer of microporous material can be dried to remove residual solvent and optionally heated to fuse the microporous particles together into a contiguous layer.
  • membrane structure configurations can be utilized, including but not limited to flat or planar configurations, tubular configurations, or spiral configurations.
  • the membrane can include a protective polymer coating or can utilize backflow or heating to regenerate the membrane.
  • the microporous material can be configured as nanoplatelets, such as zeolite nanosheets for example.
  • Zeolite nanosheet particles can have thicknesses ranging from 2 to 50 nrn, more specifically 2 to 20 nm, and even more specifically from 2 n to 10 nm.
  • Zeolite such as zeolite nanosheets can be formed from any of various zeolite structures, including but not limited to framework type MFI, MWW, FER, LTA, FAU, and mixtures of the preceding with each other or with other zeolite structures.
  • the zeolite such as zeolite nano sheets can comprise zeolite structures selected from MFI, MWW, FER, LTA framework type.
  • Zeolite nanosheets can be prepared using known techniques such as exfoliation of zeolite crystal structure precursors.
  • MFI and MWW zeolite nanosheets can be prepared by sonicating the layered precursors (muitilamellar silicalite-1 and ITQ-1 , respectively) in solvent. Prior to sonication, the zeolite layers can optionally be swollen, for example with a combination of base and surfactant, and/or melt-blending with polystyrene.
  • a prime mover 42 such as a vacuum pump for example, may be selectively coupled to the separator 36.
  • the prime mover 42 may provide a driving force to pass contaminant gas molecules through the separation component 40, such that the contaminant molecules exit from a second side of the membrane and through an outlet of the purge system 30.
  • the prime mover 42 can be positioned within the fluid loop.
  • a refrigerant pump or compressor may be used as the prime mover. Refrigerant gas tends to remain on the first side of the separation component 40 and may be returned to the heat pump 10, such as to the evaporator 18 for example, through a connection or conduit illustrated at 44.
  • a controller 50 is operably coupled to the prime mover 42 of the purge system 30.
  • the controller 50 receives system data (e.g., pressure, temperature, mass flow rates) and utilizes electronic control components, such as a microprocessor for example, to control one or more components of the purge system 30, such as various pumps, valves, and switches for example, in response to the system data.
  • system data e.g., pressure, temperature, mass flow rates
  • electronic control components such as a microprocessor for example
  • the purge system 30 illustrated and described herein is intended as an example only, and other configurations are also within the scope of the disclosure.
  • Other examples of purge systems contemplated herein are set forth in more detail in U.S. Patent Application Serial No. 15/808,837 filed on November 9, 2017, the entire contents of which is incorporated herein by reference.
  • the refrigerant may be passively decontaminated.
  • the pressure from the condenser may create a pressure differential suitable to achieve the required driving force across the separation component 40.
  • contamination passes through the membrane from a first side to a second side.
  • active decontamination of the separation component 40 is initiated.
  • the prime mover 42 is used to provide the necessary pressure differential across the separation component 40 for decontamination.
  • the separator 36 includes a housing 60 having a generally hollow interior 62.
  • the housing 60 is shown as being generally cylindrical in shape, it should be understood that a housing 60 having any shape is within the scope of the disclosure.
  • the housing 60 includes a fluid inlet 64, a first fluid outlet 66 and a second fluid outlet 68.
  • the fluid inlet 64 is arranged adjacent a first end 70 of the housing 60
  • the first fluid outlet 66 is arranged adjacent a second, opposite end 72 of the housing 60
  • the second fluid outlet 68 is arranged generally centrally along an axis X defined by the separator 36.
  • other configurations of the separator housing 60 are also contemplated herein.
  • At least one separation component 40 is mounted within the hollow interior 62 of the housing 60.
  • the at least one separation component 40 includes a plurality of degassing tubes positioned longitudinally within the hollow interior 62 of the housing 60.
  • each of the degassing tubes includes a body 74 formed from a ceramic zeolite material.
  • the degassing tubes may additionally include a metal connector 76 mounted at each end of the body 74, as shown in the FIG. 3.
  • the metal connectors 76 may be used to mount or connect the degassing tubes to another component.
  • the plurality of d egassing tubes are aligned with each other and are spaced apart from one another to permit a transverse fluid flow 7 between adjacent degassing tubes.
  • the separator 36 additionally includes one or more baffle or header plates 78 for mounting the degassing tubes within the hollow interior 62 of the housing 60.
  • each header plate 78 includes a plurality of openings formed therein, and an end of each degassing tube, and more specifically a metal connector 76 of each degassing tube, is receivable within a corresponding opening of the plurality of openings of each header plate 78.
  • an outer diameter of each of the header plates 78 is complementary to an inner diameter of the housing 60.
  • the header plates 78 act as partitions or dividers to separate the hollow 7 interior 62 of the housing 60 into a plurality of zones, such as a first zone 80, a second zone 82, and a third zone 84 for example.
  • the first zone 80 is in fluid communication with the fluid inlet 64
  • the second zone 82 is in fluid communication with the second fluid outlet 68
  • the third zone 84 is in fluid communication with the first fluid outlet 66.
  • the separator 36 may include additional baffles spaced longitudinally over the body 74 of the tubes 40 to support the plurality of degassing tubes.
  • the size and contour of the additional baffles may but need not be complementary to the hollow 7 interior 62 of the housing 60.
  • a refrigerant including contaminants output from the purge collector 32 is provided to the first zone 80 of the hollow interior 62 of the separator 36 via the fluid inlet 64 From the first zone 80, the refrigerant is provided to the plurality of degassing tubes. As the refrigerant flows through the degassing tubes 40, at least a portion of the contaminants contained therein, such as air for example, diffuses through the sidewalls of the degassing tubes into the second zone 82 of the hollow 7 interior 62 of the housing 60. From the second zone, the contaminants may be exhausted from the separator 36 via the second fluid outlet 68.
  • the refrigerant provided to the third zone 84 of the hollow interior 62 via the degassing tubes has a reduced concentration of contaminants compared to the refrigerant provided to the first zone 80 of the hollow interior 62.
  • the refrigerant is provided to the first fluid outlet 66, for return to the heat pump 10, such as via the conduit 44 for example.
  • the contaminated refrigerant is provided to an interior of the degassing tubes, and the contaminants separated therefrom transfer radially outwardly to an exterior of the degassing tubes.
  • the contaminated refrigerant contact an exterior surface of the at least one separation component 40, and the contaminants separated therefrom may transfer radially inwardly into an interior of the at least one separation component 40.
  • the at least one separation component 40 includes one or more inorganic membranes having a porous surface through which gas, but not refrigerant, can diffuse.
  • a single membrane 40 is mounted generally centrally within the hollow interior along the longitudinal axis X.
  • the separation component 40 generally includes a hollow interior 86 having a sealed first end 88 located near the first end 70 of the housing 60, and a second, open end 90, positioned adjacent the second, opposite end 72 of the housing 60.
  • a contaminated refrigerant output from the purge collector 32 is provided to the first zone 80 of the hollow interior 62 of the housing 60 of the separator 36 via the fluid inlet 64. From the first zone 80, the refrigerant flow's through one or more openings 92 formed in the first header plate 78 into the second zone 82. Within the second zone 82, the contaminated refrigerant contacts the exterior surface 94 of the at least one separation component 40, causing the contaminants, such as air for example, to diffuse through the sidewall and into the hollow interior 86 of the separation component 40.
