WO2019112849A1 - Rf pulsing within pulsing for semiconductor rf plasma processing - Google Patents
Rf pulsing within pulsing for semiconductor rf plasma processing Download PDFInfo
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- WO2019112849A1 WO2019112849A1 PCT/US2018/062765 US2018062765W WO2019112849A1 WO 2019112849 A1 WO2019112849 A1 WO 2019112849A1 US 2018062765 W US2018062765 W US 2018062765W WO 2019112849 A1 WO2019112849 A1 WO 2019112849A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32082—Radio frequency generated discharge
- H01J37/32128—Radio frequency generated discharge using particular waveforms, e.g. polarised waves
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32082—Radio frequency generated discharge
- H01J37/32174—Circuits specially adapted for controlling the RF discharge
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32082—Radio frequency generated discharge
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32082—Radio frequency generated discharge
- H01J37/321—Radio frequency generated discharge the radio frequency energy being inductively coupled to the plasma
- H01J37/3211—Antennas, e.g. particular shapes of coils
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32082—Radio frequency generated discharge
- H01J37/32137—Radio frequency generated discharge controlling of the discharge by modulation of energy
- H01J37/32146—Amplitude modulation, includes pulsing
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- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03K—PULSE TECHNIQUE
- H03K3/00—Circuits for generating electric pulses; Monostable, bistable or multistable circuits
- H03K3/80—Generating trains of sinusoidal oscillations
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- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03K—PULSE TECHNIQUE
- H03K4/00—Generating pulses having essentially a finite slope or stepped portions
- H03K4/92—Generating pulses having essentially a finite slope or stepped portions having a waveform comprising a portion of a sinusoid
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2237/00—Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
- H01J2237/32—Processing objects by plasma generation
- H01J2237/33—Processing objects by plasma generation characterised by the type of processing
- H01J2237/334—Etching
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- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03K—PULSE TECHNIQUE
- H03K5/00—Manipulating of pulses not covered by one of the other main groups of this subclass
- H03K5/01—Shaping pulses
- H03K5/02—Shaping pulses by amplifying
Definitions
- the present embodiments relate to a radio frequency (RF) pulsing within pulsing for semiconductor RF plasma processing.
- RF radio frequency
- a plasma system is used to perform a variety of operations on wafers.
- the plasma system includes a radio frequency (RF) generator, an RF match, and a plasma chamber.
- the RF generator is coupled to the RF match via an RF cable and the RF match is coupled to the plasma chamber.
- An RF power is provided via the RF cable and the RF match to the plasma chamber in which a wafer is processed.
- one or more gases are supplied to the plasma chamber and upon reception of the RF power, plasma is generated within the plasma chamber. During the supply of the one or more gases and the RF power, it is desirable that plasma processing of the wafer is controlled in a desirable manner.
- Embodiments of the disclosure provide systems, apparatus, methods and computer programs for radio frequency (RF) pulsing within pulsing for semiconductor RF plasma processing. It should be appreciated that the present embodiments can be implemented in numerous ways, e.g., a process, or an apparatus, or a system, or a piece of hardware, or a method, or a computer-readable medium. Several embodiments are described below.
- methods and apparatuses to enable simultaneous fast ON-OFF pulsing and slow pulsing e.g., level-to-level, or multi-level pulsing, or arbitrary waveform pulsing/modulation, with the fast ON-OFF pulsing being constantly embedded within the slow pulsing are described.
- Pulsed plasma with more than one pulsing frequency at the same time is provided.
- the simultaneous fast ON-OFF pulsing and the slow pulsing are implemented in a matchless plasma source.
- "pulsing within pulsing" is defined as the fast ON- OFF pulsing embedded within the slow pulsing.
- a radio frequency (RF) clock itself is running continuously at an RF frequency.
- the fast ON-OFF pulsing is to turn ON and OFF the RF clock at inputs of multiple gate drivers, which can be implemented with an AND gate in front of the inputs to the gate drivers.
- the slow pulsing or modulation is done by manipulating a rail voltage of an agile DC rail.
- a filter formed by an RF antenna or coil together with one or more reactive elements is a band pass filter for the RF frequency, which turns a square wave at an output of a bridge circuit into a sinusoidal waveform within a tuning range of the RF frequency or the RF clock frequency.
- the RF clock frequency is tuned in operation so that a plasma load, including the RF antenna and the one or more reactive elements, with or without plasma, appears as purely resistive to the output of the bridge circuit.
- the fast ON-OFF pulsing when applied to a transformer coupled plasma (TCP) source or an inductively coupled plasma (ICP) source produces cold plasma with low electron temperature and plasma potential and thus small angular ion energy distribution. Therefore, this reduces or prevents charging damage in isotropic etch processing.
- the fast ON-OFF pulsing when applied to the TCP or ICP source enables high aspect etching or deposition when combined with asynchronous bias RF pulsing.
- level-to-level or multi-level or arbitrary waveform pulsing achieves other improved process performances, such as, higher selectivity, higher etch rate, better uniformity, etc.
- the methods and apparatuses, described herein enables simultaneous operation of both the fast ON-OFF pulsing and the slow pulsing of level-to-level or multi-level or arbitrary waveform.
- Figure 1 shows an embodiment of a system for implementing pulsing within pulsing.
- Figure 2A illustrates an embodiment of a radio frequency (RF) clock signal.
- Figure 2B illustrates an embodiment of an ON-OFF pulsing signal having a frequency fFast pulsing ⁇
- Figure 2C illustrates an embodiment of an ON-OFF pulsed RF clock signal that is generated by performing an AND operation between the RF clock signal of Figure 2A and the ON-OFF pulsing signal of Figure 2B.
- Figure 3A is an embodiment of a graph illustrating a transient of electron temperature versus time t within a plasma chamber when a shaped waveform is generated using the ON-OFF pulsed RF clock signal.
- Figure 3B is an embodiment of a graph illustrating plasma potential versus the time t when the shaped waveform is generated using the ON-OFF pulsed RF clock signal.
- Figure 3C is an embodiment of a graph illustrating an ion density versus the time t when the shaped waveform is generated using the ON-OFF pulsed RF clock signal
- Figure 4A shows an embodiment of the RF clock signal in a normal view and in a zoom-in view.
