WO2019127121A1 - Preparation method for graphite-based humus - Google Patents

Preparation method for graphite-based humus Download PDF

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Publication number
WO2019127121A1
WO2019127121A1 PCT/CN2017/119072 CN2017119072W WO2019127121A1 WO 2019127121 A1 WO2019127121 A1 WO 2019127121A1 CN 2017119072 W CN2017119072 W CN 2017119072W WO 2019127121 A1 WO2019127121 A1 WO 2019127121A1
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WIPO (PCT)
Prior art keywords
humus
graphite
slurry
raw material
humification
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PCT/CN2017/119072
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French (fr)
Chinese (zh)
Inventor
李铁才
张世凡
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深圳市大富科技股份有限公司
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Priority to CN201780036350.5A priority Critical patent/CN109415277A/en
Priority to PCT/CN2017/119072 priority patent/WO2019127121A1/en
Publication of WO2019127121A1 publication Critical patent/WO2019127121A1/en

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • C05F11/02Other organic fertilisers from peat, brown coal, and similar vegetable deposits
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Definitions

  • the present application relates to the field of humic preparation, and in particular to a method for preparing a humus based on graphite.
  • Natural graphite is a mixture of long-term changes and depositions of organic organisms with the earth's crust changes hundreds of millions of years ago. The refined graphite products are widely used. At the same time, the production of graphite scrap slurry produced by processing natural graphite is also very large and is not fully utilized. This is because the graphite scrap slurry has a low content of graphite, and the recycling process is complicated and costly; directly discharging it and discharging it causes serious waste of resources.
  • the technical problem mainly solved by the present application is to provide a graphite-based humus preparation method, which can solve the problem of resource waste caused by insufficient utilization of the graphite waste slurry in the prior art.
  • one technical solution adopted in the present application is to provide a graphite-based humus preparation method.
  • the humus raw material being a raw material capable of undergoing humification reaction to form humus
  • the humus raw material and the graphite scrap slurry are mixed and subjected to a humification reaction in accordance with the requirements of the humification reaction to obtain the humus.
  • the graphite scrap slurry is a slurry of graphite processed waste.
  • the method comprises:
  • the graphite scrap slurry is concentrated into a semi-dry graphite scrap slurry.
  • the humus raw material is a comminuted raw material after pulverization.
  • the humus raw material is one or more of plant fiber powder, animal residue powder, animal waste, industrial waste or domestic garbage; and the plant fiber powder has a particle diameter of 5-50 micrometers.
  • the humus raw material and the graphite waste slurry are mixed and subjected to humification reaction, including:
  • the humus raw material and the graphite scrap slurry are mixed according to the requirements of the humification reaction, and the microorganism is added to carry out the humification reaction.
  • the microorganism is a composite microorganism combination;
  • the composite microorganism combination comprises a flora that promotes humification of the humus material;
  • the composite microorganism combination comprises a filamentous fungus, a fiber-decomposing bacterium, and a yeast.
  • the humus raw materials are different types of straw raw materials; according to different users' requirements for the humus, the different types of straw raw materials adopt different composite microbial combinations and different graphite waste slurry for humification reaction.
  • the humus is a humus slurry or a humus dry powder.
  • the humus raw material and the graphite waste slurry are mixed and subjected to humification reaction to obtain the humus, including:
  • the mixture after the humification reaction is processed into the humus slurry according to the requirements of the humus slurry, or the mixture after the humification reaction is concentrated to obtain the humus dry powder.
  • the mass fraction of nitrogen element in the graphite scrap slurry is 0.25% to 2.1%.
  • the mass fraction of phosphorus in the graphite scrap slurry is 0.6% to 3.3%.
  • the mass fraction of potassium element in the graphite scrap slurry is 0.04% to 1%.
  • the mass fraction of magnesium in the graphite scrap slurry is 0.05% to 1%.
  • the beneficial effects of the present application are: different from the prior art, the present application can recycle the graphite waste slurry produced by processing the graphite, thereby avoiding waste of resources; meanwhile, the graphite waste slurry can be combined with the humus The raw materials are combined to prepare humus at a lower cost, which is beneficial to the promotion and application of the humus.
  • FIG. 1 is a flow chart of an embodiment of a method for preparing a graphite-based humus according to the present invention
  • step S200 of FIG. 1 is a flow chart of an embodiment of step S200 of FIG. 1.
  • FIG. 1 is a flow chart of an embodiment of a method for preparing a graphite-based humus according to the present invention, the method comprising:
  • humus raw material refers to a raw material capable of undergoing humification reaction to form humus.
  • the humus raw material is one or more of plant fiber powder, animal residue powder, animal waste, industrial waste or domestic garbage; the plant fiber powder is powder after crushing straw, soybean meal or cotton aphid;
  • the animal waste includes one or more of pig manure, cow dung, chicken manure or horse manure; the animal remains are discarded animal bones, fur, corpses, etc.;
  • the industrial waste includes distiller's grains, vinegar grains One or more of cassava residue, sugar residue or furfural residue; the domestic garbage includes kitchen waste such as swill water.
  • the humus raw material may be an unpulverized humus raw material or a pulverized humus raw material.
  • the pulverized humus raw material can be sufficiently contacted with other raw materials for preparing humus to increase the reaction rate.
  • the pulverized humus raw material includes one or more of animal excrement, industrial waste or domestic garbage, it is necessary to remove animal waste, industrial waste or domestic garbage by drying or drying.
  • the water is pulverized.
  • the humus feedstock is a comminuted humus feedstock.
  • the humus raw material is a plant fiber powder; the plant fiber powder is a powder after straw pulverization; the straw is a part of the stem and leaf remaining after the plant is picked, and is usually treated by incineration, which not only pollutes the environment but also wastes resources.
  • the straw is rich in nitrogen, phosphorus, potassium, calcium, magnesium and organic matter, and is a multi-purpose renewable biological resource.
  • the waste of resources is avoided, and at the same time, the low-cost straw as the humus raw material can further reduce the cost of the prepared humus, and is beneficial to the promotion and application of the humus.
  • the straw comprises the remainder of wheat, rice, corn, potato, oil, cotton, sugar cane, and other crops after harvesting the seed; the straw comprises corn stover, sorghum straw, wheat straw, straw, rice At least one of shell, bean straw, cotton stalk, wood chips, and branches.
  • the selection of the straw type mainly considers the local material and reduces the cost. For example, for the northern region, wheat, corn, and potatoes can be selected for the remainder after harvesting seeds, or corn stover, sorghum straw, wheat straw, bean straw, cotton stalks, and the like. In the south, rice, oilseeds, sugar cane and other crops can be selected for the remainder of the harvest. Of course, other raw materials that can cause humification to form humus, such as wood chips and branches, can also be selected according to actual conditions.
  • the plant fiber powder has a particle diameter of 5 to 50 ⁇ m. Reducing the particle size of the plant fiber powder enables it to be brought into fuller contact with other raw materials for preparing humus, thereby increasing the reaction rate.
  • pulverizing plant fibers such as straw into plant fiber powder having too small a particle size not only increases the performance requirements for the pulverizing equipment, but also the plant fiber powder having a too small particle size is likely to float in the air, making the production process inconvenient. Therefore, the plant fiber powder has a particle diameter of 5 to 50 ⁇ m, for example, 5 ⁇ m, 10 ⁇ m, 20 ⁇ m, 35 ⁇ m or 48 ⁇ m.
  • the particle size of the suitable plant fiber powder can be comprehensively selected according to the actual needs of the humus preparation process and the performance of the current pulverizing equipment.
  • the graphite waste slurry is a slurry of graphite processed waste.
  • the graphite processing process usually extracts graphite elemental material, and the natural graphite contains a large amount of nutrients and trace elements suitable for biological growth accumulated in the formation process, and the graphite waste remains.
  • the nutrient and the trace elements are complete in a suitable ratio and can play a role in the preparation of the humification reaction of the humus.
  • the nutrient in the graphite waste slurry can be used as the humus raw material.
  • the supplement is beneficial to reduce the amount of the humus raw material and further reduce the cost.
  • the trace elements in the graphite waste slurry can promote the metabolism and growth of microorganisms.
  • the humification reaction is a process of colloidal substances formed by microbial decomposition of organic substances, and the main types thereof are humic acid and fulvic acid.
  • Humus has moderate cohesiveness, which can loosen the clay and bind the sand. It is a good cement for forming agglomerate structure.
  • the humification reaction of organic matter and the formation of humus are divided into two stages.
  • the humus raw material is decomposed into various simple compounds under the action of microorganisms, which is the original material constituting the main component of humus;
  • the second stage For the synthesis stage, the raw material is formed into a complex cyclic compound of different molecular weight by polymerization, that is, the humus.
