WO2018063405A1 - Microelectronic devices and methods for enhancing interconnect reliability performance using an in-situ nickel barrier layer - Google Patents

Microelectronic devices and methods for enhancing interconnect reliability performance using an in-situ nickel barrier layer Download PDF

Info

Publication number
WO2018063405A1
WO2018063405A1 PCT/US2016/055031 US2016055031W WO2018063405A1 WO 2018063405 A1 WO2018063405 A1 WO 2018063405A1 US 2016055031 W US2016055031 W US 2016055031W WO 2018063405 A1 WO2018063405 A1 WO 2018063405A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
barrier layer
depression
copper
feature
Prior art date
Application number
PCT/US2016/055031
Other languages
French (fr)
Inventor
Zachary A. ZELL
Shravan GOWRISHANKAR
A H M Shahadat HUSSAIN
Jonathan J. BURK
Seshu V. Sattiraju
Original Assignee
Intel Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Intel Corporation filed Critical Intel Corporation
Priority to PCT/US2016/055031 priority Critical patent/WO2018063405A1/en
Publication of WO2018063405A1 publication Critical patent/WO2018063405A1/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L24/10Bump connectors ; Manufacturing methods related thereto
    • H01L24/11Manufacturing methods
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L24/02Bonding areas ; Manufacturing methods related thereto
    • H01L24/03Manufacturing methods
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L24/02Bonding areas ; Manufacturing methods related thereto
    • H01L24/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L24/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L24/10Bump connectors ; Manufacturing methods related thereto
    • H01L24/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L24/13Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/03Manufacturing methods
    • H01L2224/034Manufacturing methods by blanket deposition of the material of the bonding area
    • H01L2224/03444Manufacturing methods by blanket deposition of the material of the bonding area in gaseous form
    • H01L2224/0345Physical vapour deposition [PVD], e.g. evaporation, or sputtering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/03Manufacturing methods
    • H01L2224/034Manufacturing methods by blanket deposition of the material of the bonding area
    • H01L2224/03444Manufacturing methods by blanket deposition of the material of the bonding area in gaseous form
    • H01L2224/03452Chemical vapour deposition [CVD], e.g. laser CVD
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/03Manufacturing methods
    • H01L2224/034Manufacturing methods by blanket deposition of the material of the bonding area
    • H01L2224/0346Plating
    • H01L2224/03462Electroplating
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/03Manufacturing methods
    • H01L2224/034Manufacturing methods by blanket deposition of the material of the bonding area
    • H01L2224/0346Plating
    • H01L2224/03464Electroless plating
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/03Manufacturing methods
    • H01L2224/036Manufacturing methods by patterning a pre-deposited material
    • H01L2224/0361Physical or chemical etching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/03Manufacturing methods
    • H01L2224/036Manufacturing methods by patterning a pre-deposited material
    • H01L2224/03618Manufacturing methods by patterning a pre-deposited material with selective exposure, development and removal of a photosensitive material, e.g. of a photosensitive conductive resin
    • H01L2224/0362Photolithography
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/03Manufacturing methods
    • H01L2224/038Post-treatment of the bonding area
    • H01L2224/0381Cleaning, e.g. oxide removal step, desmearing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/03Manufacturing methods
    • H01L2224/038Post-treatment of the bonding area
    • H01L2224/0383Reworking, e.g. shaping
    • H01L2224/03831Reworking, e.g. shaping involving a chemical process, e.g. etching the bonding area
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/03Manufacturing methods
    • H01L2224/038Post-treatment of the bonding area
    • H01L2224/03848Thermal treatments, e.g. annealing, controlled cooling
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/0401Bonding areas specifically adapted for bump connectors, e.g. under bump metallisation [UBM]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/05001Internal layers
    • H01L2224/0501Shape
    • H01L2224/05016Shape in side view
    • H01L2224/05018Shape in side view being a conformal layer on a patterned surface
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/05001Internal layers
    • H01L2224/0502Disposition
    • H01L2224/05026Disposition the internal layer being disposed in a recess of the surface
    • H01L2224/05027Disposition the internal layer being disposed in a recess of the surface the internal layer extending out of an opening
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/05001Internal layers
    • H01L2224/05075Plural internal layers
    • H01L2224/0508Plural internal layers being stacked
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/05001Internal layers
    • H01L2224/05099Material
    • H01L2224/051Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof
    • H01L2224/05138Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof the principal constituent melting at a temperature of greater than or equal to 950°C and less than 1550°C
    • H01L2224/05147Copper [Cu] as principal constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/05001Internal layers
    • H01L2224/05099Material
    • H01L2224/051Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof
    • H01L2224/05163Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof the principal constituent melting at a temperature of greater than 1550°C
    • H01L2224/05166Titanium [Ti] as principal constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/05001Internal layers
    • H01L2224/05099Material
    • H01L2224/051Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof
    • H01L2224/05163Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof the principal constituent melting at a temperature of greater than 1550°C
    • H01L2224/05181Tantalum [Ta] as principal constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/0554External layer
    • H01L2224/05541Structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/0554External layer
    • H01L2224/0555Shape
    • H01L2224/05556Shape in side view
    • H01L2224/05558Shape in side view conformal layer on a patterned surface
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/0554External layer
    • H01L2224/0556Disposition
    • H01L2224/05571Disposition the external layer being disposed in a recess of the surface
    • H01L2224/05572Disposition the external layer being disposed in a recess of the surface the external layer extending out of an opening
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/0554External layer
    • H01L2224/05573Single external layer
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/02Bonding areas; Manufacturing methods related thereto
    • H01L2224/04Structure, shape, material or disposition of the bonding areas prior to the connecting process
    • H01L2224/05Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
    • H01L2224/0554External layer
    • H01L2224/05599Material
    • H01L2224/056Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof
    • H01L2224/05638Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof the principal constituent melting at a temperature of greater than or equal to 950°C and less than 1550°C
    • H01L2224/05655Nickel [Ni] as principal constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/11Manufacturing methods
    • H01L2224/114Manufacturing methods by blanket deposition of the material of the bump connector
    • H01L2224/1146Plating
    • H01L2224/11462Electroplating
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/11Manufacturing methods
    • H01L2224/114Manufacturing methods by blanket deposition of the material of the bump connector
    • H01L2224/1146Plating
    • H01L2224/11464Electroless plating
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/11Manufacturing methods
    • H01L2224/116Manufacturing methods by patterning a pre-deposited material
    • H01L2224/1162Manufacturing methods by patterning a pre-deposited material using masks
    • H01L2224/11622Photolithography
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/11Manufacturing methods
    • H01L2224/118Post-treatment of the bump connector
    • H01L2224/11848Thermal treatments, e.g. annealing, controlled cooling
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L2224/13Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
    • H01L2224/13001Core members of the bump connector
    • H01L2224/13005Structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L2224/13Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
    • H01L2224/13001Core members of the bump connector
    • H01L2224/1302Disposition
    • H01L2224/13021Disposition the bump connector being disposed in a recess of the surface
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L2224/13Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
    • H01L2224/13001Core members of the bump connector
    • H01L2224/1302Disposition
    • H01L2224/13023Disposition the whole bump connector protruding from the surface
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L2224/13Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
    • H01L2224/13001Core members of the bump connector
    • H01L2224/13075Plural core members
    • H01L2224/1308Plural core members being stacked
    • H01L2224/13082Two-layer arrangements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L2224/13Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
    • H01L2224/13001Core members of the bump connector
    • H01L2224/13075Plural core members
    • H01L2224/1308Plural core members being stacked
    • H01L2224/13083Three-layer arrangements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L2224/13Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
    • H01L2224/13001Core members of the bump connector
    • H01L2224/13099Material
    • H01L2224/131Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L2224/13Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
    • H01L2224/13001Core members of the bump connector
    • H01L2224/13099Material
    • H01L2224/131Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof
    • H01L2224/13138Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof the principal constituent melting at a temperature of greater than or equal to 950°C and less than 1550°C
    • H01L2224/13147Copper [Cu] as principal constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L2224/13Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
    • H01L2224/13001Core members of the bump connector
    • H01L2224/13099Material
    • H01L2224/131Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof
    • H01L2224/13138Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof the principal constituent melting at a temperature of greater than or equal to 950°C and less than 1550°C
    • H01L2224/13155Nickel [Ni] as principal constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/15Structure, shape, material or disposition of the bump connectors after the connecting process
    • H01L2224/16Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
    • H01L2224/161Disposition
    • H01L2224/16151Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/16221Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/15Structure, shape, material or disposition of the bump connectors after the connecting process
    • H01L2224/16Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
    • H01L2224/165Material
    • H01L2224/16505Material outside the bonding interface, e.g. in the bulk of the bump connector
    • H01L2224/16507Material outside the bonding interface, e.g. in the bulk of the bump connector comprising an intermetallic compound
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/80Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
    • H01L2224/81Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a bump connector
    • H01L2224/818Bonding techniques
    • H01L2224/81801Soldering or alloying
    • H01L2224/81815Reflow soldering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/93Batch processes
    • H01L2224/94Batch processes at wafer-level, i.e. with connecting carried out on a wafer comprising a plurality of undiced individual devices

