WO2016030678A1

WO2016030678A1 - Methods of making a laminated glazing and apparatus therefor

Info

Publication number: WO2016030678A1
Application number: PCT/GB2015/052460
Authority: WO
Inventors: Peter Paulus; Joachim Pilz
Original assignee: Pilkington Group Limited
Priority date: 2014-08-27
Filing date: 2015-08-26
Publication date: 2016-03-03
Also published as: CN106794688B; EP3186204A1; US20170291842A1; KR20170045242A; CN106794688A; GB201415163D0; JP6670826B2; BR112017003607A2; BR112017003607B1; US20220177346A1; KR102675221B1; JP2017533159A

Abstract

Methods of making a laminated glazing having reduced optical distortion when installed in a vehicle are described. The laminated glazing has first and second sheets of glazing material each separately shaped between a pair of shaping members that are then laminated together. The position for bending the first sheet of glazing material may be deliberately offset from the position for bending the second sheet of glazing material. During the lamination step, the first sheet of glazing material may be displaced relative to the second sheet of glazing material by a lateral and/or longitudinal positional displacement. The first and/or second sheet of glazing material may have been cut such that after lamination at least a portion of the peripheral edges thereof are aligned. Apparatus for shaping a sheet of glazing material for carrying out the aforementioned methods is also described, as is a resulting laminated glazing.

Description

METHODS OF MAKING A LAMINATED GLAZING AND APPARATUS THEREFOR

The present invention relates to a method of making a laminated glazing, an apparatus for shaping sheets of glazing material for use in making a laminated glazing, and to a laminated glazing.

It is known that a laminated glazing for a vehicle windscreen usually comprises two bent sheets of glass joined by at least one adhesive layer, usually polyvinyl butyral (PVB). It is conventional in the art to refer to each glass sheet as a "ply". Often the adhesive layer is referred to as a "ply" i.e. a ply of PVB. The glass sheet configured to face the interior of the vehicle in which the laminated glazing is installed is often known as the "inner ply" and the glass sheet configured to face the exterior of the vehicle in which the laminated glazing is installed is often known as the "outer ply"

Each of the sheets of glass used in a laminated glazing for a vehicle is usually bent in one or two mutually perpendicular directions such that the laminated glazing is curved and many methods are known for bending initially flat glass sheets to a desired curvature.

One known method is to bend a pair of glass sheets at the same time, one sheet of glass on top of another and separated with a suitable "parting powder" such as calcium carbonate. The inner ply and outer ply are bent at the same time by gravity sag bending.

Another method is to bend the inner ply and the outer ply at different times, usually one after the other, thereby forming the inner ply and the outer ply individually.

One such method of bending the flat glass sheets individually involves conveying heated flat glass sheets between a pair of complementary shaping members and press bending each glass sheet separately. The glass sheets can then be cooled, brought together and laminated using a suitable adhesive interlay er such as PVB. Such methods are described in EP0398759A2 and WO2004/085324A1.

US4,260,408 relates to the shaping of glass sheets to be laminated and describes a cycle of operation where a pair of glass is initially sag bent by gravity followed by a press bending step.

It is conventional in the field of press bending heat softened glass sheets to locate each glass sheet in the bending position transporting the glass sheets on conveyor rolls that cause the leading edge of the glass sheet to be carried against positive stops which hold the glass sheet in position between the complementary bending members. The glass sheet is then usually lifted from the conveyor rolls and pressed between the mould members to form the desired curvature.

As is known from US 4,753,669, press bending shaping members are often covered with a covering of a knitted fibre or knitted wire mesh. In US 4,753,669 it is noted that certain woven wire screens are used in combination with fibre glass covers to increase the useful life thereof. However such wire screens may wrinkle when stretched across or pressed against compound and/or complex surfaces. The wrinkles cause irregularities in the pressing surface that may be transferred to the pressed glass sheets, causing optical distortion.

US 4,753,669 addresses this problem by providing a knitted wire mesh superimposed over an insulating material layer. The knitted wire mesh is said to provide a smooth pressing surface.

A press bending station is described in WO2005/033026A1 that includes an annular mould and a full-face mould. Holes, selectively connected to a negative pressure source, are placed in portions of the full face mould that are determined by the configuration of the annular mould when the annular mould comes into contact with a heated glass sheet during the press bending process. The heated glass sheet is drawn by negative pressure through the holes towards the full-face mould and thus acquires its shape. The full-face mould may be covered by at least one fine mesh cloth i.e. woven stainless steel.

However as optical quality requirements have become more stringent, stainless steel woven cloth covers of the type described in US 4,753,669 have still been found to produce slight deformations in the glass surface that results in an increased optical distortion in transmission i.e. when looking through the glass, in particular when the glass is inclined at an angle to the direction of vision, as is typical when the laminated glazing is installed in a vehicle as a front windscreen.

The contact of the shaping member with the glass surface slightly deforms the glass surface to produce an imprint on the major surface of the press-bent glass sheet that has been in contact with the shaping member. To the naked eye, the imprint is not visible.

It is known from "Glass Processing Days, 2003, pages 502-504 that the angle of installation of a vehicle windscreen has an effect on the optical properties. For example, the amplification of optical power varies with installation angle. Therefore as the angle of installation increases a much better optical quality is required because any faults present in the windscreen are amplified to a higher degree. One option is to improve the optical quality of the glass used to make the laminated windscreen, but it is not always possible to produce glass of improved optical quality at an acceptable commercial yield.

There is therefore a need for a method of making a laminated glazing that has reduced optical distortion when installed in a vehicle and to an apparatus for carrying out the method.

Accordingly from a first aspect the present invention provides a method of making a laminated glazing comprising the steps:

(i) transporting a first sheet of glazing material in a first direction between a pair of shaping members;

(ii) positioning the first sheet of glazing material with positioning means such that the first sheet of glazing material is at a first position for bending between the pair of shaping members;

(iii) shaping the first sheet of glazing material between the pair of shaping members; (iv) transporting the first sheet of glazing material away from between the pair of shaping members;

(v) transporting a second sheet of glazing material between the pair of shaping members;

(vi) positioning the second sheet of glazing material with positioning means such that the second sheet of glazing material is at a second position for bending between the pair of shaping members;

(vii) shaping the second sheet of glazing material between the pair of shaping members,

(viii) transporting the second sheet of glazing material away from between the pair of shaping members; and

(ix) using suitable lamination conditions to laminate the shaped first sheet of glazing material to the shaped second sheet of glazing material via at least one adhesive sheet,

wherein the first position for bending is deliberately offset from the second position for bending.

The first position for bending and the second position for bending are selected such that the first and second sheets of glazing material, when shaped in steps (iii) and (vii) respectively are able to be suitably paired to make the laminated glazing in step (ix).

A method in accordance with the present invention allows a laminated glazing to be made that has higher optical quality in transmission when measured at an angle through the laminated glazing, for example when installed in a vehicle, compared to when the optical quality is measured at normal incidence through the laminated glazing.

Suitably the positioning means has a longitudinal tolerance in a direction parallel to the first direction such that a reference point on a reference sheet of glazing material is positionable at a target location in a direction parallel to the first direction to within the longitudinal tolerance. For the avoidance of doubt by "longitudinal" it is meant that direction parallel to the direction of travel of the first sheet of glazing material. That is, the longitudinal direction is parallel to the first direction.

The longitudinal tolerance of the positioning means is the statistical variation of the location of the reference point on the reference sheet of glazing material of the for a target longitudinal location X.

If the longitudinal tolerance is δχ, then a reference point on a reference sheet of glazing material is positionable at the target longitudinal location Xto within + δχ. Typically the longitudinal tolerance is symmetrical, but it may be unsymmetrical. When the

longitudinal tolerance is symmetrical, the magnitude of the longitudinal tolerance is 2δχ.

If the longitudinal tolerance is not symmetrical then the reference point on the reference sheet of glazing material is positionable at the target longitudinal location Xto within X+ δ / and X- 6x₂ where δχ/ is the longitudinal tolerance on one side of the location X and δ ₂ is the longitudinal tolerance on the other side of the location X. When the longitudinal tolerance is not symmetrical, the magnitude of the longitudinal tolerance is |δχ/|+ |δχ₂|.

In general terms the longitudinal tolerance may be specified as a function f(x) such that a reference point on a reference sheet of glazing material is positionable at a target longitudinal location X to within ±f(x).

As an example if the longitudinal tolerance of the positioning means is 1mm and symmetrical and the target location in the longitudinal direction is 30000mm from a fixed datum, the positioning means is able to position a reference point on a reference sheet of glazing material at a position of between 29999mm and 30001mm from the fixed datum. That is, 30000+ lmm from the fixed datum. In this example the magnitude of the longitudinal tolerance is 2mm.

