WO2017048192A1 - Power generation system and method - Google Patents

Power generation system and method Download PDF

Info

Publication number
WO2017048192A1
WO2017048192A1 PCT/SG2016/050446 SG2016050446W WO2017048192A1 WO 2017048192 A1 WO2017048192 A1 WO 2017048192A1 SG 2016050446 W SG2016050446 W SG 2016050446W WO 2017048192 A1 WO2017048192 A1 WO 2017048192A1
Authority
WO
WIPO (PCT)
Prior art keywords
lng
stirling engine
power generation
regasification
thermal storage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/SG2016/050446
Other languages
French (fr)
Inventor
Fei Duan
Swapnil DUBEY
Fook Hoong CHOO
Lu QIU
Kai Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanyang Technological University
Original Assignee
Nanyang Technological University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanyang Technological University filed Critical Nanyang Technological University
Priority to US15/759,826 priority Critical patent/US10577983B2/en
Publication of WO2017048192A1 publication Critical patent/WO2017048192A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K23/00Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
    • F01K23/02Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
    • F01K23/06Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
    • F01K23/10Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle with exhaust fluid of one cycle heating the fluid in another cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K23/00Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
    • F01K23/02Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
    • F01K23/06Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
    • F01K23/067Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle the combustion heat coming from a gasification or pyrolysis process, e.g. coal gasification
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02CGAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C3/00Gas-turbine plants characterised by the use of combustion products as the working fluid
    • F02C3/20Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
    • F02C3/22Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being gaseous at standard temperature and pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02CGAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C6/00Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
    • F02C6/18Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02GHOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
    • F02G1/00Hot gas positive-displacement engine plants
    • F02G1/04Hot gas positive-displacement engine plants of closed-cycle type
    • F02G1/043Hot gas positive-displacement engine plants of closed-cycle type the engine being operated by expansion and contraction of a mass of working gas which is heated and cooled in one of a plurality of constantly communicating expansible chambers, e.g. Stirling cycle type engines
    • F02G1/053Component parts or details
    • F02G1/055Heaters or coolers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C7/00Methods or apparatus for discharging liquefied, solidified, or compressed gases from pressure vessels, not covered by another subclass
    • F17C7/02Discharging liquefied gases
    • F17C7/04Discharging liquefied gases with change of state, e.g. vaporisation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02GHOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
    • F02G2254/00Heat inputs
    • F02G2254/15Heat inputs by exhaust gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02GHOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
    • F02G2256/00Coolers
    • F02G2256/50Coolers with coolant circulation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/03Mixtures
    • F17C2221/032Hydrocarbons
    • F17C2221/033Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/05Applications for industrial use
    • F17C2270/0581Power plants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/14Combined heat and power generation [CHP]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/30Technologies for a more efficient combustion or heat usage