Definitions

  • embodiments of the present invention relate to
  • microelectronic devices and methods for enhancing interconnect reliability performance using an in- situ nickel barrier layer are provided.
  • Copper pillar and bump interconnects manufactured at the wafer-level are used in Flip Chip assembly processes, which typically utilize tin-based solder to connect die to package. While the solder is a softer, conductive material that can be reflowed upon application of heat, at elevated temperatures it tends to react with copper to form intermetallic compounds (IMC). IMCs have poor thermomechanical and electrical properties, and can compromise the electrical and reliability performance of a packaged semiconductor device. Solder can consume some or all of the 1st layer interconnect copper, which is why taller copper bumps are required to prevent IMC formation in the underlying interconnect layers.
  • IMC intermetallic compounds
  • Taller copper structures act as a sacrificial layer to solder, however, these taller copper structures also introduce higher mechanical stress upon any underlying ILD material layers at the wafer and die level, which can lead to other device failure modes.
  • Figure 1 illustrates a cross-sectional image of Solder-capped Copper bump in a packaged die 100 after aggressive reliability testing.
  • Figure 2 illustrates a process for enhancing interconnect reliability performance using an in-situ nickel barrier layer for back end metallization, e.g., forming copper interconnects for microelectronic devices (e.g., integrated circuit chips) in accordance with one embodiment.
  • Figures 3A-3E illustrate cross-sectional drawings of a microelectronic device (e.g., 300, 320, 340, 360, 380) that is fabricated in accordance with the operations of the process of Figure 2 in accordance with one embodiment.
  • a microelectronic device e.g., 300, 320, 340, 360, 380
  • FIGS. 4A-4F illustrate paired-simulated reflow experiments in accordance with certain embodiments.
  • Figures 5A-5C illustrate cross-sectional images of microelectronic devices 500, 520, and 540 having copper bump layers post resist strip in accordance with certain embodiments.
  • Figure 6 illustrates a computing device 900 in accordance with one embodiment.
  • microelectronic devices that are designed to enhance interconnect reliability performance without impacting electrical performance using an in-situ nickel barrier layer.
  • various aspects of the illustrative implementations will be described using terms commonly employed by those skilled in the art to convey the substance of their work to others skilled in the art.
  • embodiments of the present invention may be practiced with only some of the described aspects.
  • specific numbers, materials and configurations are set forth in order to provide a thorough understanding of the illustrative implementations.
  • embodiments of the present invention may be practiced without the specific details.
  • well-known features are omitted or simplified in order to not obscure the illustrative implementations.
  • Electronic connections between the electronic devices (e.g., transistors) in an integrated circuit (IC) chip are currently typically created using copper metal or alloys of copper metal.
  • Devices in an IC chip can be placed not only across the surface of the IC chip but devices can also be stacked in a plurality of layers on the IC chip.
  • Electrical interconnections between electronic devices that make up the IC chip are built using vias and trenches that are filled with conducting material. Layer(s) of insulating materials, frequently, low-k dielectric materials, separate the various components and devices in the IC chip.
  • the substrate on which the devices of the IC circuit chip are built is, for example, a silicon wafer or a silicon-on-insulator substrate.
  • Silicon wafers are substrates that are typically used in the semiconductor processing industry, although embodiments of the invention are not dependent on the type of substrate used.
  • the substrate could also be comprised of germanium, indium antimonide, lead telluride, indium arsenide, indium phosphide, gallium arsenide, gallium antimonide, and or other Group III-V materials either alone or in combination with silicon or silicon dioxide or other insulating materials.
  • IC devices that make up the chip are built on the substrate surface. At least one dielectric layer is deposited on the substrate.
  • Dielectric materials include, but are not limited to, silicon dioxide (S1O 2 ), low-k dielectrics, silicon nitrides, and or silicon oxynitrides.
  • the dielectric layer optionally includes pores or other voids to further reduce its dielectric constant.
  • low-k films are considered to be any film with a dielectric constant smaller than that of S1O 2 which has a dielectric constant of about 4.0.
  • Low-k films having dielectric constants of about 1 to about 2.7 are typical of current semiconductor fabrication processes.
  • the production of integrated circuit device structures often also includes placing a silicon dioxide film or layer, or capping layer on the surface of low-k (low dielectric constant) ILD (inter-layer dielectric) films.
  • Low-k films can be, for example, boron, phosphorous, or carbon doped silicon oxides. Carbon-doped silicon oxides can also be referred to as carbon-doped oxides (CDOs) and organo-silicate glasses (OSGs).
  • CDOs carbon-doped oxides
  • OSGs organo-silicate glasses
  • dielectric layers are patterned to create one or more trenches and or vias within which metal interconnects will be formed.
  • trenches and vias are used herein because these are the terms commonly associated with the features that are used to form metal interconnects.
  • a feature used to form a metal interconnect is a depression having any shape formed in a substrate or layer deposited on the substrate. The feature is filled with conducting interconnect material.
  • the trenches and or vias may be patterned (created) using conventional wet or dry etch semiconductor processing techniques.
  • Dielectric materials are used to isolate electrically metal interconnects from the surrounding components.
  • Barrier layers are used between the metal interconnects and the dielectric materials to prevent metal (such as copper) migration into the surrounding materials. Device failure can occur, for example, in situations in which copper metal is in contact with dielectric materials because the copper metal can ionize and penetrate into the dielectric material.
  • Barrier layers placed between a dielectric material, silicon, and or other materials and the copper interconnect can also serve to promote adhesion of the copper to the other material(s).
  • the present design adds a barrier layer to stop solder migration to the underlying interconnect layers and thus enables shorter bumps and less mechanical stress within the ILD.
  • an in-situ method creates conformally plated (through photoresist) Nickel film that is formed within a thick via beneath the copper bump.
  • Nickel is a widely used material in the semiconductor industry in first layer interconnect and packaging applications, due to its ability to act as an effective diffusion barrier to solder. Nickel will prevent the IMC from forming in underlying interconnect structures, which will enable shorter copper bumps (e.g., up to 30-40% thinner bumps) without impacting electrical or reliability performance.
  • the present design also improves (reduces) mechanical stress on the ILD stack due to a reduction of the thickness of the bump.
  • the present design is customizable to future technologies with reduced copper bump dimensions, and will enable decrease of bump height and critical dimensions (CD), and thus less Cu volume.
  • Nickel is widely used in the semiconductor industry in 1st layer interconnect and packaging applications, and is a known to act as a good diffusion barrier to Sn based solders.
  • the basic principle of the present design is that a Nickel barrier layer is added in situ and at wafer level above underlying interconnect layers with Nickel electrolytic (e.g., Nickel atomic weight % of at least 95%) or electro-less plating (e.g., Nickel atomic weight % of at least 80%) using a plate-through-photoresist process.
  • the Ni barrier layer has a minimum thickness of 1-2 microns. In other examples, the Ni barrier layer has a minimum thickness of less than 1 micron.
  • the Ni barrier is formed with no extra barrier-seed or lithography layer, and does not affect downstream fab operations. While copper has excellent current carrying properties, which makes it a viable material for interconnect layers, in the current Flip Chip assembly processes, copper in the first layer interconnect layer reacts with solder to form IMC during reliability testing. Thus to protect from solder, and prevent IMC formation in the underlying, current- carrying interconnect layers, taller Copper Bumps (e.g., 8-12 microns) are required.
