WO2018098845A1 - 一种旋喷模块式稀土采矿方法 - Google Patents
一种旋喷模块式稀土采矿方法 Download PDFInfo
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- WO2018098845A1 WO2018098845A1 PCT/CN2016/109294 CN2016109294W WO2018098845A1 WO 2018098845 A1 WO2018098845 A1 WO 2018098845A1 CN 2016109294 W CN2016109294 W CN 2016109294W WO 2018098845 A1 WO2018098845 A1 WO 2018098845A1
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- liquid collecting
- rare earth
- jet
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B59/00—Obtaining rare earth metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the invention relates to a method for mining ion-adsorbed rare earth ores, in particular to a rotary-jet modular rare earth mining method.
- China is the country with the richest rare earth resources in the world. It is known as the “rare earth kingdom”. The south is dominated by heavy rare earths and the north is dominated by light rare earths. China's rare earth minerals not only have large reserves, but also have many varieties and good quality, and the types of deposits are unique.
- Ion-adsorbed rare earth ore also known as weathering crust-leaved rare earth ore, is a rare earth mineral that exists in the form of "ionic phase” minerals and is adsorbed on the surface of "carrier” minerals. Most of the rare earth minerals are cations. The state exists and is adsorbed on a mineral carrier, such as aluminosilicate mineral or fluorocarbonate mineral adsorbed on kaolinite or muscovite.
- the ion-adsorbed rare earth ore is an ore body composed of "ion-adsorbing rare earth minerals", and the southern rare earth ore is basically an ion-adsorbing rare earth ore.
- the mining methods of ion-adsorbed rare earth ores are basically carried out by the traditional in-situ leaching mining method, which is directly on the ore body without destroying the surface vegetation of the ore body, without stripping the topsoil, without excavating and carrying the ore.
- the well network is arranged, and a series of shallow wells (tanks) are used to inject an electrolyte solution capable of exchanging rare earth ions into the ore body to cause interaction with the rare earth ions, and then wait for the collection of the mother liquid, and the stop system of the stope is basically adopted by the mountain foot.
- the liquid trench is collected, and the diffusion of the mother liquor inside the ore body is difficult to control.
- the existing in-situ leaching mining method has the following deficiencies:
- the adsorption amount of positive ions is proportional to time. The longer the time, the more positive ions are adsorbed.
- the thickness of the ore layer exceeds a certain thickness, or the permeability coefficient of the soil layer is small, it is injected from the injection hole. It takes a long time for the solution to penetrate into the tunnel at the bottom of the ore layer, which causes a large amount of adsorption of the soil ions above the tunnel. To completely leaching the bottom layer, a large amount of solution is required to be injected, which leads to an increase in the amount of water and the amount of water. The increase in the rare earth solution in the rare earth solution flowing into the tunnel is lower, so that the production cost is large.
- the existing in-situ leaching mining method is difficult to define whether the ore body is fully leached. It is difficult to form a systematic recovery of resources, the production process is relatively extensive, the recovery rate of resources is low, and the low mother liquor concentration is formed. The drawing process has caused a lot of difficulty.
- the present invention provides a rotary jet module type rare earth mining method, which is a system modular rare earth leaching mining system. Technology that increases the recovery concentration of the mother liquor and reduces the use of the extract Quantity, modular and efficient recovery of rare earth resources.
- Each mother liquor collection channel is connected to the jet borehole under several mining unit modules; 5)
- the liquid collecting manifold is arranged outside the mountain: the liquid collecting manifold is arranged obliquely along the mountain below the port of the mother liquid collecting channel, and the collecting manifold connects all the sets.
- the port of the liquid pipe flows to the foot of the mountain; 6) a liquid collecting pipe is arranged in the mother liquid collecting channel, and the collecting pipe is provided with a small hole in the circumferential direction at a distance of a certain interval, and 3-4 layers are arranged in the small hole, and the collecting pipe is provided One end is sealed and deep into the bottom of the mother liquid collection channel, and the other end of the liquid collection tube is connected to the liquid collection manifold, and the end between the mother liquid collection channel and the liquid collection tube is adhered to the end of the liquid collection manifold Fill the seal; 7) Send the hydraulic rock bit to the incident stream and drill 0.4m from the bottom of the hole, input the high-pressure extract, hydraulically break the rock bit and cut the surrounding rare earth ore body at high speed, and gradually increase the hydraulic rock bit until the top of the rich layer.
