WO2016005280A1 - Interconnecting optical fibers at a hydrocarbon fluid production facility - Google Patents
Interconnecting optical fibers at a hydrocarbon fluid production facility Download PDFInfo
- Publication number
- WO2016005280A1 WO2016005280A1 PCT/EP2015/065187 EP2015065187W WO2016005280A1 WO 2016005280 A1 WO2016005280 A1 WO 2016005280A1 EP 2015065187 W EP2015065187 W EP 2015065187W WO 2016005280 A1 WO2016005280 A1 WO 2016005280A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- window
- fiber optical
- hydrocarbon fluid
- optical cable
- collimated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/36—Mechanical coupling means
- G02B6/38—Mechanical coupling means having fibre to fibre mating means
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/36—Mechanical coupling means
- G02B6/38—Mechanical coupling means having fibre to fibre mating means
- G02B6/3807—Dismountable connectors, i.e. comprising plugs
- G02B6/381—Dismountable connectors, i.e. comprising plugs of the ferrule type, e.g. fibre ends embedded in ferrules, connecting a pair of fibres
- G02B6/3816—Dismountable connectors, i.e. comprising plugs of the ferrule type, e.g. fibre ends embedded in ferrules, connecting a pair of fibres for use under water, high pressure connectors
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B17/00—Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings
- E21B17/02—Couplings; joints
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B33/00—Sealing or packing boreholes or wells
- E21B33/02—Surface sealing or packing
- E21B33/03—Well heads; Setting-up thereof
- E21B33/04—Casing heads; Suspending casings or tubings in well heads
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B33/00—Sealing or packing boreholes or wells
- E21B33/10—Sealing or packing boreholes or wells in the borehole
- E21B33/12—Packers; Plugs
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/26—Optical coupling means
- G02B6/32—Optical coupling means having lens focusing means positioned between opposed fibre ends
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/26—Optical coupling means
- G02B6/32—Optical coupling means having lens focusing means positioned between opposed fibre ends
- G02B6/325—Optical coupling means having lens focusing means positioned between opposed fibre ends comprising a transparent member, e.g. window, protective plate
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/36—Mechanical coupling means
- G02B6/38—Mechanical coupling means having fibre to fibre mating means
- G02B6/3807—Dismountable connectors, i.e. comprising plugs
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/36—Mechanical coupling means
- G02B6/38—Mechanical coupling means having fibre to fibre mating means
- G02B6/3807—Dismountable connectors, i.e. comprising plugs
- G02B6/381—Dismountable connectors, i.e. comprising plugs of the ferrule type, e.g. fibre ends embedded in ferrules, connecting a pair of fibres
Definitions
- the invention relates to a system and method for interconnecting optical fibers at a hydrocarbon fluid production facility, such as at a crude oil, natural gas and/or other hydrocarbon fluid production well.
- the fiber In a FO connector, the fiber is glued in a ceramic ferule.
- the intermeshing connector sections then align and center these ferules, i.e. the ends of the fibers, against each other.
- Such connections show some signal loss and distortion. In a good FO-connection this loss is of the order of O.ldB.
- optical fibers cannot sustain significant shear forces.
- US patent 4,994,671 discloses a production logging tool for analyzing the composition of formation fluids in a downhole test chamber in which a light source emits near infrared rays via collimation or fiber optics.
- the collimation means may comprise a collimating mirror, a first fiber optic bundle for directing the near infrared rays to a substantially transparent window of the test chamber and a second fiber optic bundle for directing light reflected by the formation fluid to a spectrometer for detecting the composition of the formation fluid.
- the first and second fiber optic bundles are arranged in the test chamber at the same side of the light transparent window.
- a system for optically interconnecting fiber optical cables at a hydrocarbon fluid production facility comprising:
- first lens system arranged at one side of the window, which first lens system is connected to a first fiber optical cable and configured to convert a first light beam transmitted through the first fiber optical cable into a collimated light beam that is transmitted through the window;
- a second lens system ed at an opposite side of the window, which second lens system is configured to receive the collimated light beam and reconvert it into a second light beam that is transmitted into a second fiber optical cable that is connected to the second lens.
