WO2019160296A1 - Flexible touch sensor having color filter integrated therein, and manufacturing method therefor - Google Patents

Flexible touch sensor having color filter integrated therein, and manufacturing method therefor Download PDF

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Publication number
WO2019160296A1
WO2019160296A1 PCT/KR2019/001679 KR2019001679W WO2019160296A1 WO 2019160296 A1 WO2019160296 A1 WO 2019160296A1 KR 2019001679 W KR2019001679 W KR 2019001679W WO 2019160296 A1 WO2019160296 A1 WO 2019160296A1
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Prior art keywords
layer
color filter
touch sensor
flexible touch
integrated flexible
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PCT/KR2019/001679
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French (fr)
Korean (ko)
Inventor
김덕겸
이명원
지근왕
홍영균
Original Assignee
동우 화인켐 주식회사
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Publication of WO2019160296A1 publication Critical patent/WO2019160296A1/en

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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/80Constructional details
    • H10K59/8791Arrangements for improving contrast, e.g. preventing reflection of ambient light
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B43/00Operations specially adapted for layered products and not otherwise provided for, e.g. repairing; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B43/00Operations specially adapted for layered products and not otherwise provided for, e.g. repairing; Apparatus therefor
    • B32B43/006Delaminating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/041Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/041Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
    • G06F3/044Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/30Devices specially adapted for multicolour light emission
    • H10K59/38Devices specially adapted for multicolour light emission comprising colour filters or colour changing media [CCM]
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/40OLEDs integrated with touch screens
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F2203/00Indexing scheme relating to G06F3/00 - G06F3/048
    • G06F2203/041Indexing scheme relating to G06F3/041 - G06F3/045
    • G06F2203/04102Flexible digitiser, i.e. constructional details for allowing the whole digitising part of a device to be flexed or rolled like a sheet of paper
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F2203/00Indexing scheme relating to G06F3/00 - G06F3/048
    • G06F2203/041Indexing scheme relating to G06F3/041 - G06F3/045
    • G06F2203/04103Manufacturing, i.e. details related to manufacturing processes specially suited for touch sensitive devices

Definitions

  • the present invention relates to a color filter integrated flexible touch sensor and a method of manufacturing the same.
  • the touch input method is spotlighted as the next generation input method, the touch input method is introduced to various electronic devices.
  • the flexible display device refers to a display device fabricated on a flexible substrate that can bend, bend, or roll without loss of properties, and technology development is in progress in the form of flexible LCD, flexible OLED, and electronic paper.
  • a capacitive touch sensor panel overlaid on an LCD or an OLED can be used.
  • the capacitive touch sensor panel is formed of a substantially transparent conductive material such as indium tin oxide (ITO). It may be formed of a matrix of predetermined touch driving lines and touch sensing lines. These touch drive lines and touch sense lines are often arranged in rows and columns on substantially transparent substrates. When an object such as a user's finger is near the intersection of the touch drive line and the touch sense line, the capacitance between the touch drive line and the touch sense line may change. This change in capacitance can indicate that a touch is taking place at this location.
  • ITO indium tin oxide
  • Korean Patent Laid-Open No. 10-2017-0135174 includes: a plurality of color filters arranged in first and second directions on a substrate; A touch block electrode disposed on the color filter to sense a touch position of a user; A black matrix disposed on the touch block electrode between the color filters; Disclosed is a color filter array having a touch sensor disposed in one of the first and second directions and having a touch sensing line connected to the touch block electrode.
  • a polarizing plate is generally attached to an organic light emitting display device to improve optical characteristics such as anti-reflection, and a touch sensor for implementing a touch interface with a user is attached to the organic light emitting display.
  • the thickness of the polarizing plate is about 100-150 ⁇ m, which is considerably thick, no matter how thin the thickness of the touch sensor is, if the polarizing plate and the touch sensor are separately attached to the organic light emitting display device, the organic light emitting diode is emitted due to the thickness of the polarizing plate. There is a problem that the flexibility of the display device is lowered.
  • the present invention has been made in the technical background as described above, and its object is to implement two functional devices on one flexible substrate by integrating a color filter and a touch sensor.
  • Another object of the present invention is to realize a thinner and more flexible flexible display device by integrating a color filter and a touch sensor using one flexible substrate.
  • Another object of the present invention is to provide a color filter integrated flexible touch sensor excellent in uniformity and reducing defects caused by lowering flatness, and a method of manufacturing the same.
  • Another object of the present invention is to replace the anti-reflective polarizing plate provided in the organic light emitting display with a color filter to reduce the external light reflectance of the organic light emitting display and to improve color reproducibility.
  • a color filter layer on the separation layer An adhesive layer on the color filter layer; An intermediate substrate on the adhesive layer; And it provides a color filter integrated flexible touch sensor comprising a touch sensor layer on the intermediate substrate.
  • the intermediate substrate may be a glass substrate or a film substrate.
  • the intermediate substrate may include a refractive index adjusting layer.
  • the adhesive layer may be made of a photocurable adhesive.
  • the color filter integrated flexible touch sensor may further include a protective layer between the separation layer and the color filter layer.
  • the color filter integrated flexible touch sensor may further include an overcoat layer between the color filter layer and the adhesive layer.
  • forming a separation layer on a carrier substrate Forming a color filter layer on the separation layer; Forming an adhesive layer on the color filter layer; Bonding an intermediate substrate on the adhesive layer; Forming a touch sensor layer on the intermediate substrate; And it provides a method of manufacturing a color filter integrated flexible touch sensor comprising the step of separating the carrier substrate.
  • the adhesive layer may be formed of a photocurable adhesive, and the bonding of the intermediate substrate may include disposing the intermediate substrate on the adhesive layer; And photocuring the adhesive layer.
  • the method of manufacturing a color filter integrated flexible touch sensor according to the present invention further includes attaching a protective film on the touch sensor layer after forming the touch sensor layer, and after separating the carrier substrate.
  • the method may further include removing the protective film.
  • the method may further include forming a protective layer between the separation layer and the color filter layer.
  • the method of manufacturing the color filter integrated flexible touch sensor may further include forming a refractive index control layer on the intermediate substrate.
  • the method of manufacturing the color filter integrated flexible touch sensor may further include forming an overcoat layer on the color filter layer.
  • a flexible display device including the color filter integrated flexible touch sensor as described above.
  • the flexible display device may be an organic light emitting display device.
  • two functional devices may be implemented with one flexible substrate by integrating the color filter and the touch sensor.
  • a thinner and more flexible display device can be obtained by integrating the color filter and the touch sensor using one flexible substrate.
  • the flatness is improved by using an intermediate substrate, thereby reducing the occurrence of defects, thereby obtaining a uniform and excellent touch input sensing performance.
  • a color filter can be used to replace the anti-reflective polarizing plate, thereby reducing the external light reflectance and improving color reproducibility of the organic light emitting display device.
  • the thickness can be significantly reduced.
  • FIG. 1 is a cross-sectional view of a flexible color sensor integrated touch sensor according to an embodiment of the present invention.
  • FIGS. 2A to 2G are cross-sectional views of each step according to a method of manufacturing a color filter integrated flexible touch sensor according to an exemplary embodiment of the present invention.
  • FIG 3 is a cross-sectional view of a display device including a color filter integrated flexible touch sensor according to an exemplary embodiment.
  • FIG. 1 is a cross-sectional view of a flexible color sensor integrated touch sensor according to an embodiment of the present invention.
  • the color filter integrated flexible touch sensor 10 may include a separation layer 110, a protective layer 120 on the separation layer 110, and an upper portion of the protective layer 120.
  • a color filter layer formed on the black matrix 130 and the pixel region 140, an adhesive layer 150 on the color filter layer, an intermediate substrate 200 on the adhesive layer 150, and a touch sensor on the intermediate substrate 200.
  • Layer 300 may include a separation layer 110, a protective layer 120 on the separation layer 110, and an upper portion of the protective layer 120.
  • a color filter layer formed on the black matrix 130 and the pixel region 140, an adhesive layer 150 on the color filter layer, an intermediate substrate 200 on the adhesive layer 150, and a touch sensor on the intermediate substrate 200.
  • the separation layer 110 is a layer formed for peeling with the carrier substrate after the manufacture of the color filter integrated flexible touch sensor in the manufacturing process of the present invention. Therefore, the separation layer 110 may be separated from the carrier substrate through physical force.
  • the material of the separation layer 110 is not particularly limited as long as a condition of providing a certain level of peeling force and transparency is satisfied.
  • the separation layer 110 may be a polyimide polymer, a polyvinyl alcohol polymer, a polyamic acid polymer, a polyamide polymer, polyethylene Polymer, polystylene polymer, polynorbornene polymer, phenylmaleimide copolymer polymer, polyazobenzene polymer, polyphenylenephthalamide polymer , Polyester (polyester) polymer, polymethyl methacrylate (polymer) polymer, polyarylate (polymer) polymer, cinnamate (polymer) polymer, coumarin (coumarin) polymer, phthalimidine (phthalimidine) ) -Based polymers, chalc (chalcone) -based polymers, aromatic acetylene (aromatic acetylene) may be made of a polymer such as polymers, these alone or 2 Or more may be mixed and
  • the peeling force of the separation layer 110 is not particularly limited, but may be, for example, 0.01N / 25mm or more and 1N / 25mm or less, preferably 0.01N / 25mm or more and 0.1N / 25mm or less.
  • it can be easily peeled off from the carrier substrate without residue, curl and crack due to the tension generated during peeling Can be reduced.
  • the thickness of the separation layer 110 is not particularly limited, but may be, for example, 10 to 1,000 nm, preferably 50 to 500 nm. When the said range is satisfied, peeling force is stable and a uniform pattern can be formed.
  • the protective layer 120 is a layer for protecting the separation layer 110 and is an optional component formed on the separation layer 110 and may be omitted as necessary.
  • the protective layer 120 is a process chemical, a developer, a process such as a solvent of a color filter photoresist for which the separation layer 110 is used to form a color filter during the process of manufacturing the color filter integrated flexible touch sensor of the present invention. It is prevented from being damaged by exposure to the cleaning liquid generated in the liver.
  • the material of the protective layer 120 may be a polymer known in the art without limitation, for example, an organic insulating film may be applied, and among these, a curable composition comprising a polyol and a melamine curing agent. It may be formed as, but is not limited thereto.
  • polyol examples include, but are not limited to, polyether glycol derivatives, polyester glycol derivatives, polycaprolactone glycol derivatives, and the like.
  • melamine curing agents include methoxy methyl melamine derivatives, methyl melamine derivatives, butyl melamine derivatives, isobutoxy melamine derivatives and butoxy melamine Derivatives and the like, but are not limited thereto.
  • the protective layer 120 may be formed of an organic-inorganic hybrid curable composition, and when using an organic compound and an inorganic compound at the same time, it is preferable in that the cracks generated during peeling may be reduced.
  • the organic compound the above-described components may be used, and the inorganic material may include silica-based nanoparticles, silicon-based nanoparticles, glass nanofibers, and the like, but is not limited thereto.
  • the color filter layer including the black matrix 130 and the pixel region 140 is formed on the protective layer 120, and functions to reduce external light reflectance and to improve color reproducibility of the display.
  • the color filter layer may be disposed on the separation layer 110.
  • the black matrix 130 is a light blocking layer that blocks light in portions other than the pixel region 140 and prevents color mixing at the boundary of each pixel region. Therefore, the black matrix 130 is formed of an opaque material, and the pixel Patterned to surround area 140.
  • the pixel region 140 is a colored layer for color display for color display, and typically includes red, green, and blue regions, and the region is defined by a black matrix 130 pattern. .
  • the pixel area 140 does not have to include all of red, green, and blue, or only red, green, and blue, and may include only some of the colors or white (depending on the color representation of the display device). Other colors such as White) may be further included.