- a cylindrical muddy rare earth ore body is formed in the jet borehole, and then the hydraulic rock breaker bit is moved up and down to agitate and leaching the muddy rare earth ore body to become a mother liquid to be collected, and the mother liquid passes through the lower mother liquid collection channel and the liquid collecting pipe.
- the collection manifold is completed and collected.
- the rotary-jet modular rare earth mining method of the present invention utilizes a mining unit module to divide a rare earth ore body, and performs grid module division on the rare earth ore body to prevent the extract liquid from being
- the rare earth ore body has an ineffective flow along the large fracture, which greatly improves the recovery rate of rare earth ions in the ore body; further, the jet drilling hole is drilled in the mining unit module, and the jet drilling hole penetrates into the bottom of the rich ore layer,
- the extract acts as a high-pressure jet to the rare earth ore body inside the borehole of the jet stream, and starts to crush and slurry the ore body from the bottom of the rich ore layer, and gradually raises the drill bit to the top of the rich ore layer to form a cylindrical muddy rare earth ore body.
- the disc-shaped high-pressure jet ring formed by the extract is stirred and leached to obtain the final mother liquid, which is a mixture of the muddy rare earth ore body and the high-pressure extract, and the mineral particles are small.
- the mineral extraction surface area is large, so the extraction efficiency of the liquid mother liquor obtained by ion exchange of the existing electrolyte solution is high, and the resources can be recovered systematically and efficiently; the leaching of the mud ore body improves the concentration of the mother liquor and can greatly increase the production of rare earth
- the mother liquor contains a higher grade of rare earth; and because the above mother liquor is formed by directly forming a high-pressure water jet to cut the ore body by using the extract, while stirring, slurrying, and extracting rare earth minerals by the up and down movement of the jet bit, the leaching speed Faster, reducing the amount of extraction solution used, speeding up the mining speed; the mother liquor is fed through the lower collecting pipe The liquid main pipe completes the collection of the mother liquid.
- the liquid injection amount of the extract liquid can be adjusted according to the liquid concentration of the liquid collecting pipe, and whether the ore body of the mining unit is sufficiently extracted, thereby controlling the ineffective flow of the extract liquid and the blind liquid injection.
- the dosage of the extract can be controlled in time according to the design requirements; in summary, the invention can greatly reduce the electricity consumption, labor cost and raw material dosage per ton of rare earth products, and the economic benefit is remarkable.
- FIG. 1 is a schematic view showing a process of extracting a mother liquor according to an embodiment of the present invention
- Figure 2 is a cross-sectional view of the portion I of Figure 1, showing the structure of a single mining unit module;
- topsoil 1, jet drilling, 3, rich ore layer, 4, muddy rare earth ore body, 5, lean ore layer, 6, liquid collecting pipe, 7, liquid collecting pipe, 8, liquid filling main pipe, 9. Hydraulic rock breaking bit, 10, disc-shaped high-pressure jet ring, 11, extract branch pipe, 12, small hole, 13, mother liquid collection channel, 14, Clay, 15, linen.
- FIG. 1 and 2 are schematic views showing the structure of a preferred embodiment of the present invention, and a rotary jet module type rare earth mining method comprising the following steps:
- the grid unit module is divided into the ore body at the top of the mine to form several mining unit modules;
- the borehole is arranged according to the direction of the vein, forming a plurality of mother liquor collecting passages 13, each of which is connected to the jet borehole 2 under a plurality of mining unit modules. ;
- the liquid collecting manifold 7 is arranged obliquely along the mountain below the port of the mother liquid collecting passage 13, and the liquid collecting manifold 7 is connected to the ports of all the collecting tubes 6 and flows to the mountain foot;
- a liquid collecting pipe 6 is arranged in the mother liquid collecting passage 13, and the collecting pipe 6 is provided with a small hole 12 in the circumferential direction at a distance of a certain interval, and the 3-4 layers of the burlap 15 are provided in the small hole 12 to serve as a preliminary filtering mother liquid.
