WO2015179752A1 - Austempering of structural components - Google Patents
Austempering of structural components Download PDFInfo
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- WO2015179752A1 WO2015179752A1 PCT/US2015/032158 US2015032158W WO2015179752A1 WO 2015179752 A1 WO2015179752 A1 WO 2015179752A1 US 2015032158 W US2015032158 W US 2015032158W WO 2015179752 A1 WO2015179752 A1 WO 2015179752A1
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- Prior art keywords
- steel material
- carbon steel
- medium carbon
- microstructure
- component
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Classifications
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/50—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for welded joints
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
- C21D1/20—Isothermal quenching, e.g. bainitic hardening
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0068—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
Definitions
- the invention relates generally to structural steel components for automotive vehicles and trucks, and methods for manufacturing the structural steel components.
- Structural components for automotive vehicles and trucks including light, medium, and heavy-duty trucks, are oftentimes formed from hot stamped steel, ultra high strength steel (UHSS), advanced high strength steel (AHSS), high strength steel (HSS), or cast iron.
- UHSS ultra high strength steel
- AHSS advanced high strength steel
- HSS high strength steel
- cast iron cast iron
- HSS materials are cost effective, easier to form, and can provide good ductility, but provide limited strength.
- additional forming and joining multiple components into a finished assembly will impart residual stresses that may be detrimental to the performance of the assembly.
- Components formed of cast iron also tend to be costly and heavy compared to formed steel.
- the invention provides a method of manufacturing a structural steel component for an automotive vehicle or truck, for example a light, medium, or heavy-duty truck.
- the structural component has exceptional strength, reduced mass, and potentially reduced manufacturing costs, compared to structural components formed from ultra-high strength steel (UHSS), advanced high strength steel (AHSS), high strength steel (HSS), or cast iron.
- UHSS ultra-high strength steel
- AHSS advanced high strength steel
- HSS high strength steel
- cast iron cast iron.
- the structural steel component is formed from a medium carbon steel material and can be shaped to form a twist axle, spring link, control arm, pillar, trailer hitch, bumper, body or suspension attachment bracket for a truck frame, or other chassis component, body in white component, or safety-related component.
- the method includes providing a shaped component formed at least partially from a medium carbon steel material; and austempering the shaped component.
- the austempering step includes transforming the microstructure of the medium carbon steel material to a microstructure consisting predominantly of bainite.
- the medium carbon steel material includes 0.2 to 1.0 wt. % carbon (C), 0.1 to 3.0 wt. % manganese (Mn), not greater than 2.0 wt. % silicon (Si), not greater than 0.010 wt. % boron (B), not greater than 0.1 wt. % sulfur (S), and not greater than 0.2 wt. % phosphorous (P), based on the total weight of the medium carbon steel material.
- the invention also provides an austempered structural component for an automotive vehicle or truck comprising a medium carbon steel material having a
- the medium carbon steel material includes 0.2 to 1.0 wt. % carbon (C), 0.1 to 3.0 wt. % manganese (Mn), not greater than 2.0 wt. % silicon (Si), not greater than 0.010 wt. % boron (B), not greater than 0.1 wt.
- the medium carbon steel material is shaped to form a twist axle, spring link, control arm, pillar, trailer hitch, bumper, body or suspension attachment bracket for a truck frame, or other chassis component, body in white component, or safety-related component.
- Figure 1 illustrates a method of manufacturing an austempered structural component according to an example embodiment
- Figure 2 illustrates phases of an example austempering process
- FIG. 3 is a Time Temperate Transformation (TTT) curve of the example austempering process
- Figure 4 illustrates an example upper bainite microstructure
- Figure 5 illustrates an example lower bainite microstructure
- Figure 5A is an enlarged view of a portion of the lower bainite structure shown in Figure 5;
- Figure 6 is a perspective view of a B-pillar formed according to an example embodiment
- Figure 7 is a perspective view of a chassis spring link formed according to an example embodiment
- Figure 8 is a perspective view of a chassis front lower control arm formed according to an example embodiment
- Figure 9 is a perspective view of a trailer hitch formed according to an example embodiment
- Figure 10 is a perspective view of a twist axle assembly formed according to an example embodiment.
- Figure 11 is a perspective view of a suspension attachment bracket for a truck frame formed according to an example embodiment.
- a method of manufacturing an austempered structural steel component for an automotive vehicle or truck for example a light, medium, or heavy-duty truck, according to one example embodiment, is generally shown in Figure 1.
- the structural component can be used as a twist axle, spring link, control arm, pillar, trailer hitch, bumper, body or suspension attachment bracket for a truck frame, or any other type of strength driven chassis component, body in white component, or safety-related component.
- the structural component includes medium carbon steel material formed to a predetermined shape and then austempered to achieve a bainitic micro structure.
- the structural component provides exceptional strength, for example a yield strength ranging from 900 MPa to 1500 MPa, with reduced mass, compared to structural components formed from ultra-high strength steel (UHSS), advanced high strength steel (AHSS), high strength steel (HSS), or cast iron.
- UHSS ultra-high strength steel
- AHSS advanced high strength steel
- HSS high strength steel
- cast iron cast iron
- the structural component can also be manufactured with reduced manufacturing time and potentially lower manufacturing costs, compared to the structural components formed of other types of steel material. Additionally, the austempering process will temper the material, relieving residual stress from the forming and joining operations, and potentially improve the durability performance of the structural component.
- the structural component is manufactured by first providing at least one sheet, blank, or other workpiece formed at least partially of the medium carbon steel material.
- the medium carbon steel material is provided in the form of a coil and then cut into a plurality of sheets, blanks, or workpieces.
- the medium carbon steel material is typically less costly to manufacture, and thus less expensive to purchase than ultra-high strength steel (UHSS), advanced high strength steel (AHSS), high strength steel (HSS), and cast iron.
- the medium carbon steel material includes 0.2 to 1.0 weight percent (wt. %) carbon (C), 0.1 to 3.0 wt. % manganese (Mn), not greater than 2.0 wt. % silicon (Si), not greater than 0.010 wt. % boron (B), not greater than 0.1 wt. % sulfur (S), and not greater than 0.2 wt. % phosphorous (P), based on the total weight of the medium carbon steel material.
