WO2019146229A1 - Filtration module - Google Patents

Filtration module Download PDF

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Publication number
WO2019146229A1
WO2019146229A1 PCT/JP2018/043038 JP2018043038W WO2019146229A1 WO 2019146229 A1 WO2019146229 A1 WO 2019146229A1 JP 2018043038 W JP2018043038 W JP 2018043038W WO 2019146229 A1 WO2019146229 A1 WO 2019146229A1
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WO
WIPO (PCT)
Prior art keywords
hollow fiber
concentrate
fiber membrane
nozzle
sealing portion
Prior art date
Application number
PCT/JP2018/043038
Other languages
French (fr)
Japanese (ja)
Inventor
池田 啓一
森田 徹
Original Assignee
住友電気工業株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 住友電気工業株式会社 filed Critical 住友電気工業株式会社
Priority to CN201880086284.7A priority Critical patent/CN111587145B/en
Publication of WO2019146229A1 publication Critical patent/WO2019146229A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/04Hollow fibre modules comprising multiple hollow fibre assemblies

Definitions

  • the present disclosure relates to a filtration module.
  • This application claims the priority based on Japanese Patent Application No. 2018-009547 filed on Jan. 24, 2018, and incorporates all the contents described in the Japanese application.
  • a plurality of hollow fiber membranes aligned in one direction are accommodated in a cylindrical casing, and the liquid to be treated is treated from a liquid nozzle provided at one end of the casing.
  • the filtrate is supplied into the casing and discharged from the filtrate nozzle provided at the other end of the casing into the internal space of the hollow fiber membrane, and the concentrate nozzle provided on the side near the other end of the casing
  • a so-called cross flow type filtration module is used which discharges the concentrate obtained by concentrating the liquid to be treated.
  • a flow straightening cylinder having a large number of flow straightening holes is disposed so as to surround a bundle of hollow fiber membranes inside a region where the concentrated liquid nozzle of the casing is disposed, and the hollow fiber membranes are concentrated liquid It is made not to be drawn into the nozzle (see WO 2008/035593).
  • a filtration module is a cylinder having a plurality of hollow fiber membranes aligned in one direction, a plurality of hollow fiber membranes, and a concentrate nozzle on a side surface for discharging a concentrate. And a pull-in blocking member inserted into the concentrate nozzle to prevent the hollow fiber membrane from entering the concentrate nozzle.
  • FIG. 1 is a schematic cross-sectional view showing a filtration module according to an embodiment of the present disclosure.
  • FIG. 2 is a schematic enlarged perspective view of a retraction preventing member of the filtration module of FIG.
  • the present disclosure has been made based on the circumstances as described above, and it is an object of the present disclosure to provide a filtration module capable of easily removing contaminants even if the channel is blocked by the contaminants. [Effect of the present disclosure]
  • a filtration module according to an aspect of the present disclosure can easily remove the contaminants even if the channel is blocked by the contaminants.
  • a filtration module according to an aspect of the present disclosure is a cylinder having a plurality of hollow fiber membranes aligned in one direction, a plurality of hollow fiber membranes, and a concentrate nozzle on a side surface for discharging a concentrate. And a pull-in blocking member inserted into the concentrate nozzle to prevent the hollow fiber membrane from entering the concentrate nozzle.
  • the filtration module is configured such that the pull-in preventing member for preventing the hollow fiber membrane from entering into the concentrate nozzle is inserted into the concentrate nozzle, whereby contaminants in the liquid to be treated
  • the pull-in blocking member when the pull-in blocking member is closed, the pull-in blocking member can be pulled out of the concentrate nozzle for cleaning, so that the contaminants can be easily removed and the filtering ability can be recovered.
  • the pull-in blocking member seals an inner cylindrical portion disposed inside the concentrate nozzle, and a dome-shaped sealed portion having a plurality of openings for sealing the tip of the inner cylindrical portion and allowing the concentrate to pass therethrough.
  • the sealing portion may protrude into the casing, and the plurality of openings may be elongated openings extending toward the tip of the sealing portion.
  • the sealing portion can be disposed inside the casing by having the inner cylindrical portion disposed inside the concentrate nozzle, so that the hollow fiber by the flow of the concentrate can be obtained. It is possible to more reliably prevent the membrane from being drawn into the concentrate nozzle.
  • the draw-in blocking member is formed in a dome shape that seals the tip of the inner cylindrical portion, thereby increasing the total area of the plurality of openings through which the concentrate passes and securing a sufficient flow path area. be able to. Furthermore, by forming the plurality of openings in the shape of a long hole extending toward the tip of the sealing portion, even if the hollow fiber membrane may come in contact with the openings, the direction in which the openings extend and the hollow fiber membrane Since the direction of extension of the hollow fiber membrane is different from the direction in which the hollow fiber membrane extends, the hollow fiber membrane is less likely to be drawn into the opening, and the opening is not easily closed.
  • a plurality of the elongated hole-shaped openings may be formed along the longitudinal direction toward the tip of the sealing portion.
  • the total area of the plurality of openings can be increased by forming a plurality of the elongated hole-like openings in the longitudinal direction toward the tip of the sealing portion.
  • the sealing portion may have a region where the opening does not exist at the tip in the protruding direction. As described above, the sealing portion has a region where the opening does not exist at the tip in the projecting direction which tends to draw in and close the hollow fiber membrane, thereby more reliably preventing the hollow fiber membrane from being drawn in. It becomes easier to secure the strength of the sealing portion.
  • the pull-in blocking member may have a locking portion that is locked to the outer end of the concentrate nozzle.
  • the pull-in preventing member has a locking portion, and the locking portion is locked to the outer end of the concentrate nozzle, whereby the sealing portion is easily and reliably positioned at an appropriate position. Since the arrangement can be made, the pull-in of the hollow fiber membrane can be prevented more reliably.
  • FIG. 1 shows a filtration module according to an embodiment of the present disclosure.
  • the filtration module includes a membrane element 2 having a plurality of hollow fiber membranes 1 aligned in one direction, and a cylindrical casing 3 for storing the membrane element 2 having the plurality of hollow fiber membranes 1. .
  • the membrane element 2 has a first holding member 4 holding one end of the plurality of hollow fiber membranes 1 and a second holding member 5 holding the other end of the plurality of hollow fiber membranes 1 .
  • the membrane element 2 has a connecting member 6 that connects the first holding member 4 and the second holding member 5 and determines the relative position of the two.
  • the casing 3 has a treatment liquid nozzle 7 to which the treatment liquid is supplied on the end face of one end, and a filtration for discharging the filtrate which has permeated the plural hollow fiber membranes 1 on the end face of the other end.
  • a liquid nozzle 8 is provided, and a concentrated liquid nozzle 9 for discharging a concentrated liquid obtained by subtracting the filtrate from the liquid to be treated is provided on the side near the other end.
  • the filtration module further includes a pull-in blocking member 10 which is externally inserted into the concentrate nozzle 9 and prevents the hollow fiber membrane 1 from entering the concentrate nozzle 9.
  • the filtration module prevents the concentrated water from drawing the hollow fiber membrane 1 into the concentrate nozzle 9, and the pull-in prevention member 10 is inserted into the concentrate nozzle 9 from the outside.
  • the drawing-in blocking member 10 can be pulled out from the concentrate nozzle 9 to remove contaminants. For this reason, even if the flow path of the concentrate is blocked, the filtration module can easily restore the filtration capacity without decomposing the whole.
  • the membrane element 2 integrates the plurality of hollow fiber membranes 1 by the first holding member 4, the second holding member 5 and the connecting member 6, and holds the plurality of hollow fiber membranes 1 in one direction in the casing. Make it easy to do.
  • the hollow fiber membrane 1 is formed by forming a porous membrane into a tubular shape, which allows the solvent in the liquid to be treated to permeate while blocking the permeation of impurities contained in the liquid to be treated to a certain particle size or more.
  • What has resin as a main component can be used.
  • main component means a component with the highest content.
  • thermoplastic resin examples include polyethylene, polypropylene, polyvinylidene fluoride, ethylene-vinyl alcohol copolymer, polyamide, polyimide, polyetherimide, polystyrene, polysulfone, polyvinyl alcohol, polyphenylene ether, polyphenylene sulfide, cellulose acetate, polyacrylonitrile And polytetrafluoroethylene (PTFE).
  • PTFE which is excellent in mechanical strength, chemical resistance, heat resistance, weather resistance, nonflammability and the like and is porous is preferable, and uniaxially or biaxially stretched PTFE is more preferable.
  • other polymers, additives such as a lubricant and the like may be appropriately blended in the forming material of the hollow fiber membrane 1.
  • the lower limit of the ratio of the average pitch to the average outer diameter of the hollow fiber membrane 1 is preferably 1.
  • the upper limit of the ratio of the average pitch to the average outer diameter of the hollow fiber membrane 1 is preferably 3/2, more preferably 7/5.
  • the ratio of the average pitch to the average outer diameter of the hollow fiber membrane 1 does not reach the above lower limit, the hollow fiber membrane 1 is disposed in a radially crushed state, so that the production of the membrane element 2 is difficult May be
  • the ratio of the average pitch to the average outer diameter of the hollow fiber membrane 1 exceeds the above-mentioned upper limit, the density of the hollow fiber membrane 1 becomes small, and there is a possibility that sufficient filtration efficiency can not be obtained.