  • Figure 1 illustrates a cross-sectional image of Solder-capped Copper bumps in a packaged die 100 after aggressive reliability testing.
  • Figure 1 shows results of aggressive reliability tests that shows complete Copper consumption of the bump, exposing underlying interconnect layers and causing device failure modes due to electrical opens due to
  • the present design enables shorter copper bumps (e.g., less than 8-12 microns), and thus less mechanical stress within the ILD stack, and better reliability performance.
  • the Ni barrier is created in fab using a plate-through photoresist option which does not require an extra barrier-seed or lithography layer. Since a final device structure includes a buried Ni layer capped with Cu, the first layer interconnect would appear in accordance with conventional first layer interconnects. Therefore, there is no impact to Fab end of line electrical test, Sort, and packaging processes since copper remains at the top of the bump.
  • This present design provides a new approach towards forming shorter copper pillars and bumps above underlying interconnect layers through the addition of a Nickel-plated barrier layer immediately before the bump layer is filled with copper. This prevents IMC proliferation into the underlying interconnect layers and formation of electrical opens.
  • a general flow of the fab process during a formation of a bump layer is outlined in Figures 2 and 3.
  • Figure 2 illustrates a process for enhancing interconnect reliability performance using an in-situ nickel barrier layer for back end metallization, e.g., forming copper interconnects for transistor devices for microelectronic devices (e.g., integrated circuit chips) in accordance with one embodiment.
  • Figures 3A-3E illustrate cross-sectional drawings of a microelectronic device (e.g., 300, 320, 340, 360, 380) that is fabricated in accordance with the operations of the process of Figure 2 in accordance with one embodiment.
  • a depression e.g., trench or via 302
  • a conducting metal to form an electrically conducting interconnect of a microelectronic device is provided at operation 201.
  • the trench or via is a depression that is typically formed in a dielectric layer, such as ILD layers 304 and 305 through an etching process used in the semiconductor industry.
  • the ILD layers and interconnect are formed on a substrate of the device.
  • the walls and bottom of the trench or via (the side(s) of the depression) can optionally be coated with a thin barrier layer 307.
  • the thin barrier layer is deposited by ALD, CVD, or PVD, for example.
  • An optional barrier layer e.g., Titanium containing layer 307, Tantalum containing layer 307) and an optional seed layer (e.g., Copper seed layer 308) are deposited (e.g., deposited on exposed upper surfaces of ILD 304, 305, and underlying interconnect layer 306) at operation 202.
  • the seed layer is deposited by ALD, PVD, or CVD, for example.
  • lithography is performed with a photoresist layer (e.g., photoresist layer 322) being applied to a surface of the device (e.g., device 320 of Figure 3B).
  • a photoresist layer e.g., photoresist layer 322
  • Light is used to transfer a pattern from a photomask (e.g., interconnect photomask) to the photoresist layer, which is light-sensitive.
  • Chemical treatments then cause a portion of the photoresist layer to be removed. These removed portions correspond to opening 324 (and other openings) of this layer.
  • a resist surface treatment occurs at operation 206.
  • the openings are then filled with metal (e.g., in-situ Nickel barrier layer 342, copper layer) through a deposition process (e.g., electroplating, electroless plating) at operation 208.
  • metal e.g., in-situ Nickel barrier layer 342, copper layer
  • a deposition process e.g., electroplating, electroless plating
  • the Nickel barrier layer is plated through openings in the photoresist at operation 208.
  • a Copper layer e.g., copper layer 362
  • the Copper layer is disposed on the Nickel barrier layer.
  • a first Copper layer is plated through openings in the photoresist and then the Nickel barrier layer is plated through the same openings in the photoresist at operation 208. Then, a second Copper layer is plated through the same openings in the same photoresist layer at operation 210. The second Copper layer is disposed on the Nickel barrier layer.
  • a first Copper layer is plated through openings in the photoresist at operation 208 and then the Nickel barrier layer is plated through the same openings in the photoresist at operation 210. The Nickel barrier layer is disposed on the first Copper layer.
  • a resist strip, etch, and clean are performed at operation 212 to generate a device (e.g., device 380).
  • Annealing the microelectronic device provides an electrical interconnect structure having a Nickel barrier layer that prevents solder migration to underlying interconnect layers.
  • an electrodeposition process comprises the deposition of a metal onto a
  • electroless plating which is also known as chemical or auto-catalytic plating, is a non-galvanic plating process that involves several simultaneous reactions in an aqueous solution. These reactions occur without the use of external electrical power.
  • a fabrication end of line (EOL) electronic test and sort are performed on a wafer level at operation 214.
  • a fabrication EOL packaging is performed at operation 216 with die of the wafer being packaged with packaging materials.
  • An upper level metallic interconnect layer contacts solder during the packaging.
  • FIGS. 4A-4F illustrate paired-simulated reflow experiments in accordance with certain embodiments.
  • Figure 4A illustrates a cross-sectional image of a microelectronic device 400 having a conventional copper (Cu) bump deposition with a Cu thickness of IX for the Copper layer 410.
  • Figure 4C illustrates a cross-sectional image of a microelectronic device 430 having a conventional copper (Cu) bump deposition with a Cu thickness of 2X for the Copper layer 411.
  • Quick Turn Reliability Tests QTRT are performed on these microelectronic devices in which bumps capped with solder layers 401- 403 are subjected to an elevated temperature condition in order to simulate solder reflow conditions in a reliability test.
  • Figures 4B, 4D, and 4F illustrate cross-sectional images of microelectronic devices 450, 460, and 470 after the reflow of the solder layers 404-406. Copper consumption can be observed with the QTRT in Figure 4B for the conventional bump deposition with IX Cu thickness for the Copper layer 413.
  • IMC is formed down to the ILD 452 within an underlying via layer, which could lead to increased resistance and/or electrical open type failure modes.
  • the Copper layer 414 remains as a continuous film throughout the bump and underlying VIA layer in the conventional bump deposition with 2X Cu thickness as illustrated in Figure 4D and the Copper layer 415 is completely consumed down to the Nickel layer 421 in the novel method with IX Ni deposition layer, IX Cu deposition layer of Figure 4F.
  • the overall thickness of the Nickel layer in Figure 4F is greater than the Copper layer thickness left in Figure 4D.
  • the Nickel layer remains intact as an underlying barrier layer as demonstrated in Figure 4F and thus provides protection of the underlying interconnect layers with maintained electrical continuity from die to package. In principle this could help enable shorter copper bumps with matched or better electrical test and reliability data as compared to the conventional method, as well as reduced stress on the ILD stack.
  • Figures 5A-5C illustrate cross-sectional images of microelectronic devices 500, 520, and 540 having copper bump layers post resist strip in accordance with certain
  • the interconnect structure 500 includes ILD (inter-layer dielectric) films 510 and 512, optional barrier layer 507 (e.g., Titanium containing layer, Tantalum containing layer), optional seed layer 508 (e.g., Copper seed layer 508), Nickel layer 504, optional Copper bump layer 502, and Copper interconnect 506.
  • ILD inter-layer dielectric
  • barrier layer 507 e.g., Titanium containing layer, Tantalum containing layer
  • optional seed layer 508 e.g., Copper seed layer 508
  • Nickel layer 504 optional Copper bump layer 502
  • Copper interconnect 506 Copper interconnect 506.
  • the structure 500 does not includes the Copper bumper layer 502
  • the Nickel layer 504 has a thicker deposition.
  • the interconnect structure 520 includes ILD (inter-layer dielectric) films 530 and 532, optional barrier layer 527 (e.g., Titanium containing layer, Tantalum containing layer), optional seed layer 528 (e.g., Copper seed layer 528), Nickel layer 514, Copper bump layer 512, Copper layer 516, and Copper interconnect 518.
  • the interconnect structure 540 includes ILD (inter-layer dielectric) films 550 and 552, optional barrier layer 547 (e.g., Titanium containing layer, Tantalum containing layer), optional seed layer 548 (e.g.,
