WO2016186316A1 - Air purifier - Google Patents

Air purifier Download PDF

Info

Publication number
WO2016186316A1
WO2016186316A1 PCT/KR2016/003293 KR2016003293W WO2016186316A1 WO 2016186316 A1 WO2016186316 A1 WO 2016186316A1 KR 2016003293 W KR2016003293 W KR 2016003293W WO 2016186316 A1 WO2016186316 A1 WO 2016186316A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
parts
heating element
air
steam
Prior art date
Application number
PCT/KR2016/003293
Other languages
French (fr)
Korean (ko)
Inventor
김윤진
조진우
신권우
박지선
Original Assignee
주식회사 대화알로이테크
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 주식회사 대화알로이테크 filed Critical 주식회사 대화알로이테크
Publication of WO2016186316A1 publication Critical patent/WO2016186316A1/en

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D45/00Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
    • B01D45/12Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/24Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by centrifugal force
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B04CENTRIFUGAL APPARATUS OR MACHINES FOR CARRYING-OUT PHYSICAL OR CHEMICAL PROCESSES
    • B04CAPPARATUS USING FREE VORTEX FLOW, e.g. CYCLONES
    • B04C9/00Combinations with other devices, e.g. fans, expansion chambers, diffusors, water locks
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/10Heater elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12Heater elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • H05B3/14Heater elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/20Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater

