WO2019045365A1

WO2019045365A1 - Pouch type secondary battery including heat transfer member

Info

Publication number: WO2019045365A1
Application number: PCT/KR2018/009752
Authority: WO
Inventors: 문재원; 한형석; 유형균; 팽기훈
Original assignee: 주식회사 엘지화학
Priority date: 2017-08-29
Filing date: 2018-08-23
Publication date: 2019-03-07

Abstract

The present invention relates to a pouch type secondary battery comprising a laminate sheet for receiving an electrode assembly and an electrolyte, wherein the laminate sheet has a structure including an outer coating layer, a metal layer, and an inner adhesive layer, and includes a heat transfer member for connecting the electrode assembly to the metal layer of the laminate sheet.

Description

A pouch type secondary battery including a heat transfer member

This application claims priority from Korean Patent Application No. 2017-0109714, filed on August 29, 2017, the entire contents of which are incorporated herein by reference.

The present invention relates to a pouch type secondary battery including a heat transfer member and, in the case of using a battery case made of a laminate sheet, in order to enhance heat dissipation of the secondary battery without adding a separate cooling member, And a heat transfer member for connecting the pouch type secondary battery to the pouch type secondary battery.

The rechargeable secondary battery is an electric vehicle (EV), a hybrid electric vehicle (HEV), a plug-in electric vehicle (HEV) and the like, which are proposed as solutions for the air pollution of existing gasoline vehicles and diesel vehicles using fossil fuels Hybrid electric vehicles (Plug-In HEVs) and the like, and are attracting attention as a power source for devices requiring high output large capacity.

The secondary battery can be classified into a cylindrical battery cell, a prismatic battery cell, and a pouch-shaped battery cell depending on its shape. Among them, a pouch-type battery cell which can be stacked with a high degree of integration, has a high energy density per unit weight, and is inexpensive and easy to deform is attracting much attention.

The pouch-shaped battery cell means a battery cell having a battery case made of a laminate sheet, and an electrode assembly is built in the battery case.

In general, one of the main tasks of pouch-type batteries with a flexible shell is to improve safety. Lithium rechargeable batteries are subject to high temperatures and high pressures within the battery, which can be caused by abnormal operating conditions of the battery, such as internal short circuits, overcharged conditions exceeding the permissible current and voltage, exposure to high temperatures, dropping, Explosion of the battery may be caused.

Therefore, a method of increasing the heat capacity by using a thick current collector can be used. However, since the thickness of the current collector is increased, the thickness of the electrode assembly as a whole increases, which makes it difficult to design a high capacity battery cell. Alternatively, a method of preventing the temperature from increasing by adding a cooling pipe or module to the pouch-shaped battery case can be used. However, the cost of introducing a new cooling system is increased, and the size of the cooling system Therefore, it is necessary to redesign the application position and arrangement.

On the other hand, in the case of an abnormal operating state of the secondary battery, a method of shutting off the current flow can be used. However, if the temperature rises above a certain threshold, it is difficult to prevent ignition or explosion.

In addition, Korean Patent Registration No. 1697764 discloses a graphite structure; And at least one selected from the group consisting of low viscosity monomers, oligomers, resins, and combinations thereof impregnated in the graphite structure, to form a composite composite material.

Although the above-described technique discloses a material having high heat dissipation, there is a problem that there is no recognition for application to a pouch-type secondary battery, and there is a concern that the polymer composite material may react with an electrolyte solution inside the battery case.

As another prior art, Korean Patent Laid-Open Publication No. 2016-0040167 discloses a battery pack including a connection member to which dissimilar metals having different melting points are coupled, and Korean Patent Publication No. 1520168 discloses a battery pack having a clad structure Japanese Unexamined Patent Application Publication No. 2000-030975 discloses a lithium secondary battery including a structure in which a heat dissipating member is connected to a core of a metallic composite material in which ceramic particles or filler ceramic fibers or ceramic fibers are dispersed in a matrix metal However, a method for increasing the heat dissipation performance of the secondary battery is not provided.

Accordingly, there is a high need for a technique that can enhance the safety by discharging the heat inside the secondary battery without adhering additional equipment to the outside of the pouch type secondary battery while minimizing the influence on the increase in thickness of the battery cell.

The present invention has been made to solve the above-mentioned problems of the related art and a technical problem which has been demanded from the past, in a pouch type secondary battery comprising a battery case of a laminate sheet including a metal layer and a resin layer, The pouch type secondary battery can be provided with a high heat dissipation capability because the heat generated from the electrode assembly can be rapidly discharged toward the laminate sheet through the heat transfer member.

