WO2016140903A1 - Improved yields in xylene isomerization using layer mfi zeolites - Google Patents

Improved yields in xylene isomerization using layer mfi zeolites Download PDF

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WO2016140903A1
WO2016140903A1 PCT/US2016/020010 US2016020010W WO2016140903A1 WO 2016140903 A1 WO2016140903 A1 WO 2016140903A1 US 2016020010 W US2016020010 W US 2016020010W WO 2016140903 A1 WO2016140903 A1 WO 2016140903A1
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xylene
para
isomerization
zeolite
mixture
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Gregory B. KUZMANICH
Jaime G. Moscoso
Deng-Yang Jan
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Honeywell UOP LLC
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UOP LLC
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
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    • B01J35/45—Nanoparticles
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    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732—Catalytic processes
    • C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Definitions

  • the present invention relates to a zeolite catalyst for improved performance in hydrocarbon conversion processes.
  • a zeolite catalyst for improved performance in hydrocarbon conversion processes.
  • xylene isomerization for para-xylene production.
  • aromatics complexes are designed to maximize the yield of benzene and para-xylene.
  • Benzene is a versatile petrochemical building block used in many different products based on its derivation including ethylbenzene, cumene, and cyclohexane.
  • Para- xylene is also an important building block, which is used almost exclusively for the production of polyester fibers, resins, and films formed via terephthalic acid or dimethyl terephthalate intermediates.
  • an aromatics complex may be configured in many different ways depending on the desired products, available feedstocks, and investment capital available. A wide range of options permits flexibility in varying the product slate balance of benzene and para-xylene to meet downstream processing requirements.
  • U.S. Pat. No. 3,996,305 to Berger discloses a fractionation scheme primarily directed to trans alkylation of toluene and Cg alkylaromatics in order to produce benzene and xylene.
  • the trans alkylation process is also combined with an aromatics extraction process.
  • the fractionation scheme includes a single column with two streams entering and with three streams exiting the column for integrated economic benefits.
  • U.S. Pat. No. 4,341,914 to Berger discloses a transalkylation process with recycle of Cg alkylaromatics in order to increase yield of xylenes from the process.
  • the transalkylation process is also preferably integrated with a paraxylene separation zone and a xylene isomerization zone operated as a continuous loop receiving mixed xylenes from the transalkylation zone feedstock and effluent fractionation zones.
  • U.S. Pat. No. 4,642,406 to Schmidt discloses a high severity process for xylene production that employs a transalkylation zone that simultaneously performs as an
  • isomerization zone over a nonmetal catalyst.
  • High quality benzene is produced along with a mixture of xylenes, which allows para-xylene to be separated by absorptive separation from the mixture with the isomer-depleted stream being passed back to the trans alkylation zone.
  • U.S. Pat. No. 5,417,844 to Boitiaux et al. discloses a process for the selective dehydrogenation of olefins in steam cracking petrol in the presence of a nickel catalyst and is characterized in that prior to the use of the catalyst, a sulfur-containing organic compound is incorporated into the catalyst outside of the reactor prior to use.
  • a first embodiment of the invention is a process for the production of para-xylene, comprising passing a mixture of hydrocarbons comprising xylenes to an isomerization reactor, operated at isomerization reaction conditions, to form a reaction mixture over an isomerization catalyst, and to generate an effluent stream comprising p-xylene; wherein the isomerization catalyst is characterized by a zeolite having a microporous crystalline structure comprising a framework of A10 2 and Si0 2 tetrahedral units, and an empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of M m n+ R r p+ AlSiyOz where M is at least one exchangeable cation selected from the group consisting of alkali and alkaline earth metals, "m" is the mole ratio of M to Al and varies from 0 to 3, R is at least one organoammonium cation selected from the group consisting of quaternary ammonium
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the isomerization reaction conditions include a temperature between 250°C and 350°C.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the isomerization reaction conditions include a temperature between 280°C and 310°C.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the isomerization reaction conditions include a pressure sufficient to maintain the reaction mixture in the liquid phase.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the pressure is at least 1025 kPa.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the mixture of hydrocarbons further includes ethylbenzene.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph where M in the zeolite is selected from the group consisting of sodium, potassium and mixtures thereof.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph where M in the zeolite is a mixture of an alkali metal and an alkaline earth metal.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph where R in the zeolite is selected from the group consisting of tetrabutyl ammonium hydroxide, tetrabutylphosphonium hydroxide, hexamethonium dihydroxide and mixture thereof.
  • R in the zeolite is selected from the group consisting of tetrabutyl ammonium hydroxide, tetrabutylphosphonium hydroxide, hexamethonium dihydroxide and mixture thereof.
  • R is a halide or hydroxide compound of an organoammonium cation.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the catalyst is characterized by a zeolite having a microporous crystalline structure comprising a framework of A10 2 and Si0 2 tetrahedral units, further including the element E and having the empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of M m n+ R r p+ Ali.