- Figure 4B shows an embodiment of the ON-OFF pulsing signal both in a normal view and in a zoom-in view.
- Figure 4C shows an example of a multi-level pulsing waveform, which is executed in conjunction with the RF clock signal of Figure 4 A filtered by the ON-OFF pulsing signal of Figure 4B.
- Figure 4D shows an example of an arbitrary waveform, which is executed in conjunction with the RF clock signal of Figure 4A filtered by the ON-OFF pulsing signal of Figure 4B.
- Figure 5A illustrates an embodiment of an RF current in a plasma load of Figure 1 when the multi-level pulsing waveform in Figure 4C is applied.
- Figure 5B illustrates zoom-in of the RF current waveform illustrated in Figure 5A.
- Figure 5C illustrates a sinusoidal waveform, which is a zoom-in of the RF current waveform illustrated in Figure 5B.
- Figure 6 shows an embodiment of a system that includes a transformer coupled plasma (TCP) source with RF pulsing within pulsing and RF bias with RF pulsing within pulsing.
- TCP transformer coupled plasma
- Figure 7 is an example of an RF current waveform for the TCP source and an RF current waveform for the RF bias with ON-OFF asynchronous TCP-bias pulsing and multi-level TCP pulsing and arbitrary waveform bias pulsing at the same time, where ON- OFF pulsing between TCP and bias is out of phase or asynchronous.
- Figure 8A is a diagram of an embodiment of a graph to illustrate the ON-OFF pulsed RF clock signal shaped according to level-to-level pulsing.
- Figure 8B is a diagram of an embodiment of a graph to illustrate the ON-OFF pulsed RF clock signal shaped according to multi-level pulsing.
- Figure 8C is a diagram of an embodiment of a graph to illustrate the ON-OFF pulsed RF clock signal shaped according to an arbitrary waveform.
- Figure 9 is a flowchart of an embodiment of a method for generating a pulse within a pulse signal using a matchless RF source.
- Figure 10A is a diagram to illustrate pulsing-within-pulsing.
- Figure 10B is a diagram to illustrate a square wave voltage at an output of a bridge circuit.
- Figure 10C is a diagram to illustrate an RF current that is output from a bridge circuit to provide to an antenna or a plasma load.
- a radiofrequency (RF) clock signal generator is provided in addition to a fast ON-OFF pulsing frequency signal generator. Additionally, a waveform generator is provided to generate a shaping waveform. An RF clock signal that is generated by the RF clock signal generator is filtered using a pulsed signal generated by the fast ON-OFF pulsing frequency signal generator to output a filtered signal. The filtered signal is provided to a gate driver to output multiple square wave signals. The square wave signals are provided to an amplification circuit to generate an amplified square wave signal. The amplified square wave signal is then shaped using a filtered waveform. The filtered waveform is generated by filtering a direct current (DC) voltage using the shaping waveform.
- DC direct current
- the shaping waveform can be an arbitrary shaped waveform, or a multi-level waveform, or a level-to-level waveform.
- the shaping of the amplified square wave signal generates a shaped waveform.
- Higher-order harmonics of the shaped waveform is filtered by a reactive circuit to output RF power, which is provided to an electrode for processing a wafer.
- Figure 1 shows an embodiment of a system 100 for implementing a process described herein as "pulsing within pulsing".
- the system 100 includes a matchless inductively coupled plasma (ICP) source 102 having a controller, a radio frequency (RF) frequency clock 104, a fast ON-OFF pulsing frequency signal generator 106, a slow pulsing frequency signal generator 108, an AND gate 110, a gate driver 112, a half-bridge circuit 114, a direct current (DC) rail 116 that applies a DC voltage from a DC voltage source VD C , a reactive circuit 118, and another AND gate 122.
- ICP inductively coupled plasma
- An AND gate is sometimes referred to herein as a filter.
- the AND gate 122 is coupled to a drain terminal D of a field effect transistor (FET) 144A of the half-bridge circuit 114.
- a source terminal S of the FET 144A is coupled to a drain terminal D of another FET 144B of the half-bridge circuit 114 and a source terminal of the FET 144B is coupled to a ground potential.
- FET field effect transistor
- An example of the reactive circuit 118 is a variable capacitor, which is coupled to the plasma load 120 having an electrode 124, for example, an RF antenna or an RF coil.
- the RF frequency clock 104 includes an electronic oscillator that generates an RF clock signal 134, which is a digital signal or a square wave signal having a radio frequency.
- the fast ON-OFF pulsing frequency signal generator 106 includes an electronic oscillator that generates an ON-OFF pulsing signal 136, such as a digital signal or a square wave signal, having a fast ON-OFF pulsing frequency fp ast pulsing ⁇
- the fast pulsing frequency fp ast pulsing is determined based on dynamics of plasma properties during a transient from RF power ON to RF power OFF.
- ON-OFF pulsing is achieved using the AND gate 110, which performs an AND operation between the RF clock signal 134 and the ON-OFF pulsing signal 136 as inputs.
- An AND operation is an example of a filtering operation.
- the AND gate 110 outputs an ON-OFF pulsed RF clock signal 126.
- the gate driver 112 receives the ON-OFF pulsed RF clock signal 126 to output multiple square wave signals 128A and 128B.
- a gate Gl of the gate driver 112 receives the ON-OFF pulsed RF clock signal 126 and amplifies or does not amplify a magnitude of the ON-OFF pulsed RF clock signal 126 to output the square wave signal 128A. In case, the amplification is not performed, the ON-OFF pulsed RF clock signal 126 passes through the gate Gl.
- Another gate G2 of the gate driver 112 receives the ON-OFF pulsed RF clock signal 126 and inverts the ON-OFF pulsed RF clock signal 126 to output the inverted square wave signal 128B.
- Each square wave signal 128A and 128B is a digital signal or a pulsed signal. For example, each square wave signal 128A and 128B transitions between a low level and a high level.