Definitions

  • the present invention relates to an air cleaner using a plane heater.
  • the present invention relates to an air cleaner, and more particularly, to an air cleaner that can effectively remove fine dust particles.
  • an air cleaner is a device that filters air or dust in the air to clean the air.
  • the air cleaner can be broadly divided into a stand type and a side table according to its shape.
  • the present invention will be described by taking a stand type as an example.
  • FIG. 1 is a perspective view showing the appearance of a conventional air cleaner
  • Figure 2 is a cross-sectional view showing the internal configuration of a conventional air cleaner.
  • the first suction port 11 is formed in the upper front of the main body 10
  • the second suction opening 12 is formed in the lower portion
  • the discharge port 13 is formed in the upper side and the upper portion
  • the operation panel 14 is provided.
  • the interior of the main body 10 is divided into a first dust collecting space 15 and a second dust collecting space 16 of the lower, the first dust collecting space for collecting small dust particles in the first dust collecting space 15 of the upper
  • the apparatus 20 is installed and behind it is a first blower 30 composed of a blower fan 32 and a motor 33 for blowing the purified air toward the discharge port 13.
  • a second dust collecting device 40 for collecting large dust particles is installed and blown to suck air from the second suction opening 12 and blow the air toward the second dust collecting device 40.
  • the second blower 50 composed of the fan 52 and the motor 53 is installed.
  • a communication passage 61 is formed in a partition plate partitioning the first dust collecting space 15 and the second dust collecting space 16, and fine dust passing through the second dust collecting device 40 is filtered through the communication passage 61.
  • Intermediate filter 62 is installed to allow.
  • the antimicrobial prefilter 21 In the first dust collecting device 20, the antimicrobial prefilter 21, the electrostatic precipitating electrostatic filter 22, and the fine dust collecting filter 23 are arranged in order from the front to the rear.
  • the second dust collector 40 has an inlet 42 is formed in the upper side portion, the outlet 44 is formed in the upper central portion and the cyclone dust collector 41 formed with a dust outlet 43 in the lower portion and installed below The dust collecting container 46 is included.
  • the conventional air cleaner configured as described above is operated as follows.
  • the first and second blowers 30 and 50 operate to thereby operate the indoors through the first and second suction ports 11 and 12. Inhalation of the air takes place. At this time, since the dust contained in the inhaled air has relatively small dust particles on the upper side and relatively large dust particles on the lower portion due to the specific gravity difference, small dust particles are sucked toward the first suction opening 11 and the second suction opening. Large dust particles are sucked toward (12).
  • the small dust particles sucked together with the air through the upper first suction port 11 are collected while passing through the filters of the first dust collector 20 in sequence.
  • the air purified through the first dust collecting device 20 is blown toward the discharge port 13 by the operation of the first blowing device 30 and then supplied to the indoor space.
  • the primary purified air passing through the cyclone dust collecting container 41 passes through the intermediate filter 62 made of the fine dust collecting filter and flows into the first dust collecting space 15 to perform secondary purification. That is, fine dust that is not collected while passing through the cyclone dust collector 41 is collected through the intermediate filter 62.
  • the air purified through the intermediate filter 62 is blown toward the discharge port 13 by the operation of the first blower 30 together with the purified air while passing through the first dust collector 20, and then supplied to the indoor space. do.
  • the problem to be solved by the present invention is to provide an air purifier capable of maximizing the amount of dust collected by the cyclone by generating a steam plasma.
  • the problem to be solved by the present invention is to provide an air purifier capable of rapidly generating steam by using a heater including a planar heating element.
  • the air purifier according to an embodiment of the present invention.
  • a dust collecting unit for purifying the air flowing from the suction port;
  • a steam plasma generating module for supplying steam to the air introduced from the suction port to the dust collecting unit, wherein the steam plasma generating module comprises: a water storage unit; A heater composed of a surface heating element for heating water in the water storage part; And an electrode for discharging steam generated by the heater.
  • the planar heating element is 3 to 6 parts by weight of carbon nanotube particles, 0.5 to 30 parts by weight of carbon nanoparticles, 10 to 30 parts by weight of a mixed binder, 29 to 83 parts by weight of an organic solvent, and 0.5 wt.
  • the mixed binder includes an epoxy acrylate, a polyvinyl acetal, and a phenolic resin, or a hexamethylene diisocyanate, polyvinyl acetal, and a phenolic resin.
  • the mixed binder may be 10 to 150 parts by weight of polyvinyl acetal resin, 100 to 500 parts by weight of phenolic resin based on 100 parts by weight of epoxy acrylate or hexamethylene diisocyanate.
  • the air purifier may further include 0.5 to 5 parts by weight of the silane coupling agent based on 100 parts by weight of the heating paste composition.
  • the carbon nanotube particles may be multi-walled carbon nanotube particles.
  • the organic solvent is selected from carbitol acetate, butyl carbitol acetate, DBE (dibasic ester), ethyl carbitol, ethyl carbitol acetate, dipropylene glycol methyl ether, cellosolve acetate, butyl cellosolve acetate, butanol and octanol May be two or more mixed solvents.
  • the heating paste composition may be formed by screen printing, gravure printing or comma coating on a substrate.
  • the substrate may be a polyimide substrate, fiberglass mat or ceramic glass.
  • the coating on the top surface of the planar heating element may further include a protective layer formed of an organic material having a black pigment, such as silica or carbon shock rack.
  • water can be heated quickly to generate steam, and by supplying steam plasma to the air, the fine dust particles are formed into large dust masses by agglomeration of steam plasma, and then a cyclone Purification ability can be improved by collecting dust.
  • FIG. 1 is a perspective view showing the appearance of a conventional air cleaner
  • Figure 2 is a cross-sectional view showing the internal configuration of a conventional air cleaner
  • Figure 3 is a perspective view showing the configuration of an air cleaner according to an embodiment of the present invention.
  • FIG. 4 is a side view of FIG. 3
  • FIG. 5 is a perspective view illustrating an appearance of the steam plasma generating module of FIG. 3.
  • FIG. 6 is a cutaway perspective view taken along the line VI-VI of FIG. 5; FIG.
  • FIG. 7 is a perspective view of the cut along the cutting line VII-VII of FIG.
  • FIG. 8 is a perspective view of the cut along the cutting line VIII-VIII of FIG.
  • Figure 3 is a perspective view showing the configuration of an air cleaner according to an embodiment of the present invention
  • Figure 4 is a side view of Figure 3
  • Figure 5 is a perspective view showing the appearance of the steam plasma generating module of Figure 3
  • Figure 6 is Figure 5
  • Fig. 7 is a cutaway perspective view taken along the cutting line VI-VI
  • Fig. 7 is a cutaway perspective view taken along the cutting line VII-VII of Fig. 5
  • Fig. 8 is a cutaway perspective view taken along the cutting line VIII-VIII of Fig. 5.
  • the air cleaner 1 according to an embodiment of the present invention, the main body 10 having an external shape of a rectangular parallelepiped, and the suction port 12 formed on the front surface of the main body 10 And a dust collecting part 70 formed inside the main body 10 to purify the air introduced from the suction port 12, a suction duct 20 connecting the suction port 12 and the dust collecting part 70, and a suction duct ( Steam plasma generating module 100 for supplying steam to the lower portion of the 20, the blowing fan 52 is formed on the upper side of the dust collecting portion 70 to suck the outside air from the inlet 12, the dust collecting portion 70 and blowing It comprises a filtration filter 80 formed between the fan 52, and the discharge port 13 for discharging the air purified by the dust collecting section 70 and the filtration filter 80.
  • the main body 10 includes an operation panel 14 in which a control button for displaying and controlling the operation state of the air cleaner 1 is formed.
  • the dust collector 70 has a conical shape to pivot the air in order to filter heavy particles in the air introduced into the cylindrical portion 71 and the air introduced into the cylindrical portion 71 through the suction duct 20.
  • the cyclone 72 is formed and the dust outlet 76 for discharging the heavy particles, the dust collecting container 73 for collecting the heavy particles filtered under the cyclone (72), and the air purified by discharging the heavy particles It consists of the discharge duct 75 discharged from the dust collector 70.
  • a blowing fan 52 that sucks from the suction port 12 to the dust collecting unit 70 and the same.
  • the driving motor 53 is formed on the upper part of the dust collecting part 70 which is the downstream side of the dust collecting part 70. That is, the air sucked through the suction port 12 by the blower fan 52 flows into the cyclone, which is the dust collecting part 70, and rotates along the inner surface of the cyclone 72 of the cyclone.
  • the relatively large dust particles contained in the air and the dust agglomerated by steam are attached to the inner surface of the cyclone 72 and collected through the dust outlet 76 by the inclination of the inner surface of the cyclone 72.
  • the air is discharged through the discharge duct 75 of the cylindrical portion 71 along the flow flow 11 formed by the blowing fan 52.
  • the user can simply remove the dust particles accumulated by separating and emptying the dust collecting container 73.
  • the user of the air cleaner can determine the degree of contamination of the indoor air by the amount of dust accumulated in the dust collecting container (73).
  • the filtration filter 80 is installed between the discharge duct 75 and the discharge port 13 of the cyclone cylindrical portion 71 to remove the dust particles not collected by the dust collecting portion 70.
  • the filtration filter 80 is composed of a HEPA filter.
  • Hephatilter is a high-performance dust collection filter that can remove particles up to 0.1 microns in size from the air passing through and effectively remove pollen, allergens, dust, fine dust, tobacco smoke or pet hair.
  • the steam plasma generating module 100 is installed on the lower side of the suction duct 20 between the dust collecting part 70 and the suction port 12, and supplies steam to the outside air introduced through the suction port 12, thereby providing the steam.
  • the dust in the air in the suction duct 20 aggregates with each other by the electrostatic force.
  • the steam plasma generating module 100 is installed below the suction duct 20, even if there is no separate injection mechanism, steam can be introduced into the suction duct 20 by its buoyancy.
  • the steam plasma generating module 100 the water storage unit 110 for receiving water for generating steam and steam from the water contained in the water storage unit Steam plasma generating unit 120 for generating a, and the electrode 132 formed to apply a discharge to the steam generated in the steam plasma generating unit 120.
  • the water storage unit 110 is a mounting portion for seating the housing 121 surrounding the steam plasma generating unit 120 to communicate with the injection port 111 formed through the upper side to supply water and the steam plasma generating unit 120 112, an outlet 113 for supplying the water in the water storage 110 to the steam plasma generator 120, and a stopper 114 for opening and closing the injection port 111.
  • the water storage unit 110 is formed in parallel with the housing 121 of the steam plasma generating unit 120 it is possible to miniaturize the steam plasma generating module 100.
  • the steam plasma generating unit 120 has a housing 121 that is formed and fixed to the mounting portion 112 of the water storage unit 110 while having an inner space, and is installed vertically on the upper side and a heater consisting of a planar heating element
  • the porous ceramic material along the plate direction on both sides of the 122, the electrode 132 for discharging the steam generated by the heater and the water in the water storage unit 110, the planar heating element heater 122 on both sides It consists of a plurality of dispersions 124 formed to extend.
  • the heater 122 may quickly heat the water stored in the water storage unit 110 by using a surface heating element. The detailed configuration of the planar heating element will be described later.
  • the housing 121 has a hexahedron shape, the upper end is formed in an open shape, and the heater electrode mounting portion 125 for mounting the heater electrode 123 for supplying power to the heater 122 is formed on both upper sides.
  • a fixing part 126 is formed to fix the heater 122 and the dispersion 124.
  • the inner surface of the mounting portion 112 of the water storage unit 110 is formed so as not to leak the steam is joined with the outer surface of the bent extending portion of the fixing portion 126 of the housing 121.
  • the heater electrode mounting part 125 is formed as a hole (not shown) so that the rod-shaped heater electrode 123 is fitted, and the heater 122 and the dispersion 124 are fixed to the fixing part 126 so that the housing ( The end is bent outwardly by a certain length so as not to be separated from the 121).
  • the heater 122 and the dispersion 124 are mounted to the fixing part 126 of the housing 121 so that steam plasma or steam charged in the housing 121 does not leak.
  • the dispersion 124 is fixed so as to be exposed to a certain portion out of the fixing portion 126 in order to absorb the water supplied from the outlet 113 of the storage 110.
  • the dispersion 124 is elongated to directly contact water in the water storage unit 110, but the heater 122 configured as a planar heating element is installed so as not to directly contact water.
  • the water level of the water storage unit 110 is high, due to the water diffusion acceptance limit of the dispersion 124 itself, it is possible to prevent a large amount of water flowing into the dispersion 124 at the same time, the water storage unit Even if the water level of 110 is low, some water is steadily sucked up into the dispersion 124 by a capillary phenomenon or the like.
  • the dispersion 124 is installed on both sides of the heater 121 can increase the evaporation efficiency, the dispersion 124 is formed of a porous member to increase the diffusion effect of the water and at the same time to ensure long life It is made of ceramic material.
  • the cover 130 is mounted in the upper opening of the housing 121.
  • the cover 130 has a plurality of discharge ports 131 for discharging steam thereon, the electrodes 132 are mounted on both sides thereof, and a surface discharge plasma generator (not shown) on the inner surface thereof. Is formed.
  • the plasma surface discharge part serves to effectively generate plasma.
  • planar heating element will be described in detail.
  • the planar heating element may be formed by screen printing, gravure printing (or roll-to-roll gravure printing) or comma coating (or roll-to-roll comma coating) of a thick film-forming heating paste composition (hereinafter, a heating paste composition) on a substrate.
  • a heating paste composition a thick film-forming heating paste composition
  • the exothermic paste composition specifically 3 to 6 parts by weight of carbon nanotube particles, 0.5 to 30 parts by weight of carbon nanoparticles, 10 to 30 parts by weight of a mixed binder, and 29 to organic solvents based on 100 parts by weight of the exothermic paste composition. 83 parts by weight and 0.5 to 5 parts by weight of the dispersant.
  • the carbon nanotube particles may be selected from single-walled carbon nanotubes, double-walled carbon nanotubes, multi-walled carbon nanotubes, or mixtures thereof.
  • the carbon nanotube particles may be multi wall carbon nanotubes.
  • the diameter may be 5 nm to 30 nm, and the length may be 3 ⁇ m to 40 ⁇ m.
  • the carbon nanoparticles may be, for example, graphite nanoparticles, and the diameter may be 1 ⁇ m to 25 ⁇ m.
  • the mixed binder serves to allow the exothermic paste composition to have heat resistance even in the temperature range of about 300 ° C., and includes epoxy acrylate or hexamethylene diisocyanate, polyvinyl acetal, and the like.
  • Phenolic resin has a mixed form.
  • the mixed binder may be a mixture of epoxy acrylate, polyvinyl acetal, and phenolic resin, or may be a mixture of hexamethylene diisocyanate, polyvinyl acetal, and phenolic resin.
  • by increasing the heat resistance of the mixed binder even if the heat generated at a high temperature of about 300 °C has the advantage that there is no change in resistance of the material or breakage of the coating film.
  • the phenolic resin means a phenolic compound including phenol and phenol derivatives.
  • the phenol derivative may include p-cresol, o-Guaiacol, Creosol, catechol, 3-methoxy-1,2-benzenediol (3 -methoxy-1,2-Benzenediol), Homocatechol, Vinylguaiacol, Syringol, Iso-eugenol, Methoxyeugenol, o O-Cresol, 3-methyl-1,2-benzenediol, (z) -2-methoxy-4- (1-propenyl) -phenol ( (z) -2-methoxy-4- (1-propenyl) -Phenol), 2, .6-diethoxy-4- (2-propenyl) -phenol (2,6-dimethoxy-4- (2-propenyl) ) -Phenol), 3,4-dimethoxy-Phenol, 4-ethyl-1,3-benzened
  • the mixing ratio of the mixed binder may be a ratio of 10 to 150 parts by weight of polyvinyl acetal resin and 100 to 500 parts by weight of phenolic resin based on 100 parts by weight of epoxy acrylate or hexamethylene diisocyanate. If the content of the phenolic resin is 100 parts by weight or less, the heat resistance characteristics of the heat-paste composition is lowered, and if it exceeds 500 parts by weight, there is a problem that the flexibility is lowered (brittleness increase).
  • the organic solvent is used to disperse the conductive particles and the mixed binder.
  • the dispersion process can be applied to a variety of commonly used methods, for example through the ultra-sonication (Roll mill), bead mill (Bead mill) or ball mill (Ball mill) process Can be done.
  • Roll mill ultra-sonication
  • Bead mill bead mill
  • Ball mill ball mill
  • the dispersant is to make the dispersion more smoothly, and a conventional dispersant used in the art such as BYK, an amphoteric surfactant such as Triton X-100, SDS and the like and a ionic surfactant may be used.
  • a conventional dispersant used in the art such as BYK
  • an amphoteric surfactant such as Triton X-100, SDS and the like
  • a ionic surfactant may be used.
  • the exothermic paste composition according to an embodiment of the present invention may further include 0.5 to 5 parts by weight of the silane coupling agent based on 100 parts by weight of the exothermic paste composition.
  • the silane coupling agent functions as an adhesion promoter to promote adhesion between the resins in the formulation of the exothermic paste composition.
  • the silane coupling agent may be an epoxy containing silane or a merceto containing silane.
  • Examples of such silane coupling agents include epoxy and include 2- (3,4 epoxy cyclohexyl) -ethyltrimethoxysilane, 3-glycidoxytrimethoxysilane, 3-glycidoxypropyltriethoxysilane, 3-glycidoxypropyltriethoxysilane, containing amine groups, N-2 (aminoethyl) 3-amitopropylmethyldimethoxysilane, N-2 (aminoethyl) 3-aminopropyltrimethoxysilane , N-2 (aminoethyl) 3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, 3-aminopropy
  • the substrate is polycarbonate, polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyimide, cellulose ester, nylon, polypropylene, polyacrylolintril, polysulfone, polyester sulfone, polyvinylidene fluoride , Glass, glass fiber (matte), ceramic, SUS, copper or aluminum substrate, etc. may be used, but is not limited to those listed above.
  • the substrate may be appropriately selected depending on the application field of the heating element or the use temperature.
  • the planar heating element prints the drying paste composition according to the embodiments of the present invention on the substrate in a desired pattern through screen printing or gravure printing, and after drying and curing, the printing and drying / It can be formed by forming an electrode by curing. Alternatively, after printing and drying / curing the silver paste or the conductive paste, the heating paste composition according to the embodiments of the present invention may be formed by screen printing or gravure printing.
  • the surface heating element may further include a protective layer coated on the upper surface.
  • the protective layer may be formed of silica (SiO2).
  • SiO2 silica
  • the heating element has an advantage of maintaining flexibility even if coated on the heating surface.
  • Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 CNT particles 4 5 6 4 5 6 CNP Particles 8 9 15 - - - Mixed binder 20 15 22 - - - Ethyl cellulose - - - 10 12 14 Organic solvent 63 67 52 82 79 76 Dispersant (BYK) 5 4 5 4 4 4 4
  • CNT particles and CNP particles were added to a carbitol acetate solvent according to the composition of [Table 1]
  • BYK dispersant was added, and dispersion A was prepared by sonication for 60 minutes. It was. Thereafter, a mixed binder was added to the carbitol acetate solvent and then a master batch was prepared through mechanical stirring. Next, the dispersion A and the masterbatch were first kneaded through mechanical stirring, followed by a second kneading process through a 3-roll-mill process to prepare an exothermic paste composition.
  • CNT particles were added to the carbitol acetate solvent according to the composition of [Table 1], BYK dispersant was added, and a dispersion was prepared by sonication for 60 minutes. Thereafter, ethyl cellulose was added to the carbitol acetate solvent to prepare a master batch through mechanical stirring. Next, the dispersion B and the masterbatch were first kneaded through mechanical stirring, followed by a second kneading process through a 3-roll mill to prepare an exothermic paste composition.
  • FIG. 9 is an image of a planar heating element specimen prepared using the heating paste composition according to the present invention.
  • Fig. 9A is a planar heating element formed by screen printing a heat generating paste composition on a polyimide substrate.
  • Figure 9 (b) is a planar heating element formed by screen printing the heating paste composition on a glass fiber mat.
  • 9 (c) and 9 (d) are images when a protective layer is coated on the planar heating element of FIG. 9 (a).
  • FIG. 9 (c) is a black protective layer coating and FIG. 9 (d). Coated with a green protective layer).
  • planar heating element samples Example
  • planar heating element samples prepared according to the comparative example as shown in FIG. 9 (a) were measured.
  • the voltage / current applied is shown in Table 2).
  • the planar heating element corresponding to the above Examples and Comparative Examples was heated up to 40 ° C., 100 ° C. and 200 ° C., respectively, and the DC voltage when the temperature was reached and The current was measured.
  • Figure 10 shows the image of the heat stability test appearance of the planar heating element samples prepared according to the Examples and Comparative Examples, the test results are summarized in the following [Table 2].
  • Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Specific resistance ( ⁇ 10 ⁇ 2 ⁇ cm 1.9 2.55 2.96 9.73 8.52 6.23 40 °C reach DC drive voltage / current 5V / 0.2A 6V / 0.2A 7V / 0.2A 20V / 0.3A 16V / 0.2A 12V / 0.2A 100 °C reach DC driving voltage / current 9V / 0.5A 12V / 0.4A 14 V / 0.5 A 48V / 0.7A 40V / 0.7A 26V / 0.6A 200 °C reach DC drive voltage / current 20V / 0.6A 24V / 0.7A 24V / 1.0A - - - Heat stability (day) 20 days or more 20 days or more 20 days or more Bad Bad Bad Bad
  • the specific resistance was measured that the planar heating element corresponding to the embodiments is smaller than the planar heating element corresponding to the comparative examples, accordingly driving voltage / current required to reach each temperature is also embodiments
  • the planar heating element corresponding to was smaller than the planar heating element corresponding to the comparative examples. That is, it was confirmed that the planar heating element corresponding to the embodiments can be driven at a lower voltage and lower power than the comparative example.
  • planar heating elements according to Examples 1 to 3 the stability was maintained for 20 days even under an exothermic driving at 200 ° C. (no separate protective layer), whereas in Comparative Examples 1 to 3, the exothermic driving at 200 ° C. was performed. Poor phenomena were observed to swell the surface of the heating portion within time. That is, it was confirmed that the planar heating element corresponding to the embodiments can be stably driven even at a high temperature of 200 ° C. or more than the comparative example.
  • the air purifier having the configuration as described above operates as follows.
  • the air purifier When the air purifier is operated by the operation of the operation panel 14 provided on the upper part of the main body 10, the air is driven by the motor 53 and the blowing fan 52 through the inlet 12 of the main body 10. Flows into.
  • Fine dust particles contained in the air are collected by the operation of the steam plasma generating module 100 installed below the suction duct 20 of the cyclone, which is the dust collector 70.
  • the water of the steam plasma generating module 100 storage unit 110 is supplied to the housing 121 installed in the mounting unit 112 of the storage unit 110 through the outlet port 113.
  • the dispersion 124 partially exposed outside the fixing part 126 of the housing 121 absorbs and diffuses water through cohesion, surface tension, or capillary action, and is configured as a heater having a planar heating element installed between the dispersions 124 ( 122) generates the steam by heating the absorbed water.
  • a surface heating element water can be heated quickly.
  • the heater 122 may directly heat the water flowing out of the storage 110 without the dispersion 124 to generate steam.
  • fine dust particles in the air are adhered by bipolar ions of the steam plasma to form a dust mass, and the dust mass flows into the cyclone, which is the dust collecting part 70 together with the relatively large dust particles. do.
  • the dust mass and the large dust particles introduced into the cyclone are pivoted in the cyclone 72 by the centrifugal force generated by the blower fan 52 and are lowered to be collected on the inner wall of the cyclone 72 to collect the cyclone 72. Due to the inclination, it is accumulated in the dust collecting container 73 through the dust outlet 76.
  • the dust mass or large dust particles accumulated in the dust collecting container 73 can be easily removed by emptying the dust collecting container.
  • Relatively medium dust particles or uncollected dust particles are sent to the HEPA filter, which is the filtration filter 80, through the cyclone discharge duct 75, which is the dust collecting part 70, and finally filtered, and then purified clean air. Only through the discharge port 13 is discharged.