Definitions

  • This invention relates to a power generation system and method, and in particular to a power generation system and method fueled by liquefied natural gas.
  • Natural gas fuel can produce remarkably lower emissions. It produces the lowest level of C0 2 in all hydrocarbon fuels. Compared to traditional fossil fuels, natural gas reduces benzene emissions by 97%, NO x emissions by 80%, carbon monoxide (CO) emissions by 76%, and C0 2 emissions by 22%. The use of nature gas does not produce lead, sulphur emissions, or particulate matters.
  • LNG liquefied natural gas
  • LNG Since the density of LNG is 460 kg/m , the volume of LNG takes up approximately 1/600 that of natural gas. LNG is an odourless, colourless, non-corrosive, and non-toxic liquid. The unit volume reduction dramatically eases its transport. The liquefaction process of natural gas removes 0 2 , C0 2 , SO x , and water vapor. In addition, the lower fuel cost per unit mass of LNG becomes less in comparison with the traditional fossil fuels; LNG, mainly made up of paraffinic compounds, results in the combustion efficiency higher than that of traditional fossil fuels. Therefore, LNG is a promising fuel in the market of power generation.
  • the present application discloses a power generation system fuelled by LNG to recover exhaust thermal energy and cold energy from LNG regasification simultaneously with one single Stirling engine.
  • the power generation system uses LNG (or any liquid combustible gas) for gas turbine power generation after regasification of LNG, and applies cold energy from the LNG regasification and hot energy of exhaust gas from the gas turbine to drive a Stirling engine.
  • LNG or any liquid combustible gas
  • a thermal storage system based on phase change materials (PCMs) is used to store the exhaust heat, stabilize the temperature of the exhaust gas and supply heat to a hot end of the Stirling engine.
  • the advantage of this is that a higher thermal efficiency is anticipated due to the large temperature differences between the hot end and cold end.
  • the system provides a high efficient, highly integrated, and stable combined power generation system from LNG by comprehensive utilization of energies stored in LNG, including chemical energy, cold energy, and exhaust heat after combustion.
  • a power generation system comprising: a liquefied natural gas (LNG) regasification unit configured to perform a regasification process to regasify LNG supplied from an LNG source to produce natural gas, the regasification process producing cold energy; a gas turbine configured to combust the natural gas to output power, the combusting producing an exhaust gas; a thermal storage unit configured to store heat obtained from the exhaust gas; and a Stirling engine configured to output power, the Stirling engine having a hot end heated by the heat stored in the thermal storage unit and a cold end cooled by the cold energy from the regasification process.
  • LNG liquefied natural gas
  • the thermal storage unit may comprise at least one phase change material.
  • the thermal storage unit may be embedded with the hot end of the Stirling engine.
  • a heat exchanger of the regasification unit may be embedded with the cold end of the Stirling engine.
  • a method of power generation comprising the steps of:
  • Storing the heat may comprise storing the heat in at least one phase change material in the thermal storage unit.
  • the method may further comprise directly spraying the cold end of the Stirling engine with LNG.
  • Fig. 1 is a schematic illustration of a power generation system.
  • Fig. 2 is a flow chart of a method of power generation.
  • the power generation system 100 is a liquid natural gas (LNG) fuel based co-generation system 100 which comprises two engines: gas turbine engine 110 and a Stirling engine 120.
  • the gas turbine may be a 30kW turbine while the Stirling engine 120 may be a 3kW engine.
  • the outputs of the gas turbine and the Stirling engine could be up to 100MW and 10MW after scaling up.
  • the Stirling engine 120 utilizes a known Stirling cycle for outputting mechanical work as a net conversion of heat energy from cyclic compression and expansion of a fixed mass of gas under different temperatures.
  • the Stirling engine 120 has a cold end 121 and a hot end 122, between which the fixed mass of gas in the Stirling engine is allowed to move.
  • the gas expands because its temperature rises due to external heat applied to the hot end 122.
  • Expansion of the gas does work which is the output of the Stirling engine. This work is typically in the form of movement of an output piston that is moved by the gas expanding against it. Momentum obtained from the output is harnessed to compress the expanded gas. Compression of the gas increases its temperature, so cold energy is externally applied to the cold end 121 to remove heat generated by the compression.
  • the compressed gas is once again expanded by heating at the hot end 122 to repeat the work cycle.
  • the gas turbine 110 consumes natural gas 131 as the fuel which is regasified from LNG 139 in a LNG regasification unit 130, and discharges high temperature exhaust gas 111.
  • the LNG regasification unit 130 may be a double impingement unit, and is supplied with LNG 139 from an LNG storage tank 150.
  • the power generation system 100 also includes a thermal storage system 140 on the basis of PCMs.
  • the Stirling engine 120 is used to recover cold energy 132 from the LNG regasification process 130 and the heat energy in the exhaust gas 111 from the gas turbine 110, simultaneously.
  • the cold energy 132 is applied to the cold end 121 of the Stirling engine 120 to remove heat generated by compression of the gas in the Stirling engine 120, while the heat energy in the exhaust gas 111 is applied to the hot end 122 of the Stirling engine to heat and thereby expand the gas in the Stirling engine 120.
  • the first power generation subsystem 110 is the gas turbine 110.
  • Natural gas 131 which is regasified from LNG 139 in the LNG regasification unit 130, is pumped into a combustor 119 of the gas turbine 110.
  • the natural gas 131 may have a temperature of about 20 °C, or room temperature.
  • Heat energy of hot exhaust gas 111 from the gas turbine 110 is stored in a PCM thermal storage tank 148 of the thermal storage system 140 into which the hot exhaust gas 111 is passed.
  • the hot exhaust gas 111 may have a temperature of about 285 - 650 °C, while the PCM thermal storage tank 148 may have a temperature of about 220 - 600 °C, depending on the temperature of hot exhaust gas 111.