In addition, since the heat generated in normal use such as charging and discharging of the secondary battery is rapidly discharged, the lifetime of the battery can be improved and occurrence of a high temperature phenomenon due to abnormal use of the secondary battery can be prevented. It is possible to provide a secondary battery having improved safety by preventing explosion.

According to an aspect of the present invention, there is provided a pouch-

A pouch-type secondary battery comprising an electrode assembly and a laminate sheet containing an electrolyte,

Wherein the laminate sheet has a structure including an outer coating layer, a metal layer, and an inner adhesive layer,

And a heat transfer member for connecting the electrode assembly and the metal layer of the laminate sheet.

That is, a heat transfer member is positioned between the electrode assembly and the laminate sheet for the battery case, and the heat transfer member connects the electrode assembly and the metal layer of the laminate sheet. Thermal energy generated from the electrode assembly can be rapidly discharged through the metal layer of the laminate sheet have.

As described above, according to the present invention, an electrode current collector having a general thickness is used, and a thick metal plate is conventionally used as an electrode current collector, thereby preventing an increase in thickness of the entire electrode assembly. In addition, since the heat transfer member is disposed between the electrode assembly and the battery case, the size of the secondary battery can be reduced as compared with a case where a cooling member is additionally provided outside the battery case, The cost of adding the cooling member can be reduced.

In one specific example, the heat transfer member has a structure in which the electrode assembly and the metal layer of the laminate sheet are connected to each other. Even if the laminate sheet and the electrode assembly are closely arranged with the heat transfer member interposed therebetween, Since the inner adhesive layer of the laminate sheet is located between the assemblies, the electrode assembly and the metal layer of the laminate sheet are not directly connected.

The heat transfer member may be configured to include a protruding structure penetrating the inner adhesive layer of the laminate sheet in order to make the structure of the electrode assembly directly communicate with the metal layer of the laminate sheet.

The heat transfer member positioned between the electrode assembly and the laminate sheet may have a structure attached to the laminate sheet so as to contact the outermost electrode of the electrode assembly.

For example, when manufacturing a laminate sheet, a heat transfer member is placed on the outer surface of the inner adhesive layer and then laminated so that at least a part of the heat transfer member can contact the metal layer of the laminate sheet, and the heat transfer member and the laminate sheet are integrated .

When the battery case is sealed with the heat transfer member positioned on the surface of the electrode assembly after the electrode assembly is housed in the battery case, the height of the electrode assembly receiving portion, the height of the electrode assembly, and the height of the heat transfer member, May be configured to contact a metal layer. At this time, in the sealing step, the heat transfer member and the metal layer can be connected through the degassing process even if they are not connected to a part of the heat transfer member and the metal layer.

Generally, an electrode assembly having a structure in which a separator is interposed between an anode and a cathode is not coated with an electrode active material on the outer surface of the outermost electrode, so that the uncoated surface of the electrode active material is positioned on the outermost side of the electrode assembly , And when the heat transfer member is positioned between the laminate sheet and the electrode assembly, the heat transfer member may be in contact with the uncoated surface of the outermost electrode of the electrode assembly.

The heat transfer member may include a flat plate-like body and a protrusion extending in a vertical direction on one surface of the flat plate-like body, wherein the flat plate-like body is positioned between the inner adhesive layer of the laminate sheet and the outermost electrode of the electrode assembly, The projecting portion may have a structure penetrating the inner adhesive layer.

In one specific example, the heat transfer member may have a protruding structure extending in the vertical direction at the outer surface of the outermost electrode of the electrode assembly, and an end of the protruding structure may be connected to the metal layer of the laminate sheet.

The protruding structure may be a structure combined with the outermost electrode of the electrode assembly, and may be a combination of the electrode and the heat transfer member.

Alternatively, the protruding structure may be a structure separable from the outermost electrode of the electrode assembly, and may be positioned in a plane orthogonal to the plane of the outermost electrode and the metal layer of the laminate sheet. It may be a needle-pillar structure.

The projecting structure may have a structure in which a plurality of projections are uniformly formed at regular intervals. Considering the efficiency for rapidly moving the thermal energy of the electrode assembly toward the laminate sheet, a plurality of projections may be formed, It is preferable that the protruding structures are formed at regular intervals in order to uniformly deliver the electrode assembly to the entire outer surface of the electrode assembly.

