WO2015153082A1 - Continuity compositions and methods of making and using the same - Google Patents
Continuity compositions and methods of making and using the same Download PDFInfo
- Publication number
- WO2015153082A1 WO2015153082A1 PCT/US2015/019679 US2015019679W WO2015153082A1 WO 2015153082 A1 WO2015153082 A1 WO 2015153082A1 US 2015019679 W US2015019679 W US 2015019679W WO 2015153082 A1 WO2015153082 A1 WO 2015153082A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- metal carboxylate
- carboxylate salt
- continuity
- fatty amine
- composition
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0202—Alcohols or phenols
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/02—Anti-static agent incorporated into the catalyst
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Lubricants (AREA)
Abstract
Description
Claims
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2943378A CA2943378C (en) | 2014-04-02 | 2015-03-10 | Continuity compositions and methods of making and using the same |
EP19186307.5A EP3747913B1 (en) | 2014-04-02 | 2015-03-10 | Continuity compositions and olefin polymerisation method using the same |
CN201580017576.1A CN106164104A (en) | 2014-04-02 | 2015-03-10 | Continuity composition and preparation and application thereof |
ES15711025T ES2752705T3 (en) | 2014-04-02 | 2015-03-10 | Continuity compositions and olefin polymerization method using them |
EP15711025.5A EP3126404B1 (en) | 2014-04-02 | 2015-03-10 | Continuity compositions and olefin polymerisation method using the same |
RU2016142913A RU2677897C2 (en) | 2014-04-02 | 2015-03-10 | Continuity compositions and methods of making and using same |
JP2016560525A JP2017512876A (en) | 2014-04-02 | 2015-03-10 | Continuous compositions and methods of making and using them |
US15/301,137 US9676885B2 (en) | 2014-04-02 | 2015-03-10 | Continuity compositions and methods of making and using the same |
CN202210563825.9A CN114957529A (en) | 2014-04-02 | 2015-03-10 | Continuous compositions and methods of making and using the same |
BR112016022780-8A BR112016022780B1 (en) | 2014-04-02 | 2015-03-10 | CONTINUITY COMPOSITION |
US15/586,680 US10035868B2 (en) | 2014-04-02 | 2017-05-04 | Continuity compositions and methods of making and using the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201461974032P | 2014-04-02 | 2014-04-02 | |
US61/974,032 | 2014-04-02 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15/301,137 A-371-Of-International US9676885B2 (en) | 2014-04-02 | 2015-03-10 | Continuity compositions and methods of making and using the same |
US15/586,680 Division US10035868B2 (en) | 2014-04-02 | 2017-05-04 | Continuity compositions and methods of making and using the same |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2015153082A1 true WO2015153082A1 (en) | 2015-10-08 |
Family
ID=52693083
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2015/019679 WO2015153082A1 (en) | 2014-04-02 | 2015-03-10 | Continuity compositions and methods of making and using the same |
Country Status (9)
Country | Link |
---|---|
US (2) | US9676885B2 (en) |
EP (2) | EP3747913B1 (en) |
JP (1) | JP2017512876A (en) |
CN (2) | CN106164104A (en) |
BR (1) | BR112016022780B1 (en) |
CA (1) | CA2943378C (en) |
ES (1) | ES2752705T3 (en) |
RU (1) | RU2677897C2 (en) |
WO (1) | WO2015153082A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019182746A3 (en) * | 2018-03-23 | 2019-11-14 | Univation Technologies, Llc | Catalyst formulations |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2965920T3 (en) * | 2014-04-02 | 2024-04-17 | Univation Tech Llc | Catalyst composition |
BR112019015300B1 (en) | 2017-02-13 | 2023-03-28 | Univation Technologies, Llc | ETHYLENE-BASED POLYMER, PROCESS FOR COPOLYMERIZING ETHYLENE AND ONE OR MORE ALPHA-OLEFINS IN A SINGLE OLEFIN POLYMERIZATION REACTOR AND ARTICLE |