- the square wave signals 128A and 128B are in reverse synchronization with respect to each other. To illustrate, the square wave signal 128A transitions from a low power level to a high power level. During a time interval or a time at which the square wave signal 128A transitions from the low power level to the high power level, the square wave signal 128B transitions from a high power level to a low power level.
- the reverse synchronization allows the FETs 144 A and 144B of the half-bridge circuit 114 to be turned on consecutively and to be turned off consecutively.
- the half-bridge circuit 114 is sometimes referred to herein as an amplification circuit.
- the agile DC rail 116 and the half-bridge circuit 114 generates an amplified square waveform from the square wave signals 128 A and 128B.
- the FETs 144A and 144B are consecutively operated. For example, during a time period in which or a time at which the FET 144 A is turned on, the FET 144B is turned off. Moreover, during a time period in which or a time at which the FET 144B is turned on, the FET 144A is turned off.
- the FETs 144A and 144B are not on at the same time or during the same time period.
- the FET 144A When the FET 144A is on, a current flows from the DC voltage source V DC to an output 01 of the half-bridge circuit 114 to generate a voltage at the output 01 and the FET 144B is off.
- the voltage at the output 01 is generated according to the voltage values received from the pulsing frequency signal generator 108, which includes an electronic oscillator and is sometimes referred to herein as a waveform generator.
- the FET 144B is off, there is no current flowing from the output 01 to the ground potential that is coupled to the FET 144B.
- the current flows from the output 01 to the reactive circuit 118.
- the current is pushed from the DC voltage source V DC to the capacitor reactive circuit 118 when the FET 144 A is on.
- the FET 144B when the FET 144B is on and the FET 144 A is off, the voltage that is generated at the output 01 generates a current that flows from the output 01 to the ground potential coupled to the FET 144B. The current is pulled by the ground potential from the output 01. During a time interval in which the FET 144 A is off, there is no current flowing from the DC voltage source V DC to the output 01.
- the slow pulsing frequency signal generator 108 generates a shaping waveform 138, which has an envelope that has an arbitrary shape, or a multi-level pulse shape, or a level-to-level pulse shape.
- a slow pulsing frequency of the slow pulsing frequency signal generator 108 or of the shaping waveform 138 is represented as fsi ow pulsing ⁇
- the level-to-level pulse shape transitions periodically between a low power level and a high power level.
- the multi-level pulse shape transitions periodically among three or more power levels.
- the arbitrary shape has a shape that is arbitrary and repeats periodically.
- the controller 142 controls the slow pulsing frequency signal generator 108 to generate the shaping waveform 138.
- the controller 142 provides a shape of the shaping waveform 138 to the slow pulsing frequency signal generator 108.
- the slow pulsing frequency signal generator 108 generates the shaping waveform 138 that has the shape received from the controller 142.
- a shape of a waveform is a shape of an envelope of the waveform. Examples of an envelope include a peak-to-peak magnitude or a zero-to-peak magnitude.
- the AND gate 122 filters, such as ANDs, the DC voltage provided by the DC voltage source V DC with the shaping waveform 138 to generate a filtered waveform 140, which has a magnitude that is shaped according to the shaping waveform 138.
- the filtered waveform 140 is applied to the amplified square waveform at the output 01 of the half bridge circuit 114 to shape, such as increase or decrease an envelope of, the amplified square waveform to generate a shaped waveform 130 at the output 01.
- the shaped waveform 130 is a digital waveform or a square waveform.
- the envelope of the amplified square waveform is shaped or adjusted by modifying a zero-to-peak amplitude or a peak-to-peak amplitude of the amplified square waveform.
- Examples of the shaped waveform 130 include a level-to-level shaped waveform, or a multi-level shaped waveform or an arbitrary- shaped waveform and a shape of the shaped waveform 130 matches a shape of the filtered waveform 140.
- a shape of an envelope of the shaped waveform 130 matches a shape of an envelope of the filtered waveform 140.
- the reactive circuit 118 filters out or removes higher-order harmonics of the shaped waveform 130 to output or extract a shaped sinusoidal waveform 132 having RF power, which is provided to the electrode 124 of the plasma load 120 for generating or maintaining plasma within a plasma chamber for processing a substrate.
- a magnitude of the shaped waveform 130 is a combination of magnitudes of multiple waveforms, one of which has a fundamental frequency and remaining of which have the higher-order harmonics.
- the shaped sinusoidal waveform 132 having the fundamental frequency is output.
- the shaped sinusoidal waveform 132 has an envelope with a shape that matches a shape of an envelope of the shaped waveform 130.
- a plasma chamber includes the plasma load 120. Examples of processing the substrate include depositing a material on the substrate, etching the substrate, cleaning the substrate, and sputtering the substrate.
- a shape of the shaped sinusoidal waveform 132 is defined by a shape of the filtered waveform 140. For example, an envelope of the shaped sinusoidal waveform 132 has the same shape as an envelope of the filtered waveform 140.
- pulsesing within pulsing is defined as fast pulsing embedded within slow pulsing.
- the RF clock generator 104 is running continuously at the RF frequency.
- “Fast pulsing”, in some embodiments, is to turn ON and OFF the RF clock signal 134 at the input of the gate driver 112, and the turning ON and OFF may be implemented with the AND gate 110 in front of the input of the gate driver 112.
- a filter formed by an RF plasma antenna or coil together with one or more reactive elements, such as the reactive element 118, is a band pass filter for the RF frequency, which turns a square wave at a bridge output into a sinusoidal waveform within a tuning range of the RF frequency or the RF clock frequency.
- the RF clock frequency is tuned in operation so that the plasma load 120, with or without plasma, and the one or more reactive elements, appear as purely resistive to the output 01 of the half-bridge circuit 114.
- the electrode 124 instead of the electrode 124, another electrode, such as a lower electrode or a plate embedded within a substrate support, is used and RF power of the shaped sinusoidal waveform 132 is supplied to the other electrode.
- the substrate support include a chuck.
- FIG. 2A illustrates an embodiment of the RF clock signal 134.
- the RF clock signal 134 has a higher frequency than the ON-OFF pulsing signal 136, which is illustrated in Figure 2B.
