WO2016196688A8 - Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings - Google Patents

Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings Download PDF

Info

Publication number
WO2016196688A8
WO2016196688A8 PCT/US2016/035353 US2016035353W WO2016196688A8 WO 2016196688 A8 WO2016196688 A8 WO 2016196688A8 US 2016035353 W US2016035353 W US 2016035353W WO 2016196688 A8 WO2016196688 A8 WO 2016196688A8
Authority
WO
WIPO (PCT)
Prior art keywords
active materials
nano
solid
coating
solid electrolyte
Prior art date
Application number
PCT/US2016/035353
Other languages
French (fr)
Other versions
WO2016196688A1 (en
Inventor
Fabio Albano
Kevin DAHLBERG
Erik Anderson
Subhash Dhar
Srinlvasan VENKATESAN
James Trevey
David M. KING
Paul R. LICHTY
Original Assignee
Energy Power Systems LLC
Pneumaticoat Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US14/727,834 external-priority patent/US12027661B2/en
Priority claimed from US15/167,453 external-priority patent/US11996564B2/en
Priority to EP16804367.7A priority Critical patent/EP3304635A4/en
Priority to JP2017562061A priority patent/JP6932321B2/en
Priority to CN201680032297.7A priority patent/CN107851840B/en
Priority to CA2987938A priority patent/CA2987938C/en
Priority to KR1020207002674A priority patent/KR102470625B1/en
Priority to KR1020177036739A priority patent/KR20180011207A/en
Application filed by Energy Power Systems LLC, Pneumaticoat Technologies Llc filed Critical Energy Power Systems LLC
Priority to KR1020217012500A priority patent/KR20210048607A/en
Priority claimed from US15/170,374 external-priority patent/US20160351973A1/en
Priority to KR1020227040748A priority patent/KR20220161493A/en
Priority to AU2016270820A priority patent/AU2016270820A1/en
Publication of WO2016196688A1 publication Critical patent/WO2016196688A1/en
Publication of WO2016196688A8 publication Critical patent/WO2016196688A8/en
Priority to HK18112997.8A priority patent/HK1253979A1/en
Priority to AU2019240681A priority patent/AU2019240681B2/en
Priority to AU2022201282A priority patent/AU2022201282B2/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/18Cells with non-aqueous electrolyte with solid electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562Solid materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/366Composites as layered products
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/18Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/188Processes of manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0068Solid electrolytes inorganic
    • H01M2300/0071Oxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0068Solid electrolytes inorganic
    • H01M2300/008Halides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/18Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/182Cells with non-aqueous electrolyte with solid electrolyte with halogenide as solid electrolyte
    • H01M6/183Cells with non-aqueous electrolyte with solid electrolyte with halogenide as solid electrolyte with fluoride as solid electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/18Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/185Cells with non-aqueous electrolyte with solid electrolyte with oxides, hydroxides or oxysalts as solid electrolytes
    • H01M6/186Only oxysalts-containing solid electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

The present disclosure relates to a nano-engineered coating for cathode active materials, anode active materials, and solid state electrolyte materials for reducing corrosion and enhancing cycle life of a battery, and processes for applying the disclosed coating. Also disclosed is a solid state battery including a solid electrolyte layer having a solid electrolyte particle coated by a protective coating with a thickness of 100 nm or less. The protective coating is obtained by atomic layer deposition (ALD) or molecular layer deposition (MLD). Further disclosed is a solid electrolyte layer for a solid state battery, including a porous scaffold coated by a first, solid electrolyte coating. The solid electrolyte coating has a thickness of 60 μηι or less and a weight loading of at least 20 wt.% (or preferable at least 40 wt.% or at least 50 wt.%). Further disclosed is a cathode composite layer for a solid state battery.
PCT/US2016/035353 2015-06-01 2016-06-01 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings WO2016196688A1 (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
KR1020227040748A KR20220161493A (en) 2015-06-01 2016-06-01 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings
AU2016270820A AU2016270820A1 (en) 2015-06-01 2016-06-01 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings
KR1020217012500A KR20210048607A (en) 2015-06-01 2016-06-01 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings
CN201680032297.7A CN107851840B (en) 2015-06-01 2016-06-01 Nano-engineered coatings for solid state electrolytes
CA2987938A CA2987938C (en) 2015-06-01 2016-06-01 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings
KR1020207002674A KR102470625B1 (en) 2015-06-01 2016-06-01 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings
KR1020177036739A KR20180011207A (en) 2015-06-01 2016-06-01 Method for manufacturing a battery containing a nano-engineered coating and a nano-engineered coating for an anode active material, a cathode active material, and a solid-state electrolyte
EP16804367.7A EP3304635A4 (en) 2015-06-01 2016-06-01 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings
JP2017562061A JP6932321B2 (en) 2015-06-01 2016-06-01 Methods for Manufacturing Batteries Containing Nano-Processed Coatings and Nano-Processed Coatings for Anode Active Materials, Cathodic Active Materials and Solid Electrolytes
HK18112997.8A HK1253979A1 (en) 2015-06-01 2018-10-11 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings
AU2019240681A AU2019240681B2 (en) 2015-06-01 2019-10-03 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings
AU2022201282A AU2022201282B2 (en) 2015-06-01 2022-02-24 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US14/727,834 US12027661B2 (en) 2015-06-01 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings
US14/727,834 2015-06-01
US201662312277P 2016-03-23 2016-03-23
US62/312,277 2016-03-23
US62/312,227 2016-03-23
US15/167,453 2016-05-27
US15/167,453 US11996564B2 (en) 2015-06-01 2016-05-27 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings
US15/170,374 2016-06-01
US15/170,374 US20160351973A1 (en) 2015-06-01 2016-06-01 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings

Publications (2)

Publication Number Publication Date
WO2016196688A1 WO2016196688A1 (en) 2016-12-08
WO2016196688A8 true WO2016196688A8 (en) 2017-06-08

Family

ID=57441922

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2016/035353 WO2016196688A1 (en) 2015-06-01 2016-06-01 Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings

Country Status (1)

Country Link
WO (1) WO2016196688A1 (en)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11996564B2 (en) 2015-06-01 2024-05-28 Forge Nano Inc. Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings
US10854930B2 (en) 2016-10-07 2020-12-01 The Regents Of The University Of Michigan Stabilization coatings for solid state batteries
CN110249454B (en) 2017-01-23 2023-09-29 巴斯夫欧洲公司 Method for producing cathode material and reactor suitable for carrying out said method
EP3583643B1 (en) * 2017-02-17 2020-09-30 Evonik Operations GmbH Mixed lithium oxides coated with aluminium oxide and titanium oxide and process for making them
US10629949B2 (en) * 2017-04-24 2020-04-21 GM Global Technology Operations LLC Passivation of sulfide, oxide, and oxysulfide glass electrolyte films for lithium metal batteries
JP6848749B2 (en) * 2017-07-26 2021-03-24 トヨタ自動車株式会社 Secondary battery
CN107768595A (en) * 2017-10-20 2018-03-06 中国人民解放军国防科技大学 Lithium ion battery negative pole piece, preparation method thereof and lithium ion battery
KR20200104293A (en) * 2017-11-13 2020-09-03 더 리전츠 오브 더 유니버시티 오브 콜로라도, 어 바디 코퍼레이트 Thin film coating on mixed metal oxide
CN109935796A (en) * 2017-12-19 2019-06-25 成都亦道科技合伙企业(有限合伙) A kind of total oxygen compound solid state lithium battery structure and preparation method thereof
CN108155410A (en) * 2017-12-19 2018-06-12 成都亦道科技合伙企业(有限合伙) Solid electrolyte structure and preparation method thereof, lithium battery
CN109935825A (en) * 2017-12-19 2019-06-25 成都亦道科技合伙企业(有限合伙) A kind of lithium battery structure and preparation method thereof
CN109935909A (en) * 2017-12-19 2019-06-25 成都亦道科技合伙企业(有限合伙) A kind of lithium an- ode battery structure and preparation method thereof
CN108172784A (en) * 2017-12-19 2018-06-15 成都亦道科技合伙企业(有限合伙) A kind of lithium silicon-carbon composite cathode lithium battery structure and preparation method thereof
EP3750205B1 (en) * 2018-02-09 2021-09-01 Basf Se Process for making an electrode active material, and electrode active material
DE102019203546A1 (en) * 2018-04-23 2019-10-24 Volkswagen Aktiengesellschaft Particulate silicon-containing active material, negative electrode, lithium-ion battery cell, vehicle and method for producing active material and electrode
DE102018114009A1 (en) * 2018-06-12 2019-12-12 Volkswagen Aktiengesellschaft Active material body for a rechargeable battery
DE102018121275A1 (en) 2018-08-31 2020-03-05 Volkswagen Aktiengesellschaft Method and system for the deposition of a solid electrolyte on electrode active material
CN109768318A (en) * 2019-03-12 2019-05-17 浙江锋锂新能源科技有限公司 A kind of mixing solid-liquid electrolyte lithium battery
EP3832757A1 (en) 2019-12-03 2021-06-09 Belenos Clean Power Holding AG Single-ion conductive polymers for electrochemical devices
CN111600007A (en) * 2020-02-21 2020-08-28 华鼎国联四川动力电池有限公司 Lithium ion battery negative pole piece with artificial SEI film and preparation method thereof
CN111600014B (en) * 2020-05-26 2022-11-22 宁波容百新能源科技股份有限公司 Modified high-specific-capacity high-nickel ternary cathode material and preparation method thereof
CN114014285B (en) * 2020-07-16 2023-01-13 中国科学院金属研究所 Ion-conducting membrane based on two-dimensional material containing metal vacancies and preparation method thereof
CN112209393B (en) * 2020-09-25 2022-06-03 电子科技大学 Preparation method and application of aqueous all-inorganic solid electrolyte
CN112117451A (en) * 2020-09-29 2020-12-22 山东省科学院能源研究所 Mixed-phase titanium dioxide modified high-nickel ternary cathode material and preparation method and application thereof
CN113517424A (en) * 2021-04-27 2021-10-19 湖南杉杉能源科技股份有限公司 Cobalt-free positive electrode material of high-voltage lithium ion battery and preparation method thereof
CN114156478B (en) * 2021-11-30 2023-09-05 厦门韫茂科技有限公司 Positive electrode material coated with co-embedded film, preparation method and lithium ion battery
WO2023114502A1 (en) 2021-12-17 2023-06-22 Solid Power Operating, Inc. Method for production of lithium carbonate coatings for nickel-based cathodes and electrochemical cells using same
CN114133003B (en) * 2021-12-31 2022-11-11 西安建筑科技大学 Construction method of magnetic sandwich titanium-based composite anode
CN114927650B (en) * 2022-06-21 2024-06-25 银叶元素公司 Preparation method and application of silicon-based negative electrode coated by high-molecular polyurea coating