  • the lower limit of the average outer diameter of the hollow fiber membrane 1 is preferably 1 mm, more preferably 1.5 mm, and still more preferably 2 mm.
  • the upper limit of the average outer diameter of the hollow fiber membrane 1 is preferably 6 mm, more preferably 5 mm, and still more preferably 4 mm.
  • the mechanical strength of the hollow fiber membrane 1 may be insufficient.
  • the average outer diameter of the hollow fiber membrane 1 exceeds the above upper limit, the flexibility of the hollow fiber membrane 1 is insufficient, and the vibration and oscillation of the hollow fiber membrane 1 due to the contact of air bubbles become insufficient.
  • the lower limit of the average inner diameter of the hollow fiber membrane 1 is preferably 0.3 mm, more preferably 0.5 mm, and still more preferably 0.9 mm.
  • the upper limit of the average inner diameter of the hollow fiber membrane 1 is preferably 4 mm, more preferably 3 mm.
  • the pressure loss when discharging the treated liquid in the hollow fiber membrane 1 may be large.
  • the average inner diameter of the hollow fiber membrane 1 exceeds the above upper limit, the thickness of the hollow fiber membrane 1 may be reduced, and the mechanical strength and the permeation prevention effect of impurities may be insufficient.
  • the lower limit of the ratio of the average inner diameter to the average outer diameter of the hollow fiber membrane 1 is preferably 3/10, more preferably 2/5.
  • the upper limit of the ratio of the average inner diameter to the average outer diameter of the hollow fiber membrane 1 is preferably 4/5, more preferably 3/5. If the ratio of the average inner diameter to the average outer diameter of the hollow fiber membrane 1 does not reach the above lower limit, the thickness of the hollow fiber membrane 1 may be increased more than necessary and the liquid permeability of the hollow fiber membrane 1 may be reduced. On the other hand, when the ratio of the average inner diameter to the average outer diameter of the hollow fiber membrane 1 exceeds the above upper limit, the thickness of the hollow fiber membrane 1 may be reduced and the mechanical strength and the permeation inhibition effect of impurities may be insufficient. .
  • the first holding member 4 airtightly holds the end of one side of the plurality of hollow fiber membranes 1 and opens the end of one side of the plurality of hollow fiber membranes 1 and the end of one side of the casing 3 By airtightly engaging the inner wall in the vicinity of the portion, the space in the casing 3 is divided, and a small space communicating with the lumens of the plurality of hollow fiber membranes 1 is formed on one side.
  • the first holding member 4 defines an engagement shape to be engaged with the casing 3 and a support having a plurality of through holes for positioning one end of the plurality of hollow fiber membranes 1, and the support It can be set as the composition which has a filler with which a crevice with a plurality of hollow fiber membranes 1 is filled.
  • the resin composition which has a PTFE, a polyvinyl chloride, polyethylene, an ABS resin etc. as a main component is mentioned, for example.
  • any material may be used as long as it has high adhesion to the hollow fiber membrane 1 and can be cured in the support.
  • PTFE As the main component of the hollow fiber membrane 1
  • epoxy resin and polyurethane having high adhesiveness to PTFE and capable of reliably preventing the hollow fiber membrane 1 from falling off are preferable as the main component of the filler.
  • the second holding member 5 holds the end portions of the plurality of hollow fiber membranes 1 on the other side, and holds the plurality of hollow fiber membranes 1 in one direction without being entangled.
  • the second holding member 5 holds the other end of the plurality of hollow fiber membranes 1 so as not to open the internal space of the hollow fiber membrane 1. Further, the second holding member 5 does not separate the internal space on both sides in the aligning direction of the hollow fiber membranes 1 of the casing 3 so that a gap is formed between the second holding member 5 and the inner wall of the casing 3 or the treatment liquid can pass. Configured to have an opening.
  • the second holding member 5 is filled in the gap between the support and the hollow fiber membranes 1 and the support having a plurality of non-through holes for positioning the other end of the hollow fiber membranes 1. It can be set as the composition which has a filler.
  • the material of the support of the second holding member 5 and the material of the filler may be the same as the material of the support of the first holding member 4 and the filler.
  • the connecting member 6 connects the first holding member 4 and the second holding member 5 which are vertically opposed to each other, and holds the second holding member 5 at a predetermined position in the casing 3. Further, the connecting member 6 integrates the first holding member 4 and the second holding member 5 and the plurality of hollow fiber membranes 1 disposed therebetween to facilitate disassembly and assembly of the filtration module.
  • connection member 6 a support rod made of resin or metal can be used as the connection member 6.
  • the casing 3 is provided with a cylindrical main body 11 and a first sleeve 12 mounted at one end of the main body 11 and provided with an engaging structure in which the concentrate nozzle 9 and the first holding member 4 are engaged.
  • a first cap 13 sealing the end of the sleeve 12 opposite to the main body 11 and provided with the filtrate nozzle 8; and a second sleeve 14 attached to the other end of the main body 11; An end of the second sleeve 14 opposite to the main body 11 is sealed, and a second cap 15 provided with the liquid processing nozzle 7 can be provided.
  • the main body 11 With such a configuration, for example, a commercially available pipe or the like can be used as the main body 11, so the length of the hollow fiber membrane 1 to be used, that is, the filtration area can be selected relatively freely.
  • the engagement structure with the nozzle 9 and the first holding member 4 can be formed accurately and inexpensively.
  • the filtration module can be disassembled and cleaned.
  • a mounting and demounting structure of the first cap 13 and the second cap 15 for example, a screw, a flange, a ferrule, or any other structure used as a pipe joint can be adopted.
  • each component of the casing 3 examples include metals such as iron, stainless steel, aluminum and the like, for example, resin compositions mainly composed of PTFE, polyvinyl chloride, polyethylene, ABS resin, etc. Different materials may be adopted for each component.
  • the liquid nozzle 7, the filtrate nozzle 8 and the concentrate nozzle 9 have a joint structure in which piping can be connected to the outer end.
  • a joint structure a flange, a ferrule or the like may be adopted in addition to the external screw as shown.
  • the retraction prevention member 10 is shown in detail in FIG.
  • the pull-in blocking member 10 is engaged with the inner cylindrical portion 16 disposed inside the concentrate nozzle 9, the sealing portion 17 sealing the tip of the inner cylindrical portion 16, and the outer end of the concentrate nozzle 9. And a locking portion 18 to be stopped.
  • the pull-in blocking member 10 is connected to the joint structure of the concentrate nozzle 9 and fixed in an inserted state in the concentrate nozzle 9 by a mounting member 19 that presses the locking portion 18 against the outer end of the concentrate nozzle 9. Ru.
  • the inner cylindrical portion 16 is preferably formed in a tubular shape having an outer diameter having a minimum degree of clearance with the inner wall surface of the concentrate nozzle 9 so as to be able to be inserted into and removed from the concentrate nozzle 9. Further, the inner cylindrical portion 16 may be slightly reduced in diameter toward the sealing portion 17 in order to be able to be integrally formed with the sealing portion 17 and the locking portion 18 by injection molding.
  • the inner cylindrical portion 16 may be connected to the end of the pipe for discharging the concentrate, and is fixed in the concentrate nozzle 9 by the mounting member 19 connected to the end of the pipe for discharging the concentrate. May be
  • the average thickness of the inner cylindrical portion 16 may be any thickness as long as sufficient strength can be ensured, and may be, for example, 2 mm or more and 10 mm or less, although it depends on the material.
  • the sealing portion 17 is formed in a dome shape and has a plurality of openings 20 through which the concentrate passes. Further, the sealing portion 17 protrudes into the casing 3.
  • "dome shape” means the whole shape which does not have the corner
  • the sealing portion 17 By forming the sealing portion 17 in a dome shape, it becomes difficult to damage the hollow fiber membrane 1 even when contacting the hollow fiber membrane 1, and the total area of the openings 20 is increased to ensure a sufficient flow path area can do.
  • the sealing portion 17 preferably has a region where the opening 20 does not exist at the tip in the protruding direction.
  • damage to the hollow fiber membrane 1 can be more reliably prevented by having a region where the opening 20 does not exist at the tip in the projecting direction that is easily in contact with the hollow fiber membrane 1.
  • the tip of the sealing portion 17 in the protruding direction is a plane substantially parallel to the extending direction of the hollow fiber membrane 1, the hollow fiber membrane 1 is easily sucked by the flow of the concentrate, and the hollow fiber membrane 1 is sucked. Contaminants are easily attached to the opening 20 having a smaller area, and by not forming the opening 20 in this region, attachment of contaminants can be suppressed.
  • the thickness of the sealing portion 17 may be a thickness that can ensure sufficient strength, but may be slightly smaller than the inner cylinder portion 16 in order to increase the flow passage area.
  • the average thickness of the sealing portion 17 may be, for example, 2 mm or more and 10 mm or less, although it depends on the material.
  • the opening 20 of the sealing portion 17 is preferably formed in a long hole shape extending toward the tip of the sealing portion 17.