  • Nickel barrier layer can be selectively added to the bottom (Figure 5A), middle ( Figure 5B), or top of the Cu bump ( Figure 5C). Each Cu or Ni layer within the stack would require a single plating step, all using the same plate-through photoresist layer.
  • the die may include a processor, memory, communications circuitry and the like. Though a single die is illustrated, there may be none, one or several dies included in the same region of the wafer.
  • the microelectronic device may be a crystalline substrate formed using a bulk silicon or a silicon-on-insulator substructure. In other implementations, the
  • microelectronics device may be formed using alternate materials, which may or may not be combined with silicon, that include but are not limited to germanium, indium antimonide, lead telluride, indium arsenide, indium phosphide, gallium arsenide, indium gallium arsenide, gallium antimonide, or other combinations of group III-V or group IV materials. Although a few examples of materials from which the substrate may be formed are described here, any material that may serve as a foundation upon which a semiconductor device may be built falls within the scope of embodiments of the present invention.
  • FIG. 6 illustrates a computing device 900 in accordance with one embodiment of the invention.
  • the computing device 900 houses a board 902.
  • the board 902 may include a number of components, including but not limited to at least one processor 904 (e.g., microelectronic device 300, 320, 340, 360, 380, 440, 470, 500, 520, 540, etc.) and at least one communication chip 906.
  • the at least one processor 904 is physically and electrically coupled to the board 902.
  • the at least one communication chip 906 is also physically and electrically coupled to the board 902.
  • the communication chip 906 is part of the processor 904.
  • the communication chip 906 (e.g., microelectronic device 300, 320, 340, 360, 380, 440, 470, 500, 520, 540, etc.) includes an antenna unit 920.
  • computing device 900 may include other components that may or may not be physically and electrically coupled to the board 902. These other components include, but are not limited to, volatile memory (e.g., DRAM 910, 911), non-volatile memory (e.g., ROM 912), flash memory, a graphics processor 916, a digital signal processor, a crypto processor, a chipset 914, an antenna unit 920, a display, a touchscreen display 930, a touchscreen controller 922, a battery 932, an audio codec, a video codec, a power amplifier 915, a global positioning system (GPS) device 926, a compass 924, a gyroscope, a speaker, a camera 950, and a mass storage device (such as hard disk drive, compact disk (CD), digital versatile disk (DVD), and so forth).
  • volatile memory e.g., DRAM 910, 911
  • non-volatile memory e.g., ROM 912
  • flash memory e.
  • the communication chip 906 enables wireless communications for the transfer of data to and from the computing device 900.
  • wireless and its derivatives may be used to describe circuits, devices, systems, methods, techniques, communications channels, etc., that may communicate data through the use of modulated electromagnetic radiation through a non- solid medium. The term does not imply that the associated devices do not contain any wires, although in some embodiments they might not.
  • the communication chip 906 may implement any of a number of wireless standards or protocols, including but not limited to Wi-Fi (IEEE 802.11 family), WiMAX (IEEE 802.16 family), WiGig, IEEE 802.20, long term evolution (LTE), Ev-DO, HSPA+, HSDPA+, HSUPA+, EDGE, GSM, GPRS, CDMA, TDMA, DECT, Bluetooth, derivatives thereof, as well as any other wireless protocols that are designated as 3G, 4G, 5G, and beyond.
  • the computing device 900 may include a plurality of communication chips 906.
  • a first communication chip 906 may be dedicated to shorter range wireless communications such as Wi-Fi, WiGig, and Bluetooth and a second communication chip 906 may be dedicated to longer range wireless communications such as GPS, EDGE, GPRS, CDMA, WiMAX, LTE, Ev-DO, 5G, and others.
  • the at least one processor 904 of the computing device 900 includes an integrated circuit die packaged within the at least one processor 904.
  • the integrated circuit die of the processor includes one or more devices, such as microelectronic devices (e.g., microelectronic device 300, 320, 340, 360, 380, 440, 470, 500, 520, 540, etc.) in accordance with implementations of embodiments of the invention.
  • microelectronic devices e.g., microelectronic device 300, 320, 340, 360, 380, 440, 470, 500, 520, 540, etc.
  • the term "processor” may refer to any device or portion of a device that processes electronic data from registers and/or memory to transform that electronic data into other electronic data that may be stored in registers and/or memory.
  • the communication chip 906 also includes an integrated circuit die packaged within the communication chip 906.
  • the integrated circuit die of the communication chip includes one or more
  • microelectronic devices e.g., microelectronic device 300, 320, 340, 360, 380, 440, 470, 500, 520, 540, etc.).
  • Example 1 is a microelectronic device that includes a layer of dielectric material having a feature with a depression, a Nickel barrier layer formed in the depression of the feature by plating through a photoresist layer, and a first conductive layer formed in the depression of the feature by plating through the photoresist layer.
  • example 2 the subject matter of example 1 can optionally include a second conductive layer formed below the depression of the feature.
  • the Nickel barrier layer prevents migration of solder to the second conductive layer.
  • any of examples 1-2 can optionally include a barrier layer and a seed layer formed in the depression of the feature and disposed above the second conductive layer.
  • example 4 the subject matter of example 3 can optionally include the Nickel barrier layer being disposed on the seed layer.
  • example 5 the subject matter of any of examples 1-4 can optionally include the first conductive layer being disposed on the Nickel barrier layer.
  • any of examples 1-4 can optionally include the Nickel barrier layer being disposed on the first conductive layer.
  • the Nickel barrier layer prevents migration of solder to the first conductive layer.
  • any of examples 1-6 can optionally include the first and second conductive layers each comprising a Copper layer.
  • Example 8 is a microelectronic device comprising a layer of dielectric material that includes a feature with a depression, a Nickel barrier layer formed in the depression of the feature by plating through a photoresist layer, a first conductive layer formed in the depression of the feature by plating through the photoresist layer, and a second conductive layer formed in the depression of the feature by plating through the photoresist layer.
  • example 9 the subject matter of example 8 can optionally include a third conductive layer formed below the depression of the feature.
  • the Nickel barrier layer prevents migration of solder to the second and third conductive layers.
  • any of examples 8-9 can optionally include a barrier layer and a seed layer formed in the depression of the feature and disposed above the third conductive layer.
  • any of examples 8-10 can optionally include the Nickel barrier layer being disposed on the second conductive layer, which is disposed on the seed layer.
  • any of examples 8-11 can optionally include the first conductive layer being disposed on the Nickel barrier layer.
  • any of examples 8-12 can optionally include the first, second, and third conductive layers each comprising a Copper layer.
  • any of examples 8-13 can optionally include a printed circuit board that is attached to the first conductive layer of the substrate with solder.
  • Example 15 is a method that comprises providing a microelectronic device having a layer of dielectric material that includes a feature with a depression, forming a photoresist layer with openings, forming a Nickel barrier layer in the openings by plating through the photoresist layer, and forming a first conductive layer in the openings by plating through the photoresist layer.
  • the subject matter of example 15 can optionally include the Nickel barrier layer preventing migration of solder to an underlying second conductive layer.
  • any of examples 15-16 can optionally include forming a barrier layer and a seed layer in the depression of the feature with the barrier and seed layers being disposed above the second conductive layer.
  • any of examples 15-17 can optionally include the Nickel barrier layer being disposed on the seed layer.
  • any of examples 15-18 can optionally include the first conductive layer being disposed on the Nickel barrier layer.
  • any of examples 15-18 can optionally include the Nickel barrier layer being disposed on the first conductive layer.
  • the Nickel barrier layer prevents migration of solder to the first conductive layer.