  • the color filter layer may reduce the external light reflectance of the organic light emitting display and improve color reproducibility by replacing the anti-reflective polarizing plate.
  • an overcoat layer may be further included on the color filter layer.
  • the overcoat layer is formed for flattening.
  • the flattening is more advantageously achieved by the adhesive layer 150 and the intermediate substrate 200 which will be described later. There is an advantage that does not need to form. This also enables the simplification of the process and the thinning of the device.
  • An adhesive layer 150 is formed on the color filter layer, and the intermediate substrate 200 is attached by the adhesive layer 150.
  • the adhesive layer 150 performs two functions of flattening the stepped portion of the surface of the color filter layer that is not planarized and attaching the intermediate substrate 200 on the color filter layer.
  • a photocurable adhesive may be used, and the photocurable adhesive used in the art may be used without particular limitation.
  • a composition containing an epoxy compound or an acrylic monomer can be used.
  • a thin glass substrate or a flexible film substrate may be used, and in particular, a transparent film may be used.
  • polyester-based resins such as polyethylene terephthalate, polyethylene isophthalate, polyethylene naphthalate, and polybutylene terephthalate; Cellulose resins such as diacetyl cellulose and triacetyl cellulose; Polycarbonate resins; Acrylic resins such as polymethyl (meth) acrylate and polyethyl (meth) acrylate; Styrene resins such as polystyrene and acrylonitrile-styrene copolymers; Polyolefin-based resins such as polyethylene, polypropylene, cyclo-based or norbornene-structured polyolefins, ethylene-propylene copolymers; Vinyl chloride-based resins; Amide resins such as nylon and aromatic polyamides; Imide resin; Polyether sulfone resin; Sulfone resins; Polyether ether ketone resins;
  • the thickness of such a transparent film can be suitably determined, it is generally about 1-500 micrometers in terms of workability, thinness, etc., such as intensity
  • Such a transparent film may contain an appropriate one or more additives.
  • an additive a ultraviolet absorber, antioxidant, a lubricating agent, a plasticizer, a mold release agent, a coloring agent, a flame retardant, an antistatic agent, a pigment, a coloring agent, etc. are mentioned, for example.
  • the transparent film may have a structure including various functional layers such as a hard coating layer, an antireflection layer, and a gas barrier layer on one or both surfaces of the film, and the functional layer is not limited to the above-described ones. It may include.
  • the transparent film may be surface-treated as needed.
  • Such surface treatments include dry treatments such as plasma treatments, corona treatments, primer treatments, and chemical treatments such as alkali treatments including saponification treatments.
  • the intermediate substrate 200 may include an index matching layer (not shown).
  • the refractive index control layer is to improve the optical uniformity of the color filter integrated flexible touch sensor. Specifically, the refractive index control layer reduces the difference in optical characteristics due to the structural differences of the patterns of the touch sensor layer 300 on the intermediate substrate 200. In the case of including the refractive index adjusting layer, the visibility of the sensing pattern may be improved by reducing the difference in reflectance between the pattern portion and the non-patterning portion of the sensing pattern.
  • the refractive index control layer may be composed of a single film having a high refractive index of 1.5 to 1.87, the thickness may be 30nm-2000nm.
  • the refractive index adjusting layer may be formed by stacking at least two layers having different refractive indices. In the case of a multilayer film, high and low refractive materials may be repeatedly formed.
  • the refractive index control layer may be configured to include an inorganic insulating film, specific examples, SiO 2 , Al 2 O 3 , MgO, NdF 3 , SiON, Y 2 O 3 , ZnO, TiO 2 , ZrO 2 , Nb It may be configured to include one or more selected from the group consisting of 2 O 5 .
  • the refractive index control layer may be configured to include an organic insulating layer, and as a specific example, the refractive index control layer may be configured to include an organic material containing inorganic fine particles.
  • the refractive index control layer comprises an organic material containing inorganic fine particles
  • the organic material is one selected from the group consisting of acrylic resins, urethane resins, melamine resins, alkyd resins, siloxane-based polymers and organic silane condensates. It may include the above, but is not limited thereto.
  • the refractive index control layer comprises an organic material containing inorganic fine particles
  • the inorganic fine particles are SiO 2 , Al 2 O 3 , MgO, NdF 3 , SiON, Y 2 O 3 , ZnO, TiO 2 , ZrO 2 , Nb 2 It may be configured to include one or more selected from the group consisting of O 5 , but is not limited thereto.
  • the refractive index of the refractive index adjusting layer may be adjusted by adjusting the content of the inorganic fine particles.
  • the refractive index of the refractive index control layer may be increased by increasing the content of the inorganic fine particles, and conversely, the refractive index of the refractive index control layer may be reduced by reducing the content of the inorganic fine particles.
  • the refractive index adjusting layer may be formed by a deposition process or a wet coating method.
  • the touch sensor layer 300 is formed on the intermediate substrate 200.
  • the touch sensor layer 300 has a structure of an electrode pattern used in a capacitive touch sensor, and a mutual capacitive type or a self-capacitive type may be applied.
  • the grid electrode structure may be a horizontal axis and a vertical axis.
  • the intersection electrode of the horizontal axis and the vertical axis may include a bridge electrode.
  • an electrode pattern structure of a method of reading capacitance change using one electrode at each point may be provided.
  • the electrode of the touch sensor layer 300 may be formed of one or more materials selected from metals, metal nanowires, metal oxides, carbon nanotubes, graphene, conductive polymers, and conductive inks.
  • the metal may be any one of gold, silver, copper, molybdenum, aluminum, palladium, neodium, platinum, zinc, tin, titanium, or an alloy thereof.
  • the metal nanowires may be any one of silver nanowires, copper nanowires, zirconium nanowires, and gold nanowires.
  • the metal oxide is indium tin oxide (ITO), indium zinc oxide (IZO), indium zinc tin oxide (IZTO), aluminum zinc oxide (AZO), gallium zinc oxide (GZO), florin tin oxide (FTO), zinc oxide (ZnO) can be any one.
  • the conductive polymer includes polypyrrole, polythiophene, polyacetylene, PODOT, and polyaniline
  • the conductive ink includes an ink in which a metal powder and a curable polymer binder are mixed. Include.
  • the electrode of the touch sensor layer 300 may be made of a laminated structure of two or more conductive layers in some cases in order to reduce the electrical resistance.
  • the black matrix 130 pattern and the electrode pattern of the color filter layer may correspond to each other.
  • the thickness of the touch sensor layer 300 is not particularly limited, but in consideration of the flexibility of the color filter integrated flexible touch sensor, the touch sensor layer 300 is preferably a thin film.
  • the sensing electrode patterns constituting the touch sensor layer 300 may be a polygonal pattern of three, four, five, six, or seven, respectively, independently of each other.
  • the touch sensor layer 300 may include a rule pattern.
  • a regular pattern means that the pattern form has regularity.
  • the sensing electrode patterns may independently include a mesh shape such as a rectangle or a square, or a pattern like a hexagon.
  • the touch sensor layer 300 may include an irregular pattern.
  • Irregular pattern means that the shape of the pattern does not have regularity.
  • the sensing electrode patterns constituting the touch sensor layer 300 are formed of a material such as metal nanowires, carbon-based materials, polymer materials, or the like, the sensing electrode patterns may have a network structure.
  • the sensing electrode patterns may have a network structure, signals are sequentially transmitted to adjacent patterns in contact with each other, thereby realizing a pattern having high sensitivity.
  • each electrode pattern of the touch sensor layer 300 is formed on a flattened surface that is not affected by the step of the color filter layer. This can minimize the influence of the lower layer in the deposition, photography, and etching process of manufacturing the touch sensor, and ensures uniformity of characteristics such as resistance value and transmittance of the touch sensor electrode.
  • the thin film may be achieved by integrating the color filter and the touch sensor using a single flexible substrate.
  • the device In order to improve the flexible performance of the flexible device, the device should be designed in a structure that eliminates or reduces stress caused by bending and folding of the device. Cracks that are susceptible to stress in the flexible device are likely to cause cracks, and when cracks occur, deterioration deformation such as deterioration of the layer and disconnection of electrodes occurs, and corrosion occurs due to the penetration of moisture and oxygen into the crack generating part. It causes a decrease in reliability such as acceleration.
  • the thickness of the flexible device when the thickness of the flexible device is thick, it is located farther from the neutral surface than when it is thin, and thus the stress generated during bending and folding acts to a wide area, and the magnitude of the stress also increases. Therefore, the closer the portion vulnerable to the stress from the neutral plane, the smaller the stress is, thereby improving reliability.
  • the present invention through the thinning of the flexible device, it is possible to obtain an improvement in flexibility and an improvement in reliability.
  • the alignment accuracy of the color filter and the touch sensor can be improved, and the color filter and the touch sensor can be formed on flat surfaces, respectively.
  • the result is uniform visual and driving characteristics.
  • 2A to 2G are cross-sectional views of respective steps according to a method of manufacturing a color filter integrated flexible touch sensor according to an exemplary embodiment of the present invention.
  • the method of manufacturing a color filter integrated flexible touch sensor uses a method of removing a carrier substrate by using a transfer method after performing a process on a carrier substrate.
  • a separation layer 110 is formed by applying a composition for forming a separation layer.
  • a glass substrate as the carrier substrate 400, other materials may be used without being limited thereto. However, a material having heat resistance that does not deform even at high temperatures, that is, maintains flatness, to withstand the subsequent process temperature is preferable.
  • a well-known coating method can be used as a method of apply
  • spin coating, die coating, spray coating, roll coating, screen coating, slit coating, dip coating, gravure coating, etc. are mentioned.
  • an inkjet method may be used.
  • the composition for forming the separation layer is cured after coating to form the separation layer 110.
  • the curing process may be used by thermosetting or UV curing alone, or a combination of thermosetting and UV curing.
  • heating may be performed by an oven, a hot plate, or the like, and heating temperature and time may vary depending on the composition, but may be heat-treated under conditions of 10 to 120 minutes at 80 to 250 ° C.
  • the protective layer forming composition is applied to the formed separation layer 110 to form a protective layer 120.
  • the separation layer 110 may be peeled from the carrier substrate 400 by a physical force after the process on the carrier substrate 400, which is because the peeling force is very weak, the protective layer 120 for this purpose It is formed on the 110, the protective layer 120 may be formed to surround the separation layer 110 to its side.
  • the coating method and the curing process of the composition for forming a protective layer are as described above in connection with the formation of the separation layer.
  • the black matrix 130 and the pixel region 140 are formed on the formed protective layer 120.
  • the black matrix 130 is formed by patterning with an opaque organic material, and forms the pixel regions 140 of red (R), green (G), and blue (B) in a region defined by the black matrix 130 pattern.
  • R red
  • G green
  • B blue
  • the color constituting the pixel region 140 may be arbitrarily selected, and the order of formation for each color may also be arbitrarily selected.
  • an adhesive layer 150 is coated on the black matrix 130 and the pixel region 140.
  • the adhesive used as the adhesive layer 150 is a photocurable adhesive as described above, which does not require a separate drying process after the photocuring, so that the manufacturing process is simple and productivity is improved.
  • an overcoat layer may be further formed on the black matrix 130 and the pixel region 140 as needed.
  • the adhesive layer 150 may be applied on the overcoat layer. Can be.
  • the intermediate substrate 200 is disposed on the adhesive layer 150, and as shown in FIG. 2E, the adhesive layer 150 is photocured to form the intermediate substrate 200. Is bonded onto the color filter layer including the black matrix 130 and the pixel region 140.
  • electron beams, proton rays, neutron beams, and the like can be used in addition to electromagnetic waves such as ultraviolet rays such as far ultraviolet rays, ultraviolet rays, near ultraviolet rays, infrared rays, X-rays, ⁇ -rays, etc. Hardening by ultraviolet irradiation is advantageous from the ease of use, price, and the like.