  • the hollow fiber membrane 1 is in contact with the opening 20 by the opening 20 being an elongated hole extending toward the tip of the sealing portion 17, the direction in which the opening 20 extends and the hollow fiber membrane Because the direction in which 1 extends is different from the direction in which it extends, the hollow fiber membrane 1 is less likely to close the opening.
  • a plurality of openings 20 be formed in the sealing portion 17 in the longitudinal direction toward the tip of the sealing portion 17. If a long long hole extending from the vicinity of the inner cylindrical portion 16 of the sealing portion 17 to the vicinity of the tip of the sealing portion 17 is formed, the strength of the sealing portion 17 may be insufficient. By dividing and forming into two, it becomes easy to secure the strength of the sealing portion 17. For this reason, by forming the plurality of openings 20 side by side in the longitudinal direction, the aperture ratio in the circumferential direction of the sealing portion 17 can be increased, so that the total area of the plurality of openings 20 can be increased.
  • the opening 20 is preferably chamfered at least on the outer peripheral side of the sealing portion 17 so as not to be damaged even when the hollow fiber membrane 1 contacts.
  • the lower limit of the minor diameter (the width of the portion where the width of the elongated hole is constant) of the opening 20 is preferably 3 mm, more preferably 5 mm.
  • an upper limit of the breadth of opening 20 12 mm is preferred and 10 mm is more preferred. If the minor axis of the opening 20 does not reach the above lower limit, the opening 20 may be easily clogged by contaminants. On the other hand, when the minor axis of the opening 20 exceeds the above upper limit, the hollow fiber membrane is easily drawn into the opening, and the opening may be blocked.
  • a major axis (length of a long hole) of opening 20 10 mm is preferred and 15 mm is more preferred.
  • a maximum of a major axis of opening 20 30 mm is preferred and 25 mm is more preferred. If the major diameter of the opening 20 does not reach the above lower limit, the area ratio of the opening 20 in the sealing portion 17 can not be increased, and the flow passage area may not be sufficiently increased. On the other hand, when the major diameter of the opening 20 exceeds the above-mentioned upper limit, there is a possibility that it will become difficult to secure the intensity of the sealing part 17.
  • the total opening area of the plurality of openings 20 As a lower limit of the total opening area of the plurality of openings 20, 110% of the cross-sectional area in the inner cylinder part 16 is preferable, and 130% is more preferable.
  • an upper limit of the total opening area of the plurality of openings 20 180% of the cross-sectional area in the inner cylinder part 16 is preferable, and 160% is more preferable. If the total opening area of the plurality of openings 20 does not reach the above lower limit, the openings 20 may be easily clogged by foreign matter. On the other hand, when the total opening area of the plurality of openings 20 exceeds the above upper limit, the strength of the sealing portion 17 may be insufficient, or the sealing portion 17 may be too large and easily interfere with the hollow fiber membrane 1 May be
  • the locking portion 18 protrudes outward from the inner cylindrical portion 16 and abuts on the outer end of the concentrate nozzle 9 to thereby determine the position of the pull-in blocking member 10 with respect to the casing 3.
  • the pull-in blocking member 10 can be fixed at an appropriate position, and pull-in of the hollow fiber membrane 1 to the concentrate nozzle 9 can be more reliably prevented.
  • the locking portion 18 may be protruded only on a part of the outer periphery of the inner cylinder portion 16, but in order to seal airtight between the concentrate nozzle 9 and the like, the entire periphery of the inner cylinder portion 16 is sealed. It is preferable to be provided in a ring shape.
  • the locking portion 18 may have a holding structure that holds a sealing member such as an O-ring 21 that seals between the locking portion 18 and the outer end of the concentrate nozzle 9.
  • the mounting member 19 has a joint structure corresponding to the joint structure of the liquid nozzle 7 and holds the locking portion 18 in contact with the outer end of the concentrate nozzle 9.
  • the configuration of the mounting member 19 can be a flange, a ferrule or the like in addition to a union nut as shown.
  • a part or all of the attachment member 19 may be integrally formed with the pull-in preventing member 10.
  • the configuration of the membrane element having a plurality of hollow fiber membranes is arbitrary. Also, a plurality of hollow fiber membranes may be permanently disposed in the casing without forming a detachable membrane element.
  • the pull-in blocking member of the filtration module may be any one that can allow the concentrate to flow out to the concentrate nozzle and prevent the hollow fiber membrane from entering into the concentrate nozzle, and the inner cylinder part and the seal It is not restricted to what has a part.
  • locking part in a drawing-in prevention member is also arbitrary structures.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

A filtration module according to one aspect of the present disclosure is provided with: a plurality of hollow fiber membranes that are pulled into alignment in one direction; a cylindrical casing that stores the hollow fiber membranes and has, on a side surface thereof, a liquid concentrate nozzle for discharging a liquid concentrate; and an intake blocking member that is inserted into the concentrated liquid nozzle and that prevents the hollow fiber membranes from entering the liquid concentrate nozzle.

Description

濾過モジュールFiltration module
 本開示は、濾過モジュールに関する。本出願は、2018年1月24日出願の日本出願第2018‐009547号に基づく優先権を主張し、前記日本出願に記載された全ての記載内容を援用するものである。 The present disclosure relates to a filtration module. This application claims the priority based on Japanese Patent Application No. 2018-009547 filed on Jan. 24, 2018, and incorporates all the contents described in the Japanese application.
 様々な被処理液を濾過するために、一方向に引き揃えられる複数本の中空糸膜を筒状のケーシングに収容し、ケーシングの一方の端部に設けられる被処理液ノズルから被処理液をケーシング内に供給し、ケーシングの他方の端部に設けられる濾過液ノズルから中空糸膜の内部空間に透過した濾過液を排出し、ケーシングの他方の端部近傍の側面に設けられる濃縮液ノズルから被処理液を濃縮した濃縮液を排出するいわゆるクロスフロー式の濾過モジュールが使用されている。 In order to filter various liquids to be treated, a plurality of hollow fiber membranes aligned in one direction are accommodated in a cylindrical casing, and the liquid to be treated is treated from a liquid nozzle provided at one end of the casing. The filtrate is supplied into the casing and discharged from the filtrate nozzle provided at the other end of the casing into the internal space of the hollow fiber membrane, and the concentrate nozzle provided on the side near the other end of the casing A so-called cross flow type filtration module is used which discharges the concentrate obtained by concentrating the liquid to be treated.
 このような濾過モジュールでは、ケーシングの濃縮液ノズルが配設される領域の内側に、多数の整流孔を形成した整流筒を中空糸膜の束を取り囲むように配置して中空糸膜が濃縮液ノズルに引き込まれないようにしている(国際公開2008/035593号公報参照)。 In such a filtration module, a flow straightening cylinder having a large number of flow straightening holes is disposed so as to surround a bundle of hollow fiber membranes inside a region where the concentrated liquid nozzle of the casing is disposed, and the hollow fiber membranes are concentrated liquid It is made not to be drawn into the nozzle (see WO 2008/035593).
国際公開2008/035593号International Publication 2008/035559
 本開示の一態様に係る濾過モジュールは、一方向に引き揃えられた複数本の中空糸膜と、上記複数本の中空糸膜を格納し、濃縮液を排出する濃縮液ノズルを側面に有する筒状のケーシングと、上記濃縮液ノズルに挿入され、上記中空糸膜が上記濃縮液ノズル内に進入することを防止する引込阻止部材とを備える。 A filtration module according to an aspect of the present disclosure is a cylinder having a plurality of hollow fiber membranes aligned in one direction, a plurality of hollow fiber membranes, and a concentrate nozzle on a side surface for discharging a concentrate. And a pull-in blocking member inserted into the concentrate nozzle to prevent the hollow fiber membrane from entering the concentrate nozzle.
図1は、本開示の一実施形態の濾過モジュールを示す模式的断面図である。FIG. 1 is a schematic cross-sectional view showing a filtration module according to an embodiment of the present disclosure. 図2は、図1の濾過モジュールの引込阻止部材の模式的拡大斜視図である。FIG. 2 is a schematic enlarged perspective view of a retraction preventing member of the filtration module of FIG.
[開示が解決しようとする課題] [Issues that disclosure is trying to solve]
 特許文献1に開示されるような整流筒を設けた濾過モジュールでは、被処理液が繊維状の夾雑物を含む場合、夾雑物が絡みついて整流筒の整流孔が閉塞するおそれがある。一度、夾雑物により整流孔が閉塞すると、濾過モジュールを分解することなく夾雑物を取り除くことは容易ではない。 In the filtration module provided with the flow straightening cylinder as disclosed in Patent Document 1, when the liquid to be treated contains fibrous contaminants, the foreign matter may be entangled and the flow straightening holes of the flow straightening cylinder may be blocked. Once the flow straighteners are blocked by the contaminants, it is not easy to remove the contaminants without disassembling the filtration module.
 本開示は、上述のような事情に基づいてなされたものであり、夾雑物によって流路が閉塞しても、容易に夾雑物を取り除くことができる濾過モジュールを提供することを課題とする。
[本開示の効果]
The present disclosure has been made based on the circumstances as described above, and it is an object of the present disclosure to provide a filtration module capable of easily removing contaminants even if the channel is blocked by the contaminants.