  • the contaminants may be provided to the third zone 84, and ultimately, to the first fluid outlet 66 where the contaminants may be exhausted from the purge system 30.
  • the refrigerant within the second zone 82 is provided to the second fluid outlet 68 for return to the heat pump 10, such as via the conduit 44 for example.
  • the header plate 78 positioned adjacent the first end 70 of the separator 36 includes one or more holes 92 through which refrigerant within the first zone 80 is communicated to the second zone 82.
  • one or more turbulence-generating features 96 may be mounted within the hollow interior 62 of the housing 60, generally adjacent to the at least one separation component 40. The turbulence-generating features 96 are intended to mix or interrupt the flow within the second zone 82 of the housing 60, thereby increasing and/or maximizing the contact between the contaminated refrigerant and the exterior surface 94 of the separation component 40.
  • turbulence-generating features 96 include, but are not limited to turbulators, baffles, vortex creators, oscillators, and ejectors. In embodiments including a plurality of turbulence-generating features 96, the turbulence-generating features 96 may vary in one or more of type, size, and shape, or alternatively, may be substantially identical.
  • Vibration generated by operation of the heat pump 10 may damage the separation component 40, thereby reducing the functionality of tire purge system 30.
  • the separation component 40 may be isolated from the vibration of the heat pump 10.
  • the separator 36 includes one or more vibration isolators 100.
  • the vibration isolators may be formed form a flexible material, such as elastomer or rubber for example, and are configured to dampen vibrations by absorbing energy.
  • the vibration isolators 100 are vibration dampening pads positioned at an intermediate portion of the separation component 40, such as at the interface between the body 74 and the metal connectors 76 for example.
  • the vibration isolators 100 function as a connector suitable for use with both a ceramic material and metal material.
  • each separation component 40 may include a plurality of layers, and the vibration isolator 100 located at an intermediate portion of the separation component 100 may be positioned between adjacent layers thereof.
  • the vibration isolators 100 may be arranged at the interface between the separation component 40 and the header plates 78 or other components used to mounted the separation component 40 within the hollow interior 62 of the housing 60.
  • the vibration isolators 100 may be positioned at the interface between the separator 36 and the remainder of the purge system 30.
  • a vibration isolator 100 may be mounted at the portion of the housing 60 defining at least one of the fluid inlet 64, the first fluid outlet 66, and the second fluid outlet 68.
  • a purge system 30 including one or more vibration isolators 100 for limiting the vibration transmitted to the separator 36 and/or the separation component 40 ensures longer operation and durability of the separation component, while achieving minima l refrigerant loss, and lower operating and maintenance costs.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
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  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

A separator for removing contamination from a fluid of a heat pump includes a housing having a hollow interior, a separation component mounted within the hollow interior, and at least one turbulence-generating element positioned within the hollow interior adjacent the separation component.

Description

MEMBRANE PURGE SYSTEM
CROSS REFERENCE TO RELATED APPLICATIONS
This application claims the benefit of US Application No. 62/774,722, filed on December 3, 2018, which is incorporated herein by reference in its entirety.
BACKGROUND
[0001] Embodiments of the present disclosure relate generally to chiller systems used in air conditioning systems, and more particularly to a purge system for removing contaminants from a refrigeration system .
[0002] Chiller systems such as those utilizing centrifugal compressors may include sections that operate below atmospheric pressure. As a result, leaks in the chiller system may draw air into the system, contaminating the refrigerant. This contamination degrades the performance of the chiller system . To address this problem, existing low pressure chillers include a purge unit to remove contamination. Existing purge units typically use a vapor compression cycle to separate contaminant gas from the refrigerant. Existing purge units are complicated and lose refrigerant in the process of removing contamination .
BRIEF DESCRIPTION
[0003] According to an embodiment, a separator for removing contamination from a fluid of a heat pump includes a housing having a hollow in terior, a separation component mounted within the hollow interior, and at least one turbulence-generating element positioned within the hollow interior adjacent the separation component.
[0004] In addition to one or more of the features described above, or as an alternative, in further embodiments the at least one turbulence -generating element extends into a flow of the fluid adjacent to the separation component.
[0005] In addition to one or more of the features described above, or as an alternative, in further embodiments the at least one turbulence-generating element extends adjacent to an exterior surface of the separation component.
[0006] In addition to one or more of the features described above, or as an alternative, in further embodiments the at least one turbulence-generating element Includes a baffle.
[0007] In addition to one or more of the features described above, or as an alternative, in further embodiments the at least one turbulence-generating element includes a turbuiator. [0008] In addition to one or more of the features described above, or as an alternative, in further embodiments the at least one turbulence-generating element includes an ejector.
[0009] In addition to one or more of the features described above, or as an alternative, in further embodiments the at least one turbulence-generating element includes a plurality of turbulence-generating elements spaced along a longitudinal axis of the separation component.
[0010] In addition to one or more of the features described above, or as an alternative, in further embodiments the plurality of turbulence-generating elemen ts are substantially identical.
[0011] In addition to one or more of the features described above, or as an alternative, in further embodiments a configuration of at least one of the plurality of turbulence- generating elements varies from a configuration of a remainder of the plurality of turbulence- generating elements.
[0012] According to an embodiment, a separator for removing contamination from a fluid of a heat pump system includes a housing having a hollow interior, a separation component mounted within the hollow interior, and at least one vibration isolator mounted at an interface of the separation component.
[0013] In addition to one or more of the features described above, or as an alternative, in further embodiments the at least one vibration isolator is positioned at an intermediate portion of the separation component.
[0014] In addition to one or more of the features described above, or as an alternative, in further embodiments the separation component is mounted within the hollow interior by at least one header plate.
[0015] In addition to one or more of the features described above, or as an alternative, in further embodiments the at least one vibration isolator is mounted between the separation component and the at least one header plate.
[0016] In addition to one or more of the features described above, or as an alternative, in further embodiments the at least one vibration isolator is mounted at a portion of the separator fluidly connectable to the heat pump system.
[0017] In addition to one or more of the features described above, or as an alternative, in further embodiments the at least one vibration isolator is tnechnica!ly connected, but not fluidly connected to the heat pump system.
[ 0018] In addition to one or more of the features described above, or as an alternative, in further embodiments the at least one vibration isolator is formed from a flexible material. [0019] In addition to one or more of the features described above, or as an alternative, in further embodiments the at least one vibration isolator is a vibration dampening pad.
BRIEF DESCRIPTION OF THE DRAWINGS
[0020] The following descriptions should not be considered limiting in any way.
With reference to the accompanying drawings, like elements are numbered alike:
[0021] FIG 1 is a schematic diagram of a heat pump of a refrigerant system;
[0022] FIG 2 is a schematic diagram of a purge system according to an embodiment;
[0023] FIG. 3 is a perspective view' of a separator of a purge system according to an embodiment;
[ 0024] FIG. 4 is a schematic cross-sectional view' of a separator of a purge system according to an embodiment;
[0025] FIG. 5 is a schematic cross-sectional view' of a separator of a purge system according to another embodiment; and
[0026] FIG. 6 is an end view' of a header plate of a separator of a purge system according to an embodiment;
DETAILED DESCRIPTION
[0027] A detailed description of one or more embodiments of the disclosed apparatus and method are presented herein by way of exemplification and not limitation with reference to the Figures.