  • a high pressure mercury lamp As a light source at the time of ultraviolet irradiation, a high pressure mercury lamp, an electrodeless lamp, an ultrahigh pressure mercury lamp, a carbon arc lamp, a xenon lamp, a metal halide lamp, a chemical lamp, a black light, etc. can be used.
  • the touch sensor layer 300 is formed on the bonded intermediate substrate 200.
  • the structure of the touch sensor layer 300 and a method of manufacturing the same may be used without limitation in the art, which is not particularly limited in the present invention.
  • the color filter integrated flexible touch sensor is separated from the carrier substrate 400.
  • the protective film may be attached to the touch sensor layer 300 and the protective film may be removed again after removing the carrier substrate 400.
  • the color filter integrated flexible touch sensor according to an exemplary embodiment of the present invention may be combined with a display layer to be used for a display device.
  • FIG 3 is a cross-sectional view of a display device according to an exemplary embodiment of the present invention.
  • a display device may include a color filter integrated flexible touch sensor 10 and a color filter integrated flexible touch sensor 10 according to an embodiment of the present invention as described above.
  • the display layer 20 is formed.
  • any one applicable to a flexible display device may be used without limitation, and may be, for example, an OLED layer or an LCD layer.
  • the color filter integrated flexible touch sensor 10 when the display layer 20 is an OLED layer, the color filter integrated flexible touch sensor 10 according to the exemplary embodiment of the present invention may have a function of replacing an antireflective polarizing plate.
  • color filter integrated flexible touch sensor 20 display layer
  • adhesive layer 200 intermediate substrate

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  • General Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Human Computer Interaction (AREA)
  • Physics & Mathematics (AREA)
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Abstract

The present invention relates to a flexible touch sensor having a color filter integrated therein and a manufacturing method therefor, the flexible touch sensor having an intermediate substrate bonded on a color filter layer, and a touch sensor layer formed on the intermediate substrate.

Description

컬러필터 일체형 유연성 터치센서 및 그 제조 방법Color filter integrated flexible touch sensor and its manufacturing method
본 발명은 컬러필터 일체형 유연성 터치센서 및 그 제조 방법에 관한 것이다.The present invention relates to a color filter integrated flexible touch sensor and a method of manufacturing the same.
터치 입력방식이 차세대 입력방식으로 각광받으면서 다양한 전자기기에 터치 입력방식이 도입되고 있다.As the touch input method is spotlighted as the next generation input method, the touch input method is introduced to various electronic devices.
특히, 초경량, 저전력을 달성하고 휴대성이 향상된 초박막 유연성 표시장치가 차세대 표시장치로 주목받으면서 이러한 표시장치에 적용 가능한 터치센서의 개발이 요구되고 있다.In particular, as ultra-thin flexible displays that achieve ultra-light weight, low power, and improved portability are attracting attention as next-generation displays, development of touch sensors applicable to such displays is required.
유연성 표시장치란 특성의 손실 없이 휘거나 구부리거나 말 수 있는 유연한 기판 상에 제작된 표시장치를 의미하며, 유연성 LCD, 유연성 OLED, 및 전자종이와 같은 형태로 기술개발이 진행중에 있다.The flexible display device refers to a display device fabricated on a flexible substrate that can bend, bend, or roll without loss of properties, and technology development is in progress in the form of flexible LCD, flexible OLED, and electronic paper.
유연성 표시장치에 터치 입력방식을 적용하기 위해서는 LCD나 OLED에 오버레이되는 용량성 터치센서 패널을 사용할 수 있으며, 이러한 용량성 터치센서 패널은 ITO(indium tin oxide)와 같은 실질적으로 투명한 전도성 물질로 이루어져 있는 소정의 터치 구동 라인 및 터치 감지 라인의 매트릭스로 형성될 수 있다. 이들 터치 구동 라인 및 터치 감지 라인은 종종 실질적으로 투명한 기판 상에 행 및 열로 배열되어 있다. 사용자의 손가락과 같은 물체가 터치 구동 라인 및 터치 감지 라인의 교차점 근방에 있을 때, 터치 구동 라인과 터치 감지 라인 사이의 커패시턴스가 변할 수 있다. 이 커패시턴스의 변화는 이 위치에서 터치가 일어나고 있다는 것을 나타낼 수 있다. In order to apply a touch input method to a flexible display device, a capacitive touch sensor panel overlaid on an LCD or an OLED can be used. The capacitive touch sensor panel is formed of a substantially transparent conductive material such as indium tin oxide (ITO). It may be formed of a matrix of predetermined touch driving lines and touch sensing lines. These touch drive lines and touch sense lines are often arranged in rows and columns on substantially transparent substrates. When an object such as a user's finger is near the intersection of the touch drive line and the touch sense line, the capacitance between the touch drive line and the touch sense line may change. This change in capacitance can indicate that a touch is taking place at this location.
그러나, 용량성 터치센서 패널을 LCD나 OLED에 오버레이하는 경우, 표시장치의 두께 및 무게 증가, 밝기의 감소 및 제조 비용의 증가 등의 문제점이 있다.However, when the capacitive touch sensor panel is overlaid on an LCD or an OLED, there are problems such as an increase in thickness and weight of a display device, a decrease in brightness, and an increase in manufacturing cost.
이에 따라, 터치센서를 표시장치 내부에 통합하여 구성하고자 하는 시도가 이루어지고 있다. Accordingly, attempts have been made to integrate the touch sensor into the display device.
예를 들면, 대한민국 공개특허 제10-2017-0135174호에서는, 기판 상에 제1 및 제2 방향으로 배열되는 복수의 컬러 필터들과; 상기 컬러 필터 상에 배치되어 사용자의 터치 위치를 감지하는 터치 블록 전극과; 상기 컬러 필터들 사이의 상기 터치 블록 전극 상에 배치되는 블랙매트릭스와; 상기 제1 및 제2 방향 중 어느 한 방향으로 배치되며 상기 터치 블록 전극과 접속되는 터치 센싱 라인을 구비하는, 터치 센서를 가지는 컬러 필터 어레이를 개시하고 있다. For example, Korean Patent Laid-Open No. 10-2017-0135174 includes: a plurality of color filters arranged in first and second directions on a substrate; A touch block electrode disposed on the color filter to sense a touch position of a user; A black matrix disposed on the touch block electrode between the color filters; Disclosed is a color filter array having a touch sensor disposed in one of the first and second directions and having a touch sensing line connected to the touch block electrode.
그러나, 이와 같은 방법에서는 기판 상에 컬러 필터, 터치 블록 전극, 블랙 매트릭스 및 터치 센싱 라인이 차례로 적층되므로 공정 상의 평탄도가 저하되어 불량이 발생할 가능성이 높다.However, in such a method, since the color filter, the touch block electrode, the black matrix, and the touch sensing line are sequentially stacked on the substrate, the flatness of the process is lowered, which may cause a defect.
또한 상부층으로 갈수록 하부 단차 및 굴곡의 영향으로 저항값, 투과율 등의 특성에 대한 균일성이 유지되지 못하여 구동 노이즈가 발생하거나 패턴이 시인되는 등의 문제점이 발생한다. In addition, the uniformity of characteristics such as resistance value and transmittance cannot be maintained due to the influence of the lower step and bending toward the upper layer, which causes problems such as driving noise or pattern recognition.
또한, 일반적으로 유기발광 표시장치에는 반사 방지 등의 광학 특성을 개선하기 위한 편광판이 부착되며, 이 편광판과 별도로 사용자와의 터치 인터페이스를 구현하기 위한 터치 센서가 부착된다.In addition, a polarizing plate is generally attached to an organic light emitting display device to improve optical characteristics such as anti-reflection, and a touch sensor for implementing a touch interface with a user is attached to the organic light emitting display.
한편, 이러한 편광판의 두께는 약 100-150㎛로서, 상당히 두껍기 때문에, 터치 센서의 두께를 아무리 얇게 줄여도, 이 편광판과 터치 센서가 각각 별도로 유기발광 표시장치에 부착되면, 편광판의 두께로 인하여 유기발광 표시장치의 유연성이 저하되는 문제점이 있다.On the other hand, since the thickness of the polarizing plate is about 100-150 μm, which is considerably thick, no matter how thin the thickness of the touch sensor is, if the polarizing plate and the touch sensor are separately attached to the organic light emitting display device, the organic light emitting diode is emitted due to the thickness of the polarizing plate. There is a problem that the flexibility of the display device is lowered.
본 발명은 상술한 바와 같은 기술적 배경에서 안출된 것으로, 컬러필터와 터치센서를 일체화하여 하나의 유연성 기판 상에 두 개의 기능 디바이스를 구현하는 것을 그 과제로 한다.SUMMARY OF THE INVENTION The present invention has been made in the technical background as described above, and its object is to implement two functional devices on one flexible substrate by integrating a color filter and a touch sensor.
본 발명의 다른 과제는 하나의 유연성 기판을 사용하여 컬러필터와 터치센서를 일체화하여 더욱 얇고 유연한 유연성 표시장치를 구현하는 것이다.Another object of the present invention is to realize a thinner and more flexible flexible display device by integrating a color filter and a touch sensor using one flexible substrate.
본 발명의 또 다른 과제는 평탄도 저하에 따른 불량 발생을 줄이고 균일성이 우수한 컬러필터 일체형 유연성 터치센서 및 그 제조 방법을 제공하는 것이다.Another object of the present invention is to provide a color filter integrated flexible touch sensor excellent in uniformity and reducing defects caused by lowering flatness, and a method of manufacturing the same.
본 발명의 또 다른 과제는 유기발광 표시장치에 구비되는 반사 방지 편광판을 컬러필터로 대체하여 유기발광 표시장치의 외광 반사율을 줄이고 색재현성을 향상시키는 것이다.Another object of the present invention is to replace the anti-reflective polarizing plate provided in the organic light emitting display with a color filter to reduce the external light reflectance of the organic light emitting display and to improve color reproducibility.
이와 같은 과제를 해결하기 위하여, 본 발명에서는 분리층; 상기 분리층 상부의 컬러필터층; 상기 컬러필터층 상부의 접착층; 상기 접착층 상부의 중간 기재; 및 상기 중간 기재 상부의 터치센서층을 포함하는 컬러필터 일체형 유연성 터치센서를 제공한다.In order to solve this problem, in the present invention; A color filter layer on the separation layer; An adhesive layer on the color filter layer; An intermediate substrate on the adhesive layer; And it provides a color filter integrated flexible touch sensor comprising a touch sensor layer on the intermediate substrate.
상기 중간 기재는 유리 기판 또는 필름 기재일 수 있다.The intermediate substrate may be a glass substrate or a film substrate.
상기 중간 기재는 굴절률 조절층을 포함할 수 있다.The intermediate substrate may include a refractive index adjusting layer.
상기 접착층은 광경화성 접착제로 이루어질 수 있다.The adhesive layer may be made of a photocurable adhesive.
상기 컬러필터 일체형 유연성 터치센서는 상기 분리층과 상기 컬러필터층 사이의 보호층을 더 포함할 수 있다.The color filter integrated flexible touch sensor may further include a protective layer between the separation layer and the color filter layer.
상기 컬러필터 일체형 유연성 터치센서는 상기 컬러필터층과 상기 접착층 사이의 오버코트층을 더 포함할 수 있다.The color filter integrated flexible touch sensor may further include an overcoat layer between the color filter layer and the adhesive layer.
본 발명의 다른 양상에 따르면, 캐리어 기판 상에 분리층을 형성하는 단계; 상기 분리층 상부에 컬러필터층을 형성하는 단계; 상기 컬러필터층 상부에 접착층을 형성하는 단계; 상기 접착층 상에 중간 기재를 합착하는 단계; 상기 중간 기재 상부에 터치센서층을 형성하는 단계; 및 상기 캐리어 기판을 분리하는 단계를 포함하는 컬러필터 일체형 유연성 터치센서의 제조 방법이 제공된다.According to another aspect of the invention, forming a separation layer on a carrier substrate; Forming a color filter layer on the separation layer; Forming an adhesive layer on the color filter layer; Bonding an intermediate substrate on the adhesive layer; Forming a touch sensor layer on the intermediate substrate; And it provides a method of manufacturing a color filter integrated flexible touch sensor comprising the step of separating the carrier substrate.