- one end of the liquid collecting pipe 6 is sealed and penetrates into the bottom of the mother liquid collecting passage 13, and the one end of the liquid collecting pipe 6 is sealed to prevent a large amount of mud from flowing into the liquid collecting pipe 6, and the other end of the liquid collecting pipe 6 is connected to the liquid collecting main pipe 7, And sealing the seal between the mother liquid collecting passage 13 and the collecting pipe 6 at the end toward the liquid collecting main pipe 7 with the clay 14; thus the mother liquid passes from the jet drilling hole 2 of the mining unit module into the mother liquid collecting passage 13, and then passes through the set.
- the small hole 12 in the liquid pipe 6 enters the liquid collecting pipe 6, and then the mother liquid in the liquid collecting pipe 6 flows into the liquid collecting pipe 7;
- the hydraulic rock-breaking drill bit 9 is sent to the entrance flow hole 2 at a distance of 0.4 m from the bottom of the hole, and the direction of the hydraulic rock-breaking bit 9 is adjusted so that the cutting plane generated is horizontal. After confirming that the drill bit and the drill pipe are sealed, the high-pressure extraction is input.
- the liquid and hydraulic rock breaking bit 9 rotates at a high speed, and the disc-shaped high-pressure jet ring 10 sprayed therefrom cuts the surrounding rare earth ore body, and gradually increases the hydraulic rock breaking bit 9 until the top of the rich layer 3, forming a radius in the jet drilling hole 2.
- the mother liquor to be collected is stirred and leached after the muddy rare earth ore body 4, and the mother liquor passes through the lower mother liquor collecting channel 13 and The collecting pipe 6 is merged into the collecting header 7 to complete the collection.
- the drilling order of the jet drilling hole 2 and the mother liquid collecting passage 13 in the above embodiment of the present invention may be interchanged as long as the relative positional relationship is satisfied.
- the extraction process of the present invention (ie, the process of forming the mother liquor) can be carried out by monitoring the concentration of the mother liquor collected in the lower collecting pipe 6 of the mining unit module, and determining whether the mining unit is completely leached. After the leaching is finished, the corresponding extracting liquid branch pipe 11 is drilled. Rods, drills and other equipment.
- the area of the mining unit module in step 2) is 10m 2 -20m 2 , which is flexibly set according to the crack and seepage characteristics of the ore body, the jet pressure and the strength of the ore body.
- the jet bore 2 in step 3) is disposed in the center of the mountain of the mining unit module, and the diameter of the jet borehole 2 is not less than 32 mm, which can be flexibly adjusted according to the parameters of the jet drill pipe, and the depth of the drilled drill hole 2 can be specifically According to the definition of the rare earth enrichment of the mineral particles from the borehole, the drilling can be carried out using a portable backpack drill or a geological drill.
- the mother liquor collection channel 13 in step 6) is designed at the junction of the bottom of the rich layer 3 and the lean layer 5, specifically: according to the direction of the vein, a geological drilling machine is used to drill a mother liquid collecting channel 13 in the mountain body, and the drilling direction should be carried A certain upward inclination angle facilitates the self-flow of the mother liquid, and the hole depth is flexibly adjusted according to actual conditions.
- the diameter of the mother liquid collection channel 13 is 75 mm, and the interval between adjacent mother liquid collection channels 13 is 4 m; the diameter of the liquid collection tube 6 is 40 mm.
- a small hole 12 is provided at intervals of 0.1 m on the collecting pipe 6, wherein the length of the clay 14 filled between the mother liquid collecting passage 13 and the collecting pipe 6 toward the end of the liquid collecting pipe 7 is usually set to lm.