  • the humification reaction process plays a leading role by microorganisms, and the trace elements in the graphite waste slurry can catalyze the humification reaction by promoting the metabolic process of the strain, thereby obtaining higher reaction efficiency. .
  • the graphite scrap slurry has a wide range of uses.
  • the graphite scrap slurry has a wide range of sources, which can be used for preparing refractory waste graphite scrap slurry, preparing conductive material waste graphite scrap slurry, and preparing lubricating material waste graphite waste.
  • the composition of the graphite waste slurry also differs depending on the nature of the materials to be prepared and the preparation process. According to different humus requirements or standards, graphite scrap slurry of corresponding source can be used to prepare corresponding humus that meets certain requirements or standards.
  • the graphite scrap slurry refers to a graphite scrap slurry prepared by preparing a graphite electrode.
  • the graphite scrap slurry has a graphite content of less than 95%. Since the graphite scrap slurry has a low graphite content, recycling the graphite therein for recycling requires a complicated recovery and purification process, and the cost is also high.
  • the use of the graphite waste slurry having a low graphite content for preparing humus not only recycles the graphite waste slurry but also is convenient to operate. Further, before the humus raw material and the graphite waste slurry are mixed and subjected to a fermentation reaction according to the requirement of humic fermentation, the method comprises: concentrating the graphite waste slurry having a graphite content of less than 95% into a semi-dry graphite waste. Slurry.
  • Part of the moisture in the graphite scrap slurry can be removed by heating evaporation or the like to increase the content of nutrients and trace elements in the graphite scrap slurry, which is advantageous for obtaining a better fermentation effect. Additionally, concentrating the graphite waste slurry into a semi-dry graphite waste slurry facilitates transportation and use of the graphite waste slurry. Further, the graphite waste slurry concentration process may be performed at any time after the production of the graphite waste slurry, before the mixing of the humus raw material and the graphite waste slurry.
  • the graphite waste slurry contains nitrogen, phosphorus, potassium and other nutrient elements and trace elements such as calcium and magnesium, which are beneficial to the metabolism of microorganisms during fermentation, improve fermentation efficiency, and remain in the prepared fertilizer. In the process of plant growth and absorption, to improve fertilizer efficiency.
  • the graphite waste slurry used may have a water content of 45% to 85%, for example, 45%, 55%, 65%, 75%, 85%, and the like.
  • the dry material of the graphite waste slurry contains nutrients such as nitrogen, phosphorus, potassium, calcium, sulfur, magnesium, sodium, manganese, iron, and other nutrients required for the growth of crops.
  • nitrogen is 0.25% to 2.1%
  • phosphorus is 0.6% to 3.3%
  • potassium is 0.04% to 1%.
  • the humus raw material and the graphite waste slurry are mixed and subjected to a humification reaction, and the method for obtaining humus comprises: the organic fertilizer raw material and the graphite waste according to a requirement of a humification reaction
  • the slurry is mixed and a predetermined amount of microorganisms are added for humification reaction.
  • a pH adjuster may be appropriately added to adjust the pH to 6.2 to 8.5, specifically, 6.2, 6.5, 7.0, 7.5, 8.0, 8.5, etc., followed by fermentation reaction. .
  • FIG. 2 is a schematic diagram of an embodiment of step S200 in FIG. 1, the method includes:
  • the process of the humification reaction comprises:
  • the first microorganism includes yeast and fibrolytic bacteria, and the yeast is Pichia.
  • the fiber-decomposing bacteria include Bacillus brevis, Bacillus subtilis, and Staphylococcus aureus.
  • the first microorganism is mainly used to decompose the humus material into various simple compounds, that is, a raw material constituting a main component of humus.
  • the humus raw material may be a mixture of one or more of a composite plant fiber powder, such as corn stalk, sorghum straw, wheat straw, straw, rice husk, and bean straw, and the mass fraction of different fiber powders.
  • the humus raw material may be animal residue powder, animal waste, or the like; the humus raw material may also be a mixture of composite plant fiber powder and animal residue powder, animal waste, and the like.
  • the graphite scrap slurry may be a semi-dry graphite scrap slurry or the graphite scrap slurry that has not been concentrated.
  • the water is added to ensure that the humification reaction process is carried out in an environment close to the solution, and the contact area between the humification raw materials is increased, which is favorable for the improvement of the humification reaction efficiency.
  • the humification reaction process needs to be carried out in a continuous manner, and an additive for promoting the continuous reaction of the microorganisms is added to slow down the inhibition of the growth of the microorganisms in the humification reaction process to ensure production efficiency and product quality. Stable.
  • the combination of microorganisms and humification raw materials has a significant effect on the efficiency of the humification reaction. That is, for different types of straw raw materials, different microorganisms and different graphite waste slurry are needed for fermentation reaction, and a better humification reaction effect can be obtained.
  • the humus raw material used includes corn stover, sorghum straw, wheat straw
  • the microorganism includes Pichia pastoris and Bacillus subtilis
  • the graphite scrap slurry is added in an amount of 10-30 parts, for example, 10 parts.
  • the humus raw material used comprises composite plant fiber powder and animal residue powder
  • the microorganism comprises Pichia pastoris, Bacillus subtilis, Staphylococcus aureus, and the graphite waste slurry
  • the amount added is 40-80 parts, for example, 40 parts, 60 parts or 80 parts.
  • the fermentation reaction temperature may be 35 ° C, 45 ° C or 60 ° C, etc., since the humification reaction process is an exothermic process, the temperature of the humification reaction is not too high, and the selection of 35-65 ° C can increase the humification reaction rate. .
  • the higher the humification reaction temperature the shorter the humification reaction time. For example, reaction at 35 ° C for 10 days, reaction at 45 ° C for 9 days, fermentation at 60 ° C for 8 days, and the like.
  • the humus raw material mixture needs to be stirred every 8-16 hours, for example, 8 hours, 12 hours or 16 hours, on the one hand, the microorganisms and the humus which have not undergone humification reaction.
  • the raw materials are sufficiently contacted to increase the efficiency of the humification reaction process; on the other hand, the temperature of the first humus raw material can be made uniform, and the local temperature is too high to avoid a decrease in reaction efficiency.
  • an additive such as a strain growth promoter or a strain antibiotic agent may be added to the humus raw material to obtain a better conversion rate.
  • the second microorganism includes yeast, filamentous fungus, lactococcus and fibrinolytic bacteria, and in the second microorganism, the yeast is 25-35 parts by mass, and the filamentous fungus is 30-40 parts by mass, the lactic acid bacteria
  • the fiber-decomposing bacteria is 10-15 parts by mass for 10-20 parts by mass.
  • the yeast is Pichia
  • the filamentous fungus is Trichoderma viride
  • the fibrinolytic bacteria include Bacillus pumilus, Bacillus subtilis, and Staphylococcus aureus.
  • the second microorganism has a large number of microorganisms, because the second microorganism is mainly used to form the complex cyclic compound of different molecular weight by polymerization to further synthesize the humus;
  • the humus feedstock that is not completely converted in the first humification reaction is further converted to increase the utilization of the humus feedstock.
  • the second humification reaction is carried out in a closed environment, and the gas product of the second humification reaction can be used to increase the pressure of the reaction system, thereby promoting the formation of a complex ring of different molecular weights by polymerization. a compound that further increases the yield of humus.
  • an appropriate amount of urea, phosphate rock or plant ash may be added to the second humification reaction system to promote the metabolism of the second microorganism, and the conversion rate of the second humification reaction is increased.
  • the second humification reaction product is subjected to filtration or dried granulation to obtain the humus. Specifically, the second humification reaction product is filtered to obtain a humus slurry, the humus slurry is granulated, and the obtained granules are dried to obtain the humus dry powder. According to different needs, the second humification reaction product is made into humus in different states.
  • the humus slurry can be directly applied to the soil and is convenient to use.
  • the humus dry powder is convenient for long-distance transportation and long-term storage, and can add other raw materials as needed to obtain better effects.
  • Example 1 Example 2
  • Example 3 Organic matter (wt%) ⁇ 45 48 51 69 61
  • Table 1 is a comparison table of graphite-based humic properties prepared by the present invention.
  • the organic matter and total nutrients are measured by a drying base, the moisture is measured by fresh samples, and the humus is used as a kind of organic fertilizer, and the detection standard and the detection method thereof can be See NY525-2012 Organic Fertilizer Standard.
  • the humus prepared by the method of the present invention conforms to the NY525-2012 organic fertilizer standard and can be put into use. Meanwhile, in the process of Examples 1-3, the amount of the graphite waste slurry added is increased, the amount of microorganisms added is decreased, but the total organic matter and total nutrient content of the prepared humus are increased, indicating that the graphite waste slurry can be combined with The humic materials are combined to catalyze the humification reaction.