상기 접착층은 광경화성 접착제로 이루어질 수 있으며, 상기 중간 기재를 합착하는 단계는 상기 접착층 상에 상기 중간 기재를 배치하는 단계; 및 상기 접착층을 광경화하는 단계를 포함할 수 있다.The adhesive layer may be formed of a photocurable adhesive, and the bonding of the intermediate substrate may include disposing the intermediate substrate on the adhesive layer; And photocuring the adhesive layer.
본 발명의 컬러필터 일체형 유연성 터치센서의 제조 방법은 상기 터치센서층을 형성하는 단계 이후에, 상기 터치센서층 상부에 보호필름을 부착하는 단계를 더 포함하고, 상기 캐리어 기판을 분리하는 단계 이후에, 상기 보호필름을 제거하는 단계를 더 포함할 수 있다. The method of manufacturing a color filter integrated flexible touch sensor according to the present invention further includes attaching a protective film on the touch sensor layer after forming the touch sensor layer, and after separating the carrier substrate. The method may further include removing the protective film.
또한, 상기 분리층과 상기 컬러필터층 사이에 보호층을 형성하는 단계를 더 포함할 수 있다.The method may further include forming a protective layer between the separation layer and the color filter layer.
상기 컬러필터 일체형 유연성 터치센서의 제조 방법은 상기 중간 기재 상에 굴절률 조절층을 형성하는 단계를 더 포함할 수 있다.The method of manufacturing the color filter integrated flexible touch sensor may further include forming a refractive index control layer on the intermediate substrate.
상기 컬러필터 일체형 유연성 터치센서의 제조 방법은 상기 컬러필터층 상에 오버코트층을 형성하는 단계를 더 포함할 수 있다.The method of manufacturing the color filter integrated flexible touch sensor may further include forming an overcoat layer on the color filter layer.
본 발명의 또 다른 양상에 따르면 상술한 바와 같은 컬러필터 일체형 유연성 터치센서를 포함하는 유연성 표시장치가 제공된다.According to still another aspect of the present invention, there is provided a flexible display device including the color filter integrated flexible touch sensor as described above.
상기 유연성 표시장치는 또는 유기발광 표시장치일 수 있다.The flexible display device may be an organic light emitting display device.
본 발명의 컬러필터 일체형 유연성 터치센서에서는 컬러필터와 터치센서를 일체화하여 하나의 유연성 기판으로 두 개의 기능 디바이스를 구현할 수 있다.In the color filter integrated flexible touch sensor of the present invention, two functional devices may be implemented with one flexible substrate by integrating the color filter and the touch sensor.
본 발명의 컬러필터 일체형 유연성 터치센서에서는 하나의 유연성 기판을 사용하여 컬러필터와 터치센서를 일체화하여 더욱 얇고 유연한 표시장치를 얻을 수 있다.In the color filter integrated flexible touch sensor of the present invention, a thinner and more flexible display device can be obtained by integrating the color filter and the touch sensor using one flexible substrate.
본 발명의 컬러필터 일체형 유연성 터치센서에서는 중간 기재를 사용함으로써 평탄도가 개선되어 불량 발생을 줄일 수 있으며, 이에 따라 균일하고 우수한 터치 입력 감지 성능을 얻을 수 있다.In the color filter integrated flexible touch sensor of the present invention, the flatness is improved by using an intermediate substrate, thereby reducing the occurrence of defects, thereby obtaining a uniform and excellent touch input sensing performance.
본 발명의 컬러필터 일체형 유연성 터치센서를 유기발광 표시장치에 적용하면, 컬러필터로 반사 방지 편광판을 대체할 수 있어 유기발광 표시장치의 외광 반사율을 줄이고 색재현성을 향상시킬 뿐 아니라 유기발광 표시장치의 두께를 현저히 줄일 수 있다.When the color filter integrated flexible touch sensor of the present invention is applied to an organic light emitting display device, a color filter can be used to replace the anti-reflective polarizing plate, thereby reducing the external light reflectance and improving color reproducibility of the organic light emitting display device. The thickness can be significantly reduced.
도 1은 본 발명의 일 실시예에 따른 컬러필터 일체형 유연성 터치센서의 단면도이다.1 is a cross-sectional view of a flexible color sensor integrated touch sensor according to an embodiment of the present invention.
도 2a 내지 도 2g는 본 발명의 일 실시예에 따른 컬러필터 일체형 유연성 터치센서의 제조방법에 따른 각 단계별 공정 단면도이다.2A to 2G are cross-sectional views of each step according to a method of manufacturing a color filter integrated flexible touch sensor according to an exemplary embodiment of the present invention.
도 3은 본 발명의 일 실시예에 따른 컬러필터 일체형 유연성 터치센서를 포함하는 표시장치의 단면도이다.3 is a cross-sectional view of a display device including a color filter integrated flexible touch sensor according to an exemplary embodiment.
이하, 도면을 참조하여 본 발명에 따른 컬러필터 일체형 유연성 터치센서 및 그 제조 방법의 바람직한 실시예에 관하여 상세히 설명한다. 다만 본 명세서에 첨부된 도면들은 본 발명을 설명하기 위한 예시일 뿐, 본 발명이 도면에 의해 한정되는 것은 아니다. 또한, 설명 상의 편의를 위해 일부 구성요소들은 도면 상에서 과장되게 표현되거나, 축소 또는 생략되어 있을 수 있다.Hereinafter, with reference to the drawings will be described in detail a preferred embodiment of the color filter integrated flexible touch sensor according to the present invention and a manufacturing method thereof. However, the drawings attached to the present specification are only examples for describing the present invention, and the present invention is not limited to the drawings. In addition, some of the components may be exaggerated, reduced or omitted in the drawings for convenience of description.
도 1은 본 발명의 일 실시예에 따른 컬러필터 일체형 유연성 터치센서의 단면도이다.1 is a cross-sectional view of a flexible color sensor integrated touch sensor according to an embodiment of the present invention.
본 발명의 일 실시예에 따른 컬러필터 일체형 유연성 터치센서(10)는, 도 1을 참조하면, 분리층(110), 분리층(110) 상부의 보호층(120), 보호층(120) 상부에 형성되며 블랙매트릭스(130)와 화소영역(140)을 포함하는 컬러필터층, 컬러필터층 상부의 접착층(150), 접착층(150) 상부의 중간 기재(200) 및 중간 기재 상부(200)의 터치센서층(300)을 포함한다. Referring to FIG. 1, the color filter integrated flexible touch sensor 10 according to an exemplary embodiment of the present invention may include a separation layer 110, a protective layer 120 on the separation layer 110, and an upper portion of the protective layer 120. A color filter layer formed on the black matrix 130 and the pixel region 140, an adhesive layer 150 on the color filter layer, an intermediate substrate 200 on the adhesive layer 150, and a touch sensor on the intermediate substrate 200. Layer 300.
분리층(110)은 본 발명의 제조공정에서 컬러필터 일체형 유연성 터치센서의 제조가 완료된 후에 캐리어 기판과의 박리를 위해 형성하는 층이다. 따라서 분리층(110)은 캐리어 기판과는 물리적인 힘을 통해 분리될 수 있다.The separation layer 110 is a layer formed for peeling with the carrier substrate after the manufacture of the color filter integrated flexible touch sensor in the manufacturing process of the present invention. Therefore, the separation layer 110 may be separated from the carrier substrate through physical force.
일정 수준의 박리력과 투명성을 제공하는 조건을 충족시키면 분리층(110)의 소재는 특별히 한정되지 않는다. 예를 들어, 분리층(110)은 폴리이미드(polyimide)계 고분자, 폴리비닐알코올(poly vinyl alcohol)계 고분자, 폴리아믹산(polyamic acid)계 고분자, 폴리아미드(polyamide)계 고분자, 폴리에틸렌(polyethylene)계 고분자, 폴리스타일렌(polystylene)계 고분자, 폴리노보넨(polynorbornene)계 고분자, 페닐말레이미드 공중합체(phenylmaleimide copolymer)계 고분자, 폴리아조벤젠(polyazobenzene)계 고분자, 폴리페닐렌프탈아미드(polyphenylenephthalamide)계 고분자, 폴리에스테르(polyester)계 고분자, 폴리메틸 메타크릴레이트(polymethyl methacrylate)계 고분자, 폴리아릴레이트(polyarylate)계 고분자, 신나메이트(cinnamate)계 고분자, 쿠마린(coumarin)계 고분자, 프탈리미딘(phthalimidine)계 고분자, 칼콘(chalcone)계 고분자, 방향족 아세틸렌계(aromatic acetylene) 고분자 등의 고분자로 제조된 것일 수 있으며, 이들은 단독 또는 2종 이상 혼합되어 사용될 수 있다.The material of the separation layer 110 is not particularly limited as long as a condition of providing a certain level of peeling force and transparency is satisfied. For example, the separation layer 110 may be a polyimide polymer, a polyvinyl alcohol polymer, a polyamic acid polymer, a polyamide polymer, polyethylene Polymer, polystylene polymer, polynorbornene polymer, phenylmaleimide copolymer polymer, polyazobenzene polymer, polyphenylenephthalamide polymer , Polyester (polyester) polymer, polymethyl methacrylate (polymer) polymer, polyarylate (polymer) polymer, cinnamate (polymer) polymer, coumarin (coumarin) polymer, phthalimidine (phthalimidine) ) -Based polymers, chalc (chalcone) -based polymers, aromatic acetylene (aromatic acetylene) may be made of a polymer such as polymers, these alone or 2 Or more may be mixed and used.
분리층(110)의 박리력은 특별히 한정되지 않으나, 예를 들어, 0.01N/25mm 이상 1N/25mm 이하일 수 있으며, 바람직하게는 0.01N/25mm 이상 0.1N/25mm 이하일 수 있다. 상기 범위를 만족하는 경우, 본 발명의 컬러필터 일체형 유연성 터치센서의 제조공정에서, 캐리어 기판으로부터 잔여물 없이 용이하게 박리될 수 있으며, 박리시 발생하는 장력에 의한 컬(curl) 및 크랙(crack)을 저감할 수 있다.The peeling force of the separation layer 110 is not particularly limited, but may be, for example, 0.01N / 25mm or more and 1N / 25mm or less, preferably 0.01N / 25mm or more and 0.1N / 25mm or less. When satisfying the above range, in the manufacturing process of the color filter integrated flexible touch sensor of the present invention, it can be easily peeled off from the carrier substrate without residue, curl and crack due to the tension generated during peeling Can be reduced.
분리층(110)의 두께는 특별히 한정되지 않으나, 예를 들어, 10 내지 1,000㎚일 수 있으며, 바람직하게는 50 내지 500㎚일 수 있다. 상기 범위를 만족하는 경우, 박리력이 안정하고, 균일한 패턴을 형성할 수 있다.The thickness of the separation layer 110 is not particularly limited, but may be, for example, 10 to 1,000 nm, preferably 50 to 500 nm. When the said range is satisfied, peeling force is stable and a uniform pattern can be formed.
보호층(120)은 상기 분리층(110)을 보호하기 위한 층으로 분리층(110) 위에 형성되며 필요에 따라 생략될 수 있는 선택적인 구성요소이다. The protective layer 120 is a layer for protecting the separation layer 110 and is an optional component formed on the separation layer 110 and may be omitted as necessary.