  • M is at least one exchangeable cation selected from the group consisting of alkali and alkaline earth metals
  • "m” is the mole ratio of M to (Al+E) and varies from 0 to 3
  • R is at least one organoammonium cation selected from the group consisting of quaternary ammonium cations, di quaternary ammonium cations
  • "r” is the mole ratio of R to (Al+E) and has a value of 0.1 to 30.0
  • n is the weight average valence of M and has a value of 1 to 2
  • "p” is the weighted average valence of Ri and has a value of 1 to 2
  • E is an element selected from the group consisting of gallium, iron, boron, indium and mixtures thereof
  • "x” is the mole fraction of E and has a value from 0 to 1.0
  • "y” is the mole ratio of Si to (Al+E) and varies from greater than 32 to 200
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph further comprising passing the effluent stream to a para-xylene separation unit to generate a para-xylene process stream and a second stream comprising meta-xylene and ortho-xylene.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the separation unit is an adsorption separation unit and generates and extract stream comprising para-xylene and desorbent and a raffinate stream comprising meta-xylene and ortho-xylene.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph further comprising passing the extract stream to a fractionation unit to generate a bottoms stream comprising para-xylene and an overhead stream comprising desorbent.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the raffinate stream is passed to the isomerization reactor.
  • a second embodiment of the invention is a process for the production of para- xylene, comprising passing a mixture of hydrocarbons comprising xylenes to an
  • isomerization reactor operated at isomerization reaction conditions, to form a reaction mixture over an isomerization catalyst, and to generate an effluent stream comprising para- xylene;
  • the isomerization catalyst is characterized by a catalyst having a 2-D layered MFI structure, to generate a process stream comprising olefins, wherein the catalyst is a zeolite of claim 1 having a microporous crystalline structure comprising a framework of A10 2 and Si0 2 tetrahedral units, further including the element E and having the empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of M m n+ R r p+ Ali -x E x Si y O z where M is at least one exchangeable cation selected from the group consisting of alkali and alkaline earth metals, "m" is the mole ratio of M to (Al+E) and varies from 0 to 3, R is at least one organoammonium cation selected from
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the second embodiment in this paragraph wherein the isomerization reaction conditions include a temperature between 250°C and 350°C.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the second embodiment in this paragraph wherein the isomerization reaction conditions include a pressure sufficient to maintain the reaction mixture in the liquid phase.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the second embodiment in this paragraph wherein the pressure is at least 1025 kPa.
  • An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the second embodiment in this paragraph wherein the mixture of hydrocarbons further includes ethylbenzene.
  • Para-xylene production is a valuable commercial process, wherein the reduction of losses can entail a significant economic advantage.
  • One method of improving para-xylene yields is to increase the conversion from C 8 compounds to para-xylene and to reduce losses during that conversion.
  • the operating of a liquid phase xylene isomerization reactor using a conventional MFI catalyst generates a significant xylene loss per pass. The loss is greater than 1.5%.
  • the invention of a new catalyst allows for a significant reduction in the xylene loss.
  • the new catalyst has a new zeolitic MFI morphology and can achieve comparable para- xylene content with xylene losses of around 0.2% or less.
  • the present invention is a process for the production of para-xylene.
  • the process includes passing a mixture of hydrocarbons including xylenes to an isomerization reactor, operated at isomerization reaction conditions to generate an effluent stream having para- xylene, or p-xylene.
  • the reaction conditions include forming a reaction mixture comprising C 8 hydrocarbons and passing the mixture over an isomerization catalyst.
  • the present invention utilizes a new catalyst that reduces the loss of xylenes during the isomerization process.
  • the catalyst is a zeolite catalyst made by using a charge density mismatch method.
  • the isomerization catalyst is a zeolite having a microporous crystalline structure comprising a framework of A10 2 and Si0 2 tetrahedral units, and an empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of:
  • the catalyst comprises M, which is at least one exchangeable cation selected from the group consisting of alkali and alkaline earth metals, R, which is at least one
  • organoammonium cation selected from the group consisting of quaternary ammonium cations, diquaternary ammonium cations, E, which is at least one element from gallium, iron, boron and indium.
  • Aluminum and silicon are supplied from alumina and silica.
  • "m” is the mole ratio of M to Al and varies from 0 to 3
  • "r” is the mole ratio of R to Al and has a value of 0.1 to 30.0
  • "y” is the mole ratio of Si to Al and varies from greater than 32 to 200
  • "z” is the mole ratio of O to Al.
  • the value "n” is the weight average valence of M and has a value of 1 to 2
  • "p” is the weighted average valence of R and has a value of 1 to 2.
  • the value of "z” is determined by the equation:
  • the catalyst can be further characterized by its unique x-ray diffraction pattern as at least the d spacing and intensities set forth in Table A:
  • the M in the zeolite can be a mixture of alkali metals and alkaline earth metals, with a preferred M including sodium and potassium.
  • the R cation can be selected from one or more of quaternary ammonium cations, quaternary phosphonium cations, and methonium cations.
  • the R cation can come from an halide compound or a hydroxide compound.
  • Preferred R cations for the zeolite are selected from the reactive materials including one or more of tetrabutyl ammonium hydroxide, tetrabutylphosphonium hydroxide and hexamethonium dihydroxide.