- interconnecting fiber optical cables at a hydrocarbon fluid production facility comprising:
- Figure 1 is a schematic longitudinal sectional view of a well with fiber optical cables interconnected by pressure resistant collimated couplers;
- Figure 2 is a schematic longitudinal sectional view of another well with fiber optical cables interconnected by pressure resistant collimated couplers;
- Figure 3 is a schematic longitudinal sectional view of a wellhead comprising fiber optical cables
- Figure 4 is a schematic longitudinal sectional view of a pressure resistant collimated coupler.
- the present disclosure involves a collimated optical coupler comprising:
- first lens system arranged at one side of the window, which first lens system is connected to a first fiber optical cable and configured to convert a first light beam transmitted through the first fiber optical cable into a collimated light beam that is transmitted through the window;
- a second lens system arranged at an opposite side of the window, which second lens system is configured to receive the collimated light beam and reconvert it into a second light beam that is transmitted into a second fiber optical cable that is connected to the second lens.
- the window thus is a pressure resistant light transparent window, capable of allowing passage of light between the first and second fiber optical cables through a pressure barrier.
- the pressure resistant light transparent window may be made of glass and be sealingly arranged in and penetrating a pressure barrier in a wall of the
- hydrocarbon fluid facility which may be configured to resist a pressure difference of 100 Bar and optionally of 1000 Bar to prevent leakage of hydrocarbon fluid to the environment .
- the hydrocarbon fluid production facility may be a hydrocarbon fluid production well traversing a
- pressurized hydrocarbon fluid containing formation and a plurality of pressure resistant light transparent windows may be arranged at several locations in the well, such as in the wellhead, a tubing hanger, and downhole below the tubing hanger, wherein the pressure resistant windows in the wellhead and tubing hanger may have a smaller width than at least one pressure resistant window downhole in the well.
- Figure 1 shows a hydrocarbon fluid production well 1 comprising a wellhead 2 with a tubing hanger 3 from which a production tubing 4 is suspended.
- the wellhead 2 is sealingly connected to an upper casing section 5 that is sealingly secured within the surrounding formation 6 by a cement sheath 7.
- a lower casing section 8 is suspended from the upper casing section 5 by means of a packer 9 and is also sealingly secured within the surrounding formation by a cement sheath 10.
- a lower section of the production tubing 4 is sealingly secured to the surrounding upper casing section by another packer 11.
- the well 1 is equipped with a fiber optical sensing and/or communication assembly 12 comprising a series of pressure resistant collimated optical couplers 13, 14, 15 and 16 according to the invention that are shown in, and will be described in more detail with reference to, Figures 3 and 4. It is observed that the depicted optical coupler 16 is an example of a collimated coupler used in a wet connect system.
- Figure 2 shows another hydrocarbon fluid production well 21 comprising a wellhead 22 with a tubing hanger 23 from which a production tubing 24 is suspended.
- the wellhead 22 is sealingly connected to an upper casing section 25 that is sealingly secured within the
- a lower casing section 28 is suspended from the upper casing section 25 by means of a packer 29 and is also sealingly secured within the surrounding formation by a cement sheath 30.
- a lower section of the production tubing 24 is sealingly secured to the surrounding upper casing section 25 by another packer 31.
- the well 21 comprises a permeable hydrocarbon fluid inflow zone (not shown) in which the pressure may exceed 100 Bar.
- the well 21 is equipped with a fiber optical sensing and/or communication assembly 32 comprising a series of pressure resistant collimated optical couplers 33 and 34 according to the invention that are shown in, and will be described in more detail with reference to, Figures 3 and 4.
- the fiber optical cable assembly 12 is embedded in the cement sheath 27 surrounding the upper casing section 27, whereas in the well 1 shown in Figure 1 an upper part of the fiber optical assembly 12 is arranged in the annulus between the upper casing section 5 and the production tubing 4, whilst a lower part of the fiber optical assembly 12 is arranged within the cement sheath 10 surrounding the lower casing section 8.
- the collimated optical coupler can be assembled by:
- These steps may be repeated to form a series of the collimated optical couplers.
- These may be arranged in the wellhead, in the tubing hanger and downhole in the well below the tubing hanger, whereby the windows in the wellhead and the tubing hanger each have a smaller width than the window downhole in the well below the tubing hanger.