  • Exhaust gas that leaves the PCM thermal storage tank 148 as emission 142 may have a temperature of about 200 °C.
  • the second power generator 120 is the Stirling engine 120 which operates between its high temperature or hot end (3 ⁇ 4) 122 and its cold end (7c) 121.
  • the hot end 122 is heated by a thermal fluid loop 141 of the thermal storage system 140 with heat from the PCM tank 148, and may have a temperature of about 200 - 580 °C.
  • the cold end 121 is cooled by cold energy from a thermal fluid loop 133 of the LNG regasification unit 130, and may have a temperature of about -100 °C.
  • Boiling temperature (at 1 atm) of LNG is -162 °C, which significantly decreases the cold end 121 temperature of the Stirling engine 120, and increases its energy efficiency.
  • regasification of LNG 139 in the LNG regasification unit 130 heats the LNG 139 to produce natural gas 131 for the gas turbine 110 and also cools the cold end 121 of the Stirling engine 120.
  • Thermal energy from the hot exhaust gas 111 of the gas turbine 110 is stored in the thermal storage unit 140 and applied to maintain the hot end 122 of the Stirling cycle 120.
  • the LNG regasification unit 130 and the thermal storage unit 140 are thus two core components in the system 100.
  • the LNG regasification unit 130 comprises a heat exchanger 135 in which the LNG 139 absorbs heat energy and converts into gas phase 131 on one side of the heat exchanger 135. On the other side of the heat exchanger 135, the heat is taken away and the object is cooled down to a very low temperature.
  • the heat exchanger 135 may be embedded in the Stirling engine 120, i.e. embedded with the cold end 121 of the Stirling engine 120, so that the heat transfer is conducted directly between the LNG 139 undergoing regasification in the regasification unit 130 and the Stirling engine 120.
  • LNG 139 from the LNG storage tank 150 may also simultaneously be sprayed (or otherwise impinged) onto the cold end 121 of the Stirling engine 120.
  • the thermal storage 140 can be integrated into the power generation system 120 to allow thermal energy to be stored and dispatched when power is required.
  • PCMs are employed as the storage media in the thermal storage tank 148. Operating around a melting point of PCM stabilizes the temperature of the hot end 122 of the Stirling engine 120, thereby maintaining the hot end 122 of the Stirling cycle 120.
  • the exhaust gas 111 flows over the PCM tank 148 to charge the thermal storage system 140.
  • the PCM tank 148 collects the heat from the exhaust gas 111 of the gas turbine 110 during operation.
  • the heat transfer fluids 141 are circulated by a pump (not shown) to discharge the heat from the thermal storage tank 140.
  • the heated heat transfer fluids 141 then send the heat to the Stirling engine 120 power generation system.
  • the cooled heat transfer fluids 149 return to the PCM storage tank 148 for the next cycle.
  • Pre-heating elements (not shown) are preferably installed in the tanks 148 to melt the PCMs at the beginning. Another function of the pre-heating elements is to make up the heat of the PCMs when it is in an emergent freeze situation.
  • the tank 148 will be operated at atmospheric pressure, similar to commercial oil storage tanks.
  • the proposed tanks 148 are preferably fabricated from stainless steel, and use self-supporting roofs.
  • a heat exchanging tube for transferring thermal energy to superheat vapor is preferably be installed.
  • wall, bottom, and roof of the tanks 148 are insulated preferably with mineral wool batts and calcium silicate block insulation, respectively.
  • the insulated foundation preferably comprises the following layers; (1) concrete slab, (2) foam glass insulation, (3) insulating fire bricks, (4) thin steel plate liner, and (5) sand.
  • a perimeter ring wall of insulating firebricks is preferably provided to support the weight of the walls and roof of the tank 148.
  • the thermal storage unit 140 also can be embedded in the Stirling engine 120, i.e., directly coupled with the hot end 122 of the Stirling engine 120, to make the system 100 more compact. In this case, the thermal fluid cycle is no longer needed as heat transfer is performed directly between the PCMs of the thermal storage unit 140 and the hot end 122 of the Stirling engine 120.
  • Natural gas (NG) is an environmentally friendly fuel which is still in high reserve on earth.
  • far field transportation of NG is necessary due to significant diversity of distribution of NG on the planet.
  • the most common and economical way to transport NG is to ship the liquid phase as LNG.
  • LNG needs to be regasified into gas phase for utilization.
  • the more popular NG is as a fuel in the global market, the more LNG transportation and regasification will be performed. This translates into a large amount of cold energy being produced in the LNG regasification process.
  • gas turbine power generator is still a very important method to supply electricity in many countries which produces a significant amount of waste heat.
  • the currently disclosed power generation system 100 presents an innovative method to recover this huge amount of cold energy from LNG regasifiaction 130 as well as the heat energy in exhaust gas of the gas turbine 110 to be converted by the Stirling engine 120 into useful work. It has a potential for commercial application in energy industry.
  • a Stirling engine 120 is used to utilize the cold energy during regasification process of LNG 130 and the low temperature heat from exhaust gas from the gas turbine 110, the large temperature difference enhances the overall thermal efficiency of the Stirling engine 120. Simultaneous utilization of cold energy and low temperature heat solves the difficulties for recovering them efficiently.
  • thermal storage system 140 on the basis of PCMs is applied to store the exhaust heat and stabilize the temperature of the exhaust gas 111 for the Stirling engine 120, operation of the power generation system 100 is more stable compared to other known systems.
  • a method 200 of generating power comprises regasifiying LNG in a regasification process to produce natural gas (210), combusting the natural gas in a gas turbine to output power and produce an exhaust gas (220), storing heat obtained from the exhaust gas in a thermal storage unit (230), and heating a hot end of a Stirling engine with heat stored in the thermal storage unit and cooling a cold end of the Stirling engine in the regasification process to output power with the Stirling engine (240).