  • the isomerization reaction conditions include a temperature between 250°C and 350°C, with a preferred reaction temperature between 280°C and 310°C.
  • the reaction conditions include a pressure sufficient to maintain the reaction mixture in the liquid phase.
  • the pressure in the reactor is at least 1025 kPa, with a preferred reactor pressure in the range of 1750 kPa to 2400 kPa.
  • the feedstream preferably comprises C 8 aromatics, having meta-xylene and ortho- xylene.
  • the feedstream can also include ethylbenzene, wherein the isomerization reactor converts the meta-xylene and ortho-xylene to para-xylene, and the ethylbenzene to benzene.
  • the effluent stream leaving the isomerization reactor includes para-xylene is passed to a para-xylene separation unit to generate a para-xylene process stream, and a second stream comprising meta-xylene, ortho-xylene and ethylbenzene.
  • the para-xylene separation unit can comprise an adsorption separation unit, wherein the para-xylene process stream is the extract stream and the second stream is the raffinate stream.
  • the extract stream and raffinate streams can include a desorbent.
  • the extract stream is passed to a fractionation unit to generate a bottoms stream comprising para-xylene and an overhead stream comprising desorbent.
  • the process can further include passing the raffinate stream to the isomerization reactor.
  • the raffinate stream can also be passed to a second fractionation column to separate the desorbent from the raffinate stream before passing the raffinate stream to the
  • the catalyst is characterized by a zeolite having a microporous crystalline structure comprising a framework of A10 2 and Si0 2 tetrahedral units, further including the element E and having the empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of:
  • M is at least one exchangeable cation selected from the group consisting of alkali and alkaline earth metals
  • "m” is the mole ratio of M to (Al+E) and varies from 0 to 3
  • R is at least one organoammonium cation selected from the group consisting of quaternary ammonium cations, di quaternary ammonium cations
  • "r” is the mole ratio of R to (Al+E) and has a value of 0.1 to 30.0
  • n is the weight average valence of M and has a value of 1 to 2
  • "p” is the weighted average valence of R and has a value of 1 to 2
  • E is an element selected from the group consisting of gallium, iron, boron, indium and mixtures thereof
  • "x” is the mole fraction of E and has a value from 0 to 1.0
  • "y” is the mole ratio of Si to (Al+E) and varies from greater than 32 to 200
  • catalyst A Commercial pentasil zeolite from TOSOH (lot:HSZ-900-940 HA) was formulated into a catalyst containing 70% zeolite and 30% silica.
  • the zeolite was mixed with LUDOX AS-40 and Hi-Sil 250 into a muller mixer. Additional water was added to the Muller mixer, while mixing, until dough with a proper texture for extrusion was formed. The dough was extruded to form 1/16" diameter trilobes, which were dried at 100°C overnight and then sized to a length to diameter ratio of 3.
  • the dry extrudates was calcined in a box oven with a flowing air at 560°C for 6 hours to remove the template. This is referred to as catalyst A.
  • An aluminosilicate reaction solution was prepared by first mixing 13.73 g of aluminum tri-sec-butoxide (95 + %), 559.89 g tetrabutylphosphonium hydroxide (40 mass-
  • the product was identified as a pentasil zeolite by powder x-ray diffraction.
  • the pentasil zeolite of example 3 was formulated into a catalyst containing 70% zeolite and 30% silica.
  • the zeolite was mixed with LUDOX AS-40 and Hi-Sil 250 into a muller mixer. Additional water was added to the Muller mixer, while mixing, until dough with a proper texture for extrusion was formed.
  • the dough was extruded to form 1/16" diameter trilobes, which were dried at 100°C overnight and then sized to a length to diameter ratio of 3.
  • the dry extrudates was calcined in a box oven with a flowing air at 560°C for 6 hours to remove the template.
  • the calcined support was then exchanged using a 10 wt-% H 4 NO 3 solution at 75°C for one hour. This was followed by water wash using 20 cc of water per cc of extrudates. The H 4 NO 3 exchange and water wash was repeated three more times. The extrudates was then dried at 120°C for 4 hours and then activated at 550°C. This is labeled catalyst B.
  • An aluminosilicate reaction solution was prepared by first mixing 13.87 g of aluminum tri-sec-butoxide (95 + %), 386.39 g tetrabutylammonium hydroxide (55 mass-% solution), and 300 g of ice water mixture while stirring vigorously. After thorough mixing, 580.35 g tetraethyl orthosilicate was added. The reaction mixture was homogenized for an additional hour with a high speed mechanical stirrer. A composite aqueous solution containing 2.73 g of NaOH dissolved in 116.67 g distilled water was added, drop-wise, to the aluminosilicate solution.
  • reaction mixture was homogenized for 1 hour, transferred to a 2000 ml Parr stainless steel autoclave which was heated to 115°C and maintained at that temperature for 57 hrs.
  • the solid product was recovered by centrifugation, washed with de-ionized water, and dried at 80°C.
  • the product was identified as a pentasil zeolite by powder x-ray diffraction.
  • the pentasil zeolite of example 3 was formulated into a catalyst containing 70% zeolite and 30% silica.