  • the total nitrogen, phosphorus, potassium, aphid egg mortality and heavy metal content of the humus prepared by the invention are all tested to meet the NY525-2012 organic fertilizer standard.
  • Table 3 is a graphite-based humus yield table prepared by the present invention. It can be seen from the contents of Table 1-2 and the examples that the raw material cost and time cost of the example 1 and the blank example are similar, but the humus prepared by the two is similar. Different yields, it can be clearly seen that the yield of humus in Comparative Example 1 is 1.11 times that in the blank case, that is, in the case of the same access, adding an appropriate amount of graphite fertilizer slurry to the fermentation raw material can increase the yield by 11%. Effectively increasing the output value is beneficial to further reducing the price per unit weight of the humus and promoting its promotion and application.
  • the present application discloses a method for preparing a humus based on graphite, the method comprising: providing a humus raw material and a graphite waste slurry respectively, wherein the humus raw material refers to a raw material capable of humification reaction to form humus a material; mixing the humus raw material and the graphite scrap slurry according to a humification reaction and performing a humification reaction to obtain the humus.
  • the present application can recycle the graphite waste slurry produced by processing the graphite, thereby avoiding waste of resources; at the same time, the graphite waste slurry can be combined with the humus raw material to prepare humus at a lower cost. Conducive to the promotion and application of the humus.

Abstract

Disclosed in the present application is a preparation method for a graphite-based humus, the method comprising: respectively providing a humus raw material and a graphite waste slurry, wherein the humus raw material refers to a raw material capable of carrying out a humification reaction to generate humus; and mixing the humus raw material and the graphite waste slurry and performing a humification reaction according to requirements of the humification reaction to obtain the humus. By means of said method, the present application can recycle the graphite waste slurry produced by processing the graphite, thereby avoiding waste of resources. Further, the graphite waste slurry can be compounded with the humus raw material to prepare humus at a lower cost, being beneficial to the promotion and application of the humus.

Description

一种基于石墨的腐殖质的制备方法Preparation method of graphite-based humus 【技术领域】[Technical Field]
本申请涉及腐殖质制备领域,特别是涉及一种基于石墨的腐殖质的制备方法。The present application relates to the field of humic preparation, and in particular to a method for preparing a humus based on graphite.
【背景技术】【Background technique】
天然石墨是几亿年前的有机生物随地壳变迁长期变化、沉积而来的混合物,其精炼后的产物石墨单质用途广泛。与此同时,天然石墨经加工后产生的石墨废料浆料产量也非常巨大,且没有被充分利用。这是因为,所述石墨废料浆料中石墨的含量较低,回收利用过程较为复杂且成本高;直接将其废弃排放造成了严重的资源浪费。Natural graphite is a mixture of long-term changes and depositions of organic organisms with the earth's crust changes hundreds of millions of years ago. The refined graphite products are widely used. At the same time, the production of graphite scrap slurry produced by processing natural graphite is also very large and is not fully utilized. This is because the graphite scrap slurry has a low content of graphite, and the recycling process is complicated and costly; directly discharging it and discharging it causes serious waste of resources.
【发明内容】[Summary of the Invention]
本申请主要解决的技术问题是提供一种基于石墨的腐殖质制备方法,能够解决现有技术中石墨废料浆料没有充分利用造成的资源浪费问题。The technical problem mainly solved by the present application is to provide a graphite-based humus preparation method, which can solve the problem of resource waste caused by insufficient utilization of the graphite waste slurry in the prior art.
为解决上述技术问题,本申请采用的一个技术方案是:提供一种基于石墨的腐殖质制备方法。In order to solve the above technical problems, one technical solution adopted in the present application is to provide a graphite-based humus preparation method.
其中,包括:Among them, including:
分别提供腐殖质原料和石墨废料浆料,所述腐殖质原料是指能够发生腐殖化反应生成腐殖质的原始材料;Providing a humus raw material and a graphite waste slurry respectively, the humus raw material being a raw material capable of undergoing humification reaction to form humus;
按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应,以获得所述腐殖质。The humus raw material and the graphite scrap slurry are mixed and subjected to a humification reaction in accordance with the requirements of the humification reaction to obtain the humus.
其中,所述石墨废料浆料为石墨经加工后的废料的浆料。Wherein, the graphite scrap slurry is a slurry of graphite processed waste.
其中,所述按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应之前,包括:Wherein, according to the requirement of the humification reaction, before the humus raw material and the graphite waste slurry are mixed and subjected to humification reaction, the method comprises:
将所述石墨废料浆料浓缩成半干石墨废料浆料。The graphite scrap slurry is concentrated into a semi-dry graphite scrap slurry.
其中,所述腐殖质原料为粉碎后的腐殖质原料。Wherein, the humus raw material is a comminuted raw material after pulverization.
其中,所述腐殖质原料为植物纤维粉、动物残体粉末、动物排泄物、工业废弃物或生活垃圾中的一种或多种;所述植物纤维粉的粒径为5-50微米。Wherein, the humus raw material is one or more of plant fiber powder, animal residue powder, animal waste, industrial waste or domestic garbage; and the plant fiber powder has a particle diameter of 5-50 micrometers.
其中,所述按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应,包括:Wherein, according to the requirement of the humification reaction, the humus raw material and the graphite waste slurry are mixed and subjected to humification reaction, including:
按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合,并加入微生物进行腐殖化反应。The humus raw material and the graphite scrap slurry are mixed according to the requirements of the humification reaction, and the microorganism is added to carry out the humification reaction.
其中,所述微生物为复合微生物组合;所述复合微生物组合包括促使所述腐殖质原料腐殖化的菌群;所述复合微生物组合包括丝状真菌、纤维分解菌、酵母菌。Wherein the microorganism is a composite microorganism combination; the composite microorganism combination comprises a flora that promotes humification of the humus material; the composite microorganism combination comprises a filamentous fungus, a fiber-decomposing bacterium, and a yeast.
其中,所述腐殖质原料为不同类型的秸秆原料;根据不同用户对所述腐殖质的要求,所述不同类型的秸秆原料采用不同的复合微生物组合和不同的石墨废料浆料进行腐殖化反应。Wherein, the humus raw materials are different types of straw raw materials; according to different users' requirements for the humus, the different types of straw raw materials adopt different composite microbial combinations and different graphite waste slurry for humification reaction.
其中,所述腐殖质为腐殖质浆料或者腐殖质干粉。Wherein, the humus is a humus slurry or a humus dry powder.
其中,所述按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应,以获得所述腐殖质,包括:Wherein, according to the requirement of the humification reaction, the humus raw material and the graphite waste slurry are mixed and subjected to humification reaction to obtain the humus, including:
按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应;Mixing the humus raw material and the graphite scrap slurry according to the requirements of the humification reaction and performing a humification reaction;
根据腐殖质浆料的要求,将腐殖化反应后的混合物加工成所述腐殖质浆料,或者,将腐殖化反应后的混合物进行浓缩,以获得所述腐殖质干粉。The mixture after the humification reaction is processed into the humus slurry according to the requirements of the humus slurry, or the mixture after the humification reaction is concentrated to obtain the humus dry powder.
其中,所述石墨废料浆料中氮元素的质量份数为0.25%~2.1%。Wherein, the mass fraction of nitrogen element in the graphite scrap slurry is 0.25% to 2.1%.
其中,所述石墨废料浆料中磷元素的质量分数为0.6%~3.3%。Wherein, the mass fraction of phosphorus in the graphite scrap slurry is 0.6% to 3.3%.
其中,所述石墨废料浆料中钾元素的质量分数为0.04%~1%。Wherein, the mass fraction of potassium element in the graphite scrap slurry is 0.04% to 1%.
其中,所述石墨废料浆料中镁元素的质量分数为0.05%~1%。Wherein, the mass fraction of magnesium in the graphite scrap slurry is 0.05% to 1%.
本申请的有益效果是:区别于现有技术的情况,本申请能够将石墨经加工后产生的石墨废料浆料回收利用,避免了资源浪费;同时,所述石墨废料浆料 能够与所述腐殖质原料配合,以更低的成本制备腐殖质,有利于所述腐殖质的推广应用。The beneficial effects of the present application are: different from the prior art, the present application can recycle the graphite waste slurry produced by processing the graphite, thereby avoiding waste of resources; meanwhile, the graphite waste slurry can be combined with the humus The raw materials are combined to prepare humus at a lower cost, which is beneficial to the promotion and application of the humus.
【附图说明】[Description of the Drawings]
图1是本发明基于石墨的腐殖质的制备方法一实施例的流程图;1 is a flow chart of an embodiment of a method for preparing a graphite-based humus according to the present invention;
图2是图1中步骤S200的一实施例的流程图。2 is a flow chart of an embodiment of step S200 of FIG. 1.