- multiple pulses of the RF clock signal 134 are generated in a time period in which one pulse of the ON-OFF pulsing signal 136 is generated.
- the RF clock signal 134 includes multiple instances 212A, 212B, and 212B of an ON state and includes multiple instances 214A and 214B of an OFF state.
- the instance 214A follows the instance 212A and the instance 212B follows the instance 214A.
- the instance 214B follows the instance 212B and the instance 212C follows the instance 214B.
- FIG. 2B illustrates an embodiment of the ON-OFF pulsing signal 136 having the frequency f Fast pulsing ⁇
- the ON-OFF pulsing signal 136 has a radio frequency lower than the frequency of the RF clock signal 134.
- an on time of a pulse of the ON- OFF pulsing signal 136 is greater than that on time of a pulse of the RF clock signal 134.
- an off time of a pulse of the ON-OFF pulsing signal 136 is greater than that an off time of a pulse of the RF clock signal 134.
- the ON-OFF pulsing signal 136 has multiple instances 210A, 210B, and 210C of an ON state and multiple instances 208 A and 208B of an OFF state.
- the instances of the ON state and the instances of the OFF state repeat periodically.
- the instance 210A is followed by the instance 208A.
- the instance 208A is followed by the instance 210B and the instance 210B is followed by the instance 208B.
- the instance 208B is followed by the instance 210C.
- FIG. 2C illustrates an embodiment of the ON-OFF pulsed RF clock that is generated by performing the AND operation.
- the pulses of the RF clock signal 134 that are between two adjacent ON pulses of the ON-OFF pulsing signal 136 are filtered out by the AND gate 110 to generate the ON-OFF pulsed RF clock signal 126.
- the ON-OFF pulsed RF clock 126 includes a train Tl of pulses of the RF clock signal 134, a train T2 of pulses of the RF clock signal 134, and a train T3 of pulses of the RF clock signal 134.
- the train Tl occurs during the instance 210A of the ON state, the train 210B occurs during the instance 210B of the ON state, and the train 210C occurs during the instance 210C of the ON state.
- the train Tl is separated from the train T2 by the instance 208A of the OFF state and the train T2 is separated from the train T3 by the instance 208B of the OFF state.
- the ON-OFF pulsed RF clock signal 126 excludes ON- OFF pulses of the RF clock signal 134. Pulses of the ON-OFF pulsed RF clock signal 126 during each instance 208A and 208B are filtered out by the AND gate 110 of Figure 1.
- Figure 3A is an embodiment of a graph illustrating a transient of electron temperature kTe within the plasma chamber versus time t when the shaped waveform 130 of Figure 1 is generated using the ON-OFF pulsed RF clock signal 126.
- the electron temperature transitions from a high state to a low state when the RF power is supplied to the plasma load 120.
- Figure 3B is an embodiment of a graph illustrating plasma potential Vp within the plasma chamber versus the time t when the shaped waveform 130 is generated using the ON-OFF pulsed RF clock signal 126.
- the plasma potential Vp transitions from a high state to a low state when the RF power is supplied to the plasma load 120.
- Figure 3C is an embodiment of a graph illustrating ion density Ni within the plasma chamber versus the time t when the shaped waveform 130 is generated using the ON- OFF pulsed RF clock signal 126.
- the time t in each Figure 3A through 3C is measured in microseconds. As illustrated in Figures 3A and 3C, it takes about 10 microseconds for electron temperature to transition from a high level to a low level during an OFF time, while the ion density remains at about 80%. So the fast ON-OFF pulsing frequency fp ast pulsing may be up to 25 kilohertz (kHz) or higher with a range from about 1 kHz to about 1 megahertz (MHz).
- kHz kilohertz
- MHz megahertz
- the plasma chamber, described herein is a conductor etch chamber used for processing a 300 millimeter wafer. This is just one example.
- the plasma chamber, described herein is a chamber used for processing wafers of other sizes. To illustrate, the plasma chamber is used to process a 200 mm wafer or 450 mm wafer or a wafer of another size.
- Angular ion energy as a function of electron temperature, quickly reaches a minimum in an OFF time of the ON-OFF pulsing signal 136.
- bias RF is asynchronously ON-OFF pulsed with TCP ON-OFF pulsing
- ions accelerated by the bias RF in the TCP OFF time have a high directionality towards a wafer to produce a desirable vertical profile for etch or a desirable bottom-up deposition for gap fill. This is how high aspect ratio etching is performed to achieve an aspect ratio of up to about 150 in a deep silicon etching (DSE) process.
- DSE deep silicon etching
- the multi-level pulsing frequency is limited by a speed of moving the DC rail 116, with a range of the frequency f si ow pulsing from about 10 hertz (Hz) to about 1 kHz.
- the speed of moving the DC rail 116 is a speed of turning on and off the FETs 144A and 144B of Figure 1. If TCP ON-OFF pulsing operates at a low pulsing frequency or has a large OFF time of the ON-OFF pulsing signal 136, etch rate is limited by a low average ion density in the OFF time.
- the fast ON-OFF pulsing frequency fp ast pulsing is embedded within slow multi-level or arbitrary waveform pulsing or level-to-level pulsing having the slow pulsing frequency fsi ow pulsing ⁇
- fast ON-OFF pulsing of the bias RF is asynchronized or out-of-phase with the fast ON-OFF pulsing of the TCP source, at the same frequency f Fast pulsing ⁇ ON-OFF pulsing is executed constantly with asynchronization between TCP and bias, while multi-level or arbitrary waveform pulsing for TCP source and bias RF run independently from each other at their own slow pulsing frequencies.
- Figure 4A shows an embodiment of the RF clock signal 134 in a normal view and in a zoom-in view.
- the RF clock signal 134 pulses at a high frequency, such as a radio frequency, between a high level and a low level.
- Figure 4B shows an embodiment of the ON-OFF pulsing signal 136 both in a normal view and in a zoom-in view.
- the ON-OFF pulsing signal 136 pulses between a high level and a low level at a frequency lower than that of the RF clock signal 134 and the frequency of the ON-OFF pulsing signal 136 is used to filter the RF clock signal 134.