  • the zeolite was mixed with LUDOX AS-40 and Hi-Sil 250 into a Muller mixer. Additional water was added to the Muller mixer, while mixing, until dough with a proper texture for extrusion was formed.
  • the dough was extruded to form 1/16" diameter trilobes, which were dried at 100°C overnight and then sized to a length to diameter ratio of 3.
  • the dry extrudates was calcined in a box oven with a flowing air at 560°C for 6 hours to remove the template.
  • the calcined support was then exchanged using a 10 wt-% H 4 NO 3 solution at 75°C for one hour. This was followed by water wash using 20 cc of water per cc of extrudates. The H 4 NO 3 exchange and water wash was repeated three more times. The extrudates was then dried at 120°C for 4 hours and then activated at 550°C.
  • Catalyst A was evaluated for xylene isomerization and ethyl-benzene retention using a pilot plant flow reactor processing a non-equilibrium C 8 aromatic feed having the following composition in wt-%:
  • Pilot-plant test conditions and results are as follows.
  • the above feed contacted the Catalyst at a pressure of 3.5 MPa in the liquid phase at a weight hourly space velocity of 10 under a range of temperatures.
  • the resulting performance measures are shown below:
  • the "Xylene Loss” is in mol-% defined as "(l-( para, meta, ortho xylene in product)/( -( para, meta, ortho xylene in feed))* 100", which represents material that has to be circulated to another unit in an aromatics complex. Such circulation is expensive and a low amount of C 8 ring loss is preferred. Al 1+ represents material that is heavier than 145 molecular weight. This material represents unrecoverable losses. Ethylbenzene conversion, 2 to 4.5% was low in all cases.

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Abstract

A process for the production of para-xylene is presented. The process includes the isomerization of C8 aromatics to para-xylene utilizing a new catalyst. The new catalyst is a layer MFI zeolite and is represented by the empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of: Mm n+R r p+ AlSiyOz where M is at least one exchangeable cation selected from the group consisting of alkali and alkaline earth metals and R is at least one organoammonium cation.

Description

IMPROVED YIELDS IN XYLENE ISOMERIZATION USING LAYER MFI ZEOLITES
STATEMENT OF PRIORITY
[OOOl] This application claims priority to U.S. Application No. 14/636541 which was filed March 3, 2015, the contents of which are hereby incorporated by reference in its entirety.
FIELD OF THE INVENTION
[0002] The present invention relates to a zeolite catalyst for improved performance in hydrocarbon conversion processes. In particular in the process of xylene isomerization for para-xylene production.
BACKGROUND
[0003] Most new aromatics complexes are designed to maximize the yield of benzene and para-xylene. Benzene is a versatile petrochemical building block used in many different products based on its derivation including ethylbenzene, cumene, and cyclohexane. Para- xylene is also an important building block, which is used almost exclusively for the production of polyester fibers, resins, and films formed via terephthalic acid or dimethyl terephthalate intermediates. Accordingly, an aromatics complex may be configured in many different ways depending on the desired products, available feedstocks, and investment capital available. A wide range of options permits flexibility in varying the product slate balance of benzene and para-xylene to meet downstream processing requirements.
[0004] A prior art aromatics complex flow scheme has been disclosed by Meyers in the Handbook of Petroleum Refining Processes, 2d. Edition in 1997 by McGraw-Hill.
[0005] U.S. Pat. No. 3,996,305 to Berger discloses a fractionation scheme primarily directed to trans alkylation of toluene and Cg alkylaromatics in order to produce benzene and xylene. The trans alkylation process is also combined with an aromatics extraction process. The fractionation scheme includes a single column with two streams entering and with three streams exiting the column for integrated economic benefits.
[0006] U.S. Pat. No. 4,341,914 to Berger discloses a transalkylation process with recycle of Cg alkylaromatics in order to increase yield of xylenes from the process. The transalkylation process is also preferably integrated with a paraxylene separation zone and a xylene isomerization zone operated as a continuous loop receiving mixed xylenes from the transalkylation zone feedstock and effluent fractionation zones.
[0007] U.S. Pat. No. 4,642,406 to Schmidt discloses a high severity process for xylene production that employs a transalkylation zone that simultaneously performs as an
isomerization zone over a nonmetal catalyst. High quality benzene is produced along with a mixture of xylenes, which allows para-xylene to be separated by absorptive separation from the mixture with the isomer-depleted stream being passed back to the trans alkylation zone.
[0008] U.S. Pat. No. 5,417,844 to Boitiaux et al. discloses a process for the selective dehydrogenation of olefins in steam cracking petrol in the presence of a nickel catalyst and is characterized in that prior to the use of the catalyst, a sulfur-containing organic compound is incorporated into the catalyst outside of the reactor prior to use.
[0009] The importance of para-xylene production has led to the development of many different processes. However, there are losses associated with these processes.
Improvements to reduce and minimize losses are important for the economics of para-xylene production.