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)

Abstract

A power generation system comprising: a liquefied natural gas (LNG) regasification unit configured to perform a regasification process to regasify LNG supplied from an LNG source to produce natural gas, the regasification process producing cold energy; a gas turbine configured to combust the natural gas to output power, the combusting producing an exhaust gas; a thermal storage unit configured to store heat obtained from the exhaust gas; and a Stirling engine configured to output power, the Stirling engine having a hot end heated by the heat stored in the thermal storage unit and a cold end cooled by the cold energy from the regasification process.

Description

POWER GENERATION SYSTEM AND METHOD
FIELD
This invention relates to a power generation system and method, and in particular to a power generation system and method fueled by liquefied natural gas.
BACKGROUND
Compared with traditional long-carbon-chain fossil fuels, natural gas has high reserves, a higher energy density, and does not contain sulphur. Natural gas fuel can produce remarkably lower emissions. It produces the lowest level of C02 in all hydrocarbon fuels. Compared to traditional fossil fuels, natural gas reduces benzene emissions by 97%, NOx emissions by 80%, carbon monoxide (CO) emissions by 76%, and C02 emissions by 22%. The use of nature gas does not produce lead, sulphur emissions, or particulate matters. When natural gas is cooled to a temperature of approximately -162 °C at atmospheric pressure, it condenses into liquefied natural gas (LNG). Since the density of LNG is 460 kg/m , the volume of LNG takes up approximately 1/600 that of natural gas. LNG is an odourless, colourless, non-corrosive, and non-toxic liquid. The unit volume reduction dramatically eases its transport. The liquefaction process of natural gas removes 02, C02, SOx, and water vapor. In addition, the lower fuel cost per unit mass of LNG becomes less in comparison with the traditional fossil fuels; LNG, mainly made up of paraffinic compounds, results in the combustion efficiency higher than that of traditional fossil fuels. Therefore, LNG is a promising fuel in the market of power generation.
Although LNG is convenient to transport and store with a specific volume compared with the gas phase, it is necessary to regasify LNG before combustion can take place in a gas turbine for stationary power generation. A large amount of cold energy can be produced during the regasification process while exhaust gas from combustion of regasified LNG in the gas turbine contains abundant low-temperature thermal energy.
Various LNG regasification systems have been disclosed, as well as systems to generate energy or power using the cold energy produced during LNG regasification. However, efficiency in regasification and power generation is still not optimized in any of the known systems, and can be further improved. SUMMARY
The present application discloses a power generation system fuelled by LNG to recover exhaust thermal energy and cold energy from LNG regasification simultaneously with one single Stirling engine.
The power generation system uses LNG (or any liquid combustible gas) for gas turbine power generation after regasification of LNG, and applies cold energy from the LNG regasification and hot energy of exhaust gas from the gas turbine to drive a Stirling engine. A thermal storage system based on phase change materials (PCMs) is used to store the exhaust heat, stabilize the temperature of the exhaust gas and supply heat to a hot end of the Stirling engine.
The advantage of this is that a higher thermal efficiency is anticipated due to the large temperature differences between the hot end and cold end. The system provides a high efficient, highly integrated, and stable combined power generation system from LNG by comprehensive utilization of energies stored in LNG, including chemical energy, cold energy, and exhaust heat after combustion.
According to a first aspect, there is provided a power generation system comprising: a liquefied natural gas (LNG) regasification unit configured to perform a regasification process to regasify LNG supplied from an LNG source to produce natural gas, the regasification process producing cold energy; a gas turbine configured to combust the natural gas to output power, the combusting producing an exhaust gas; a thermal storage unit configured to store heat obtained from the exhaust gas; and a Stirling engine configured to output power, the Stirling engine having a hot end heated by the heat stored in the thermal storage unit and a cold end cooled by the cold energy from the regasification process.
The thermal storage unit may comprise at least one phase change material.
The thermal storage unit may be embedded with the hot end of the Stirling engine.
A heat exchanger of the regasification unit may be embedded with the cold end of the Stirling engine.
According to a second aspect, there is provided a method of power generation, the method comprising the steps of:
(a) regasifiying LNG in a regasification process to produce natural gas, the regasification process producing cold energy;
(b) combusting the natural gas in a gas turbine to output power, the combusting producing an exhaust gas;
(c) storing heat obtained from the exhaust gas in a thermal storage unit; and
(d) heating a hot end of a Stirling engine with the heat stored in the thermal storage unit and cooling a cold end of the Stirling engine with cold energy from the regasification process to output power with the Stirling engine.
Storing the heat may comprise storing the heat in at least one phase change material in the thermal storage unit.
The method may further comprise directly spraying the cold end of the Stirling engine with LNG. BRIEF DESCRIPTION OF FIGURES
In order that the invention may be fully understood and readily put into practical effect there shall now be described by way of non-limitative example only exemplary embodiments of the present invention, the description being with reference to the accompanying illustrative drawings.