- the medium carbon steel material includes 0.25 to 0.45 weight percent (wt. %) carbon (C), 0.4 to 2.0 wt. % manganese (Mn), not greater than 1.0 wt.
- the medium carbon steel material can also include other alloying elements and/or incidental impurities in addition to manganese (Mn), sulfur (S), and phosphorous (P).
- the balance of the composition typically consists of iron (Fe).
- the medium carbon steel material can include iron (Fe) in an amount of at least 50 wt. , or at least 70.0 wt. , or at least 90.0 wt. , based on the total weight of the medium carbon steel material.
- the medium carbon steel material is SAE 1038.
- the SAE 1038 material includes 0.35 to 0.41 wt. % carbon (C), 0.6 to 0.9 wt. % manganese (Mn), 0.07 to 0.6 wt. % silicon (Si), 0.0 to 0.010 wt. % boron (B), not greater than 0.05 wt. % sulfur (S), not greater than 0.04 wt. %
- the medium carbon steel material used to form the structural component could also be referred to as a low to medium carbon steel material.
- the sheet, blank, or workpiece used to form the structural component should have an appropriate size and thickness, which depends on the type of structural component to be formed and its application.
- the method can also include forming the structural component from a plurality of different steel materials, wherein at least one of the steel materials is the medium carbon steel material.
- the second steel material is different from the medium carbon steel material, for example a low carbon steel material, such as SAE 1010, or any UHSS, AHSS, or HSS material.
- the second steel material is not selected to form bainite during the austempering process, like the medium carbon steel material.
- the different steel materials are typically provided as separate sheets, blanks, or workpieces.
- the method includes providing a first blank formed of the medium carbon steel material, specifically SAE 1038, and a second blank formed of the second steel material, specifically SAE 1010 which is a low carbon steel material.
- the different steel materials can be provided in a single sheet, blank, or workpiece.
- the different steel materials can be mixed together, or the different steel materials can form distinct regions of the single sheet, blank, or workpiece.
- the method next includes shaping the at least one sheet, blank, or workpiece to a predetermined shape.
- the predetermined shape is typically selected such that after the austempering process, the structural component can be used in an automotive vehicle or truck application, including light, medium, or heavy-duty truck application.
- the shaping step typically includes stamping, bending, and/or molding the at least one blank, sheet, or workpiece.
- the shaping step can also or alternatively include piercing, pinching, cutting, shearing, and/or any other type of metal forming operation.
- the strength of the medium carbon steel material is relatively low at this point during the manufacturing process, for example, the yield strength typically ranges from 300 to 500 MPa at this point.
- the shaping step can be conducted without heating the medium carbon steel material.
- the medium carbon steel material is easier to form than ultra high strength steel (UHSS), advanced high strength steel (AHSS), and potentially the high strength steel (HSS).
- the method can include forming the separate components independent of one another to achieve distinct shapes, and then joining the shaped components together.
- the joining step typically includes welding, but other types of joining techniques could be used, such as brazing, friction stir welding, or mechanical fastening.
- the two or more sheets, blanks, or workpieces can be joined first and then formed together to achieve a predetermined shape.
- the method includes austempering the shaped component to increase the yield strength of the medium carbon steel material, for example to achieve a yield strength ranging from 900 to 1500 MPa.
- Figure 2 illustrates phases of the austempering process according to one example embodiment
- Figure 3 is a Time Temperate Transformation (TTT) curve of the austempering process according to the example embodiment.
- TTT curve was obtained from The Hand Book on Mechanical Maintenance, available at
- the austempering process first includes heating the shaped component until the medium carbon steel material includes austenite, and typically predominantly austenite.
- the medium carbon steel material is heated until it reaches a fully austenitized state, wherein the microstructure of the steel material consists essentially of austenite.
- the heating step includes heating the shaped component to a temperature above 750° C, for example between 800° C and 950° C.
- the duration of the heating step Tl can vary depending on the type and quantity of steel material used. If the shaped component includes two or more different steel materials, then the heating step is typically conducted until the microstructure of each steel material includes austenite or consists essentially of austenite.
- the heating step can be conducted in an oven.
- the austempering process includes rapidly quenching the shaped component to a predetermine temperature, and maintaining the quenched component at that predetermined temperature until the microstructure of the medium carbon steel material includes bainite.
- the microstructure of the medium carbon steel material consists predominantly of bainite or essentially of bainite by the end of the quenching step. In other words, the majority of the microstructure of the medium carbon steel material is bainite.
- the quenching step is conducted at a rate T2 fast enough to prevent transformation of the austenite microstructure of the medium carbon steel material to another microstructure different from bainite.
- the quenching step is conducted quickly enough to avoid the "nose" region of the TTT curve shown in Figure 3, where an undesired phase transformation would begin.
- the predetermined temperature selected for the quenching step causes the microstructure of the medium carbon steel material to transform from austenite to bainite, and thus the temperature depends on the specific steel material employed.
- the predetermined temperature achieved at the end of the quenching step ranges from 300 to 600° C.
- the quenching step is a batch process conducted in a nitrite and/or nitrate salt bath.
- other quenching techniques can be used, including continuous processing during the part forming process.
- the amount of time T3 that the shaped component is held at the predetermined temperature in the quenching process also varies depending on the type of steel material used.
- the steps of quenching and maintaining the shaped component at the predetermined temperature during the quenching process can cause the austenite of the medium carbon steel material to transform to various different types of bainite
- microstructures depending on the specific temperature and type of medium carbon steel material employed.
- the medium carbon steel material is SAE 1038, either an upper bainite microstructure or a lower bainite microstructure is formed.
- the upper bainite microstructure is also referred to as "feathery bainite.” It comprises very small cementite platelets generally oriented parallel with the long direction of the ferrite needles, and thus the upper bainite microstructure resembles pearlite.
- the upper bainite microstructure also typically provides a hardness around Rockwell C 40. However, the hardness will vary based on the material and the temperature.
- Figure 4 illustrates an example upper bainite microstructure.
- the lower bainite microstructure is also referred to as "acicular bainite.” As the transformation temperature decreases, the ferrite needles become thinner and the carbide platelets become smaller and more closely spaced. The cementite platelets also reorient to an angle relative to the long axis of the ferrite needles.
