WO2019217328A1

WO2019217328A1 - Gel and polymer based flow meters

Info

Publication number: WO2019217328A1
Application number: PCT/US2019/030941
Authority: WO
Inventors: Luca Bonanomi; Vincenzo COSTANZA; Chiara Daraio; Giovanni Moscato
Original assignee: California Institute of Technology
Current assignee: California Institute of Technology
Priority date: 2018-05-07
Filing date: 2019-05-06
Publication date: 2019-11-14
Anticipated expiration: 2020-11-07
Also published as: US11255870B2; US11768218B2; US20220283198A1; US20190339298A1

Abstract

A sensor includes a heater, a thermal insulator between two thermometer layers, the heater generating a thermal gradient within the thermal insulator. The thermometers give an indirect measurement of fluid flow around the sensor, based on their temperature readings. The thermometers are flexible layers including gels.

Description

GEL AND POLYMER BASED FLOW METERS

CROSS REFERENCE TO RELATED APPLICATIONS

[0001] The present application claims priority to US Provisional Patent Application No. 62/667,742, filed on May 7, 2018, the disclosure of which is incorporated herein by reference in its entirety.

TECHNICAL FIELD

[0002] The present disclosure relates to flow meters. More particularly, it relates to gel and polymer based flow meters.

BRIEF DESCRIPTION OF DRAWINGS

[0003] The accompanying drawings, which are incorporated into and constitute a part of this specification, illustrate one or more embodiments of the present disclosure and, together with the description of example embodiments, serve to explain the principles and implementations of the disclosure.

[0004] Fig. 1 illustrates convection for a surface.

[0005] Fig. 2 illustrates an exemplary sensor.

[0006] Fig. 3 illustrates an exemplary cross section of a device based on pectin cross-linked by calcium ions as a temperature sensitive layer.

[0007] Fig. 4 illustrates exemplary data for the temperature difference between the two thermometers in a sensor.

[0008] Fig. 5 illustrates a sensor.

SUMMARY [0009] In a first aspect of the disclosure, a method is described, the method comprising: at least one heater layer; at least one first thermometer layer; at least one second thermometer layer; and at least one thermal insulator layer between the first thermometer layer and the second thermometer layer, wherein: the at least one first thermometer layer and the at least second thermometer layer are gel materials, the at least one first thermometer layer is thermally insulated from an environment surrounding the sensor, the at least one second thermometer layer is thermally accessible by the environment, and the at least one heater layer is configured to generate a constant heat flux through the at least one first thermometer layer, the at least one thermal insulator layer, and the at least one second thermometer layer, thus generating a thermal gradient within the at least one thermal insulator.

DETAILED DESCRIPTION

[0010] The present disclosure describes flow meters based on gel or polymers, for example for aerodynamics applications. Aerodynamics measurements and wind tunnel experiments are of great importance in engineering: experiments carried out in wind tunnels allow investigation of the complex phenomena developing due to fluid-bodies and fluid-fluid interactions, while also enabling validation of computational fluid dynamics (CFD) code. The main aim of a wind tunnel experiment is often to acquire the pressure and velocity distribution around scaled-down models of structures of interest. Using this data, it is then possible to compute the forces acting on the body subject of the experiment, e.g. the drag force acting on a car, or the lift force generated by a wing.

[0011] Measuring techniques typically employed for aerodynamics measurements focus on pressure distributions or fluid velocities. For example, one technique referred to as a pressure tap is based on a Pitot tube used to measure static and dynamic pressure at a single point. Pressure taps and pressure sensitive paints are based on pressure distributions, while laser Doppler velocimetry is based on fluid velocities. Several of these sensors are typically attached to surfaces of interest of models tested in wind tunnels. In post processing, pressure distributions can be approximately reconstructed from the punctual pressure measurements. [0012] Thermal flow meters can measure flow rate even at very low pressure, without affecting the flow. As illustrated in Fig. 5, the sensors combine one or more heating elements (510) and several temperature sensors (505) placed on the surface around the heater (Fig. 5 panel a). Heat is exchanged between the sensor and the fluid flowing at a temperature different from the heating element (Fig. 5, panel b). The flow rate is then determined by measuring the temperature distribution along the sensor created by the flowing fluid. In general, the temperature of the sensor cannot be raised arbitrarily, since high temperatures can be hazardous and can affect the flow. Therefore, the temperature gradient over the sensor is typically not particularly pronounced (the temperature variations are in the order of hundreds of milliKelvin). To achieve acceptable readings from these measurements, especially at low flow densities, commercially available devices are based on MEMS technology and on very accurate temperature sensors. Platinum is one of the most used thermistor, but it has a temperature sensitivity of about 0.4 /°C. The maximum resistance variation of a thermistor in the considered temperature range for a thermal flow meter is of approximately milliOhms, which requires low-noise read-out electronics to be effectively measured. Furthermore, to optimize the temperature measurements, the thermistors are usually suspended. This requires a complicated fabrication process, which further raise the price for this type of sensors.