보호층(120)은 본 발명의 컬러필터 일체형 유연성 터치센서를 제조하는 공정 중에 분리층(110)이 컬러 필터 형성을 위해 사용되는 컬러 필터용 포토레지스트의 용매 등과 같은 공정용 화학물질이나 현상액, 공정간 발생하는 세정액 등에 노출되어 손상되는 것을 방지한다.The protective layer 120 is a process chemical, a developer, a process such as a solvent of a color filter photoresist for which the separation layer 110 is used to form a color filter during the process of manufacturing the color filter integrated flexible touch sensor of the present invention. It is prevented from being damaged by exposure to the cleaning liquid generated in the liver.
보호층(120)의 소재로는 당 기술분야에 공지된 고분자가 제한없이 사용될 수 있으며, 예를 들면 유기 절연막이 적용될 수 있으며, 그 중에서도 폴리올(polyol) 및 멜라민(melamine) 경화제를 포함하는 경화성 조성물로 형성된 것일 수 있으나, 이에 한정되는 것은 아니다. The material of the protective layer 120 may be a polymer known in the art without limitation, for example, an organic insulating film may be applied, and among these, a curable composition comprising a polyol and a melamine curing agent. It may be formed as, but is not limited thereto.
폴리올의 구체적인 종류로는 폴리에테르 글리콜(polyether glycol) 유도체, 폴리에스테르 글리콜(polyester glycol) 유도체, 폴리카프로락톤 글리콜(polycaprolactone glycol) 유도체 등을 들 수 있으나, 이에 한정되는 것은 아니다.Specific examples of the polyol include, but are not limited to, polyether glycol derivatives, polyester glycol derivatives, polycaprolactone glycol derivatives, and the like.
멜라민 경화제의 구체적인 종류로는 메톡시 메틸 멜라민(methoxy methyl melamine) 유도체, 메틸 멜라민(methyl melamine) 유도체, 부틸 멜라민(butyl melamine) 유도체, 이소부톡시 멜라민(isobutoxy melamine) 유도체 및 부톡시 멜라민(butoxy melamine) 유도체 등을 들 수 있으나, 이에 한정되는 것은 아니다.Specific types of melamine curing agents include methoxy methyl melamine derivatives, methyl melamine derivatives, butyl melamine derivatives, isobutoxy melamine derivatives and butoxy melamine Derivatives and the like, but are not limited thereto.
다른 예로, 보호층(120)은 유무기 하이브리드 경화성 조성물로 형성될 수 있으며, 유기 화합물과 무기 화합물을 동시에 사용하는 경우, 박리시 발생하는 크랙을 저감할 수 있다는 점에서 바람직하다.As another example, the protective layer 120 may be formed of an organic-inorganic hybrid curable composition, and when using an organic compound and an inorganic compound at the same time, it is preferable in that the cracks generated during peeling may be reduced.
유기 화합물로는 전술한 성분이 사용될 수 있고, 무기물로는 실리카계 나노 입자, 실리콘계 나노 입자, 유리 나노 섬유 등을 들 수 있으나, 이에 한정되는 것은 아니다.As the organic compound, the above-described components may be used, and the inorganic material may include silica-based nanoparticles, silicon-based nanoparticles, glass nanofibers, and the like, but is not limited thereto.
블랙매트릭스(130)와 화소영역(140)으로 구성되는 컬러필터층은 보호층(120) 상에 형성되어 있으며, 외광 반사율을 줄이고, 디스플레이의 색 재현성을 높이는 기능을 수행한다.The color filter layer including the black matrix 130 and the pixel region 140 is formed on the protective layer 120, and functions to reduce external light reflectance and to improve color reproducibility of the display.
한편, 보호층(120)이 생략되는 경우에는 분리층(110) 상에 컬러필터층이 배치될 수 있다. Meanwhile, when the protective layer 120 is omitted, the color filter layer may be disposed on the separation layer 110.
블랙매트릭스(130)는 화소영역(140)을 제외한 부분의 빛을 차단하고 각 화소영역의 경계에서 혼색을 방지하는 역할을 하는 차광층이며, 따라서 블랙매트릭스(130)는 불투명 물질로 형성되고, 화소영역(140)을 둘러싸도록 패터닝되어 있다. The black matrix 130 is a light blocking layer that blocks light in portions other than the pixel region 140 and prevents color mixing at the boundary of each pixel region. Therefore, the black matrix 130 is formed of an opaque material, and the pixel Patterned to surround area 140.
화소영역(140)은 컬러 디스플레이용 색 구현을 위한 착색층으로 통상적으로 적색(Red), 녹색(Green), 청색(Blue) 영역을 포함하며, 블랙매트릭스(130) 패턴에 의해 그 영역이 정의된다. The pixel region 140 is a colored layer for color display for color display, and typically includes red, green, and blue regions, and the region is defined by a black matrix 130 pattern. .
그러나, 화소영역(140)이 적색, 녹색, 청색을 모두 포함하여야 하거나 적색, 녹색, 청색만을 포함하여야 하는 것은 아니며, 표시장치의 색상 표현 방식에 따라 이 중 임의의 일부 색상만이 포함되거나 백색(White) 등과 같은 다른 색상이 더 포함될 수도 있다.However, the pixel area 140 does not have to include all of red, green, and blue, or only red, green, and blue, and may include only some of the colors or white (depending on the color representation of the display device). Other colors such as White) may be further included.
컬러필터층은 본 발명의 실시예에 따른 컬러필터 일체형 유연성 터치센서를 유기발광 표시장치에 적용할 경우 반사 방지 편광판을 대체하여 유기발광 표시장치의 외광 반사율을 줄이고 색재현성을 향상시킬 수 있다.When the color filter integrated flexible touch sensor according to the exemplary embodiment of the present invention is applied to the organic light emitting display, the color filter layer may reduce the external light reflectance of the organic light emitting display and improve color reproducibility by replacing the anti-reflective polarizing plate.
한편, 도면 상에 도시되어 있지는 않지만, 컬러필터층 상부에 오버코트층이 더 포함될 수도 있다. 그러나, 통상 오버코트층은 평탄화를 위해 형성하는데, 본 발명의 일 실시예에 따른 컬러필터 일체형 유연성 터치센서에서는 후술할 접착층(150) 및 중간 기재(200)에 의해 평탄화가 더욱 유리하게 달성되므로 오버코트층을 형성하지 않아도 되는 이점이 있다. 또한 이로 인하여 공정의 단순화와 장치의 박막화를 달성할 수 있다. Although not shown in the drawings, an overcoat layer may be further included on the color filter layer. However, in general, the overcoat layer is formed for flattening. In the color filter integrated flexible touch sensor according to the exemplary embodiment of the present invention, the flattening is more advantageously achieved by the adhesive layer 150 and the intermediate substrate 200 which will be described later. There is an advantage that does not need to form. This also enables the simplification of the process and the thinning of the device.
컬러필터층 상부에는 접착층(150)이 형성되고 접착층(150)에 의해 중간 기재(200)가 부착되어 있다.An adhesive layer 150 is formed on the color filter layer, and the intermediate substrate 200 is attached by the adhesive layer 150.
접착층(150)은 평탄화되어 있지 않은 컬러필터층 표면의 단차부를 평탄화시키고 컬러필터층 상에 중간 기재(200)를 부착하는 두 가지 기능을 수행한다. The adhesive layer 150 performs two functions of flattening the stepped portion of the surface of the color filter layer that is not planarized and attaching the intermediate substrate 200 on the color filter layer.
접착층(150)으로는 광경화형 접착제가 사용될 수 있으며, 이 기술분야에서 사용되는 광경화형 접착제를 특별한 제한 없이 사용할 수 있다. 예를 들면, 에폭시 화합물 또는 아크릴계 단량체를 포함하는 조성물을 사용할 수 있다.As the adhesive layer 150, a photocurable adhesive may be used, and the photocurable adhesive used in the art may be used without particular limitation. For example, a composition containing an epoxy compound or an acrylic monomer can be used.
중간 기재(200)로는 박형 유리 기판 또는 유연성 필름 기재를 사용할 수 있으며, 특히 투명필름을 사용할 수 있다. As the intermediate substrate 200, a thin glass substrate or a flexible film substrate may be used, and in particular, a transparent film may be used.
투명필름은 투명성, 기계적 강도, 열안정성이 우수한 필름이 사용될 수 있으며, 구체적인 예로는, 폴리에틸렌테레프탈레이트, 폴리에틸렌이소프탈레이트, 폴리에틸렌나프탈레이트, 폴리부틸렌테레프탈레이트 등의 폴리에스테르계 수지; 디아세틸셀룰로오스, 트리아세틸셀룰로오스 등의 셀룰로오스계 수지; 폴리카보네이트계 수지; 폴리메틸(메타)아크릴레이트, 폴리에틸(메타)아크릴레이트 등의 아크릴계 수지; 폴리스티렌, 아크릴로니트릴-스티렌 공중합체 등의 스티렌계 수지; 폴리에틸렌, 폴리프로필렌, 시클로계 또는 노보넨 구조를 갖는 폴리올레핀, 에틸렌-프로필렌 공중합체 등의 폴리올레핀계 수지; 염화비닐계 수지; 나일론, 방향족 폴리아미드 등의 아미드계 수지; 이미드계 수지; 폴리에테르술폰계 수지; 술폰계 수지; 폴리에테르에테르케톤계 수지; 황화 폴리페닐렌계 수지; 비닐알코올계 수지; 염화비닐리덴계 수지; 비닐부티랄계 수지; 알릴레이트계 수지; 폴리옥시메틸렌계 수지; 에폭시계 수지 등과 같은 열가소성 수지로 구성된 필름을 들 수 있으며, 상기 열가소성 수지의 블렌드물로 구성된 필름도 사용할 수 있다. 또한, (메타)아크릴계, 우레탄계, 아크릴우레탄계, 에폭시계, 실리콘계 등의 열경화형 수지 또는 자외선 경화형 수지로 된 필름을 이용할 수도 있다. As the transparent film, a film having excellent transparency, mechanical strength and thermal stability may be used. Specific examples thereof include polyester-based resins such as polyethylene terephthalate, polyethylene isophthalate, polyethylene naphthalate, and polybutylene terephthalate; Cellulose resins such as diacetyl cellulose and triacetyl cellulose; Polycarbonate resins; Acrylic resins such as polymethyl (meth) acrylate and polyethyl (meth) acrylate; Styrene resins such as polystyrene and acrylonitrile-styrene copolymers; Polyolefin-based resins such as polyethylene, polypropylene, cyclo-based or norbornene-structured polyolefins, ethylene-propylene copolymers; Vinyl chloride-based resins; Amide resins such as nylon and aromatic polyamides; Imide resin; Polyether sulfone resin; Sulfone resins; Polyether ether ketone resins; Sulfided polyphenylene resins; Vinyl alcohol-based resins; Vinylidene chloride-based resins; Vinyl butyral resin; Allyl resins; Polyoxymethylene resin; And films composed of thermoplastic resins such as epoxy resins, and the like, and films composed of blends of the above thermoplastic resins may also be used. Moreover, the film of thermosetting resin or ultraviolet curable resin, such as (meth) acrylic-type, urethane type, acrylurethane type, epoxy type, silicone type, can also be used.
이와 같은 투명필름의 두께는 적절히 결정할 수 있지만, 일반적으로는 강도나 취급성 등의 작업성, 박층성 등의 점에서 1 내지 500㎛ 정도이며, 1 내지 300㎛가 바람직하고, 5 내지 200㎛가 보다 바람직하다.Although the thickness of such a transparent film can be suitably determined, it is generally about 1-500 micrometers in terms of workability, thinness, etc., such as intensity | strength and handleability, and 1-300 micrometers is preferable, and 5-200 micrometers is More preferred.