Abstract

Embodiments of the invention include a microelectronic device that includes a layer dielectric material that includes a feature with a depression. A Nickel barrier layer is formed in the depression of the feature and a first conductive layer is formed in the depression of the feature. The microelectronic device can optionally include a second conductive layer formed below the depression of the feature.

Description

MICROELECTRONIC DEVICES AND METHODS FOR ENHANCING
INTERCONNECT RELIABILITY PERFORMANCE USING AN IN-SITU NICKEL
BARRIER LAYER FIELD OF THE INVENTION
Embodiments of the present invention relate generally to the manufacture of
semiconductor devices. In particular, embodiments of the present invention relate to
microelectronic devices and methods for enhancing interconnect reliability performance using an in- situ nickel barrier layer.
BACKGROUND OF THE INVENTION
Copper pillar and bump interconnects manufactured at the wafer-level are used in Flip Chip assembly processes, which typically utilize tin-based solder to connect die to package. While the solder is a softer, conductive material that can be reflowed upon application of heat, at elevated temperatures it tends to react with copper to form intermetallic compounds (IMC). IMCs have poor thermomechanical and electrical properties, and can compromise the electrical and reliability performance of a packaged semiconductor device. Solder can consume some or all of the 1st layer interconnect copper, which is why taller copper bumps are required to prevent IMC formation in the underlying interconnect layers. Taller copper structures act as a sacrificial layer to solder, however, these taller copper structures also introduce higher mechanical stress upon any underlying ILD material layers at the wafer and die level, which can lead to other device failure modes. BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 illustrates a cross-sectional image of Solder-capped Copper bump in a packaged die 100 after aggressive reliability testing.
Figure 2 illustrates a process for enhancing interconnect reliability performance using an in-situ nickel barrier layer for back end metallization, e.g., forming copper interconnects for microelectronic devices (e.g., integrated circuit chips) in accordance with one embodiment.
Figures 3A-3E illustrate cross-sectional drawings of a microelectronic device (e.g., 300, 320, 340, 360, 380) that is fabricated in accordance with the operations of the process of Figure 2 in accordance with one embodiment.
FIGS. 4A-4F illustrate paired-simulated reflow experiments in accordance with certain embodiments. Figures 5A-5C illustrate cross-sectional images of microelectronic devices 500, 520, and 540 having copper bump layers post resist strip in accordance with certain
embodiments.
Figure 6 illustrates a computing device 900 in accordance with one embodiment.
DETAILED DESCRIPTION OF THE INVENTION
Described herein are microelectronic devices that are designed to enhance interconnect reliability performance without impacting electrical performance using an in-situ nickel barrier layer. In the following description, various aspects of the illustrative implementations will be described using terms commonly employed by those skilled in the art to convey the substance of their work to others skilled in the art. However, it will be apparent to those skilled in the art that embodiments of the present invention may be practiced with only some of the described aspects. For purposes of explanation, specific numbers, materials and configurations are set forth in order to provide a thorough understanding of the illustrative implementations. However, it will be apparent to one skilled in the art that embodiments of the present invention may be practiced without the specific details. In other instances, well-known features are omitted or simplified in order to not obscure the illustrative implementations.
Various operations will be described as multiple discrete operations, in turn, in a manner that is most helpful in understanding embodiments of the present invention, however, the order of description should not be construed to imply that these operations are necessarily order dependent. In particular, these operations need not be performed in the order of presentation.
Electronic connections between the electronic devices (e.g., transistors) in an integrated circuit (IC) chip are currently typically created using copper metal or alloys of copper metal. Devices in an IC chip can be placed not only across the surface of the IC chip but devices can also be stacked in a plurality of layers on the IC chip. Electrical interconnections between electronic devices that make up the IC chip are built using vias and trenches that are filled with conducting material. Layer(s) of insulating materials, frequently, low-k dielectric materials, separate the various components and devices in the IC chip.
The substrate on which the devices of the IC circuit chip are built is, for example, a silicon wafer or a silicon-on-insulator substrate. Silicon wafers are substrates that are typically used in the semiconductor processing industry, although embodiments of the invention are not dependent on the type of substrate used. The substrate could also be comprised of germanium, indium antimonide, lead telluride, indium arsenide, indium phosphide, gallium arsenide, gallium antimonide, and or other Group III-V materials either alone or in combination with silicon or silicon dioxide or other insulating materials. IC devices that make up the chip are built on the substrate surface. At least one dielectric layer is deposited on the substrate. Dielectric materials include, but are not limited to, silicon dioxide (S1O2), low-k dielectrics, silicon nitrides, and or silicon oxynitrides. The dielectric layer optionally includes pores or other voids to further reduce its dielectric constant. Typically, low-k films are considered to be any film with a dielectric constant smaller than that of S1O2 which has a dielectric constant of about 4.0. Low-k films having dielectric constants of about 1 to about 2.7 are typical of current semiconductor fabrication processes. The production of integrated circuit device structures often also includes placing a silicon dioxide film or layer, or capping layer on the surface of low-k (low dielectric constant) ILD (inter-layer dielectric) films. Low-k films can be, for example, boron, phosphorous, or carbon doped silicon oxides. Carbon-doped silicon oxides can also be referred to as carbon-doped oxides (CDOs) and organo-silicate glasses (OSGs). To form electrical interconnects, dielectric layers are patterned to create one or more trenches and or vias within which metal interconnects will be formed. The terms trenches and vias are used herein because these are the terms commonly associated with the features that are used to form metal interconnects. In general, a feature used to form a metal interconnect is a depression having any shape formed in a substrate or layer deposited on the substrate. The feature is filled with conducting interconnect material. The trenches and or vias may be patterned (created) using conventional wet or dry etch semiconductor processing techniques. Dielectric materials are used to isolate electrically metal interconnects from the surrounding components. Barrier layers are used between the metal interconnects and the dielectric materials to prevent metal (such as copper) migration into the surrounding materials. Device failure can occur, for example, in situations in which copper metal is in contact with dielectric materials because the copper metal can ionize and penetrate into the dielectric material. Barrier layers placed between a dielectric material, silicon, and or other materials and the copper interconnect can also serve to promote adhesion of the copper to the other material(s).
The present design adds a barrier layer to stop solder migration to the underlying interconnect layers and thus enables shorter bumps and less mechanical stress within the ILD. In this present design, an in-situ method creates conformally plated (through photoresist) Nickel film that is formed within a thick via beneath the copper bump. Nickel is a widely used material in the semiconductor industry in first layer interconnect and packaging applications, due to its ability to act as an effective diffusion barrier to solder. Nickel will prevent the IMC from forming in underlying interconnect structures, which will enable shorter copper bumps (e.g., up to 30-40% thinner bumps) without impacting electrical or reliability performance. The present design also improves (reduces) mechanical stress on the ILD stack due to a reduction of the thickness of the bump. The present design is customizable to future technologies with reduced copper bump dimensions, and will enable decrease of bump height and critical dimensions (CD), and thus less Cu volume.
Nickel is widely used in the semiconductor industry in 1st layer interconnect and packaging applications, and is a known to act as a good diffusion barrier to Sn based solders. The basic principle of the present design is that a Nickel barrier layer is added in situ and at wafer level above underlying interconnect layers with Nickel electrolytic (e.g., Nickel atomic weight % of at least 95%) or electro-less plating (e.g., Nickel atomic weight % of at least 80%) using a plate-through-photoresist process. In one example, the Ni barrier layer has a minimum thickness of 1-2 microns. In other examples, the Ni barrier layer has a minimum thickness of less than 1 micron. The Ni barrier is formed with no extra barrier-seed or lithography layer, and does not affect downstream fab operations. While copper has excellent current carrying properties, which makes it a viable material for interconnect layers, in the current Flip Chip assembly processes, copper in the first layer interconnect layer reacts with solder to form IMC during reliability testing. Thus to protect from solder, and prevent IMC formation in the underlying, current- carrying interconnect layers, taller Copper Bumps (e.g., 8-12 microns) are required.