【具体实施方式】【Detailed ways】
请参考图1,图1是本发明基于石墨的腐殖质的制备方法一实施例的流程图,所述方法包括:Please refer to FIG. 1. FIG. 1 is a flow chart of an embodiment of a method for preparing a graphite-based humus according to the present invention, the method comprising:
S100、分别提供腐殖质原料和石墨废料浆料,所述腐殖质原料是指能够发生腐殖化反应生成腐殖质的原始材料。S100, respectively providing a humus raw material and a graphite waste slurry, wherein the humus raw material refers to a raw material capable of undergoing humification reaction to form humus.
在所述步骤S100中,需要提供制备所述腐殖质的腐殖质原料和石墨废料浆料。所述腐殖质原料为植物纤维粉、动物残体粉末、动物排泄物、工业废弃物或生活垃圾中的一种或多种;所述植物纤维粉为秸秆、豆粕或棉粕粉碎后的粉末;所述动物排泄物包括猪粪、牛粪、鸡粪或马粪中的一种或多种;所述动物残体为废弃的动物骨骼、皮毛、尸体等;所述工业废弃物包括酒糟、醋糟、木薯渣、糖渣或糠醛渣中的一种或多种;所述生活垃圾包括泔水等餐厨垃圾。所述腐殖质原料可以为未粉碎的腐殖质原料,也可以为粉碎后的腐殖质原料。所述粉碎后的腐殖质原料能够与制备腐殖质的其它原料充分接触,提高反应速率。当所述粉碎的腐殖质原料中包括动物排泄物、工业废弃物或生活垃圾中的一种或多种时,需要将动物排泄物、工业废弃物或生活垃圾采用晒干或烘干的方式脱除水分后再进行粉碎。在一个实施例中,所述腐殖质原料为粉碎后的腐殖质原料。In the step S100, it is necessary to provide a humus raw material and a graphite scrap slurry for preparing the humus. The humus raw material is one or more of plant fiber powder, animal residue powder, animal waste, industrial waste or domestic garbage; the plant fiber powder is powder after crushing straw, soybean meal or cotton aphid; The animal waste includes one or more of pig manure, cow dung, chicken manure or horse manure; the animal remains are discarded animal bones, fur, corpses, etc.; the industrial waste includes distiller's grains, vinegar grains One or more of cassava residue, sugar residue or furfural residue; the domestic garbage includes kitchen waste such as swill water. The humus raw material may be an unpulverized humus raw material or a pulverized humus raw material. The pulverized humus raw material can be sufficiently contacted with other raw materials for preparing humus to increase the reaction rate. When the pulverized humus raw material includes one or more of animal excrement, industrial waste or domestic garbage, it is necessary to remove animal waste, industrial waste or domestic garbage by drying or drying. The water is pulverized. In one embodiment, the humus feedstock is a comminuted humus feedstock.
进一步的,所述腐殖质原料为植物纤维粉;所述植物纤维粉为秸秆粉碎后的粉末;秸秆即为植物采摘后剩余的茎叶部分,通常采用焚烧的方法进行处理, 不仅污染环境且浪费资源;而秸秆富含氮、磷、钾、钙、镁和有机质等,是一种具有多用途的可再生的生物资源。将其作为腐殖质原料一方面避免资源的浪费,同时,将价格低廉的秸秆作为所述腐殖质原料能够进一步降低制备的腐殖质的成本,有利于所述腐殖质的推广应用。在一个实施例中,所述秸秆包括小麦、水稻、玉米、薯类、油料、棉花、甘蔗和其它农作物在收获籽实后的剩余部分;所述秸秆包括玉米秸、高粱秸、麦秸、稻草、稻壳、豆秸、棉秆、木屑以及树枝中的至少一种。所述秸秆种类的选择主要是考虑就地取材及降低成本。如,对于北方地区,可以选择小麦、玉米、薯类等在收获籽实后的剩余部分,或者玉米秸、高粱秸、麦秸、豆秸、棉秆等。南方地区可以选择水稻、油料、甘蔗和其它农作物在收获籽实后的剩余部分。当然,也可以根据实际情况选择其它能够发生腐殖化反应生成腐殖质的原始材料,如木屑以及树枝等。Further, the humus raw material is a plant fiber powder; the plant fiber powder is a powder after straw pulverization; the straw is a part of the stem and leaf remaining after the plant is picked, and is usually treated by incineration, which not only pollutes the environment but also wastes resources. The straw is rich in nitrogen, phosphorus, potassium, calcium, magnesium and organic matter, and is a multi-purpose renewable biological resource. As a humus raw material, on the one hand, the waste of resources is avoided, and at the same time, the low-cost straw as the humus raw material can further reduce the cost of the prepared humus, and is beneficial to the promotion and application of the humus. In one embodiment, the straw comprises the remainder of wheat, rice, corn, potato, oil, cotton, sugar cane, and other crops after harvesting the seed; the straw comprises corn stover, sorghum straw, wheat straw, straw, rice At least one of shell, bean straw, cotton stalk, wood chips, and branches. The selection of the straw type mainly considers the local material and reduces the cost. For example, for the northern region, wheat, corn, and potatoes can be selected for the remainder after harvesting seeds, or corn stover, sorghum straw, wheat straw, bean straw, cotton stalks, and the like. In the south, rice, oilseeds, sugar cane and other crops can be selected for the remainder of the harvest. Of course, other raw materials that can cause humification to form humus, such as wood chips and branches, can also be selected according to actual conditions.
更进一步的,所述植物纤维粉的粒径为5-50微米。降低所述植物纤维粉的粒径能够使其与制备腐殖质的其它原料更充分的接触,提高反应速率。但是,将秸秆等植物纤维粉碎成粒径太小的植物纤维粉不仅增加对粉碎设备的性能要求,且粒径太小的植物纤维粉容易漂浮在空气中,使生产过程较为不便。因此,所述植物纤维粉的粒径为5-50微米,如,5微米、10微米、20微米、35微米或48微米。总之,可以根据所述腐殖质制备过程的实际需要及当前粉碎设备的性能,综合选择合适的所述植物纤维粉的粒径。Further, the plant fiber powder has a particle diameter of 5 to 50 μm. Reducing the particle size of the plant fiber powder enables it to be brought into fuller contact with other raw materials for preparing humus, thereby increasing the reaction rate. However, pulverizing plant fibers such as straw into plant fiber powder having too small a particle size not only increases the performance requirements for the pulverizing equipment, but also the plant fiber powder having a too small particle size is likely to float in the air, making the production process inconvenient. Therefore, the plant fiber powder has a particle diameter of 5 to 50 μm, for example, 5 μm, 10 μm, 20 μm, 35 μm or 48 μm. In summary, the particle size of the suitable plant fiber powder can be comprehensively selected according to the actual needs of the humus preparation process and the performance of the current pulverizing equipment.
所述石墨废料浆料为石墨经加工后废料的浆料,石墨加工过程通常是提取石墨单质,而天然石墨在形成过程中积累的大量适合生物生长所需的营养物质和微量元素残存在石墨废料浆料中,所述营养物质和微量元素种类齐全且比例合适,能够在制备腐殖质的腐殖化反应过程中发挥作用,一方面,所述石墨废料浆料中的营养物质可以作为所述腐殖质原料的补充,有利于减少所述腐殖质原料的用量,进一步降低成本。另一方面,所述石墨废料浆料中的微量元素能够促进微生物的新陈代谢及生长发育。具体的,所述腐殖化反应是有机物经微生物分解转化形成的胶体物质的过程,其主要种类有胡敏酸和富里酸。腐殖质 具有适度的黏结性,能够使黏土疏松,砂土黏结,是形成团粒结构的良好胶结剂。有机物发生腐殖化反应,生成腐殖质的过程分为两个阶段,第一阶段将所述腐殖质原料在微生物作用下分解为各种简单的化合物,即为构成腐殖质主要成分的原始材料;第二阶段为合成阶段,将所述原始材料通过聚合作用形成不同分子量的复杂环状化合物,即为所述腐殖质。所述腐殖化反应过程过微生物起主导作用,而石墨废料浆料中的微量元素,能够通过促进所述菌种的新陈代谢过程的方式催化所述腐殖化反应,进而获得更高的反应效率。The graphite waste slurry is a slurry of graphite processed waste. The graphite processing process usually extracts graphite elemental material, and the natural graphite contains a large amount of nutrients and trace elements suitable for biological growth accumulated in the formation process, and the graphite waste remains. In the slurry, the nutrient and the trace elements are complete in a suitable ratio and can play a role in the preparation of the humification reaction of the humus. On the one hand, the nutrient in the graphite waste slurry can be used as the humus raw material. The supplement is beneficial to reduce the amount of the humus raw material and further reduce the cost. On the other hand, the trace elements in the graphite waste slurry can promote the metabolism and growth of microorganisms. Specifically, the humification reaction is a process of colloidal substances formed by microbial decomposition of organic substances, and the main types thereof are humic acid and fulvic acid. Humus has moderate cohesiveness, which can loosen the clay and bind the sand. It is a good cement for forming agglomerate structure. The humification reaction of organic matter and the formation of humus are divided into two stages. In the first stage, the humus raw material is decomposed into various simple compounds under the action of microorganisms, which is the original material constituting the main component of humus; the second stage For the synthesis stage, the raw material is formed into a complex cyclic compound of different molecular weight by polymerization, that is, the humus. The humification reaction process plays a leading role by microorganisms, and the trace elements in the graphite waste slurry can catalyze the humification reaction by promoting the metabolic process of the strain, thereby obtaining higher reaction efficiency. .