Citations (167)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3221002A (en) | 1963-09-26 | 1965-11-30 | Cabot Corp | Process for polymerization utilizing a surface treated inorganic solid catalyst |
US3231550A (en) | 1964-06-04 | 1966-01-25 | Union Carbide Corp | Olefin polymerization |
US3242099A (en) | 1964-03-27 | 1966-03-22 | Union Carbide Corp | Olefin polymerization catalysts |
US3248179A (en) | 1962-02-26 | 1966-04-26 | Phillips Petroleum Co | Method and apparatus for the production of solid polymers of olefins |
US4077904A (en) | 1976-06-29 | 1978-03-07 | Union Carbide Corporation | Olefin polymerization process and catalyst therefor |
US4115639A (en) | 1971-06-24 | 1978-09-19 | Union Carbide Corporation | Ethylene polymerization with ether modified catalyst |
US4124532A (en) | 1975-03-28 | 1978-11-07 | Montedison S.P.A. | Catalysts for polymerizing olefins |
US4154701A (en) | 1978-05-01 | 1979-05-15 | Standard Oil Company (Indiana) | Olefin polymerization catalyst |
US4159965A (en) | 1976-09-28 | 1979-07-03 | Asahi Kasei Kogyo Kabushiki Kaisha | Catalyst useful for polymerizing olefins |
US4210559A (en) | 1978-10-30 | 1980-07-01 | Standard Oil Company (Indiana) | Catalyst for the preparation of polyalpha-olefins having broad molecular weight distributions |
US4263422A (en) | 1979-12-31 | 1981-04-21 | The Dow Chemical Company | Polymerization of olefins with dual, independently supported catalysts |
US4271060A (en) | 1979-09-17 | 1981-06-02 | Phillips Petroleum Company | Solution polymerization process |
US4302565A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization |
US4302566A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Preparation of ethylene copolymers in fluid bed reactor |
US4325837A (en) | 1980-08-12 | 1982-04-20 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
GB2105355A (en) | 1981-08-24 | 1983-03-23 | Exxon Research Engineering Co | Gas phase method for producing copolymers of ethylene and higher alpha-olefins |
US4482687A (en) | 1979-10-26 | 1984-11-13 | Union Carbide Corporation | Preparation of low-density ethylene copolymers in fluid bed reactor |
US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
US4564605A (en) | 1983-11-23 | 1986-01-14 | Bp Chemicals Limited | Catalyst and process for polymerizing olefins |
US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
US4613484A (en) | 1984-11-30 | 1986-09-23 | Phillips Petroleum Company | Loop reactor settling leg system for separation of solid polymers and liquid diluent |
US4665208A (en) | 1985-07-11 | 1987-05-12 | Exxon Chemical Patents Inc. | Process for the preparation of alumoxanes |
US4672096A (en) | 1984-04-04 | 1987-06-09 | Mobil Oil Corporation | Catalyst composition for polymerizing alpha-olefins |
US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US4721763A (en) | 1982-06-24 | 1988-01-26 | Bp Chemicals Limited | Process for the polymerization and copolymerization of alpha-olefins in fluidized bed |
EP0277004A1 (en) | 1987-01-30 | 1988-08-03 | Exxon Chemical Patents Inc. | Catalysts, method of preparing these catalysts and method of using said catalysts |
EP0277003A1 (en) | 1987-01-30 | 1988-08-03 | Exxon Chemical Patents Inc. | Catalysts, method of preparing these catalysts, and polymerization processes wherein these catalysts are used |
US4874734A (en) | 1987-04-03 | 1989-10-17 | Mitsui Petrochemical Industries, Ltd. | Process for producing solid catalyst for polymerization of olefins |
US4879359A (en) | 1986-12-29 | 1989-11-07 | Bp Chemicals Limited | Process for polymerising ethylene using a chromium oxide catalyst |
US4908463A (en) | 1988-12-05 | 1990-03-13 | Ethyl Corporation | Aluminoxane process |