- FIG. 3 shows in more detail how the fiber optical cable assembly 12 shown in Figure 1 is equipped with collimated couplers 13 and 14 that penetrate through the wellhead 2 and tubing hanger 3.
- FIG 4 shows in further detail the collimated coupler 13 shown in Figures 1 and 3.
- the coupler 13 comprises cylindrical steel housing 40 with intermeshing upper and lower housing sections 40A and 40B that are screwed together by screws 40C.
- a light transparent glass window 41 is sealing secured between the upper and lower housing sections 40A and 40B by means of a pair of O-rings 42 and 43.
- the glass window 41 has a thickness T which is sufficient to withstand a pressure difference of at least 100 Bar to prevent that pressurized well effluents escape into the environment via the coupler 13.
- the upper and lower housing sections 40A and 40B each comprise a set of three cylindrical holes 44A-C and 45A-C in which first and second fiber optical cable sets 46A-C and 47A-C and associated first and second
- collimation lens systems 48A-C and 50A-C are arranged.
- the lens systems 48A-C and 50A-C and the window 41 may comprise mirrors and/or prisms.
- the first lens systems 48A-C are each configured to convert light beams transmitted through the first fiber optical cable sections 46A-C into collimated collinear light beams 51A-C, which are transmitted through the pressure resistant light transparent glass window 41 to the second lens systems 50A-C, which are configured to reconvert the collimated light beams into a de-collimated light beams 52A-C that are transmitted into the second fiber optical cable sets 47A-C and vice versa.
- system shown in Figure 4 for optically interconnecting fiber optical cables46A-C, 47A-C in a hydrocarbon fluid production facility 1 comprises:
- a first lens system set 48A-C which is arranged at one side of the window 41 and configured to convert a first light beam transmitted through a first fiber optical cable set 46A-C into a collimated light beam 51A-C that is transmitted through the window 41;
- a second lens system set 50A-C which is arranged at an opposite side of the window 41 and configured to receive and reconvert the collimated light beam 51A-C into a second light beam 52A-C that is transmitted into a second fiber optical cable 47A-C.
- the system according to the invention may provide downhole optic signal transfer through a pressure resistant glass window 41 that is sealed within a pressure barrier and the use of prisms, lenses, ' grin ' -lenses, (parabolic) mirrors and/or other lens systems to form a collimated optic signal coupling across the window 41.
- prisms, lenses, ' grin ' -lenses, (parabolic) mirrors and/or other lens systems to form a collimated optic signal coupling across the window 41.
- Such systems are currently solely available for use in a air or another controlled
- the novelty is in using these systems in less controlled environment, such as downhole and/or at a wellhead or tubing hanger of a hydrocarbon fluid production facility for in-situ connection of one or more fiber optical cables.
- a larger size of the window 41 will reduce the problems with dirt/sand disrupting the signal transfer.
- a small window 41 would be used to transfer a signal through a pressure barrier in a penetrator application.
- the collimated signal transfer system basically involves divergence of the optical signal to a diameter that can be handled better, followed by collimation of the signal, using lenses 48A-C or mirrors, in a collinear beam. Some distance away, this beam is focused, again using lens system sets 50A-C or mirrors and inserted in the next fiber 47A-C.
- the dual-collimator system provides a credible long- term pressure barrier using a small glass window in a penetrator for a high pressure differential.
- a second lens system 50A-C converges the light and injects it in the second fibers 47A-C.
- Grin lenses can also be used for a downhole coupling. Losses for a coupling system based on Grin lenses with a diameter of 1.8mm are not reported by ThorLabs.
- Collimated signal transfer would require an optical window that is a pressure barrier. Since physical properties of steel and glass are both well known, it is possible to design a reliable glass-to-metal seal.
- Signal transfer may require a window with a diameter of no more than 2mm if Grin lenses can be used.
- the thickness of this window is optically irrelevant.
- Shear failure of the glass can be prevented by using glass with an optimized crystal structure.
- the signal transfer takes place through a window with the smallest possible area, in order to minimize the force on the seal.
- Axial or non-axial wet-connectable collimated coupling designs may be used in the method and system according to the invention, for example:
- interconnect first and second fiber optical cable sets or bundles may comprise providing a first lens system set that is connected to the first fiber optical cable set or bundle and a providing a second lens system set that is connected to the second fiber optical cable set or bundle .