Suitably the positioning means has a lateral tolerance in a direction perpendicular to the first direction such that a reference point on a reference sheet of glazing material is positionable at a target location in a direction parallel to the first direction to within the lateral tolerance. For the avoidance of doubt, by "lateral" it is meant that direction perpendicular to the direction of travel of the first sheet of glazing material. That is, the lateral direction is perpendicular to the first direction.

The lateral tolerance of the positioning means is the statistical variation of the location of the reference point on the reference sheet of glazing material for a target lateral location Y.

If the lateral tolerance is 5y, then a reference point on a reference sheet of glazing material is positionable at the target longitudinal location Y to within + 5y. Typically the lateral tolerance is symmetrical, but it may be unsymmetrical. When the longitudinal tolerance is symmetrical, the magnitude of the lateral tolerance is 25y.

If the lateral tolerance is not symmetrical then the reference point on the reference sheet of glazing material is positionable at the target lateral location Y to within Y+ 6yi and Y- by ₂ where 5y/ is the lateral tolerance on one side of the location Y and by ₂ is the lateral tolerance on the other side of the location Y.

In general terms the lateral tolerance may be specified as a function f(y) such that a reference point on a reference sheet of glazing material is positionable at a target lateral location Y to within ±f(y).

As an example if the lateral tolerance of the positioning means is 2mm and

symmetrical and the target location in the lateral direction is 20000mm from a fixed datum, the positioning means is able to position a reference point on a reference sheet of glazing material at a position of between 19998mm and 20002mm from the fixed datum. That is, 20000+2mm from the fixed datum. In this example the magnitude of the longitudinal tolerance is 4mm.

Typically the lateral tolerance is less than 2.0mm i.e. between 0.001mm and

1.999mm, preferably less than 1.5mm, more preferably less than 1.0mm, even more preferably less than 0.5mm, even more preferably between 0.001mm and 0.5mm, most preferably between 0.01mm and 0.2mm.

Typically the longitudinal tolerance is less than 2.0mm i.e. between 0.001mm and 1.999mm, preferably less than 1.5mm, more preferably less than 1.0mm, even more preferably less than 0.5mm, even more preferably between 0.001mm and 0.5mm, most preferably between 0.01mm and 0.2mm.

In prior art methods used to individually shape first and second sheets of glass between a pair of shaping members, the aim is to position each sheet of glass at the same position to within the lateral tolerance and the longitudinal tolerance of the positioning means such that the first and second sheets of glass are a congruent pair.

In such prior art methods the target position for bending each sheet of glazing material is that position between the shaping members such that when the sheet of glazing material is shaped between the shaping members, the shape imparted to the sheet of glazing material is the desired shape. Typically the desired shape is defined in terms of a CAD model and there may be slight deviations in the shape that is actually produced after bending between the pair of shaping members and the CAD model. Such deviations are usually specified by the customer and the manufacturing process is typically configured to deliver a product to an agreed specification.

The two glass plies which, together with a ply of adhesive interlayer material, make up a standard automotive laminated window, are for convenience referred to as the inner and outer ply respectively, according to which of the plies forms the inner and outer surfaces of the window when installed in its intended position in a vehicle. Each ply has two major faces, and after lamination, the ply of interlayer material adheres to opposed major faces of the glass plies.

For a laminated window of shallow curvature of large radius, it is acceptable for both plies to be the same size (referring to the size of the flat glass sheet as cut, which is then fed onto the bending line) and bent to the same curvature. Such plies need not be distinguished during bending, or, at any rate, the inner and outer plies can be bent on the same bending equipment on the same bending line if desired. However, other windscreen designs frequently require the glass to possess deep or sharp (small radius) or complex curvature, or indeed most or all of these characteristics. To achieve reliable lamination without excessive breakage, it is important for the glass plies to nest together well, that is to say, the glass plies should fit together well when assembled, i.e. when superimposed in the correct order with a ply of interlayer material in between the glass plies. The plies will only nest accurately if the curvatures of their proximate opposed major faces match, after due allowance for the thickness of the interlayer. To put it another way, if one considers corresponding small portions of each of the glass plies (portions which are small enough for their curvature to be considered to be circular), the curvature of such portions needs to be concentric when they are adjacent each other in the assembled condition if they are to nest accurately. From a consideration of the geometry involved, it will be appreciated that one glass ply (for a windscreen, the inner ply) needs to be of slightly smaller size and bent to slightly smaller radii of curvature so that the plies nest accurately. The term "congruent pair", as herein employed, includes a pair comprising inner and outer plies of slightly different sizes as just described.

Whilst the nesting is important, bent glass sheets with a large radius of curvature are less sensitive to the change in curvature so the inner and outer glass plies can often be shaped with the same degree of curvature and successfully laminated, providing there are no rapid changes of curvature

When the first and second sheets of glazing material have the same, or substantially the same, outline shape, the target position for bending is the same for each of sheet and is typically the geometric centre of the major surface or the centre of mass of the sheet. When one of the first and second sheets of glazing material is of a slightly different size, as described above, the first and second sheets of glazing material have a similar shape so typically the target position for bending each sheet is usually such that the geometric centre (or centre of mass) of each sheet is positioned at the same place in relation to the shaping members. Given that positioning means typically act upon an edge of a sheet of glazing material, in order to align the geometric centres of the first and second sheets of glazing material at the same positions in relation to the shaping members, the positioning means compensates for the size difference between the first and second sheets of glazing material. For example, if the inner ply is shorter in the direction of conveyance then the positioning means are moved upstream to compensate. That is, if the downstream edge of the inner ply is displaced relative to the downstream edge of the outer ply by k mm, the positioning means may be moved k mm upstream such that the central bending point of the first and second plies remains at the same position relative to the shaping members.

The present invention aims to deliberately offset the bending position of the first sheet of glazing material with respect to the bending position of the second sheet of glazing material.

This allows a consistently high optical quality laminated glazing to be produced during a production run. The degree of displacement of the first position for bending and the second position for bending should not be too excessive so that high lamination stresses are avoided. If lamination stresses become too high, it is difficult, and in extreme cases not possible, to make the laminated glazing.

Suitably the first position is offset from the second position by a lateral displacement being greater than the lateral tolerance and/or a longitudinal displacement being greater than the longitudinal tolerance.

Suitably when the first sheet of glazing material is at the first position the positioning means are in a first configuration and when the second sheet of glazing material is at the second position the positioning means are in a second configuration. Suitably when the positioning means are in the first configuration, a reference point on a reference sheet of glazing material positioned by the positioning means between the pair of shaping members is at a first location.

Suitably when the positioning means are in the second configuration, the reference point on the reference sheet of glazing material positioned by the positioning means between the pair of shaping members is at a second location.

Suitably the first location is displaced relative to the second location by a lateral positional displacement being greater than the lateral tolerance and/or a longitudinal positional displacement being greater than the longitudinal tolerance.

Usually the lateral positional displacement is the same as the lateral displacement.

Usually the longitudinal positional displacement is the same as the longitudinal displacement.

For the avoidance of doubt in a preferred embodiment of the first aspect of the present invention there is provided a method of making a laminated glazing comprising the steps: (i) transporting a first sheet of glazing material in a first direction between a pair of shaping members;

(ii) positioning the first sheet of glazing material with positioning means such that the first sheet of glazing material is at a first position for bending between the pair of shaping members, the positioning means having a lateral tolerance in a direction perpendicular to the first direction and a longitudinal tolerance in a direction parallel to the first direction such that the positioning means is able to position a reference point on a reference sheet of glazing material between the pair of shaping members at a target location to within the lateral tolerance and to within the longitudinal tolerance;

(iii) shaping the first sheet of glazing material between the pair of shaping members;

(iv) transporting the first sheet of glazing material away from between the pair of shaping members;

(vi) positioning the second sheet of glazing material with positioning means such that the second sheet of glazing material is in a second position for bending between the pair of shaping members,

(ix) using suitable lamination conditions to laminate the first sheet of glazing material to the second sheet of glazing material via at least one adhesive sheet, wherein the first position and the second position are selected such that the first sheet and second sheet, when shaped, are able to be paired to make the laminated glazing,

further wherein when the first sheet of glazing material is at the first position the positioning means are in a first configuration and when the second sheet of glazing material is at the second position the positioning means are in a second configuration, characterised in that when the positioning means are in the first configuration and the reference sheet of glazing material is positioned by the positioning means between the pair of shaping members, the reference point on the reference sheet of glazing material is at a first location, and when the positioning means are in the second configuration and the reference sheet of glazing material is positioned by the positioning means between the pair of shaping members, the reference point on the reference sheet of glazing material is at a second location, wherein the first location is displaced relative to the second location by a lateral positional displacement being greater than the lateral tolerance and/or a longitudinal displacement being greater than the longitudinal tolerance. The reference point on the reference sheet of glazing material may be anywhere on a major surface thereof. Suitably the reference point on the sheet of glazing material is at the geometric centre of the major surface or the centre of mass of the reference sheet of glazing material.