US4918038A (en) | 1987-10-29 | 1990-04-17 | Union Carbide Chemicals And Plastics Company Inc. | Process for the production of polyethylene with a broad and/or bimodal molecular weight distribution |
US4924018A (en) | 1989-06-26 | 1990-05-08 | Ethyl Corporation | Alkylaluminoxane process |
US4935474A (en) | 1983-06-06 | 1990-06-19 | Exxon Research & Engineering Company | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
US4952540A (en) | 1987-02-14 | 1990-08-28 | Mitsui Petrochemical Industries, Ltd. | Finely divided aluminoxane, process for producing same and its use |
US4960741A (en) | 1988-03-03 | 1990-10-02 | Bp Chemicals Limited | Ziegler-Natta catalyst |
US4968827A (en) | 1989-06-06 | 1990-11-06 | Ethyl Corporation | Alkylaluminoxane process |
EP0416815A2 (en) | 1989-08-31 | 1991-03-13 | The Dow Chemical Company | Constrained geometry addition polymerization catalysts, processes for their preparation, precursors therefor, methods of use, and novel polymers formed therewith |
US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
EP0420436A1 (en) | 1989-09-13 | 1991-04-03 | Exxon Chemical Patents Inc. | Olefin polymerization catalysts |
US5026798A (en) | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
US5028670A (en) | 1988-07-15 | 1991-07-02 | Bp Chemicals Limited | Process for the gas-phase polymerization of olefins in a fluidized-bed reactor |
US5041584A (en) | 1988-12-02 | 1991-08-20 | Texas Alkyls, Inc. | Modified methylaluminoxane |
US5066741A (en) | 1990-03-22 | 1991-11-19 | The Dow Chemical Company | Process for preparation of syndiotactic vinyl aromatic polymers |
US5077255A (en) | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
US5091352A (en) | 1988-09-14 | 1992-02-25 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins |
US5093415A (en) | 1987-05-19 | 1992-03-03 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing stereoregular polymers having a narrow molecular weight distribution |
US5103031A (en) | 1989-02-21 | 1992-04-07 | Ethyl Corporation | Falling film aluminoxane process |
US5124418A (en) | 1985-11-15 | 1992-06-23 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
EP0495375A2 (en) | 1991-01-16 | 1992-07-22 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US5157137A (en) | 1991-07-26 | 1992-10-20 | Ethyl Corporation | Method of making gel free alkylaluminoxane solutions |
EP0516476A2 (en) | 1991-05-29 | 1992-12-02 | Se-Kure Controls, Inc. | Anti-theft sensor |
EP0520732A1 (en) | 1991-06-24 | 1992-12-30 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by ligand abstraction with lewis acids |
US5198400A (en) | 1987-05-20 | 1993-03-30 | Quantum Chemical Corporation | Mixed chromium catalysts and polymerizations utilizing same |
US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US5204419A (en) | 1986-11-20 | 1993-04-20 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing olefins |
US5206197A (en) | 1991-03-04 | 1993-04-27 | The Dow Chemical Company | Catalyst composition for preparation of syndiotactic vinyl aromatic polymers |
US5206199A (en) | 1987-04-20 | 1993-04-27 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
WO1993008221A2 (en) | 1991-10-15 | 1993-04-29 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
US5235081A (en) | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
US5237025A (en) | 1990-10-09 | 1993-08-17 | Phillips Petroleum Company | Process for making bimodal polyolefins using two independent particulate catalysts |
US5236998A (en) | 1991-03-07 | 1993-08-17 | Occidental Chemical Corporation | Process for the manufacture of linear polyethylene containing α-alkene commonomers |
US5241025A (en) | 1987-01-30 | 1993-08-31 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