[0028] Referring now' to FIG. I, an example of a heat pump 10 is illustrated. As used herein, the terni heat pump is intended to include any system capable of heating and/or cooling, such as a vapor compression system, a sorption system, a geothermal system, a waste heat recovery system, a heat based cooling system, and a heating system. As showm, the heat pump 10 includes a compressor 12, a condenser 14, an expansion valve 16, and an evaporator 18 arranged to form a fluid loop. The compressor 12 pressurizes heat transfer fluid in its gaseous state, w'hich both heats the fluid and provides pressure to circulate it through the system. In some embodiments, the heat transfer fluid, or refrigerant, includes an organic compound. For example, in some embodiments, the refrigerant comprises at least one of a hydrocarbon, substituted hydrocarbon, a halogen-substituted hydrocarbon, a fluoro- substituted hydrocarbon, or a chloro-fluoro-substrtuted hydrocarbon.
[0029] The hot pressurized gaseous heat transfer fluid exiting from the
compressor 12 flows through a conduit 20 to a heat rejection heat exchanger such as condenser 14 The condenser is operable to transfer heat from the heat transfer fluid to the surrounding environment resulting in condensation of the hot gaseous heat transfer fluid to a pressuri zed moderate temperature liquid. The liquid heat transfer fluid exiting from the condenser 14 flows through conduit 22 to expansion valve 16, where the pressure is reduced. The reduced pressure liquid heat transfer fluid exiting the expansion valve 16 flows through conduit 24 to a heat absorption heat exchanger such as evaporator 18 The evaporator 18 functions to absorb heat from the surrounding environment and boil the heat transfer fluid. Gaseous heat transfer fluid exiting the evaporator 18 flows through conduit 26 to the compressor 12, so that the cycle may be repeated.
[0030] The heat pump 10 has the effect of transferring heat from the environment surrounding the evaporator 18 to the environment surrounding the condenser 14 The thermodynamic properties of the heat transfer fluid must allow it to reach a high enough temperature when compressed so that it is greater than the environment surrounding the condenser 14, allowing heat to be transferred to the surrounding environment. The thermodynamic properties of the heat transfer fluid must also have a boiling point at its post expansion pressure that allows the temperature surrounding the evaporator 18 to provide heat to vaporize the liquid heat transfer fluid.
[ 0031] Various types of refrigeration systems may be classified as a heat pump 10 as illustrated and described herein. One such refrigeration system is a chiller system. Portions of a refrigeration system, such as the cooler of a chiller system for example, may operate at a low pressure (e.g. , less than atmosphere) which can cause contamination (e.g., ambient air) to be drawn into fluid loop of the heat pump 10 The contamination degrades performance of the refrigeration system. To improve operation, the heat pump 10 may additionally include a purge system 30 for removing contamination from the heat transfer fluid of the heat pump 10
[0032] With reference now' to FIG. 2, an example of a purge system 30 is illustrated in more detail. As shown, the purge system 30 includes a purge collector 32 connected to the condenser 14 of a heat pump 10 via a purge connection 34 The purge collector 32 receives purge gas including refrigerant gas and contaminants, such as nitrogen and oxygen for example, from the purge connection 34 The purge system 30 additionally includes at least one separator 36 arranged downstream from and in fluid communication with an outlet 38 of the purge collector 32. In the illustrated, non-limiting embodiment, the separator 36 includes at least one separating component 40, such as a membrane for example, for separating contaminants from the refrigerant gas. Although a single separator 36 is illustrated, it should be understood that embodiments including a plurality of separators 36, arranged in series or parallel, are also contemplated herein.
[0033] in embodiments where the separation component 40 includes a membrane, the membrane may includes a porous inorganic material. Examples of porous inorganic material can include ceramics such as metal oxides or metal silicates, more specifically
aluminosilicates, (e.g., Chabazite Framework (CHA) zeolite, Linde type A (LTA) zeolite, porous carbon, porous glass, clays (e.g., Montmori!lonrte, Halloysite). Porous inorganic materials can also include porous metals such as platinum and nickel. Hybrid inorganic- organic materials such as a metal organic framework (MQF) can also be used. Other materials can be present in the membrane such as a carrier in which a mieroporous material can be dispersed, which can be included for structural or process considerations.
[0034] Metal organic framework materials are well-known in the art, and comprise metal ions or clusters of metal ions coordinated to organic ligands to form one-, two- or three-dimensional structures. A metal-organic framework can be characterized as a coordination network with organic ligands containing voids. The coordination network can be characterized as a coordination compound extending, through repeating coordination entities, in one dimension, but with cross-links between two or more individual chains, loops, or spiro-links, or a coordination compound extending through repeating coordination entities in tw'o or three dimensions. Coordination compounds can include coordination polymers with repeating coordination entities extending in one, two, or three dimensions. Examples of organic ligands include but are not limited to bidentate carboxylat.es (e.g., oxalic acid, succinic acid, phthalic acid isomers, etc.), tridentate carboxylates (e.g., citric acid, trimesic acid), azoles (e.g., 1 ,2,3-triazole), as well as other known organic ligands. A wide variety of metals can be included in a metal organic framework. Examples of specific metal organic framework materials include but are not limited to zeolitic imidazole framew'ork (ZIP), HKUST-1.
[0035] In some embodiments, pore sizes of the material of the membrane can be characterized by a pore size distribution with an average pore size from 2.5 A to 10.0 A, and a pore size distribution of at least 0.1 A. In some embodiments, the average pore size for the porous material can be in a range with a lower end of 2.5 A to 4.0 A and an upper end of 2.6 A to 10.0 A. A . In some embodiments, the average pore size can be in a range having a lower end of 2.5 A, 3.0 A, 3.5 A, and an upper end of 3.5 A, 5.0 A, or 6.0 A. These range endpoints can be independently combined to form a number of different ranges, and ail ranges for each possible combination of range endpoints are hereby disclosed. Porosity of the material can be in a range having a lower end of 5%, 10%, or 15%, and an upper end of 85%, 90%, or 95% (percentages by volume). These range endpoints can be independently combined to form a number of different ranges, and all ranges for each possible combination of range endpoints are hereby disclosed.
[0036] The above microporous materials can be synthesized by hydrothermal or solvothermal techniques (e.g., sol-gel) where crystals are slowly grown from a solution. Templating for the micro structure can be provided by a secondary building unit (SBU) and the organic ligands. Alternate synthesis techniques are also available, such as physical vapor deposition or chemical vapor deposition, in which metal oxide precursor layers are deposited, either as a primary microporous material, or as a precursor to an MOF structure formed by exposure of the precursor layers to sublimed ligand molecules to impart a phase
transformation to an MOF crystal lattice.
[0037] In some embodiments, the above-described membrane materials can provide a technical effect of promoting separation of contaminants (e.g., nitrogen, oxygen and/or water molecules) from refrigerant gas, which is condensable. Other air-permeable materials, such as porous or non-porous polymers can be subject to solvent interaction with the matrix material, which can interfere with effective separation. In some embodiments, the capabilities of the materials described herein can provide a technical effect of promoting the implementation of a various example embodiments of refrigeration systems with purge, as described in more detail with reference to the example embodiments below.