As is conventional in the art, a bent vehicle windscreen typically has the peripheral edges of the inner and outer plies aligned. As discussed above, this is achieved by cutting the inner ply slightly smaller than the outer ply. For curvature about one axis only, the inner glass ply is cut to be slightly shorter in the direction perpendicular to the axis of bending. For bending in two directions, the inner glass ply is cut to be smaller in both directions.

It is to be understood that during assembly, i.e. the process where the first and second sheets of glazing material are combined with a sheet of adhesive such as PVB (i.e. at step (viii)), conventionally the two glasses are adjusted centrally so there is no misalignment between the sheets of glazing material.

It will be readily apparent that by using positioning means having worse positional accuracy, such that the magnitude of the lateral and/or longitudinal tolerance is increased (for example a larger δχ and/or 5y), the likelihood of making a laminated glazing having an improved optical distortion in transmission increases. However the randomness associated with this approach means it is not possible to deliver consistent quality over a production run.

It will also be readily apparent that as the installation angle changes, the amount of offset required also changes. By using the optical path of horizontal light rays passing through a curved laminated glazing inclined at an angle to the vertical, it is possible to derive the following equation for the deviation of the horizontal light ray as it passes through the curved laminated glazing: d x tan x sin 6_h (1)

Where d is the overall thickness of the laminated glazing in millimetres, n is the refractive index of the glazing material at 540nm, and θπ_,ν is the intended installation angle of the laminated glazing (relative to a horizontal orientation or a vertical orientation θ_ν).

It is possible using equation (1) to calculate the amount of offset required.

In accordance with the present invention the first position for shaping the first sheet of glazing material is deliberately offset relative to the second position for bending the second sheet of glazing material.

Preferably longitudinal displacement and/or the lateral displacement and/or the longitudinal positional displacement and/or the lateral positional displacement is less than or equal to

where d is the overall thickness of the laminated glazing in millimetres, n is the refractive index of the glazing material at 540nm, and θπ_,ν is the intended installation angle of the laminated glazing relative to a horizontal orientation or a vertical orientation (θ_ν) and m is less than or equal to 5, more preferably less than or equal to 4, even more preferably less than or equal to 3, most preferably less than or equal to 2.

where d is the overall thickness of the laminated glazing in millimetres, n is the refractive index of the glazing material at 540nm, and θπ_,ν is the intended installation angle of the laminated glazing relative to a horizontal orientation or a vertical orientation (θ_ν).

For example, for a vehicle windscreen consisting of two plies of soda-lime-silica glass having a thickness of 2.1mm joined by a 0.76mm thick ply of polyvinyl butyral the thickness of the resulting laminated glass is 4.96mm. Therefore in the equation above, d = 4.96mm, n = 1.52 and for an installation angle of 60° from the vertical (θ_ν = 60°), the positional displacement is 3.4387mm.

Preferably the lateral positional displacement and/or longitudinal positional displacement and/or lateral displacement and/or longitudinal displacement is between

³/₂ x d x tan ( sin^-1 (- x sin 6_{h v} ) and V₂ ^χ d x tan ( sin^-1 (- x sin 6_{h v} )\

The formula in equation (1) applies when the laminated glazing has a plurality of sheets of glazing material of similar refractive index and a plurality of sheets of adhesive interlayer having a similar refractive index to the refractive index of the sheets of glazing material.

For example, the above formula applies for a laminated glazing having two sheets of soda-lime-silica glass joined by an interlayer structure consisting of two or three sheets of polyvinyl butyral. The above formula applies equally for a laminated glazing having three sheets of soda-lime-silica glass joined by two sheets of polyvinyl butyral.

If the refractive index of the sheets of interlayer material and/or sheets of glazing material vary significantly from that of a soda-lime-silica glass then the above formula is modified accordingly.

Preferably d is between 2mm and 10mm.

Preferably n is between 1.5 and 1.8, more preferably 1.52.

Preferably θ_ν is between 20° and 80°, more preferably between 50° and 70°.

Preferably is between -45° and +45°, more preferably 0°.

Preferably the lateral positional displacement and/or the longitudinal positional displacement vary between a lower limit and an upper limit. The lower limit for the lateral positional displacement and/or the longitudinal positional displacement is 0.5mm, or 1.0mm or 1.5mm or 2.0mm. The upper limit for the lateral positional displacement and/or the longitudinal positional displacement is 1.0mm, or 1.5mm, or 2.0mm, or 2.5mm, or 3.0mm, or 3.5mm, or 4.0mm, or 4.5mm, or 5.0mm, or 5.5mm, or 6.0mm, or 6.5mm, or 7.0mm, or 7.5mm, or 8.0mm. For example, the lateral positional displacement and/or the longitudinal positional displacement is between 0.5mm and 8.0mm, more preferably between 1.5mm and 7.0 mm, even more preferably between 1.5mm and 6.0mm, most preferably 1.5 and 4.0mm. Other combination of lower and upper limit is possible.

Preferably the lateral displacement and/or the longitudinal displacement vary between a lower limit and an upper limit. The lower limit for the lateral displacement and/or the longitudinal displacement is 0.5mm, or 1.0mm or 1.5mm or 2.0mm. The upper limit for the lateral displacement and/or the longitudinal displacement is 1.0mm, or 1.5mm, or 2.0mm, or 2.5mm, or 3.0mm, or 3.5mm, or 4.0mm, or 4.5mm, or 5.0mm, or 5.5mm, or 6.0mm, or 6.5mm, or 7.0mm, or 7.5mm, or 8.0mm. For example, the lateral displacement and/or the longitudinal displacement is between 0.5mm and 8.0mm, more preferably between 1.5mm and 7.0 mm, even more preferably between 1.5mm and 6.0mm, most preferably 1.5 and 4.0mm. Other combination of lower and upper limit is possible.

An alternative method for improving the optical quality is to bend the first and second sheets of glazing material such that the first and second positions for bending are the same to within the lateral tolerance and the longitudinal tolerance of the positioning means. The first and second sheets of glazing material are then offset relative to each prior to the first and second sheets of glazing material being laminated together. The amount of offset during the lamination step is such that the first and second sheets of glazing material are still able to be joined by the at least one adhesive sheet to make the laminated glazing.

Accordingly the present invention provides from a second aspect a method of manufacturing a laminated glazing comprising the steps:

(i) transporting a first sheet of glazing material between a pair of shaping members;

(iv) transporting the first sheet of glazing material away from between the first pair of shaping members;

(vii) shaping the second sheet of glazing material between the pair of shaping members;

(viii) transporting the second sheet of glazing material away from between the first pair of shaping members; and

(ix) using suitable lamination conditions to laminate the first sheet of glazing material to the second sheet of glazing material via at least one adhesive sheet,

characterised in that the when the first sheet of glazing material is positioned relative to the second sheet of glazing material during the lamination step, the first sheet of glazing material is displaced relative to the second sheet of glazing material by a lateral positional

displacement and/or a longitudinal positional displacement. The first position and the second position are selected such that the first sheet and second sheet, when shaped, are a congruent pair.

Suitably the positioning means has a longitudinal tolerance in a direction parallel to the first direction such that a reference point on a reference sheet of glazing material is positionable at a target location in a direction parallel to the first direction to within the longitudinal tolerance.

Suitably the positioning means has a lateral tolerance in a direction perpendicular to the first direction such that a reference point on a reference sheet of glazing material is positionable at a target location in a direction parallel to the first direction to within the lateral tolerance. Preferably the first position and the second position are the same to within the lateral tolerance.

Preferably the first position and the second position are the same to within the longitudinal tolerance.

To define the first position of the first sheet of glazing material it is helpful to consider a reference point on the sheet of glazing material. The pair of shaping members are configured such that when the reference point on the sheet of glazing material are aligned with a fixed reference point on the shaping members, the desired curvature may be imparted to the sheet of glazing material. Each of the inner and outer plies are shaped in this way, with the appropriate reference point on the glazing being aligned with the reference points on the shaping members to achieve the desired degree of shaping. Due to the tolerance in the positioning means, it is possible to position the reference point on the sheet of glazing material to within the lateral and/or longitudinal tolerance of the positioning means.