- the lower bainite microstructure comprises a black needle-like structure and thus resembles martensite.
- the cementite platelets of the lower bainite microstructure are typically oriented at an angle of about 55 degrees relative to the long axis of the ferrite needles.
- the hardness of the lower bainite microstructure is typically around Rockwell C 60. However, the hardness will vary based on the material and the temperature.
- Figure 5 illustrates an example lower bainite microstructure. The photomicrographs used to draft Figures 4 and 5 were obtained from The Hand Book on Mechanical Maintenance, available at
- each material is subjected to the same austempering process.
- each of the different steel materials transforms from an austenitic to a bainitic
- the at least one other steel material present in the shaped component transforms to a microstructure different from the bainitic microstructure.
- the SAE 1038 material transforms from an austenitic microstructure to a lower bainite microstructure while the SAE 1010 material transforms from an austenitic microstructure to a mixed microstructure consisting primarily of ferrite and pearlite, and including a lesser amount of bainite and martensite.
- the shaped component includes the medium carbon steel material mixed with a second steel material different from the medium carbon steel material, and thus the finished structural component includes a mixture of different microstructures.
- the different steel materials present in the shaped component can achieve various other microstructures during the phase transformation step while the medium carbon steel material transforms to the bainitic microstructure.
- the structural component can be coated, painted, and/or shipped as normal.
- the steps of the method of manufacturing the structural component, including the phases of the austempering process, can all be performed at the same geographical location, or can be performed at various different geographical locations.
- the sheets, blanks, or workpieces can be shaped and welded at one location, and then austempered at another location.
- the structural component provided by the present invention includes the medium carbon steel material having the bainitic microstructure, such as an upper bainite or lower bainite microstructure.
- the structural component can include at least one second steel material in addition to and different from the medium carbon which has a microstructure different from the bainitic microstructure.
- the structural component can include the first blank formed of the medium carbon steel material having the bainitic microstructure welded to the second blank formed of the SAE 1010 low carbon steel material having the micro structure which consists consisting primarily of ferrite and pearlite, and including a lesser amount of bainite and martensite.
- the structural component provided by the invention can be used in various different automotive or truck applications, including light, medium, and heavy-duty truck applications.
- the structural component can be used as a twist axle, spring link, control arm, pillar, trailer hitch, bumper, body or suspension attachment bracket for a truck frame, or any other type of strength driven chassis component, body in white component, or safety-related component.
- the structural component also provides exceptional strength, for example a strength ranging from 900 MPa to 1500 MPa, reduced mass, and potentially reduced costs, compared to structural components formed from ultra-high strength steel (UHSS), advanced high strength steel (AHSS), high strength steel (HSS), and cast iron.
- Figures 6-11 illustrate several example structural components 10 each formed at least partially of the austempered medium carbon steel material with the bainitic microstructure.
- the structural component 10 of Figure 6 is a B-pillar formed entirely of the austempered medium carbon steel material with the bainitic microstructure.
- the structural component 10 of Figure 7 is a chassis spring link including first parts 12 formed of the austempered low to medium carbon steel material with the bainitic microstructure and second parts 14 formed of the low carbon steel material with the mixed microstructure.
- the first parts 12 of the spring link are beams and the second parts 14 are bushings.
- the structural component 10 of Figure 8 is a chassis front lower control arm including first parts 12 formed of the austempered low to medium carbon steel material with the bainitic microstructure and second parts 14 formed of the low carbon steel material with the mixed microstructure.
- the first parts 12 of the control arm are wishbone- shaped plates and the second parts 14 are bushings.
- the structural component 10 of Figure 9 is a trailer hitch including a plurality of parts 12 each formed of the austempered low to medium carbon steel material with the bainitic micro structure.
- the parts 12 of the trailer hitch include a tubular arm, mounting brackets, and a receiver tube.
- the structural component 10 of Figure 10 is a twist axle assembly including first parts 12 formed of the austempered low to medium carbon steel material with the bainitic micro structure and second parts 14 formed of the low carbon steel material with the mixed microstructure.
- the first parts 12 of the twist axle assembly include an elongated beam, control arms, spindle brackets, and spring brackets.
- the second parts 14 of the twist axle assembly include conventional connecters and bushings.
- the structural component 10 of Figure 11 is a suspension attachment bracket for a truck frame, such as a light, medium, or heavy-duty truck frame.
- the suspension bracket includes a plurality of parts 12 each formed of the austempered medium carbon steel material with the bainitic microstructure.
- the parts 12 of the suspension attachment bracket are joined together, for example by welding.
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Abstract
An austempered structural steel component for an automotive vehicle, and a method for manufacturing the component, is provided. The structural component can be a twist axle, spring link, control arm, pillar, trailer hitch, bumper, body or suspension attachment bracket for a truck frame, or other chassis, body in white, or safety-related component. The structural component is at least partially formed of medium carbon steel having a bainitic microstructure. The medium carbon steel can include 0.2 to 1.0 wt. % carbon, 0.1 to 3.0 wt. % manganese, not greater than 2.0 wt. % silicon, 0.0 to 0.010 wt. % boron, not greater than 0.1 wt. % sulfur, and not greater than 0.2 wt. % phosphorous. The medium carbon steel provides a yield strength of 900 to 1500 MPa. The structural component is also lighter and can potentially be manufactured with reduced costs, compared to structural components formed from other steel materials.
Description
AUSTEMPERING OF STRUCTURAL COMPONENTS
CROSS REFERENCE TO RELATED APPLICATION
[0001] This PCT patent application claims the benefit of and priority to U.S.
Provisional Patent Application Serial No. 62/002,287 filed May 23, 2014 entitled
"Austempering Of Structural Components", the entire disclosure of the application is incorporated herein by reference.
BACKGROUND OF THE INVENTION
1. Field of the Invention
[0002] The invention relates generally to structural steel components for automotive vehicles and trucks, and methods for manufacturing the structural steel components.