- Figure 4C shows an example of a slow pulsing waveform, such as a multi level pulsing waveform 410A, which is executed simultaneously with the RF clock signal 134 of Figure 4A and the ON-OFF pulsing signal 136 of Figure 4B.
- the multi-level pulsing waveform 410A has a multi-level shaped envelope 412A and is an example of the shaping waveform 138 of Figure 1.
- the multi-level shaped envelope 412A is multi-level pulse-shaped and has multiple power levels, such as PWR1, PWR2, PWR3, and PWR4, to be applied to the DC voltage of the DC voltage source V DC ⁇
- the multiple power levels repeat periodically.
- the filtered waveform 140 having the multi-level shaped envelope 412A is output from the AND gate 122 of Figure 1.
- FIG. 4D shows an example of another slow pulsing waveform, such as an arbitrary waveform 410B, which is executed simultaneously with the RF clock signal 134 of Figure 4A and the ON-OFF pulsing signal 136 of Figure 4B.
- the arbitrary waveform 410B is has an arbitrary- shaped envelope 412B and is another example of the shaping waveform 138 of Figure 1.
- the arbitrary- shaped envelope 412B has varying magnitudes for application to the DC voltage of the DC voltage source V DC ⁇
- the filtered waveform 140 having the arbitrary-shaped envelope 412B is generated by the AND gate 122 of Figure 1.
- Figure 5 A illustrates an embodiment of an RF current waveform 501 in the plasma load 120 of Figure 1 when the multi-level pulsing waveform 410A in Figure 4C is applied.
- a section, labeled as A, in Figure 5A has multiple portions 502, 504, 506, 508, 510, 512, 514, 516, 518, and 520 of the RF current waveform 501.
- the RF current waveform 501 is generated in the plasma load 120 and is representative of the shaped sinusoidal waveform 132 of Figure 1.
- Figure 5B illustrates zoom-in of the RF current waveform 501 illustrated in Figure 5 A.
- the section A of Figure 5 A is illustrated in detail in Figure 5B.
- all the portions 502, 504, 506, 508, 510, 512, 514, 516, 518, and 520 are visible in Figure 5B in detail.
- Each portion 502, 504, 506, 508, 510, 512, 514, 516, 518, and 520 is a sinusoidal RF signal, which is illustrated in Figure 5C.
- Figure 5C illustrates a sinusoidal waveform, which is a zoom-in of the RF current waveform 501 illustrated in Figure 5B.
- Figure 5C is a zoom-in of a section labeled as B in Figure 5B.
- each portion 510 and 512 is a sinusoidal signal.
- Figure 6 shows an embodiment of a system 600 that includes combined TCP source and RF bias with RF pulsing within pulsing.
- the system 600 includes the matchless ICP source 102 of Figure 1.
- the system 600 further includes a NOT gate 623, such as an inverter, and a matchless bias source 602.
- the matchless bias source 602 includes the controller 142, an RF frequency clock 604, the fast ON-OFF pulsing frequency signal generator 106, an AND gate 610, a slow pulsing frequency signal generator 608, a gate driver 612, a half-bridge circuit 614, a DC rail 616 that is applied a DC voltage of another DC voltage source V DC , a reactive circuit 618, and an AND gate 622.
- An example of the reactive circuit 618 is an inductor, which is coupled to a plasma load 620.
- the electrode 124 is a coil or an antenna of the plasma chamber and a bias electrode 638 is a lower electrode embedded within a substrate support of the plasma chamber.
- the RF clock 604 has the same structure and function as the RF clock 104.
- the gate driver 612 has the same structure and function as the gate driver 112 and the agile DC rail 616 has the same structure and function as the agile DC rail 116.
- the slow pulsing frequency signal generator 608 has the same structure and function as the slow pulsing frequency signal generator 108.
- the slow pulsing frequency signal generator 608 operates independently of the slow pulsing frequency generator 108. For example, the slow pulsing frequency signal generator 608 generates an arbitrary shape waveform and simultaneously, the slow pulsing frequency signal generator 108 generates a multi-level shape waveform.
- the RF clock 604 generates an RF clock signal 622.
- the NOT gate 623 inverts the ON-OFF pulsing signal 136 to output an inverted ON-OFF pulsing signal 624. For example, during a time interval in which the ON-OFF pulsing signal 136 has an ON state, the inverted ON-OFF pulsing signal 624 has an OFF state and during a time interval in which the ON-OFF pulsing signal 136 has an OFF state, the inverted ON-OFF pulsing signal 624 has an ON state.
- the AND gate 610 filters the RF clock signal 622 with the inverted ON-OFF pulsing signal 624 to output an ON-OFF pulsed RF clock signal 626.
- the ON-OFF pulsed RF clock signal 626 has an OFF state or a low power level and during the time period in which the ON-OFF pulsed RF clock signal 126 has an OFF state or a low power level, the ON-OFF pulsed RF clock signal 626 has an ON state or a high power level.
- Multiple instances of the ON state of the ON-OFF pulsed RF clock signal 626 has a train of ON-OFF pulses of the RF clock signal 622 with no pulses of the RF clock signal 622 during multiple instance of the OFF state of the ON-OFF pulsed RF clock signal 626.
- a gate G3 of the gate driver 612 receives the ON-OFF pulsed RF clock signal 626 and amplifies or does not amplify the ON-OFF pulsed RF clock signal 626 to output a square wave signal 628A.
- the ON-OFF pulsed RF clock signal 626 passes through the gate G3 and is output as the square wave signal 628A.
- a gate G4 of the gate driver 612 receives the ON-OFF pulsed RF clock signal 626 and inverts the ON-OFF pulsed RF clock signal 626 to output a square wave signal 628B.
- the square wave signal 628B is reversely synchronized compared to the square wave signal 628A.
- the half-bridge circuit 614 receives the square wave signals 628A and 628B and generates an amplified square waveform from the square wave signals 628A and 628B.
- the slow pulsing frequency signal generator 608 generates a shaping waveform 630, which has an envelope that has an arbitrary shape, or a multi-level pulse shape, or a level-to-level pulse shape.
- the controller 142 controls the slow pulsing frequency signal generator 608 to generate the shaping waveform 630.