[0013] Pressure sensitive paints are a special class of paints which can react to pressure changes. These paints are generally composed of a porous polymeric matrix mixed with luminescent organic molecules. When using this technique, models are spray-coated with such paints before being placed in the wind tunnel. The model is illuminated by light of a specific wavelength, causing an electronic excitation in the luminescent molecule. The wavelength is based on the specific luminophore incorporated into the paint. The return to electronic ground state of the luminophore can be attained by either a radiative process, or a radiationless process. In the former case, the relaxation results in photonic emission, while in the latter, interaction with oxygen molecules results in the electron returning to its ground state without photonic emission, a process known as oxygen quenching of luminescence. A pressure sensitive paint is thus, in fact, an oxygen sensor. As the local oxygen (partial) pressure increases, so does the local oxygen concentration, resulting in stronger luminescence quenching. The net effect is a paint whose luminescence decreases as pressure increases. The re-emitted light is finally detected using a camera and, after calibration, the pressure distribution can be computed with virtually unlimited spatial resolution. Notable disadvantages of pressures sensitive paints are the rather long preparation time (deposition and curing time of the paints), and the relatively high velocity range at which they operate (Ma > 0.3). Pressure sensitive paints are only suited for use in air flows, as their functioning mechanism relies on the oxygen contained in the gas flow.

[0014] Laser Doppler velocimetry is a measuring technique that exploits light scattering due to particles either naturally occurring, or induced, in the flow. Particles moving with the fluid are illuminated with a split laser beam. The shift in frequency between scattered and incident light is proportional to the velocity of the scattering particles, due to the Doppler effect.

[0015] The present disclosure describes sensors to perform measurements based on thermal effects, convection in particular. Convection is one of the three heat transfer mechanisms, being the one prevailing in fluids. The convective heat transfer law states that a surface immersed in a moving fluid experiences a heat flux proportional to the temperature difference existing between the surface itself and the fluid, i.e.: q" = a - (T - T_¥)

[0016] where: q" is the convective heat flux per unit area leaving the surface in Wm ², a is the convective heat transfer coefficient in WK^_1m ², T is the temperature of the surface in K, and T_¥ is the temperature of the fluid in K. The heat transfer coefficient a is generally very difficult to compute, as it is dependent on many parameters including fluid properties (such as density and specific heat) and problem- specific geometry. In any case, though, a strong dependence of a on the fluid velocity can be observed. In other words, the faster the fluid moves over the surface, the higher the heat transfer coefficient a.

[0017] This principle is exploited by hot-wire anemometers, i.e. a class of instruments capable of measuring free-stream air velocity (or wind speed, hence the name) based on the aforementioned principle. A hot-wire anemometer is composed of a metallic wire heated significantly above ambient temperature by resistive Joule effect. A feedback loop keeps the wire at a constant temperature by controlling the current through the wire. As the fluid moves around the wire, some of the generated heat is subtracted by convection, thus prompting a response by the feedback loop and an increased current. Since the magnitude of this effect holds a strong dependence on fluid velocity, a calibration procedure allows obtaining the free- stream speed as function of the control effort, that is the electric current in the wire. Hot-wire anemometers are used in free stream conditions, and by construction they offer a very limited spatial resolution. Therefore, their use in wind tunnel experiments is limited to the determination of the free- flowing air speed. A conformal heat-flux sensor, improving on the principle of a hot-wire anemometer with higher spatial resolution and attached on model surfaces in wind tunnel is an advantageous alternative to measure quantities of interest during experiments. The present disclosure describes how to design these conformal heat-flux sensors.

[0018] With reference to Fig. 1, a surface (105) at a temperature T2, immersed in a moving fluid, exchanges heat with the fluid at a rate depending on the fluid’s temperature T_¥, its velocity v, and a problem-specific coefficient a, which is strongly dependent on the fluid’s velocity v. In Fig. 1, the underlying physical phenomenon is described by the convection heat transfer law.