2. Related Art
[0003] Structural components for automotive vehicles and trucks, including light, medium, and heavy-duty trucks, are oftentimes formed from hot stamped steel, ultra high strength steel (UHSS), advanced high strength steel (AHSS), high strength steel (HSS), or cast iron. Although the hot stamped components provide high strength, use of the hot stamped components is limited due to low ductility and/or high manufacturing costs. The UHSS and AHSS materials are high cost and are oftentimes difficult to form into the complex shapes required for many automotive vehicle or truck applications. By
comparison, the HSS materials are cost effective, easier to form, and can provide good ductility, but provide limited strength. However, additional forming and joining multiple components into a finished assembly will impart residual stresses that may be detrimental to the performance of the assembly. Components formed of cast iron also tend to be costly and heavy compared to formed steel.
SUMMARY OF THE INVENTION
[0004] The invention provides a method of manufacturing a structural steel component for an automotive vehicle or truck, for example a light, medium, or heavy-duty truck. The structural component has exceptional strength, reduced mass, and potentially reduced manufacturing costs, compared to structural components formed from ultra-high strength steel (UHSS), advanced high strength steel (AHSS), high strength steel (HSS), or cast iron. The structural steel component is formed from a medium carbon steel material and can be shaped to form a twist axle, spring link, control arm, pillar, trailer hitch, bumper, body or suspension attachment bracket for a truck frame, or other chassis component, body in white component, or safety-related component.
[0005] According to one embodiment, the method includes providing a shaped component formed at least partially from a medium carbon steel material; and austempering the shaped component. The austempering step includes transforming the microstructure of the medium carbon steel material to a microstructure consisting predominantly of bainite.
[0006] Another embodiment provides a method of manufacturing an austempered structural component for an automotive vehicle or truck formed at least partially from a medium carbon steel material having a microstructure which includes bainite. In this embodiment, the medium carbon steel material includes 0.2 to 1.0 wt. % carbon (C), 0.1 to 3.0 wt. % manganese (Mn), not greater than 2.0 wt. % silicon (Si), not greater than 0.010 wt. % boron (B), not greater than 0.1 wt. % sulfur (S), and not greater than 0.2 wt. % phosphorous (P), based on the total weight of the medium carbon steel material.
[0007] The invention also provides an austempered structural component for an automotive vehicle or truck comprising a medium carbon steel material having a
microstructure consisting predominantly of bainite.
[0008] Another embodiment provides an austempered structural component for an automotive vehicle or truck comprising a medium carbon steel material and having a microstructure which includes bainite. In this embodiment, the medium carbon steel material includes 0.2 to 1.0 wt. % carbon (C), 0.1 to 3.0 wt. % manganese (Mn), not greater than 2.0 wt. % silicon (Si), not greater than 0.010 wt. % boron (B), not greater than 0.1 wt.
% sulfur (S), and not greater than 0.2 wt. % phosphorous (P), based on the total weight of the medium carbon steel material. The medium carbon steel material is shaped to form a twist axle, spring link, control arm, pillar, trailer hitch, bumper, body or suspension attachment bracket for a truck frame, or other chassis component, body in white component, or safety-related component.
BRIEF DESCRIPTION OF THE DRAWINGS
[0009] Other advantages of the present invention will be readily appreciated, as the same becomes better understood by reference to the following detailed description when considered in connection with the accompanying drawings wherein:
[0010] Figure 1 illustrates a method of manufacturing an austempered structural component according to an example embodiment;
[0011] Figure 2 illustrates phases of an example austempering process;
[0012] Figure 3 is a Time Temperate Transformation (TTT) curve of the example austempering process;
[0013] Figure 4 illustrates an example upper bainite microstructure;
[0014] Figure 5 illustrates an example lower bainite microstructure;
[0015] Figure 5A is an enlarged view of a portion of the lower bainite structure shown in Figure 5;
[0016] Figure 6 is a perspective view of a B-pillar formed according to an example embodiment;
[0017] Figure 7 is a perspective view of a chassis spring link formed according to an example embodiment;
[0018] Figure 8 is a perspective view of a chassis front lower control arm formed according to an example embodiment;
[0019] Figure 9 is a perspective view of a trailer hitch formed according to an example embodiment;
[0020] Figure 10 is a perspective view of a twist axle assembly formed according to an example embodiment; and
[0021] Figure 11 is a perspective view of a suspension attachment bracket for a truck frame formed according to an example embodiment.
DESCRIPTION OF THE EXAMPLE EMBODIMENTS
[0022] A method of manufacturing an austempered structural steel component for an automotive vehicle or truck, for example a light, medium, or heavy-duty truck, according to one example embodiment, is generally shown in Figure 1. The structural component can be used as a twist axle, spring link, control arm, pillar, trailer hitch, bumper, body or suspension attachment bracket for a truck frame, or any other type of strength driven chassis component, body in white component, or safety-related component. The structural component includes medium carbon steel material formed to a predetermined shape and then austempered to achieve a bainitic micro structure. The structural component provides exceptional strength, for example a yield strength ranging from 900 MPa to 1500 MPa, with reduced mass, compared to structural components formed from ultra-high strength steel (UHSS), advanced high strength steel (AHSS), high strength steel (HSS), or cast iron. The structural component can also be manufactured with reduced manufacturing time and potentially lower manufacturing costs, compared to the structural components formed of other types of steel material. Additionally, the austempering process will temper the
material, relieving residual stress from the forming and joining operations, and potentially improve the durability performance of the structural component.
[0023] The structural component is manufactured by first providing at least one sheet, blank, or other workpiece formed at least partially of the medium carbon steel material. In one embodiment, the medium carbon steel material is provided in the form of a coil and then cut into a plurality of sheets, blanks, or workpieces. The medium carbon steel material is typically less costly to manufacture, and thus less expensive to purchase than ultra-high strength steel (UHSS), advanced high strength steel (AHSS), high strength steel (HSS), and cast iron.