- the method may be used in methods to monitor and manage production of hydrocarbon fluid in a well or other hydrocarbon fluid production facility comprising: - optically interconnecting the fiber optical cables as described herein to form an interconnected fiber optical cable assembly;
- the method according to the invention may be used in methods to monitor and manage production of hydrocarbon fluid in a refinery and/or chemical plant and/or transportation of hydrocarbon fluid in a
- Possible variations of the method and system according to the invention include any variation in mode or modulation of the signal. Further refinement of the optical system, e.g. using prisms and mirrors, is expected to lead to further improvement in system dimensions and pressure rating. Improved optical systems are also expected to allow transmission of multiple optical signals through a single collimated coupler.
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- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Fluid Mechanics (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Mechanical Engineering (AREA)
- Optical Couplings Of Light Guides (AREA)
- Light Guides In General And Applications Therefor (AREA)
Abstract
Description
Claims
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/323,570 US9939588B2 (en) | 2014-07-07 | 2015-07-03 | Interconnecting optical fibers at a hydrocarbon fluid production facility |
| GB1621792.9A GB2542719A (en) | 2014-07-07 | 2015-07-03 | Interconnecting optical fibers at a hydrocarbon fluid production facility |
| BR112016030752-6A BR112016030752B1 (en) | 2014-07-07 | 2015-07-03 | SYSTEM AND METHOD FOR OPTICALLY INTERCONNECTING FIBER OPTIC CABLES IN A HYDROCARBON FLUID PRODUCTION FACILITY |
| AU2015286862A AU2015286862B2 (en) | 2014-07-07 | 2015-07-03 | Interconnecting optical fibers at a hydrocarbon fluid production facility |
| CA2954195A CA2954195A1 (en) | 2014-07-07 | 2015-07-03 | Interconnecting optical fibers at a hydrocarbon fluid production facility |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14175937.3 | 2014-07-07 | ||
| EP14175937 | 2014-07-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2016005280A1 true WO2016005280A1 (en) | 2016-01-14 |
Family
ID=51062724
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2015/065187 Ceased WO2016005280A1 (en) | 2014-07-07 | 2015-07-03 | Interconnecting optical fibers at a hydrocarbon fluid production facility |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9939588B2 (en) |
| AU (1) | AU2015286862B2 (en) |
| BR (1) | BR112016030752B1 (en) |
| CA (1) | CA2954195A1 (en) |
| GB (1) | GB2542719A (en) |
| WO (1) | WO2016005280A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3299857A1 (en) * | 2016-09-21 | 2018-03-28 | Siemens Aktiengesellschaft | Fiber-optical subsea connector |
| CN108150153A (en) * | 2016-12-02 | 2018-06-12 | 中国石油天然气股份有限公司 | An anti-instrument drop device for cable testing in oil and gas wells |
| WO2019213081A1 (en) * | 2018-05-01 | 2019-11-07 | Baker Hughes, A Ge Company, Llc | Gas sensor including optic fiber connector |
| US11435252B2 (en) | 2018-05-01 | 2022-09-06 | Baker Hughes, A Ge Company, Llc | Gas sensor system |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11092761B2 (en) * | 2019-12-04 | 2021-08-17 | Baker Hughes Oilfield Operations Llc | Downhole fiber optic connector with fiber channel independent testing apparatus |
| CN117330559B (en) * | 2023-11-29 | 2024-07-05 | 中国科学院深海科学与工程研究所 | Deep sea in-situ Raman spectrometer |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4759601A (en) * | 1985-06-24 | 1988-07-26 | Schlumberger Technology Corporation | Fiber optic connector assembly |
| US20130192851A1 (en) * | 2012-01-26 | 2013-08-01 | Schlumberger Technology Corporation | Providing coupler portions along a structure |