[Effect of the present disclosure]
 本開示の一態様に係る濾過モジュールは、夾雑物によって流路が閉塞しても、容易に夾雑物を取り除くことができる。
[本開示の実施形態の説明]
 本開示の一態様に係る濾過モジュールは、一方向に引き揃えられた複数本の中空糸膜と、上記複数本の中空糸膜を格納し、濃縮液を排出する濃縮液ノズルを側面に有する筒状のケーシングと、上記濃縮液ノズルに挿入され、上記中空糸膜が上記濃縮液ノズル内に進入することを防止する引込阻止部材とを備える。
The filtration module according to an aspect of the present disclosure can easily remove the contaminants even if the channel is blocked by the contaminants.
[Description of the embodiment of the present disclosure]
A filtration module according to an aspect of the present disclosure is a cylinder having a plurality of hollow fiber membranes aligned in one direction, a plurality of hollow fiber membranes, and a concentrate nozzle on a side surface for discharging a concentrate. And a pull-in blocking member inserted into the concentrate nozzle to prevent the hollow fiber membrane from entering the concentrate nozzle.
 当該濾過モジュールは、上記中空糸膜が上記濃縮液ノズル内に進入することを防止する上記引込阻止部材が上記濃縮液ノズルに挿入されるよう構成されていることによって、被処理液中の夾雑物により上記引込阻止部材が閉塞した場合には、この引込阻止部材を上記濃縮液ノズルから引き抜いてクリーニングすることができるので、容易に夾雑物を取り除いて濾過能力を回復することができる。 The filtration module is configured such that the pull-in preventing member for preventing the hollow fiber membrane from entering into the concentrate nozzle is inserted into the concentrate nozzle, whereby contaminants in the liquid to be treated Thus, when the pull-in blocking member is closed, the pull-in blocking member can be pulled out of the concentrate nozzle for cleaning, so that the contaminants can be easily removed and the filtering ability can be recovered.
 上記引込阻止部材が、上記濃縮液ノズルの内側に配置される内筒部と、この内筒部の先端を封止し、上記濃縮液を通過させる複数の開口を有するドーム状の封止部とを有し、上記封止部が上記ケーシング内に突出し、上記複数の開口が上記封止部の先端に向かって延びる長穴状の開口であってもよい。この構成によれば、上記引込阻止部材が上記濃縮液ノズルの内側に配置される内筒部を有することによって、封止部をケーシングの内側に配置することができ、濃縮液の流れによる中空糸膜の濃縮液ノズル内への引き込みをより確実に防止することができる。また、上記引込阻止部材が上記内筒部の先端を封止するドーム状に形成されることによって、上記濃縮液を通過させる複数の開口の合計面積を大きくして十分な流路面積を確保することができる。さらに、上記複数の開口が上記封止部の先端に向かって延びる長穴状に形成されることによって、前記開口に中空糸膜が接触することがあっても、開口が延びる方向と中空糸膜が延びる方向とが異なる方向となるため、中空糸膜が開口内に引き込まれにくく、開口を閉塞しにくい。 The pull-in blocking member seals an inner cylindrical portion disposed inside the concentrate nozzle, and a dome-shaped sealed portion having a plurality of openings for sealing the tip of the inner cylindrical portion and allowing the concentrate to pass therethrough. The sealing portion may protrude into the casing, and the plurality of openings may be elongated openings extending toward the tip of the sealing portion. According to this configuration, the sealing portion can be disposed inside the casing by having the inner cylindrical portion disposed inside the concentrate nozzle, so that the hollow fiber by the flow of the concentrate can be obtained. It is possible to more reliably prevent the membrane from being drawn into the concentrate nozzle. Further, the draw-in blocking member is formed in a dome shape that seals the tip of the inner cylindrical portion, thereby increasing the total area of the plurality of openings through which the concentrate passes and securing a sufficient flow path area. be able to. Furthermore, by forming the plurality of openings in the shape of a long hole extending toward the tip of the sealing portion, even if the hollow fiber membrane may come in contact with the openings, the direction in which the openings extend and the hollow fiber membrane Since the direction of extension of the hollow fiber membrane is different from the direction in which the hollow fiber membrane extends, the hollow fiber membrane is less likely to be drawn into the opening, and the opening is not easily closed.
 上記長穴状の開口が上記封止部の先端に向かって長手方向に並んで複数形成されてもよい。このように、上記長穴状の開口が上記封止部の先端に向かって長手方向に並んで複数形成されることによって、上記複数の開口の合計面積を大きくすることができる。 A plurality of the elongated hole-shaped openings may be formed along the longitudinal direction toward the tip of the sealing portion. Thus, the total area of the plurality of openings can be increased by forming a plurality of the elongated hole-like openings in the longitudinal direction toward the tip of the sealing portion.
 上記封止部が、その突出方向先端に、上記開口が存在しない領域を有してもよい。このように、上記封止部が、上記中空糸膜を引き込んで閉塞し易い突出方向先端に、上記開口が存在しない領域を有することによって、上記中空糸膜を引き込むことをより確実に防止すると共に上記封止部の強度を確保することがより簡単となる。 The sealing portion may have a region where the opening does not exist at the tip in the protruding direction. As described above, the sealing portion has a region where the opening does not exist at the tip in the projecting direction which tends to draw in and close the hollow fiber membrane, thereby more reliably preventing the hollow fiber membrane from being drawn in. It becomes easier to secure the strength of the sealing portion.
 上記引込阻止部材が、上記濃縮液ノズルの外側端部に係止される係止部を有してもよい。このように、上記引込阻止部材が係止部を有し、この係止部が上記濃縮液ノズルの外側端部に係止されることによって、上記封止部を容易且つ確実に適切な位置に配置することができるので、中空糸膜の引き込みをより確実に防止できる。 The pull-in blocking member may have a locking portion that is locked to the outer end of the concentrate nozzle. In this manner, the pull-in preventing member has a locking portion, and the locking portion is locked to the outer end of the concentrate nozzle, whereby the sealing portion is easily and reliably positioned at an appropriate position. Since the arrangement can be made, the pull-in of the hollow fiber membrane can be prevented more reliably.
[本開示の実施形態の詳細]
 以下、本開示に係る濾過モジュールの各実施形態について図面を参照しつつ詳説する。
Details of Embodiments of the Present Disclosure
Hereinafter, embodiments of the filtration module according to the present disclosure will be described in detail with reference to the drawings.
 図1に、本開示の一実施形態に係る濾過モジュールを示す。当該濾過モジュールは、一方向に引き揃えられた複数本の中空糸膜1を有する膜エレメント2と、この複数本の中空糸膜1を有する膜エレメント2を格納する筒状のケーシング3とを備える。 FIG. 1 shows a filtration module according to an embodiment of the present disclosure. The filtration module includes a membrane element 2 having a plurality of hollow fiber membranes 1 aligned in one direction, and a cylindrical casing 3 for storing the membrane element 2 having the plurality of hollow fiber membranes 1. .
 膜エレメント2は、複数本の中空糸膜1の一方の端部を保持する第1保持部材4と、複数本の中空糸膜1の他方の端部を保持する第2保持部材5とを有する。また、膜エレメント2は、第1保持部材4及び第2保持部材5間を接続し、両者の相対位置を定める連結部材6を有する。 The membrane element 2 has a first holding member 4 holding one end of the plurality of hollow fiber membranes 1 and a second holding member 5 holding the other end of the plurality of hollow fiber membranes 1 . In addition, the membrane element 2 has a connecting member 6 that connects the first holding member 4 and the second holding member 5 and determines the relative position of the two.
 ケーシング3は、一方の端部の端面に被処理液が供給される被処理液ノズル7を有し、他方の端部の端面に複数本の中空糸膜1を透過した濾過液を排出する濾過液ノズル8を有し、他方の端部近傍の側面に被処理液から濾過液を差し引いた濃縮液を排出する濃縮液ノズル9を有する。 The casing 3 has a treatment liquid nozzle 7 to which the treatment liquid is supplied on the end face of one end, and a filtration for discharging the filtrate which has permeated the plural hollow fiber membranes 1 on the end face of the other end. A liquid nozzle 8 is provided, and a concentrated liquid nozzle 9 for discharging a concentrated liquid obtained by subtracting the filtrate from the liquid to be treated is provided on the side near the other end.
 当該濾過モジュールは、濃縮液ノズル9に外側から挿入され、中空糸膜1が上記濃縮液ノズル9内に進入することを防止する引込阻止部材10をさらに備える。 The filtration module further includes a pull-in blocking member 10 which is externally inserted into the concentrate nozzle 9 and prevents the hollow fiber membrane 1 from entering the concentrate nozzle 9.