EP0561476A1 (en) | 1992-03-18 | 1993-09-22 | Akzo Nobel N.V. | Polymethylaluminoxane of enhanced solution stability |
US5248801A (en) | 1992-08-27 | 1993-09-28 | Ethyl Corporation | Preparation of methylaluminoxanes |
EP0570982A1 (en) | 1992-05-22 | 1993-11-24 | Tosoh Corporation | Catalysts and process for producing olefin polymers |
EP0573120A1 (en) | 1992-06-05 | 1993-12-08 | SOLVAY (Société Anonyme) | Process for producing a catalyst system, process for the (co)polymerization of olefins and (co)polymers of at least one olefin |
US5281679A (en) | 1991-11-07 | 1994-01-25 | Exxon Chemical Patents Inc. | Catalyst and method of broadening polymer molecular weight distribution and increasing polymer tensile impact strength and products made thereof |
US5283278A (en) | 1990-04-11 | 1994-02-01 | Bp Chemicals Limited | Gas phase olefin polymerization process |
WO1994007928A1 (en) | 1992-10-02 | 1994-04-14 | The Dow Chemical Company | Supported homogeneous catalyst complexes for olefin polymerization |
EP0594218A1 (en) | 1986-09-24 | 1994-04-27 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing olefins |
US5308815A (en) | 1991-07-26 | 1994-05-03 | Ethyl Corporation | Heterogeneous methylaluminoxane catalyst system |
WO1994010180A1 (en) | 1992-11-02 | 1994-05-11 | Akzo N.V. | Aryloxyaluminoxanes |
US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
US5318935A (en) | 1990-12-27 | 1994-06-07 | Exxon Chemical Patents Inc. | Amido transition metal compound and a catalyst system for the production of isotatic polypropylene |
US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
US5359015A (en) | 1991-11-07 | 1994-10-25 | Exxon Chemical Patents Inc. | Metallocene catalysts and their production and use |
US5384299A (en) | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US5391529A (en) | 1993-02-01 | 1995-02-21 | Albemarle Corporation | Siloxy-aluminoxane compositions, and catalysts which include such compositions with a metallocene |
US5391660A (en) | 1992-01-14 | 1995-02-21 | Nippon Oil Company, Limited | Process for preparing polyolefines |
US5391793A (en) | 1992-11-02 | 1995-02-21 | Akzo Nobel N.V. | Aryloxyaluminoxanes |
US5395810A (en) | 1991-09-30 | 1995-03-07 | Fina Technology, Inc. | Method of making a homogeneous-heterogenous catalyst system for olefin polymerization |
US5405922A (en) | 1993-04-26 | 1995-04-11 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
US5408015A (en) | 1987-12-29 | 1995-04-18 | Mobil Oil Corporation | Mixed chromium catalyst,and alkene and alkyl aluminum hydride-modified ziegler catalyst for multimodal HDPE |
WO1995014044A1 (en) | 1993-11-19 | 1995-05-26 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
US5420090A (en) | 1991-01-18 | 1995-05-30 | The Dow Chemical Company | Silica supported transition metal catalysts |
US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
US5453471A (en) | 1994-08-02 | 1995-09-26 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization process |
US5453410A (en) | 1992-01-06 | 1995-09-26 | The Dow Chemical Company | Catalyst composition |
US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
US5470811A (en) | 1993-08-06 | 1995-11-28 | Exxon Chemical Patents Inc. | Polymerization catalysts, their production and use |
US5473202A (en) | 1992-06-05 | 1995-12-05 | Brian Platner | Control unit for occupancy sensor switching of high efficiency lighting |
US5502124A (en) | 1992-07-01 | 1996-03-26 | Exxon Chemical Patents Inc. | Transition metal olefin polymerization processes |
WO1996011961A1 (en) | 1994-10-13 | 1996-04-25 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
WO1996023010A2 (en) | 1995-01-24 | 1996-08-01 | E.I. Du Pont De Nemours And Company | α-OLEFINS AND OLEFIN POLYMERS AND PROCESSES THEREFOR |