| GB2509052A (en) * | 2012-11-19 | 2014-06-25 | Bercleys Consulting Ltd | Optical fibre connector |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4090572A (en) * | 1976-09-03 | 1978-05-23 | Nygaard-Welch-Rushing Partnership | Method and apparatus for laser treatment of geological formations |
| US4360249A (en) * | 1979-10-17 | 1982-11-23 | Tetra-Tech, Inc. | Optical feedthrough for pressure vessels |
| US4682846A (en) * | 1981-11-19 | 1987-07-28 | The United States Of America As Represented By The Secretary Of The Navy | Hermetic high pressure fiber optic bulkhead penetrator |
| US4666242A (en) * | 1984-06-21 | 1987-05-19 | Lockheed Corporation | Underwater electro-optical connector including cable terminal unit with electro-optical probe |
| US4994671A (en) | 1987-12-23 | 1991-02-19 | Schlumberger Technology Corporation | Apparatus and method for analyzing the composition of formation fluids |
| DE10261108A1 (en) * | 2002-12-20 | 2004-07-01 | Volkswagen Ag | Arrangement for coupling optical cables has base and counter plates with mirror systems such that plates are coupled together with light emanating from first cable coupled into second and vice-versa |
| JP2009217062A (en) * | 2008-03-11 | 2009-09-24 | Mitsutoyo Corp | Vacuum optical fiber connector and optical fiber terminal structure |
| US8564768B2 (en) * | 2009-04-17 | 2013-10-22 | Schlumberger Technology Corporation | High pressure and high temperature optical spectroscopy cell using spherical surfaced lenses in direct contact with a fluid pathway |
-
2015
- 2015-07-03 GB GB1621792.9A patent/GB2542719A/en not_active Withdrawn
- 2015-07-03 CA CA2954195A patent/CA2954195A1/en not_active Abandoned
- 2015-07-03 AU AU2015286862A patent/AU2015286862B2/en active Active
- 2015-07-03 WO PCT/EP2015/065187 patent/WO2016005280A1/en not_active Ceased
- 2015-07-03 US US15/323,570 patent/US9939588B2/en active Active
- 2015-07-03 BR BR112016030752-6A patent/BR112016030752B1/en active IP Right Grant
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4759601A (en) * | 1985-06-24 | 1988-07-26 | Schlumberger Technology Corporation | Fiber optic connector assembly |
| US20130192851A1 (en) * | 2012-01-26 | 2013-08-01 | Schlumberger Technology Corporation | Providing coupler portions along a structure |
| GB2509052A (en) * | 2012-11-19 | 2014-06-25 | Bercleys Consulting Ltd | Optical fibre connector |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3299857A1 (en) * | 2016-09-21 | 2018-03-28 | Siemens Aktiengesellschaft | Fiber-optical subsea connector |
| CN108150153A (en) * | 2016-12-02 | 2018-06-12 | 中国石油天然气股份有限公司 | An anti-instrument drop device for cable testing in oil and gas wells |
| CN108150153B (en) * | 2016-12-02 | 2021-08-03 | 中国石油天然气股份有限公司 | An anti-drop device for cable testing instruments in oil and gas wells |
| WO2019213081A1 (en) * | 2018-05-01 | 2019-11-07 | Baker Hughes, A Ge Company, Llc | Gas sensor including optic fiber connector |
| GB2587986A (en) * | 2018-05-01 | 2021-04-14 | Baker Hughes Holdings Llc | Gas sensor including optic fiber connector |
| US11287408B2 (en) | 2018-05-01 | 2022-03-29 | Baker Hughes, A Ge Company, Llc | Gas sensor including optic fiber connector |
| GB2587986B (en) * | 2018-05-01 | 2022-06-01 | Baker Hughes Holdings Llc | Gas sensor including optic fiber connector |
| US11435252B2 (en) | 2018-05-01 | 2022-09-06 | Baker Hughes, A Ge Company, Llc | Gas sensor system |
| US11609142B2 (en) | 2018-05-01 | 2023-03-21 | Baker Hughes Holdings Llc | Gas sensor system |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2015286862A1 (en) | 2016-12-22 |
| US20170139147A1 (en) | 2017-05-18 |
| GB2542719A (en) | 2017-03-29 |
| AU2015286862B2 (en) | 2018-01-04 |
| CA2954195A1 (en) | 2016-01-14 |
| US9939588B2 (en) | 2018-04-10 |
| BR112016030752A2 (en) | 2017-08-22 |
| GB201621792D0 (en) | 2017-02-01 |
| BR112016030752B1 (en) | 2022-09-06 |
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