石墨的用途广泛,相应的,所述石墨废料浆料的来源也非常广,其可以为制备耐火材料废弃的石墨废料浆料、制备导电材料废弃的石墨废料浆料、制备润滑材料废弃的石墨废料浆料,根据制备的不同材料的性质和制备工艺的不同,所述石墨废料浆料的组成也存在差异。根据不同的腐殖质的要求或者标准,可以采用相应来源的石墨废料浆料来制备对应的满足一定要求或者标准的腐殖质。本发明一实施例中,所述的石墨废料浆料是指制备石墨电极废弃的石墨废料浆料。Graphite has a wide range of uses. Correspondingly, the graphite scrap slurry has a wide range of sources, which can be used for preparing refractory waste graphite scrap slurry, preparing conductive material waste graphite scrap slurry, and preparing lubricating material waste graphite waste. The composition of the graphite waste slurry also differs depending on the nature of the materials to be prepared and the preparation process. According to different humus requirements or standards, graphite scrap slurry of corresponding source can be used to prepare corresponding humus that meets certain requirements or standards. In an embodiment of the invention, the graphite scrap slurry refers to a graphite scrap slurry prepared by preparing a graphite electrode.
在一个实施例中,所述石墨废料浆料的石墨含量在95%以下。由于所述石墨废料浆料的石墨含量低,回收其中的石墨进行重复利用需要复杂的回收及提纯工艺,成本也较高。而将所述石墨含量较低的所述石墨废料浆料用于制备腐殖质不仅将所述石墨废料浆料回收利用且操作方便。进一步的,所述按照腐殖质发酵的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行发酵反应之前,包括:将石墨含量在95%以下的石墨废料浆料浓缩成半干石墨废料浆料。可以通过加热蒸发等方式除去所述石墨废料浆料中的部分水分,提高所述石墨废料浆料中营养物质和微量元素的含量,有利于获得更好的发酵效果。此外,将所述石墨废料浆料浓缩成半干石墨废料浆料便于所述石墨废料浆料的运输和使用。更进一步的,所述石墨废料浆料浓缩过程可以在所述石墨废料浆料产生之后,所述腐殖质原料和所述石墨废料浆料混合之前的任意时刻进行。In one embodiment, the graphite scrap slurry has a graphite content of less than 95%. Since the graphite scrap slurry has a low graphite content, recycling the graphite therein for recycling requires a complicated recovery and purification process, and the cost is also high. The use of the graphite waste slurry having a low graphite content for preparing humus not only recycles the graphite waste slurry but also is convenient to operate. Further, before the humus raw material and the graphite waste slurry are mixed and subjected to a fermentation reaction according to the requirement of humic fermentation, the method comprises: concentrating the graphite waste slurry having a graphite content of less than 95% into a semi-dry graphite waste. Slurry. Part of the moisture in the graphite scrap slurry can be removed by heating evaporation or the like to increase the content of nutrients and trace elements in the graphite scrap slurry, which is advantageous for obtaining a better fermentation effect. Additionally, concentrating the graphite waste slurry into a semi-dry graphite waste slurry facilitates transportation and use of the graphite waste slurry. Further, the graphite waste slurry concentration process may be performed at any time after the production of the graphite waste slurry, before the mixing of the humus raw material and the graphite waste slurry.
进一步的,所述石墨废料浆料中含有氮、磷、钾等营养元素及钙、镁等微 量元素,这些一方面有利于发酵过程中微生物的新陈代谢,提高发酵效率,同时,留存在制备的肥料中,供植物生长过程吸收利用,以提高肥效。具体的,所采用的石墨废料浆料中含水量可在45%~85%,例如可以是45%、55%、65%、75%、85%等。其中,在石墨废料浆料的绝干物料中,含有氮、磷、钾、钙、硫、镁、钠、锰、铁等营养元素,以及其它一些农作物生长所需要的营养元素。具体地,石墨废料浆料中(均为质量份数,且所述质量份数为绝干质量份数)含氮0.25%~2.1%、磷0.6%~3.3%、钾0.04%~1%、钙0.03%~1%、镁0.05%~1%、硫0.03%~0.12%、钠0.02%~0.05%、锰0.02%~0.03%、铁0.02%~0.04%。Further, the graphite waste slurry contains nitrogen, phosphorus, potassium and other nutrient elements and trace elements such as calcium and magnesium, which are beneficial to the metabolism of microorganisms during fermentation, improve fermentation efficiency, and remain in the prepared fertilizer. In the process of plant growth and absorption, to improve fertilizer efficiency. Specifically, the graphite waste slurry used may have a water content of 45% to 85%, for example, 45%, 55%, 65%, 75%, 85%, and the like. Among them, the dry material of the graphite waste slurry contains nutrients such as nitrogen, phosphorus, potassium, calcium, sulfur, magnesium, sodium, manganese, iron, and other nutrients required for the growth of crops. Specifically, in the graphite scrap slurry (all parts by mass, and the parts by mass are absolute dry parts), nitrogen is 0.25% to 2.1%, phosphorus is 0.6% to 3.3%, and potassium is 0.04% to 1%. Calcium 0.03% to 1%, magnesium 0.05% to 1%, sulfur 0.03% to 0.12%, sodium 0.02% to 0.05%, manganese 0.02% to 0.03%, and iron 0.02% to 0.04%.
S200、按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应,以获得所述腐殖质。S200: mixing the humus raw material and the graphite waste slurry according to a requirement of a humification reaction and performing a humification reaction to obtain the humus.
为获得腐殖质,所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应,所述获得腐殖质的方法包括:按照腐殖化反应的要求,将所述有机肥料原料和所述石墨废料浆料混合,并加入预定量的微生物进行腐殖化反应。将腐殖质原料和石墨废料浆料混合后,在进行发酵反应前,可适当加入pH调节剂,调节pH至6.2~8.5,具体如6.2、6.5、7.0、7.5、8.0、8.5等,然后进行发酵反应。In order to obtain humus, the humus raw material and the graphite waste slurry are mixed and subjected to a humification reaction, and the method for obtaining humus comprises: the organic fertilizer raw material and the graphite waste according to a requirement of a humification reaction The slurry is mixed and a predetermined amount of microorganisms are added for humification reaction. After mixing the humus raw material and the graphite waste slurry, before the fermentation reaction, a pH adjuster may be appropriately added to adjust the pH to 6.2 to 8.5, specifically, 6.2, 6.5, 7.0, 7.5, 8.0, 8.5, etc., followed by fermentation reaction. .
具体的,请参考图2,图2是图1中所述步骤S200的一实施例的示意图,所述方法包括:Specifically, please refer to FIG. 2, which is a schematic diagram of an embodiment of step S200 in FIG. 1, the method includes:
S210、按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应。S210, mixing the humus raw material and the graphite scrap slurry according to the requirement of the humification reaction and performing a humification reaction.
在所述步骤S210中,所述腐殖化反应的过程包括:In the step S210, the process of the humification reaction comprises:
1)将1-5质量份的第一微生物溶解在50-100份水,得到第一微生物溶液。这是因为,以溶液方式释放的微生物能够与所述腐殖质原料充分接触,提高腐殖化反应效率;所述第一微生物包括酵母菌和纤维分解菌,所述酵母菌为毕赤酵母菌,所述纤维分解菌包括短小芽孢杆菌、枯草芽孢杆菌及腐生葡萄球菌等。所述第一微生物主要用于将所述腐殖质原料分解为各种简单的化合物,即为构成腐殖质主要成分的原始材料。1) Dissolving 1-5 parts by mass of the first microorganism in 50-100 parts of water to obtain a first microorganism solution. This is because the microorganism released in solution can be sufficiently contacted with the humus raw material to increase the efficiency of the humification reaction; the first microorganism includes yeast and fibrolytic bacteria, and the yeast is Pichia. The fiber-decomposing bacteria include Bacillus brevis, Bacillus subtilis, and Staphylococcus aureus. The first microorganism is mainly used to decompose the humus material into various simple compounds, that is, a raw material constituting a main component of humus.