[0024] In one example embodiment, the medium carbon steel material includes 0.2 to 1.0 weight percent (wt. %) carbon (C), 0.1 to 3.0 wt. % manganese (Mn), not greater than 2.0 wt. % silicon (Si), not greater than 0.010 wt. % boron (B), not greater than 0.1 wt. % sulfur (S), and not greater than 0.2 wt. % phosphorous (P), based on the total weight of the medium carbon steel material. In another example, the medium carbon steel material includes 0.25 to 0.45 weight percent (wt. %) carbon (C), 0.4 to 2.0 wt. % manganese (Mn), not greater than 1.0 wt. % silicon (Si), not greater than 0.010 wt. % boron (B), not greater than 0.05 wt. % sulfur (S), and not greater than 0.1 wt. % phosphorous (P), based on the total weight of the medium carbon steel material. The medium carbon steel material can also include other alloying elements and/or incidental impurities in addition to manganese (Mn), sulfur (S), and phosphorous (P). The balance of the composition typically consists of iron (Fe). For example, the medium carbon steel material can include iron (Fe) in an amount of at least 50 wt. , or at least 70.0 wt. , or at least 90.0 wt. , based on the total weight of the medium carbon steel material. In another example embodiment, the medium carbon steel material is SAE 1038. The SAE 1038 material includes 0.35 to 0.41 wt. % carbon (C), 0.6 to 0.9 wt. % manganese (Mn), 0.07 to 0.6 wt. % silicon (Si), 0.0 to 0.010 wt.
% boron (B), not greater than 0.05 wt. % sulfur (S), not greater than 0.04 wt. %
phosphorous (P) or not greater than 0.03 wt. % phosphorous (P), and a balance of iron (Fe). Table 1 below provides three example steel compositions that can be used as the medium carbon steel material.
Table 1
[0025] The medium carbon steel material used to form the structural component could also be referred to as a low to medium carbon steel material. The sheet, blank, or workpiece used to form the structural component should have an appropriate size and thickness, which depends on the type of structural component to be formed and its application.
[0026] The method can also include forming the structural component from a plurality of different steel materials, wherein at least one of the steel materials is the medium carbon steel material. The second steel material is different from the medium carbon steel material, for example a low carbon steel material, such as SAE 1010, or any UHSS, AHSS, or HSS material. The second steel material is not selected to form bainite during the austempering process, like the medium carbon steel material. The different steel materials are typically provided as separate sheets, blanks, or workpieces. In one example
embodiment, the method includes providing a first blank formed of the medium carbon steel material, specifically SAE 1038, and a second blank formed of the second steel material, specifically SAE 1010 which is a low carbon steel material. Alternatively, the different steel materials can be provided in a single sheet, blank, or workpiece. For example, the different steel materials can be mixed together, or the different steel materials can form distinct regions of the single sheet, blank, or workpiece.
[0027] The method next includes shaping the at least one sheet, blank, or workpiece to a predetermined shape. The predetermined shape is typically selected such that after the austempering process, the structural component can be used in an automotive vehicle or truck application, including light, medium, or heavy-duty truck application. The shaping step typically includes stamping, bending, and/or molding the at least one blank, sheet, or workpiece. However, the shaping step can also or alternatively include piercing, pinching, cutting, shearing, and/or any other type of metal forming operation. The strength of the medium carbon steel material is relatively low at this point during the manufacturing process, for example, the yield strength typically ranges from 300 to 500 MPa at this point. Thus, the shaping step can be conducted without heating the medium carbon steel material. In other words, the medium carbon steel material is easier to form than ultra high strength steel (UHSS), advanced high strength steel (AHSS), and potentially the high strength steel (HSS).
[0028] If two or more sheets, blanks, or workpieces are used to form the structural component, then the method can include forming the separate components independent of one another to achieve distinct shapes, and then joining the shaped components together. The joining step typically includes welding, but other types of joining techniques could be used, such as brazing, friction stir welding, or mechanical fastening. Alternatively, the two
or more sheets, blanks, or workpieces can be joined first and then formed together to achieve a predetermined shape.
[0029] After the shaping and possible joining steps, the method includes austempering the shaped component to increase the yield strength of the medium carbon steel material, for example to achieve a yield strength ranging from 900 to 1500 MPa. Figure 2 illustrates phases of the austempering process according to one example embodiment, and Figure 3 is a Time Temperate Transformation (TTT) curve of the austempering process according to the example embodiment. The TTT curve was obtained from The Hand Book on Mechanical Maintenance, available at
http ://practicalmaintenance.net/?p= 1345. The process is typically conducted in an inert atmosphere to prevent scaling along the shaped component. When the shaped component includes two or more different steel materials, the different steel materials are subjected to the same austempering process, at the same time.
[0030] The austempering process first includes heating the shaped component until the medium carbon steel material includes austenite, and typically predominantly austenite. Preferably, the medium carbon steel material is heated until it reaches a fully austenitized state, wherein the microstructure of the steel material consists essentially of austenite. Typically, the heating step includes heating the shaped component to a temperature above 750° C, for example between 800° C and 950° C. The duration of the heating step Tl can vary depending on the type and quantity of steel material used. If the shaped component includes two or more different steel materials, then the heating step is typically conducted until the microstructure of each steel material includes austenite or consists essentially of austenite. The heating step can be conducted in an oven.
[0031] Once the at least one steel material of the shaped component is austenitized, the austempering process includes rapidly quenching the shaped component to a
predetermine temperature, and maintaining the quenched component at that predetermined temperature until the microstructure of the medium carbon steel material includes bainite. Preferably, the microstructure of the medium carbon steel material consists predominantly of bainite or essentially of bainite by the end of the quenching step. In other words, the majority of the microstructure of the medium carbon steel material is bainite. The quenching step is conducted at a rate T2 fast enough to prevent transformation of the austenite microstructure of the medium carbon steel material to another microstructure different from bainite. Preferably, the quenching step is conducted quickly enough to avoid the "nose" region of the TTT curve shown in Figure 3, where an undesired phase transformation would begin.
[0032] The predetermined temperature selected for the quenching step causes the microstructure of the medium carbon steel material to transform from austenite to bainite, and thus the temperature depends on the specific steel material employed. Typically, the predetermined temperature achieved at the end of the quenching step ranges from 300 to 600° C. In the example embodiment, the quenching step is a batch process conducted in a nitrite and/or nitrate salt bath. However, other quenching techniques can be used, including continuous processing during the part forming process. The amount of time T3 that the shaped component is held at the predetermined temperature in the quenching process also varies depending on the type of steel material used.