Assuming the inner ply is cut in the conventional manner it is possible to offset the inner ply relative to the outer ply such that the optical distortion at an installation angle is reduced.

The disadvantage with this approach is that if the plies are cut in a conventional manner, at least one of the peripheral edges of the laminated glazing will not be aligned. This could be reduced by cutting the inner ply to a suitable external configuration such that the edges do align.

However given that by offsetting the plies the inner and outer plies no longer nest as precisely together, lamination stresses may be increased. In some embodiments the conditions for lamination are varied such that lamination stresses are reduced. For example the time and /or temperature of steps during the lamination process may be varied to improve flow of the adhesive sheet. The autoclave process may be varied (temperature and/or time to improve the adhesive sheet flow thereby reducing lamination stresses)

The misaligned edges may be hidden from view by appropriate encapsulation to cover the edges of the laminate. Such encapsulation is known in the art, for example use of polyurethane gaskets.

From a third aspect the present invention provides a method of manufacturing a laminated glazing comprising the steps:

(ii) positioning the first sheet of glazing material with positioning means such that the first sheet of glazing material is at a first position for bending between the pair of shaping members,

(vi) positioning the second sheet of glazing material with positioning means such that the second sheet of glazing material is at a second position between the pair of shaping members;

(ix) laminating the first sheet of glazing material to the second sheet of glazing material via at least one adhesive sheet,

characterised in that the when the first sheet of glazing material is positioned relative to the second sheet of glazing material during the lamination step, the first sheet of glazing material is displaced relative to the second sheet of glazing material and wherein the first sheet of glazing material and/or the second sheet of glazing material have been cut such that after lamination at least a portion of the peripheral edges of the first and/or second sheets of glazing material are aligned.

Suitably the positioning means has a lateral tolerance and a longitudinal tolerance such that the positioning means is able to position a reference point on a reference sheet of glazing material between the pair of shaping members to within the lateral tolerance and the longitudinal tolerance

Preferably the first and/or second sheet of glazing material has been cut prior to being shaped, such that if the first and second sheets of glazing material were shaped in a conventional manner they would not form a congruent pair.

Preferably the first and/or second sheet of glazing material has been cut after being shaped.

From a fourth aspect the present invention provides apparatus for shaping a sheet of glazing material, in particular a glass sheet, the apparatus comprising:

(i) a pair of shaping members,

(ii) means for transporting the sheet of glazing material between the pair of shaping members and

(iii) positioning means for positioning the sheet of glazing material at a position for bending between the pair of shaping members, wherein the positioning means has a lateral tolerance and a longitudinal tolerance; and

(iv) control means for controlling the configuration of the positioning means, wherein the control means is able to place the positioning means in a first configuration, such that with the positioning means in the first configuration, a reference sheet of glazing material is positionable between the pair of shaping members and a reference point on the reference sheet of glazing material is at a first lateral position and/or a first longitudinal position, and wherein the control means is able to place the positioning means in a second

configuration, such that with the positioning means in the second configuration, the reference sheet of glazing material is positionable between the pair of shaping members and the reference point on the reference sheet of glazing material is at a second lateral position and/or a second longitudinal position, the first lateral position being displaced relative to the second lateral position by more than the lateral tolerance and/or the first longitudinal position being displaced relative to the second longitudinal position by more than the longitudinal tolerance.

By using an apparatus according to the fourth aspect of the present invention a first sheet of glazing material shaped between the pair of shaping members with the positioning means in the first configuration, and a second sheet of glazing material shaped between the pair of shaping members with the positioning means in the second configuration are able to be laminated together with an adhesive ply to produce a laminated glazing, in particular an automotive windscreen, having an improved optical quality in transmission when measured at an angle relative to a normal to the surface of the laminated glazing, compared to the optical quality of an equivalent laminated glazing measured at the same angle of incidence and made with the first sheet of glazing material shaped between the pair of shaping members with the positioning means in the first configuration and the second sheet of glazing material shaped between the pair of shaping members with the positioning means in the first configuration.

By using an apparatus according to the fourth aspect of the invention a first sheet of glazing material shaped between the pair of shaping members with the positioning means in the first configuration, and a second sheet of glazing material shaped between the pair of shaping members with the positioning means in the second configuration are able to be laminated together with an adhesive ply to produce a laminated glazing, in particular an automotive windscreen, having an improved optical quality in transmission when measured at an angle relative to a normal to the surface of the laminated glazing, compared to the optical quality of an equivalent laminated glazing measured at the same angle of incidence and made with the first sheet of glazing material shaped between the pair of shaping members with the positioning means in the second configuration and the second sheet of glazing material shaped between the pair of shaping members with the positioning means in the second configuration. Preferably the first lateral position is displaced relative to the second lateral position by an amount varying between a lower limit and an upper limit. The lower limit is 0.5mm, or 1.0mm or 1.5mm or 2.0mm. The upper limit is 1.0mm, or 1.5mm, or 2.0mm, or 2.5mm, or 3.0mm, or 3.5mm, or 4.0mm, or 4.5mm, or 5.0mm, or 5.5mm, or 6.0mm, or 6.5mm, or 7.0mm, or 7.5mm, or 8.0mm. For example, the first lateral position is displaced relative to the second lateral position by between 0.5mm and 8.0mm, more preferably between 1.5mm and 7.0 mm, even more preferably between 1.5mm and 6.0mm, most preferably 1.5 and 4.0mm. Other combination of lower and upper limit is possible.

Preferably the first longitudinal position is displaced relative to the second

longitudinal position by an amount varying between a lower limit and an upper limit. The lower limit is 0.5mm, or 1.0mm or 1.5mm or 2.0mm. The upper limit is 1.0mm, or 1.5mm, or 2.0mm, or 2.5mm, or 3.0mm, or 3.5mm, or 4.0mm, or 4.5mm, or 5.0mm, or 5.5mm, or 6.0mm, or 6.5mm, or 7.0mm, or 7.5mm, or 8.0mm. For example, the first lateral position is displaced relative to the second lateral position by between 0.5mm and 8.0mm, more preferably between 1.5mm and 7.0 mm, even more preferably between 1.5mm and 6.0mm, most preferably 1.5 and 4.0mm. Other combination of lower and upper limit is possible.

In any or all of the first, second, third and fourth aspects of the present invention the pair of shaping members is usually a complementary pair of shaping members comprising a first shaping member and a second shaping member. Usually the first and second shaping members are vertically disposed relative to each other and each is configured for vertical movement relative thereto, but the first and second shaping members may be horizontally disposed relative to one another and configured for horizontal movement relative thereto. When the first and second shaping members are vertically disposed relative to each other i.e. the first shaping member is above the second shaping member, the first shaping member is usually referred to as an upper shaping member or a male shaping member and the second shaping member is usually referred to as a lower shaping member or a female shaping member.

Suitably the first shaping member has at least one concave portion and the second shaping member has a corresponding complementary convex portion.

The first shaping member may have at least one convex portion, in which case the second shaping member has a corresponding complementary concave portion.

The first shaping member may be a full surface contact shaping member.

The second shaping member may be a full surface contact shaping member.

As is known in the art a full surface contact shaping member is configured such that the shaping member has a surface that is able to contact a major portion of, if not all of, the major surface of the sheet of glazing material that comes into contact with the shaping member.

The first shaping member may be a ring mould, configured to contact the sheet of glazing material being shaped slightly inboard of the peripheral edge of the sheet of glazing material.

The second shaping member may be a ring mould, configured to contact the sheet of glazing material being shaped slightly inboard of the peripheral edge of the sheet of glazing material. When the first shaping member is a ring mould, preferably the second shaping member is a full surface contact mould.

When the second shaping member is a ring mould, preferably the first shaping member is a full surface contact mould.

From a fifth aspect the present invention provides a laminated glazing comprising at least two sheets of glazing material (a first sheet of glazing material and a second sheet of glazing material), joined by an interlayer structure comprising at least one (a first) sheet of adhesive interlayer material, the first sheet of glazing material, the second sheet of glazing material and the first sheet of adhesive interlayer material each having a first major surface and a second opposing major surface, the laminated glazing being configured such that the second major surface of the first sheet of glazing material faces the first major surface of the first sheet of adhesive interlayer material, and the first major surface of the second sheet of glazing material faces the second major surface of the first sheet of interlayer material, there being a first imprint on at least a portion of the first major surface of the first sheet of glazing material and substantially the same imprint on at least a portion of the first major surface of the second sheet of glazing material, wherein when viewed at zero angle of incidence to the radius of curvature of the first sheet of glazing material, the imprint on the first major surface of the first sheet of glazing material is offset from the imprint on the first major surface of the second sheet of glazing material.