 当該濾過モジュールは、濃縮水が中空糸膜1を濃縮液ノズル9内に引き込むことを防止する引込阻止部材10が濃縮液ノズル9に外側から挿入されるので、引込阻止部材10の流路が被処理液(濃縮液)中の夾雑物によって閉塞した場合に、引込阻止部材10を濃縮液ノズル9から引き抜いて夾雑物を取り除くことができる。このため、当該濾過モジュールは、濃縮液の流路が閉塞しても、全体を分解することなく、容易に濾過能力を回復することができる。 The filtration module prevents the concentrated water from drawing the hollow fiber membrane 1 into the concentrate nozzle 9, and the pull-in prevention member 10 is inserted into the concentrate nozzle 9 from the outside. In the case of blocking by contaminants in the treatment liquid (concentrate), the drawing-in blocking member 10 can be pulled out from the concentrate nozzle 9 to remove contaminants. For this reason, even if the flow path of the concentrate is blocked, the filtration module can easily restore the filtration capacity without decomposing the whole.
 以下、当該濾過モジュールの各構成要素について詳述する。 Hereinafter, each component of the said filtration module is explained in full detail.
<濾過エレメント>
 膜エレメント2は、複数の中空糸膜1を第1保持部材4、第2保持部材5及び連結部材6によって一体化し、ケーシング内で複数の中空糸膜1を一方向に引き揃えた状態で保持することを容易にする。
<Filtration element>
The membrane element 2 integrates the plurality of hollow fiber membranes 1 by the first holding member 4, the second holding member 5 and the connecting member 6, and holds the plurality of hollow fiber membranes 1 in one direction in the casing. Make it easy to do.
(中空糸膜)
 中空糸膜1は、被処理液中の溶媒を透過させる一方、被処理液に含まれる一定粒径以上の不純物の透過を阻止する多孔性の膜を管状に成形したものであり、例えば熱可塑性樹脂を主成分とするものを用いることができる。ここで、「主成分」とは、最も含有量の多い成分を意味する。
(Hollow fiber membrane)
The hollow fiber membrane 1 is formed by forming a porous membrane into a tubular shape, which allows the solvent in the liquid to be treated to permeate while blocking the permeation of impurities contained in the liquid to be treated to a certain particle size or more. What has resin as a main component can be used. Here, "main component" means a component with the highest content.
 上記熱可塑性樹脂としては、例えばポリエチレン、ポリプロピレン、ポリフッ化ビニリデン、エチレン-ビニルアルコール共重合体、ポリアミド、ポリイミド、ポリエーテルイミド、ポリスチレン、ポリサルホン、ポリビニルアルコール、ポリフェニレンエーテル、ポリフェニレンサルファイド、酢酸セルロース、ポリアクリロニトリル、ポリテトラフルオロエチレン(PTFE)等が挙げられる。これらの中でも機械的強度、耐薬品性、耐熱性、耐候性、不燃性等に優れ、多孔質性であるPTFEが好ましく、1軸又は2軸延伸したPTFEがより好ましい。なお、中空糸膜1の形成材料には、他のポリマー、潤滑剤などの添加剤等が適宜配合されていてもよい。 Examples of the thermoplastic resin include polyethylene, polypropylene, polyvinylidene fluoride, ethylene-vinyl alcohol copolymer, polyamide, polyimide, polyetherimide, polystyrene, polysulfone, polyvinyl alcohol, polyphenylene ether, polyphenylene sulfide, cellulose acetate, polyacrylonitrile And polytetrafluoroethylene (PTFE). Among these, PTFE which is excellent in mechanical strength, chemical resistance, heat resistance, weather resistance, nonflammability and the like and is porous is preferable, and uniaxially or biaxially stretched PTFE is more preferable. In addition, other polymers, additives such as a lubricant and the like may be appropriately blended in the forming material of the hollow fiber membrane 1.
 中空糸膜1の平均外径に対する平均ピッチの比の下限としては、1が好ましい。一方、中空糸膜1の平均外径に対する平均ピッチの比の上限としては、3/2が好ましく、7/5がより好ましい。中空糸膜1の平均外径に対する平均ピッチの比が上記下限に満たない場合、中空糸膜1が径方向に押し潰された状態で配置されることになるので膜エレメント2の製造が困難となるおそれがある。一方、中空糸膜1の平均外径に対する平均ピッチの比が上記上限を超える場合、中空糸膜1の密度が小さくなることによって十分な濾過効率が得られないおそれがある。 The lower limit of the ratio of the average pitch to the average outer diameter of the hollow fiber membrane 1 is preferably 1. On the other hand, the upper limit of the ratio of the average pitch to the average outer diameter of the hollow fiber membrane 1 is preferably 3/2, more preferably 7/5. When the ratio of the average pitch to the average outer diameter of the hollow fiber membrane 1 does not reach the above lower limit, the hollow fiber membrane 1 is disposed in a radially crushed state, so that the production of the membrane element 2 is difficult May be On the other hand, when the ratio of the average pitch to the average outer diameter of the hollow fiber membrane 1 exceeds the above-mentioned upper limit, the density of the hollow fiber membrane 1 becomes small, and there is a possibility that sufficient filtration efficiency can not be obtained.
 中空糸膜1の平均外径の下限としては、1mmが好ましく、1.5mmがより好ましく、2mmがさらに好ましい。一方、中空糸膜1の平均外径の上限としては、6mmが好ましく、5mmがより好ましく、4mmがさらに好ましい。中空糸膜1の平均外径が上記下限に満たない場合、中空糸膜1の機械的強度が不十分となるおそれがある。一方、中空糸膜1の平均外径が上記上限を超える場合、中空糸膜1の可撓性が不足することにより気泡の接触による中空糸膜1の振動及び搖動が不十分となり、中空糸膜1間の隙間を拡げて気泡を中空糸膜1の束の中心部まで案内することができないおそれや、中空糸膜1の断面積に対する表面積の比が小さくなって濾過効率が低下するおそれがある。 The lower limit of the average outer diameter of the hollow fiber membrane 1 is preferably 1 mm, more preferably 1.5 mm, and still more preferably 2 mm. On the other hand, the upper limit of the average outer diameter of the hollow fiber membrane 1 is preferably 6 mm, more preferably 5 mm, and still more preferably 4 mm. When the average outer diameter of the hollow fiber membrane 1 does not reach the above lower limit, the mechanical strength of the hollow fiber membrane 1 may be insufficient. On the other hand, when the average outer diameter of the hollow fiber membrane 1 exceeds the above upper limit, the flexibility of the hollow fiber membrane 1 is insufficient, and the vibration and oscillation of the hollow fiber membrane 1 due to the contact of air bubbles become insufficient. There is a possibility that the air gap can not be guided to the central portion of the bundle of hollow fiber membranes 1 by expanding the gap between 1 and that the ratio of the surface area to the cross sectional area of hollow fiber membranes 1 becomes small and the filtration efficiency decreases. .
 中空糸膜1の平均内径の下限としては、0.3mmが好ましく、0.5mmがより好ましく、0.9mmがさらに好ましい。一方、中空糸膜1の平均内径の上限としては、4mmが好ましく、3mmがより好ましい。中空糸膜1の平均内径が上記下限に満たない場合、中空糸膜1内の処理済液を排出するときの圧損が大きくなるおそれがある。一方、中空糸膜1の平均内径が上記上限を超える場合、中空糸膜1の厚さが小さくなって機械的強度及び不純物の透過阻止効果が不十分となるおそれがある。 The lower limit of the average inner diameter of the hollow fiber membrane 1 is preferably 0.3 mm, more preferably 0.5 mm, and still more preferably 0.9 mm. On the other hand, the upper limit of the average inner diameter of the hollow fiber membrane 1 is preferably 4 mm, more preferably 3 mm. When the average inner diameter of the hollow fiber membrane 1 does not reach the above lower limit, the pressure loss when discharging the treated liquid in the hollow fiber membrane 1 may be large. On the other hand, when the average inner diameter of the hollow fiber membrane 1 exceeds the above upper limit, the thickness of the hollow fiber membrane 1 may be reduced, and the mechanical strength and the permeation prevention effect of impurities may be insufficient.
 中空糸膜1の平均外径に対する平均内径の比の下限としては、3/10が好ましく、2/5がより好ましい。一方、中空糸膜1の平均外径に対する平均内径の比の上限としては、4/5が好ましく、3/5がより好ましい。中空糸膜1の平均外径に対する平均内径の比が上記下限に満たない場合、中空糸膜1の厚さが必要以上に大きくなって中空糸膜1の透液性が低下するおそれがある。一方、中空糸膜1の平均外径に対する平均内径の比が上記上限を超える場合、中空糸膜1の厚さが小さくなって機械的強度及び不純物の透過阻止効果が不十分となるおそれがある。 The lower limit of the ratio of the average inner diameter to the average outer diameter of the hollow fiber membrane 1 is preferably 3/10, more preferably 2/5. On the other hand, the upper limit of the ratio of the average inner diameter to the average outer diameter of the hollow fiber membrane 1 is preferably 4/5, more preferably 3/5. If the ratio of the average inner diameter to the average outer diameter of the hollow fiber membrane 1 does not reach the above lower limit, the thickness of the hollow fiber membrane 1 may be increased more than necessary and the liquid permeability of the hollow fiber membrane 1 may be reduced. On the other hand, when the ratio of the average inner diameter to the average outer diameter of the hollow fiber membrane 1 exceeds the above upper limit, the thickness of the hollow fiber membrane 1 may be reduced and the mechanical strength and the permeation inhibition effect of impurities may be insufficient. .