[0033] The steps of quenching and maintaining the shaped component at the predetermined temperature during the quenching process can cause the austenite of the medium carbon steel material to transform to various different types of bainite
microstructures, depending on the specific temperature and type of medium carbon steel material employed. In the example embodiment wherein the medium carbon steel material
is SAE 1038, either an upper bainite microstructure or a lower bainite microstructure is formed.
[0034] The upper bainite microstructure is also referred to as "feathery bainite." It comprises very small cementite platelets generally oriented parallel with the long direction of the ferrite needles, and thus the upper bainite microstructure resembles pearlite. The upper bainite microstructure also typically provides a hardness around Rockwell C 40. However, the hardness will vary based on the material and the temperature. Figure 4 illustrates an example upper bainite microstructure.
[0035] The lower bainite microstructure is also referred to as "acicular bainite." As the transformation temperature decreases, the ferrite needles become thinner and the carbide platelets become smaller and more closely spaced. The cementite platelets also reorient to an angle relative to the long axis of the ferrite needles. The lower bainite microstructure comprises a black needle-like structure and thus resembles martensite. The cementite platelets of the lower bainite microstructure are typically oriented at an angle of about 55 degrees relative to the long axis of the ferrite needles. The hardness of the lower bainite microstructure is typically around Rockwell C 60. However, the hardness will vary based on the material and the temperature. Figure 5 illustrates an example lower bainite microstructure. The photomicrographs used to draft Figures 4 and 5 were obtained from The Hand Book on Mechanical Maintenance, available at
http ://practicalmaintenance.net/?p= 1345.
[0036] When the shaped component is formed of two or more different steel materials, each material is subjected to the same austempering process. In one embodiment, each of the different steel materials transforms from an austenitic to a bainitic
microstructure. In another embodiment, while the medium carbon steel material transforms to the bainitic microstructure, the at least one other steel material present in the shaped
component transforms to a microstructure different from the bainitic microstructure. For example, during the phase transformation of the first blank formed of SAE 1038 joined to the second blank formed of SAE 1010, the SAE 1038 material transforms from an austenitic microstructure to a lower bainite microstructure while the SAE 1010 material transforms from an austenitic microstructure to a mixed microstructure consisting primarily of ferrite and pearlite, and including a lesser amount of bainite and martensite. In another embodiment, the shaped component includes the medium carbon steel material mixed with a second steel material different from the medium carbon steel material, and thus the finished structural component includes a mixture of different microstructures. The different steel materials present in the shaped component can achieve various other microstructures during the phase transformation step while the medium carbon steel material transforms to the bainitic microstructure.
[0037] After the microstructure transformation is complete, the structural component can be coated, painted, and/or shipped as normal. The steps of the method of manufacturing the structural component, including the phases of the austempering process, can all be performed at the same geographical location, or can be performed at various different geographical locations. For example, the sheets, blanks, or workpieces can be shaped and welded at one location, and then austempered at another location.
[0038] The structural component provided by the present invention includes the medium carbon steel material having the bainitic microstructure, such as an upper bainite or lower bainite microstructure. As discussed above, the structural component can include at least one second steel material in addition to and different from the medium carbon which has a microstructure different from the bainitic microstructure. For example, the structural component can include the first blank formed of the medium carbon steel material having the bainitic microstructure welded to the second blank formed of the SAE 1010 low carbon
steel material having the micro structure which consists consisting primarily of ferrite and pearlite, and including a lesser amount of bainite and martensite.
[0039] The structural component provided by the invention can be used in various different automotive or truck applications, including light, medium, and heavy-duty truck applications. For example, the structural component can be used as a twist axle, spring link, control arm, pillar, trailer hitch, bumper, body or suspension attachment bracket for a truck frame, or any other type of strength driven chassis component, body in white component, or safety-related component. The structural component also provides exceptional strength, for example a strength ranging from 900 MPa to 1500 MPa, reduced mass, and potentially reduced costs, compared to structural components formed from ultra-high strength steel (UHSS), advanced high strength steel (AHSS), high strength steel (HSS), and cast iron. Figures 6-11 illustrate several example structural components 10 each formed at least partially of the austempered medium carbon steel material with the bainitic microstructure.
[0040] The structural component 10 of Figure 6 is a B-pillar formed entirely of the austempered medium carbon steel material with the bainitic microstructure.
[0041] The structural component 10 of Figure 7 is a chassis spring link including first parts 12 formed of the austempered low to medium carbon steel material with the bainitic microstructure and second parts 14 formed of the low carbon steel material with the mixed microstructure. The first parts 12 of the spring link are beams and the second parts 14 are bushings.
[0042] The structural component 10 of Figure 8 is a chassis front lower control arm including first parts 12 formed of the austempered low to medium carbon steel material with the bainitic microstructure and second parts 14 formed of the low carbon steel material with the mixed microstructure. The first parts 12 of the control arm are wishbone- shaped plates and the second parts 14 are bushings.
[0043] The structural component 10 of Figure 9 is a trailer hitch including a plurality of parts 12 each formed of the austempered low to medium carbon steel material with the bainitic micro structure. The parts 12 of the trailer hitch include a tubular arm, mounting brackets, and a receiver tube.
[0044] The structural component 10 of Figure 10 is a twist axle assembly including first parts 12 formed of the austempered low to medium carbon steel material with the bainitic micro structure and second parts 14 formed of the low carbon steel material with the mixed microstructure. The first parts 12 of the twist axle assembly include an elongated beam, control arms, spindle brackets, and spring brackets. The second parts 14 of the twist axle assembly include conventional connecters and bushings.
[0045] The structural component 10 of Figure 11 is a suspension attachment bracket for a truck frame, such as a light, medium, or heavy-duty truck frame. The suspension bracket includes a plurality of parts 12 each formed of the austempered medium carbon steel material with the bainitic microstructure. The parts 12 of the suspension attachment bracket are joined together, for example by welding.
[0046] Obviously, many modifications and variations of the present invention are possible in light of the above teachings and may be practiced otherwise than as specifically described while within the scope of the following claims.
Claims
Claim 1. A method of manufacturing a structural component for an automotive vehicle or truck, comprising the steps of:
providing a shaped component formed at least partially from a medium carbon steel material; and
austempering the shaped component, wherein the austempering step includes transforming the microstructure of the medium carbon steel material to a microstructure consisting predominantly of bainite.