SUMMARY
[0010] A first embodiment of the invention is a process for the production of para-xylene, comprising passing a mixture of hydrocarbons comprising xylenes to an isomerization reactor, operated at isomerization reaction conditions, to form a reaction mixture over an isomerization catalyst, and to generate an effluent stream comprising p-xylene; wherein the isomerization catalyst is characterized by a zeolite having a microporous crystalline structure comprising a framework of A102 and Si02 tetrahedral units, and an empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of Mm n+R r p+ AlSiyOz where M is at least one exchangeable cation selected from the group consisting of alkali and alkaline earth metals, "m" is the mole ratio of M to Al and varies from 0 to 3, R is at least one organoammonium cation selected from the group consisting of quaternary ammonium cations, di quaternary ammonium cations, "r" is the mole ratio of R to Al and has a value of 0.1 to 30.0 "n" is the weight average valence of M and has a value of 1 to 2, "p" is the weighted average valence of R and has a value of 1 to 2, "y" is the mole ratio of Si to Al and varies from greater than 32 to 200 and "z" is the mole ratio of O to Al and has a value determined by the equation z=(m n+r p+3+4 y)/2 and it is characterized in that it has the x- ray diffraction pattern having at least the d spacing and intensities set forth in the following Table A:
Table A
Figure imgf000004_0001
[OOl 1] An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the isomerization reaction conditions include a temperature between 250°C and 350°C. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the isomerization reaction conditions include a temperature between 280°C and 310°C. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the isomerization reaction conditions include a pressure sufficient to maintain the reaction mixture in the liquid phase. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the pressure is at least 1025 kPa. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the mixture of hydrocarbons further includes ethylbenzene. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph where M in the zeolite is selected from the group consisting of sodium, potassium and mixtures thereof. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph where M in the zeolite is a mixture of an alkali metal and an alkaline earth metal. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph where R in the zeolite is selected from the group consisting of tetrabutyl ammonium hydroxide, tetrabutylphosphonium hydroxide, hexamethonium dihydroxide and mixture thereof. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph where R is a halide or hydroxide compound of an organoammonium cation. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the catalyst is characterized by a zeolite having a microporous crystalline structure comprising a framework of A102 and Si02 tetrahedral units, further including the element E and having the empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of Mm n+R r p+ Ali. xExSiyOz where M is at least one exchangeable cation selected from the group consisting of alkali and alkaline earth metals, "m" is the mole ratio of M to (Al+E) and varies from 0 to 3, R is at least one organoammonium cation selected from the group consisting of quaternary ammonium cations, di quaternary ammonium cations, "r" is the mole ratio of R to (Al+E) and has a value of 0.1 to 30.0 "n" is the weight average valence of M and has a value of 1 to 2, "p" is the weighted average valence of Ri and has a value of 1 to 2, E is an element selected from the group consisting of gallium, iron, boron, indium and mixtures thereof, "x" is the mole fraction of E and has a value from 0 to 1.0, "y" is the mole ratio of Si to (Al+E) and varies from greater than 32 to 200 and "z" is the mole ratio of O to (Al+E) and has a value determined by the equation z = (m n + r p + 3 + 4 y)/2. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph further comprising passing the effluent stream to a para-xylene separation unit to generate a para-xylene process stream and a second stream comprising meta-xylene and ortho-xylene. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the separation unit is an adsorption separation unit and generates and extract stream comprising para-xylene and desorbent and a raffinate stream comprising meta-xylene and ortho-xylene. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph further comprising passing the extract stream to a fractionation unit to generate a bottoms stream comprising para-xylene and an overhead stream comprising desorbent. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the first embodiment in this paragraph wherein the raffinate stream is passed to the isomerization reactor.
[0012] A second embodiment of the invention is a process for the production of para- xylene, comprising passing a mixture of hydrocarbons comprising xylenes to an
isomerization reactor, operated at isomerization reaction conditions, to form a reaction mixture over an isomerization catalyst, and to generate an effluent stream comprising para- xylene; wherein the isomerization catalyst is characterized by a catalyst having a 2-D layered MFI structure, to generate a process stream comprising olefins, wherein the catalyst is a zeolite of claim 1 having a microporous crystalline structure comprising a framework of A102 and Si02 tetrahedral units, further including the element E and having the empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of Mm n+R r p+ Ali-xExSiyOz where M is at least one exchangeable cation selected from the group consisting of alkali and alkaline earth metals, "m" is the mole ratio of M to (Al+E) and varies from 0 to 3, R is at least one organoammonium cation selected from the group consisting of quaternary ammonium cations, di quaternary ammonium cations, "r" is the mole ratio of R to (Al+E) and has a value of 0.1 to 30.0 "n" is the weight average valence of M and has a value of 1 to 2, "p" is the weighted average valence of R and has a value of 1 to 2, E is an element selected from the group consisting of gallium, iron, boron, indium and mixtures thereof, "x" is the mole fraction of E and has a value from 0 to 1.0, "y" is the mole ratio of Si to (Al+E) and varies from greater than 32 to 200 and "z" is the mole ratio of O to (Al+E) and has a value determined by the equation z = (m n + r p + 3 + 4 y)/2 and it is characterized in that it has the x-ray diffraction pattern having at least the d spacing and intensities set forth in the following Table A:
Table A
Figure imgf000006_0001
[0013] An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the second embodiment in this paragraph wherein the isomerization reaction conditions include a temperature between 250°C and 350°C. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the second embodiment in this paragraph wherein the isomerization reaction conditions include a pressure sufficient to maintain the reaction mixture in the liquid phase. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the second embodiment in this paragraph wherein the pressure is at least 1025 kPa. An embodiment of the invention is one, any or all of prior embodiments in this paragraph up through the second embodiment in this paragraph wherein the mixture of hydrocarbons further includes ethylbenzene.