2)将所述第一微生物溶液与100质量份腐殖质原料、40-100质量份所述石墨废料浆料混合,并采用机械搅拌的方式混合均匀,得到第一腐殖质原料。2) mixing the first microorganism solution with 100 parts by mass of the humus raw material, 40-100 parts by mass of the graphite scrap slurry, and uniformly mixing by mechanical stirring to obtain a first humus raw material.
所述腐殖质原料可以为复合植物纤维粉,如,玉米秸、高粱秸、麦秸、稻草、稻壳、豆秸的纤维粉中的一种或多种的混合物,且不同种纤维粉的质量份数相同或不同;所述腐殖质原料可以为动物残体粉末、动物排泄物等;所述腐殖质原料还可以为复合植物纤维粉末与动物残体粉末、动物排泄物等的混合物。所述石墨废料浆料可以为半干石墨废料浆料或未经浓缩的所述石墨废料浆料。所述水的加入是为了保证腐殖化反应过程在接近溶液的环境下进行,提高腐殖化原料间的接触面积,有利于腐殖化反应效率的提升。此外,所述腐殖化反应过程需要采用连续的方式进行,还需加入促进所述微生物连续反应的添加剂,以减缓腐殖化反应过程产物对微生物生长的抑制作用,以保证生产效率和产品质量的稳定。The humus raw material may be a mixture of one or more of a composite plant fiber powder, such as corn stalk, sorghum straw, wheat straw, straw, rice husk, and bean straw, and the mass fraction of different fiber powders. The humus raw material may be animal residue powder, animal waste, or the like; the humus raw material may also be a mixture of composite plant fiber powder and animal residue powder, animal waste, and the like. The graphite scrap slurry may be a semi-dry graphite scrap slurry or the graphite scrap slurry that has not been concentrated. The water is added to ensure that the humification reaction process is carried out in an environment close to the solution, and the contact area between the humification raw materials is increased, which is favorable for the improvement of the humification reaction efficiency. In addition, the humification reaction process needs to be carried out in a continuous manner, and an additive for promoting the continuous reaction of the microorganisms is added to slow down the inhibition of the growth of the microorganisms in the humification reaction process to ensure production efficiency and product quality. Stable.
对于腐殖化反应过程而言,微生物与腐殖化原料的配合对腐殖化反应的效率有显著的影响。即,针对不同类型的秸秆原料,需要采用不同的微生物和不同的石墨废料浆料进行发酵反应,能够获得更好的腐殖化反应效果。如采用的所述腐殖质原料包括玉米秸、高粱秸、麦秸时,所述微生物包括毕赤酵母菌和枯草芽孢杆菌,且所述石墨废料浆料的添加量为10-30份,如,10份、20份或30份;采用的所述腐殖质原料包括复合植物纤维粉、动物残体粉末时,所述微生物包括毕赤酵母菌、枯草芽孢杆,腐生葡萄球菌,且所述石墨废料浆料的添加量为40-80份,如,40份、60份或80份。For the humification reaction process, the combination of microorganisms and humification raw materials has a significant effect on the efficiency of the humification reaction. That is, for different types of straw raw materials, different microorganisms and different graphite waste slurry are needed for fermentation reaction, and a better humification reaction effect can be obtained. When the humus raw material used includes corn stover, sorghum straw, wheat straw, the microorganism includes Pichia pastoris and Bacillus subtilis, and the graphite scrap slurry is added in an amount of 10-30 parts, for example, 10 parts. 20 parts or 30 parts; when the humus raw material used comprises composite plant fiber powder and animal residue powder, the microorganism comprises Pichia pastoris, Bacillus subtilis, Staphylococcus aureus, and the graphite waste slurry The amount added is 40-80 parts, for example, 40 parts, 60 parts or 80 parts.
3)将所述第一腐殖质原料在35-65℃下反应7-10天,且每隔8-16小时搅拌一次,得到第一腐殖化反应产物;3) reacting the first humus raw material at 35-65 ° C for 7-10 days, and stirring once every 8-16 hours to obtain a first humification reaction product;
所述发酵反应温度可以为35℃、45℃或60℃等,由于腐殖化反应过程为放热过程,腐殖化反应的温度不宜过高,选择35-65℃能够提高腐殖化反应速率。相应的,腐殖化反应温度越高,腐殖化反应时间越短。如35℃反应10天、45℃反应9天、60℃发酵8天等。在腐殖化反应过程中,需要每隔8-16小时对所述 腐殖质原料混合物进行搅拌,如,8小时、12小时或16小时,一方面使微生物与未进行腐殖化反应的所述腐殖质原料充分接触,以提高腐殖化反应过程的效率;另一方面能够使所述第一腐殖质原料温度均匀,避免局部温度过高造成反应效率降低。当然,为获得更好的腐殖化反应效果,可以在所述腐殖质原料中添加菌种生长促进剂、菌种抗病剂等添加剂,获得更好的转化率。The fermentation reaction temperature may be 35 ° C, 45 ° C or 60 ° C, etc., since the humification reaction process is an exothermic process, the temperature of the humification reaction is not too high, and the selection of 35-65 ° C can increase the humification reaction rate. . Correspondingly, the higher the humification reaction temperature, the shorter the humification reaction time. For example, reaction at 35 ° C for 10 days, reaction at 45 ° C for 9 days, fermentation at 60 ° C for 8 days, and the like. During the humification reaction, the humus raw material mixture needs to be stirred every 8-16 hours, for example, 8 hours, 12 hours or 16 hours, on the one hand, the microorganisms and the humus which have not undergone humification reaction. The raw materials are sufficiently contacted to increase the efficiency of the humification reaction process; on the other hand, the temperature of the first humus raw material can be made uniform, and the local temperature is too high to avoid a decrease in reaction efficiency. Of course, in order to obtain a better humification reaction effect, an additive such as a strain growth promoter or a strain antibiotic agent may be added to the humus raw material to obtain a better conversion rate.
4)向所述第一腐殖化反应产物中加入1-3质量份的第二微生物,并搅拌均匀,密闭反应3-5天,得到第二腐殖化反应产物。4) 1-3 parts by mass of the second microorganism is added to the first humification reaction product, and stirred uniformly, and the reaction is sealed for 3-5 days to obtain a second humification reaction product.
所述第二微生物包括酵母菌、丝状真菌、乳酸球菌及纤维分解菌,第二微生物中,所述酵母菌25-35质量份,所述丝状真菌为30-40质量份,所述乳酸菌为10-20质量份,所述纤维分解菌为10-15质量份。所述酵母菌为毕赤酵母菌、所述丝状真菌为黑绿木霉、所述纤维分解菌包括短小芽孢杆菌、枯草芽孢杆菌及腐生葡萄球菌等。所述第二微生物中微生物种类较多,这是因为第二微生物主要用于将所述原始材料通过聚合作用形成不同分子量的复杂环状化合物,进一步合成所述腐殖质;同时,还需要将所述第一腐殖化反应中未完全转化的所述腐殖质原料进一步转化,以提高所述腐殖质原料的利用率。而在密闭的环境下进行所述第二腐殖化反应,能够利用所述第二腐殖化反应的气体产物提高反应体系的压力,促进所述原始材料通过聚合作用形成不同分子量的复杂环状化合物,进一步提高腐殖质的产率。当然,还可以向所述第二腐殖化反应体系中添加适量的尿素、磷矿粉或草木灰以促进第二微生物的新陈代谢,提高所述第二腐殖化反应的转化率。The second microorganism includes yeast, filamentous fungus, lactococcus and fibrinolytic bacteria, and in the second microorganism, the yeast is 25-35 parts by mass, and the filamentous fungus is 30-40 parts by mass, the lactic acid bacteria The fiber-decomposing bacteria is 10-15 parts by mass for 10-20 parts by mass. The yeast is Pichia, the filamentous fungus is Trichoderma viride, and the fibrinolytic bacteria include Bacillus pumilus, Bacillus subtilis, and Staphylococcus aureus. The second microorganism has a large number of microorganisms, because the second microorganism is mainly used to form the complex cyclic compound of different molecular weight by polymerization to further synthesize the humus; The humus feedstock that is not completely converted in the first humification reaction is further converted to increase the utilization of the humus feedstock. The second humification reaction is carried out in a closed environment, and the gas product of the second humification reaction can be used to increase the pressure of the reaction system, thereby promoting the formation of a complex ring of different molecular weights by polymerization. a compound that further increases the yield of humus. Of course, an appropriate amount of urea, phosphate rock or plant ash may be added to the second humification reaction system to promote the metabolism of the second microorganism, and the conversion rate of the second humification reaction is increased.