- the controller 142 provides a shape of the shaping waveform 630 to the slow pulsing frequency signal generator 608.
- the shape of the shaping waveform 630 can be different from or the same as the shape of the shaping waveform 138.
- the slow pulsing frequency signal generator 608 generates the shaping waveform 630 that has the shape received from the controller 142.
- the AND gate 622 filters, such as ANDs, the DC voltage provided by the DC voltage source V DC of the matchless bias source 602 with the shaping waveform 630 to generate a filtered waveform 632, which has its magnitude shaped according to the shaping waveform 630.
- the filtered waveform 632 has an envelope of a shape that is the same as a shape of an envelope of the shaping waveform 630.
- the filtered waveform 632 is applied to the amplified square waveform at an output 02 of the half-bridge circuit 614 to shape, such as increase or decrease an envelope of, the amplified square waveform of the matchless bias source 602 to generate a shaped waveform 634 at the output 02.
- the shaped waveform 634 is a digital waveform or a square waveform.
- the envelope of the amplified square waveform generated within the matchless bias source 602 is adjusted by modifying a zero-to-peak amplitude or a peak-to-peak amplitude of the amplified square waveform.
- the shaped waveform 634 include a level-to-level shaped waveform, or a multi-level shaped waveform, or an arbitrary-shaped waveform and a shape of the shaped waveform 634 matches a shape of the filtered waveform 632.
- a shape of an envelope of the shaped waveform 634 matches a shape of an envelope of the filtered waveform 632.
- the reactive circuit 618 filters out or removes higher-order harmonics of the shaped waveform 634 to output or extract a shaped sinusoidal waveform 636 having RF power.
- the RF power of the shaped sinusoidal waveform 636 is provided to the bias electrode 638 of the plasma load 620 for generating or maintaining plasma within the plasma chamber to process a substrate supported on the substrate support of the plasma chamber.
- a magnitude of the shaped waveform 634 is a combination of magnitudes of multiple waveforms, one of which has a fundamental frequency and remaining of which have the higher-order harmonics. By filtering out the higher-order harmonics, the shaped sinusoidal waveform 636 having the fundamental frequency is output.
- the shaped sinusoidal waveform 636 has an envelope with a shape that matches a shape of an envelope of the shaped waveform 634.
- a shape of the shaped sinusoidal waveform 636 is defined by a shape of the filtered waveform 632.
- an envelope of the shaped sinusoidal waveform 636 has the same shape as an envelope of the filtered waveform 632.
- the matchless ICP source 102 supplies the shaped sinusoidal waveform 132 with RF pulsing within pulsing to the plasma load 120 of the plasma chamber and the matchless bias source 602 supplies the shaped sinusoidal waveform 636 with RF pulsing within pulsing to the plasma load 620 of the plasma chamber.
- the shaped sinusoidal waveform 636 is reversely synchronized compared to the shaped sinusoidal waveform 132.
- the shaped sinusoidal waveform 636 has a low power level and at a time or during a time period in which the shaped sinusoidal waveform 132 has a low power level, the shaped sinusoidal waveform 636 has a high power level.
- one or more capacitors are used as a reactive circuit.
- one or more inductors are used as a reactive circuit.
- a phase shifter is used to shift a phase of the ON-OFF pulsing signal 136 to output an ON-OFF pulsing signal that is provided to the AND gate 610.
- Figure 7 is an example of the RF current waveform 501 for the TCP source and an RF current waveform 704 for the RF bias with ON-OFF asynchronous TCP-bias pulsing and multi-level TCP pulsing and arbitrary waveform bias pulsing at the same time, where ON-OFF pulsing between TCP and bias is out of phase or asynchronous.
- the slow pulsing frequency signal generator 108 generates a multi-level pulse shaping waveform to provide the RF current waveform 501 to the plasma load 120 and the slow pulsing frequency signal generator 608 generates an arbitrary-shaped shaping waveform to provide the RF current waveform 704 to the plasma load 620.
- the ON-OFF pulsing between TCP and bias is in phase.
- Figure 8A is a diagram of an embodiment of a graph to illustrate a shaped waveform 802 that is applied to a plasma load, such as the plasma load 120 of Figure 6 or the plasma load 620 of Figure 6.
- the shaped waveform 802 is an example of the shaped waveform 130 generated at the output 01 of the half-bridge circuit 114 of Figure 6 or of the shaped waveform 634 generated at the output 02 of the half-bridge circuit 614 of Figure 6.
- the graph of Figure 8A plots a magnitude or an amplitude of the shaped waveform 802 over the time t.
- the shaped waveform 802 is generated based on the RF clock signal 134 and a shaping waveform 804.
- the shaping waveform 804 is an example of the shaping waveform 138 generated by the slow pulsing frequency signal generator 108 or of a shaping waveform generated by the slow pulsing frequency signal generator 608 of Figure 6.
- the shaped waveform 802 is generated when a slow pulsing frequency signal generator, such as the slow pulsing frequency signal generator 108 or 608, applies level-to-level pulsing to the RF clock signal 134.
- the shaped waveform 802 periodically transitions between a low power level and a high power level.
- Figure 8B is a diagram of an embodiment of a graph to illustrate a shaped waveform 810 that is applied to the plasma load 120 of Figure 6 or the plasma load 620 of Figure 6.
- the shaped waveform 810 is another example of the shaped waveform 130 generated at the output 01 of the half-bridge circuit 114 of Figure 6 or of the shaped waveform 634 generated at the output 02 of the half-bridge circuit 614 of Figure 6.
- the graph of Figure 8B plots a magnitude of the shaped waveform 810 over the time t.
- the shaped waveform 810 is generated based on the RF clock signal 134 and a shaping waveform 812, which is an example of the shaping waveform 138 generated by the slow pulsing frequency signal generator 108 or of a shaping waveform generated by the slow pulsing frequency signal generator 608 of Figure 6.
- the shaped waveform 810 is generated when the slow pulsing frequency signal generator 108 or 608 applies multi-level pulsing to the RF clock signal 134.