Abstract

Disclosed is an air purifier using a sheet-type heating element. The air purifier, according to one embodiment of the present invention, comprises: a suction port; a dust collecting part for purifying air introduced from the suction port; and a steam plasma generation module for supplying steam to the air introduced to the dust collecting part from the suction port, wherein the steam plasma generation module comprises a water storage part, a heater comprising a sheet-type heating element for heating water in the water storage part, and an electrode for electrically discharging steam generated by the heater, wherein the sheet-type heating element comprises, for 100 parts by weight of a heating paste composition, 3-6 parts by weight of carbon nanotube particles, 0.5-30 parts by weight of carbon nanoparticles, 10-30 parts by weight of a mixed binder, 29-83 parts by weight of an organic solvent, and 0.5-5 parts by weight of a dispersant, wherein the mixed binder comprises a heating paste composition having epoxy acrylate, polyvinyl acetal, and phenol-based resin mixed, or hexamethylene diisocyanate, polyvinyl acetal, and phenol-based resin mixed.

Description

공기 청정기air cleaner
본 발명은 면상 발열체를 이용한 공기 청정기에 관한 것이다. The present invention relates to an air cleaner using a plane heater.
본 발명은 공기청정기에 관한 것으로, 보다 상세하게는 미세 먼지 입자들을 효과적으로 제거할 수 있는 공기청정기에 관한 것이다.The present invention relates to an air cleaner, and more particularly, to an air cleaner that can effectively remove fine dust particles.
일반적으로 공기청정기는 공기 중의 먼지나 세균 등을 걸러 내어 공기를 깨끗하게 하는 장치로, 그 형태에 따라 크게 스탠드 타입(Stand Type)과 협탁식으로 나눌 수 있다. 이하, 본 명세서에서는, 설명의 편의를 위하여, 스탠드 타입을 예로 들어 본 발명에 대하여 기술하고자 한다.In general, an air cleaner is a device that filters air or dust in the air to clean the air. The air cleaner can be broadly divided into a stand type and a side table according to its shape. Hereinafter, in the present specification, for convenience of description, the present invention will be described by taking a stand type as an example.
도 1은 종래의 공기청정기의 외형을 도시한 사시도이고, 도 2는 종래의 공기청정기의 내부구성을 도시한 단면도이다.1 is a perspective view showing the appearance of a conventional air cleaner, Figure 2 is a cross-sectional view showing the internal configuration of a conventional air cleaner.
도 1 및 도 2에 도시된 바와 같이, 본체(10)의 전면 상부에는 제1흡입구(11)가 형성되고 하부에는 제2흡입구(12)가 형성되며 상측에는 토출구(13)가 형성되며 또한 상부에는 조작패널(14)이 마련된다. 본체(10)의 내부는 상부의 제1집진공간(15)과 하부의 제2집진공간(16)으로 구획되고, 상부의 제1집진공간(15)에는 작은 먼지 입자들을 집진하기 위한 제1집진장치(20)가 설치되고 그 후방에는 정화된 공기를 토출구(13)쪽으로 송풍하기 위해 송풍팬(32)과 모터(33)로 구성된 제1송풍장치(30)가 설치된다. 1 and 2, the first suction port 11 is formed in the upper front of the main body 10, the second suction opening 12 is formed in the lower portion, the discharge port 13 is formed in the upper side and the upper portion The operation panel 14 is provided. The interior of the main body 10 is divided into a first dust collecting space 15 and a second dust collecting space 16 of the lower, the first dust collecting space for collecting small dust particles in the first dust collecting space 15 of the upper The apparatus 20 is installed and behind it is a first blower 30 composed of a blower fan 32 and a motor 33 for blowing the purified air toward the discharge port 13.
하부의 제2집진공간(16)에는 큰 먼지 입자들을 집진하기 위한 제2집진장치(40)가 설치되고 제2흡입구(12)로부터 공기를 흡입하여 제2집진장치(40) 쪽으로 송풍하기 위해 송풍팬(52)과 모터(53)로 구성된 제2송풍장치(50)가 설치된다. 또한 제1집진공간(15)과 제2집진공간(16)을 구획하는 구획판에는 연통유로(61)가 형성되며 연통유로(61)에는 제2집진장치(40)를 거친 미세먼지가 걸러질 수 있도록 중간필터(62)가 설치된다.In the lower second dust collecting space 16, a second dust collecting device 40 for collecting large dust particles is installed and blown to suck air from the second suction opening 12 and blow the air toward the second dust collecting device 40. The second blower 50 composed of the fan 52 and the motor 53 is installed. In addition, a communication passage 61 is formed in a partition plate partitioning the first dust collecting space 15 and the second dust collecting space 16, and fine dust passing through the second dust collecting device 40 is filtered through the communication passage 61. Intermediate filter 62 is installed to allow.
제1집진장치(20)는 전방에서 후방으로 향균프리필터(21), 전기집진식 정전필터(22), 미세집진필터(23)가 겹층을 이루며 순서대로 배열된다. 한편, 제2집진장치(40)는 상측 측면부에 입구(42)가 형성되고 상측 중앙부에 출구(44)가 형성되며 하부에 분진배출구(43)가 형성된 사이클론 집진통(41)과 그 하부에 설치된 집진용기(46)를 포함한다.In the first dust collecting device 20, the antimicrobial prefilter 21, the electrostatic precipitating electrostatic filter 22, and the fine dust collecting filter 23 are arranged in order from the front to the rear. On the other hand, the second dust collector 40 has an inlet 42 is formed in the upper side portion, the outlet 44 is formed in the upper central portion and the cyclone dust collector 41 formed with a dust outlet 43 in the lower portion and installed below The dust collecting container 46 is included.
상기와 같이 구성된 종래의 공기청정기는 다음과 같이 동작된다.The conventional air cleaner configured as described above is operated as follows.
본체(10) 상부에 마련된 조작패널(14)을 통해 공기청정기의 가동이 이루어지면 제1,2송풍장치(30,50)가 동작하고 이에 의해 제1,2흡입구(11,12)를 통해 실내공기의 흡입이 이루어진다. 이 때 흡입되는 공기 중에 포함된 먼지는 비중차에 의해 상대적으로 작은 먼지 입자들이 상부에 위치하고 상대적으로 큰 먼지 입자들이 하부에 위치하기 때문에 제1흡입구(11) 쪽으로 작은 먼지 입자들이 흡입되고 제2흡입구 (12)쪽으로 큰 먼지 입자들이 흡입된다.When the air cleaner is operated through the operation panel 14 provided on the main body 10, the first and second blowers 30 and 50 operate to thereby operate the indoors through the first and second suction ports 11 and 12. Inhalation of the air takes place. At this time, since the dust contained in the inhaled air has relatively small dust particles on the upper side and relatively large dust particles on the lower portion due to the specific gravity difference, small dust particles are sucked toward the first suction opening 11 and the second suction opening. Large dust particles are sucked toward (12).
따라서 상부의 제1흡입구(11)를 통해 공기와 함께 흡입된 작은 먼지 입자들은 제1집진장치(20)의 필터들을 차례로 통과하면서 집진이 이루어진다. 그리고 제1집진장치(20)를 통해 정화된 공기는 제1송풍장치(30)의 동작에 의해 토출구(13) 쪽으로 송풍되어 다시 실내공간으로 공급된다.Therefore, the small dust particles sucked together with the air through the upper first suction port 11 are collected while passing through the filters of the first dust collector 20 in sequence. In addition, the air purified through the first dust collecting device 20 is blown toward the discharge port 13 by the operation of the first blowing device 30 and then supplied to the indoor space.
하부의 제2흡입구(12)를 통해 공기와 함께 흡입된 큰 먼지 입자들은 제2송풍장치(50)의 동작에 의해 제2집진장치(40)의 사이클론 집진통(41) 내부로 송풍되고, 사이클론 집진통(41) 내부를 선회하는 과정에서 사이클론 집진통(41) 내면에 부착되어 집진된다. 그리고 사이클론 집진통(41) 내부에 집진된 먼지는 하부의 분진배출구(43)를 통해 흘러내려 집진용기(46) 내에 쌓인다.Large dust particles sucked together with air through the lower second inlet 12 are blown into the cyclone dust collector 41 of the second dust collector 40 by the operation of the second blower 50, and the cyclone In the process of turning inside the dust collecting container 41 is attached to the inner surface of the cyclone dust collecting container 41 is collected. And dust collected in the cyclone dust collector 41 flows down through the dust discharge port 43 of the lower portion is accumulated in the dust collecting container 46.
또 사이클론 집진통(41) 내부를 거치면서 1차로 정화된 공기는 미세집진필터로 이루어진 중간필터(62)를 통과하여 제1집진공간(15)으로 흐르면서 2차 정화가 이루어진다. 즉 사이클론 집진통(41)을 통과하면서 미처 집진되지 않은 미세먼지들이 중간필터(62)를 통해 집진된다. 그리고 중간필터(62)를 거쳐 정화된 공기는 제1집진장치(20)를 거치면서 정화된 공기와 함께 제1송풍장치(30)의 동작에 의해 토출구(13) 쪽으로 송풍되어 다시 실내공간으로 공급된다.In addition, the primary purified air passing through the cyclone dust collecting container 41 passes through the intermediate filter 62 made of the fine dust collecting filter and flows into the first dust collecting space 15 to perform secondary purification. That is, fine dust that is not collected while passing through the cyclone dust collector 41 is collected through the intermediate filter 62. The air purified through the intermediate filter 62 is blown toward the discharge port 13 by the operation of the first blower 30 together with the purified air while passing through the first dust collector 20, and then supplied to the indoor space. do.
그러나, 이러한 공기청정기는 사이클론에서 집진효율을 높이기 위하여 추가적인 송풍팬(52)과 이를 구동하는 모터(53)가 필요하기 때문에 소비전력이 상승하고 작동 소음이 크며 본체가 커지는 문제점이 있었다. 또한, 상대적으로 가벼운 미세 먼지 입자들은 사이클론에 의해서 집진되지 않고 겹층 구조의 필터와 중간필터에 의해 집진되기 때문에 필터의 교체와 청소로 인한 유지보수 비용이 증가되는 문제점이 있었다.However, such an air cleaner has a problem in that power consumption is increased, operating noise is large, and the main body is large because an additional blower fan 52 and a motor 53 for driving the air cleaner are required to increase dust collection efficiency in a cyclone. In addition, because the relatively light fine dust particles are not collected by the cyclone, but are collected by a layered filter and an intermediate filter, there is a problem in that maintenance costs due to replacement and cleaning of the filter are increased.
본 발명이 해결하고자 하는 과제는, 스팀플라즈마를 발생시켜 사이클론에 의해 집진되는 먼지의 양을 극대화할 수 있는 공기 청정기를 제공하는 것이다. The problem to be solved by the present invention is to provide an air purifier capable of maximizing the amount of dust collected by the cyclone by generating a steam plasma.
본 발명이 해결하고자 하는 과제는, 면상 발열체를 포함하는 히터를 사용하여 스팀을 급속히 발생시킬 수 있는 공기 청정기를 제공하는 것이다. The problem to be solved by the present invention is to provide an air purifier capable of rapidly generating steam by using a heater including a planar heating element.
상기와 같은 기술적 과제를 해결하기 위해, 본 발명의 실시예에 따른 공기 청정기는 흡입구; 상기 흡입구로부터 유입되는 공기를 정화시키는 집진부; 및 상기 흡입구로부터 상기 집진부로 유입되는 상기 공기에 스팀을 공급하는 스팀 플라즈마 발생모듈;을 포함하며,상기 스팀 플라즈마 발생모듈은 물 저장부; 상기 물 저장부의 물을 가열하기 위한 면상 발열체로 구성된 히터; 및 상기 히터에 의해 생성된 스팀에 방전을 하기 위한 전극;을 포함하고, In order to solve the above technical problem, the air purifier according to an embodiment of the present invention; A dust collecting unit for purifying the air flowing from the suction port; And a steam plasma generating module for supplying steam to the air introduced from the suction port to the dust collecting unit, wherein the steam plasma generating module comprises: a water storage unit; A heater composed of a surface heating element for heating water in the water storage part; And an electrode for discharging steam generated by the heater.
상기 면상 발열체는 발열페이스트 조성물 100 중량부에 대하여 탄소나노튜브 입자 3 내지 6중량부, 탄소나노입자 0.5 내지 30중량부, 혼합 바인더 10 내지 30중량부, 유기 용매 29 내지 83 중량부, 및 분산제 0.5 내지 5중량부를 포함하고, 상기 혼합 바인더는 에폭시 아크릴레이트 , 폴리비닐 아세탈 및 페놀계 수지가 혼합되거나 헥사메틸렌 디이소시아네이트, 폴리비닐 아세탈 및 페놀계 수지가 혼합되는 발열 페이스트 조성물을 포함한다. The planar heating element is 3 to 6 parts by weight of carbon nanotube particles, 0.5 to 30 parts by weight of carbon nanoparticles, 10 to 30 parts by weight of a mixed binder, 29 to 83 parts by weight of an organic solvent, and 0.5 wt. To 5 parts by weight, wherein the mixed binder includes an epoxy acrylate, a polyvinyl acetal, and a phenolic resin, or a hexamethylene diisocyanate, polyvinyl acetal, and a phenolic resin.
상기 혼합 바인더는 에폭시 아크릴레이트 또는 헥사메틸렌 디이소시아네이트 100 중량부에 대하여 폴리비닐 아세탈 수지 10 내지 150 중량부, 페놀계수지 100 내지 500 중량부가 혼합될 수 있다. The mixed binder may be 10 to 150 parts by weight of polyvinyl acetal resin, 100 to 500 parts by weight of phenolic resin based on 100 parts by weight of epoxy acrylate or hexamethylene diisocyanate.
상기 공기 청정기는 발열 페이스트 조성물 100 중량부에 대하여 실란 커플링제 0.5 내지 5 중량부를 더 포함할 수 있다. The air purifier may further include 0.5 to 5 parts by weight of the silane coupling agent based on 100 parts by weight of the heating paste composition.
상기 탄소나노튜브입자는 다중벽 탄소나노튜브 입자일 수 있다. The carbon nanotube particles may be multi-walled carbon nanotube particles.
상기 유기 용매는 카비톨 아세테이트, 부틸 카비톨 아세테이트, DBE(dibasic ester), 에틸카비톨, 에틸카비톨아세테이트, 디프로필렌글리콜메틸에테르, 셀로솔브아세테이트, 부틸셀로솔브아세테이트, 부탄올 및 옥탄올 중에서 선택되는 2 이상의 혼합 용매일 수 있다. The organic solvent is selected from carbitol acetate, butyl carbitol acetate, DBE (dibasic ester), ethyl carbitol, ethyl carbitol acetate, dipropylene glycol methyl ether, cellosolve acetate, butyl cellosolve acetate, butanol and octanol May be two or more mixed solvents.
상기 발열 페이스트 조성물을 기판상에 스크린 인쇄, 그라비아 인쇄 또는 콤마코팅하여 형성될 수 있다. The heating paste composition may be formed by screen printing, gravure printing or comma coating on a substrate.
상기 기판은 폴리이미드 기판, 유리섬유 매트 또는 세라믹 유리일 수 있다. The substrate may be a polyimide substrate, fiberglass mat or ceramic glass.
상기 면상발열체 상부면에 코팅되는 것으로, 실리카 또는 카본븍랙과 같은 흑색 안료를 구비하는 유기물로 형성되는 보호층을 더 포함할 수 있다. The coating on the top surface of the planar heating element, may further include a protective layer formed of an organic material having a black pigment, such as silica or carbon shock rack.
본 발명에 의하면, 면상 발열체를 이용함으로서 물을 신속하게 가열하여 스팀을 발생시킬 수 있고, 공기에 스팀 플라즈마를 공급함으로서, 스팀플라즈마의 응집작용에 의해 미세 먼지 입자들을 큰 먼지덩어리로 만든 후, 사이클론을 이용해 집진 제거함으로써 정화능력을 향상시킬 수 있다. According to the present invention, by using a surface heating element, water can be heated quickly to generate steam, and by supplying steam plasma to the air, the fine dust particles are formed into large dust masses by agglomeration of steam plasma, and then a cyclone Purification ability can be improved by collecting dust.