The imprint on the first major surface may be produced when the initially flat sheet of glazing material is bent between a pair of complementary pressing members.

A laminated glazing according to the first aspect of the present invention has a higher degree of optical distortion when measured at normal incidence compared to when the glazing is inclined at an angle. In contrast, a conventional laminated glazing comprising a first and second press bent glass sheet, each glass sheet having been press bent individually though the same pair of complementary pressing members, has the lowest optical distortion when measured at normal incidence, and the optical quality in transmission decreases as the rake angle increases.

It should be noted that in addition to the optical distortion arising from the shaping process, there may be additional optical distortion causes by thickness variations of the adhesive sheet. These additional optical distortions still have low power at normal incidence, and higher power at increased angles of inclination (as described in Glass Processing Days, 2003, pages 502-504 and shown in figure 7 of said document).

In view of these additional sources of optical distortion, a laminated glazing produced according to the present invention may have lowest optical distortion at normal incidence but having a much slower rate of increase with increasing inclination angle of the laminated glazing.

The amount of offset is more than is obtainable from the conventional manufacturing tolerances. For example, the tolerance or positional accuracy of a conventional press-bending furnace is within +0.5mm, meaning that a sheet of glass can be positioned in the same place between a pair of press bending members to within +0.5mm.

Preferably the first imprint on the first major surface of the first sheet of glazing material extends over the entire first major surface of the first sheet of glazing material.

The contact between the first and/or second major surface of the sheet of glazing material and a pressing member configured to contact that particular surface may give rise to an imprint on that major surface

Preferably the imprint on the first major surface of the second sheet of glazing material extends over the entire first major surface of the first sheet of glazing material.

It will be readily apparent that unless the first and second sheets of glazing material are bent at exactly the same location between a pair of shaping members, the imprint on the first and second sheets of glazing material will not be exactly the same. However given the first and second sheets of glazing material have been bent between the same pair of shaping members, there will be at least one portion of the respective major surface of each of the first and second sheets of glazing material where the imprint is the same.

Preferably the second major surface of the first and second sheets of glazing material has a second imprint thereon.

Preferably when viewed at zero angle of incidence to the radius of curvature of the first sheet of glazing material, the imprint on the second major surface of the first sheet of glazing material is offset from the imprint on the second major surface of the second sheet of glazing material.

The imprint on the second major surface of the first and second sheet of glazing material may be produced when the respective sheet of glazing material is shaped between a complementary pair of press bending members.

When one or both of the complementary press bending members is configured to apply a negative pressure therethrough, such that a sheet of heat softened glazing material may be drawn to the shaping surface of the respective complementary press bending member, this may also be responsible for enhancing at least some or all of the imprint on the respective surface of the heat softened sheet of glazing material.

When a sheet of glazing material is shaped in such a manner, one or both of the press bending members may be configured such that the entire major surface area of the sheet of glazing material is contacted.

Typically each sheet of glazing material in the laminated glazing is positioned between the press bending members in the same position relative to both the pressing members.

The amount of offset is greater than that introduced due to normal manufacturing tolerances. Typically each glass sheet can be positioned between the shaping member to a positional accuracy of less 5mm, or less than 4mm, or less than 3mm, or less than 2mm, or less than 1mm.

The amount of offset between the imprints is greater than the repeatability of the positional accuracy. The amount of offset between the imprints is greater than 0.5mm, or greater than 1mm, or greater than 1.5mm, or greater than 2mm, or greater than 2.5mm, or greater than 3mm, or greater than 3.5mm, or greater than 4mm, or greater than 4.5mm, or greater than 5mm.

Laminated glazings according to the present invention may be curved in one or more directions. Preferably the radius of curvature in at least one of the one or more directions is between 500mm and 20000mm, more preferably between 1000mm and 8000mm. When the laminated glazing is curved in two or more directions, preferably two of the two or more direction of curvature are mutually orthogonal.

A glazing material suitable for use in all or any of the first, second, third, fourth and fifth aspects of the present invention is glass, in particular glass having a soda-lime-silica glass composition. For example, the first and/or second sheet of glazing material may be a sheet of soda-lime-silica glass.

A typical soda-lime-silica glass composition is (by weight), Si0₂ 69 - 74 %; A1₂0₃ 0 - 3 %; Na₂0 10 - 16 %; K₂0 0 - 5 %; MgO 0 - 6 %; CaO 5 - 14 %; S03 0 - 2 %; Fe₂0₃ 0.005 - 2 %. The glass may also contain other additives, for example, refining aids, which would normally be present in an amount of up to 2 %. The soda-lime-silica glass composition may contain other colouring agents such as Co₃0₄, NiO and Se to impart to the glass a desired colour when viewed in transmitted light. The transmitted glass colour may be measured in terms of a recognised standard such as BS EN410.

Embodiments of the present invention will now be described by way of example only with reference to the accompanying drawings, in which:

Figure 1 shows a schematic plan view of a sheet of glazing material prior to being shaped;

Figure 2 shows a cross-section of a curved laminated glazing;

Figure 3 shows a plan view of two glass sheets prior to being shaped;

Figure 4 shows a cross-sectional view of a laminated glazing using two curved sheets of glazing material that have the configuration shown in figure 3 prior to being shaped;

Figure 5 shows a curvature measurement map of a glass sheet that has been press bent between a male die and a female support ring;

Figure 6 show a schematic plan view of a conveyor of a press bending furnace;

Figure 7 shows a side view of a portion of a press bending furnace; Figure 8 shows the positional variation of a locator used to position glass sheets between shaping members of a press bending furnace;

Figure 9 shows the position of a locator at two positions;

Figure 10 shows a plan view of how two plies of glass may be offset to improve optical quality in transmission;

Figure 11 shows a cross-sectional view of a laminated glazing where the plies have been offset prior to lamination;

Figure 12 shows how normalised optical power of a laminated glazing varies with misalignment between the inner and outer plies;

Figure 13 shows how the optical quality in transmission (in millidioptres) varies with the amount of offset (in mm) between the inner and outer plies; and

Figure 14 shows how the optical quality in transmission (in millidioptres) varies with rake angle (angle of inclination from the vertical).

Figure 1 shows a plan view of a glass sheet of the type used for a ply of a vehicle windscreen. Depending upon the radius of curvature of the bent vehicle windscreen, each of the inner and outer plies may be cut to the same peripheral dimensions. If each ply 1, 3 has the same external dimensions, then when bent the edges of the glass sheets do not exactly align in the laminated glazing. This is shown in Figure 2, where the glass sheet 3 is the outer ply and the glass sheet 1 is the inner ply. Glass ply 1 is joined to the glass ply 3 by an adhesive sheet 5 of polyvinyl butyral (PVB). The degree of misalignment may be acceptable to a customer, especially for low radius of curvature. Furthermore there may be a polyurethane gasket or the like around the peripheral edge of the curved windscreen so that the misalignment is not seen.

The geometric centre C is shown in the major surface of the glass ply 1, 3. When bending, the intention is to position the point C on each ply 1, 3 at the same position between press bending members. The axis A- A' is suitably positioned and is parallel to the parallel edges of the glass ply 1, 3. The axis B-B' is perpendicular to the axis A-A' and is positioned mid-way between the upper and lower edges of the glass ply 1, 3.

Figure 3 shows a plan view of glass sheets 11 and 13. Glass sheet 11 is the flat blank for the inner ply of the laminated vehicle glazing and glass sheet 13 is the flat blank for the outer ply of the laminated vehicle glazing. The external dimensions of the glass sheet 11 (shown as a dashed line) are smaller than the external dimensions of the glass sheet 13. The external dimensions of the glass sheet 11 are chosen such that the edges of the bent glass sheets align in the final laminated glazing.

The edges of the individual glass sheets 1, 3 of the laminated glazing 10 shown in figure 2 are not aligned, whereas the edges of the individual glass sheets 11, 13 of the laminated glazing 20 shown in figure 4 are aligned. In figure 4, glass ply 11 is joined to glass ply 13 by means of adhesive sheet 15, which in this example is PVB but may be EVA.

The point C lies at the geometric centre of each of the glass plies 11, 13. When bending, the intention is to position the point C on each ply 11, 13 at the same position between press bending members. The axis A- A' is suitably positioned and is parallel to the parallel edges of the glass ply 1, 3. The axis B-B' is perpendicular to the axis A-A' and is positioned mid-way between the upper and lower edges of the glass ply 11, 13.