[0038] The membrane material can be self-supporting or it can be supported, for example, as a layer on a porous support or integrated with a matrix support material. In some embodiments, thickness of a support for a supported membrane can range from 50 nm to 1000 nm, more specifically from 100 nm to 750 nm, and even more specifically from 250 nm to 500 nm. In the case of tubular membranes, fiber diameters can range from 100 nm to 2000 nm, and fiber lengths can range from 0.2 m to 2 m.
[0039] In some embodiments, the microporous material can be deposited on a support as particles in a powder or dispersed in a liquid earner using various techniques such as spray coating, dip coating, solution casting, etc. The dispersion can contain various additives, such as dispersing aids, rheology modifiers, etc. Polymeric additives can be used; however, a polymer binder is not needed, although a polymer binder can be included and in some embodiments is included such as with a mixed matrix membrane comprising a microporous inorganic material (e.g., microporous ceramic particles) in an organic (e.g., organic polymer) matrix. However, a polymer binder present in an amount sufficient to form a contiguous polymer phase can provide passageways in the membrane for larger molecules to bypass the molecular sieve particles. Accordingly, in some embodiments a polymer binder is excluded.
In other embodiments, a polymer binder can he present in an amount below that needed to form a contiguous polymer phase, such as embodiments in which the membrane is in series with other membranes that may be more restrictive. In some embodiments, particles of the microporous material (e.g., particles with sizes of 0.01 pm to 10 mm, or in some
embodiments from 0.5 pm to 10 pm) can be applied as a powder or dispersed in a liquid carrier (e.g., an organic solvent or aqueous liquid carrier) and coated onto the support followed by removal of the liquid. In some embodiments, tire application of solid particles of microporous material from a liquid composition to the support surface can be assisted by application of a pressure differential across the support. For example a vacuum can be applied from the opposite side of the support as the liquid composition comprising the solid microporous particles to assist in application of the solid particles to the surface of the support. A coated layer of microporous material can be dried to remove residual solvent and optionally heated to fuse the microporous particles together into a contiguous layer.
Various membrane structure configurations can be utilized, including but not limited to flat or planar configurations, tubular configurations, or spiral configurations. In some embodiments, the membrane can include a protective polymer coating or can utilize backflow or heating to regenerate the membrane.
[0040] In some embodiments, the microporous material can be configured as nanoplatelets, such as zeolite nanosheets for example. Zeolite nanosheet particles can have thicknesses ranging from 2 to 50 nrn, more specifically 2 to 20 nm, and even more specifically from 2 n to 10 nm. Zeolite such as zeolite nanosheets can be formed from any of various zeolite structures, including but not limited to framework type MFI, MWW, FER, LTA, FAU, and mixtures of the preceding with each other or with other zeolite structures. In a more specific group of exemplary embodiments, the zeolite such as zeolite nano sheets can comprise zeolite structures selected from MFI, MWW, FER, LTA framework type. Zeolite nanosheets can be prepared using known techniques such as exfoliation of zeolite crystal structure precursors. For example, MFI and MWW zeolite nanosheets can be prepared by sonicating the layered precursors (muitilamellar silicalite-1 and ITQ-1 , respectively) in solvent. Prior to sonication, the zeolite layers can optionally be swollen, for example with a combination of base and surfactant, and/or melt-blending with polystyrene. The zeolite layered precursors are typically prepared using conventional techniques for preparation of microporous materials such as sol-gel methods. [0041] With continued reference to FIG. 2, a prime mover 42, such as a vacuum pump for example, may be selectively coupled to the separator 36. The prime mover 42 may provide a driving force to pass contaminant gas molecules through the separation component 40, such that the contaminant molecules exit from a second side of the membrane and through an outlet of the purge system 30. In an embodiment, the prime mover 42 can be positioned within the fluid loop. For example, a refrigerant pump or compressor may be used as the prime mover. Refrigerant gas tends to remain on the first side of the separation component 40 and may be returned to the heat pump 10, such as to the evaporator 18 for example, through a connection or conduit illustrated at 44.
[0042] A controller 50 is operably coupled to the prime mover 42 of the purge system 30. In an embodiment, the controller 50 receives system data (e.g., pressure, temperature, mass flow rates) and utilizes electronic control components, such as a microprocessor for example, to control one or more components of the purge system 30, such as various pumps, valves, and switches for example, in response to the system data. The purge system 30 illustrated and described herein is intended as an example only, and other configurations are also within the scope of the disclosure. Other examples of purge systems contemplated herein are set forth in more detail in U.S. Patent Application Serial No. 15/808,837 filed on November 9, 2017, the entire contents of which is incorporated herein by reference.
[0043] When the heat pump 10 is operational, the refrigerant may be passively decontaminated. The pressure from the condenser may create a pressure differential suitable to achieve the required driving force across the separation component 40. As a result, contamination passes through the membrane from a first side to a second side. When the heat pump 10 is non-operational, active decontamination of the separation component 40 is initiated. During active decontamination, the prime mover 42 is used to provide the necessary pressure differential across the separation component 40 for decontamination.
[0044] With reference now to FIGS. 3 - 5, various configurations of tire separator 36 are shown. In each of the embodiments illustrated herein, the separator 36 includes a housing 60 having a generally hollow interior 62. Although the housing 60 is shown as being generally cylindrical in shape, it should be understood that a housing 60 having any shape is within the scope of the disclosure. In addition, the housing 60 includes a fluid inlet 64, a first fluid outlet 66 and a second fluid outlet 68. In the illustrated embodiments, the fluid inlet 64 is arranged adjacent a first end 70 of the housing 60, the first fluid outlet 66 is arranged adjacent a second, opposite end 72 of the housing 60, and the second fluid outlet 68 is arranged generally centrally along an axis X defined by the separator 36. However, other configurations of the separator housing 60 are also contemplated herein.
[0045] At least one separation component 40 is mounted within the hollow interior 62 of the housing 60. As shown in FIG. 3, in an embodiment, the at least one separation component 40 includes a plurality of degassing tubes positioned longitudinally within the hollow interior 62 of the housing 60. In an embodiment, each of the degassing tubes includes a body 74 formed from a ceramic zeolite material. The degassing tubes may additionally include a metal connector 76 mounted at each end of the body 74, as shown in the FIG. 3.
The metal connectors 76 may be used to mount or connect the degassing tubes to another component. In the illustrated, non-limiting embodiment, the plurality of d egassing tubes are aligned with each other and are spaced apart from one another to permit a transverse fluid flow7 between adjacent degassing tubes.
[0046] The separator 36 additionally includes one or more baffle or header plates 78 for mounting the degassing tubes within the hollow interior 62 of the housing 60. As shown, each header plate 78 includes a plurality of openings formed therein, and an end of each degassing tube, and more specifically a metal connector 76 of each degassing tube, is receivable within a corresponding opening of the plurality of openings of each header plate 78. In the illustrated, non-limiting embodiment, an outer diameter of each of the header plates 78 is complementary to an inner diameter of the housing 60. As a result, the header plates 78 act as partitions or dividers to separate the hollow7 interior 62 of the housing 60 into a plurality of zones, such as a first zone 80, a second zone 82, and a third zone 84 for example. The first zone 80 is in fluid communication with the fluid inlet 64, the second zone 82 is in fluid communication with the second fluid outlet 68, and the third zone 84 is in fluid communication with the first fluid outlet 66. It should be understood that the separator 36 may include additional baffles spaced longitudinally over the body 74 of the tubes 40 to support the plurality of degassing tubes. In such embodiments, the size and contour of the additional baffles, may but need not be complementary to the hollow7 interior 62 of the housing 60.