Figure 1 illustrates a cross-sectional image of Solder-capped Copper bumps in a packaged die 100 after aggressive reliability testing. Figure 1 shows results of aggressive reliability tests that shows complete Copper consumption of the bump, exposing underlying interconnect layers and causing device failure modes due to electrical opens due to
IMC/void formation.
The present design enables shorter copper bumps (e.g., less than 8-12 microns), and thus less mechanical stress within the ILD stack, and better reliability performance. In addition, the Ni barrier is created in fab using a plate-through photoresist option which does not require an extra barrier-seed or lithography layer. Since a final device structure includes a buried Ni layer capped with Cu, the first layer interconnect would appear in accordance with conventional first layer interconnects. Therefore, there is no impact to Fab end of line electrical test, Sort, and packaging processes since copper remains at the top of the bump.
This present design provides a new approach towards forming shorter copper pillars and bumps above underlying interconnect layers through the addition of a Nickel-plated barrier layer immediately before the bump layer is filled with copper. This prevents IMC proliferation into the underlying interconnect layers and formation of electrical opens. A general flow of the fab process during a formation of a bump layer is outlined in Figures 2 and 3.
Figure 2 illustrates a process for enhancing interconnect reliability performance using an in-situ nickel barrier layer for back end metallization, e.g., forming copper interconnects for transistor devices for microelectronic devices (e.g., integrated circuit chips) in accordance with one embodiment. Figures 3A-3E illustrate cross-sectional drawings of a microelectronic device (e.g., 300, 320, 340, 360, 380) that is fabricated in accordance with the operations of the process of Figure 2 in accordance with one embodiment. In Figure 3A, a depression (e.g., trench or via 302) that is to be filled with a conducting metal to form an electrically conducting interconnect of a microelectronic device is provided at operation 201. The trench or via is a depression that is typically formed in a dielectric layer, such as ILD layers 304 and 305 through an etching process used in the semiconductor industry. The ILD layers and interconnect are formed on a substrate of the device. The walls and bottom of the trench or via (the side(s) of the depression) can optionally be coated with a thin barrier layer 307. The thin barrier layer is deposited by ALD, CVD, or PVD, for example. An optional barrier layer (e.g., Titanium containing layer 307, Tantalum containing layer 307) and an optional seed layer (e.g., Copper seed layer 308) are deposited (e.g., deposited on exposed upper surfaces of ILD 304, 305, and underlying interconnect layer 306) at operation 202. The seed layer is deposited by ALD, PVD, or CVD, for example. At operation 204, lithography is performed with a photoresist layer (e.g., photoresist layer 322) being applied to a surface of the device (e.g., device 320 of Figure 3B). Light is used to transfer a pattern from a photomask (e.g., interconnect photomask) to the photoresist layer, which is light-sensitive. Chemical treatments then cause a portion of the photoresist layer to be removed. These removed portions correspond to opening 324 (and other openings) of this layer. A resist surface treatment occurs at operation 206. The openings are then filled with metal (e.g., in-situ Nickel barrier layer 342, copper layer) through a deposition process (e.g., electroplating, electroless plating) at operation 208. In one example, the Nickel barrier layer is plated through openings in the photoresist at operation 208. Then, a Copper layer (e.g., copper layer 362) is plated through these same openings in the same photoresist layer at operation 210. The Copper layer is disposed on the Nickel barrier layer.
In another example, a first Copper layer is plated through openings in the photoresist and then the Nickel barrier layer is plated through the same openings in the photoresist at operation 208. Then, a second Copper layer is plated through the same openings in the same photoresist layer at operation 210. The second Copper layer is disposed on the Nickel barrier layer. In another example, a first Copper layer is plated through openings in the photoresist at operation 208 and then the Nickel barrier layer is plated through the same openings in the photoresist at operation 210. The Nickel barrier layer is disposed on the first Copper layer.
A resist strip, etch, and clean are performed at operation 212 to generate a device (e.g., device 380). Annealing the microelectronic device provides an electrical interconnect structure having a Nickel barrier layer that prevents solder migration to underlying interconnect layers. In general, an electrodeposition process comprises the deposition of a metal onto a
semiconductor substrate from an electrolytic solution that comprises ions of the metal to be deposited. In one example, a negative bias is placed on the substrate. The electrolyte solution can be referred to as a plating bath or an electroplating bath. The positive ions of the metal are attracted to the negatively biased substrate. The negatively biased substrate reduces the ions and the metal deposits onto the substrate. In another example, electroless plating, which is also known as chemical or auto-catalytic plating, is a non-galvanic plating process that involves several simultaneous reactions in an aqueous solution. These reactions occur without the use of external electrical power.
A fabrication end of line (EOL) electronic test and sort are performed on a wafer level at operation 214. A fabrication EOL packaging is performed at operation 216 with die of the wafer being packaged with packaging materials. An upper level metallic interconnect layer contacts solder during the packaging.
FIGS. 4A-4F illustrate paired-simulated reflow experiments in accordance with certain embodiments. Figure 4A illustrates a cross-sectional image of a microelectronic device 400 having a conventional copper (Cu) bump deposition with a Cu thickness of IX for the Copper layer 410. Figure 4C illustrates a cross-sectional image of a microelectronic device 430 having a conventional copper (Cu) bump deposition with a Cu thickness of 2X for the Copper layer 411. Figure 4Eillustrates a cross-sectional image of a microelectronic device 440 having a reduced thickness copper (Cu) bump deposition for the Copper layer 412 with a novel in-situ nickel layer 420. Quick Turn Reliability Tests (QTRT) are performed on these microelectronic devices in which bumps capped with solder layers 401- 403 are subjected to an elevated temperature condition in order to simulate solder reflow conditions in a reliability test.
Figures 4B, 4D, and 4F illustrate cross-sectional images of microelectronic devices 450, 460, and 470 after the reflow of the solder layers 404-406. Copper consumption can be observed with the QTRT in Figure 4B for the conventional bump deposition with IX Cu thickness for the Copper layer 413. In this case, IMC is formed down to the ILD 452 within an underlying via layer, which could lead to increased resistance and/or electrical open type failure modes. The Copper layer 414 remains as a continuous film throughout the bump and underlying VIA layer in the conventional bump deposition with 2X Cu thickness as illustrated in Figure 4D and the Copper layer 415 is completely consumed down to the Nickel layer 421 in the novel method with IX Ni deposition layer, IX Cu deposition layer of Figure 4F. However, the overall thickness of the Nickel layer in Figure 4F is greater than the Copper layer thickness left in Figure 4D. The Nickel layer remains intact as an underlying barrier layer as demonstrated in Figure 4F and thus provides protection of the underlying interconnect layers with maintained electrical continuity from die to package. In principle this could help enable shorter copper bumps with matched or better electrical test and reliability data as compared to the conventional method, as well as reduced stress on the ILD stack.
Figures 5A-5C illustrate cross-sectional images of microelectronic devices 500, 520, and 540 having copper bump layers post resist strip in accordance with certain
embodiments. The interconnect structure 500 includes ILD (inter-layer dielectric) films 510 and 512, optional barrier layer 507 (e.g., Titanium containing layer, Tantalum containing layer), optional seed layer 508 (e.g., Copper seed layer 508), Nickel layer 504, optional Copper bump layer 502, and Copper interconnect 506. In one example, if the structure 500 does not includes the Copper bumper layer 502, then the Nickel layer 504 has a thicker deposition. The interconnect structure 520 includes ILD (inter-layer dielectric) films 530 and 532, optional barrier layer 527 (e.g., Titanium containing layer, Tantalum containing layer), optional seed layer 528 (e.g., Copper seed layer 528), Nickel layer 514, Copper bump layer 512, Copper layer 516, and Copper interconnect 518. The interconnect structure 540 includes ILD (inter-layer dielectric) films 550 and 552, optional barrier layer 547 (e.g., Titanium containing layer, Tantalum containing layer), optional seed layer 548 (e.g.,