Figure 5 shows a curvature measurement map 21 of a curved glass sheet that has been press bent between a male die and a female support ring. The male die has a convex shaping face covered with a woven stainless steel cloth which contacts the surface of the initially flat, heat softened glass sheet to impart a concave curvature thereto.

The curved glass sheet has a desired curvature as specified in a CAD drawing of the glazing. On the curvature measurement map 21, the deviation of actual curvature of the curved glass sheet at a given point from the desired curvature at that point (as specified by the CAD drawing) is specified by a pixel having a particular grey level i.e. a certain level of reference RGB values to indicate no deviation. That is, if there is no deviation from the desired curvature there would be a grey point having a particular shade (a reference shade) on the curvature measurement map 21. The greater the deviation of actual curvature of the curved glass sheet at a given point from the desired curvature at that point (as specified by the CAD drawing), the greater is the variation in the shade of grey for the pixel away from the shade of grey representing no deviation. Positive and negative deviations may be represented on the curvature measurement map. The area of the curvature measurement map 21 near the upper edge, as indicated by arrow 22, is almost entirely black indicating that part of the curved glass sheet has the greatest deviation from the desired curvature. In the region 22 the deviation is of the order of a few tenths of a micron.

The curvature measurement map 21 shows that instead of being smooth i.e. the curvature map is all one shade of grey, the surface of the curved glass sheet is covered with an imprint. This imprint is from the stainless steel woven cloth that covers the surface of the male die. The imprint on the glass surface may be enhanced if the male die is configured to use negative pressure reducing means capable of drawing the heat softened sheet towards the shaping surface of the male die. This type of male die is described in WO2005/033026A1. Given that the imprint is of the order of a few hundredths to a few tenths of a micron, to the human eye the surface of the curved glass sheet appears smooth.

The points a, b, c and d lie at the corners of a rectangle e. At the centre of the rectangle e is the point C. The rectangle abed may be particularly relevant since this is an important vision area for a vehicle windscreen.

A heat softened glass sheet that is pressed between a male die covered with a stainless steel woven cloth and the female support ring will have the imprint on the concave surface. If the female shaping member is a full surface complementary shaping member instead of a support ring, there may be an imprint on both opposed major surfaces of the press bent glass sheet.

Figure 6 shows a schematic plan view of part of a press bending furnace 30 and figure 7 shows a schematic side view of part of the furnace 30. The furnace 30 has a number of conveyor rolls 32 that define a longitudinal direction of travel, for example as shown by arrow 34. Each roller 32 rotates in a clockwise direction as shown for one roller by arrow 36. A glass sheet 31 is shown being transported on the rollers 32 in the direction of arrow 34 so as to position the glass sheet 31 between the male die 35 and the female support ring 37. The glass sheet 31 is transported by direct contact with the rollers i.e. the glass sheet 31 is not carried on a ring mould or the like prior to being positioned between the male die 35 and the female support ring 37.

The shaping surface of the male die 5 is covered with a stainless steel woven cloth. The male die 35 may be of the type described in WO2005/033026A1. The direction indicated by arrow 34 is perpendicular to the rollers 32 and parallel to the longitudinal axis of the bending furnace.

A pair of locators 38, 39 are raised when the glass sheet 31 is in the desired position between the shaping members for bending. The locators (often known as stops) are configured to act on the leading edge of the flat glass sheet 31.

Each locator 38, 39 is in electrical communication with a controller 40. The controller is used to actuate the locators at the correct time and may take inputs from suitable sensors such as photodiodes upstream thereof. Such sensors provide positional input of the glass sheet, or a portion thereof, such as an edge portion of the glass sheet, to the controller so that the controller actuates the locators to correctly position the glass sheet 31 in between the shaping members 35, 37.

Once the glass sheet 31 is supported on the female support ring 37 (by movement of the female support ring 37 relative to the rollers), the male die 35 moves relative to the female support ring 37 to press bend the glass sheet therebetween. For example, the male die 35 is moveable vertically relative to the female support ring 37 in the direction of arrow 35'. As is conventional in the art, the female support ring 37 may be segmented to permit displacement of the female support ring 37 above the level of the conveyor rolls 32, for example as described in US4,015,968.

After the glass sheet is bent, the glass sheet is suitably transported to a cooling furnace. For example the glass sheet may be transported by means known in the art, such as on rollers, by air flotation, or carried on a shuttle ring. In figure 6 and figure 7 the bent glass 31 is transported on rollers 42.

The locators 38, 39 have a positional accuracy which determines how consistent the bending operation is. When the control means actuates the locators ideally each locator 38, 39 should stop subsequent glass sheets 31 at the same position each time for bending between the male die 35 and the support ring 37. For example the imaginary reference point C on the glass sheet 31 should coincide with the imaginary reference point M located at the centre of the male die. The reference point C may be located at the geometric centre of the flat glass sheet 31. In practice each locator 38, 39 is able to be position to within a lateral tolerance and a longitudinal tolerance.

This is illustrated in figure 8. Figure 8 shows a plan view of locator 38 positioned between roller 32 and roller 42. The locator 38 is shown as having a circular perimeter but other configuration of perimeter for each locator 38, 39 may be used.

The target longitudinal position for the locator 38 is X and the target lateral position for the locator 38 is F. The target position X lies along lateral axis X-X ' and the target position F lies along longitudinal axis -F". The position X, Flies at the intersection of axis X-X ' with the axis -F". The axis X-X' is parallel to the lateral axis (or direction) of the furnace and the axis -F" is parallel to the longitudinal axis (or direction) of the furnace. Typically the rollers 32, 42 are parallel to the lateral axis of the furnace.

The positions X, Y may be measured relative to a fixed point on the furnace, for example the position of the first conveyor roller, the entrance to the furnace, etc. The lateral tolerance is ±δχ and the longitudinal tolerance is ±5y. Therefore the locator 38 may be positioned at the point X, Fto within +δχ and ±5y. Shown in phantom is the locator 38' at position X+ δχ , F + 5y.

Note that in this example the centre point of the locator 38 is desired to be at the point X, Fbut it may be some other fixed point on the locator. The dimensions of the locator may be taken into account when positioning the locator at a given point X, Y such that the reference point C on the flat glass sheet is correctly positioned between the shaping members.

In prior art systems for separately shaping two glass sheets for use as inner and outer plies in a laminated glazing such as a vehicle windscreen, the locators 38, 39 target for the same position for each ply, taking into account any dimensional change of the inner ply, as described in relation to figure 3 and 4. Consequently the imprint on the surface of the glass sheets in contact with the stainless steel woven cloth covering the male die 35 is the same.

Figure 9 shows how the locator 38 is used to position the glass sheets between the male die 35 and the female support ring 37 according to the first aspect of the present invention.

The locator 38 is shown at a first position 38 (1). This position of the locator is XI, Yl and is at the intersection of axis ΧΓ-ΧΓ and ΥΓ-ΥΓ The axis 7'- 7"is parallel to the lateral axis of the furnace and the axis ΥΓ-ΥΓ ' is parallel to the longitudinal axis of the furnace. The outer ply of a vehicle windscreen is positioned by the locator at position XI, Yl such that the reference point C on the outer ply is in the correct position for bending between the shaping members.

In order to consistently achieve improved optical quality in transmission for laminated windscreens installed in a vehicle at a typical installation angle off-normal, the position for bending of the inner ply for the vehicle windscreen is deliberately offset with respect to the position for bending the outer ply. The locator 38 is moved from position 38(1) to position 38(2) such that the desired position is at X2, Y2, which lies at the intersection of axis 2'- 2" and Y2'-Y2". The axis X2^,-X2^{, ,}is parallel to the lateral axis of the furnace and the axis 72'- 72" is parallel to the longitudinal axis of the furnace. The outer ply of a vehicle windscreen is positioned by the locator at position X2, Y2, shown as 38 (2). The position of the locator 38 is changed using the controller 40.

As described with reference to figure 8, the locator 38 may be positioned at position XI, Yl to within +δχ and ±5y. Given that the same locator 38 is used to position both the glass sheets for the outer and inner plies of the vehicle windscreen, the locator 38 may be positioned at position X2, Y2 to within +δχ and ±5y.

The magnitude of the lateral separation between axis 77 '-77" and axis 72 '-72" is greater than the twice the magnitude of the lateral tolerance of the locator 38, that is

The magnitude of the longitudinal separation between axis XV -XV and axis

XT'- 2" is greater than the twice the magnitude of the longitudinal tolerance of the locator 38, that is |72 - 71 | > 2 \hy\.