[0047] During operation, a refrigerant including contaminants output from the purge collector 32 is provided to the first zone 80 of the hollow interior 62 of the separator 36 via the fluid inlet 64 From the first zone 80, the refrigerant is provided to the plurality of degassing tubes. As the refrigerant flows through the degassing tubes 40, at least a portion of the contaminants contained therein, such as air for example, diffuses through the sidewalls of the degassing tubes into the second zone 82 of the hollow7 interior 62 of the housing 60. From the second zone, the contaminants may be exhausted from the separator 36 via the second fluid outlet 68. Accordingly, the refrigerant provided to the third zone 84 of the hollow interior 62 via the degassing tubes has a reduced concentration of contaminants compared to the refrigerant provided to the first zone 80 of the hollow interior 62. Once output into the third zone 84, the refrigerant is provided to the first fluid outlet 66, for return to the heat pump 10, such as via the conduit 44 for example. Accordingly, in the non-limiting embodiment of FIG 3, the contaminated refrigerant is provided to an interior of the degassing tubes, and the contaminants separated therefrom transfer radially outwardly to an exterior of the degassing tubes.
[0048] In another embodiment, best shown in FIGS. 4 and 5, the contaminated refrigerant contact an exterior surface of the at least one separation component 40, and the contaminants separated therefrom may transfer radially inwardly into an interior of the at least one separation component 40. For example, in the non-limiting embodiment of FIGS. 4- 5, the at least one separation component 40 includes one or more inorganic membranes having a porous surface through which gas, but not refrigerant, can diffuse. As shown, a single membrane 40 is mounted generally centrally within the hollow interior along the longitudinal axis X. However, it should be understood that embodiments including a plurality of membranes are also within the scope of the disclosure. The separation component 40 generally includes a hollow interior 86 having a sealed first end 88 located near the first end 70 of the housing 60, and a second, open end 90, positioned adjacent the second, opposite end 72 of the housing 60.
[0049] During operation of the system of FIGS. 4 and 5 , a contaminated refrigerant output from the purge collector 32 is provided to the first zone 80 of the hollow interior 62 of the housing 60 of the separator 36 via the fluid inlet 64. From the first zone 80, the refrigerant flow's through one or more openings 92 formed in the first header plate 78 into the second zone 82. Within the second zone 82, the contaminated refrigerant contacts the exterior surface 94 of the at least one separation component 40, causing the contaminants, such as air for example, to diffuse through the sidewall and into the hollow interior 86 of the separation component 40. From the hollow interior 86 of the separation component 40, the contaminants may be provided to the third zone 84, and ultimately, to the first fluid outlet 66 where the contaminants may be exhausted from the purge system 30. The refrigerant within the second zone 82 is provided to the second fluid outlet 68 for return to the heat pump 10, such as via the conduit 44 for example. By positioning the second fluid outlet 68 at the downstream end of the second zone 82 relative to the direction of flow through the separator 36, the refrigerant output from the separator 36 has a reduced concentration of contaminants therein compared to the refrigerant provided to the fluid inlet 64 of the separator 36.
[0050] in the illustrated, non-limiting embodiments of FIGS. 4 and 5, the header plate 78 positioned adjacent the first end 70 of the separator 36 includes one or more holes 92 through which refrigerant within the first zone 80 is communicated to the second zone 82. In such embodiments, one or more turbulence-generating features 96 may be mounted within the hollow interior 62 of the housing 60, generally adjacent to the at least one separation component 40. The turbulence-generating features 96 are intended to mix or interrupt the flow within the second zone 82 of the housing 60, thereby increasing and/or maximizing the contact between the contaminated refrigerant and the exterior surface 94 of the separation component 40. Including one or more the turbulence -generating will not only improve the performance of the purge system 30, but will also increase the robustness and reliability of the separator 36. Examples of suitable turbulence-generating features 96 include, but are not limited to turbulators, baffles, vortex creators, oscillators, and ejectors. In embodiments including a plurality of turbulence-generating features 96, the turbulence-generating features 96 may vary in one or more of type, size, and shape, or alternatively, may be substantially identical.
[ 0051] Vibration generated by operation of the heat pump 10 may damage the separation component 40, thereby reducing the functionality of tire purge system 30.
Accordingly, in an embodiment, the separation component 40 may be isolated from the vibration of the heat pump 10. With reference again to FIG. 3, in an embodiment, the separator 36 includes one or more vibration isolators 100. The vibration isolators may be formed form a flexible material, such as elastomer or rubber for example, and are configured to dampen vibrations by absorbing energy. In the illustrated, non-limiting embodiment, the vibration isolators 100 are vibration dampening pads positioned at an intermediate portion of the separation component 40, such as at the interface between the body 74 and the metal connectors 76 for example. In such embodiments, the vibration isolators 100 function as a connector suitable for use with both a ceramic material and metal material. Accordingly, vibrations from the heat pump 10, which may be transmitted from the separator housing 60 to the metal connectors 76 via the header plate 78, are dampened by the one or more vibration isolators 100 mounted at each end of the separation component 40. In other embodiments, each separation component 40 may include a plurality of layers, and the vibration isolator 100 located at an intermediate portion of the separation component 100 may be positioned between adjacent layers thereof. [0052] In another embodiment, beset shown in FIG. 6, the vibration isolators 100 may be arranged at the interface between the separation component 40 and the header plates 78 or other components used to mounted the separation component 40 within the hollow interior 62 of the housing 60. Alternatively, or in addition, the vibration isolators 100 may be positioned at the interface between the separator 36 and the remainder of the purge system 30. For example, a vibration isolator 100 may be mounted at the portion of the housing 60 defining at least one of the fluid inlet 64, the first fluid outlet 66, and the second fluid outlet 68.
[0053] A purge system 30 including one or more vibration isolators 100 for limiting the vibration transmitted to the separator 36 and/or the separation component 40 ensures longer operation and durability of the separation component, while achieving minima l refrigerant loss, and lower operating and maintenance costs.
[ 0054] The term“about” is intended to include the degree of error associated with measurement of the particular quantity based upon the equipment available at the time of filing the application
[0055] The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the present disclosure. As used herein, the singular forms“a”,“an” and“the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or“comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, element components, and/or groups thereof.
[0056] While the present disclosure has been described with reference to an exemplary embodiment or embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the present disclosure. In addition, many modifications may be made to adapt a particular situation or materi al to the teachings of the present disclosure without departing from the essential scope thereof. Therefore, it is intended that the present disclosure not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this present disclosure, but that the present disclosure will include all embodiments falling within the scope of the claims.

Claims

What is claimed is:
1. A separator for removing contamination from a fluid of a heat pump comprising: a housing having a hollow interior;
a separation component mounted within the hollow interior; and
at least one turbulence-generating element positioned within the hollow interior adjacent the separation component.
2. The separator of claim 1, wherein the at least one turbulence-generating element extends into a flow of the fluid adjacent to the separation component.