Claim 2. The method of Claim 1, wherein the medium carbon steel material includes 0.2 to 1.0 wt. % carbon (C), 0.1 to 3.0 wt. % manganese (Mn), not greater than 2.0 wt. % silicon (Si), not greater than 0.010 wt. % boron, not greater than 0.1 wt. % sulfur (S), and not greater than 0.2 wt. % phosphorous (P), based on the total weight of the medium carbon steel material.
Claim 3. The method of Claim 2, wherein the medium carbon steel material includes 0.25 to 0.45 wt. % carbon (C), 0.4 to 2.0 wt. % manganese (Mn), not greater than 1.0 wt. % silicon (Si), not greater than 0.01 wt. % boron (B), not greater than 0.05 wt. % sulfur (S), and not greater than 0.1 wt. % phosphorous (P), based on the total weight of the medium carbon steel material.
Claim 4. The method of Claim 1, wherein the austempering step includes heating the shaped component until the microstructure of the medium carbon steel material includes austenite, and quenching the heated shaped component until the microstructure of
the medium carbon steel material transforms to the microstructure consisting predominantly of bainite.
Claim 5. The method of Claim 4, wherein the heating step includes heating the medium carbon steel material to a temperature above 750° C, and the quenching step includes cooling the medium carbon steel material to a temperature of 300 to 600° C.
Claim 6. The method of Claim 1, wherein the shaped component is partially formed of at least one second steel material different from the medium carbon steel material.
Claim 7. The method of Claim 6, wherein the step of providing the shaped component includes mixing the medium carbon steel material and the at least one second steel material to provide a single workpiece, and shaping the single workpiece.
Claim 8. The method of Claim 6, wherein the step of providing the shaped component includes providing a first workpiece formed of the medium carbon steel material, providing a second workpiece formed of the at least one second steel material, and joining the workpieces together.
Claim 9. The method of Claim 6, wherein the austempering step includes heating the medium carbon steel material and the at least one second steel material together until the microstructure of both steel materials includes austenite, and quenching the medium carbon steel material and the at least one second steel material together until the medium carbon steel material has a microstructure consisting predominantly of bainite and
the at least one second steel material has a microstructure different from the microstructure consisting predominantly of bainite.
Claim 10. The method of Claim 1, wherein the step of providing the shaped component includes providing a workpiece formed at least partially from the medium carbon steel material, and shaping the workpiece to the shape of a twist axle, spring link, control arm, pillar, trailer hitch, bumper, body or suspension attachment bracket, or other chassis, body in white, or safety-related component.
Claim 11. The method of Claim 1, wherein the step of providing the shaped component includes providing a workpiece formed at least partially from the medium carbon steel material and shaping the workpiece to the shape of a twist axle, spring link, control arm, pillar, trailer hitch, bumper, body or suspension attachment bracket, or other chassis, body in white, or safety-related component;
the medium carbon steel material includes 0.25 to 0.45 wt. % carbon (C), 0.4 to 2.0 wt. % manganese (Mn), not greater than 1.0 wt. % silicon (Si), not greater than 0.01 wt. % boron (B), not greater than 0.05 wt. % sulfur (S), and not greater than 0.1 wt. %
phosphorous (P), based on the total weight of the medium carbon steel material;
the austempering step includes heating the shaped component to a temperature above 750° C in an oven until the microstructure of the medium carbon steel material consists essentially of austenite;
the austempering step further includes quenching the heated shaped component to a temperature of 300 to 600° C in a nitrite and/or nitrate salt bath, and holding the quenched shaped component at a temperature of 300 to 600° C until the microstructure of the medium
carbon steel material transforms from the microstructure consisting essentially of austenite to the microstructure consisting predominantly of bainite; and
the microstructure consisting predominantly of bainite includes at least one of upper bainite and lower bainite.
Claim 12. A method of manufacturing a structural component for an automotive vehicle or truck, comprising the steps of:
providing a shaped component formed at least partially from a medium carbon steel material, the medium carbon steel material including 0.2 to 1.0 wt. % carbon (C), 0.1 to 3.0 wt. % manganese (Mn), not greater than 2.0 wt. % silicon (Si), not greater than 0.010 wt. % boron (B), not greater than 0.1 wt. % sulfur (S), and not greater than 0.2 wt. % phosphorous (P), based on the total weight of the medium carbon steel material; and
austempering the shaped component, wherein the austempering step includes transforming the microstructure of the medium carbon steel material to a microstructure including bainite.
Claim 13. The method of Claim 12, wherein the medium carbon steel material includes 0.25 to 0.45 wt. % carbon (C), 0.4 to 2.0 wt. % manganese (Mn), not greater than 1.0 wt. % silicon (Si), not greater than 0.01 wt. % boron (B), not greater than 0.05 wt. % sulfur (S), and not greater than 0.1 wt. % phosphorous (P), based on the total weight of the medium carbon steel material.
Claim 14. A structural component for an automotive vehicle or truck, comprising:
a medium carbon steel material, the medium carbon steel material being
austempered and having a microstructure consisting predominantly of bainite.
Claim 15. The structural component of Claim 14, wherein the medium carbon steel material includes 0.2 to 1.0 wt. % carbon (C), 0.1 to 3.0 wt. % manganese (Mn), not greater than 2.0 wt. % silicon (Si), 0.0 to 0.010 wt. % boron (B), not greater than 0.1 wt. % sulfur (S), and not greater than 0.2 wt. % phosphorous (P), based on the total weight of the medium carbon steel material.
Claim 16. The structural component of Claim 15, wherein the medium carbon steel material includes 0.25 to 0.45 wt. % carbon (C), 0.4 to 2.0 wt. % manganese (Mn), not greater than 1.0 wt. % silicon (Si), 0.0 to 0.010 wt. % boron (B), not greater than 0.05 wt. % sulfur (S), and not greater than 0.1 wt. % phosphorous (P), based on the total weight of the medium carbon steel material.
Claim 17. The structural component of Claim 14, wherein the medium carbon steel material is shaped to form a twist axle, spring link, control arm, pillar, trailer hitch, bumper, body or suspension attachment bracket, or other chassis, body in white, or safety- related component.