Fig. 1 is a schematic illustration of a power generation system.
Fig. 2 is a flow chart of a method of power generation.
DETAILED DESCRIPTION
Exemplary embodiments of the power generation system 100 will be described below with reference to Figs. 1 and 2. The same reference numerals are used throughout the figures to denote the same or similar parts among the various embodiments.
The power generation system 100 is a liquid natural gas (LNG) fuel based co-generation system 100 which comprises two engines: gas turbine engine 110 and a Stirling engine 120. In one embodiment, the gas turbine may be a 30kW turbine while the Stirling engine 120 may be a 3kW engine. However, the outputs of the gas turbine and the Stirling engine could be up to 100MW and 10MW after scaling up.
The Stirling engine 120 utilizes a known Stirling cycle for outputting mechanical work as a net conversion of heat energy from cyclic compression and expansion of a fixed mass of gas under different temperatures. The Stirling engine 120 has a cold end 121 and a hot end 122, between which the fixed mass of gas in the Stirling engine is allowed to move. At the hot end 122, the gas expands because its temperature rises due to external heat applied to the hot end 122. Expansion of the gas does work which is the output of the Stirling engine. This work is typically in the form of movement of an output piston that is moved by the gas expanding against it. Momentum obtained from the output is harnessed to compress the expanded gas. Compression of the gas increases its temperature, so cold energy is externally applied to the cold end 121 to remove heat generated by the compression. The compressed gas is once again expanded by heating at the hot end 122 to repeat the work cycle.
The gas turbine 110 consumes natural gas 131 as the fuel which is regasified from LNG 139 in a LNG regasification unit 130, and discharges high temperature exhaust gas 111. The LNG regasification unit 130 may be a double impingement unit, and is supplied with LNG 139 from an LNG storage tank 150. The power generation system 100 also includes a thermal storage system 140 on the basis of PCMs. The Stirling engine 120 is used to recover cold energy 132 from the LNG regasification process 130 and the heat energy in the exhaust gas 111 from the gas turbine 110, simultaneously. The cold energy 132 is applied to the cold end 121 of the Stirling engine 120 to remove heat generated by compression of the gas in the Stirling engine 120, while the heat energy in the exhaust gas 111 is applied to the hot end 122 of the Stirling engine to heat and thereby expand the gas in the Stirling engine 120.
A schematic illustration of the power generation system 100 is shown in Fig. 1. The first power generation subsystem 110 is the gas turbine 110. Natural gas 131, which is regasified from LNG 139 in the LNG regasification unit 130, is pumped into a combustor 119 of the gas turbine 110. The natural gas 131 may have a temperature of about 20 °C, or room temperature. Heat energy of hot exhaust gas 111 from the gas turbine 110 is stored in a PCM thermal storage tank 148 of the thermal storage system 140 into which the hot exhaust gas 111 is passed. The hot exhaust gas 111 may have a temperature of about 285 - 650 °C, while the PCM thermal storage tank 148 may have a temperature of about 220 - 600 °C, depending on the temperature of hot exhaust gas 111. Exhaust gas that leaves the PCM thermal storage tank 148 as emission 142 may have a temperature of about 200 °C.
The second power generator 120 is the Stirling engine 120 which operates between its high temperature or hot end (¾) 122 and its cold end (7c) 121. The hot end 122 is heated by a thermal fluid loop 141 of the thermal storage system 140 with heat from the PCM tank 148, and may have a temperature of about 200 - 580 °C. The cold end 121 is cooled by cold energy from a thermal fluid loop 133 of the LNG regasification unit 130, and may have a temperature of about -100 °C.
Boiling temperature (at 1 atm) of LNG is -162 °C, which significantly decreases the cold end 121 temperature of the Stirling engine 120, and increases its energy efficiency. In the power generation system 100, regasification of LNG 139 in the LNG regasification unit 130 heats the LNG 139 to produce natural gas 131 for the gas turbine 110 and also cools the cold end 121 of the Stirling engine 120. Thermal energy from the hot exhaust gas 111 of the gas turbine 110 is stored in the thermal storage unit 140 and applied to maintain the hot end 122 of the Stirling cycle 120. Aside from the Stirling engine 120, the LNG regasification unit 130 and the thermal storage unit 140 are thus two core components in the system 100.
The LNG regasification unit 130 comprises a heat exchanger 135 in which the LNG 139 absorbs heat energy and converts into gas phase 131 on one side of the heat exchanger 135. On the other side of the heat exchanger 135, the heat is taken away and the object is cooled down to a very low temperature.
In one embodiment of a compact design of the system 100, the heat exchanger 135 may be embedded in the Stirling engine 120, i.e. embedded with the cold end 121 of the Stirling engine 120, so that the heat transfer is conducted directly between the LNG 139 undergoing regasification in the regasification unit 130 and the Stirling engine 120.
In order to enhance heat transfer rate as well as the LNG phase change rate, LNG 139 from the LNG storage tank 150 may also simultaneously be sprayed (or otherwise impinged) onto the cold end 121 of the Stirling engine 120.
To enable the Stirling cycle power generation system 120 to achieve stable electric output, the thermal storage 140 can be integrated into the power generation system 120 to allow thermal energy to be stored and dispatched when power is required. PCMs are employed as the storage media in the thermal storage tank 148. Operating around a melting point of PCM stabilizes the temperature of the hot end 122 of the Stirling engine 120, thereby maintaining the hot end 122 of the Stirling cycle 120.