US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
US5616661A (en) | 1995-03-31 | 1997-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling particle growth during production of sticky polymers |
US5627242A (en) | 1996-03-28 | 1997-05-06 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling gas phase fluidized bed polymerization reactor |
WO1997022635A1 (en) | 1995-12-19 | 1997-06-26 | Exxon Chemical Patents Inc. | High temperature olefin polymerization process |
US5648310A (en) | 1993-12-23 | 1997-07-15 | Union Carbide Chemicals & Plastics Technology Corporation | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture |
US5665818A (en) | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
US5668228A (en) | 1993-05-20 | 1997-09-16 | Bp Chemicals Limited | Polymerization process |
EP0634421B1 (en) | 1993-07-13 | 1997-10-08 | Mitsui Petrochemical Industries, Ltd. | Process for gas phase polymerization of olefin |
US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
EP0802203A1 (en) | 1996-04-18 | 1997-10-22 | Repsol Quimica S.A. | Process for obtaining a catalytic system for the polymerization of alpha-olefins in suspension, in gas phase at low and high temperature or in a mass at high pressure and high or low temperature |
US5688880A (en) | 1995-12-11 | 1997-11-18 | The Dow Chemical Company | Readily supportable metal complexes |
US5691264A (en) | 1994-07-08 | 1997-11-25 | Spherilene S.P.A. | Components and catalysts for the polymerization of olefins |
US5693838A (en) | 1995-11-13 | 1997-12-02 | Albemarle Corporation | Aluminoxane process and product |
US5719241A (en) | 1993-04-07 | 1998-02-17 | Fina Research, S.A. | Process for producing polyolefins and polyolefin catalyst |
WO1998007515A1 (en) | 1996-08-19 | 1998-02-26 | Northwestern University | Use of group 13 metal perfluoroaryl fluoro anions in metallocene catalysts for olefin polymerization |
US5723399A (en) | 1995-09-14 | 1998-03-03 | Showa Denko K.K. | Ethylenic polymerization catalyst |
WO1998009996A1 (en) | 1996-09-06 | 1998-03-12 | Hyundai Petrochemical Co., Ltd. | Catalyst system for (co)polymerization of olefins and process for the preparation of olefin (co)polymers using the catalyst system |
US5731451A (en) | 1996-07-12 | 1998-03-24 | Akzo Nobel Nv | Modified polyalkylauminoxane composition formed using reagent containing aluminum trialkyl siloxide |
US5731253A (en) | 1995-07-27 | 1998-03-24 | Albemarle Corporation | Hydrocarbylsilloxy - aluminoxane compositions |
US5744656A (en) | 1996-10-25 | 1998-04-28 | Boulder Scientific Company | Conversion of hexafluorobenzene to bromopentafluorobenzene |
US5747406A (en) | 1997-01-10 | 1998-05-05 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for the production of olefin polymers |
EP0615981B1 (en) | 1993-02-12 | 1998-05-06 | TARGOR GmbH | Supported catalyst system, its preparation and its use in olefin polymerisation |
US5763723A (en) | 1989-08-10 | 1998-06-09 | Phillips Petroleum Company | Chromium compounds and uses thereof |
US5767031A (en) | 1995-06-07 | 1998-06-16 | Fina Technology, Inc. | Ziegler-Natta catalysts modified with metallocenes |
US5770755A (en) | 1994-11-15 | 1998-06-23 | Phillips Petroleum Company | Process to prepare polymeric metallocenes |
WO1998030602A1 (en) | 1997-01-14 | 1998-07-16 | Dsm N.V. | A process for polymerizing olefins |
WO1998030603A1 (en) | 1997-01-14 | 1998-07-16 | Dsm N.V. | A process for polymerizing olefins |
WO1998032775A1 (en) | 1997-01-28 | 1998-07-30 | Borealis A/S | New activator system for metallocene compounds |
EP0781299B1 (en) | 1994-09-12 | 1998-09-09 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