또한, 본 발명에 의하면, 송풍팬과 모터를 1개만 사용하므로 추가적인 송풍팬과 모터가 필요가 없게 되어 소비전력과 작동소음이 저감되며 소형화가 가능하다. In addition, according to the present invention, since only one blower fan and a motor are used, an additional blower fan and a motor are not required, thereby reducing power consumption and operation noise, and miniaturization is possible.
또한, 본 발명에 의하면, 또한, 플라즈마 소스로 순수한 물을 스팀화하여 사용하므로 건조한 실내공기를 가습하는 효과를 얻을 수 있으며, 대기중의 공기를 플라즈마 소스로 사용하는 경우에 비하여 오존이 없는 깨끗한 공기를 얻을 수 있다. In addition, according to the present invention, since pure water is used as a plasma source by steaming, it is possible to obtain the effect of humidifying dry indoor air, and clean air without ozone as compared with the case of using atmospheric air as a plasma source. Can be obtained.
도 1은 종래의 공기청정기의 외형을 도시한 사시도1 is a perspective view showing the appearance of a conventional air cleaner
도 2는 종래의 공기청정기의 내부구성을 도시한 단면도Figure 2 is a cross-sectional view showing the internal configuration of a conventional air cleaner
도 3은 본 발명의 일 실시예에 따른 공기청정기의 구성을 도시한 사시도Figure 3 is a perspective view showing the configuration of an air cleaner according to an embodiment of the present invention
도 4는 도 3의 측면도4 is a side view of FIG. 3
도 5는 도 3의 스팀 플라즈마 발생모듈의 외형을 도시한 사시도5 is a perspective view illustrating an appearance of the steam plasma generating module of FIG. 3.
도 6은 도 5의 절단선 Ⅵ-Ⅵ에 따른 절개 사시도FIG. 6 is a cutaway perspective view taken along the line VI-VI of FIG. 5; FIG.
도 7은 도 5의 절단선 VII-VII에 따른 절개 사시도7 is a perspective view of the cut along the cutting line VII-VII of FIG.
도 8은 도 5의 절단선 VIII-VIII에 따른 절개 사시도8 is a perspective view of the cut along the cutting line VIII-VIII of FIG.
도 9는 본 발명에 따른 발열 페이스트 조성물을 이용하여 제작한 면상발열체 시편의 이미지9 is an image of a planar heating element specimen prepared using a heating paste composition according to the present invention
도 10은 실시예 및 비교예에 따라 제조된 면상발열체 샘플들의 발열안정성 시험 모습의 이미지.10 is an image of the heat stability test appearance of the planar heating element samples prepared according to the Examples and Comparative Examples.
본 발명은 다양한 변경을 가할 수 있고 여러가지 실시예를 가질 수 있는바, 특정 실시예들을 도면에 예시하고 상세한 설명에 상세하게 설명하고자 한다. 그러나, 이는 본 발명을 특정한 실시 형태에 대해 한정하려는 것이 아니며, 본 발명의 사상 및 기술범위에 포함되는 모든 변경, 균등물 내지 대체물을 포함하는 것으로 이해되어야 한다.As the invention allows for various changes and numerous embodiments, particular embodiments will be illustrated in the drawings and described in detail in the written description. However, this is not intended to limit the present invention to specific embodiments, it should be understood to include all modifications, equivalents, and substitutes included in the spirit and scope of the present invention.
이하에서는 첨부된 도면을 참조하여 본 발명을 구체적으로 설명한다.Hereinafter, with reference to the accompanying drawings will be described in detail the present invention.
도 3은 본 발명의 일 실시예에 따른 공기청정기의 구성을 도시한 사시도, 도 4는 도 3의 측면도, 도 5는 도 3의 스팀 플라즈마 발생모듈의 외형을 도시한 사시도, 도 6은 도 5의 절단선 Ⅵ-Ⅵ에 따른 절개 사시도이며, 도 7은 도 5의 절단선 VII-VII에 따른 절개 사시도, 도 8은 도 5의 절단선 VIII-VIII에 따른 절개 사시도이다.Figure 3 is a perspective view showing the configuration of an air cleaner according to an embodiment of the present invention, Figure 4 is a side view of Figure 3, Figure 5 is a perspective view showing the appearance of the steam plasma generating module of Figure 3, Figure 6 is Figure 5 Fig. 7 is a cutaway perspective view taken along the cutting line VI-VI, Fig. 7 is a cutaway perspective view taken along the cutting line VII-VII of Fig. 5, and Fig. 8 is a cutaway perspective view taken along the cutting line VIII-VIII of Fig. 5.
도 3 및 도 4에 도시된 바와 같이, 본 발명의 일 실시예에 따른 공기청정기(1)는, 직육면체 형상의 외형을 갖는 본체(10)와, 본체(10)의 전면에 형성된 흡입구(12)와, 흡입구(12)로부터 유입된 공기를 정화시키도록 본체(10) 내부에 형성된 집진부(70)와, 흡입구(12)와 집진부(70) 사이를 연결하는 흡입 덕트(20)와, 흡입 덕트(20)의 하부에 스팀를 공급하는 스팀 플라즈마 발생모듈(100)과, 집진부(70)의 상측에 형성되어 흡입구(12)로부터의 외부 공기를 흡입하는 송풍팬(52)과, 집진부(70)와 송풍팬(52)사이에 형성된 여과 필터(80)와, 집진부(70)와 여과 필터(80)에 의해 정화된 공기를 배출하는 토출구(13)를 포함하여 구성된다. 3 and 4, the air cleaner 1 according to an embodiment of the present invention, the main body 10 having an external shape of a rectangular parallelepiped, and the suction port 12 formed on the front surface of the main body 10 And a dust collecting part 70 formed inside the main body 10 to purify the air introduced from the suction port 12, a suction duct 20 connecting the suction port 12 and the dust collecting part 70, and a suction duct ( Steam plasma generating module 100 for supplying steam to the lower portion of the 20, the blowing fan 52 is formed on the upper side of the dust collecting portion 70 to suck the outside air from the inlet 12, the dust collecting portion 70 and blowing It comprises a filtration filter 80 formed between the fan 52, and the discharge port 13 for discharging the air purified by the dust collecting section 70 and the filtration filter 80.
상기 본체(10)는, 공기청정기(1)의 동작상태를 표시하고 제어하는 제어 버튼이 형성된 조작패널(14)을 구비한다. The main body 10 includes an operation panel 14 in which a control button for displaying and controlling the operation state of the air cleaner 1 is formed.
상기 집진부(70)는 흡입덕트(20)를 통해 외부 공기가 유입되는 원통부(71)와, 원통부(71)에 유입된 공기 중의 무거운 입자를 걸러내기 위하여 공기를 선회 운동시키도록 원뿔 형상으로 형성되고 무거운 입자를 배출하는 먼지배출구(76)가 형성된 사이클론(72)과, 사이클론(cyclone, 72)의 하부에 걸러진 무거운 입자를 모으는 집진 용기(73)와, 무거운 입자를 배출시켜 정화된 공기가 집진부(70)로부터 배출되는 배출 덕트(75)로 구성된다. The dust collector 70 has a conical shape to pivot the air in order to filter heavy particles in the air introduced into the cylindrical portion 71 and the air introduced into the cylindrical portion 71 through the suction duct 20. The cyclone 72 is formed and the dust outlet 76 for discharging the heavy particles, the dust collecting container 73 for collecting the heavy particles filtered under the cyclone (72), and the air purified by discharging the heavy particles It consists of the discharge duct 75 discharged from the dust collector 70.
여기서, 집진부(70)로 유입된 공기가 사이클론(72) 내부에서 선회운동을 할 수 있도록 원심력을 부여하기 위해, 흡입구(12)로부터 집진부(70)에 이르기까지 흡입하는 송풍팬(52) 및 이를 구동하는 모터(53)가 집진부(70)의 하류측인 집진부(70)의 상부에 형성된다. 즉, 상기 송풍팬(52)에 의해서 흡입구(12)를 통해 흡입된 공기는 집진부(70)인 사이클론 내부로 유입되어 사이클론의 사이클론(72) 내부면을 따라 선회운동을 하게 된다. 이 과정에서 공기에 포함된 상대적으로 큰 먼지 입자들과 스팀에 의해 응집된 먼지 덩어리들은 사이클론(72)의 내면에 부착 집진된 후 사이클론(72) 내면의 경사에 의해 먼지배출구(76)를 통해 집진용기(73)에 쌓이게 되고, 공기는 송풍팬(52)에 의해 형성되는 유동 흐름(11)을 따라 원통부(71)의 배출덕트(75)를 통해 배출된다. Here, in order to impart centrifugal force to allow the air introduced into the dust collecting unit 70 to swing inside the cyclone 72, a blowing fan 52 that sucks from the suction port 12 to the dust collecting unit 70 and the same. The driving motor 53 is formed on the upper part of the dust collecting part 70 which is the downstream side of the dust collecting part 70. That is, the air sucked through the suction port 12 by the blower fan 52 flows into the cyclone, which is the dust collecting part 70, and rotates along the inner surface of the cyclone 72 of the cyclone. In this process, the relatively large dust particles contained in the air and the dust agglomerated by steam are attached to the inner surface of the cyclone 72 and collected through the dust outlet 76 by the inclination of the inner surface of the cyclone 72. Accumulated in the container 73, the air is discharged through the discharge duct 75 of the cylindrical portion 71 along the flow flow 11 formed by the blowing fan 52.
먼지배출구(76)를 통해 배출되는 먼지 입자들이 상기 집진용기(73) 내에 쌓이게 되면, 사용자는 집진용기(73)를 분리하여 비움으로써 쌓인 먼지 입자들을 간단하게 제거할 수 있다. 또한, 공기청정기의 사용자는 집진용기(73)에 쌓인 먼지의 량에 의해서 실내공기의 오염 정도를 확인할 수 있다.When the dust particles discharged through the dust outlet 76 is accumulated in the dust collecting container 73, the user can simply remove the dust particles accumulated by separating and emptying the dust collecting container 73. In addition, the user of the air cleaner can determine the degree of contamination of the indoor air by the amount of dust accumulated in the dust collecting container (73).
상기 여과 필터(80)는 상기 집진부(70)에 의해 미처 집진되지 않은 먼지 입자들을 제거하기 위하여 사이클론 원통부(71)의 배출덕트(75)와 토출구(13) 사이에 설치된다. 여기서, 여과 필터(80)는 헤파필터(HEPA filter)로 구성된다. 헤파틸터는 고성능 집진필터로서 통과하는 공기로부터 최고 0.1 미크론 크기의 미립자를 제거할 수 있으며 꽃가루나 알레르기물질, 먼지, 미세먼지, 담배연기 또는 애완동물 털 등도 효과적으로 제거할 수 있다. The filtration filter 80 is installed between the discharge duct 75 and the discharge port 13 of the cyclone cylindrical portion 71 to remove the dust particles not collected by the dust collecting portion 70. Here, the filtration filter 80 is composed of a HEPA filter. Hephatilter is a high-performance dust collection filter that can remove particles up to 0.1 microns in size from the air passing through and effectively remove pollen, allergens, dust, fine dust, tobacco smoke or pet hair.
상기 스팀 플라즈마 발생모듈(100)은 상기 집진부(70)와 흡입구(12) 사이의 흡입 덕트(20)의 하측에 설치되어, 흡입구(12)를 통해 유입되는 외부 공기에 스팀를 공급함에 따라, 스팀의 정전기력에 의하여 흡입 덕트(20) 내의 공기 중의 먼지를 서로 응집시킨다. 여기서, 스팀 플라즈마 발생모듈(100)이 흡입 덕트(20)의 하측에 설치됨에 따라, 별도의 분사 기구가 없더라도 스팀가 자체의 부력에 의하여 흡입 덕트(20)의 내부로 유입될 수 있게 된다.The steam plasma generating module 100 is installed on the lower side of the suction duct 20 between the dust collecting part 70 and the suction port 12, and supplies steam to the outside air introduced through the suction port 12, thereby providing the steam. The dust in the air in the suction duct 20 aggregates with each other by the electrostatic force. Here, since the steam plasma generating module 100 is installed below the suction duct 20, even if there is no separate injection mechanism, steam can be introduced into the suction duct 20 by its buoyancy.
보다 구체적으로는, 도 5 내지 도 8에 도시된 바와 같이, 상기 스팀 플라즈마 발생모듈(100)은, 스팀을 발생시키는 물을 수용하는 물저장부(110)와, 물저장부에 수용된 물로부터 스팀을 발생시키는 스팀 플라즈마발생부(120)와, 스팀 플라즈마발생부(120)에서 발생된 스팀에 방전을 인가하도록 형성된 전극(132)으로 구성된다. More specifically, as shown in Figures 5 to 8, the steam plasma generating module 100, the water storage unit 110 for receiving water for generating steam and steam from the water contained in the water storage unit Steam plasma generating unit 120 for generating a, and the electrode 132 formed to apply a discharge to the steam generated in the steam plasma generating unit 120.
여기서, 물저장부(110)는 물을 공급하도록 상측에 관통 형성된 주입구(111)와, 스팀 플라즈마발생부(120)와 연통되도록 스팀 플라즈마발생부(120)를 감싸는 하우징(121)을 안착시키는 장착부(112)와, 물저장부(110) 내부의 물을 스팀 플라즈마발생부(120)로 공급하는 유출구(113)와, 주입구(111)를 개폐하는 마개(114)를 구비한다. 상기 물저장부(110)는 스팀 플라즈마발생부(120)의 하우징(121)과 나란하게 형성됨으로써 스팀 플라즈마 발생모듈(100)의 소형화가 가능해진다.Here, the water storage unit 110 is a mounting portion for seating the housing 121 surrounding the steam plasma generating unit 120 to communicate with the injection port 111 formed through the upper side to supply water and the steam plasma generating unit 120 112, an outlet 113 for supplying the water in the water storage 110 to the steam plasma generator 120, and a stopper 114 for opening and closing the injection port 111. The water storage unit 110 is formed in parallel with the housing 121 of the steam plasma generating unit 120 it is possible to miniaturize the steam plasma generating module 100.
상기 스팀 플라즈마발생부(120)는, 내부 공간을 가지면서 물저장부(110)의 장착부(112)에 형합되어 고정되는 하우징(121)과, 상측에 수직으로 세워지게 설치되고 면상 발열체로 구성된 히터(122)와, 상기 히터에 의해 생성되는 스팀에 방전을 하기 위한 전극(132)과, 물저장부(110) 내의 물과 접촉하도록 면상 발열체 히터(122)의 양측에 판면 방향을 따라 다공성 세라믹 재질로 연장 형성된 다수의 분산체(124)로 구성된다. 상기 히터(122)는 면상 발열체를 사용함으로서 물저장부(110)에 저장된 물을 신속하게 가열할 수 있다. 상기 면상 발열체의 상세 구성에 대해서는 후술하기로 한다. The steam plasma generating unit 120 has a housing 121 that is formed and fixed to the mounting portion 112 of the water storage unit 110 while having an inner space, and is installed vertically on the upper side and a heater consisting of a planar heating element The porous ceramic material along the plate direction on both sides of the 122, the electrode 132 for discharging the steam generated by the heater and the water in the water storage unit 110, the planar heating element heater 122 on both sides It consists of a plurality of dispersions 124 formed to extend. The heater 122 may quickly heat the water stored in the water storage unit 110 by using a surface heating element. The detailed configuration of the planar heating element will be described later.
이 때, 하우징(121)은 육면체 형상으로 상단부는 개구된 형상으로 형성되며, 상부 양측면에는 히터(122)에 전원을 공급하는 히터전극(123)을 장착하기 위한 히터전극 장착부(125)가 형성되고, 하단부에는 히터(122)와 분산체(124)를 고정하는 고정부(126)가 형성된다. 또한, 물저장부(110)의 장착부(112)의 내면은 하우징(121)의 고정부(126)의 절곡연장 형성된 부분의 외면과 형합되어 스팀이 누설되지 않도록 형성된다. At this time, the housing 121 has a hexahedron shape, the upper end is formed in an open shape, and the heater electrode mounting portion 125 for mounting the heater electrode 123 for supplying power to the heater 122 is formed on both upper sides. At the lower end, a fixing part 126 is formed to fix the heater 122 and the dispersion 124. In addition, the inner surface of the mounting portion 112 of the water storage unit 110 is formed so as not to leak the steam is joined with the outer surface of the bent extending portion of the fixing portion 126 of the housing 121.