The exhaust gas 111 flows over the PCM tank 148 to charge the thermal storage system 140. The PCM tank 148 collects the heat from the exhaust gas 111 of the gas turbine 110 during operation. The heat transfer fluids 141 are circulated by a pump (not shown) to discharge the heat from the thermal storage tank 140. The heated heat transfer fluids 141 then send the heat to the Stirling engine 120 power generation system. The cooled heat transfer fluids 149 return to the PCM storage tank 148 for the next cycle. Pre-heating elements (not shown) are preferably installed in the tanks 148 to melt the PCMs at the beginning. Another function of the pre-heating elements is to make up the heat of the PCMs when it is in an emergent freeze situation. The tank 148 will be operated at atmospheric pressure, similar to commercial oil storage tanks. The proposed tanks 148 are preferably fabricated from stainless steel, and use self-supporting roofs. A heat exchanging tube for transferring thermal energy to superheat vapor is preferably be installed. To reduce heat loss, wall, bottom, and roof of the tanks 148 are insulated preferably with mineral wool batts and calcium silicate block insulation, respectively. The insulated foundation preferably comprises the following layers; (1) concrete slab, (2) foam glass insulation, (3) insulating fire bricks, (4) thin steel plate liner, and (5) sand. A perimeter ring wall of insulating firebricks is preferably provided to support the weight of the walls and roof of the tank 148.
Alternatively, the thermal storage unit 140 also can be embedded in the Stirling engine 120, i.e., directly coupled with the hot end 122 of the Stirling engine 120, to make the system 100 more compact. In this case, the thermal fluid cycle is no longer needed as heat transfer is performed directly between the PCMs of the thermal storage unit 140 and the hot end 122 of the Stirling engine 120.
It can be predicted that LNG is promising in the market of power generation. Natural gas (NG) is an environmentally friendly fuel which is still in high reserve on earth. However, far field transportation of NG is necessary due to significant diversity of distribution of NG on the planet. The most common and economical way to transport NG is to ship the liquid phase as LNG. After delivery, LNG needs to be regasified into gas phase for utilization. The more popular NG is as a fuel in the global market, the more LNG transportation and regasification will be performed. This translates into a large amount of cold energy being produced in the LNG regasification process. On the other hand, gas turbine power generator is still a very important method to supply electricity in many countries which produces a significant amount of waste heat. It is estimated that cold energy with an amount of 100 MJ will be output per hour for each MWe of power generation for a high efficiency power plant (such as TITAN250 with a capacity of 21.75 MWe). This accounts for just the latent heat of LNG-to-NG phase change alone. The value will be higher if sensible energy is accounted for. Power plants with low capacity (such as SATURN20 with a capacity of 1.21 MWe) consume 50% more fuels and waste around 150 MJ cold energy per hour for each MWe of power generation.
Therefore, the currently disclosed power generation system 100 presents an innovative method to recover this huge amount of cold energy from LNG regasifiaction 130 as well as the heat energy in exhaust gas of the gas turbine 110 to be converted by the Stirling engine 120 into useful work. It has a potential for commercial application in energy industry.
Among the advantages of the power generation system 100, because a Stirling engine 120 is used to utilize the cold energy during regasification process of LNG 130 and the low temperature heat from exhaust gas from the gas turbine 110, the large temperature difference enhances the overall thermal efficiency of the Stirling engine 120. Simultaneous utilization of cold energy and low temperature heat solves the difficulties for recovering them efficiently.
As the thermal storage system 140 on the basis of PCMs is applied to store the exhaust heat and stabilize the temperature of the exhaust gas 111 for the Stirling engine 120, operation of the power generation system 100 is more stable compared to other known systems.
With the power generation system 100, energy stored in LNG 139 including chemical energy and cold energy, and low temperature heat from exhaust gas 111 are all efficiently harnessed. All energy sources for the power generation system 100 come from LNG, and no extra energy sources or fuels are needed. By using LNG cold energy 133 and the gas turbine exhaust heat 111 simultaneously, high efficient recovery of both energies can be achieved with the Stirling engine 120 due to enhancement of thermal efficiency from the large temperature difference and the inherent high efficiency of the Stirling engine 120. Overall efficiency is expected to have an improvement of about 5% to 30% compared with conventional LNG fueled gas turbine power generation systems without recovery of cold energy and exhaust heat.
Using the power generation system 100 described above, referring to Fig. 2, a method 200 of generating power comprises regasifiying LNG in a regasification process to produce natural gas (210), combusting the natural gas in a gas turbine to output power and produce an exhaust gas (220), storing heat obtained from the exhaust gas in a thermal storage unit (230), and heating a hot end of a Stirling engine with heat stored in the thermal storage unit and cooling a cold end of the Stirling engine in the regasification process to output power with the Stirling engine (240).
Whilst there has been described in the foregoing description exemplary embodiments of the present invention, it will be understood by those skilled in the technology concerned that many variations and combinations in details of design, construction and/or operation may be made without departing from the present invention.