[0014] Other objects, advantages and applications of the present invention will become apparent to those skilled in the art from the following detailed description.
DETAILED DESCRIPTION [0015] Para-xylene production is a valuable commercial process, wherein the reduction of losses can entail a significant economic advantage. One method of improving para-xylene yields is to increase the conversion from C8 compounds to para-xylene and to reduce losses during that conversion. The operating of a liquid phase xylene isomerization reactor using a conventional MFI catalyst generates a significant xylene loss per pass. The loss is greater than 1.5%. The invention of a new catalyst allows for a significant reduction in the xylene loss. The new catalyst has a new zeolitic MFI morphology and can achieve comparable para- xylene content with xylene losses of around 0.2% or less.
[0016] The present invention is a process for the production of para-xylene. The process includes passing a mixture of hydrocarbons including xylenes to an isomerization reactor, operated at isomerization reaction conditions to generate an effluent stream having para- xylene, or p-xylene. The reaction conditions include forming a reaction mixture comprising C8 hydrocarbons and passing the mixture over an isomerization catalyst. The present invention utilizes a new catalyst that reduces the loss of xylenes during the isomerization process. The catalyst is a zeolite catalyst made by using a charge density mismatch method. The isomerization catalyst is a zeolite having a microporous crystalline structure comprising a framework of A102 and Si02 tetrahedral units, and an empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of:
Mm n+R r p+ AlSiyOz.
[0017] The catalyst comprises M, which is at least one exchangeable cation selected from the group consisting of alkali and alkaline earth metals, R, which is at least one
organoammonium cation selected from the group consisting of quaternary ammonium cations, diquaternary ammonium cations, E, which is at least one element from gallium, iron, boron and indium. Aluminum and silicon are supplied from alumina and silica. In the formula, "m" is the mole ratio of M to Al and varies from 0 to 3, "r" is the mole ratio of R to Al and has a value of 0.1 to 30.0, "y" is the mole ratio of Si to Al and varies from greater than 32 to 200 and "z" is the mole ratio of O to Al. The value "n" is the weight average valence of M and has a value of 1 to 2, and "p" is the weighted average valence of R and has a value of 1 to 2. The value of "z" is determined by the equation:
z=(m n+rp+3+4 y)/2.
[0018] The catalyst can be further characterized by its unique x-ray diffraction pattern as at least the d spacing and intensities set forth in Table A:
Table A
Figure imgf000008_0001
[0019] The M in the zeolite can be a mixture of alkali metals and alkaline earth metals, with a preferred M including sodium and potassium. The R cation can be selected from one or more of quaternary ammonium cations, quaternary phosphonium cations, and methonium cations. The R cation can come from an halide compound or a hydroxide compound.
Preferred R cations for the zeolite are selected from the reactive materials including one or more of tetrabutyl ammonium hydroxide, tetrabutylphosphonium hydroxide and hexamethonium dihydroxide.
[0020] The isomerization reaction conditions include a temperature between 250°C and 350°C, with a preferred reaction temperature between 280°C and 310°C. The reaction conditions include a pressure sufficient to maintain the reaction mixture in the liquid phase. In one embodiment, the pressure in the reactor is at least 1025 kPa, with a preferred reactor pressure in the range of 1750 kPa to 2400 kPa.
[0021] The feedstream preferably comprises C8 aromatics, having meta-xylene and ortho- xylene. The feedstream can also include ethylbenzene, wherein the isomerization reactor converts the meta-xylene and ortho-xylene to para-xylene, and the ethylbenzene to benzene.
[0022] The effluent stream leaving the isomerization reactor includes para-xylene is passed to a para-xylene separation unit to generate a para-xylene process stream, and a second stream comprising meta-xylene, ortho-xylene and ethylbenzene. The para-xylene separation unit can comprise an adsorption separation unit, wherein the para-xylene process stream is the extract stream and the second stream is the raffinate stream. The extract stream and raffinate streams can include a desorbent. The extract stream is passed to a fractionation unit to generate a bottoms stream comprising para-xylene and an overhead stream comprising desorbent. The process can further include passing the raffinate stream to the isomerization reactor. The raffinate stream can also be passed to a second fractionation column to separate the desorbent from the raffinate stream before passing the raffinate stream to the
isomerization reactor.