그리고, 상기 히터전극 장착부(125)는 봉상의 히터전극(123)이 끼워지도록 구멍(미도시)으로 형성되고, 고정부(126)에는 히터(122)와 분산체(124)가 고정되어 하우징(121)으로부터 이탈되지 않도록 끝단이 일정길이만큼 외부로 절곡연장 형성되어 있다. 히터(122)와 분산체(124)는 하우징(121) 내에 충전된 스팀 플라즈마또는 스팀가 누설되지 않도록 하우징(121)의 고정부(126)에 장착된다. 이 때, 분산체(124)는 저장부(110)의 유출구(113)로부터 공급되는 물을 흡수하기 위해서 고정부(126) 밖으로 일정부분 노출되도록 고정된다.In addition, the heater electrode mounting part 125 is formed as a hole (not shown) so that the rod-shaped heater electrode 123 is fitted, and the heater 122 and the dispersion 124 are fixed to the fixing part 126 so that the housing ( The end is bent outwardly by a certain length so as not to be separated from the 121). The heater 122 and the dispersion 124 are mounted to the fixing part 126 of the housing 121 so that steam plasma or steam charged in the housing 121 does not leak. At this time, the dispersion 124 is fixed so as to be exposed to a certain portion out of the fixing portion 126 in order to absorb the water supplied from the outlet 113 of the storage 110.
또한, 도 7에 도시된 바와 같이, 분산체(124)는 물저장부(110) 내의 물과 직접 접촉하도록 길게 연장되지만, 면상 발열체로 구성된 히터(122)는 물과 직접 접촉하지 않도록 설치된다. 또한, 물저장부(110)의 수위가 높더라도, 분산체(124) 자체의 물 확산 수용 한계에 의하여 한꺼번에 많은 물이 분산체(124) 내부로 유입 확산되는 것을 방지할 수 있으며, 물저장부(110)의 수위가 낮더라도, 모세관 현상 등에 의하여 분산체(124)에 어느 정도의 물이 꾸준히 빨려 올려진다. In addition, as shown in FIG. 7, the dispersion 124 is elongated to directly contact water in the water storage unit 110, but the heater 122 configured as a planar heating element is installed so as not to directly contact water. In addition, even if the water level of the water storage unit 110 is high, due to the water diffusion acceptance limit of the dispersion 124 itself, it is possible to prevent a large amount of water flowing into the dispersion 124 at the same time, the water storage unit Even if the water level of 110 is low, some water is steadily sucked up into the dispersion 124 by a capillary phenomenon or the like.
한편, 분산체(124)가 상기 히터(121)의 양측면에 설치되어 증발 효율을 높일 수 있으며, 분산체(124)를 다공성 부재로 형성하여 물의 확산효과를 높임과 동시에, 장수명을 확보하기 위하여 내열 세라믹 재질로 형성된다. On the other hand, the dispersion 124 is installed on both sides of the heater 121 can increase the evaporation efficiency, the dispersion 124 is formed of a porous member to increase the diffusion effect of the water and at the same time to ensure long life It is made of ceramic material.
그리고, 하우징(121)의 상단 개구부에는 커버부(130)가 장착된다. 커버부(130)는, 그 상부에 스팀를 방출하는 방출구(131)가 복수개 형성되고, 그 양측면에 전극(132)이 장착되며, 내면에 플라즈마 면 방전부(surface discharge plasma generator)(미도시)가 형성된다. 상기 플라즈마 면 방전부는 플라즈마를 효과적으로 생성할 수 있는 역할을 한다.The cover 130 is mounted in the upper opening of the housing 121. The cover 130 has a plurality of discharge ports 131 for discharging steam thereon, the electrodes 132 are mounted on both sides thereof, and a surface discharge plasma generator (not shown) on the inner surface thereof. Is formed. The plasma surface discharge part serves to effectively generate plasma.
이하에서는 면상 발열체에 대해 상세히 살펴보기로 한다. Hereinafter, the planar heating element will be described in detail.
면상 발열체는 후막 형성용 발열 페이스트 조성물(이하, 발열 페스트 조성물)을 기판 상에 스크린 인쇄, 그라비아 인쇄(내지 롤투롤 그라비아 인쇄) 또는 콤마코팅(내지 롤투롤 콤마코팅)하여 형성될 수 있다.The planar heating element may be formed by screen printing, gravure printing (or roll-to-roll gravure printing) or comma coating (or roll-to-roll comma coating) of a thick film-forming heating paste composition (hereinafter, a heating paste composition) on a substrate.
먼저, 발열 페이스트 조성물에 대해 살펴보면, 구체적으로 발열 페이스트 조성물 100 중량부에 대하여 탄소나노튜브 입자 3 내지 6중량부, 탄소나노입자 0.5 내지 30 중량부, 혼합 바인더 10 내지 30 중량부, 유기 용매 29 내지 83 중량부 및 분산제 0.5 내지 5 중량부를 포함한다.First, referring to the exothermic paste composition, specifically 3 to 6 parts by weight of carbon nanotube particles, 0.5 to 30 parts by weight of carbon nanoparticles, 10 to 30 parts by weight of a mixed binder, and 29 to organic solvents based on 100 parts by weight of the exothermic paste composition. 83 parts by weight and 0.5 to 5 parts by weight of the dispersant.
상기 탄소나노튜브 입자는 단일벽 탄소나노튜브, 이중벽 탄소나노튜브, 다중벽 탄소나노튜브 또는 이들의 혼합물로부터 선택될 수 있다. 예컨대 상기 탄소나노튜브 입자는 다중벽 탄소나노튜브(multi wall carbon nanotube)일 수 있다. 상기 탄소나노튜브 입자가 다중벽 탄소나노튜브일 때, 직경은 5nm 내지 30nm 일 수 있고, 길이는 3㎛ 내지 40㎛일 수 있다.The carbon nanotube particles may be selected from single-walled carbon nanotubes, double-walled carbon nanotubes, multi-walled carbon nanotubes, or mixtures thereof. For example, the carbon nanotube particles may be multi wall carbon nanotubes. When the carbon nanotube particles are multi-walled carbon nanotubes, the diameter may be 5 nm to 30 nm, and the length may be 3 μm to 40 μm.
상기 탄소나노입자는 예컨대 그라파이트 나노입자일 수 있으며, 직경은 1㎛ 내지 25㎛일 수 있다.The carbon nanoparticles may be, for example, graphite nanoparticles, and the diameter may be 1 μm to 25 μm.
혼합 바인더는 발열 페이스트 조성물이 300℃ 가량의 온도 범위에서도 내열성을 가질 수 있도록 하는 기능을 하는 것으로, 에폭시 아크릴레이트(Epocy acrylate) 또는 헥사메틸렌 디이소시아네이트(Hexamethylene diisocyanate), 폴리비닐 아세탈(Polyvinyl acetal) 및 페놀계 수지(Phenol resin)가 혼합된 형태를 갖는다. 예컨대 상기 혼합 바인더는 에폭시 아크릴레이트, 폴리비닐 아세탈 및 페놀계 수지가 혼합된 형태일 수 있고, 또는 헥사메틸렌 디이소시아네이트, 폴리비닐 아세탈 및 페놀계 수지가 혼합된 형태일 수도 있다. 본 발명에서는 혼합 바인더의 내열성을 높임으로써, 300℃ 가량의 고온으로 발열시키는 경우에도 물질의 저항 변화나 도막의 파손이 없다는 장점을 갖는다.The mixed binder serves to allow the exothermic paste composition to have heat resistance even in the temperature range of about 300 ° C., and includes epoxy acrylate or hexamethylene diisocyanate, polyvinyl acetal, and the like. Phenolic resin has a mixed form. For example, the mixed binder may be a mixture of epoxy acrylate, polyvinyl acetal, and phenolic resin, or may be a mixture of hexamethylene diisocyanate, polyvinyl acetal, and phenolic resin. In the present invention, by increasing the heat resistance of the mixed binder, even if the heat generated at a high temperature of about 300 ℃ has the advantage that there is no change in resistance of the material or breakage of the coating film.
여기에서 페놀계 수지는 폐놀 및 페놀 유도체를 포함하는 페놀계 화합물을 의미한다. 예컨대 상기 페놀 유도체는 p-크레졸(p-Cresol), o-구아야콜(o-Guaiacol), 크레오졸(Creosol), 카테콜(Catechol), 3-메톡시-1,2-벤젠디올(3-methoxy-1,2-Benzenediol), 호모카테콜(Homocatechol), 비닐구아야콜(vinylguaiacol), 시링콜(Syringol), 이소-유제놀(Iso-eugenol), 메톡시 유제놀(Methoxyeugenol), o-크레졸(o-Cresol), 3-메틸-1,2-벤젠디올(3-methoxy-1,2-Benzenediol), (z)-2-메톡시-4-(1-프로페닐)-페놀((z)-2-methoxy-4-(1-propenyl)-Phenol), 2,.6-디에톡시-4-(2-프로페닐)-페놀(2,6-dimethoxy-4-(2-propenyl)-Phenol), 3,4-디메톡시-페놀(3,4-dimethoxy-Phenol), 4-에틸-1,3-벤젠디올(4ethyl-1,3-Benzenediol), 레졸 페놀(Resole phenol), 4-메틸-1,2-벤젠디올(4-methyl-1,2-Benzenediol), 1,2,4-벤젠트리올(1,2,4-Benzenetriol), 2-메톡시-6-메틸페놀(2-Methoxy-6-methylphenol), 2-메톡시-4-비닐페놀(2-Methoxy-4-vinylphenol) 또는4-에틸-2-메톡시-페놀(4-ethyl-2-methoxy-Phenol) 등이 있으며, 이에 한정되는 것은 아니다.Herein, the phenolic resin means a phenolic compound including phenol and phenol derivatives. For example, the phenol derivative may include p-cresol, o-Guaiacol, Creosol, catechol, 3-methoxy-1,2-benzenediol (3 -methoxy-1,2-Benzenediol), Homocatechol, Vinylguaiacol, Syringol, Iso-eugenol, Methoxyeugenol, o O-Cresol, 3-methyl-1,2-benzenediol, (z) -2-methoxy-4- (1-propenyl) -phenol ( (z) -2-methoxy-4- (1-propenyl) -Phenol), 2, .6-diethoxy-4- (2-propenyl) -phenol (2,6-dimethoxy-4- (2-propenyl) ) -Phenol), 3,4-dimethoxy-Phenol, 4-ethyl-1,3-benzenediol, Resol phenol, 4-methyl-1,2-benzenediol (4-methyl-1,2-Benzenediol), 1,2,4-benzenetriol (1,2,4-Benzenetriol), 2-methoxy-6-methylphenol (2-Methoxy-6-methylphenol), 2-Methoxy-4-vinylphenol or 4-ethyl-2-methoxy-phenol (4-ethyl-2-methoxy-Phenol) Such as Information that is not.
상기 혼합 바인더의 혼합 비율은 에폭시 아크릴레이트 또는 헥사메틸렌 디이소시아네이트 100 중량부에 대하여 폴리비닐 아세탈수지 10 내지 150 중량부, 페놀계 수지 100 내지 500 중량부의 비율일 수 있다. 페놀계 수지의 함량이 100 중량부 이하인 경우 발열 페이스트 조성물의 내열 특성이 저하되며, 500 중량부를 초과하는 경우에는 유연성이 저하되는 문제가 있다(취성 증가).The mixing ratio of the mixed binder may be a ratio of 10 to 150 parts by weight of polyvinyl acetal resin and 100 to 500 parts by weight of phenolic resin based on 100 parts by weight of epoxy acrylate or hexamethylene diisocyanate. If the content of the phenolic resin is 100 parts by weight or less, the heat resistance characteristics of the heat-paste composition is lowered, and if it exceeds 500 parts by weight, there is a problem that the flexibility is lowered (brittleness increase).
유기 용매는 상기 전도성 입자 및 혼합 바인더를 분산시키기 위한 것으로, 카비톨 아세테이트(Carbitol acetate), 부틸 카비톨 아세테이트(Butyl carbotol acetate), DBE(dibasic ester), 에틸카비톨(Ethyl Carbitol), 에틸카비톨아세테이트, 디프로필렌글리콜메틸에테르(dipropylene glycol methyl ether), 셀로솔브아세테이트(Cellosolve acetate), 부틸셀로솔브아세테이트, 부탄올(Butanol) 및 옥탄올(Octanol) 중에서 선택되는 2 이상의 혼합 용매일 수 있다.The organic solvent is used to disperse the conductive particles and the mixed binder. Carbitol acetate, butyl carbotol acetate, dibasic ester, ethyl carbitol, ethyl carbitol It may be at least two mixed solvents selected from acetate, dipropylene glycol methyl ether, cellosolve acetate, butyl cellosolve acetate, butanol and octanol.
한편, 분산을 위한 공정은 통상적으로 사용되는 다양한 방법들이 적용될 수 있으며, 예를 들면 초음파처리(Ultra-sonication), 롤밀(Roll mill), 비드밀(Bead mill) 또는 볼밀(Ball mill) 과정을 통해 이루어질 수 있다.On the other hand, the dispersion process can be applied to a variety of commonly used methods, for example through the ultra-sonication (Roll mill), bead mill (Bead mill) or ball mill (Ball mill) process Can be done.
분산제는 상기 분산을 보다 원활하게 하기 위한 것으로, BYK류와 같이 당업계에서 이용되는 통상의 분산제, Triton X-100과 같은 양쪽성 계면활성제, SDS등과 가은 이온성 계면활성제를 이용할 수 있다.The dispersant is to make the dispersion more smoothly, and a conventional dispersant used in the art such as BYK, an amphoteric surfactant such as Triton X-100, SDS and the like and a ionic surfactant may be used.
본 발명의 일실시예에 따른 발열 페이스트 조성물은 발열 페이스트 조성물 100 중량부에 대하여 실란 커플링제 0.5 내지 5 중량부를 더 포함할 수 있다.The exothermic paste composition according to an embodiment of the present invention may further include 0.5 to 5 parts by weight of the silane coupling agent based on 100 parts by weight of the exothermic paste composition.
실란커플링제는 발열 페이스트 조성물의 배합시에 수지들간에 접착력을 증진시키는 접착증진제 기능을 한다. 실란 커플링제는 에폭시 함유 실란 또는 머켑토 함유 실란일 수 있다. 이러한 실란 커플링제의 예로는 에폭시가 함유된 것으로 2-(3,4 에폭시 사이클로헥실)-에틸트리메톡시실란, 3-글리시독시트리메톡시실란, 3-글리시독시프로필트리에톡시실란, 3-글리시독시프로필트리에톡시실란이 있고, 아민기가 함유된 것으로 N-2(아미노에틸)3-아미토프로필메틸디메톡시실란, N-2(아미노에틸)3-아미노프로필트리메톡시실란, N-2(아미노에틸)3-아미노프로필트리메톡시실란, 3-아미노프로필트리에톡시실란, 3-아미노프로필트리에톡시실, 3-트리에톡시실리-N-(1,2-디메틸뷰틸리덴)프로필아민, N-페닐-3-아미노프로필트리메톡시실란이 있으며, 머켑토가 함유된 것으로 3-머켑토프로필메틸디메톡시실란, 3-머켑토프로필트리에톡시실란, 이소시아네이트가 함유된 3-이소시아네이트프로필트리에톡시실란 등이 있으며, 상기 나열한 것으로 한정되지 않는다.The silane coupling agent functions as an adhesion promoter to promote adhesion between the resins in the formulation of the exothermic paste composition. The silane coupling agent may be an epoxy containing silane or a merceto containing silane. Examples of such silane coupling agents include epoxy and include 2- (3,4 epoxy cyclohexyl) -ethyltrimethoxysilane, 3-glycidoxytrimethoxysilane, 3-glycidoxypropyltriethoxysilane, 3-glycidoxypropyltriethoxysilane, containing amine groups, N-2 (aminoethyl) 3-amitopropylmethyldimethoxysilane, N-2 (aminoethyl) 3-aminopropyltrimethoxysilane , N-2 (aminoethyl) 3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, 3-aminopropyltriethoxysil, 3-triethoxysil-N- (1,2-dimethyl Butylidene) propylamine, N-phenyl-3-aminopropyltrimethoxysilane, containing merceto, 3-mercetopropylmethyldimethoxysilane, 3-mercetopropyltriethoxysilane, isocyanate Contained 3-isocyanatepropyltriethoxysilane and the like and are limited to those listed above. No.
여기에서 상기 기판은 폴리카보네이트, 폴리에틸렌테레프탈레이트(PET), 폴리에틸렌나프탈레이트(PEN), 플리이미드, 셀룰로스 에스텔, 나일론, 폴리프로필렌, 폴리아크릴로린트릴, 폴리술폰, 폴리에스테르술폰, 폴리비닐리덴플롤라이드, 유리, 유리섬유(매트), 세라믹, SUS, 구리 또는 알루미늄 기판 등이 사용될 수 있으며, 상기 나열된 것들로 한정되는 것은 아니다. 상기 기판은 발열체의 응용 분야나 사용온도에 따라 적절히 선택될 수 있다.Wherein the substrate is polycarbonate, polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyimide, cellulose ester, nylon, polypropylene, polyacrylolintril, polysulfone, polyester sulfone, polyvinylidene fluoride , Glass, glass fiber (matte), ceramic, SUS, copper or aluminum substrate, etc. may be used, but is not limited to those listed above. The substrate may be appropriately selected depending on the application field of the heating element or the use temperature.
면상 발열체는 상기 기판 상에 본 발명의 실시예들에 따른 발열 페이스트 조성물을 스크린 인쇄 또는 그라비아 인쇄를 통해 원하는 패턴으로 인쇄하고, 건조 및 경화한 후에, 상부에 은 페이스트 또는 도전성 페이스트를 인쇄 및 건조/경화 시킴으로써 전극을 형성함으로써 형성될 수 있다. 또는 은 페이스트 또는 도전성 페이스트를 인쇄 및 건조/경화한 후에 상부에 본 발명의 실시예들에 따른 발열 페이스트 조성물을 스크린 인쇄 또는 그라비아 인쇄함으로써 형성하는 것도 가능하다.The planar heating element prints the drying paste composition according to the embodiments of the present invention on the substrate in a desired pattern through screen printing or gravure printing, and after drying and curing, the printing and drying / It can be formed by forming an electrode by curing. Alternatively, after printing and drying / curing the silver paste or the conductive paste, the heating paste composition according to the embodiments of the present invention may be formed by screen printing or gravure printing.
한편, 상기 면상 발열체는 상부면에 코팅되는 보호층을 더 포함할 수 있다. 상기 보호층은 실리카(SiO₂)로 형성될 수 있다. 보호층이 실리카로 형성되는 경우에는 발열면에 코팅되더라도 발열체가 유연성을 유지할 수 있는 장점을 갖는다.On the other hand, the surface heating element may further include a protective layer coated on the upper surface. The protective layer may be formed of silica (SiO₂). When the protective layer is formed of silica, the heating element has an advantage of maintaining flexibility even if coated on the heating surface.