Copper seed layer 548), Nickel layer 544, Copper bump layer 542, and Copper interconnect 548. With the approach of the novel process of Figure 2, the Nickel barrier layer can be selectively added to the bottom (Figure 5A), middle (Figure 5B), or top of the Cu bump (Figure 5C). Each Cu or Ni layer within the stack would require a single plating step, all using the same plate-through photoresist layer.
It will be appreciated that, in a system on a chip embodiment, the die may include a processor, memory, communications circuitry and the like. Though a single die is illustrated, there may be none, one or several dies included in the same region of the wafer.
In one embodiment, the microelectronic device may be a crystalline substrate formed using a bulk silicon or a silicon-on-insulator substructure. In other implementations, the
microelectronics device may be formed using alternate materials, which may or may not be combined with silicon, that include but are not limited to germanium, indium antimonide, lead telluride, indium arsenide, indium phosphide, gallium arsenide, indium gallium arsenide, gallium antimonide, or other combinations of group III-V or group IV materials. Although a few examples of materials from which the substrate may be formed are described here, any material that may serve as a foundation upon which a semiconductor device may be built falls within the scope of embodiments of the present invention.
Figure 6 illustrates a computing device 900 in accordance with one embodiment of the invention. The computing device 900 houses a board 902. The board 902 may include a number of components, including but not limited to at least one processor 904 (e.g., microelectronic device 300, 320, 340, 360, 380, 440, 470, 500, 520, 540, etc.) and at least one communication chip 906. The at least one processor 904 is physically and electrically coupled to the board 902. In some implementations, the at least one communication chip 906 is also physically and electrically coupled to the board 902. In further implementations, the communication chip 906 is part of the processor 904. In one example, the communication chip 906 (e.g., microelectronic device 300, 320, 340, 360, 380, 440, 470, 500, 520, 540, etc.) includes an antenna unit 920.
Depending on its applications, computing device 900 may include other components that may or may not be physically and electrically coupled to the board 902. These other components include, but are not limited to, volatile memory (e.g., DRAM 910, 911), non-volatile memory (e.g., ROM 912), flash memory, a graphics processor 916, a digital signal processor, a crypto processor, a chipset 914, an antenna unit 920, a display, a touchscreen display 930, a touchscreen controller 922, a battery 932, an audio codec, a video codec, a power amplifier 915, a global positioning system (GPS) device 926, a compass 924, a gyroscope, a speaker, a camera 950, and a mass storage device (such as hard disk drive, compact disk (CD), digital versatile disk (DVD), and so forth).
The communication chip 906 enables wireless communications for the transfer of data to and from the computing device 900. The term "wireless" and its derivatives may be used to describe circuits, devices, systems, methods, techniques, communications channels, etc., that may communicate data through the use of modulated electromagnetic radiation through a non- solid medium. The term does not imply that the associated devices do not contain any wires, although in some embodiments they might not. The communication chip 906 may implement any of a number of wireless standards or protocols, including but not limited to Wi-Fi (IEEE 802.11 family), WiMAX (IEEE 802.16 family), WiGig, IEEE 802.20, long term evolution (LTE), Ev-DO, HSPA+, HSDPA+, HSUPA+, EDGE, GSM, GPRS, CDMA, TDMA, DECT, Bluetooth, derivatives thereof, as well as any other wireless protocols that are designated as 3G, 4G, 5G, and beyond. The computing device 900 may include a plurality of communication chips 906. For instance, a first communication chip 906 may be dedicated to shorter range wireless communications such as Wi-Fi, WiGig, and Bluetooth and a second communication chip 906 may be dedicated to longer range wireless communications such as GPS, EDGE, GPRS, CDMA, WiMAX, LTE, Ev-DO, 5G, and others.
The at least one processor 904 of the computing device 900 includes an integrated circuit die packaged within the at least one processor 904. In some implementations of embodiments of the invention, the integrated circuit die of the processor includes one or more devices, such as microelectronic devices (e.g., microelectronic device 300, 320, 340, 360, 380, 440, 470, 500, 520, 540, etc.) in accordance with implementations of embodiments of the invention. The term "processor" may refer to any device or portion of a device that processes electronic data from registers and/or memory to transform that electronic data into other electronic data that may be stored in registers and/or memory.
The communication chip 906 also includes an integrated circuit die packaged within the communication chip 906. In accordance with another implementation of embodiments of the invention, the integrated circuit die of the communication chip includes one or more
microelectronic devices (e.g., microelectronic device 300, 320, 340, 360, 380, 440, 470, 500, 520, 540, etc.).
The following examples pertain to further embodiments. Example 1 is a microelectronic device that includes a layer of dielectric material having a feature with a depression, a Nickel barrier layer formed in the depression of the feature by plating through a photoresist layer, and a first conductive layer formed in the depression of the feature by plating through the photoresist layer.
In example 2, the subject matter of example 1 can optionally include a second conductive layer formed below the depression of the feature. The Nickel barrier layer prevents migration of solder to the second conductive layer.
In example 3, the subject matter of any of examples 1-2 can optionally include a barrier layer and a seed layer formed in the depression of the feature and disposed above the second conductive layer.
In example 4, the subject matter of example 3 can optionally include the Nickel barrier layer being disposed on the seed layer. In example 5, the subject matter of any of examples 1-4 can optionally include the first conductive layer being disposed on the Nickel barrier layer.
In example 6, the subject matter of any of examples 1-4 can optionally include the Nickel barrier layer being disposed on the first conductive layer. The Nickel barrier layer prevents migration of solder to the first conductive layer.
In example 7, the subject matter of any of examples 1-6 can optionally include the first and second conductive layers each comprising a Copper layer.
Example 8 is a microelectronic device comprising a layer of dielectric material that includes a feature with a depression, a Nickel barrier layer formed in the depression of the feature by plating through a photoresist layer, a first conductive layer formed in the depression of the feature by plating through the photoresist layer, and a second conductive layer formed in the depression of the feature by plating through the photoresist layer.
In example 9, the subject matter of example 8 can optionally include a third conductive layer formed below the depression of the feature. The Nickel barrier layer prevents migration of solder to the second and third conductive layers.
In example 10, the subject matter of any of examples 8-9 can optionally include a barrier layer and a seed layer formed in the depression of the feature and disposed above the third conductive layer.
In example 11, the subject matter of any of examples 8-10 can optionally include the Nickel barrier layer being disposed on the second conductive layer, which is disposed on the seed layer.
In example 12, the subject matter of any of examples 8-11 can optionally include the first conductive layer being disposed on the Nickel barrier layer.
In example 13, the subject matter of any of examples 8-12 can optionally include the first, second, and third conductive layers each comprising a Copper layer.
In example 14, the subject matter of any of examples 8-13 can optionally include a printed circuit board that is attached to the first conductive layer of the substrate with solder.
Example 15 is a method that comprises providing a microelectronic device having a layer of dielectric material that includes a feature with a depression, forming a photoresist layer with openings, forming a Nickel barrier layer in the openings by plating through the photoresist layer, and forming a first conductive layer in the openings by plating through the photoresist layer. In example 16, the subject matter of example 15 can optionally include the Nickel barrier layer preventing migration of solder to an underlying second conductive layer.
In example 17, the subject matter of any of examples 15-16 can optionally include forming a barrier layer and a seed layer in the depression of the feature with the barrier and seed layers being disposed above the second conductive layer.
In example 18, the subject matter of any of examples 15-17 can optionally include the Nickel barrier layer being disposed on the seed layer.
In example 19, the subject matter of any of examples 15-18 can optionally include the first conductive layer being disposed on the Nickel barrier layer.
In example 20, the subject matter of any of examples 15-18 can optionally include the Nickel barrier layer being disposed on the first conductive layer. The Nickel barrier layer prevents migration of solder to the first conductive layer.