이러한 투명필름은 적절한 1종 이상의 첨가제가 함유된 것일 수도 있다. 첨가제로는, 예컨대 자외선흡수제, 산화방지제, 윤활제, 가소제, 이형제, 착색방지제, 난연제, 대전방지제, 안료, 착색제 등을 들 수 있다. 상기 투명 필름은 필름의 일면 또는 양면에 하드코팅층, 반사방지층, 가스배리어층과 같은 다양한 기능성층을 포함하는 구조일 수 있으며, 기능성층은 전술한 것으로 한정되는 것은 아니며, 용도에 따라 다양한 기능성층을 포함할 수 있다.Such a transparent film may contain an appropriate one or more additives. As an additive, a ultraviolet absorber, antioxidant, a lubricating agent, a plasticizer, a mold release agent, a coloring agent, a flame retardant, an antistatic agent, a pigment, a coloring agent, etc. are mentioned, for example. The transparent film may have a structure including various functional layers such as a hard coating layer, an antireflection layer, and a gas barrier layer on one or both surfaces of the film, and the functional layer is not limited to the above-described ones. It may include.
또한, 필요에 따라 투명필름은 표면 처리된 것일 수 있다. 이러한 표면 처리로는 플라즈마 처리, 코로나 처리, 프라이머 처리 등의 건식 처리, 검화 처리를 포함하는 알칼리 처리 등의 화학 처리 등을 들 수 있다.In addition, the transparent film may be surface-treated as needed. Such surface treatments include dry treatments such as plasma treatments, corona treatments, primer treatments, and chemical treatments such as alkali treatments including saponification treatments.
또한, 중간 기재(200)는 굴절률 조절층(index matching layer)(도시하지 않음)을 포함할 수 있다. In addition, the intermediate substrate 200 may include an index matching layer (not shown).
굴절률 조절층은 컬러필터 일체형 유연성 터치센서의 광학적 균일도를 개선하기 위한 것으로서, 구체적으로는 중간 기재(200) 상부의 터치센서층(300)의 각 패턴들의 위치별 구조적 차이에 의한 광학적 특성 차이를 감소시키는 기능을 하며, 이와 같이 굴절률 조절층을 포함하는 경우, 감지 패턴의 패턴부와 비패턴부의 반사율 차이를 감소시켜 감지 패턴의 시인성을 개선할 수 있다.The refractive index control layer is to improve the optical uniformity of the color filter integrated flexible touch sensor. Specifically, the refractive index control layer reduces the difference in optical characteristics due to the structural differences of the patterns of the touch sensor layer 300 on the intermediate substrate 200. In the case of including the refractive index adjusting layer, the visibility of the sensing pattern may be improved by reducing the difference in reflectance between the pattern portion and the non-patterning portion of the sensing pattern.
굴절률 조절층은 1.5 내지 1.87의 고굴절률을 갖는 단일막으로 구성될 수 있으며, 두께는 30㎚ - 2000㎚일 수 있다.The refractive index control layer may be composed of a single film having a high refractive index of 1.5 to 1.87, the thickness may be 30nm-2000nm.
또는 굴절률 조절층은 굴절률이 서로 다른 적어도 2개의 층이 적층되어 형성된 것일 수도 있다. 다층막일 경우에는 고굴절 및 저굴절의 물질이 반복되어 형성될 수 있다.Alternatively, the refractive index adjusting layer may be formed by stacking at least two layers having different refractive indices. In the case of a multilayer film, high and low refractive materials may be repeatedly formed.
하나의 예로, 굴절률 조절층은 무기 절연막을 포함하여 구성될 수 있으며, 구체적인 예로, SiO2, Al2O3, MgO, NdF3, SiON, Y2O3, ZnO, TiO2, ZrO2, Nb2O5로 이루어진 군에서 선택된 1종 이상을 포함하도록 구성될 수 있다.As one example, the refractive index control layer may be configured to include an inorganic insulating film, specific examples, SiO 2 , Al 2 O 3 , MgO, NdF 3 , SiON, Y 2 O 3 , ZnO, TiO 2 , ZrO 2 , Nb It may be configured to include one or more selected from the group consisting of 2 O 5 .
다른 예로, 굴절률 조절층은 유기 절연막을 포함하여 구성될 수 있으며, 구체적인 예로, 굴절률 조절층은 무기 미립자가 함유된 유기물을 포함하도록 구성될 수 있다.As another example, the refractive index control layer may be configured to include an organic insulating layer, and as a specific example, the refractive index control layer may be configured to include an organic material containing inorganic fine particles.
굴절률 조절층이 무기 미립자가 함유된 유기물을 포함하여 구성되는 경우, 예를 들어, 유기물은 아크릴 수지, 우레탄 수지, 멜라민 수지, 알키드 수지, 실록산계 폴리머, 유기 실란 축합물로 이루어진 군에서 선택된 1종 이상을 포함할 수 있으나, 이에 한정되지는 않는다.When the refractive index control layer comprises an organic material containing inorganic fine particles, for example, the organic material is one selected from the group consisting of acrylic resins, urethane resins, melamine resins, alkyd resins, siloxane-based polymers and organic silane condensates. It may include the above, but is not limited thereto.
굴절률 조절층이 무기 미립자가 함유된 유기물을 포함하여 구성되는 경우, 무기 미립자는 SiO2, Al2O3, MgO, NdF3, SiON, Y2O3, ZnO, TiO2, ZrO2, Nb2O5로 이루어진 군에서 선택된 1종 이상을 포함하도록 구성될 수 있으나, 이에 한정되지는 않는다. When the refractive index control layer comprises an organic material containing inorganic fine particles, the inorganic fine particles are SiO 2 , Al 2 O 3 , MgO, NdF 3 , SiON, Y 2 O 3 , ZnO, TiO 2 , ZrO 2 , Nb 2 It may be configured to include one or more selected from the group consisting of O 5 , but is not limited thereto.
굴절률 조절층이 무기 미립자가 함유된 유기물을 포함하여 구성되는 경우, 예를 들어, 무기 미립자의 함량을 조절하여 굴절률 조절층의 굴절률을 조절하도록 구성될 수 있다. 예를 들어, 무기 미립자의 함량을 높여 굴절률 조절층의 굴절률을 높이고, 반대로, 무기 미립자의 함량을 줄여 굴절률 조절층의 굴절률을 낮출 수 있다.When the refractive index adjusting layer includes an organic material containing inorganic fine particles, for example, the refractive index of the refractive index adjusting layer may be adjusted by adjusting the content of the inorganic fine particles. For example, the refractive index of the refractive index control layer may be increased by increasing the content of the inorganic fine particles, and conversely, the refractive index of the refractive index control layer may be reduced by reducing the content of the inorganic fine particles.
굴절률 조절층은 증착 공정 또는 습식 코팅 방식으로 형성될 수 있다.The refractive index adjusting layer may be formed by a deposition process or a wet coating method.
중간 기재(200) 상부에는 터치센서층(300)이 형성되어 있다. The touch sensor layer 300 is formed on the intermediate substrate 200.
터치센서층(300)은 정전용량 방식 터치센서에 사용되는 전극 패턴의 구조를 가지며, 상호 정전용량 방식(mutual-capacitive type) 또는 자기 정전용량 방식(self-capacitive type)이 적용될 수 있다. The touch sensor layer 300 has a structure of an electrode pattern used in a capacitive touch sensor, and a mutual capacitive type or a self-capacitive type may be applied.
상호 정전용량 방식일 경우, 가로축과 세로축의 격자 전극구조일 수 있다. 가로축과 세로축의 전극의 교차점에는 브리지 전극을 포함할 수 있다.In the case of the mutual capacitance type, the grid electrode structure may be a horizontal axis and a vertical axis. The intersection electrode of the horizontal axis and the vertical axis may include a bridge electrode.
자기 정전용량 방식일 경우, 각 지점의 한 개의 전극을 사용해 정전용량 변화를 읽어내는 방식의 전극 패턴 구조를 가질 수 있다. In the case of the self capacitance method, an electrode pattern structure of a method of reading capacitance change using one electrode at each point may be provided.
터치센서층(300)의 전극은 금속, 금속 나노와이어, 금속 산화물, 탄소 나노튜브, 그래핀, 전도성 고분자 및 도전성 잉크에서 선택된 하나 이상의 물질로 형성될 수 있다.The electrode of the touch sensor layer 300 may be formed of one or more materials selected from metals, metal nanowires, metal oxides, carbon nanotubes, graphene, conductive polymers, and conductive inks.
여기서, 금속은 금, 은, 구리, 몰리브덴, 알루미늄, 팔라듐, 네오듐, 백금, 아연, 주석, 티타늄 또는 이들의 합금 중 어느 하나가 될 수 있다.Here, the metal may be any one of gold, silver, copper, molybdenum, aluminum, palladium, neodium, platinum, zinc, tin, titanium, or an alloy thereof.
그리고, 금속 나노와이어는 은 나노와이어, 구리 나노와이어, 지르코늄 나노와이어, 금 나노와이어 중 어느 하나가 될 수 있다.The metal nanowires may be any one of silver nanowires, copper nanowires, zirconium nanowires, and gold nanowires.
그리고, 금속 산화물은 인듐틴옥사이드(ITO), 인듐징크옥사이드(IZO), 인듐징크틴옥사이드(IZTO), 알루미늄징크옥사이드(AZO), 갈륨징크옥사이드(GZO), 플로린틴옥사이드(FTO), 징크옥사이드(ZnO) 중 어느 하나가 될 수 있다.In addition, the metal oxide is indium tin oxide (ITO), indium zinc oxide (IZO), indium zinc tin oxide (IZTO), aluminum zinc oxide (AZO), gallium zinc oxide (GZO), florin tin oxide (FTO), zinc oxide (ZnO) can be any one.
상기 전도성 고분자는 폴리피롤(polypyrrole), 폴리티오펜(polythiophene), 폴리아세틸렌(polyacetylene), 피닷(PEDOT) 및 폴리아닐린(polyaniline)을 포함하며, 상기 도전성 잉크는 금속파우더와 경화성 고분자 바인더가 혼합된 잉크를 포함한다.The conductive polymer includes polypyrrole, polythiophene, polyacetylene, PODOT, and polyaniline, and the conductive ink includes an ink in which a metal powder and a curable polymer binder are mixed. Include.
또한, 터치센서층(300)의 전극은 전기 저항을 저감시키기 위해 경우에 따라서는 2 이상의 전도층의 적층 구조로 이루어질 수 있다. In addition, the electrode of the touch sensor layer 300 may be made of a laminated structure of two or more conductive layers in some cases in order to reduce the electrical resistance.
터치센서층(300)의 전극이 금속 또는 금속 메시로 이루어지는 경우, 컬러필터층의 블랙매트릭스(130) 패턴과 전극 패턴이 대응하도록 형성될 수 있다.When the electrode of the touch sensor layer 300 is formed of a metal or a metal mesh, the black matrix 130 pattern and the electrode pattern of the color filter layer may correspond to each other.
터치센서층(300)의 두께는 특별히 한정되지 않으나, 컬러필터 일체형 유연성 터치센서의 유연성을 고려할 때 가급적 박막인 것이 바람직하다.The thickness of the touch sensor layer 300 is not particularly limited, but in consideration of the flexibility of the color filter integrated flexible touch sensor, the touch sensor layer 300 is preferably a thin film.
예를 들어, 터치센서층(300)을 구성하는 감지 전극 패턴들은 서로 독립적으로 3각형, 4각형, 5각형, 6각형 또는 7각형 이상의 다각형 패턴일 수 있다.For example, the sensing electrode patterns constituting the touch sensor layer 300 may be a polygonal pattern of three, four, five, six, or seven, respectively, independently of each other.
또한, 예를 들어, 터치센서층(300)은 규칙 패턴을 포함할 수 있다. 규칙 패턴이란, 패턴의 형태가 규칙성을 갖는 것을 의미한다. 예들 들어, 감지 전극 패턴들은 서로 독립적으로 직사각형 또는 정사각형과 같은 메쉬 형태나, 육각형과 같은 형태의 패턴을 포함할 수 있다.Also, for example, the touch sensor layer 300 may include a rule pattern. A regular pattern means that the pattern form has regularity. For example, the sensing electrode patterns may independently include a mesh shape such as a rectangle or a square, or a pattern like a hexagon.