S220、根据腐殖质浆料的要求,将腐殖化反应后的混合物加工成所述腐殖质浆料,或者,将腐殖化反应后的混合物进行浓缩,以获得所述腐殖质干粉S220, processing the mixture after the humification reaction into the humus slurry according to the requirement of the humus slurry, or concentrating the mixture after the humification reaction to obtain the humus dry powder
将所述第二腐殖化反应产物进过滤或烘干造粒,得到所述腐殖质。具体的,将所述第二腐殖化反应产物过滤得到腐殖质浆料,将所述腐殖质浆料进行造粒,并将得到的颗粒进行烘干,得到所述腐殖质干粉。根据不同的需求,将所述第二腐殖化反应产物制成不同状态的腐殖质。所述腐殖质浆料可以直接施用到土 地中,使用较为方便。而所述腐殖质干粉便于长距离运输和长期保存,且能够根据需要添加其它原料获得更好的效果。The second humification reaction product is subjected to filtration or dried granulation to obtain the humus. Specifically, the second humification reaction product is filtered to obtain a humus slurry, the humus slurry is granulated, and the obtained granules are dried to obtain the humus dry powder. According to different needs, the second humification reaction product is made into humus in different states. The humus slurry can be directly applied to the soil and is convenient to use. The humus dry powder is convenient for long-distance transportation and long-term storage, and can add other raw materials as needed to obtain better effects.
下面通过实施例来对本发明进行具体说明。The invention will now be specifically described by way of examples.
空白例Blank example
1)将4质量份的第一微生物溶解在100份水,得到第一微生物溶液;1) dissolving 4 parts by mass of the first microorganism in 100 parts of water to obtain a first microorganism solution;
2)将100质量份玉米秸与所述第一微生物溶液混合,并采用机械搅拌的方式混合均匀,得到第一腐殖质原料;2) mixing 100 parts by mass of corn stover with the first microorganism solution, and uniformly mixing by mechanical stirring to obtain a first humus raw material;
3)将所述第一腐殖质原料在45℃下反应9天,且每隔12小时搅拌一次,得到第一腐殖化反应产物;3) reacting the first humus raw material at 45 ° C for 9 days, and stirring once every 12 hours to obtain a first humification reaction product;
4)向所述第一腐殖化反应产物中加入1质量份的第二微生物,并搅拌均匀,密闭反应4天,得到第二腐殖化反应产物;4) adding 1 part by mass of the second microorganism to the first humification reaction product, stirring uniformly, and sealing the reaction for 4 days to obtain a second humification reaction product;
5)将所述第二腐殖化反应产物进行过滤,得到所述腐殖质。5) filtering the second humification reaction product to obtain the humus.
实施例1Example 1
1)将4质量份的第一微生物溶解在100份水,得到第一微生物溶液;1) dissolving 4 parts by mass of the first microorganism in 100 parts of water to obtain a first microorganism solution;
2)将所述第一微生物溶液、100质量份玉米秸、50质量份所述石墨废料浆料混合,并采用机械搅拌的方式混合均匀,得到第一腐殖质原料;2) mixing the first microbial solution, 100 parts by mass of corn stover, 50 parts by mass of the graphite scrap slurry, and uniformly mixing by mechanical stirring to obtain a first humus raw material;
3)将所述第一腐殖质原料在45℃下反应9天,且每隔12小时搅拌一次,得到第一腐殖化反应产物;3) reacting the first humus raw material at 45 ° C for 9 days, and stirring once every 12 hours to obtain a first humification reaction product;
4)向所述第一腐殖化反应产物中加入2质量份的第二微生物,并搅拌均匀,密闭反应4天,得到第二腐殖化反应产物;4) adding 2 parts by mass of the second microorganism to the first humification reaction product, stirring uniformly, and sealing the reaction for 4 days to obtain a second humification reaction product;
5)将所述第二腐殖化反应产物进行过滤,得到所述腐殖质。5) filtering the second humification reaction product to obtain the humus.
实施例2Example 2
1)将1质量份的第一微生物溶解在50份水,得到第一微生物溶液;1) dissolving 1 part by mass of the first microorganism in 50 parts of water to obtain a first microorganism solution;
2)将所述第一微生物溶液、100质量份玉米秸、100质量份所述石墨废料浆料混合,并采用机械搅拌的方式混合均匀,得到第一腐殖质原料;2) mixing the first microbial solution, 100 parts by mass of corn stover, 100 parts by mass of the graphite scrap slurry, and uniformly mixing by mechanical stirring to obtain a first humus raw material;
3)将所述第一腐殖质原料在35℃下反应10天,且每隔16小时搅拌一次, 得到第一腐殖化反应产物;3) reacting the first humus raw material at 35 ° C for 10 days, and stirring once every 16 hours to obtain a first humification reaction product;
4)向所述第一腐殖化反应产物中加入3量份的第二微生物,并搅拌均匀,密闭反应3天,得到第二腐殖化反应产物;4) adding 3 parts of the second microorganism to the first humification reaction product, stirring uniformly, and sealing the reaction for 3 days to obtain a second humification reaction product;
5)将所述第二腐殖化反应产物进行过滤,得到所述腐殖质。5) filtering the second humification reaction product to obtain the humus.
实施例3Example 3
1)将3质量份的第一微生物溶解在80份水,得到第一微生物溶液;1) dissolving 3 parts by mass of the first microorganism in 80 parts of water to obtain a first microorganism solution;
2)将所述第一微生物溶液、100质量份玉米秸与50质量份所述石墨废料浆料混合,并采用机械搅拌的方式混合均匀,得到第一腐殖质原料;2) mixing the first microbial solution, 100 parts by mass of corn stalk with 50 parts by mass of the graphite scrap slurry, and uniformly mixing by mechanical stirring to obtain a first humus raw material;
3)将所述第一腐殖质原料在60℃下反应8天,且每隔8小时搅拌一次,得到第一腐殖化反应产物;3) reacting the first humus raw material at 60 ° C for 8 days, and stirring once every 8 hours to obtain a first humification reaction product;
4)向所述第一腐殖化反应产物中加入1质量份的第二微生物,并搅拌均匀,密闭反应5天,得到第二腐殖化反应产物;4) adding 1 part by mass of the second microorganism to the first humification reaction product, stirring uniformly, and sealing the reaction for 5 days to obtain a second humification reaction product;
5)将所述第二腐殖化反应产物进行造粒,并将得到的第二腐殖化反应产物烘干,得到所述腐殖质干粉。5) granulating the second humification reaction product, and drying the obtained second humification reaction product to obtain the humus dry powder.
表1 本发明制备的基于石墨的腐殖质性能对照表Table 1 Comparison of graphite-based humic properties prepared by the present invention
项目project 检测标准Testing standard 空白例Blank example 实施例1Example 1 实施例2Example 2 实施例3Example 3
有机质(wt%)Organic matter (wt%) ≥45≥45 4848 5151 6969 6161
总养分(wt%)Total nutrient (wt%) ≥5.0≥5.0 5.75.7 6.06.0 6.86.8 6.36.3
水分(wt%)Moisture (wt%) ≤30≤30 2929 3030 23twenty three 2626
酸碱度(pH)pH (pH) 5.5-8.55.5-8.5 5.95.9 6.26.2 6.16.1 7.27.2
表1为本发明制备的基于石墨的腐殖质性能对照表,所述有机质及总养分以烘干基进行测量,水分以鲜样进行测量,腐殖质作为有机肥料的一种,其检测标准和检测方法可参见NY525-2012有机肥料标准。Table 1 is a comparison table of graphite-based humic properties prepared by the present invention. The organic matter and total nutrients are measured by a drying base, the moisture is measured by fresh samples, and the humus is used as a kind of organic fertilizer, and the detection standard and the detection method thereof can be See NY525-2012 Organic Fertilizer Standard.
从表1中可以看出,采用本发明方法制备的腐殖质符合NY525-2012有机肥料标准,能够投入使用。同时,从实施例1-3的过程中,所述石墨废料浆料加入量提升,微生物加入量降低,但制备的腐殖质总有机质和总养分含量有所增加,表明所述石墨废料浆料能够与腐殖质原料相配合,催化发腐殖化反应的进行。As can be seen from Table 1, the humus prepared by the method of the present invention conforms to the NY525-2012 organic fertilizer standard and can be put into use. Meanwhile, in the process of Examples 1-3, the amount of the graphite waste slurry added is increased, the amount of microorganisms added is decreased, but the total organic matter and total nutrient content of the prepared humus are increased, indicating that the graphite waste slurry can be combined with The humic materials are combined to catalyze the humification reaction.