Claim 18. The structural component of Claim 14 further including at least one second steel material different from the medium carbon steel material.
Claim 19. The structural component of Claim 18, wherein the at least one second steel material is mixed with the medium carbon steel material.
Claim 20. The structural component of Claim 18, wherein the at least one second steel material is joined to the medium carbon steel material.
Claim 21. The structural component of Claim 18, wherein the at least one second steel material has a micro structure different from the micro structure of the medium carbon steel material consisting predominantly of bainite.
Claim 22. A structural component for an automotive vehicle or truck, comprising:
a medium carbon steel material including 0.2 to 1.0 wt. % carbon (C), 0.1 to 3.0 wt. % manganese (Mn), not greater than 2.0 wt. % silicon (Si), 0.0 to 0.010 wt. % boron (B), not greater than 0.1 wt. % sulfur (S), and not greater than 0.2 wt. % phosphorous (P), based on the total weight of the medium carbon steel material; and
the medium carbon steel material being austempered and having a micro structure including bainite.
Claim 23. The structural component of Claim 22, wherein the medium carbon steel material includes 0.25 to 0.45 wt. % carbon (C), 0.4 to 2.0 wt. % manganese (Mn), not greater than 1.0 wt. % silicon (Si), 0.0 to 0.010 wt. % boron (B), not greater than 0.05 wt. % sulfur (S), and not greater than 0.1 wt. % phosphorous (P), based on the total weight of the medium carbon steel material.
Claim 24. The structural component of Claim 22, wherein the medium carbon steel material is shaped to form a twist axle, spring link, control arm, pillar, trailer hitch, bumper, body or suspension attachment bracket, or other chassis, body in white, or safety- related component.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE112015002421.2T DE112015002421T5 (en) | 2014-05-23 | 2015-05-22 | Annealing structural components |
| US15/312,650 US20170183758A1 (en) | 2014-05-23 | 2015-05-22 | Austempering Of Structural Components |
| CN201580025996.4A CN106460084A (en) | 2014-05-23 | 2015-05-22 | Austempering of structural components |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462002287P | 2014-05-23 | 2014-05-23 | |
| US62/002,287 | 2014-05-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2015179752A1 true WO2015179752A1 (en) | 2015-11-26 |
Family
ID=54554828
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2015/032158 Ceased WO2015179752A1 (en) | 2014-05-23 | 2015-05-22 | Austempering of structural components |
Country Status (4)
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|---|---|
| US (1) | US20170183758A1 (en) |
| CN (1) | CN106460084A (en) |
| DE (1) | DE112015002421T5 (en) |
| WO (1) | WO2015179752A1 (en) |
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| CN107962362A (en) * | 2017-11-23 | 2018-04-27 | 重庆派斯克刀具制造股份有限公司 | A kind of method for improving planing tool cutter hub intensity |
| DE102018216186B3 (en) | 2018-09-21 | 2019-06-27 | Audi Ag | Narrow spring link for the suspension on a motor vehicle |
| CN109355573B (en) * | 2018-12-03 | 2020-08-14 | 东北大学 | A kind of one-steel multi-stage hot-rolled steel plate based on carbon distribution technology and its manufacturing method |
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| US2194872A (en) * | 1937-04-28 | 1940-03-26 | Renault Louis | Manufacture of cylinders and cooling jackets of internal combustion engines |
| US6177205B1 (en) * | 1996-05-24 | 2001-01-23 | Bwg Butzbacher Weichenbau Gmbh | Process for producing a permanent way component and such a component |
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| US3631585A (en) * | 1966-10-17 | 1972-01-04 | North American Rockwell | Method of making a friction-welded drive axle shaft having an annular section of flash metal |
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| CN1230599A (en) * | 1998-03-27 | 1999-10-06 | 李昭奇 | Bainite steel plate spring for vehicle and its heat treatment |
| CN1962122A (en) * | 2005-11-11 | 2007-05-16 | 郭继伟 | Process for manufacturing bimetal compound casting liner plate |
| WO2008042982A2 (en) * | 2006-10-03 | 2008-04-10 | Cola Jr Gary M | Microtreatment of iron-based alloy, apparatus and method therefor, and articles resulting therefrom |
| NL2002248C2 (en) * | 2008-11-24 | 2010-05-26 | Weweler Nv | Hardening of flexible trailing arms. |
| CN102021479B (en) * | 2010-12-13 | 2012-08-01 | 首钢总公司 | Si-containing medium carbon steel and thermal treatment method for Si-containing medium carbon steel to obtain high strength and elasticity |
-
2015
- 2015-05-22 WO PCT/US2015/032158 patent/WO2015179752A1/en not_active Ceased
- 2015-05-22 CN CN201580025996.4A patent/CN106460084A/en active Pending
- 2015-05-22 US US15/312,650 patent/US20170183758A1/en not_active Abandoned
- 2015-05-22 DE DE112015002421.2T patent/DE112015002421T5/en not_active Withdrawn
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2194872A (en) * | 1937-04-28 | 1940-03-26 | Renault Louis | Manufacture of cylinders and cooling jackets of internal combustion engines |
| US6177205B1 (en) * | 1996-05-24 | 2001-01-23 | Bwg Butzbacher Weichenbau Gmbh | Process for producing a permanent way component and such a component |
| US20090302094A1 (en) * | 2005-04-29 | 2009-12-10 | The Timken Company | Welding together low and high carbon steels |
| US20090208773A1 (en) * | 2007-08-24 | 2009-08-20 | Lehigh University | Graded transitions for joining dissimilar metals and methods of fabrication therefor |
| WO2012146812A1 (en) * | 2011-04-29 | 2012-11-01 | Consejo Superior De Investigaciones Científicas (Csic) | 38mnv6 bainitic steel, method for obtaining same and use thereof |
| WO2013188100A1 (en) * | 2012-05-25 | 2013-12-19 | Cola Gary M | Microtreatment and microstructure of carbide containing iron-based alloy |
Also Published As
| Publication number | Publication date |
|---|---|
| DE112015002421T5 (en) | 2017-05-11 |
| CN106460084A (en) | 2017-02-22 |
| US20170183758A1 (en) | 2017-06-29 |
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