3. The separator of claim 2, wherein the at least one turbulence-generating element extends adjacent to an exterior surface of the separation component
4. The separator of claim 1, wherein the at least one turbulence-generating element includes a baffle.
5. The separator of claim 1, wherein the at least one turbulence-generating element includes a turbulator.
6. The separator of claim 1, wherein the at least one turbulence-generating element includes an ejector.
7. The separator of claim 1, wherein the at least one turbulence-generating element includes a plurality of turbulence-generating elements spaced along a longitudinal axis of the separation component.
8. The separator of claim 7, wherein the plurality of turbulence-generating elements are substantially identical.
9. The separator of claim 7, wherein a configuration of at least one of the plurality of turbulence-generating elements varies from a configuration of a remainder of the plurality of turbulence-generating elements .
10. A separator for removing contamination from a fluid of a heat pump system comprising:
a housing having a hollow7 interior;
a separation component mounted within the hollow7 interior; and
at least one vibration isolator mounted at an interface of the separation component.
11. The separator of claim 10, wherein the at least one vibration isolator is positioned at an intermediate portion of the separation component
12. The separator of claim 10, wherein the separation component is mounted within the hollow interior by at least one header plate.
13. The separator of claim 12 , wherein the at least one vibration i solator is mounted between the separation component and the at least one header plate.
14. The separator of claim 10, wherein the at least one vibration isolator is mounted at a portion of the separator fluidly connectable to the heat pump system.
15. The separator of claim 10, wherein the at least one vibration isolator is mecfanical!y connected, but not fluidly connected to the heat pump system.
16. The separator of claim 10, wherein the at least one vibration isolator is formed from a flexible material.
17. The separator of claim 10, wherein the at least one vibration isolator is a vibration dampening pad.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116407958A (en) * 2023-04-07 2023-07-11 西安交通大学 A hollow composite self-supporting membrane, its preparation method and application, and a refrigerant separation device

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112334720A (en) 2018-12-03 2021-02-05 开利公司 Enhanced refrigeration purification system
US11911724B2 (en) 2018-12-03 2024-02-27 Carrier Corporation Enhanced refrigeration purge system
US11913693B2 (en) 2018-12-03 2024-02-27 Carrier Corporation Enhanced refrigeration purge system
CN115522177B (en) * 2021-07-23 2023-05-09 上海汉钟精机股份有限公司 Intelligent powder discharge control method for coating process of solar cells
EP4283222A1 (en) * 2022-05-26 2023-11-29 Carrier Corporation Refrigeration system comprising a purge system and associated method of operating a purge system
EP4300010A1 (en) * 2022-06-28 2024-01-03 Carrier Corporation Refrigeration system, the associated method of operating a purge system, and separator system
DE102022118973A1 (en) * 2022-07-28 2024-02-08 Agilent Technologies, Inc. A Delaware Corporation Degasser with two weakly coupled rooms and/or with restriction adjustment device

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997017125A1 (en) * 1995-11-06 1997-05-15 Buxbaum Robert E Apparatus and methods for gas extraction
EP0875281A1 (en) * 1997-04-29 1998-11-04 Praxair Technology, Inc. Integrated solid electrolyte ionic conductor separator-cooler
EP0943367A1 (en) * 1998-03-20 1999-09-22 Toray Industries, Inc. Fluid separation element
US9579605B1 (en) * 2016-03-31 2017-02-28 Membrane Technology And Research, Inc. Gas separation module and assembly
US20180243685A1 (en) * 2017-02-27 2018-08-30 Honeywell International Inc. Dual stripper with water sweep gas

Family Cites Families (125)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2044166A (en) 1934-09-21 1936-06-16 Frank A Hayden Furniture
GB1112580A (en) 1965-10-08 1968-05-08 Continental Oil Co Volume compensation in vapour sorption systems
SE7812682L (en) * 1978-01-05 1979-07-06 Kuesters Eduard FILTER DEVICE
US4304102A (en) 1980-04-28 1981-12-08 Carrier Corporation Refrigeration purging system
US4316364A (en) 1980-05-07 1982-02-23 Spauschus Hans O Vapor compression refrigerant system monitor
US4417451A (en) 1980-05-07 1983-11-29 Hilliard-Lyons Patent Management, Inc. Vapor compression refrigerant system monitor and gas removal apparatus
EP0284850B1 (en) 1987-03-09 1992-06-17 Uop Improved adsorptive purification process
US4842621A (en) 1987-03-26 1989-06-27 The Dow Chemical Company Recovery process
US5059374A (en) 1989-02-09 1991-10-22 The Dow Chemical Company Method for sealing a hollow fiber membrane module in a case
US4906256A (en) 1989-03-23 1990-03-06 Membrane Technology & Research, Inc. Membrane process for treatment of fluorinated hydrocarbon-laden gas streams
US5032148A (en) 1989-11-07 1991-07-16 Membrane Technology & Research, Inc. Membrane fractionation process
JP3166108B2 (en) 1989-11-07 2001-05-14 メンブレイン・テクノロジー・アンド・リサーチ・インコーポレイテッド Cooling method for purging and collecting coolant
ATE201148T1 (en) 1989-11-07 2001-06-15 Membrane Tech & Res Inc METHOD FOR RECOVERING CONDENSABLE COMPONENTS FROM GAS STREAMS
US5044166A (en) 1990-03-05 1991-09-03 Membrane Technology & Research, Inc. Refrigeration process with purge and recovery of refrigerant
US5156657A (en) 1990-03-29 1992-10-20 The Boc Group, Inc. Process for pre-purification of air for separation
US4984431A (en) 1990-06-20 1991-01-15 Carrier Corporation High efficiency purge system
US5062273A (en) 1990-07-12 1991-11-05 E. I. Du Pont De Nemours And Company Method and apparatus for removal of gas from refrigeration system
US5071451A (en) 1990-12-28 1991-12-10 Membrane Technology & Research, Inc. Membrane process and apparatus for removing vapors from gas streams
JPH0552452A (en) 1991-08-28 1993-03-02 Hitachi Zosen Corp Deaerating device for absorption type freezer
FR2695568B1 (en) 1992-09-14 1994-10-21 Air Liquide Method and installation for gas separation by permeation.