[0019] When the temperatures T_¥ and T2 are known, and the heat flux is known, it is possible to invert the convection law to obtain:

[0020] Because of the strong dependence of a on the fluid’s velocity, measuring a provides information on the fluid’s velocity. The larger a is, the larger the flow speed. In some embodiments, as described in the present disclosure, a sensor can be fabricated based on the physics describing Fig. 1. A sensor, in some embodiments, comprises two thin thermometers separated by a thermal insulator. Fig. 2 illustrates an example of a sensor comprising a heater (205), a first thermometer (210), a thermal insulator (215), and a second thermometer (220).

[0021] The thermometers comprise a temperature sensitive material, such as a gel or a polymer. One surface of the sensor is insulated, whereas the opposite surface is exposed to the moving fluid, and is thus able to exchange heat therewith. A heater imposes a constant heat flux through the device, building a temperature gradient within the insulator. The temperature gradient is measured using the first and second thermometers, thus allowing the computation of the convective heat-transfer coefficient a. The larger the temperature difference between the temperatures of the first and second thermometers, Ti and T₂, the larger a, and thus the larger the flow speed. The convective coefficient a can be calculated as:

[0022] where: k is the thermal conductivity of the insulator; 7), T2 are, respectively, the temperatures of the two thermometers on either side of the insulator; T_¥ is the temperature of the fluid, and t is the thickness of the insulating layer. In some embodiments, a different arrangement or number of layers may be used, based on at least an insulating layer between two thermometers, and a heater. In some embodiments, the sensors can comprise several thermometer layers, and several heating or cooling layers. The sensors can comprise thin electrical heaters, resistive heaters, polyimide foil heaters, an electrical circuit heating by Joule effect, or a Peltier element. The sensor may also comprise a heater or cooling layer that incorporates a microfluidic circuit or channel. One of the thermometer layers is thermally accessible by the environment.

[0023] Fig. 3 illustrates an exemplary cross section of a device based on pectin cross-linked by calcium ions as a temperature sensitive layer (a thermometer). In the embodiment of Fig. 3, the sensor comprises a polyimide layer (305), a thermal insulator layer (310), a heater (315), a thermometer based on pectin (320), a thermal insulator (330), a thermometer based on pectin (335), and a polyimide layer (340). In this embodiment, pectin is used for temperature sensing, however other materials may be used instead. In this example, the insulator (310) comprises NASBIS® (NAno Silica Ball InSulator), a flexible, thermally insulating material. In this embodiment, the insulator (330) comprises a polydimethylsiloxane (PDMS). Gold electrodes (325) can be used for the two pectin thermometers.

[0024] Fig. 4 illustrates exemplary data for the temperature difference between the two thermometers, which are at temperatures Ti and T₂, as a function of the flow speed. A larger difference between Ti and T₂ corresponds to a larger flow speed. The device can be calibrated to provide the actual flow speed calculated from the temperature difference. The sensor can be designed as an array of similar pixels to provide a spatial map of the flow’s speed. Several sensors can be applied on a model surface to measure the flow speed at different location, thus realizing a conformal sensor array. The sensor can be fabricated from flexible materials, and can therefore be conformally attached to curved surfaces.

[0025] As described above, the present disclosure combines a thin heater with a class of organic, temperature-sensitive materials, which show a high resistance versus temperature response. The thin heater serves as a heat source, while the temperature sensitive material, deposited as a thin film or as an array of sensors, provides the temperature feedback. In some embodiments, the sensors of the present disclosure are based on organic bio-molecules, such as pectin, alginate, chitosan or a combination of these. Pectin-based thin films as described above are very responsive to temperature. Pectin is made of structurally and functionally very complex, acid- rich polysaccharides. In low-ester pectin, ionic bridges are formed, at near neutral pH, between Ca²⁺ ions and the ionized carboxyl groups of the galacturonic acid present in the molecule, forming an“egg box” structure in which cations are stored. Because the cross-linking between pectin molecules decreases exponentially with temperature, increasing the temperature of a Ca²⁺-cross-linked pectin results in a dramatic increase of ionic conduction. Ca²⁺-cross-linked pectin can be deposited on flexible substrate. The resulting ultrathin membranes (20-200 pm thin) show a variation in their resistance of two order of magnitudes over 45 °C. As a comparison, a standard platinum thermistor (PtlOO), varies its resistance by only about 1.5 times over the same interval. Besides possessing an extreme temperature responsivity, these pectin films have a very high signal -to-noise ratio and can sense temperature variation of at least 10 mK. Pectin layers can also be produced on extended areas, and can monitor 2D temperature distributions thanks to their extraordinary responsivity and sensitivity. These advantages allow collecting flow information on extended areas, instead of the localized data provided by standard flow meters.