이하, 본 발명에 따른 후막 형성용 발열 페이스트 조성물 및 이를 이용한 면상 발열체를 시험예를 통하여 상세히 설명한다. 하기 시험예는 본 발명을 설명하기 위한 예시일 뿐, 본 발명이 하기 시험예에 의해 한정되는 것은 아니다.Hereinafter, the heat generating paste composition for forming a thick film and the planar heating element using the same according to the present invention will be described in detail. The following test examples are only examples for explaining the present invention, and the present invention is not limited by the following test examples.
시험예Test Example
(1) 실시예 및 비교예의 준비(1) Preparation of Examples and Comparative Examples
하기 [표1]과 같이 실시예(3종류) 및 비교예(3종류)를 준비하였다. [표 1]에 표기된 조성비는 중량%로 기재된 것임을 밝혀둔다.As shown in Table 1 below, examples (three types) and comparative examples (three types) were prepared. Note that the composition ratios shown in Table 1 are described in weight percent.
실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3
CNT 입자CNT particles 44 55 66 44 55 66
CNP 입자CNP Particles 88 99 1515 -- -- --
혼합 바인더 Mixed binder 2020 1515 2222 -- -- --
에틸셀룰로오스Ethyl cellulose -- -- -- 1010 1212 1414
유기용매Organic solvent 6363 6767 5252 8282 7979 7676
분산제(BYK)Dispersant (BYK) 55 44 55 44 44 44
실시예들의 경우 CNT 입자와, CNP 입자(실시예 1 내지 3)를 [표 1]의 조성에 따라 카비톨아세테이트 용매에 첨가하고 BYK 분산제를 첨가한 후, 60분간 초음파 처리를 통해 분산액 A를 제조하였다. 이후, 혼합 바인더를 카비톨아세테이트 용매에 첨가한 후 기계적 교반을 통해 마스터 배치를 제조하였다. 다음으로 상기 분산액 A 및 마스터배치를 기계적 교반을 통해 1차 혼련한 후에 3-롤-밀 과정을 거쳐 2차 혼련함으로써 발열 페이스트 조성물을 제조하였다.In the case of Examples, CNT particles and CNP particles (Examples 1 to 3) were added to a carbitol acetate solvent according to the composition of [Table 1], BYK dispersant was added, and dispersion A was prepared by sonication for 60 minutes. It was. Thereafter, a mixed binder was added to the carbitol acetate solvent and then a master batch was prepared through mechanical stirring. Next, the dispersion A and the masterbatch were first kneaded through mechanical stirring, followed by a second kneading process through a 3-roll-mill process to prepare an exothermic paste composition.
비교예들의 경우 CNT 입자를 [표 1]의 조성에 따라 카비톨아세테이트 용매에 첨가하고 BYK 분산제를 첨가한 후, 60분간 초음파 처리를 통해 분산액을 제조하였다. 이후, 에틸셀룰로오스를 카비톨아세테이트 용매에 첨가한 후 기계적 교반을 통해 마스터 배치를 제조하였다. 다음으로 상기 분산액 B 및 마스터배치를 기계적 교반을 통해 1차 혼련한 후에 3-롤-밀 과정을 거쳐 2차 혼련함으로써 발열페이스트 조성물을 제조하였다.For the comparative examples, CNT particles were added to the carbitol acetate solvent according to the composition of [Table 1], BYK dispersant was added, and a dispersion was prepared by sonication for 60 minutes. Thereafter, ethyl cellulose was added to the carbitol acetate solvent to prepare a master batch through mechanical stirring. Next, the dispersion B and the masterbatch were first kneaded through mechanical stirring, followed by a second kneading process through a 3-roll mill to prepare an exothermic paste composition.
(2) 면상 발열체 특성 평가(2) Evaluation of Planar Heating Element Characteristics
실시예 및 비교예에 따른 발열 페이스트 조성물을 10×10cm 크기로 폴리이미드 기판 위에 스크린 인쇄하고 경화한 후에, 상부 양단에는 은 페이스트 전극을 인쇄하고 경화하여 면상 발열체 샘플을 제조하였다.After heating and curing the exothermic paste compositions according to Examples and Comparative Examples on a polyimide substrate with a size of 10 × 10 cm, silver paste electrodes were printed and cured on both upper ends to prepare a planar heating element sample.
관련하여 도 9는 본 발명에 따른 발열 페이스트 조성물을 이용하여 제작한 면상 발열체 시편의 이미지이다. 도 9(a)는 폴리이미드 기판 위에 발열 페이스트 조성물이 스크린 인쇄되어 형성된 면상 발열체이다. 도 9(b)는 유리섬유 매트 위에 발열 페이스트 조성물이 스크린 인쇄되어 형성된 면상 발열체이다. 도 9(c) 및 도 9(d)는 도 9(a)의 면상 발열체 상부에 보호층을 코팅한 경우의 이미지이다.(도 9(c)는 검은색 보호층 코팅, 도 9(d)는 녹색 보호층 코팅).9 is an image of a planar heating element specimen prepared using the heating paste composition according to the present invention. Fig. 9A is a planar heating element formed by screen printing a heat generating paste composition on a polyimide substrate. Figure 9 (b) is a planar heating element formed by screen printing the heating paste composition on a glass fiber mat. 9 (c) and 9 (d) are images when a protective layer is coated on the planar heating element of FIG. 9 (a). FIG. 9 (c) is a black protective layer coating and FIG. 9 (d). Coated with a green protective layer).
도 9(a)에 나타난 것과 같은 면상 발열체 샘플(실시예) 및 상기 비교예에 따라 제조된 면상 발열체 샘플들의 비저항을 측정하였다 인가되는 전압/전류는 표2에 표기됨). 또한, 인가되는 전압/전류에 따른 승온 효과를 확인하기 위해 상기 실시예 및 비교예에 해당하는 면상 발열체를 각각 40℃, 100℃ 및 200℃까지 승온시키고, 상기 온도에 도달하였을 때의 DC 전압 및 전류를 측정하였다.Specific resistance of the planar heating element samples (Example) and planar heating element samples prepared according to the comparative example as shown in FIG. 9 (a) was measured. The voltage / current applied is shown in Table 2). In addition, in order to confirm the temperature increase effect according to the applied voltage / current, the planar heating element corresponding to the above Examples and Comparative Examples was heated up to 40 ° C., 100 ° C. and 200 ° C., respectively, and the DC voltage when the temperature was reached and The current was measured.
또한, 각 샘플들에 대하여 200℃에서의 발열안정성을 테스트하였다. 관련하여, 도 10에서는 실시예 및 비교예에 따라 제조된 면상 발열체 샘플들의 발열안정성 시험 모습의 이미지를 나타내었으며, 시험결과는 하기 [표 2]에 정리하였다.In addition, exothermic stability at 200 ° C. was tested for each sample. In this regard, Figure 10 shows the image of the heat stability test appearance of the planar heating element samples prepared according to the Examples and Comparative Examples, the test results are summarized in the following [Table 2].
실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3
비저항(×10ˇ²ΩcmSpecific resistance (× 10ˇ²Ωcm 1.91.9 2.552.55 2.962.96 9.739.73 8.528.52 6.236.23
40℃ 도달 DC 구동 전압/전류40 ℃ reach DC drive voltage / current 5V/0.2A5V / 0.2A 6V/0.2A6V / 0.2A 7V/0.2A7V / 0.2A 20V/0.3A20V / 0.3A 16V/0.2A16V / 0.2A 12V/0.2A12V / 0.2A
100℃ 도달 DC 구동 전압/전류100 ℃ reach DC driving voltage / current 9V/0.5A9V / 0.5A 12V/0.4A12V / 0.4A 14V/0.5A14 V / 0.5 A 48V/0.7A48V / 0.7A 40V/0.7A40V / 0.7A 26V/0.6A26V / 0.6A
200℃ 도달 DC 구동 전압/전류200 ℃ reach DC drive voltage / current 20V/0.6A20V / 0.6A 24V/0.7A24V / 0.7A 24V/1.0A24V / 1.0A -- -- --
발열안정성(day)Heat stability (day) 20일 이상20 days or more 20일 이상20 days or more 20일 이상20 days or more 불량Bad 불량Bad 불량Bad
상기 [표 2]를 참조하며, 비저항은 실시예들에 해당하는 면상 발열체가 비교예들에 해당하는 면상 발열체보다 작게 측정되었으며, 이에 따라 각 온도 에 도달하기 위해 필요한 구동 전압/전류 역시 실시예들에 해당하는 면상 발열체가 비교예들에 해당하는 면상 발열체보다 작게 측정되었다. 즉 실시예들에 해당하는 면상 발열체가 비교예보다 저전압 및 저전력으로 구동 가능함을 확인할 수 있었다.Referring to the above [Table 2], the specific resistance was measured that the planar heating element corresponding to the embodiments is smaller than the planar heating element corresponding to the comparative examples, accordingly driving voltage / current required to reach each temperature is also embodiments The planar heating element corresponding to was smaller than the planar heating element corresponding to the comparative examples. That is, it was confirmed that the planar heating element corresponding to the embodiments can be driven at a lower voltage and lower power than the comparative example.
또한, 실시예 1 내지 3에 따른 면상 발열체에서는 200℃의 발열 구동하에서도 20일간 안정성이 유지되는 것으로 나타나는 반면에(별도의 보호층 없음), 비교예 1 내지 3에서는 200℃의 발열 구동시 2시간 이내에 발열부 표면이 부풀어 오르는 불량 현상이 관찰되었다. 즉 실시예들에 해당하는 면상 발열체가 비교예보다 200℃이상의 고온에서도 안정적으로 구동 가능함을 확인할 수 있었다. In addition, in the planar heating elements according to Examples 1 to 3, the stability was maintained for 20 days even under an exothermic driving at 200 ° C. (no separate protective layer), whereas in Comparative Examples 1 to 3, the exothermic driving at 200 ° C. was performed. Poor phenomena were observed to swell the surface of the heating portion within time. That is, it was confirmed that the planar heating element corresponding to the embodiments can be stably driven even at a high temperature of 200 ° C. or more than the comparative example.
상기와 같은 구성을 가진 공기 청정기는 다음과 같이 동작한다. The air purifier having the configuration as described above operates as follows.
본체(10)의 상부에 구비된 조작패널(14)의 조작에 의해서 공기 청정기가 작동되면 모터(53)와 송풍팬(52)에 의해서 공기가 본체(10)의 흡입구(12)를 통해서 본체 내부로 유입된다. When the air purifier is operated by the operation of the operation panel 14 provided on the upper part of the main body 10, the air is driven by the motor 53 and the blowing fan 52 through the inlet 12 of the main body 10. Flows into.
상기 집진부(70)인 사이클론의 흡입덕트(20) 하부에 설치된 스팀플라즈마 발생모듈(100)의 작동에 의해서 공기 중에 포함된 미세 먼지 입자들이 집진된다. Fine dust particles contained in the air are collected by the operation of the steam plasma generating module 100 installed below the suction duct 20 of the cyclone, which is the dust collector 70.
스팀플라즈마 발생모듈(100) 저장부(110)의 물은 유출구(113)를 통해서 저장부(110)의 장착부(112)에 설치된 하우징(121)으로 공급된다. 하우징(121)의 고정부(126) 밖으로 일정부분 노출된 분산체(124)가 응집력이나 표면장력 또는 모세관현상을 통해 물을 흡수 확산하고, 분산체(124) 사이에 설치된 면상 발열체로 구성된 히터(122)가 흡수된 물을 가열하여 스팀을 생성한다. 면상 발열체를 이용함으로써 물을 빨리 가열할 수 있다. 한편, 상기 분산체(124) 없이 저장부(110)에서 흘러나온 물을 히터(122)가 직접 가열하여 스팀을 생성하도록 구성할 수도 있다.The water of the steam plasma generating module 100 storage unit 110 is supplied to the housing 121 installed in the mounting unit 112 of the storage unit 110 through the outlet port 113. The dispersion 124 partially exposed outside the fixing part 126 of the housing 121 absorbs and diffuses water through cohesion, surface tension, or capillary action, and is configured as a heater having a planar heating element installed between the dispersions 124 ( 122) generates the steam by heating the absorbed water. By using a surface heating element, water can be heated quickly. Meanwhile, the heater 122 may directly heat the water flowing out of the storage 110 without the dispersion 124 to generate steam.
스팀이 하우징(121)내에 충전된 상태에서, 하우징(121)의 상단 개구부에 장착된 커버부(130)의 양측면에 장착된 전극(132)에 고압을 인가하면 전극(132) 사이에서 코로나방전이 일어나 스팀플라즈마가 생성되고, 이러한 스팀플라즈마는 커버부(130)의 방출구(131)를 통해 흡입덕트(20) 내부로 유입된다. 스팀플라즈마 발생모듈(100)이 상기 흡입덕트(20) 하부에 설치되어 있기 때문에 별도의 공급 기구가 없더라도 스팀플라즈마가 자체의 부력에 의해서 흡입덕트(20) 내부로 스스로 유입된다. 흡입덕트(20) 내부로 유입된 스팀플라즈마는 흡입되는 공기 중의 미세 먼지 입자들을 응집하여 집진하게 된다.When steam is charged in the housing 121, when high pressure is applied to the electrodes 132 mounted on both sides of the cover 130 mounted at the upper opening of the housing 121, corona discharge is generated between the electrodes 132. The steam plasma is generated, and the steam plasma is introduced into the suction duct 20 through the outlet 131 of the cover 130. Since the steam plasma generating module 100 is installed below the suction duct 20, even without a separate supply mechanism, the steam plasma is introduced into the suction duct 20 by its own buoyancy. The steam plasma introduced into the suction duct 20 collects and collects the fine dust particles in the sucked air.
본 발명에서는, 스팀플라즈마의 쌍극자이온(bipolar ion)에 의해 공기 중의 미세 먼지 입자들이 응착되어 먼지 덩어리를 이루게 되고, 이러한 먼지 덩어리는 상대적으로 큰 먼지 입자들과 함께 집진부(70)인 사이클론 내부로 유입된다. 사이클론 내부로 유입된 먼지 덩어리와 큰 먼지 입자들은 송풍팬(52)에 의해 발생된 원심력에 의해 사이클론(72)에서 선회운동을 하며 하강하여 사이클론(72)의 내면벽에 집진되고 사이클론(72)의 경사 때문에 먼지배출구(76)를 통해서 집진용기(73)에 쌓이게 된다. 이렇게 집진용기(73)에 쌓인 먼지 덩어리나 큰 먼지 입자들은 집진용기를 비움으로써 간단히 제거할 수 있다.In the present invention, fine dust particles in the air are adhered by bipolar ions of the steam plasma to form a dust mass, and the dust mass flows into the cyclone, which is the dust collecting part 70 together with the relatively large dust particles. do. The dust mass and the large dust particles introduced into the cyclone are pivoted in the cyclone 72 by the centrifugal force generated by the blower fan 52 and are lowered to be collected on the inner wall of the cyclone 72 to collect the cyclone 72. Due to the inclination, it is accumulated in the dust collecting container 73 through the dust outlet 76. The dust mass or large dust particles accumulated in the dust collecting container 73 can be easily removed by emptying the dust collecting container.
상대적으로 중간 크기의 먼지 입자들 또는 미처 집진되지 못한 먼지 입자들은 집진부(70)인 사이클론의 배출덕트(75)를 통해서 여과 필터(80)인 헤파필터로 보내져서 최종적으로 걸러진 후, 정화된 깨끗한 공기만 토출구(13)를 통해서 토출된다. Relatively medium dust particles or uncollected dust particles are sent to the HEPA filter, which is the filtration filter 80, through the cyclone discharge duct 75, which is the dust collecting part 70, and finally filtered, and then purified clean air. Only through the discharge port 13 is discharged.
이상, 본 발명의 실시예들에 대하여 설명하였다. 그러나 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자라면 특허청구범위에 기재된 본 발명의 기술적 사상의 범위 내에서 기술의 구체적 적용에 따른 단순한 설계변경, 일부 구성요소의 생략, 단순한 용도의 변경 등의 형태로 본 발명을 다양하게 변형할 수 있을 것이며, 이 또한 본 발명의 권리범위 내에 포함됨은 자명하다.In the above, embodiments of the present invention have been described. However, those skilled in the art to which the present invention pertains, within the scope of the technical spirit of the present invention described in the claims, simple design changes, omission of some components, simple use changes, etc. It will be apparent that the present invention may be variously modified in the form of the present invention, which is also included within the scope of the present invention.