(第1保持部材)
 第1保持部材4は、複数の中空糸膜1の一方側の端部を気密に保持し、これら複数の中空糸膜1の一方側の端部を開放すると共に、ケーシング3の一方側の端部近傍の内壁に気密に係合することによりケーシング3内の空間を区分し、一方側に複数の中空糸膜1の内腔に連通する小空間を形成する。
(First holding member)
The first holding member 4 airtightly holds the end of one side of the plurality of hollow fiber membranes 1 and opens the end of one side of the plurality of hollow fiber membranes 1 and the end of one side of the casing 3 By airtightly engaging the inner wall in the vicinity of the portion, the space in the casing 3 is divided, and a small space communicating with the lumens of the plurality of hollow fiber membranes 1 is formed on one side.
 第1保持部材4は、ケーシング3に係合する係合形状を画定すると共に、複数の中空糸膜1の一方側の端部を位置決めする複数の貫通穴を有する支持体と、この支持体と複数の中空糸膜1との隙間に充填される充填材とを有する構成とすることができる。 The first holding member 4 defines an engagement shape to be engaged with the casing 3 and a support having a plurality of through holes for positioning one end of the plurality of hollow fiber membranes 1, and the support It can be set as the composition which has a filler with which a crevice with a plurality of hollow fiber membranes 1 is filled.
 上記支持体の材質としては、例えばPTFE、ポリ塩化ビニル、ポリエチレン、ABS樹脂等を主成分とする樹脂組成物が挙げられる。 As a material of the said support body, the resin composition which has a PTFE, a polyvinyl chloride, polyethylene, an ABS resin etc. as a main component is mentioned, for example.
 上記充填材としては、中空糸膜1に対して高い接着性を有し、支持体内で硬化できるものであればよい。特に中空糸膜1の主成分としてPTFEを用いる場合、充填材の主成分としては、PTFEに対して高い接着性を有し、中空糸膜1の脱落を確実に防止できるエポキシ樹脂及びポリウレタンが好ましい。支持体に充填材を充填することにより、中空糸膜1と支持体との間の空間を気密に封止することができ、濾過された処理済液に濾過されていない被処理液が外部から混入することを防止できる。 As the filler, any material may be used as long as it has high adhesion to the hollow fiber membrane 1 and can be cured in the support. In particular, when using PTFE as the main component of the hollow fiber membrane 1, epoxy resin and polyurethane having high adhesiveness to PTFE and capable of reliably preventing the hollow fiber membrane 1 from falling off are preferable as the main component of the filler. . By filling the support with the filler, the space between the hollow fiber membrane 1 and the support can be airtightly sealed, and the non-filtered liquid to be treated is filtered from the outside from the outside. It can prevent mixing.
(第2保持部材)
 第2保持部材5は、複数の中空糸膜1の他方側の端部を保持することで、複数の中空糸膜1を絡み合うことなく一方向に引き揃えた状態に保持する。この第2保持部材5は、中空糸膜1の内部空間を開放させないように複数の中空糸膜1の他方側の端部を保持する。また、第2保持部材5は、ケーシング3の中空糸膜1の引き揃え方向両側の内部空間を隔離しないために、ケーシング3の内壁との間に隙間を形成するか、被処理液が通過可能な開口を有するよう構成される。
(Second holding member)
The second holding member 5 holds the end portions of the plurality of hollow fiber membranes 1 on the other side, and holds the plurality of hollow fiber membranes 1 in one direction without being entangled. The second holding member 5 holds the other end of the plurality of hollow fiber membranes 1 so as not to open the internal space of the hollow fiber membrane 1. Further, the second holding member 5 does not separate the internal space on both sides in the aligning direction of the hollow fiber membranes 1 of the casing 3 so that a gap is formed between the second holding member 5 and the inner wall of the casing 3 or the treatment liquid can pass. Configured to have an opening.
 第2保持部材5は、複数の中空糸膜1の他方側の端部を位置決めする複数の非貫通穴を有する支持体と、この支持体と複数の中空糸膜1との隙間に充填される充填材とを有する構成とすることができる。 The second holding member 5 is filled in the gap between the support and the hollow fiber membranes 1 and the support having a plurality of non-through holes for positioning the other end of the hollow fiber membranes 1. It can be set as the composition which has a filler.
 第2保持部材5の支持体及び充填材の材質としては、第1保持部材4の支持体及び充填材の材質と同様とすることができる。 The material of the support of the second holding member 5 and the material of the filler may be the same as the material of the support of the first holding member 4 and the filler.
(連結部材)
 連結部材6は、上下に対向する第1保持部材4と第2保持部材5との間を連結して、第2保持部材5をケーシング3内の所定位置に保持する。また、連結部材6は、第1保持部材4及び第2保持部材5並びにこれらの間に配設される複数の中空糸膜1を一体化して、当該濾過モジュールの分解及び組み立てを容易にする。
(Connection member)
The connecting member 6 connects the first holding member 4 and the second holding member 5 which are vertically opposed to each other, and holds the second holding member 5 at a predetermined position in the casing 3. Further, the connecting member 6 integrates the first holding member 4 and the second holding member 5 and the plurality of hollow fiber membranes 1 disposed therebetween to facilitate disassembly and assembly of the filtration module.
 この連結部材6としては、例えば樹脂製、金属製の支持棒等を用いることができる。 For example, a support rod made of resin or metal can be used as the connection member 6.
<ケーシング>
 ケーシング3は、筒状の本体11と、この本体11の一方側の端部に装着され、濃縮液ノズル9及び第1保持部材4が係合する係合構造が設けられた第1スリーブ12と、このスリーブ12の本体11と反対側の端部を封止し、濾過液ノズル8が設けられた第1キャップ13と、本体11の他方側の端部に装着される第2スリーブ14と、この第2スリーブ14の本体11と反対側の端部を封止し、被処理液ノズル7が設けられた第2キャップ15とを有する構成とすることができる。
<Casing>
The casing 3 is provided with a cylindrical main body 11 and a first sleeve 12 mounted at one end of the main body 11 and provided with an engaging structure in which the concentrate nozzle 9 and the first holding member 4 are engaged. A first cap 13 sealing the end of the sleeve 12 opposite to the main body 11 and provided with the filtrate nozzle 8; and a second sleeve 14 attached to the other end of the main body 11; An end of the second sleeve 14 opposite to the main body 11 is sealed, and a second cap 15 provided with the liquid processing nozzle 7 can be provided.
 このような構成とすることによって、本体11として例えば市販のパイプ等を用いることができるので、使用する中空糸膜1の長さつまり濾過面積を比較的自由に選択することができる。特に、本体11と第1スリーブ12と分離して作成することで、ノズル9及び第1保持部材4との係合構造を正確且つ安価に形成することができる。 With such a configuration, for example, a commercially available pipe or the like can be used as the main body 11, so the length of the hollow fiber membrane 1 to be used, that is, the filtration area can be selected relatively freely. In particular, by separately forming the main body 11 and the first sleeve 12, the engagement structure with the nozzle 9 and the first holding member 4 can be formed accurately and inexpensively.
 また、第1キャップ13及び第2キャップ15を第1スリーブ12及び第2スリーブ14に対してそれぞれ着脱可能に構成することにより、当該濾過モジュールを分解洗浄することが可能となる。この第1キャップ13及び第2キャップ15の着脱構造としては、例えばねじ、フランジ、フェルール等、配管の継ぎ手として用いられる任意の構造を採用することができる。 In addition, by configuring the first cap 13 and the second cap 15 to be attachable to and detachable from the first sleeve 12 and the second sleeve 14, respectively, the filtration module can be disassembled and cleaned. As a mounting and demounting structure of the first cap 13 and the second cap 15, for example, a screw, a flange, a ferrule, or any other structure used as a pipe joint can be adopted.
 これらケーシング3の各構成要素の材質としては、例えば鉄、ステンレス鋼、アルミニウム等の金属、例えばPTFE、ポリ塩化ビニル、ポリエチレン、ABS樹脂等を主成分とする樹脂組成物などを挙げることができ、構成要素毎に異なる材質を採用してもよい。 Examples of the material of each component of the casing 3 include metals such as iron, stainless steel, aluminum and the like, for example, resin compositions mainly composed of PTFE, polyvinyl chloride, polyethylene, ABS resin, etc. Different materials may be adopted for each component.
 被処理液ノズル7、濾過液ノズル8及び濃縮液ノズル9は、外側の端部に配管を接続可能な継ぎ手構造を有する。この継ぎ手構造としては、図示するような外ねじの他、フランジ、フェルール等を採用してもよい。 The liquid nozzle 7, the filtrate nozzle 8 and the concentrate nozzle 9 have a joint structure in which piping can be connected to the outer end. As the joint structure, a flange, a ferrule or the like may be adopted in addition to the external screw as shown.