The projecting structure connects the electrode assembly and the metal layer of the laminate sheet through the inner adhesive layer of the laminate sheet. The height of the projecting structure may be 100% to 120% based on the thickness of the inner adhesive layer of the laminate sheet. And preferably from 110% to 120%.

When the height of the protruding structure is less than 100% of the thickness of the inner adhesive layer of the laminate sheet, the electrode assembly is not connected to the metal layer of the laminate sheet. When the height is more than 120%, the electrode assembly is separated from the laminate sheet The space is widened to widen unnecessarily wasted space, and the problem of lowering the heat dissipation effect may occur, which is not preferable.

Specifically, in consideration of the fact that the height of the inner adhesive layer of the laminate sheet is generally 20 μm to 100 μm, the height of the protruding structure may be in the range of 20 μm to 140 μm, preferably in the range of 22 μm to 120 μm Lt; / RTI >

When the height of the protruding structure is less than 20 μm, the electrode assembly is not connected to the metal layer of the laminate sheet. If the height is larger than 120 μm, the space between the electrode assembly and the laminate sheet is widened and unnecessarily wasted It is not preferable because space is increased.

It is preferable that the electrode assembly has a structure in which a separator is interposed between the positive electrode and the negative electrode to laminate the electrode assembly. For example, The assembly may be a stacked electrode assembly, a stacked / folded electrode assembly, or a lamination / stacked electrode assembly, or a structure in which one or more of the electrode assemblies are stacked.

When each of the stacked electrode assembly, the stacked / folded electrode assembly, and the lamination / stacked electrode assembly is a unit cell, the planar size of the unit cells may be the same. However, The cells may be stacked.

According to another aspect of the present invention, there is provided a pouch-type secondary battery having a structure in which an outermost electrode of an electrode assembly and a metal layer of a battery case are connected to each other. When the upper case and the lower case of the battery case are heat- Considering that contact between metal layers of each case can be made, in order to prevent a short circuit of the secondary battery, the outermost electrodes of the electrode assembly may be composed of the same electrode.

Alternatively, when only one of the outermost electrodes of the electrode assembly is connected to the metal layer of the battery case, it is of course possible that the outermost electrodes of the electrode assembly are made of different electrodes.

The heat transfer member is a member for quickly discharging heat energy inside the battery cell to the outside of the battery cell, and the heat transfer member is preferably made of a metal having high thermal conductivity.

For example, the heat transfer member may be a member made of aluminum (Al), copper (Cu), silver (Ag), gold (Au), nickel (Ni), tungsten (W), carbon (C) , And may be composed of aluminum or copper.

The present invention can also provide a battery pack including the pouch type secondary battery.

Specifically, the battery pack may be used as a power source for devices requiring high-temperature safety, long cycle characteristics, and high rate characteristics. Examples of such devices include a mobile device, a wearable device A power tool powered by an electric motor; An electric vehicle including an electric vehicle (EV), a hybrid electric vehicle (HEV), a plug-in hybrid electric vehicle (PHEV), and the like; An electric motorcycle including an electric bike (E-bike) and an electric scooter (E-scooter); An electric golf cart; And an energy storage system, but the present invention is not limited thereto.

The structure of these devices and their fabrication methods are well known in the art, and a detailed description thereof will be omitted herein.

1 is a vertical cross-sectional view of an electrode assembly according to one embodiment.

2 is an exploded perspective view of a laminate sheet, a heat transfer member, and a portion of an electrode according to one embodiment.

Figure 3 is a vertical cross-sectional view of the laminate sheet, heat transfer member and electrode portion of Figure 2;

4 is an exploded perspective view of a laminate sheet, a heat transfer member, and a part of an electrode according to another embodiment.

Figure 5 is a vertical cross-sectional view of a portion of the laminate sheet, heat transfer member and electrode of Figure 4;

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings. However, the detailed description of known functions and configurations incorporated herein will be omitted when it may unnecessarily obscure the subject matter of the present invention.

The same reference numerals are used for portions having similar functions and functions throughout the drawings. Throughout the specification, when a part is connected to another part, it includes not only a case where it is directly connected but also a case where the other part is indirectly connected with another part in between. In addition, the inclusion of an element does not exclude other elements, but may include other elements, unless specifically stated otherwise.

The present invention will be described in detail with reference to the drawings.

1 schematically shows a vertical sectional view of an electrode assembly used in a pouch-type secondary battery of the present invention.

1, the electrode assembly 100 includes a positive electrode coated with a positive electrode active material 101 on one side or both sides of a positive electrode current collector 102 and a negative electrode active material 103 on one side or both sides of the negative electrode current collector 104 And a separator 110 interposed between the anode and the cathode.