In this example, δχ is 0.5mm, so the longitudinal tolerance is +0.5mm i.e. δχ = +0.5mm. Also, hy is 0.5mm, so the lateral tolerance is +0.5mm i.e. hy = +0.5mm. The lateral separation between axis 77'-77" and axis Υ2^,-Υ2^, ' was 2.5mm and the longitudinal separation between axis XV -XV and axis 2'- 2" was 2.5mm.

The first glass sheet positioned by locator 38 at position XI, Yl is shaped between the male die 35 and female support ring 37. A second glass sheet positioned by locator 38 at position X2, Y2 is shaped between the male die 35 and female support ring 37.

Once cooled, the first and second glass sheets are laminated together with a sheet of

PVB.

The optical quality of the laminated glazing was found to have a higher quality when inclined at an angle of 60° to the vertical compared to when measured at normal incidence i.e. the laminated glazing is inclined at 0° to the vertical.

Since the locator 38 is at a first position to bend the outer ply and at a deliberately offset second position to bend the inner ply, the imprints on the major surfaces of the outer and inner plies are offset relative to each other when viewed at normal incidence.

In an alternative embodiment to that shown in figure 9, the longitudinal separation between axis XV -XV and axis 2'- 2" is less than or equal to twice the longitudinal tolerance of the locator 38 i.e. 2 ^χ δχ. The axes ΧΓ-XV and 2'- 2" may be collinear. In another alternative embodiment to that shown in figure 9, the lateral separation between axis ΥΓ-Υ1" and axis 72'-Y2" is less than or equal to twice the lateral tolerance of the locator 38 i.e. 2 ^χ by. The axes ΥΓ-Υ1" and Υΐ-ΥΤ' may be collinear.

In another alternative embodiment to that shown in figure 9, a first locator is used to position the first glass sheet at position XI, Yl and a second different locator is used to position the second glass sheet at position X2, Y2.

Another way to achieve the offset between the outer and inner plies is described with reference to figures 8, 10 and 11.

Figure 10 shows two flat glass plies 51, 53. The outer glass ply 51 is positioned between the male die 35 and female support ring 37 by the locator 38 at position X, Y. The outer glass ply 51 is shaped and cooled and transported away on rollers 42.

As is conventional in the art, the inner glass ply 53 is also positioned between the male die 35 and female support ring 37 by the locator 38 at position X, Y. The inner glass ply 53 is also shaped and cooled and transported away on rollers 42.

In accordance with the second aspect of the present invention, and with particular reference to figure 11, prior to the lamination process, the shaped outer ply 51 is offset relative to the shaped inner ply 53 i.e. the outer ply 51 is first laid up, then a sheet of PVB 55 is placed on the shaped outer ply 51, followed by the shaped inner ply being placed on the sheet of PVB 55 but offset relative to the shaped outer ply 51. The amount of offset in relation to axis q-q' and/or r- should be more than twice the respective longitudinal/lateral tolerance of the locators to ensure consistently better optical quality in transmission.

The imaginary reference point Ml lies on the major surface of the outer ply 51 and is that point that was in contact with the male die 35 at imaginary point M on the surface of the male die. The imaginary reference point M2 lies on the surface of the inner ply and is that point that was in contact with the male die 35 at imaginary point M on the surface of the male die. The reference points Ml, M2 are located at the geometric centre of the major surface of the inner and outer plies 51, 53.

In a conventional lamination process when the inner and outer plies are laid up for lamination the imaginary references points Ml and M2 are aligned. In this way, the resulting laminated glazing would have the edges aligned. However in accordance with the present invention the imaginary reference points Ml and M2 are deliberately offset by more than twice the magnitude of the lateral tolerance and/or longitudinal tolerance of the locators. In this way, the imprint on the major surface of the outer ply that was in contact with the male die 35 and the imprint on the major surface of the inner ply that was in contact with the male die 35 are offset relative to one another when viewed at normal incidence to the surface of the laminated glazing.

A consequence of this is that the edges of the laminated glazing 57 are not aligned, as shown in figure 11 and the inner ply 53 may have an overlap region 54 that extends beyond periphery of the outer ply 51 in one direction and is inboard the periphery of the outer ply in the opposite direction.

To avoid the overlap 54 the overlapping edges prior to laminating the two plies 51, 53 may be removed by cutting for example. Alternatively, the flat glass sheets prior to being shaped may be suitably cut such that when they are misaligned the edges are aligned in the resulting laminated glazing. It will be apparent that the shapes may be cut to have an outline defined by the degree of overlap between the outer and inner plies as shown in figure 10.

The laminated glazing may be encapsulated such that the peripheral edge of the laminate is covered with a gasket of suitable material such as polyurethane. Using

encapsulation in this way hides the misaligned edges.

To illustrate the effect of misaligning the outer ply relative to the inner ply a number of laminated vehicle windscreens were made. Each windscreen has an inner ply of 2.1mm float glass joined to an outer ply of 2.1mm float glass via an adhesive sheet of PVB.

Each inner ply and a corresponding outer ply were made by press bending each individual glass ply between the same press bending members using substantially the same bending conditions. In particular the position of the inner ply and the outer ply between the press bending members was such that the surface imprint would align if laid up in a conventional manner during the lamination process. A suitable press bending furnace is described in WO2004/085324A1, in particular the figures and related description thereof. Other suitable press bending furnaces are known, for example as described in EP0398759A2.

Five windscreens were made where the inner ply was misaligned horizontally with respect to the outer ply. In this context, "horizontal" means the direction with respect to the windscreen in the installed position.

A test was designed to simulate the situation, where a driver looks "cross-car" through a vehicle windscreen, i.e. whilst sat in the driver's seat, the driver looks through the portion of the vehicle windscreen on the passenger side of the vehicle, as for example when observing traffic lights. When the driver looks through the glass in this way, the optical path of light has a horizontal angel of inclination to the normal of the glass surface of the order of 45°. Each sample was tilted to 61° from the vertical to simulate an installation angle and then rotated about the vertical axis in a clockwise and anti-clockwise direction of 45°.

In order to assess the optical affects, the optical power in a region in the centre of the windscreen under test was measured, see for example the region abed on figure 5. The region was approximately 300mm x 300mm and the optical power in transmission was measured using a technique as described in WO2004/083835A1. A parameter ROC was used to define each windscreen under test. The parameter ROC is the difference between the maximum optical power and minimum optical power within a certain distance and is used to describe the observable distortions in the glass. For each measurement angle +45° and -45°, the optical power characterised in terms of the parameter ROC in the test region of each respective windscreen was measured and an average calculated. For each angle of rotation the measured optical power characterised in terms of the parameter ROC was divided by the average optical power:

Optical Power (+45°)

Normalised Optical Power (+45°) =—

V₂[Optical Power (-45°)+0ptical Power (+45°)]

Optical Power (-45°)

Normalised Optical Power (—45°) =—

V₂[Optical Power (-45°)+0ptical Power (+45°)]

This test was carried out on each of the five windscreens. The five windscreens were made with a different degree of misalignment between the inner ply and the outer ply when the plies were laid up for lamination:

Table 1

The results are shown in figure 12 which shows how the normalised optical power (in the direction of arrow 60) varies as a function of misalignment (in mm) of the inner and outer plies (in the direction of arrow 62). For clockwise rotation (shown as line 64), the normalised optical power of the windscreen reduces when the misalignment increases in a positive direction. For anti-clockwise rotation (shown as line 66), the normalised optical power reduces when the misalignment increases in the negative direction.

It would therefore be expected that as the vertical misalignment increases the optical power will reduce in a similar way.

To determine the effect of vertical misalignment, ten windscreens were made where the inner 2.1mm glass ply was moved upwards relative to the outer 2.1mm glass ply prior to being laminated. A positive displacement represents an upwards misalignment. In this context, upwards means the upper portion of the windscreen in the installed position at an angle of about 61° from the vertical i.e. the portion of the windscreen nearest the vehicle roof is the upper part of the windscreen. Figure 13 shows how the ROC in millidioptres (axis 70) varies with the amount of offset in mm (axis 72) between the inner and outer plies with each windscreen installed at an angle of about 61° from the vertical. As the vertical misalignment increases, the ROC in a central zone of the windscreen is seen to vary. Samples having misalignment in the 2-3mm region shown significantly lower distortion (30-40 millidioptres) compared to

70 millidioptres for a conventional windscreen where there is no misalignment between the inner and outer plies.

The line through the data points on figure 13 is a line of best fit.

To determine the effect of rake angle on optical quality a number of windscreens were made where the vertical misalignment between the inner and outer plies was changed. Four samples were made where the misalignment was -0.25mm (line 85), +0.7mm (line 86), +2.4mm (line 87) and +2.6mm (line 88) and the results are shown in figure 14.