此外,经检测,本发明制备的腐殖质中总氮、磷、钾、蛔虫卵死亡率及重金属含量均满足NY525-2012有机肥料标准。In addition, the total nitrogen, phosphorus, potassium, aphid egg mortality and heavy metal content of the humus prepared by the invention are all tested to meet the NY525-2012 organic fertilizer standard.
表2 本发明制备的基于石墨的腐殖质收益表Table 2 Graphite-based humus yield table prepared by the present invention
  空白例Blank example 实施例1Example 1
产量比较Yield comparison 54质量份54 parts by mass 60质量份60 parts by mass
产值比较Comparison of output value 11 1.111.11
表3为本发明制备的基于石墨的腐殖质收益表,结合表1-2及实施例的内容可以看出,实施例1与空白例投入的原料成本和时间成本相近,但二者制备的腐殖质的产量不同,可以明显看出,对比例1中腐殖质的产量是空白例中的1.11倍,也就是在相同通入的情况下,在发酵原料中添加适量的石墨肥料浆料能够将产量提高11%,有效提高产值,有利于进一步降低所述腐殖质的单位重量的价格,促进其推广应用。综上所述,本申请公开了一种基于石墨的腐殖质的制备方法,所述方法包括:分别提供腐殖质原料和石墨废料浆料,所述腐殖质原料是指能够发生腐殖化反应生成腐殖质的原始材料;按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应,以获得所述腐殖质。通过上述方式,本申请能够将石墨经加工后产生的石墨废料浆料回收利用,避免了资源浪费;同时,所述石墨废料浆料能够与所述腐殖质原料配合,以更低的成本制备腐殖质,有利于所述腐殖质的推广应用。Table 3 is a graphite-based humus yield table prepared by the present invention. It can be seen from the contents of Table 1-2 and the examples that the raw material cost and time cost of the example 1 and the blank example are similar, but the humus prepared by the two is similar. Different yields, it can be clearly seen that the yield of humus in Comparative Example 1 is 1.11 times that in the blank case, that is, in the case of the same access, adding an appropriate amount of graphite fertilizer slurry to the fermentation raw material can increase the yield by 11%. Effectively increasing the output value is beneficial to further reducing the price per unit weight of the humus and promoting its promotion and application. In summary, the present application discloses a method for preparing a humus based on graphite, the method comprising: providing a humus raw material and a graphite waste slurry respectively, wherein the humus raw material refers to a raw material capable of humification reaction to form humus a material; mixing the humus raw material and the graphite scrap slurry according to a humification reaction and performing a humification reaction to obtain the humus. In the above manner, the present application can recycle the graphite waste slurry produced by processing the graphite, thereby avoiding waste of resources; at the same time, the graphite waste slurry can be combined with the humus raw material to prepare humus at a lower cost. Conducive to the promotion and application of the humus.
以上所述仅为本申请的实施方式,并非因此限制本申请的专利范围,凡是利用本申请说明书及附图内容所作的等效结构或等效流程变换,或直接或间接运用在其他相关的技术领域,均同理包括在本申请的专利保护范围内。The above description is only the embodiment of the present application, and thus does not limit the scope of the patent application, and the equivalent structure or equivalent process transformation of the specification and the drawings of the present application, or directly or indirectly applied to other related technologies. The fields are all included in the scope of patent protection of this application.

Claims (14)

  1. 一种基于石墨的腐殖质的制备方法,其特征在于,所述方法包括:A method for preparing a humus based on graphite, characterized in that the method comprises:
    分别提供腐殖质原料和石墨废料浆料,所述腐殖质原料是指能够发生腐殖化反应生成腐殖质的原始材料;Providing a humus raw material and a graphite waste slurry respectively, the humus raw material being a raw material capable of undergoing humification reaction to form humus;
    按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应,以获得所述腐殖质。The humus raw material and the graphite scrap slurry are mixed and subjected to a humification reaction in accordance with the requirements of the humification reaction to obtain the humus.
  2. 根据权利要求1所述的方法,其特征在于,所述石墨废料浆料为石墨经加工后的废料的浆料。The method of claim 1 wherein said graphite scrap slurry is a slurry of graphite processed waste.
  3. 根据权利要求2所述的方法,其特征在于,所述按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应之前,包括:The method according to claim 2, wherein the mixing of the humus raw material and the graphite waste slurry and the humification reaction according to the requirements of the humification reaction comprises:
    将所述石墨废料浆料浓缩成半干石墨废料浆料。The graphite scrap slurry is concentrated into a semi-dry graphite scrap slurry.
  4. 根据权利要求1所述的方法,其特征在于,所述腐殖质原料为粉碎后的腐殖质原料。The method according to claim 1, wherein the humus raw material is a pulverized humus raw material.
  5. 根据权利要求4所述的方法,其特征在于,所述腐殖质原料为植物纤维粉、动物残体粉末、动物排泄物、工业废弃物或生活垃圾中的一种或多种;所述植物纤维粉的粒径为5-50微米。The method according to claim 4, wherein the humus raw material is one or more of plant fiber powder, animal residue powder, animal waste, industrial waste or domestic garbage; The particle size is 5-50 microns.
  6. 根据权利要求1所述的方法,其特征在于,所述按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应,包括:The method according to claim 1, wherein said humus raw material and said graphite scrap slurry are mixed and subjected to humification reaction according to the requirements of the humification reaction, comprising:
    按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合,并加入微生物进行腐殖化反应。The humus raw material and the graphite scrap slurry are mixed according to the requirements of the humification reaction, and the microorganism is added to carry out the humification reaction.
  7. 根据权利要求6所述的方法,其特征在于,所述微生物为复合微生物组合;所述复合微生物组合包括促使所述腐殖质原料腐殖化的菌群;所述复合微生物组合包括丝状真菌、纤维分解菌、酵母菌。The method according to claim 6, wherein said microorganism is a composite microorganism combination; said composite microorganism combination comprises a flora that promotes humification of said humus material; said composite microorganism combination comprises filamentous fungi, fiber Decomposing bacteria and yeast.
  8. 根据权利要求7所述的方法,其特征在于,所述腐殖质原料为不同类型的秸秆原料;根据不同用户对所述腐殖质的要求,所述不同类型的秸秆原料采 用不同的复合微生物组合和不同的石墨废料浆料进行腐殖化反应。The method according to claim 7, wherein the humus raw materials are different types of straw raw materials; according to different users' requirements for the humus, the different types of straw raw materials adopt different composite microbial combinations and different The graphite waste slurry is subjected to a humification reaction.
  9. 根据权利要求1所述的方法,其特征在于,所述腐殖质为腐殖质浆料或者腐殖质干粉。The method according to claim 1, wherein the humus is a humus slurry or a humus dry powder.
  10. 根据权利要求9所述的方法,其特征在于,所述按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应,以获得所述腐殖质,包括:The method according to claim 9, wherein said humus raw material and said graphite scrap slurry are mixed and subjected to humification reaction in accordance with a humification reaction to obtain said humus, including :
    按照腐殖化反应的要求,将所述腐殖质原料和所述石墨废料浆料混合并进行腐殖化反应;Mixing the humus raw material and the graphite scrap slurry according to the requirements of the humification reaction and performing a humification reaction;
    根据腐殖质浆料的要求,将腐殖化反应后的混合物加工成所述腐殖质浆料,或者,将腐殖化反应后的混合物进行浓缩,以获得所述腐殖质干粉。The mixture after the humification reaction is processed into the humus slurry according to the requirements of the humus slurry, or the mixture after the humification reaction is concentrated to obtain the humus dry powder.
  11. 根据权利要求1所述的方法,其特征在于,所述石墨废料浆料中氮元素的质量份数为0.25%~2.1%。The method according to claim 1, wherein the graphite scrap slurry has a mass fraction of nitrogen element of 0.25% to 2.1%.
  12. 根据权利要求1所述的方法,其特征在于,所述石墨废料浆料中磷元素的质量分数为0.6%~3.3%。The method according to claim 1, wherein the graphite scrap slurry has a mass fraction of phosphorus in the range of 0.6% to 3.3%.
  13. 根据权利要求1所述的方法,其特征在于,所述石墨废料浆料中钾元素的质量分数为0.04%~1%。The method according to claim 1, wherein the mass fraction of potassium element in the graphite scrap slurry is from 0.04% to 1%.
  14. 根据权利要求1所述的方法,其特征在于,所述石墨废料浆料中镁元素的质量分数为0.05%~1%。The method according to claim 1, wherein the graphite scrap slurry has a mass fraction of magnesium in the range of 0.05% to 1%.
PCT/CN2017/119072 2017-12-27 2017-12-27 Preparation method for graphite-based humus WO2019127121A1 (en)

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CN114032701A (en) * 2021-11-29 2022-02-11 广东省汇林包装科技集团有限公司 Preparation method and application of straw semi-pulping raw material
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