[0023] In another embodiment, the catalyst is characterized by a zeolite having a microporous crystalline structure comprising a framework of A102 and Si02 tetrahedral units, further including the element E and having the empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of:
Mm n+R r p+ Al1-xExSiyOz
[0024] where M is at least one exchangeable cation selected from the group consisting of alkali and alkaline earth metals, "m" is the mole ratio of M to (Al+E) and varies from 0 to 3, R is at least one organoammonium cation selected from the group consisting of quaternary ammonium cations, di quaternary ammonium cations, "r" is the mole ratio of R to (Al+E) and has a value of 0.1 to 30.0 "n" is the weight average valence of M and has a value of 1 to 2, "p" is the weighted average valence of R and has a value of 1 to 2, E is an element selected from the group consisting of gallium, iron, boron, indium and mixtures thereof, "x" is the mole fraction of E and has a value from 0 to 1.0, "y" is the mole ratio of Si to (Al+E) and varies from greater than 32 to 200 and "z" is the mole ratio of O to (Al+E) and has a value determined by the equation:
z = (m n + rp + 3 + 4 y)/2.
EXAMPLE 1 (Commercial reference example)
[0025] Commercial pentasil zeolite from TOSOH (lot:HSZ-900-940 HA) was formulated into a catalyst containing 70% zeolite and 30% silica. In the catalyst preparation, the zeolite was mixed with LUDOX AS-40 and Hi-Sil 250 into a muller mixer. Additional water was added to the Muller mixer, while mixing, until dough with a proper texture for extrusion was formed. The dough was extruded to form 1/16" diameter trilobes, which were dried at 100°C overnight and then sized to a length to diameter ratio of 3. The dry extrudates was calcined in a box oven with a flowing air at 560°C for 6 hours to remove the template. This is referred to as catalyst A.
EXAMPLE 2
[0026] An aluminosilicate reaction solution was prepared by first mixing 13.73 g of aluminum tri-sec-butoxide (95+%), 559.89 g tetrabutylphosphonium hydroxide (40 mass-
% solution), and 200 g of ice water mixture while stirring vigorously. After thorough mixing, 574.76 g tetraethyl orthosilicate was added. The reaction mixture was homogenized for an additional hour with a high speed mechanical stirrer. A composite aqueous solution containing 2.70 g of NaOH dissolved in 48.92 g distilled water, was added, drop-wise, to the aluminosilicate solution. After the addition was completed, the resulting reaction mixture was homogenized for 1 hour, transferred to a 2000 ml Parr stainless steel autoclave which was heated to 115°C and maintained at that temperature for 120 hrs. The solid product was recovered by centrifugation, washed with de-ionized water, and dried at 80°C.
[0027] The product was identified as a pentasil zeolite by powder x-ray diffraction.
Representative diffraction lines observed for the product are shown in Table 1. A portion of the material was calcined by ramping to 560°C for 5 hours followed by a 8 hour dwell in air. The BET surface area was 526 m2/g, the micropore area was 220 m2/g, the mesopore area was 306 m2/g, the micropore volume was 0.115 cc/g, and mesopore volume was 0.99 cc/g. Scanning Electron Microscopy (SEM) revealed clusters of nano spheres of less than 20 nm. Chemical analysis was as follows: 1.22% Al, 42.8% Si, and 0.70% Na, Na/Al=0.67,
Si/Al2=49.8.
TABLE 1
Figure imgf000011_0001
EXAMPLE 3 (PENTASIL LAYERED EXTRUDATES)
[0028] The pentasil zeolite of example 3 was formulated into a catalyst containing 70% zeolite and 30% silica. In the catalyst preparation, the zeolite was mixed with LUDOX AS-40 and Hi-Sil 250 into a muller mixer. Additional water was added to the Muller mixer, while mixing, until dough with a proper texture for extrusion was formed. The dough was extruded to form 1/16" diameter trilobes, which were dried at 100°C overnight and then sized to a length to diameter ratio of 3. The dry extrudates was calcined in a box oven with a flowing air at 560°C for 6 hours to remove the template. The calcined support was then exchanged using a 10 wt-% H4NO3 solution at 75°C for one hour. This was followed by water wash using 20 cc of water per cc of extrudates. The H4NO3 exchange and water wash was repeated three more times. The extrudates was then dried at 120°C for 4 hours and then activated at 550°C. This is labeled catalyst B.
EXAMPLE 4
[0029] An aluminosilicate reaction solution was prepared by first mixing 13.87 g of aluminum tri-sec-butoxide (95+%), 386.39 g tetrabutylammonium hydroxide (55 mass-% solution), and 300 g of ice water mixture while stirring vigorously. After thorough mixing, 580.35 g tetraethyl orthosilicate was added. The reaction mixture was homogenized for an additional hour with a high speed mechanical stirrer. A composite aqueous solution containing 2.73 g of NaOH dissolved in 116.67 g distilled water was added, drop-wise, to the aluminosilicate solution. After the addition was completed, the resulting reaction mixture was homogenized for 1 hour, transferred to a 2000 ml Parr stainless steel autoclave which was heated to 115°C and maintained at that temperature for 57 hrs. The solid product was recovered by centrifugation, washed with de-ionized water, and dried at 80°C.
[0030] The product was identified as a pentasil zeolite by powder x-ray diffraction.