US5598714A (en) 1993-02-19 1997-02-04 Rti Technologies, Inc. Method and apparatus for separation of refrigerant from a purge gas mixture of refrigerant and non-condensible gas
US5355685A (en) 1993-03-15 1994-10-18 Phillips Petroleum Company Purification of refrigerant
JPH07294065A (en) 1994-04-28 1995-11-10 Matsushita Refrig Co Ltd Refrigeration system
US5858065A (en) 1995-07-17 1999-01-12 American Air Liquide Process and system for separation and recovery of perfluorocompound gases
JP3343192B2 (en) 1995-07-28 2002-11-11 松下電器産業株式会社 Construction method of refrigeration system
US5636526A (en) 1995-09-28 1997-06-10 Gas Research Institute Apparatus and method for automatically purging an absorption cooling system
US5611841A (en) 1995-09-29 1997-03-18 Membrane Technology And Research, Inc. Vapor recovery process using baffled membrane module
JP3637716B2 (en) 1997-01-30 2005-04-13 松下電器産業株式会社 How to install an air conditioner
US5806322A (en) 1997-04-07 1998-09-15 York International Refrigerant recovery method
US6641733B2 (en) * 1998-09-25 2003-11-04 U. S. Filter Wastewater Group, Inc. Apparatus and method for cleaning membrane filtration modules
US6128916A (en) 1997-11-28 2000-10-10 Enerfex, Inc. Membrane technology to remove non-condensable gases from refrigeration systems
JPH11248298A (en) 1998-02-27 1999-09-14 Matsushita Electric Ind Co Ltd Refrigeration cycle
DE29900752U1 (en) * 1999-01-18 1999-08-12 Ianiero, Argentino F., Dipl.-Ing., 82110 Germering Device for membrane filtration, in particular of liquids and gases
US6134899A (en) 1999-03-19 2000-10-24 Spx Corporation Refrigerant recovery and recharging system with automatic air purging
US6224763B1 (en) * 1999-05-05 2001-05-01 Alberta Res Council Hollow-fiber membrane device including a split disk tube sheet support
EP1127606A1 (en) * 2000-02-24 2001-08-29 Stichting Energieonderzoek Centrum Nederland(ECN) Membrane module for the separation of fluid mixtures
US6442963B1 (en) 2000-06-23 2002-09-03 Snap-On Technologies, Inc. Non-condensable purge technique using refrigerant temperature offset
US6923944B2 (en) * 2000-07-07 2005-08-02 Robert E. Buxbaum Membrane reactor for gas extraction
US6739142B2 (en) 2000-12-04 2004-05-25 Amos Korin Membrane desiccation heat pump
US6527831B2 (en) 2000-12-29 2003-03-04 Praxair Technology, Inc. Argon purification process
US20020148238A1 (en) 2001-04-13 2002-10-17 Blume Bryan A. System and method for reconditioning a chiller
US6457326B1 (en) 2001-06-21 2002-10-01 Carrier Corporation Purge system for absorption unit
US6564564B2 (en) 2001-10-22 2003-05-20 American Standard International Inc. Purge
US20060011535A1 (en) 2002-10-07 2006-01-19 Shiro Ikeda Multi-tube separation membrane module
EP1615713A4 (en) * 2003-04-22 2006-11-02 Entegris Inc Pleated construction for effecting gas transfer membrane
JP3680278B2 (en) 2003-06-20 2005-08-10 ダイキン工業株式会社 Refrigeration equipment construction method and refrigeration equipment
CN100552330C (en) 2003-06-20 2009-10-21 大金工业株式会社 Construction method of refrigeration device and refrigeration device
JP4265369B2 (en) 2003-10-22 2009-05-20 ダイキン工業株式会社 Refrigeration equipment construction method and refrigeration equipment
JP2005127563A (en) 2003-10-22 2005-05-19 Daikin Ind Ltd Refrigeration equipment construction method and refrigeration equipment
JP4007307B2 (en) 2003-10-22 2007-11-14 ダイキン工業株式会社 Refrigeration equipment construction method
JP2005127564A (en) 2003-10-22 2005-05-19 Daikin Ind Ltd Refrigeration equipment construction method and refrigeration equipment
JP2005127565A (en) 2003-10-22 2005-05-19 Daikin Ind Ltd Refrigeration equipment construction method and refrigeration equipment
US7282148B2 (en) 2003-10-30 2007-10-16 International Business Machines Corporation Porous silicon composite structure as large filtration array
US6925821B2 (en) 2003-12-02 2005-08-09 Carrier Corporation Method for extracting carbon dioxide for use as a refrigerant in a vapor compression system
WO2006070918A1 (en) 2004-12-28 2006-07-06 Showa Denko K.K. Evaporator
RU2280496C1 (en) * 2005-01-19 2006-07-27 Государственное образовательное учреждение высшего профессионального образования "Воронежская государственная технологическая академия" Membrane apparatus with the variable section of the stream
SG158911A1 (en) 2005-01-21 2010-02-26 Exxonmobil Res & Eng Co Improved catalytic reformer unit and unit operation
US7918921B2 (en) 2005-02-04 2011-04-05 Membrane Technology And Research, Inc Gas separation membrane module assembly with residue manifold
US7393388B2 (en) * 2005-05-13 2008-07-01 United Technologies Corporation Spiral wound fuel stabilization unit for fuel de-oxygenation
EP1950512A4 (en) 2005-10-17 2014-04-02 Yue Zhang Automatic gas discharging device for lithium-bromid machine and method thereof
WO2007080685A1 (en) 2006-01-11 2007-07-19 Ngk Insulators, Ltd. Method of separating liquid mixture
JP4897298B2 (en) 2006-01-17 2012-03-14 サンデン株式会社 Gas-liquid separator module
US20070193285A1 (en) 2006-02-21 2007-08-23 Knight Paul A Testing for Leaks in a Two-Phase Liquid Cooling System
US7758670B2 (en) 2006-07-11 2010-07-20 Membrane Technology And Research, Inc Four-port gas separation membrane module assembly
US7780768B2 (en) 2006-11-28 2010-08-24 Inogen, Inc. Gas concentrator with improved water rejection capability
US7713333B2 (en) 2006-12-20 2010-05-11 Praxair Technology, Inc. Adsorbents for pressure swing adsorption systems and methods of use therefor
US8182592B2 (en) 2006-12-29 2012-05-22 Ube Industries, Ltd. Shell feed type gas separation membrane module
DE102007009760A1 (en) 2007-02-27 2008-09-04 Danfoss A/S Dryer filter unit for refrigerant circuits
GB0704797D0 (en) 2007-03-13 2007-04-18 Phoenix Ipr Ltd Membrane structures and their production and use
WO2009091403A1 (en) 2008-01-17 2009-07-23 Carrier Corporation Refrigerant vapor compression system with lubricant cooler
CN101254918B (en) 2008-03-31 2010-12-08 大连理工大学 Carbon Dioxide Purification Unit by Adsorption Distillation Technology
US8216473B2 (en) 2008-06-13 2012-07-10 Solution Dynamics, Llc Apparatus and methods for solution processing using reverse osmosis
EP2312241B1 (en) 2008-06-24 2019-11-27 Mitsubishi Electric Corporation Refrigerating cycle apparatus, and air-conditioning apparatus
US8055453B2 (en) 2008-09-19 2011-11-08 Raytheon Company Sensing and estimating in-leakage air in a subambient cooling system
CN100533003C (en) 2008-10-15 2009-08-26 东南大学 Air source solution heat pump device based on reverse osmosis membrane solution regeneration
DE102008053828A1 (en) 2008-10-30 2010-05-12 Airbus Deutschland Gmbh Improved adsorption cooling system and adsorption cooling process for an aircraft