- the high-pressure extract in step 7) in the embodiment can be fed into the jet drill pipe of the hydraulic rock-breaking drill bit 9 through the extract branch pipe 11, the extract liquid branch pipe 11 is located above the jet borehole 2, and the extract liquid branch pipe 11 is connected to The liquid injection manifold 8 is used to replenish the extract.
- an anti-seepage layer may be further disposed under the liquid collecting pipe 6.
- the role of the anti-seepage layer mainly to prevent the mother liquid from continuing to penetrate downward, which is not conducive to the collection of the mother liquid. If there is an impervious rock layer within 2m below the liquid collecting pipe 6, there may be no anti-seepage layer; if there is no adjacent impervious rock layer, it may be adopted. Cement grouting forms an anti-seepage shell, and high-pressure water is injected to raise the groundwater level as an anti-seepage layer.
- the invention can greatly reduce the power consumption, labor cost and raw material dosage required per ton of rare earth products, and the advantages are as follows:
- the mining unit module is used to divide the rare earth ore body, and the high pressure jet will be used in the mining unit module.
- the rare earth ore body forms a cylindrical mud slurry, and the system recovers resources steadily and efficiently;
- the liquid injection amount of the extract liquid can be adjusted according to the liquid concentration of the liquid collecting pipe 6, the mineral body of the mining unit module is defined to be fully extracted, and the ineffective flow of the extract liquid and the blind liquid injection are controlled. Timely control according to design requirements;
- the inside of the ore body can be properly filled or cemented, and the restoration of the mine ecological environment and groundwater resources can be realized, the mountain collapse and landslide can be prevented, and the ecological environment can be protected.
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Abstract
Description
Claims (8)
- 一种旋喷模块式稀土采矿方法,包括以下步骤:1)探明矿层:探明山体稀土矿层的分布及矿层的厚度;2)在矿山顶部对矿体进行网格单元模块划分,形成若干个开采单元模块;3)在每个开采单元模块的山体上面布置射流钻孔(2),射流钻孔(2)的深度由表土层(1)直至富矿层(3)底部;4)在富矿层(3)底部与贫矿层(5)的交界处,按照矿脉的走向布置钻孔,形成多个母液收集通道(13),每个母液收集通道(13)在若干个开采单元模块下方与其射流钻孔(2)连通;5)在山体外布置集液总管(7):集液总管(7)位于母液收集通道(13)的端口下方沿山体倾斜布置,集液总管(7)连接所有集液管(6)的端口并流向山脚;6)在母液收集通道(13)内设置集液管(6),集液管(6)每间隔一段距离在周向上设有一圈小孔(12),小孔(12)处用麻布(15)包3-4层,集液管(6)的一端密封并深入母液收集通道(13)底部,集液管(6)的另一端连接集液总管(7),并将母液收集通道(13)与集液管(6)之间在朝向集液总管(7)的一端用粘土(14)填实封口;7)将水力破岩钻头(9)送入射流钻孔(2)距离孔底0.4m处,输入高压萃取液,水力破岩钻头(9)高速转动切割周围稀土矿体,逐渐提升水力破岩钻头(9)直到富矿层(3)顶部,在射流钻孔(2)内形成圆柱状泥浆质稀土矿体(4),再上下移动水力破岩钻头(9)对泥浆质稀土矿体(4)搅拌、浸析后成为待收集的母液,母液经下部的母液收集通道(13)及集液管 (6)汇入集液总管(7)完成收集。