Claims

A power generation system comprising:
a liquefied natural gas (LNG) regasification unit configured to perform a regasification process to regasify LNG supplied from an LNG source to produce natural gas, the regasification process producing cold energy;
a gas turbine configured to combust the natural gas to output power, the combusting producing an exhaust gas;
a thermal storage unit configured to store heat obtained from the exhaust gas; and a Stirling engine configured to output power, the Stirling engine having a hot end heated by the heat stored in the thermal storage unit and a cold end cooled by the cold energy from the regasification process.
The power generation system of claim 1 , wherein the thermal storage unit comprises at least one phase change material.
The power generation system of claim 1 or claim 2, wherein the thermal storage unit is embedded with the hot end of the Stirling engine.
The power generation system of any one of the preceding claims, wherein a heat exchanger of the regasification unit is embedded with the cold end of the Stirling engine.
A method of power generation, the method comprising the steps of:
(a) regasifiying LNG in a regasification process to produce natural gas, the regasification process producing cold energy;
(b) combusting the natural gas in a gas turbine to output power, the combusting producing an exhaust gas;
(c) storing heat obtained from the exhaust gas in a thermal storage unit; and
(d) heating a hot end of a Stirling engine with the heat stored in the thermal storage unit and cooling a cold end of the Stirling engine with cold energy from the regasification process to output power with the Stirling engine.
6. The method of claim 5, wherein storing the heat comprises storing the heat in at least one phase change material in the thermal storage unit.
7. The method of claim 5 or claim 6, further comprising directly spraying the cold end of the Stirling engine with LNG.
PCT/SG2016/050446 2015-09-15 2016-09-15 Power generation system and method Ceased WO2017048192A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US15/759,826 US10577983B2 (en) 2015-09-15 2016-09-15 Power generation system and method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SG10201507652V 2015-09-15
SG10201507652V 2015-09-15

Publications (1)

Publication Number Publication Date
WO2017048192A1 true WO2017048192A1 (en) 2017-03-23

Family

ID=58289241

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SG2016/050446 Ceased WO2017048192A1 (en) 2015-09-15 2016-09-15 Power generation system and method

Country Status (2)

Country Link
US (1) US10577983B2 (en)
WO (1) WO2017048192A1 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107933328A (en) * 2017-11-15 2018-04-20 瑞华特装(天津)低温设备有限公司 A kind of electric automobile LNG distance increasing units
CN109882292A (en) * 2019-03-27 2019-06-14 赫普科技发展(北京)有限公司 A LNG gas turbine coupled cold energy power generation system and power generation method
US10577983B2 (en) 2015-09-15 2020-03-03 Nanyang Technological University Power generation system and method
WO2022007918A1 (en) * 2020-07-09 2022-01-13 林曦 Waste heat energy conversion system
FR3152541A1 (en) * 2023-09-06 2025-03-07 Yves Vandecandelaere Steam and Stirling Engine Powered Renewable Energy Generator Set

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2017016744A (en) * 2017-12-19 2019-06-20 Centro De Investigacion En Mat Avanzados S C Cogeneration system for integration into solar water heating systems.
CN109538322A (en) * 2018-11-28 2019-03-29 华电电力科学研究院有限公司 A kind of LNG gasification system and working method based on stirling generator group
WO2022191771A1 (en) * 2021-03-10 2022-09-15 Lim Shao Lin A cooling system
CN116717321A (en) * 2023-06-07 2023-09-08 毕节高新技术产业开发区国家能源大规模物理储能技术研发中心 Regenerative natural gas residual pressure utilization system

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3937017A (en) * 1973-08-09 1976-02-10 Maschinenfabrik Augsburg-Nurnberg Aktiengesellschaft External combustion hot gas engine system
RU2166705C1 (en) * 1999-11-01 2001-05-10 Военный инженерно-космический университет им. А.Ф. Можайского High-efficiency power refrigerating plant
JP2006200431A (en) * 2005-01-20 2006-08-03 Nissan Diesel Motor Co Ltd Engine system
JP2008175151A (en) * 2007-01-19 2008-07-31 Chugoku Electric Power Co Inc:The Cogeneration system using cold of liquefied gas and method for operating same
CN102434257A (en) * 2011-11-17 2012-05-02 徐明奇 Waste heat power generation device for vehicle and ship engines
US20130091839A1 (en) * 2010-06-09 2013-04-18 Chubu Electric Power Company, Incorporated Power recovery system
JP2014207719A (en) * 2011-07-08 2014-10-30 川崎重工業株式会社 Hybrid power system
US20150053367A1 (en) * 2011-08-09 2015-02-26 Neil Parkinson Thermal Energy Storage Apparatus