JP2010159952A (en) 2008-12-08 2010-07-22 Kankyo Soken:Kk Device and method of separating refrigerant gas and non-condensable gas
US8652332B2 (en) 2009-01-09 2014-02-18 Massachusetts Institute Of Technology Liquid filtration using pressure difference across a hydrophobic membrane
CN201363956Y (en) 2009-03-06 2009-12-16 彭建国 Adsorption refrigerating machine
JPWO2010106881A1 (en) 2009-03-16 2012-09-20 日本碍子株式会社 Zeolite separation membrane arrangement, method for producing the same, method for separating mixed fluid, and mixed fluid separation device
US7891202B1 (en) 2009-10-07 2011-02-22 Johnson Controls Technology Company Absorption system
WO2011053683A1 (en) 2009-10-30 2011-05-05 Solution Dynamics, Llc Improved absorption refrigeration cycles; apparatus; and methods
CN101852524B (en) 2010-06-10 2012-07-04 大连三洋制冷有限公司 Refrigerant pollution automatic monitoring and scavenging system
JP5585307B2 (en) 2010-08-25 2014-09-10 三菱化学株式会社 VOC recovery equipment
US9718023B2 (en) 2010-11-04 2017-08-01 Ube Industries, Ltd. Gas separation membrane module and gas separation method
CN201954828U (en) 2011-01-11 2011-08-31 河北玉星生物工程有限公司 Efficient and energy-saving lithium bromide refrigerator
EP2481474B1 (en) * 2011-01-27 2015-06-24 Filtrox Engineering AG Sealing assembly for rod-shaped ceramic filter elements
US8394171B2 (en) 2011-03-17 2013-03-12 Uop Llc Methods for controlling impurity buildup on adsorbent for pressure swing adsorption processes
JP5890981B2 (en) * 2011-08-19 2016-03-22 日立造船株式会社 Separation membrane module
ITRE20110084A1 (en) 2011-10-17 2013-04-18 Ufi Innovation Ct Srl FILTERING GROUP
US9074801B2 (en) 2011-11-14 2015-07-07 Bosch Automotive Services Solutions INC. Apparatus and method for identifying and operating air purge in safe mode and having a dip tube
US10190808B2 (en) 2012-04-30 2019-01-29 Trane International Inc. Refrigeration system with purge and acid filter
US20130283832A1 (en) 2012-04-30 2013-10-31 Trane International Inc. Refrigeration system with purge using enrivonmentally-suitable chiller refrigerant
WO2014024961A1 (en) 2012-08-10 2014-02-13 宇部興産株式会社 Gas-separating membrane module
US9199191B2 (en) 2012-08-17 2015-12-01 Ube Industries, Ltd. Gas separation membrane module and method of replacing a hollow fiber element
KR101533348B1 (en) 2012-12-05 2015-07-03 한라비스테온공조 주식회사 Absorption type air conditioning system for automotive vehicles
US20160025393A1 (en) 2013-03-15 2016-01-28 Armstrong International, Inc. Refrigeration Purger Monitor
US9067169B2 (en) 2013-05-28 2015-06-30 Uop Llc Methods of preparing an impurity-depleted hydrogen stream, methods of analyzing content of an impurity-depleted hydrogen stream, and pressure swing adsorption apparatuses
FR3006909B1 (en) 2013-06-18 2020-10-16 Nitrocraft PROCESS FOR DEPURING A GAS MIXTURE AND CORRESPONDING GENERATOR
US9987568B2 (en) 2013-08-09 2018-06-05 Carrier Corporation Purge system for chiller system
US10584906B2 (en) 2013-08-09 2020-03-10 Carrier Corporation Refrigeration purge system
US9339768B2 (en) * 2013-08-23 2016-05-17 3M Innovative Properties Company Multi-cartridge membrane contactors, modules, systems, and related methods
CN203657302U (en) 2013-12-30 2014-06-18 上海宝丰机械制造有限公司 Air separator of refrigeration system
JP2015136364A (en) 2014-01-21 2015-07-30 ノリ・トレーディング有限会社 Device of long-term freshness keeping container and warehouse for such as vegetable, fruit and grain with reliable safety using system of air purification of superfine water and cultivation environment in natural world
JP6221889B2 (en) * 2014-03-26 2017-11-01 三菱ケミカル株式会社 Multi-tube separation membrane module
EP3364131A1 (en) 2014-04-04 2018-08-22 Climeon AB Removal of non-condensble gases from a closed-loop process
CN105091407B (en) 2014-05-08 2019-05-17 松下知识产权经营株式会社 heat pump device
US9989285B2 (en) 2014-07-31 2018-06-05 John H Fountain Purging apparatus
US9073808B1 (en) 2014-09-15 2015-07-07 Membrane Technology And Research, Inc. Process for recovering olefins in polyolefin plants
CN113877433B (en) 2015-02-25 2024-06-14 三菱化学株式会社 Separation membrane assembly and repair method thereof
NL2014701B1 (en) 2015-04-23 2017-01-26 Green Vision Holding Bv Method and device for desulphurizing a gas mixture according to a pressure swing adsorption process.
CA2991624A1 (en) 2015-07-13 2017-01-19 Nuvera Fuel Cells, LLC Pressure swing adsorbers with flow regulation by orifices
CN106352619B (en) 2015-07-14 2020-05-12 株式会社不二工机 Storage device
US9610534B1 (en) 2015-09-10 2017-04-04 Chevron U.S.A. Inc. Process for gas separations using zeolite SSZ-13
JP6682301B2 (en) 2016-03-08 2020-04-15 三菱重工サーマルシステムズ株式会社 Vapor compression refrigerator and control method thereof
CN109073300A (en) 2016-04-19 2018-12-21 开利公司 Cleaning systems for refrigerator systems
US10247457B2 (en) 2016-04-22 2019-04-02 Daikin Applied Americas Inc. Non-condensable gas purge system for refrigeration circuit
CN107763910A (en) 2016-08-17 2018-03-06 约克(无锡)空调冷冻设备有限公司 The method for exhausting of exhaust apparatus, refrigeration air-conditioning unit and incoagulable gas
CN108344214B (en) 2017-01-23 2020-03-17 约克(无锡)空调冷冻设备有限公司 Exhaust device, refrigeration air-conditioning system and exhaust method of non-condensable gas
CN106895617A (en) 2017-04-18 2017-06-27 中国海洋大学 For the separator of incoagulable gas in the ammonia absorption type refrigeration circulatory system
CN108061410A (en) 2017-11-29 2018-05-22 青岛海尔空调电子有限公司 A kind of refrigerant cleaning and filtering device and air conditioner
CN108413665A (en) 2018-04-26 2018-08-17 东南大学 The separator of incoagulable gas and ammonia in ammonia absorption type refrigeration system
CN112334720A (en) 2018-12-03 2021-02-05 开利公司 Enhanced refrigeration purification system
US11913693B2 (en) 2018-12-03 2024-02-27 Carrier Corporation Enhanced refrigeration purge system
US11911724B2 (en) 2018-12-03 2024-02-27 Carrier Corporation Enhanced refrigeration purge system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997017125A1 (en) * 1995-11-06 1997-05-15 Buxbaum Robert E Apparatus and methods for gas extraction
EP0875281A1 (en) * 1997-04-29 1998-11-04 Praxair Technology, Inc. Integrated solid electrolyte ionic conductor separator-cooler
EP0943367A1 (en) * 1998-03-20 1999-09-22 Toray Industries, Inc. Fluid separation element
US9579605B1 (en) * 2016-03-31 2017-02-28 Membrane Technology And Research, Inc. Gas separation module and assembly
US20180243685A1 (en) * 2017-02-27 2018-08-30 Honeywell International Inc. Dual stripper with water sweep gas

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116407958A (en) * 2023-04-07 2023-07-11 西安交通大学 A hollow composite self-supporting membrane, its preparation method and application, and a refrigerant separation device

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