Claims

CLAIMS What is claimed is:
1. A microelectronic device comprising:
a layer of dielectric material that includes a feature with a depression;
a Nickel barrier layer formed in the depression of the feature; and
a first conductive layer formed in the depression of the feature.
2. The microelectronic device of claim 1, further comprising:
a second conductive layer formed below the depression of the feature, wherein the
Nickel barrier layer prevents migration of solder to the second conductive layer.
3. The microelectronic device of claim 2 further comprising:
a barrier layer and a seed layer formed in the depression of the feature and disposed above the second conductive layer.
4. The microelectronic device of claim 3 wherein the Nickel barrier layer is disposed on the seed layer.
5. The microelectronic device of claim 4, wherein the first conductive layer is disposed on the Nickel barrier layer.
6. The microelectronic device of claim 1, wherein the Nickel barrier layer is disposed on the first conductive layer, wherein the Nickel barrier layer prevents migration of solder to the first conductive layer.
7. The microelectronic device of claim 1, wherein the first and second conductive layers each comprise a Copper layer.
8. A microelectronic device comprising:
a layer of dielectric material that includes a feature with a depression;
a Nickel barrier layer formed in the depression of the feature;
a first conductive layer formed in the depression of the feature; and
a second conductive layer formed in the depression of the feature.
9. The microelectronic device of claim 8, further comprising:
a third conductive layer formed below the depression of the feature, wherein the Nickel barrier layer prevents migration of solder to the second and third conductive layers.
10. The microelectronic device of claim 9 further comprising:
a barrier layer and a seed layer formed in the depression of the feature and disposed above the third conductive layer.
11. The microelectronic device of claim 10 wherein the Nickel barrier layer is disposed on the second conductive layer, which is disposed on the seed layer.
12. The microelectronic device of claim 8, wherein the first conductive layer is disposed on the Nickel barrier layer.
13. The microelectronic device of claim 8, wherein the first, second, and third conductive layers each comprise a Copper layer.
14. The microelectronic device of claim 8, further comprising:
a printed circuit board that is attached to the first conductive layer of the substrate with solder.
15. A method comprising:
providing a microelectronic device having a layer of dielectric material that includes a feature with a depression;
forming a Nickel barrier layer in the depression of the feature; and
forming a first conductive layer in the depression of the feature.
16. The method of claim 15, wherein the Nickel barrier layer prevents migration of solder to an underlying second conductive layer.
17. The method of claim 16 further comprising:
forming a barrier layer and a seed layer in the depression of the feature and disposed above the second conductive layer.
18. The method of claim 17 wherein the Nickel barrier layer is disposed on the seed layer.
19. The method of claim 15, wherein the first conductive layer is disposed on the Nickel barrier layer.
20. The method of claim 15, wherein the Nickel barrier layer is disposed on the first conductive layer, wherein the Nickel barrier layer prevents migration of solder to the first conductive layer.
PCT/US2016/055031 2016-09-30 2016-09-30 Microelectronic devices and methods for enhancing interconnect reliability performance using an in-situ nickel barrier layer WO2018063405A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/US2016/055031 WO2018063405A1 (en) 2016-09-30 2016-09-30 Microelectronic devices and methods for enhancing interconnect reliability performance using an in-situ nickel barrier layer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2016/055031 WO2018063405A1 (en) 2016-09-30 2016-09-30 Microelectronic devices and methods for enhancing interconnect reliability performance using an in-situ nickel barrier layer

Publications (1)

Publication Number Publication Date
WO2018063405A1 true WO2018063405A1 (en) 2018-04-05

Family

ID=61760136

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2016/055031 WO2018063405A1 (en) 2016-09-30 2016-09-30 Microelectronic devices and methods for enhancing interconnect reliability performance using an in-situ nickel barrier layer

Country Status (1)

Country Link
WO (1) WO2018063405A1 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050208748A1 (en) * 2004-03-17 2005-09-22 International Business Machines Corporation Method for forming robust solder interconnect structures by reducing effects of seed layer underetching
US20060030139A1 (en) * 2002-06-25 2006-02-09 Mis J D Methods of forming lead free solder bumps and related structures
US20080083983A1 (en) * 2006-10-10 2008-04-10 Samsung Electronics Co., Ltd. Bump electrode including plating layers and method of fabricating the same
US20110101527A1 (en) * 2009-11-05 2011-05-05 Taiwan Semiconductor Manufacturing Company, Ltd. Mechanisms for forming copper pillar bumps
US20140227831A1 (en) * 2008-12-11 2014-08-14 Taiwan Semiconductor Manufacturing Company, Ltd. Front Side Copper Post Joint Structure for Temporary Bond in TSV Application

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060030139A1 (en) * 2002-06-25 2006-02-09 Mis J D Methods of forming lead free solder bumps and related structures
US20050208748A1 (en) * 2004-03-17 2005-09-22 International Business Machines Corporation Method for forming robust solder interconnect structures by reducing effects of seed layer underetching
US20080083983A1 (en) * 2006-10-10 2008-04-10 Samsung Electronics Co., Ltd. Bump electrode including plating layers and method of fabricating the same
US20140227831A1 (en) * 2008-12-11 2014-08-14 Taiwan Semiconductor Manufacturing Company, Ltd. Front Side Copper Post Joint Structure for Temporary Bond in TSV Application
US20110101527A1 (en) * 2009-11-05 2011-05-05 Taiwan Semiconductor Manufacturing Company, Ltd. Mechanisms for forming copper pillar bumps

Similar Documents

Publication Publication Date Title
CN102332435B (en) Electronic component and manufacturing method of same
US9735090B2 (en) Integrated circuit devices having through-silicon vias and methods of manufacturing such devices
US20120161320A1 (en) Cobalt metal barrier layers
US8508018B2 (en) Barrier layers
US11329008B2 (en) Method for manufacturing semiconductor package for warpage control
US10714386B2 (en) Integrated circuit interconnect structure having metal oxide adhesive layer
JP7182834B2 (en) Manufacturing methods and structures for semiconductor devices with superconducting metal through silicon vias
KR20170017878A (en) Selective diffusion barrier between metals of an integrated circuit device
CN106328583B (en) CVD metal seed layer
US11037802B2 (en) Package substrate having copper alloy sputter seed layer and high density interconnects
US8779589B2 (en) Liner layers for metal interconnects
JP2003203914A (en) Semiconductor integrated circuit device and manufacturing method therefor
US20150017798A1 (en) Method of manufacturing through-silicon-via
WO2018063405A1 (en) Microelectronic devices and methods for enhancing interconnect reliability performance using an in-situ nickel barrier layer
US9312207B2 (en) Semiconductor device
US11367684B2 (en) Recessed metal interconnects to mitigate EPE-related via shorting
US20240021549A1 (en) Connector and method for forming the same
US11610810B2 (en) Maskless air gap enabled by a single damascene process
US20220068802A1 (en) Metal line and via barrier layers, and via profiles, for advanced integrated circuit structure fabrication
TW201731056A (en) Dielectric buffer layer
KR20230140328A (en) Die bonding pads and methods of forming the same
US8053895B2 (en) Metal line of semiconductor device having a multilayer molybdenum diffusion barrier and method for forming the same

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 16918094

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 16918094

Country of ref document: EP

Kind code of ref document: A1