또한, 예를 들어, 터치센서층(300)은 불규칙 패턴을 포함할 수 있다. 불규칙 패턴이란 패턴의 형태가 규칙성을 갖지 아니한 것을 의미한다.Also, for example, the touch sensor layer 300 may include an irregular pattern. Irregular pattern means that the shape of the pattern does not have regularity.
또한, 예를 들어, 터치센서층(300)을 구성하는 감지 전극 패턴들이 금속 나노와이어, 탄소계 물질류, 고분자 물질류 등의 재료로 형성된 경우, 감지 전극 패턴들은 망상 구조를 가질 수 있다. 감지 전극 패턴들이 망상 구조를 갖는 경우, 서로 접촉하여 인접하는 패턴들에 순차적으로 신호가 전달되므로, 높은 감도를 갖는 패턴을 실현할 수 있다.Also, for example, when the sensing electrode patterns constituting the touch sensor layer 300 are formed of a material such as metal nanowires, carbon-based materials, polymer materials, or the like, the sensing electrode patterns may have a network structure. When the sensing electrode patterns have a network structure, signals are sequentially transmitted to adjacent patterns in contact with each other, thereby realizing a pattern having high sensitivity.
이와 같이, 터치센서층(300)이 중간 기재(200) 상부에 형성되므로, 터치센서층(300)의 각 전극 패턴이 컬러필터층의 단차에 의한 영향을 받지 않는 평탄화된 면 상에 형성된다. 이는 터치센서 제조의 증착, 사진, 식각 공정에서 하부막의 영향을 최소화할 수 있으며, 터치센서 전극의 저항값, 투과율 등의 특성에 대한 균일성이 확보된다.As such, since the touch sensor layer 300 is formed on the intermediate substrate 200, each electrode pattern of the touch sensor layer 300 is formed on a flattened surface that is not affected by the step of the color filter layer. This can minimize the influence of the lower layer in the deposition, photography, and etching process of manufacturing the touch sensor, and ensures uniformity of characteristics such as resistance value and transmittance of the touch sensor electrode.
즉, 본 발명에서는 단일한 유연성 기재를 사용하여 컬러필터와 터치센서를 일체화하여 박막화를 달성할 수 있다. That is, in the present invention, the thin film may be achieved by integrating the color filter and the touch sensor using a single flexible substrate.
유연성 장치의 유연 성능을 향상시키기 위해서는 장치의 굽힘(bending) 및 접힘(folding)에 의한 응력(stress)을 해소하거나 적게 받는 구조로 장치가 설계되어야 한다. 유연성 장치에서 응력에 취약한 부분은 이에 의한 크랙(crack)이 생기기 쉬우며, 크랙이 발생하면 해당 층의 기능 저하 및 전극의 단선 등 파괴 변형이 일어나고 크랙 발생부에 수분 및 산소의 침투로 인해 부식발생 가속화 등 신뢰성의 저하를 가져온다. In order to improve the flexible performance of the flexible device, the device should be designed in a structure that eliminates or reduces stress caused by bending and folding of the device. Cracks that are susceptible to stress in the flexible device are likely to cause cracks, and when cracks occur, deterioration deformation such as deterioration of the layer and disconnection of electrodes occurs, and corrosion occurs due to the penetration of moisture and oxygen into the crack generating part. It causes a decrease in reliability such as acceleration.
즉, 유연성 장치의 두께가 두꺼운 경우는 얇을 때 보다 중립면에서 멀리 위치하게 되므로 굽힘 및 접힘시 발생하는 응력이 넓은 영역까지 작용하게 되며, 응력의 크기 또한 커지는 구조적 특성을 가지게 된다. 따라서, 응력에 취약한 부분을 중립면에서 가까이 둘수록 응력을 작게 받게 되고 이에 따른 신뢰성을 향상시킬 수 있다. In other words, when the thickness of the flexible device is thick, it is located farther from the neutral surface than when it is thin, and thus the stress generated during bending and folding acts to a wide area, and the magnitude of the stress also increases. Therefore, the closer the portion vulnerable to the stress from the neutral plane, the smaller the stress is, thereby improving reliability.
본 발명에서는 유연성 장치의 박막화를 통해 유연 성능의 향상과 이에 따른 신뢰성 개선 효과를 얻을 수 있다.In the present invention, through the thinning of the flexible device, it is possible to obtain an improvement in flexibility and an improvement in reliability.
또한, 단일한 유연성 기재를 사용하여 기재의 양면에 컬러필터와 터치센서를 형성함에 따라 컬러필터와 터치센서의 정렬의 정밀도를 높일 수 있으며, 컬러필터와 터치센서를 각각 평탄한 면 상에 형성할 수 있어 균일한 시각적 및 구동 특성을 얻을 수 있다.In addition, by forming a color filter and a touch sensor on both sides of the substrate using a single flexible substrate, the alignment accuracy of the color filter and the touch sensor can be improved, and the color filter and the touch sensor can be formed on flat surfaces, respectively. The result is uniform visual and driving characteristics.
이제 본 발명의 일 실시예에 따른 컬러필터 일체형 유연성 터치센서의 제조방법을 자세히 설명한다. 도 2a 내지 도 2g는 본 발명의 일 실시예에 따른 컬러필터 일체형 유연성 터치센서의 제조방법에 따른 각 단계별 단면도이다.Now, a method of manufacturing a color filter integrated flexible touch sensor according to an embodiment of the present invention will be described in detail. 2A to 2G are cross-sectional views of respective steps according to a method of manufacturing a color filter integrated flexible touch sensor according to an exemplary embodiment of the present invention.
본 발명의 일 실시예에 따른 컬러필터 일체형 유연성 터치센서의 제조방법은 캐리어 기판 상에서 공정을 진행한 후 전사공법을 사용하여 캐리어 기판을 제거하는 방식을 사용한다. The method of manufacturing a color filter integrated flexible touch sensor according to an exemplary embodiment of the present invention uses a method of removing a carrier substrate by using a transfer method after performing a process on a carrier substrate.
먼저, 도 2a에 나타난 바와 같이, 캐리어 기판(400)을 준비한 후, 분리층 형성용 조성물을 도포하여 분리층(110)을 형성한다. First, as shown in FIG. 2A, after preparing a carrier substrate 400, a separation layer 110 is formed by applying a composition for forming a separation layer.
캐리어 기판(400)으로는 유리 기판을 사용하는 것이 바람직하지만, 이에 제한되지 않고 다른 재질을 사용할 수도 있다. 다만, 이후의 공정 온도를 견딜 수 있도록 고온에서도 변형이 되지 않는, 즉 평탄성을 유지할 수 있는 내열성을 가진 재료가 바람직하다.Although it is preferable to use a glass substrate as the carrier substrate 400, other materials may be used without being limited thereto. However, a material having heat resistance that does not deform even at high temperatures, that is, maintains flatness, to withstand the subsequent process temperature is preferable.
분리층 형성용 조성물을 도포하는 방법으로는 공지의 코팅 방법을 사용할 수 있다. 예를 들면, 스핀 코팅, 다이 코팅, 스프레이 코팅, 롤 코팅, 스크린 코팅, 슬릿 코팅, 딥 코팅, 그라비아 코팅 등을 들 수 있다. 또는 잉크젯 방식이 사용될 수도 있다. A well-known coating method can be used as a method of apply | coating the composition for separation layer formation. For example, spin coating, die coating, spray coating, roll coating, screen coating, slit coating, dip coating, gravure coating, etc. are mentioned. Alternatively, an inkjet method may be used.
분리층 형성용 조성물은 코팅 후 경화시켜 분리층(110)을 형성한다. 이때 경화 공정은 열경화 또는 UV경화를 단독으로 사용하거나, 열경화 및 UV 경화를 조합하여 사용할 수 있다. 열경화를 사용할 경우 오븐, 핫 플레이트 등에 의해 가열할 수 있으며, 가열 온도 및 시간은 조성물에 따라 달라질 수 있으나 일례로 80 내지 250℃에서 10 내지 120 분의 조건으로 열처리할 수 있다.The composition for forming the separation layer is cured after coating to form the separation layer 110. At this time, the curing process may be used by thermosetting or UV curing alone, or a combination of thermosetting and UV curing. In the case of using thermal curing, heating may be performed by an oven, a hot plate, or the like, and heating temperature and time may vary depending on the composition, but may be heat-treated under conditions of 10 to 120 minutes at 80 to 250 ° C.
다음으로, 형성된 분리층(110) 상에 보호층 형성용 조성물을 도포하여 보호층(120)을 형성한다. Next, the protective layer forming composition is applied to the formed separation layer 110 to form a protective layer 120.
분리층(110)은 캐리어 기판(400) 상에서 공정을 진행한 후에 물리적인 힘에 의해 캐리어 기판(400)으로부터 박리될 수 있으며 이는 박리력이 매우 약하기 때문에 이를 위해 보호층(120)을 분리층(110) 위에 형성하며, 보호층(120)은 분리층(110)을 그 측면까지 감싸도록 형성될 수도 있다. The separation layer 110 may be peeled from the carrier substrate 400 by a physical force after the process on the carrier substrate 400, which is because the peeling force is very weak, the protective layer 120 for this purpose It is formed on the 110, the protective layer 120 may be formed to surround the separation layer 110 to its side.
보호층 형성용 조성물의 코팅 방법 및 경화 공정은 분리층의 형성과 관련하여 전술한 바와 같다.The coating method and the curing process of the composition for forming a protective layer are as described above in connection with the formation of the separation layer.
이제, 도 2b에 나타난 바와 같이, 형성된 보호층(120) 상에 블랙매트릭스(130) 및 화소영역(140)을 형성한다. 블랙매트릭스(130)는 불투명 유기 재료로 패터닝하여 형성하며, 블랙매트릭스(130) 패턴에 의하여 정의되는 영역에 적색(R), 녹색(G), 청색(B)의 화소영역(140)을 형성한다. 전술한 바와 같이, 화소영역(140)을 구성하는 색상은 임의로 선택될 수 있으며, 각 색상별 형성의 순서 또한 임의로 선택할 수 있다. As shown in FIG. 2B, the black matrix 130 and the pixel region 140 are formed on the formed protective layer 120. The black matrix 130 is formed by patterning with an opaque organic material, and forms the pixel regions 140 of red (R), green (G), and blue (B) in a region defined by the black matrix 130 pattern. . As described above, the color constituting the pixel region 140 may be arbitrarily selected, and the order of formation for each color may also be arbitrarily selected.
다음, 도 2c에 나타난 바와 같이, 블랙매트릭스(130)와 화소영역(140) 상에 접착층(150)을 도포한다. 접착층(150)으로 사용되는 접착제는 상술한 바와 같은 광경화형 접착제이며, 이는 광경화 후 별도의 건조 공정이 필요하지 않으므로 제조공정이 단순하여 생산성이 향상된다. Next, as shown in FIG. 2C, an adhesive layer 150 is coated on the black matrix 130 and the pixel region 140. The adhesive used as the adhesive layer 150 is a photocurable adhesive as described above, which does not require a separate drying process after the photocuring, so that the manufacturing process is simple and productivity is improved.
한편, 도면 상에 도시하지는 않았지만, 필요에 따라서는 블랙매트릭스(130)와 화소영역(140) 상에 오버코트층을 추가로 형성할 수 있으며, 이 경우에는 접착층(150)을 오버코트층 상에 도포할 수 있다.Although not shown in the drawings, an overcoat layer may be further formed on the black matrix 130 and the pixel region 140 as needed. In this case, the adhesive layer 150 may be applied on the overcoat layer. Can be.