Representative diffraction lines observed for the product are shown in Table 2. The product composition was determined by elemental analysis to consist of the following mole ratios: Si/Al = 24.9, Na/Al = 0.92. A portion of the material was calcined by ramping to 560°C for 5 hours followed by a 8 hour dwell in air. The BET surface area was 517 m2/g, the micropore area was 258 m2/g, the mesopore area was 259 m2/g, the micropore volume was 0.135 cc/g, and mesopore volume was 0.94 cc/g. Scanning Electron Microscopy (SEM) revealed clusters of nano spheres of less than 20 nm. Chemical analysis was as follows: 1.73% Al, 44.9% Si, and 1.37% Na, Na/Al=0.93, Si/Al2=49.8.
TABLE 2
Figure imgf000012_0001
EXAMPLE 5
[0031] The pentasil zeolite of example 3 was formulated into a catalyst containing 70% zeolite and 30% silica. In the catalyst preparation, the zeolite was mixed with LUDOX AS-40 and Hi-Sil 250 into a Muller mixer. Additional water was added to the Muller mixer, while mixing, until dough with a proper texture for extrusion was formed. The dough was extruded to form 1/16" diameter trilobes, which were dried at 100°C overnight and then sized to a length to diameter ratio of 3. The dry extrudates was calcined in a box oven with a flowing air at 560°C for 6 hours to remove the template. The calcined support was then exchanged using a 10 wt-% H4NO3 solution at 75°C for one hour. This was followed by water wash using 20 cc of water per cc of extrudates. The H4NO3 exchange and water wash was repeated three more times. The extrudates was then dried at 120°C for 4 hours and then activated at 550°C.
EXAMPLE 6
[0032] Catalyst A was evaluated for xylene isomerization and ethyl-benzene retention using a pilot plant flow reactor processing a non-equilibrium C8 aromatic feed having the following composition in wt-%:
Figure imgf000013_0001
[0033] Pilot-plant test conditions and results are as follows. The above feed contacted the Catalyst at a pressure of 3.5 MPa in the liquid phase at a weight hourly space velocity of 10 under a range of temperatures. The resulting performance measures are shown below:
Figure imgf000013_0002
[0034] Note that the "Xylene Loss" is in mol-% defined as "(l-( para, meta, ortho xylene in product)/( -( para, meta, ortho xylene in feed))* 100", which represents material that has to be circulated to another unit in an aromatics complex. Such circulation is expensive and a low amount of C8 ring loss is preferred. Al 1+ represents material that is heavier than 145 molecular weight. This material represents unrecoverable losses. Ethylbenzene conversion, 2 to 4.5% was low in all cases.
[0035] While the invention has been described with what are presently considered the preferred embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but it is intended to cover various modifications and equivalent arrangements included within the scope of the appended claims.

Claims

1. A process for the production of para-xylene, comprising:
passing a mixture of hydrocarbons comprising xylenes to an isomerization reactor, operated at isomerization reaction conditions, to form a reaction mixture over an
isomerization catalyst, and to generate an effluent stream comprising p-xylene;
wherein the isomerization catalyst is characterized by a zeolite having a microporous crystalline structure comprising a framework of A102 and Si02 tetrahedral units, and an empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of:
Mm n+R r p+ AlSiyOz where M is at least one exchangeable cation selected from the group consisting of alkali and alkaline earth metals, "m" is the mole ratio of M to Al and varies from 0 to 3, R is at least one organoammonium cation selected from the group consisting of quaternary ammonium cations, di quaternary ammonium cations, "r" is the mole ratio of R to Al and has a value of 0.1 to 30.0 "n" is the weight average valence of M and has a value of 1 to 2, "p" is the weighted average valence of R and has a value of 1 to 2, "y" is the mole ratio of Si to Al and varies from greater than 32 to 200 and "z" is the mole ratio of O to Al and has a value determined by the equation: z=(m n+rp+3+4 y)/2 and it is characterized in that it has the x-ray diffraction pattern having at least the d spacing and intensities set forth in the following Table A:
Table A
Figure imgf000014_0001
2. The process of claim 1 wherein the isomerization reaction conditions include a temperature between 250°C and 350°C.
3. The process of claim 2 wherein the isomerization reaction conditions include a temperature between 280°C and 310°C.
4. The process of claim 1 wherein the pressure is at least 1025 kPa.
5. The process of claim 1 wherein the mixture of hydrocarbons further includes ethylbenzene.
6. The process of claim 1 where M in the zeolite is selected from the group consisting of sodium, potassium and mixtures thereof.
7. The process of claim 1 where M in the zeolite is a mixture of an alkali metal and an alkaline earth metal.
8. The process of claim 1 where R in the zeolite is selected from the group consisting of tetrabutyl ammonium hydroxide, tetrabutylphosphonium hydroxide, hexamethonium dihydroxide and mixture thereof.
9. The process of claim 1 where R is a halide or hydroxide compound of an
organoammonium cation.
10. The process of claim 1 further comprising:
passing the effluent stream to a para-xylene separation unit to generate a para-xylene process stream and a second stream comprising meta-xylene and ortho-xylene.
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