In the electrode assembly 100, the cathode is located at the uppermost outermost electrode, and the anode is located at the lowermost outermost electrode. However, since the outermost electrodes at both ends of the electrode assembly 100 may be the same as each other, the same electrode may be positioned at the anode or the cathode.

The uppermost outermost electrode of the electrode assembly 100 is a single-sided negative electrode coated with the negative electrode active material 103 only on the inner surface of the negative electrode collector 104 and the outermost electrode of the lower electrode is formed only on the inner surface of the positive electrode collector 102 Side electrodes coated with an electrode active material, and the other central electrodes except for the outermost electrodes are composed of a double-sided electrode coated with an electrode active material on both sides of the electrode current collector.

Thus, since the electrode current collector of the metal material is located at the outermost side of the electrode assembly facing the heat transfer member, the heat energy of the electrode assembly can quickly move toward the pouch case through the heat transfer member.

In addition, if an uncoated electrode having no electrode active material is used as the outermost electrode, a lamination / stacked electrode assembly, a stack / folding type electrode assembly may be used instead of the stacked electrode assembly 100 of FIG. 1 .

FIG. 2 schematically shows an exploded perspective view of a laminate sheet, a heat transfer member, and a part of an electrode according to one embodiment, and FIG. 3 is a vertical sectional view of the state in which the laminate sheet, heat transfer member, As shown in FIG.

2 and 3, the laminate sheet 210 is a layered structure in which an outer coating layer 201, a metal layer 202 and an inner adhesive layer 203 are sequentially laminated. The inner surface of the laminate sheet 210 faces the heat transfer member 220 and the plate body 221 of the heat transfer member 220 is disposed between the inner adhesive layer 203 and the electrode 234 of the laminate sheet 210 And the protruding portion 222 is in contact with the metal layer 202 through the inside of the internal adhesive layer 203.

Although the projecting portion 222 is shown as a rectangular parallelepiped structure, it may have a hemispherical shape in the direction of the metal layer, a triangular pyramid structure as a whole, or a linear structure. However, in order to improve heat dissipation, It is preferable to make it wide.

The height h2 of the protrusion 222 is shown to be the same as the thickness h1 of the internal adhesive layer 203. The height h2 of the protrusion 222 is in the range of 100% to 120% based on the thickness h1 of the internal adhesive layer 203 .

The protrusion 22 is a structure protruding in a direction perpendicular to the plane of the plate-like body 221, and the protrusions 222 are positioned to be spaced apart from each other at a uniform interval.

Therefore, the thermal energy of the electrode assembly moves from the outermost electrode in the direction of the metal layer of the laminate sheet through the heat transfer member, and the heat energy can be uniformly and rapidly transferred throughout the entirety of the outermost electrode.

FIG. 4 schematically shows an exploded perspective view of a laminate sheet, a heat transfer member and a part of an electrode according to another embodiment, and FIG. 5 is a cross-sectional view of a laminate sheet, a heat transfer member, As shown in FIG.

4 and 5, the laminate sheet 310 is a layered structure in which an outer coating layer 301, a metal layer 302, and an inner adhesive layer 303 are sequentially laminated.

On the upper surface of the electrode 334, a heat transfer member 332 is attached in a direction perpendicular to the upper surface of the electrode. When the electrode 334 and the combined body 330 of the heat transfer member 332 are housed in the battery case, The metal layer 332 penetrates the internal adhesive layer 303 of the laminate sheet 310 as a battery case and contacts the metal layer 302 of the laminate sheet 310. [

The shape and height of the heat transfer member 332 can be seen to be the same as the protrusion 222 of the heat transfer member 220, and a description thereof will be omitted.

In the case where the electrode assembly and the heat transfer member are combined, it is preferable to use the assembly in manufacturing the electrode assembly, considering the convenience of the process. When the heat transfer member 332 is used, There is an advantage that the capacity of the battery can be increased by the thickness of the plate-like body.

That is, the pouch type secondary battery according to the present invention has a structure including a heat transfer member inside a battery case, and it is possible to provide a secondary battery with improved safety by allowing heat energy generated in the battery to be discharged.

Hereinafter, the present invention will be described with reference to embodiments thereof, but it should be understood that the scope of the present invention is not limited thereto.

Thermal conductivity measurement

In order to confirm the difference between the thermal conductivity of the conductive adhesive generally used and the thermal conductivity of the heat transfer member according to the present invention, seven kinds of commercially available conductive adhesives were shown as Comparative Examples 1 to 7, Are shown in Examples 1 to 5 and their thermal conductivities were measured.