[0026] In some embodiments, the pectin films can be crosslinked by Ca, Cu, or Mg. Instead of pectin, other materials may be used, for example alginate crosslinked by Ca, Cu, or Mg. In some embodiments, the sensors can be based on specific materials. The present disclosure describes some exemplary materials in the following. These materials can also be used for purposes other than flow sensors. Therefore, the materials in the following are described both for use in flow sensors, and for use unrelated to flow sensors. The present disclosure therefore describes, in some embodiments, a flow meter comprising one or more hydrogel-based temperature sensors, and one or more heating (or cooling) elements. For example, a sensor can comprise, as described above, a resistive heater coupled with two local pectin-based temperature sensors.

[0027] As known to the person of ordinary skill in the art, pectin, a component of all higher plant cell walls, is made of structurally and functionally very complex, acid-rich polysaccharides. Pectin plays several roles in plants— for example, it is an essential structural component of cell walls and binds ions and enzymes. In high-ester pectins, at acidic pH, individual pectin chains are linked together by hydrogen bonds and hydrophobic interactions. In contrast, in low-ester pectins, ionic bridges are formed, at near neutral pH, between Ca²⁺ ions and the ionized carboxyl groups of the galacturonic acid, forming an“egg box” in which cations are stored. Since the crosslinking between pectin molecules decreases exponentially with temperature, increasing the temperature of a Ca²⁺-crosslinked pectin increases ionic conduction.

[0028] Currently, the potential applications of pectin gels as temperature-sensing elements in mobile phones and automotive applications are challenged by several factors. First, the temperature responsivity and conductivity of hydrogel-based pectin are both highly dependent on the water content of the membrane, whereas the water content is subjected to fluctuations in ambient humidity and temperature. Secondly, being a water-based gel, the applicable temperature range of a pectin gel is limited. The increased evaporation of water at higher temperatures also renders the membrane unstable at higher temperature ranges (>70 °C). Further, due to the intrinsic rigidity of pectin's molecular structure, the flexibility of pectin membranes is dependent on their water content. Excessively reducing the pectin water content results in shrinkage of the pectin membranes, detachment of the membrane from electrodes, and increased brittleness of the membrane. [0029] The examples set forth above are provided to those of ordinary skill in the art as a complete disclosure and description of how to make and use the embodiments of the disclosure, and are not intended to limit the scope of what the inventor/inventors regard as their disclosure.

[0030] Modifications of the above-described modes for carrying out the methods and systems herein disclosed that are obvious to persons of skill in the art are intended to be within the scope of the following claims. All patents and publications mentioned in the specification are indicative of the levels of skill of those skilled in the art to which the disclosure pertains. All references cited in this disclosure are incorporated by reference to the same extent as if each reference had been incorporated by reference in its entirety individually.

[0031] It is to be understood that the disclosure is not limited to particular methods or systems, which can, of course, vary. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only, and is not intended to be limiting. As used in this specification and the appended claims, the singular forms "a," "an," and "the" include plural referents unless the content clearly dictates otherwise. The term“plurality” includes two or more referents unless the content clearly dictates otherwise. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the disclosure pertains.

Claims

CLAIMS What is claimed is:

1. A sensor comprising:

at least one heater layer;

at least one first thermometer layer;

at least one second thermometer layer; and

at least one thermal insulator layer between the first thermometer layer and the second thermometer layer,

wherein:

the at least one first thermometer layer and the at least second thermometer layer are gel materials,

the at least one first thermometer layer is thermally insulated from an environment surrounding the sensor,

the at least one second thermometer layer is thermally accessible by the environment, and

the at least one heater layer is configured to generate a constant heat flux through the at least one first thermometer layer, the at least one thermal insulator layer, and the at least one second thermometer layer, thus generating a thermal gradient within the at least one thermal insulator.

2. The sensor of claim 1, wherein the at least one heater layer is selected from the group consisting of: an electrical heater, a resistive heater, a polyimide foil heater, an electrical circuit heating by Joule effect, and a Peltier element.

3. The sensor of any one of claims 1-2, wherein the at least one first thermometer layer and the at least one second thermometer layer are selected from the group consisting of: pectin, alginate, chitosan, and any combination thereof.

4. The sensor of any one of claims 1-3, wherein the at least one thermal insulator is made of polydimethylsiloxane.

5. The sensor of any one of claims 1-4, wherein the at least one heater layer, the at least one first thermometer layer, the at least one second thermometer layer, and the at least one thermal insulator are flexible layers.

6. The sensor of any one of claims 1-5, wherein the at least one first thermometer layer or the at least one second thermometer layer comprise pectin and Ca²⁺.