- 根据权利要求1所述的一种旋喷模块式稀土采矿方法,其特征是:所述开采单元模块的面积为10m2-20m2。
- 根据权利要求1所述的一种旋喷模块式稀土采矿方法,其特征是:所述射流钻孔(2)设置在开采单元模块的山体中央,射流钻孔(2)的直径不少于32mm。
- 根据权利要求1所述的一种旋喷模块式稀土采矿方法,其特征是:所述母液收集通道(13)的直径为75mm,相邻母液收集通道(13)的间隔为4m。
- 根据权利要求4所述的一种旋喷模块式稀土采矿方法,其特征是:所述集液管(6)的直径为40mm,在集液管(6)上每间隔0.1m设置一圈小孔(12)。
- 根据权利要求1所述的一种旋喷模块式稀土采矿方法,其特征是:所述母液收集通道(13)与集液管(6)之间在朝向集液总管(7)一端所填实的粘土(14)的长度为lm。
- 根据权利要求1至6任一项所述的一种旋喷模块式稀土采矿方法,其特征是:所述高压萃取液通过萃取液支管(11)输入水力破岩钻头(9)的射流钻杆,萃取液支管(11)位于射流钻孔(2)的上方外部,萃取液支管(11)连通至注液总管(8)。
- 根据权利要求1至6任一项所述的一种旋喷模块式稀土采矿方法,其特征是:在所述集液管(6)的下方还设置有防渗层。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2016431138A AU2016431138B2 (en) | 2016-11-29 | 2016-12-09 | Rotary jet-grouting modular rare-earth mining process |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611069486.X | 2016-11-29 | ||
| CN201611069486.XA CN106591606B (zh) | 2016-11-29 | 2016-11-29 | 一种旋喷模块式稀土采矿方法 |
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| WO2018098845A1 true WO2018098845A1 (zh) | 2018-06-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| PCT/CN2016/109294 Ceased WO2018098845A1 (zh) | 2016-11-29 | 2016-12-09 | 一种旋喷模块式稀土采矿方法 |
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| Country | Link |
|---|---|
| CN (1) | CN106591606B (zh) |
| AU (1) | AU2016431138B2 (zh) |
| WO (1) | WO2018098845A1 (zh) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110685693A (zh) * | 2019-10-25 | 2020-01-14 | 江西离子型稀土工程技术研究有限公司 | 一种离子型稀土原地浸矿截流收液装置及其使用方法 |
| CN112699618A (zh) * | 2020-12-18 | 2021-04-23 | 赣江新区澳博颗粒科技研究院有限公司 | 一种离子型稀土矿原地浸矿过程数值模拟方法 |
| CN115341094A (zh) * | 2022-07-28 | 2022-11-15 | 中国矿业大学 | 离子型稀土矿原地浸取智能开采系统 |
| CN115896489A (zh) * | 2021-08-25 | 2023-04-04 | 中国科学院江西稀土研究院 | 一种从稀土浸出母液中富集稀土的方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109469472B (zh) * | 2018-12-19 | 2020-12-11 | 四川共拓岩土科技股份有限公司 | 一种离子型稀土矿原地浸取开采方法 |
| CN111020184B (zh) * | 2019-12-13 | 2021-08-10 | 四川共拓岩土科技股份有限公司 | 一种辐射孔喷射式稀土采取方法 |
| CN117187556B (zh) * | 2023-08-15 | 2026-02-06 | 贺州稀有稀土矿业有限公司 | 一种离子型稀土矿底部反向注液方法 |
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| CN110685693A (zh) * | 2019-10-25 | 2020-01-14 | 江西离子型稀土工程技术研究有限公司 | 一种离子型稀土原地浸矿截流收液装置及其使用方法 |
| CN112699618A (zh) * | 2020-12-18 | 2021-04-23 | 赣江新区澳博颗粒科技研究院有限公司 | 一种离子型稀土矿原地浸矿过程数值模拟方法 |
| CN112699618B (zh) * | 2020-12-18 | 2023-01-17 | 赣江新区澳博颗粒科技研究院有限公司 | 一种离子型稀土矿原地浸矿过程数值模拟方法 |
| CN115896489A (zh) * | 2021-08-25 | 2023-04-04 | 中国科学院江西稀土研究院 | 一种从稀土浸出母液中富集稀土的方法 |
| CN115341094A (zh) * | 2022-07-28 | 2022-11-15 | 中国矿业大学 | 离子型稀土矿原地浸取智能开采系统 |
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| CN106591606B (zh) | 2018-11-06 |
| AU2016431138B2 (en) | 2019-11-07 |
| AU2016431138A1 (en) | 2019-07-11 |
| CN106591606A (zh) | 2017-04-26 |
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