- Figure 8C is a diagram of an embodiment of a graph to illustrate a shaped waveform 820 that is supplied to the plasma load 120 of Figure 6 or the plasma load 620 of Figure 6.
- the shaped waveform 820 is yet another example of the shaped waveform 130 generated at the output 01 of the half-bridge circuit 114 of Figure 6 or of the shaped waveform 634 generated at the output 02 of the half-bridge circuit 614 of Figure 6.
- the graph of Figure 8C plots a magnitude of the shaped waveform 820 versus the time t.
- the shaped waveform 820 is generated based on the RF clock signal 134 and a shaping waveform 822, which is an example of the shaping waveform 138 generated by the slow pulsing frequency signal generator 108 or of a shaping waveform generated by the slow pulsing frequency signal generator 608 of Figure 6.
- the shaped waveform 820 is generated when the slow pulsing frequency signal generator 108 or 608 applies arbitrary-shaped pulsing to the RF clock signal 134.
- FIG. 9 is a flowchart of an embodiment of a method 900 to illustrate generation of an RF waveform that is applied to a plasma load, such as the plasma load 120 or 620 of Figure 6.
- the method 900 includes an operation 902 of defining an ON-OFF pulsed RF clock, such as the ON-OFF pulsed RF clock 126 or 626 of Figure 6.
- the ON-OFF pulsed RF clock has a train of ON-OFF pulses separated by an OFF state having no ON-OFF pulses.
- the method 900 further includes an operation 902 of applying a shaping waveform, such as the shaping waveform 138 or 630 ( Figure 6), which adjusts a magnitude of the ON-OFF pulsed RF clock to generate a shaped sinusoidal waveform.
- the shaped sinusoidal waveform can be the shaped sinusoidal waveform 132 or 636 illustrated in Figure 6.
- the method 900 includes an operation 904 of sending the shaped sinusoidal waveform to an electrode of a plasma load, such as the plasma load 120 or 620 of Figure 6.
- Figure 10A is a diagram of an embodiment of a graph 1000 that plots a slow pulsing signal 1006 versus the time t, a fast pulsing signal 1008 versus the time t, and the RF clock signal 134 versus the time t.
- the slow pulsing signal 1006 is an example of the shaping waveform 138 or 630 of Figure 6 and the fast pulsing signal 1008 is an example of the ON- OFF pulsing signal 136 of Figure 6.
- Figure 10A illustrates a multi-level pulsing for the slow pulsing signal 1006, with simultaneous fast ON-OFF pulsing.
- Figure 10B is a diagram of an embodiment of a graph 1002 that plots a square wave voltage 1012 at the output 01 of the half-bridge circuit 114 of Figure 1 versus the time t.
- the square wave voltage 1012 is an example of the shaped waveform 130 provided at the output 01.
- Figure 10C is a diagram of an embodiment of a graph 1004 that plots an RF current 1014 in a sinusoidal waveform output from the half-bridge circuit 114 of Figure 1.
- the RF current 1014 is provided to the electrode 124 of Figure 1 or the plasma load 120 of Figure 1.
- the RF current 1014 is an example of the shaped sinusoidal waveform 132 of Figure 1.
- Embodiments, described herein may be practiced with various computer system configurations including hand-held hardware units, microprocessor systems, microprocessor-based or programmable consumer electronics, minicomputers, mainframe computers and the like.
- the embodiments, described herein can also be practiced in distributed computing environments where tasks are performed by remote processing hardware units that are linked through a computer network.
- a controller e.g., a host computer, etc. is part of a system, which may be part of the above-described examples.
- the system includes semiconductor processing equipment, including a processing tool or tools, chamber or chambers, a platform or platforms for processing, and/or specific processing components (a wafer pedestal, a gas flow system, etc.).
- the system is integrated with electronics for controlling its operation before, during, and after processing of a semiconductor wafer or substrate.
- the electronics is referred to as the“controller,” which may control various components or subparts of the system.
- the controller is programmed to control any process disclosed herein, including a delivery of process gases, temperature settings (e.g., heating and/or cooling), pressure settings, vacuum settings, power settings, RF generator settings, RF matching circuit settings, frequency settings, flow rate settings, fluid delivery settings, positional and operation settings, wafer transfers into and out of a tool and other transfer tools and/or load locks connected to or interfaced with the system.
- temperature settings e.g., heating and/or cooling
- pressure settings e.g., vacuum settings, power settings, RF generator settings, RF matching circuit settings, frequency settings, flow rate settings, fluid delivery settings, positional and operation settings
- wafer transfers into and out of a tool and other transfer tools and/or load locks connected to or interfaced with the system e.g., temperature settings (e.g., heating and/or cooling), pressure settings, vacuum settings, power settings, RF generator settings, RF matching circuit settings, frequency settings, flow rate settings, fluid delivery settings, positional and operation settings, wafer transfers into and out of a tool
- the controller is defined as electronics having various integrated circuits, logic, memory, and/or software that receive instructions, issue instructions, control operation, enable cleaning operations, enable endpoint measurements, and the like.
- the integrated circuits include chips in the form of firmware that store program instructions, digital signal processors (DSPs), chips defined as Application Specific Integrated Circuits (ASICs), programmable logic devices (PLDs), one or more microprocessors, or microcontrollers that execute program instructions (e.g., software).
- the program instructions are instructions communicated to the controller in the form of various individual settings (or program files), defining operational parameters for carrying out a process on or for a semiconductor wafer.
- the operational parameters are, in some embodiments, a part of a recipe defined by process engineers to accomplish one or more processing steps during the fabrication of one or more layers, materials, metals, oxides, silicon, silicon dioxide, surfaces, circuits, and/or dies of a wafer.
- the controller in some embodiments, is a part of or coupled to a computer that is integrated with, coupled to the system, otherwise networked to the system, or a combination thereof.
- the controller is in a“cloud” or all or a part of a fab host computer system, which allows for remote access for wafer processing.
- the controller enables remote access to the system to monitor current progress of fabrication operations, examines a history of past fabrication operations, examines trends or performance metrics from a plurality of fabrication operations, to change parameters of current processing, to set processing steps to follow a current processing, or to start a new process.