Claims (8)

  1. 흡입구; Inlet;
    상기 흡입구로부터 유입되는 공기를 정화시키는 집진부; 및 A dust collecting unit for purifying the air flowing from the suction port; And
    상기 흡입구로부터 상기 집진부로 유입되는 상기 공기에 스팀을 공급하는 스팀 플라즈마 발생모듈;을 포함하며,And a steam plasma generating module for supplying steam to the air introduced from the suction port to the dust collecting unit.
    상기 스팀 플라즈마 발생모듈은The steam plasma generating module
    물 저장부;Water storage unit;
    상기 물 저장부의 물을 가열하기 위한 면상 발열체로 구성된 히터; 및 A heater composed of a surface heating element for heating water in the water storage part; And
    상기 히터에 의해 생성된 스팀에 방전을 하기 위한 전극;을 포함하고, And an electrode for discharging steam generated by the heater.
    상기 면상 발열체는 The planar heating element
    발열페이스트 조성물 100 중량부에 대하여 탄소나노튜브 입자 3 내지 6중량부, 탄소나노입자 0.5 내지 30중량부, 혼합 바인더 10 내지 30중량부, 유기 용매 29 내지 83 중량부, 및 분산제 0.5 내지 5중량부를 포함하고, 3 to 6 parts by weight of carbon nanotube particles, 0.5 to 30 parts by weight of carbon nanoparticles, 10 to 30 parts by weight of a mixed binder, 29 to 83 parts by weight of an organic solvent, and 0.5 to 5 parts by weight of a dispersant based on 100 parts by weight of the exothermic paste composition. Including,
    상기 혼합 바인더는 에폭시 아크릴레이트 , 폴리비닐 아세탈 및 페놀계 수지가 혼합되거나 헥사메틸렌 디이소시아네이트, 폴리비닐 아세탈 및 페놀계 수지가 혼합되는 발열 페이스트 조성물을 포함하는 공기 청정기.The mixed binder includes an exothermic paste composition in which epoxy acrylate, polyvinyl acetal and phenolic resin are mixed or hexamethylene diisocyanate, polyvinyl acetal and phenolic resin are mixed.
  2. 제1항에 있어서, The method of claim 1,
    상기 혼합 바인더는 에폭시 아크릴레이트 또는 헥사메틸렌 디이소시아네이트 100 중량부에 대하여 폴리비닐 아세탈 수지 10 내지 150 중량부, 페놀계수지 100 내지 500 중량부가 혼합되는 공기 청정기.The mixed binder is 10 to 150 parts by weight of polyvinyl acetal resin, 100 to 500 parts by weight of phenolic resin based on 100 parts by weight of epoxy acrylate or hexamethylene diisocyanate.
  3. 제1항 또는 제2항에 있어서, The method according to claim 1 or 2,
    발열 페이스트 조성물 100 중량부에 대하여 실란 커플링제 0.5 내지 5 중량부를 더 포함하는 공기 청정기.An air purifier further comprising 0.5 to 5 parts by weight of the silane coupling agent based on 100 parts by weight of the exothermic paste composition.
  4. 제1항 또는 제2항에 있어서, The method according to claim 1 or 2,
    상기 탄소나노튜브입자는 다중벽 탄소나노튜브 입자인 공기 청정기.The carbon nanotube particles are multi-walled carbon nanotube particles.
  5. 제1항 또는 제2항에 있어서, The method according to claim 1 or 2,
    상기 유기 용매는 카비톨 아세테이트, 부틸 카비톨 아세테이트, DBE(dibasic ester), 에틸카비톨, 에틸카비톨아세테이트, 디프로필렌글리콜메틸에테르, 셀로솔브아세테이트, 부틸셀로솔브아세테이트, 부탄올 및 옥탄올 중에서 선택되는 2 이상의 혼합 용매인 공기 청정기.The organic solvent is selected from carbitol acetate, butyl carbitol acetate, DBE (dibasic ester), ethyl carbitol, ethyl carbitol acetate, dipropylene glycol methyl ether, cellosolve acetate, butyl cellosolve acetate, butanol and octanol Air freshener that is two or more mixed solvents.
  6. 제1항에 있어서, 상기 면상 발열체는 According to claim 1, wherein the planar heating element
    상기 발열 페이스트 조성물을 기판상에 스크린 인쇄, 그라비아 인쇄 또는 콤마코팅하여 형성되는 공기 청정기.An air purifier formed by screen printing, gravure printing or comma coating the exothermic paste composition on a substrate.
  7. 제6항에 있어서, The method of claim 6,
    상기 기판은 폴리이미드 기판, 유리섬유 매트 또는 세라믹 유리인 공기 청정기.The substrate is a polyimide substrate, glass fiber mat or ceramic glass.
  8. 제6항에 있어서, The method of claim 6,
    상기 면상 발열체 상부면에 코팅되는 것으로, 실리카 또는 카본븍랙과 같은 흑색 안료를 구비하는 유기물로 형성되는 보호층을 더 포함하는 공기 청정기.The air purifier is coated on the top surface of the planar heating element, and further comprises a protective layer formed of an organic material having a black pigment such as silica or carbon shock.
PCT/KR2016/003293 2015-05-15 2016-03-30 Air purifier WO2016186316A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20150067926 2015-05-15
KR10-2015-0067926 2015-05-15