<引込阻止部材>
 図2に、引込阻止部材10を詳しく示す。この引込阻止部材10は、濃縮液ノズル9の内側に配置される内筒部16と、この内筒部16の先端を封止する封止部17と、濃縮液ノズル9の外側端部に係止される係止部18とを有する。
<Retraction blocking member>
The retraction prevention member 10 is shown in detail in FIG. The pull-in blocking member 10 is engaged with the inner cylindrical portion 16 disposed inside the concentrate nozzle 9, the sealing portion 17 sealing the tip of the inner cylindrical portion 16, and the outer end of the concentrate nozzle 9. And a locking portion 18 to be stopped.
 この引込阻止部材10は、濃縮液ノズル9の継ぎ手構造に接続され、係止部18を濃縮液ノズル9の外側端部に押圧する取付部材19によって、濃縮液ノズル9内に挿入状態に固定される。 The pull-in blocking member 10 is connected to the joint structure of the concentrate nozzle 9 and fixed in an inserted state in the concentrate nozzle 9 by a mounting member 19 that presses the locking portion 18 against the outer end of the concentrate nozzle 9. Ru.
(内筒部)
 内筒部16は、濃縮液ノズル9に抜き差し可能となるよう、濃縮液ノズル9の内壁面との間に最低限度のクリアランスを有する外径を有する筒状に形成されることが好ましい。また、内筒部16は、封止部17及び係止部18と一体に射出成型によって形成可能とするために、封止部17に向かって僅かに縮径してもよい。
(Inner cylinder)
The inner cylindrical portion 16 is preferably formed in a tubular shape having an outer diameter having a minimum degree of clearance with the inner wall surface of the concentrate nozzle 9 so as to be able to be inserted into and removed from the concentrate nozzle 9. Further, the inner cylindrical portion 16 may be slightly reduced in diameter toward the sealing portion 17 in order to be able to be integrally formed with the sealing portion 17 and the locking portion 18 by injection molding.
 内筒部16は、濃縮液を排出する配管の先端に接続されていてもよく、濃縮液を排出する配管の先端に接続された取付部材19によって濃縮液ノズル9内に固定されるものであってもよい。 The inner cylindrical portion 16 may be connected to the end of the pipe for discharging the concentrate, and is fixed in the concentrate nozzle 9 by the mounting member 19 connected to the end of the pipe for discharging the concentrate. May be
 内筒部16の平均厚さとしては、十分な強度を確保できる厚さであればよく、材質にもよるが、例えば2mm以上10mm以下とすることができる。 The average thickness of the inner cylindrical portion 16 may be any thickness as long as sufficient strength can be ensured, and may be, for example, 2 mm or more and 10 mm or less, although it depends on the material.
(封止部)
 封止部17は、ドーム状に形成され、濃縮液を通過させる複数の開口20を有する。また、封止部17は、ケーシング3内に突出する。なお、「ドーム状」とは、例えば球面状、楕円球面状、頂部を面取りした円錐面状等の滑らかに膨出した角のない形状全般を意味する。
(Sealing part)
The sealing portion 17 is formed in a dome shape and has a plurality of openings 20 through which the concentrate passes. Further, the sealing portion 17 protrudes into the casing 3. In addition, "dome shape" means the whole shape which does not have the corner | angular shape which expanded smoothly, such as spherical shape, elliptical spherical shape, the conical surface shape which chamfered the top, etc., for example.
 封止部17がドーム状に形成されることによって、中空糸膜1に接触しても中空糸膜1を損傷しにくくなると共に、開口20の合計面積を大きくして十分な流路面積を確保することができる。 By forming the sealing portion 17 in a dome shape, it becomes difficult to damage the hollow fiber membrane 1 even when contacting the hollow fiber membrane 1, and the total area of the openings 20 is increased to ensure a sufficient flow path area can do.
 封止部17は、その突出方向先端に、開口20が存在しない領域を有することが好ましい。このように、中空糸膜1と接触しやすい突出方向先端に、開口20が存在しない領域を有することによって、中空糸膜1の損傷をより確実に防止することができる。また、封止部17の突出方向先端部は、中空糸膜1の延在方向と略平行な面となるため、濃縮液の流れによって中空糸膜1が吸い付きやすく、中空糸膜1が吸い付いて面積が小さくなった開口20には夾雑物が付着しやすくなるため、この領域に開口20を形成しないことで、夾雑物の付着を抑制することができる。 The sealing portion 17 preferably has a region where the opening 20 does not exist at the tip in the protruding direction. Thus, damage to the hollow fiber membrane 1 can be more reliably prevented by having a region where the opening 20 does not exist at the tip in the projecting direction that is easily in contact with the hollow fiber membrane 1. In addition, since the tip of the sealing portion 17 in the protruding direction is a plane substantially parallel to the extending direction of the hollow fiber membrane 1, the hollow fiber membrane 1 is easily sucked by the flow of the concentrate, and the hollow fiber membrane 1 is sucked. Contaminants are easily attached to the opening 20 having a smaller area, and by not forming the opening 20 in this region, attachment of contaminants can be suppressed.
 封止部17の厚さは、十分な強度を確保できる厚さであればよいが、流路面積を大きくするために、内筒部16よりも僅かに小さくするとよい。封止部17の平均厚さとしては、材質にもよるが、例えば2mm以上10mm以下とすることができる。 The thickness of the sealing portion 17 may be a thickness that can ensure sufficient strength, but may be slightly smaller than the inner cylinder portion 16 in order to increase the flow passage area. The average thickness of the sealing portion 17 may be, for example, 2 mm or more and 10 mm or less, although it depends on the material.
 封止部17の開口20は、封止部17の先端に向かって延びる長穴状に形成されることが好ましい。このように、開口20が封止部17の先端に向かって延びる長穴状であることによって、開口20に中空糸膜1が接触することがあっても、開口20が延びる方向と中空糸膜1が延びる方法とが異なる方向となるため、中空糸膜1が開口を閉塞しにくい。 The opening 20 of the sealing portion 17 is preferably formed in a long hole shape extending toward the tip of the sealing portion 17. Thus, even if the hollow fiber membrane 1 is in contact with the opening 20 by the opening 20 being an elongated hole extending toward the tip of the sealing portion 17, the direction in which the opening 20 extends and the hollow fiber membrane Because the direction in which 1 extends is different from the direction in which it extends, the hollow fiber membrane 1 is less likely to close the opening.
 また、封止部17には、開口20が封止部17の先端に向かって長手方向に並んで複数形成されることがより好ましい。封止部17の内筒部16の近傍から封止部17の先端近傍まで延びる長い長穴を形成すると封止部17の強度が不十分となるおそれがあるが、長手方向に複数の開口20に分割して形成することによって封止部17の強度を確保することが容易となる。このため、複数の開口20を長手方向に並んで形成することによって、封止部17の周方向における開口率を大きくすることができるため、複数の開口20の合計面積を大きくすることができる。 Further, it is more preferable that a plurality of openings 20 be formed in the sealing portion 17 in the longitudinal direction toward the tip of the sealing portion 17. If a long long hole extending from the vicinity of the inner cylindrical portion 16 of the sealing portion 17 to the vicinity of the tip of the sealing portion 17 is formed, the strength of the sealing portion 17 may be insufficient. By dividing and forming into two, it becomes easy to secure the strength of the sealing portion 17. For this reason, by forming the plurality of openings 20 side by side in the longitudinal direction, the aperture ratio in the circumferential direction of the sealing portion 17 can be increased, so that the total area of the plurality of openings 20 can be increased.
 開口20は、中空糸膜1が接触しても損傷しないよう、少なくとも封止部17の外面側の周縁部が面取りされていることが好ましい。 The opening 20 is preferably chamfered at least on the outer peripheral side of the sealing portion 17 so as not to be damaged even when the hollow fiber membrane 1 contacts.
 開口20の短径(長穴の幅が一定である部分の幅)の下限としては、3mmが好ましく、5mmがより好ましい。一方、開口20の短径の上限としては、12mmが好ましく、10mmがより好ましい。開口20の短径が上記下限に満たない場合、夾雑物により開口20が閉塞しやすくなるおそれがある。一方、開口20の短径が上記上限を超える場合、中空糸膜が開口内に引き込まれやすく、開口が閉塞するおそれがある。 The lower limit of the minor diameter (the width of the portion where the width of the elongated hole is constant) of the opening 20 is preferably 3 mm, more preferably 5 mm. On the other hand, as an upper limit of the breadth of opening 20, 12 mm is preferred and 10 mm is more preferred. If the minor axis of the opening 20 does not reach the above lower limit, the opening 20 may be easily clogged by contaminants. On the other hand, when the minor axis of the opening 20 exceeds the above upper limit, the hollow fiber membrane is easily drawn into the opening, and the opening may be blocked.