- a remote computer (e.g. a server) provides process recipes to the system over a computer network, which includes a local network or the Internet.
- the remote computer includes a user interface that enables entry or programming of parameters and/or settings, which are then communicated to the system from the remote computer.
- the controller receives instructions in the form of settings for processing a wafer. It should be understood that the settings are specific to a type of process to be performed on a wafer and a type of tool that the controller interfaces with or controls.
- the controller is distributed, such as by including one or more discrete controllers that are networked together and working towards a common purpose, such as the fulfilling processes described herein.
- An example of a distributed controller for such purposes includes one or more integrated circuits on a chamber in communication with one or more integrated circuits located remotely (such as at a platform level or as part of a remote computer) that combine to control a process in a chamber.
- the system includes a plasma etch chamber, a deposition chamber, a spin-rinse chamber, a metal plating chamber, a clean chamber, a bevel edge etch chamber, a physical vapor deposition (PVD) chamber, a chemical vapor deposition (CVD) chamber, an atomic layer deposition (ALD) chamber, an atomic layer etch (ALE) chamber, an ion implantation chamber, and any other semiconductor processing chamber that is associated or used in fabrication and/or manufacturing of semiconductor wafers.
- PVD physical vapor deposition
- CVD chemical vapor deposition
- ALD atomic layer deposition
- ALE atomic layer etch
- ion implantation chamber any other semiconductor processing chamber that is associated or used in fabrication and/or manufacturing of semiconductor wafers.
- TCP transformer coupled plasma
- the above-described operations apply to other types of plasma chambers, e.g., conductor tools, a dielectric etch chamber, an ion implantation chamber, a chamber having a showerhead, etc.
- the controller communicates with one or more of other tool circuits or modules, other tool components, cluster tools, other tool interfaces, adjacent tools, neighboring tools, tools located throughout a factory, a main computer, another controller, or tools used in material transport that bring containers of wafers to and from tool locations and/or load ports in a semiconductor manufacturing factory.
- Some of the embodiments also relate to a hardware unit or an apparatus for performing these operations.
- the apparatus is specially constructed for a special purpose computer.
- the computer When defined as a special purpose computer, the computer performs other processing, program execution or routines that are not part of the special purpose, while still being capable of operating for the special purpose.
- the operations, described herein, are performed by a computer selectively activated, or are configured by one or more computer programs stored in a computer memory, or are obtained over a computer network.
- the data may be processed by other computers on the computer network, e.g., a cloud of computing resources.
- Non-transitory computer-readable medium is any data storage hardware unit, e.g., a memory device, etc., that stores data, which is thereafter read by a computer system.
- Examples of the non- transitory computer-readable medium include hard drives, network attached storage (NAS), ROM, RAM, compact disc-ROMs (CD-ROMs), CD-recordables (CD-Rs), CD-rewritables (CD-RWs), magnetic tapes and other optical and non-optical data storage hardware units.
- the non-transitory computer-readable medium includes a computer- readable tangible medium distributed over a network-coupled computer system so that the computer-readable code is stored and executed in a distributed fashion.
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Abstract
Description
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Priority Applications (13)
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| CN202410906942.XA CN119030506A (en) | 2017-12-07 | 2018-11-28 | RF pulses within pulses for semiconductor RF plasma processing |
| CN201880078948.5A CN111434039B (en) | 2017-12-07 | 2018-11-28 | In-pulse RF pulses for semiconductor RF plasma processing |
| KR1020247001439A KR102730398B1 (en) | 2017-12-07 | 2018-11-28 | Rf pulsing within pulsing for semiconductor rf plasma processing |
| US16/888,613 US11342159B2 (en) | 2017-12-07 | 2018-11-28 | RF pulsing within pulsing for semiconductor RF plasma processing |
| KR1020207019533A KR102626357B1 (en) | 2017-12-07 | 2018-11-28 | RF Pulsing within Pulsing for Semiconductor RF Plasma Processing |
| JP2020529679A JP7296962B2 (en) | 2017-12-07 | 2018-11-28 | RF pulse within a pulse for semiconductor RF plasma processing |
| KR1020247037538A KR20240163199A (en) | 2017-12-07 | 2018-11-28 | Rf pulsing within pulsing for semiconductor rf plasma processing |
| US17/729,451 US11728136B2 (en) | 2017-12-07 | 2022-04-26 | RF pulsing within pulsing for semiconductor RF plasma processing |
| JP2023096641A JP7515661B2 (en) | 2017-12-07 | 2023-06-13 | RF pulses within pulses for semiconductor RF plasma processing - Patents.com |
| US18/348,320 US12424410B2 (en) | 2017-12-07 | 2023-07-06 | RF pulsing within pulsing for semiconductor RF plasma processing |
| JP2024106537A JP7792995B2 (en) | 2017-12-07 | 2024-07-02 | RF pulses within pulses for semiconductor RF plasma processing |
| US19/313,650 US20250391638A1 (en) | 2017-12-07 | 2025-08-28 | Rf pulsing within pulsing for semiconductor rf plasma processing |
| JP2025251066A JP2026053443A (en) | 2017-12-07 | 2025-12-16 | RF pulses in pulses for semiconductor RF plasma processing |
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| US17/729,451 Continuation US11728136B2 (en) | 2017-12-07 | 2022-04-26 | RF pulsing within pulsing for semiconductor RF plasma processing |
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| KR20200086751A (en) | 2020-07-17 |
| JP2021508413A (en) | 2021-03-04 |
| JP7296962B2 (en) | 2023-06-23 |
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| US20200335305A1 (en) | 2020-10-22 |
| JP2023116656A (en) | 2023-08-22 |
| KR20240163199A (en) | 2024-11-18 |
| JP2026053443A (en) | 2026-03-25 |
| TW201935517A (en) | 2019-09-01 |
| JP2024138325A (en) | 2024-10-08 |
| US20220254608A1 (en) | 2022-08-11 |
| CN111434039A (en) | 2020-07-17 |
| US11342159B2 (en) | 2022-05-24 |
| TW202449845A (en) | 2024-12-16 |
| CN119030506A (en) | 2024-11-26 |
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