In figure 14, the axis 80 denotes the rake angle in degrees (°), that is, the angle of inclination with respect to the vertical. The axis 82 denotes the measured ROC value (in millidioptres) in a central zone of the windscreen i.e. a region abed as shown in figure 5. At a rake angle of 0° i.e. normal incidence, samples with an offset of +2.4mm and +2.6mm show higher values of ROC in the central zone compared to a windscreen manufactured in a conventional manner.

As the rake angle increases, the +2.4mm (line 87) and +2.6mm (line 88) samples exhibit a minimum in ROC at around 30° rake angle. At a rake angle of 70° the samples +2.4mm (line 87) and +2.6mm (line 88) have significantly lower ROC compared to the samples with little misalignment (80-100 millidioptres compared to >120millidioptres).

Without being bound by theory, one explanation for the optical power not having a minimum at zero millidioptres is that there is still some optical distortion caused by the PVB adhesive sheet, in particular thickness variations of the PVB sheet.

The examples above demonstrate that when the inner and outer plies are bent using a conventional press bending furnace, by deliberately offsetting the bent plies when they are laid up for lamination can result in a laminated glazing having a better optical quality when measured at an installation angle (i.e. around 60° from the vertical) compared to when measured at normal incidence (i.e. at 0° from vertical).

It would be expected that similar behaviour would be observed if the inner and outer glass plies were offset with respect to each other when each ply was press bent between the shaping members. Consequently the inner and outer plies would be deliberately press bent at different position between the shaping members.

The present invention provides particular application for the production of vehicle windscreens, especially windows for cars. Such windows typically comply with the requirements of ECE R43.

Claims

1. A method of making a laminated glazing comprising the steps:

(vi) positioning the second sheet of glazing material with positioning means such that the second sheet of glazing material is at a second position for bending between the pair of shaping members,

2. A method according to claim 1, wherein the first position for bending and the second position for bending are selected such that the first and second sheets of glazing material, when shaped in steps (iii) and (vii) respectively are able to be suitably paired to make the laminated glazing in step (ix).

3. A method according to claim 1 or claim 2, wherein the positioning means has a longitudinal tolerance in a direction parallel to the first direction such that a reference point on a reference sheet of glazing material is positionable at a target location in a direction parallel to the first direction to within the longitudinal tolerance.

4. A method according to claim 3, wherein the magnitude of the longitudinal tolerance is less than 2.0mm, preferably less than 1.0mm.

5. A method according to claim 3 or claim 4, wherein the positioning means has a lateral tolerance in a direction perpendicular to the first direction such that a reference point on a reference sheet of glazing material is positionable at a target location in a direction parallel to the first direction to within the lateral tolerance.

6. A method according to claim 5, wherein the magnitude of the lateral tolerance is less than 2.0mm, preferably less than 1.0mm.

7. A method according to any preceding claim, wherein the first position is offset from the second position by a lateral displacement being greater than the magnitude of the lateral tolerance and/or a longitudinal displacement being greater than the magnitude of the longitudinal tolerance.

8. A method according to any preceding claim, wherein when the first sheet of glazing material is at the first position the positioning means are in a first configuration and when the second sheet of glazing material is at the second position the positioning means are in a second configuration.

9. A method according to claim 8, wherein when the positioning means are in the first configuration, a reference point on a reference sheet of glazing material positioned by the positioning means between the pair of shaping members is at a first location, and when the positioning means are in the second configuration, the reference point on the reference sheet of glazing material positioned by the positioning means between the pair of shaping members is at a second location, further wherein the first location of the reference point on the reference sheet of glazing material is displaced relative to the second location of the reference point on the reference sheet of glazing material by a lateral displacement being greater than the magnitude of the lateral tolerance and/or a longitudinal displacement being greater than the magnitude of the longitudinal tolerance.

10. A method according to claim 9, wherein the lateral positional displacement is the same as the lateral displacement.

11. A method according to claim 9 or claim 10, wherein the longitudinal positional displacement is the same as the longitudinal displacement.

12. A method according to any of the claims 9 to 11, wherein the lateral displacement and/or longitudinal displacement is less than m ^χ d x tan (sin^"1 Q x sin ø)), where d is the intended thickness of the laminated glazing in millimetres, n is the refractive index of the first and/or second sheet of glazing material at 540nm and Θ is the intended installation angle of the laminated glazing and m is less than or equal to 5, preferably m is less than or equal to 4, more preferably m is less than or equal to 3, even more preferably m is less than or equal to 2.

13. A method according to any of the claims 9 to 12, wherein the lateral displacement and/or longitudinal displacement is less than or equal to d x tan (sin^"1 Q x sin ø)) where d is intended thickness of the laminated glazing in millimetres, n is the refractive index of the first and/or second sheet of glazing material at 540nm and Θ is the intended installation angle of the laminated glazing.

14. A method according to any of the claims 9 to 12, wherein the lateral displacement and/or longitudinal positional displacement is between ³/₂ ^χ d x tan (sin^"1 Q x sin ø)) and

V₂ x d x tan (sin^-1 x sin ^ where d is the intended thickness of the laminated glazing in millimetres, n is the refractive index of the first and/or second sheet of glazing material at 540nm and Θ is the intended installation angle of the laminated glazing.

15. A method according to any of the claims 12 to 14, wherein d is between 2mm and 10mm.

16. A method according to any of the claims 12 to 15, wherein n is between 1.5 and 1.8, preferably 1.52.

17. A method according to any of the claims 12 to 16, wherein Θ is between 20° and 80°, preferably between 50° and 70°.

18. A method of manufacturing a laminated glazing comprising the steps: (i) transporting a first sheet of glazing material in a first direction between a pair of shaping members;

(vii) laminating the first sheet of glazing material to the second sheet of glazing material via at least one adhesive sheet,

displacement and/or a longitudinal position displacement.

19. A method according to claim 18, wherein the positioning means has a longitudinal tolerance in a direction parallel to the first direction such that a reference point on a reference sheet of glazing material is positionable at a target location in a direction parallel to the first direction to within the longitudinal tolerance.

20. A method according to claim 19, wherein the positioning means has a lateral tolerance in a direction perpendicular to the first direction such that the reference point on the reference sheet of glazing material is positionable at the target location in a direction parallel to the first direction to within the lateral tolerance.

21. A method according to claim 19 or claim 20, wherein the first position is the same as the second position to within the lateral tolerance and/or the longitudinal tolerance.

22. A method of manufacturing a laminated glazing comprising the steps:

(vi) positioning the second sheet of glazing material with positioning means such that the second sheet of glazing material is in a second position between the pair of shaping members;

23. A method according to claim 22, wherein the first and/or second sheet of glazing material has been cut prior to being shaped, such that if the first and second sheets of glazing material were shaped in a conventional manner they would not form a congruent pair.

24. A method according to any of the preceding claims, wherein the first and/or second sheet of glazing material is a glass sheet, in particular a soda-lime-silica glass sheet.

25. Apparatus for shaping a sheet of glazing material, in particular a glass sheet, the apparatus comprising: (i) a pair of shaping members,

configuration, such that with the positioning means in the second configuration, the reference sheet of glazing material is positionable between the pair of shaping members and the reference point on the reference sheet of glazing material is at a second lateral position and/or a second longitudinal position,

the first lateral position being displaced relative to the second lateral position by more than the lateral tolerance and/or the first longitudinal position being displaced relative to the second longitudinal position by more than the longitudinal tolerance.

26. A laminated glazing comprising at least two sheets of glazing material (a first sheet of glazing material and a second sheet of glazing material), joined by an interlay er structure comprising at least one (a first) sheet of adhesive interlayer material, the first sheet of glazing material, the second sheet of glazing material and the first sheet of adhesive interlayer material each having a first major surface and a second opposing major surface, the laminated glazing being configured such that the second major surface of the first sheet of glazing material faces the first major surface of the first sheet of adhesive interlayer material, and the first major surface of the second sheet of glazing material faces the second major surface of the first sheet of interlayer material, there being an imprint on at least a portion of the first major surface of the first sheet of glazing material and substantially the same imprint on at least a portion of the first major surface of the second sheet of glazing material, wherein when viewed at zero angle of incidence to the radius of curvature of the first sheet of glazing material, the imprint on the first major surface of the first sheet of glazing material is offset from the imprint on the first major surface of the second sheet of glazing material.

27. A laminated glazing according to claim 26, wherein the amount of offset between the imprints is greater than 0.5mm, or greater than 1mm, or greater than 1.5mm, or greater than mm, or greater than 2.5mm, or greater than 3mm, or greater than 3.5mm, or greater thanmm, or greater than 4.5mm, or greater than 5mm.