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4462212A (en) * 1981-12-30 1984-07-31 Knoeoes Stellan Unitary heat engine/heat pump system
US5127369A (en) * 1991-05-21 1992-07-07 Goldshtik Mikhail A Engine employing rotating liquid as a piston
JP4174619B2 (en) * 2001-10-11 2008-11-05 株式会社レーベン販売 External combustion engine driven by heat pump
US7694514B2 (en) * 2007-08-08 2010-04-13 Cool Energy, Inc. Direct contact thermal exchange heat engine or heat pump
US20100212656A1 (en) * 2008-07-10 2010-08-26 Infinia Corporation Thermal energy storage device
JP5523935B2 (en) * 2010-06-09 2014-06-18 株式会社神戸製鋼所 Vaporization method, vaporization apparatus used therefor, and vaporization system provided with the same
WO2017048192A1 (en) 2015-09-15 2017-03-23 Nanyang Technological University Power generation system and method

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3937017A (en) * 1973-08-09 1976-02-10 Maschinenfabrik Augsburg-Nurnberg Aktiengesellschaft External combustion hot gas engine system
RU2166705C1 (en) * 1999-11-01 2001-05-10 Военный инженерно-космический университет им. А.Ф. Можайского High-efficiency power refrigerating plant
JP2006200431A (en) * 2005-01-20 2006-08-03 Nissan Diesel Motor Co Ltd Engine system
JP2008175151A (en) * 2007-01-19 2008-07-31 Chugoku Electric Power Co Inc:The Cogeneration system using cold of liquefied gas and method for operating same
US20130091839A1 (en) * 2010-06-09 2013-04-18 Chubu Electric Power Company, Incorporated Power recovery system
JP2014207719A (en) * 2011-07-08 2014-10-30 川崎重工業株式会社 Hybrid power system
US20150053367A1 (en) * 2011-08-09 2015-02-26 Neil Parkinson Thermal Energy Storage Apparatus
CN102434257A (en) * 2011-11-17 2012-05-02 徐明奇 Waste heat power generation device for vehicle and ship engines

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10577983B2 (en) 2015-09-15 2020-03-03 Nanyang Technological University Power generation system and method
CN107933328A (en) * 2017-11-15 2018-04-20 瑞华特装(天津)低温设备有限公司 A kind of electric automobile LNG distance increasing units
CN109882292A (en) * 2019-03-27 2019-06-14 赫普科技发展(北京)有限公司 A LNG gas turbine coupled cold energy power generation system and power generation method
WO2022007918A1 (en) * 2020-07-09 2022-01-13 林曦 Waste heat energy conversion system
FR3152541A1 (en) * 2023-09-06 2025-03-07 Yves Vandecandelaere Steam and Stirling Engine Powered Renewable Energy Generator Set

Also Published As

Publication number Publication date
US10577983B2 (en) 2020-03-03
US20180266279A1 (en) 2018-09-20

Similar Documents

Publication Publication Date Title
US10577983B2 (en) Power generation system and method
Ding et al. Liquid air energy storage
EP2753861B2 (en) Method and apparatus for power storage
Li et al. Load shifting of nuclear power plants using cryogenic energy storage technology
Medrano et al. State of the art on high-temperature thermal energy storage for power generation. Part 2—Case studies
CN102758690B (en) Efficient high-pressure liquid air energy storage/release system
CN102822614B (en) Systems and methods of thermal transfer and/or storage
EP2602443A1 (en) Electricity storage
US20150000248A1 (en) Combined Cycle CAES Technology (CCC)
Ghilardi et al. Integration of ocean thermal energy conversion and pumped thermal energy storage: system design, off-design and LCOS evaluation
KR102084796B1 (en) A system for saving and generating the electric power using supercritical carbon dioxide
CN109386316A (en) A kind of LNG cold energy and BOG Combustion Energy joint utilize system and method
He et al. Thermo-conversion of a physical energy storage system with high-energy density: Combination of thermal energy storage and gas-steam combined cycle
JP2009540238A (en) Liquefied natural gas (LNG) vaporization and storage method, and plant
CN107060927A (en) Waste heat recycling system and its method and power station
RU2273742C1 (en) Energy-accumulating plant
Łaciak et al. Possibilities of Liquefied Natural Gas (LNG) use for power generation
Najjar et al. Using novel compressed‐air energy storage systems as a green strategy in sustainable power generation–a review
Wang et al. Comparative study of an innovative coldly integrated pumped thermal electricity storage system: Thermo-economic assessment and multi-objective optimization
Nasir et al. A review on technologies with electricity generation potentials using liquified natural gas regasification cold energy
Wu et al. Performance simulation on NG/O2 combustion gas and steam mixture cycle with energy storage and CO2 capture
CN202811238U (en) High-pressure liquid-state air energy storage/release system
Guo et al. Optimization of dynamic compressed CO2 energy storage system: The role of supercritical fluid properties
Zhang et al. An integrated energy storage system coupling Ca (OH) 2/CaO/CaCO3 thermochemical energy storage, supercritical CO2 cycle, and CO2 capture
CN114555915B (en) Method for liquefying and storing carbon dioxide in carbon dioxide power plant

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 16846969

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 11201801740R

Country of ref document: SG

WWE Wipo information: entry into national phase

Ref document number: 15759826

Country of ref document: US

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 16846969

Country of ref document: EP

Kind code of ref document: A1