접착층(150) 도포 후에는, 도 2d에 나타난 바와 같이, 접착층(150) 상부에 중간 기재(200)를 배치하고, 도 2e에 나타난 바와 같이, 접착층(150)을 광경화하여 중간 기재(200)를 블랙매트릭스(130)와 화소영역(140)을 포함하는 컬러필터층 상부에 합착한다. After applying the adhesive layer 150, as shown in FIG. 2D, the intermediate substrate 200 is disposed on the adhesive layer 150, and as shown in FIG. 2E, the adhesive layer 150 is photocured to form the intermediate substrate 200. Is bonded onto the color filter layer including the black matrix 130 and the pixel region 140.
접착층의 광경화에 있어서는, 원자외선, 자외선, 근자외선, 적외선 등의 광선, X선, γ선 등의 전자파 외에, 전자선, 프로톤선, 중성 자선 등을 이용할 수 있으나, 경화 속도, 조사 장치의 입수의 용이성, 가격 등으로부터 자외선 조사에 의한 경화가 유리하다.In the photocuring of the adhesive layer, electron beams, proton rays, neutron beams, and the like can be used in addition to electromagnetic waves such as ultraviolet rays such as far ultraviolet rays, ultraviolet rays, near ultraviolet rays, infrared rays, X-rays, γ-rays, etc. Hardening by ultraviolet irradiation is advantageous from the ease of use, price, and the like.
자외선 조사를 행할 때의 광원으로서는, 고압 수은등, 무전극 램프, 초고압 수은등, 카본 아크 램프, 제논 램프, 메탈할라이드 램프, 케미컬 램프, 블랙라이트 등이 이용될 수 있다.As a light source at the time of ultraviolet irradiation, a high pressure mercury lamp, an electrodeless lamp, an ultrahigh pressure mercury lamp, a carbon arc lamp, a xenon lamp, a metal halide lamp, a chemical lamp, a black light, etc. can be used.
이제, 도 2f에 나타난 바와 같이, 접착된 중간 기재(200) 상에 터치센서층(300)을 형성한다. 2F, the touch sensor layer 300 is formed on the bonded intermediate substrate 200.
터치센서층(300)의 구조 및 그 제조 방법은 이 기술분야에서 알려진 것을 제한 없이 사용할 수 있으며 본 발명에서 이를 특별히 한정하지 않는다. The structure of the touch sensor layer 300 and a method of manufacturing the same may be used without limitation in the art, which is not particularly limited in the present invention.
터치센서층(300)의 형성이 완료되면, 도 2g에 나타난 바와 같이, 캐리어 기판(400)으로부터 컬러필터 일체형 유연성 터치센서를 분리한다. When the formation of the touch sensor layer 300 is completed, as shown in FIG. 2G, the color filter integrated flexible touch sensor is separated from the carrier substrate 400.
한편, 도면 상에 도시하지는 않았지만, 터치센서를 보호하기 위하여 터치센서층(300) 상에 보호필름을 부착하고 캐리어 기판(400)을 제거한 후에 보호필름을 다시 제거할 수도 있다.Although not shown in the drawings, in order to protect the touch sensor, the protective film may be attached to the touch sensor layer 300 and the protective film may be removed again after removing the carrier substrate 400.
본 발명의 일 실시예에 따른 컬러필터 일체형 유연성 터치센서는 표시장치용으로 사용되기 위하여 표시층과 결합될 수 있다. The color filter integrated flexible touch sensor according to an exemplary embodiment of the present invention may be combined with a display layer to be used for a display device.
도 3은 본 발명의 일 실시예에 따른 표시장치의 단면도이다.3 is a cross-sectional view of a display device according to an exemplary embodiment of the present invention.
도 3을 참조하면, 본 발명의 일 실시예에 따른 표시장치는 상술한 바와 같은 본 발명의 일 실시예에 따른 컬러필터 일체형 유연성 터치센서(10) 및 컬러필터 일체형 유연성 터치센서(10) 하부의 표시층(20)을 포함하여 이루어진다.Referring to FIG. 3, a display device according to an embodiment of the present invention may include a color filter integrated flexible touch sensor 10 and a color filter integrated flexible touch sensor 10 according to an embodiment of the present invention as described above. The display layer 20 is formed.
표시층(20)으로는 유연성 표시장치에 적용할 수 있는 것을 제한 없이 사용할 수 있으며, 예를 들면, OLED층이거나 LCD층일 수 있다. 특히, 표시층(20)이 OLED층일 경우, 본 발명의 일 실시예에 따른 컬러필터 일체형 유연성 터치센서(10)는 반사방지 편광판을 대체하는 기능을 가질 수 있다.As the display layer 20, any one applicable to a flexible display device may be used without limitation, and may be, for example, an OLED layer or an LCD layer. In particular, when the display layer 20 is an OLED layer, the color filter integrated flexible touch sensor 10 according to the exemplary embodiment of the present invention may have a function of replacing an antireflective polarizing plate.
이상에서 본 발명의 바람직한 실시예에 대하여 도면을 참조하여 설명하였다. 그러나, 본 발명은 상술한 실시예에 한정되는 것은 아니며, 본 발명의 본질적인 특성에서 벗어나지 않는 범위에서 변형된 형태로 본 발명이 구현될 수 있음을 이해할 수 있을 것이다. 상술한 본 발명의 실시예들은 독립적으로 또는 그 특징들의 일부 또는 전부를 조합하여 적용될 수 있다. The preferred embodiment of the present invention has been described above with reference to the drawings. However, the present invention is not limited to the above-described embodiments, and it will be understood that the present invention can be implemented in a modified form without departing from the essential characteristics of the present invention. The above-described embodiments of the present invention may be applied independently or in combination with some or all of its features.
그러므로, 본 발명의 범위는 전술한 설명이 아니라 특허청구범위에 의해 정해지며, 그와 동등한 범위 내에 있는 모든 차이점은 본 발명에 포함되는 것으로 해석되어야 할 것이다.Therefore, the scope of the present invention is defined by the claims rather than the foregoing description, and all differences within the scope will be construed as being included in the present invention.
[부호의 설명][Description of the code]
10: 컬러필터 일체형 유연성 터치센서 20: 표시층10: color filter integrated flexible touch sensor 20: display layer
110: 분리층 120: 보호층110: separation layer 120: protective layer
130: 블랙매트릭스 140: 화소영역130: black matrix 140: pixel area
150: 접착층 200: 중간 기재150: adhesive layer 200: intermediate substrate
300: 터치센서층 400: 캐리어 기판300: touch sensor layer 400: carrier substrate

Claims (14)

  1. 분리층;Separation layer;
    상기 분리층 상부의 컬러필터층;A color filter layer on the separation layer;
    상기 컬러필터층 상부의 접착층;An adhesive layer on the color filter layer;
    상기 접착층 상부의 중간 기재; 및An intermediate substrate on the adhesive layer; And
    상기 중간 기재 상부의 터치센서층을 포함하는 컬러필터 일체형 유연성 터치센서.Color filter integrated flexible touch sensor comprising a touch sensor layer on the intermediate substrate.
  2. 제 1 항에 있어서,The method of claim 1,
    상기 중간 기재는 유리 기판 또는 필름 기재인 컬러필터 일체형 유연성 터치센서.The intermediate substrate is a color filter integrated flexible touch sensor is a glass substrate or a film substrate.
  3. 제 1 항에 있어서,The method of claim 1,
    상기 중간 기재는 굴절률 조절층을 포함하는 컬러필터 일체형 유연성 터치센서.The intermediate substrate is a color filter integrated flexible touch sensor comprising a refractive index control layer.
  4. 제 1 항에 있어서,The method of claim 1,
    상기 접착층은 광경화성 접착제로 이루어진 컬러필터 일체형 유연성 터치센서.The adhesive layer is a color filter integrated flexible touch sensor made of a photocurable adhesive.
  5. 제 1 항에 있어서,The method of claim 1,
    상기 분리층과 상기 컬러필터층 사이에 보호층을 더 포함하는 컬러필터 일체형 유연성 터치센서.A color filter integrated flexible touch sensor further comprising a protective layer between the separation layer and the color filter layer.
  6. 제 1 항에 있어서,The method of claim 1,
    상기 컬러필터층과 상기 접착층 사이의 오버코트층을 더 포함하는 컬러필터 일체형 유연성 터치센서.The color filter integrated flexible touch sensor further comprises an overcoat layer between the color filter layer and the adhesive layer.
  7. 캐리어 기판 상에 분리층을 형성하는 단계;Forming a separation layer on the carrier substrate;
    상기 분리층 상부에 컬러필터층을 형성하는 단계;Forming a color filter layer on the separation layer;
    상기 컬러필터층 상부에 접착층을 형성하는 단계;Forming an adhesive layer on the color filter layer;
    상기 접착층 상에 중간 기재를 합착하는 단계; Bonding an intermediate substrate on the adhesive layer;
    상기 중간 기재 상부에 터치센서층을 형성하는 단계; 및Forming a touch sensor layer on the intermediate substrate; And
    상기 캐리어 기판을 분리하는 단계를 포함하는 컬러필터 일체형 유연성 터치센서의 제조 방법.The manufacturing method of a color filter integrated flexible touch sensor comprising the step of separating the carrier substrate.
  8. 제 7 항에 있어서,The method of claim 7, wherein
    상기 접착층은 광경화성 접착제로 이루어지며;The adhesive layer is made of a photocurable adhesive;
    상기 중간 기재를 합착하는 단계는 Bonding the intermediate substrate is
    상기 접착층 상에 상기 중간 기재를 배치하는 단계; 및Disposing the intermediate substrate on the adhesive layer; And
    상기 접착층을 광경화하는 단계를 포함하는 컬러필터 일체형 유연성 터치센서의 제조 방법.The method of manufacturing a color filter integrated flexible touch sensor comprising the step of photocuring the adhesive layer.
  9. 제 7 항에 있어서,The method of claim 7, wherein
    상기 터치센서층을 형성하는 단계 이후에,After forming the touch sensor layer,
    상기 터치센서층 상부에 보호필름을 부착하는 단계를 더 포함하고,Attaching a protective film on the touch sensor layer;
    상기 캐리어 기판을 분리하는 단계 이후에,After separating the carrier substrate,
    상기 보호필름을 제거하는 단계를 더 포함하는 컬러필터 일체형 유연성 터치센서의 제조 방법.The method of manufacturing a color filter integrated flexible touch sensor further comprising the step of removing the protective film.
  10. 제 7 항에 있어서,The method of claim 7, wherein
    상기 분리층과 상기 컬러필터층 사이에 보호층을 형성하는 단계를 더 포함하는 컬러필터 일체형 유연성 터치센서의 제조 방법. Forming a protective layer between the separation layer and the color filter layer further comprising a color filter integrated flexible touch sensor.
  11. 제 7 항에 있어서,The method of claim 7, wherein
    상기 중간 기재 상에 굴절률 조절층을 형성하는 단계를 더 포함하는 컬러필터 일체형 유연성 터치센서의 제조 방법. Forming a refractive index control layer on the intermediate substrate further comprising the color filter integrated flexible touch sensor manufacturing method.
  12. 제 7 항에 있어서,The method of claim 7, wherein
    상기 컬러필터층 상에 오버코트층을 형성하는 단계를 더 포함하는 컬러필터 일체형 유연성 터치센서의 제조 방법. And forming an overcoat layer on the color filter layer.
  13. 제 1 항 내지 제 6 항 중 어느 한 항의 컬러필터 일체형 유연성 터치센서를 포함하는 유연성 표시장치.The flexible display device of claim 1, further comprising a color filter integrated flexible touch sensor.
  14. 제 13 항에 있어서,The method of claim 13,
    상기 유연성 표시장치는 액정 표시장치 또는 유기발광 표시장치인 유연성 표시장치.The flexible display device is a liquid crystal display device or an organic light emitting display device.
PCT/KR2019/001679 2018-02-19 2019-02-12 Flexible touch sensor having color filter integrated therein, and manufacturing method therefor WO2019160296A1 (en)

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