 開口20の長径(長穴の長さ)の下限としては、10mmが好ましく、15mmがより好ましい。一方、開口20の長径の上限としては、30mmが好ましく、25mmがより好ましい。開口20の長径が上記下限に満たない場合、封止部17における開口20の面積率を大きくすることができず、流路面積を十分に大きくできないおそれがある。一方、開口20の長径が上記上限を超える場合、封止部17の強度を確保しにくくなるおそれがある。
 複数の開口20の合計開口面積の下限としては、内筒部16内の断面積の110%が好ましく、130%がより好ましい。一方、複数の開口20の合計開口面積の上限としては、内筒部16内の断面積の180%が好ましく、160%がより好ましい。複数の開口20の合計開口面積が上記下限に満たない場合、開口20が夾雑物により閉塞しやすくなるおそれがある。一方、複数の開口20の合計開口面積が上記上限を超える場合、封止部17の強度が不十分となるおそれや、封止部17が大きくなり過ぎて中空糸膜1に過度に干渉しやすくなるおそれがある。
As a minimum of a major axis (length of a long hole) of opening 20, 10 mm is preferred and 15 mm is more preferred. On the other hand, as a maximum of a major axis of opening 20, 30 mm is preferred and 25 mm is more preferred. If the major diameter of the opening 20 does not reach the above lower limit, the area ratio of the opening 20 in the sealing portion 17 can not be increased, and the flow passage area may not be sufficiently increased. On the other hand, when the major diameter of the opening 20 exceeds the above-mentioned upper limit, there is a possibility that it will become difficult to secure the intensity of the sealing part 17.
As a lower limit of the total opening area of the plurality of openings 20, 110% of the cross-sectional area in the inner cylinder part 16 is preferable, and 130% is more preferable. On the other hand, as an upper limit of the total opening area of the plurality of openings 20, 180% of the cross-sectional area in the inner cylinder part 16 is preferable, and 160% is more preferable. If the total opening area of the plurality of openings 20 does not reach the above lower limit, the openings 20 may be easily clogged by foreign matter. On the other hand, when the total opening area of the plurality of openings 20 exceeds the above upper limit, the strength of the sealing portion 17 may be insufficient, or the sealing portion 17 may be too large and easily interfere with the hollow fiber membrane 1 May be
(係止部)
 係止部18は、内筒部16から外側に突出し、濃縮液ノズル9の外側端部に当接することによって、引込阻止部材10のケーシング3に対する位置を定める。これにより、引込阻止部材10を適切な位置に固定して、中空糸膜1の濃縮液ノズル9への引き込みをより確実に防止することができる。
(Locking part)
The locking portion 18 protrudes outward from the inner cylindrical portion 16 and abuts on the outer end of the concentrate nozzle 9 to thereby determine the position of the pull-in blocking member 10 with respect to the casing 3. As a result, the pull-in blocking member 10 can be fixed at an appropriate position, and pull-in of the hollow fiber membrane 1 to the concentrate nozzle 9 can be more reliably prevented.
 係止部18は、内筒部16の外周の一部分にのみ突設されてもよいが、濃縮液ノズル9との間を気密に封止するために、内筒部16の全周に亘って環状に突設されることが好ましい。係止部18は、濃縮液ノズル9の外側端部との間を封止する例えばOリング21等のシール部材を保持する保持構造を有してもよい。 The locking portion 18 may be protruded only on a part of the outer periphery of the inner cylinder portion 16, but in order to seal airtight between the concentrate nozzle 9 and the like, the entire periphery of the inner cylinder portion 16 is sealed. It is preferable to be provided in a ring shape. The locking portion 18 may have a holding structure that holds a sealing member such as an O-ring 21 that seals between the locking portion 18 and the outer end of the concentrate nozzle 9.
<取付部材>
 取付部材19は、被処理液ノズル7の継ぎ手構造に対応する継ぎ手構造を有し、係止部18を濃縮液ノズル9の外側端部に当接する状態に保持する。この取付部材19の構成としては、図示するようなユニオンナットの他、フランジ、フェルール等とすることができる。
<Mounting member>
The mounting member 19 has a joint structure corresponding to the joint structure of the liquid nozzle 7 and holds the locking portion 18 in contact with the outer end of the concentrate nozzle 9. The configuration of the mounting member 19 can be a flange, a ferrule or the like in addition to a union nut as shown.
 この取付部材19は、被処理液ノズル7の継ぎ手構造によっては、その一部又は全部が引込阻止部材10と一体に形成されてもよい。 Depending on the joint structure of the liquid nozzle 7, a part or all of the attachment member 19 may be integrally formed with the pull-in preventing member 10.
[その他の実施形態]
 今回開示された実施の形態は全ての点で例示であって制限的なものではないと考えられるべきである。本発明の範囲は、上記実施形態の構成に限定されるものではなく、特許請求の範囲によって示され、特許請求の範囲と均等の意味及び範囲内での全ての変更が含まれることが意図される。
Other Embodiments
It should be understood that the embodiments disclosed herein are illustrative and non-restrictive in every respect. The scope of the present invention is not limited to the configurations of the above embodiments, but is indicated by the claims, and is intended to include all modifications within the meaning and scope equivalent to the claims. Ru.
 当該濾過モジュールにおいて、複数の中空糸膜を有する膜エレメントの構成は任意である。また、着脱可能な膜エレメントを形成せず、ケーシング内に複数の中空糸膜を恒久的に配設してもよい。 In the filtration module, the configuration of the membrane element having a plurality of hollow fiber membranes is arbitrary. Also, a plurality of hollow fiber membranes may be permanently disposed in the casing without forming a detachable membrane element.
 当該濾過モジュールの引込阻止部材は、濃縮液が濃縮液ノズルに流出することを許容し、中空糸膜が濃縮液ノズル内に進入することを防止できるものであればよく、内筒部と封止部とを有するものに限られない。また、引込阻止部材における係止部も任意の構成である。 The pull-in blocking member of the filtration module may be any one that can allow the concentrate to flow out to the concentrate nozzle and prevent the hollow fiber membrane from entering into the concentrate nozzle, and the inner cylinder part and the seal It is not restricted to what has a part. Moreover, the latching | locking part in a drawing-in prevention member is also arbitrary structures.
1 中空糸膜
2 膜エレメント
3 ケーシング
4 第1保持部材
5 第2保持部材
6 連結部材
7 被処理液ノズル
8 濾過液ノズル
9 濃縮液ノズル
10 引込阻止部材
11 本体
12 第1スリーブ
13 第1キャップ
14 第2スリーブ
15 第2キャップ
16 内筒部
17 封止部
18 係止部
19 取付部材
20 開口
21 Oリング
DESCRIPTION OF SYMBOLS 1 Hollow fiber membrane 2 Membrane element 3 Casing 4 First holding member 5 Second holding member 6 Connection member 7 Treated liquid nozzle 8 Filtrate nozzle 9 Concentrated liquid nozzle 10 Pull-in blocking member 11 Body 12 First sleeve 13 First cap 14 Second sleeve 15 Second cap 16 Inner cylindrical portion 17 Sealing portion 18 Locking portion 19 Mounting member 20 Opening 21 O-ring

Claims (5)

  1.  一方向に引き揃えられた複数本の中空糸膜と、
     上記複数本の中空糸膜を格納し、濃縮液を排出する濃縮液ノズルを側面に有する筒状のケーシングと、
     上記濃縮液ノズルに挿入され、上記中空糸膜が上記濃縮液ノズル内に進入することを防止する引込阻止部材と
     を備える濾過モジュール。
    A plurality of hollow fiber membranes aligned in one direction;
    A cylindrical casing having at its side a concentrate nozzle for storing the plurality of hollow fiber membranes and discharging a concentrate;
    A filtration prevention member inserted into the concentrate nozzle to prevent the hollow fiber membrane from entering the concentrate nozzle.
  2.  上記引込阻止部材が、
     上記濃縮液ノズルの内側に配置される内筒部と、
     この内筒部の先端を封止し、上記濃縮液を通過させる複数の開口を有するドーム状の封止部とを有し、
     上記封止部が上記ケーシング内に突出し、
     上記複数の開口が上記封止部の先端に向かって延びる長穴状の開口である請求項1に記載の濾過モジュール。
    The pull-in blocking member is
    An inner cylindrical portion disposed inside the concentrate nozzle;
    And a dome-shaped sealing portion having a plurality of openings for sealing the tip of the inner cylindrical portion and allowing the concentrate to pass therethrough;
    The sealing portion projects into the casing;
    The filtration module according to claim 1, wherein the plurality of openings are oblong openings extending toward the tip of the sealing portion.
  3.  上記長穴状の開口が上記封止部の先端に向かって長手方向に並んで複数形成される請求項2に記載の濾過モジュール。 The filtration module according to claim 2, wherein a plurality of the elongated hole-shaped openings are formed in a longitudinal direction toward the tip of the sealing portion.
  4.  上記封止部が、上記封止部の先端に、上記開口が存在しない領域を有する請求項2又は請求項3に記載の濾過モジュール。 The filtration module according to claim 2 or 3, wherein the sealing portion has a region where the opening does not exist at the tip of the sealing portion.
  5.  上記引込阻止部材が、上記濃縮液ノズルの外側端部に係止される係止部を有する請求項1から請求項4のいずれか1項に記載の濾過モジュール。 The filtration module according to any one of claims 1 to 4, wherein the pull-in preventing member has a locking portion that is locked to the outer end of the concentrate nozzle.
PCT/JP2018/043038 2018-01-24 2018-11-21 Filtration module WO2019146229A1 (en)

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JP2018009547A JP7003685B2 (en) 2018-01-24 2018-01-24 Filtration module

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