Publications (1)

Publication Number Publication Date
WO2016186316A1 true WO2016186316A1 (en) 2016-11-24

Family

ID=57320533

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2016/003293 WO2016186316A1 (en) 2015-05-15 2016-03-30 Air purifier

Country Status (1)

Country Link
WO (1) WO2016186316A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11696370B2 (en) 2020-04-22 2023-07-04 Whirlpool Corporation Household appliance with immersible heater

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040077658A (en) * 2001-11-02 2004-09-06 플라스마솔 코포레이션 Sterilization and decontamination system using a plasma discharge and a filter
KR100761279B1 (en) * 2006-04-24 2007-10-04 엘지전자 주식회사 Air cleaner
KR20100100285A (en) * 2009-03-06 2010-09-15 주식회사 엑사이엔씨 Heater using paste composition
JP2013100454A (en) * 2011-10-14 2013-05-23 Jnc Corp Heat-radiating coating composition and heat-radiating member using the same
KR101294596B1 (en) * 2012-02-09 2013-08-09 한화케미칼 주식회사 Composition and method of carbon nanotube paste for flat heating element device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040077658A (en) * 2001-11-02 2004-09-06 플라스마솔 코포레이션 Sterilization and decontamination system using a plasma discharge and a filter
KR100761279B1 (en) * 2006-04-24 2007-10-04 엘지전자 주식회사 Air cleaner
KR20100100285A (en) * 2009-03-06 2010-09-15 주식회사 엑사이엔씨 Heater using paste composition
JP2013100454A (en) * 2011-10-14 2013-05-23 Jnc Corp Heat-radiating coating composition and heat-radiating member using the same
KR101294596B1 (en) * 2012-02-09 2013-08-09 한화케미칼 주식회사 Composition and method of carbon nanotube paste for flat heating element device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11696370B2 (en) 2020-04-22 2023-07-04 Whirlpool Corporation Household appliance with immersible heater

Similar Documents

Publication Publication Date Title
WO2016111465A1 (en) Blowing apparatus of vehicle air-conditioning system including electric dust collecting unit and control method thereof
WO2016182199A1 (en) Battery pre-heating apparatus for hybrid vehicle and control method therefor
KR102632715B1 (en) Air purification devices and apparatus
WO2016186314A1 (en) Pot for vehicle
CN105992527A (en) Electronic cigarette
CN1261227C (en) Resin electrode and electrostatic dust collector using the same
CN101745463A (en) Electric precipitator and high voltage electrode thereof
WO2016186316A1 (en) Air purifier
KR20180104841A (en) Infrared air purifier using high temperature light
WO2013095029A1 (en) Carbon nanotube-coated down feather for storing heat, and winter clothing using same
WO2016182196A1 (en) Heating apparatus for semiconductor vacuum line using sheet heater
WO2021095964A1 (en) Air purification apparatus comprising compatible lower body
WO2016182198A1 (en) Heating device for electric vehicle and method for controlling same
JP2006187739A (en) Dust collector and air-conditioner
WO2016186315A1 (en) Drying device
CN107649290A (en) A kind of electrostatic precipitation module of high-pressure polar plate coating insulating coating
WO2021256645A1 (en) Air circulator having function to remove harmful substances such as fine dust
WO2018194432A9 (en) Membrane including porous substrate layer and cnt/chitosan nanohybrid coating layer, and electrostatic dust collection system including same
WO2019124623A1 (en) Plasma wire having carbon-based coating layer, and dust collector using same
WO2016186313A1 (en) Heating element fabric having heating paste composition, and heating steering wheel using same
WO2015174697A1 (en) Heating paste composition, and sheet heating element, heating roller, heating unit and heating module using same
WO2022265171A1 (en) Apparatus for preventing contamination of vehicle air conditioner
KR20160133943A (en) Heater for airconditioner
KR101642701B1 (en) Dish washer
WO2020027468A1 (en) Multifunctional indoor air conditioner

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 16796643

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 16796643

Country of ref document: EP

Kind code of ref document: A1