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6468657B1 (en) * 1998-12-04 2002-10-22 The Regents Of The University Of California Controllable ion-exchange membranes
US20080057386A1 (en) * 2002-10-15 2008-03-06 Polyplus Battery Company Ionically conductive membranes for protection of active metal anodes and battery cells
US20050233214A1 (en) * 2003-11-21 2005-10-20 Marple Jack W High discharge capacity lithium battery
KR101201170B1 (en) * 2006-03-21 2012-11-13 삼성에스디아이 주식회사 Positive electrode for lithium rechargeable battery and Lithium rechargeable battery comprising the same and Method of making the lithium rechargeable battery
US9236612B2 (en) * 2007-11-14 2016-01-12 Kureha Corporation Positive electrode mixture for nonaqueous battery and positive electrode structure
US8236452B2 (en) * 2009-11-02 2012-08-07 Nanotek Instruments, Inc. Nano-structured anode compositions for lithium metal and lithium metal-air secondary batteries
US20120301778A1 (en) * 2011-03-17 2012-11-29 James Trevey Solid-state multi-layer electrolyte, electrochemical cell and battery including the electrolyte, and method of forming same

Also Published As

Publication number Publication date
WO2016196688A1 (en) 2016-12-08

Similar Documents

Publication Publication Date Title
WO2016196688A8 (en) Nano-engineered coatings for anode active materials, cathode active materials, and solid-state electrolytes and methods of making batteries containing nano-engineered coatings
JP2020047597A5 (en) Method for producing positive electrode active material and method for producing lithium ion secondary battery
WO2014093519A8 (en) Ceramic coating on battery separators
JP2017527970A5 (en)
CN102916149B (en) A kind of lithium battery micro-pore septum and preparation technology thereof
CN104617328B (en) A kind of long-life lithium rechargeable battery and its manufacture method
WO2009107964A3 (en) Anode coated with lithium fluoride compounds, method for preparing the same, and lithium secondary battery having the same
WO2011112042A3 (en) Organic polymer-silicon composite particle, preparation method for same, and cathode and lithium secondary battery including same
WO2011062998A3 (en) Anodes for lithium ion batteries
WO2011142575A3 (en) Anode active material for a lithium secondary battery, method for preparing same, and lithium secondary battery including same
WO2016209460A3 (en) High energy density hybrid pseudocapacitors and method of making and using the same
WO2016062126A1 (en) Method and apparatus for preparation of composite membrane for lithium batteries by multilayer co-extrusion coating
WO2016057457A3 (en) Electolyte composition for a zinc-halide battery and bipolar electrode comprising a titanium carbide coated cathode box
RU2015144166A (en) COMPOSITIONS FOR PRELIMINARY PROCESSING, AND ALSO WAYS OF COATING THE BATTERY ELECTRODE
WO2012074300A3 (en) Lithium secondary battery
WO2012013685A3 (en) Carbon coated lithium transition metal phosphate and process for its manufacture
TW201130186A (en) Metal oxide coated positive electrode materials for lithium-based batteries
EP2223368A4 (en) Negative electrode for battery and lithium battery using the same
WO2010138760A3 (en) Novel composite anode materials for lithium ion batteries
Oltean et al. On the origin of the capacity fading for aluminium negative electrodes in Li-ion batteries
EP2466678A4 (en) Lithium secondary battery
BR112012009165A2 (en) structured silicon battery anodes
WO2015102701A3 (en) Formation of solid oxide fuel cells
RU2016149759A (en) BATTERY WITH A NON-AQUEOUS ELECTROLYTE
SG155121A1 (en) Anode and secondary battery

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 16804367

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2017562061

Country of ref document: JP

Kind code of ref document: A

ENP Entry into the national phase

Ref document number: 2987938

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 20177036739

Country of ref document: KR

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 2016804367

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 2016270820

Country of ref document: AU

Date of ref document: 20160601

Kind code of ref document: A