The thermal conductivity was measured using a Mathis TC-30 at room temperature of 25 ° C. ASTM C 518 was referred to the relevant standard for thermal conductivity measurement. In addition, it is possible to measure thermal conductivity using equipment that can simultaneously measure the thermal conductivity of solids, liquids and pastes in addition to the above equipment.

Manufacturers and basic materials of Comparative Examples 1 to 7 are shown in Table 1 below.

The results of measurement of the thermal conductivities of the heat conducting members of Examples 1 to 5 and the conductive adhesives of Comparative Examples 1 to 7 are shown in Table 2 below.

Referring to Table 2, even when the same base material is made of the same material, it can be seen that the conductive base material has significantly lower thermal conductivity than the base material made of the heat conductive material.

For example, comparing Example 1 and Comparative Example 1 where the base material is aluminum, it can be seen that the thermal conductivity of Example 1 is about 196 times the thermal conductivity of Comparative Example 1.

Therefore, even if a pouch-type secondary battery having a structure in which a conductive adhesive agent is applied between the electrode assembly and the laminate sheet and the electrode assembly is connected to the metal layer of the laminate sheet through the conductive adhesive agent is used, , It can be expected that it is not easy to rapidly discharge the heat energy generated in the pouch type secondary battery to the outside of the battery case.

It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.

- Explanation of symbols

100: electrode assembly

101: cathode active material

102: positive collector

103: anode active material

104: cathode collector

110: Membrane

201, 301: outer coating layer

202, 302: metal layer

203, 303: internal adhesive layer

210, 310: Laminate sheet

220. 332: Heat transfer member

221: Plate type body

222:

234, 334: electrode

330: Combination of electrode and heat transfer member

h1: thickness of inner adhesive layer

h2: Height of protrusion

As described above, the pouch type secondary battery according to the present invention includes a heat transfer member for connecting the electrode assembly and the metal layer of the laminate sheet in the battery case, thereby minimizing an increase in the thickness of the entire secondary battery. , It is possible to prevent the capacity of the battery cell from being reduced.

In addition, since the heat energy generated in the battery can be quickly discharged to the outside of the battery case, it is possible to prevent the thermal runaway phenomenon caused by the abnormal use of the secondary battery. As a result, And a secondary battery having improved safety can be provided.

Claims

A pouch-type secondary battery comprising an electrode assembly and a laminate sheet containing an electrolyte,

Wherein the laminate sheet has a structure including an outer coating layer, a metal layer, and an inner adhesive layer,

And a heat transfer member for connecting the electrode assembly and the metal layer of the laminate sheet.
The pouch type secondary battery according to claim 1, wherein the heat transfer member includes a protruding structure penetrating the inner adhesive layer of the laminate sheet.
The pouch type secondary battery according to claim 1, wherein the heat transfer member is attached to the laminate sheet so as to be in contact with the outermost electrode of the electrode assembly.
The pouch type secondary battery according to claim 1, wherein the heat transfer member comprises a flat plate-shaped body and a protrusion extending in a vertical direction from one surface of the flat plate-shaped body.
The pouch type secondary battery according to claim 1, wherein the heat transfer member is a protruding structure extending in a vertical direction on an outer surface of an outermost electrode of the electrode assembly.
The pouch-type secondary battery according to claim 2 or 5, wherein the protruding structure has a plurality of protrusions uniformly formed at regular intervals.
The pouch-type secondary battery according to claim 2 or 5, wherein the height of the protruding structure is 100% to 120% based on the thickness of the inner adhesive layer of the laminate sheet.
The pouch type secondary battery according to claim 2 or 5, wherein the height of the protruding structure is in the range of 20 탆 to 140 탆.
The pouch type secondary battery according to claim 1, wherein the electrode assembly is at least one selected from the group consisting of a stacked electrode assembly, a stack / folding electrode assembly, and a lamination / stacked electrode assembly.
The pouch type secondary battery according to claim 9, wherein the outermost electrodes of the electrode assembly are formed of the same or different electrodes.
The pouch type secondary battery according to claim 1, wherein the heat transfer member is made of a metal having high thermal conductivity.
The heat transfer member according to claim 1, wherein the heat transfer member is made of aluminum (Al), copper (Cu), silver (Ag), gold (Au), nickel (Ni), tungsten (W), carbon (C) Wherein the pouch type secondary battery comprises at least one member selected from the group consisting of polyolefins.