EP0500944B1 (en) | 1990-07-24 | 1998-10-07 | Mitsui Chemicals, Inc. | Catalyst for alpha-olefin polymerization and production of poly-alpha-olefin therewith |
WO1998043983A1 (en) | 1997-04-03 | 1998-10-08 | Colorado State University Research Foundation | Polyhalogenated monoheteroborane anion compositions |
US5847177A (en) | 1996-10-10 | 1998-12-08 | Albemarle Corporation | Production of hydrocarbon-soluble hydrocarbylaluminoxanes |
US5849852A (en) | 1993-05-17 | 1998-12-15 | Solvay Polyolefins Europe--Belgium (Societe Anonyme) | Support for catalysts, process for the manufacture of a precursor gel of a support for catalysts, catalyst for the polymerization of olefins and process for the polymerization of olefins by means of this catalyst |
US5856256A (en) | 1996-02-20 | 1999-01-05 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
US5859653A (en) | 1993-11-25 | 1999-01-12 | Canon Kabushiki Kaisha | Ink jet recording apparatus for maintaining constant distance between recording head and recording medium |
WO1999001460A1 (en) | 1997-07-02 | 1999-01-14 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
EP0891990A2 (en) | 1997-07-15 | 1999-01-20 | Phillips Petroleum Company | High solids slurry polymerization |
EP0893454A1 (en) | 1997-02-07 | 1999-01-27 | Mitsui Chemicals, Inc. | Olefin polymerization catalyst and process for the production of olefin polymers |
US5869723A (en) | 1995-06-08 | 1999-02-09 | Showa Denko K.K. | Ionic compound and olefin polymerization catalyst containing the same |
US5889128A (en) | 1997-04-11 | 1999-03-30 | Massachusetts Institute Of Technology | Living olefin polymerization processes |
WO1999015534A1 (en) | 1997-09-19 | 1999-04-01 | The Dow Chemical Company | Modified alumoxane catalyst activator |
WO1999018135A1 (en) | 1997-10-06 | 1999-04-15 | Targor Gmbh | Catalyst system |
US5942459A (en) | 1995-02-21 | 1999-08-24 | Mitsubishi Chemical Corporation | Catalysts for olefin polymerization and a process for preparing olefin polymers therewith |
WO2000002930A1 (en) * | 1998-07-10 | 2000-01-20 | Univation Technologies Llc | A catalyst composition and methods for its preparation and use in a polymerization process |
US6069213A (en) | 1997-12-16 | 2000-05-30 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed catalyst system |
WO2000069922A2 (en) | 1999-05-17 | 2000-11-23 | Univation Technologies, Llc | Method of polymerization |
WO2001030860A1 (en) | 1999-10-22 | 2001-05-03 | Univation Technologies, Llc | Catalyst systems and their use in a polymerization process |
WO2001030861A1 (en) | 1999-10-22 | 2001-05-03 | Univation Technologies, Llc | Catalyst compositions, methods of polymerization, and polymers therefrom |
US6265338B1 (en) | 1989-09-13 | 2001-07-24 | Exxon Chemical Patents, Inc. | Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin copolymer production catalysts |
US6309997B1 (en) | 1997-04-25 | 2001-10-30 | Mitsui Chemicals, Inc. | Olefin polymerization catalysts, transition metal compounds, processes for olefin polymerization, and α-olefin/conjugated diene copolymers |
US6333389B2 (en) | 1998-12-18 | 2001-12-25 | Univation Technologies, Llc | Olefin polymerization catalysts, their production and use |
WO2002046246A2 (en) | 2000-12-04 | 2002-06-13 | Univaton Technologies, Llc | Polimerization process |
WO2002050088A1 (en) | 2000-12-18 | 2002-06-27 | Univation Technologies, Llc | Preparation of polymerization catalysts |
WO2002050133A2 (en) * | 2000-12-18 | 2002-06-27 | Univation Technologies, Llc | A method for preparing a supported catalyst system and its use in a polymerization process |
WO2004026921A1 (en) | 2002-09-20 | 2004-04-01 | Exxonmobil Chemical Patents Inc. | Polymer production at supercritical conditions |
US6884748B2 (en) | 2002-09-04 | 2005-04-26 | Univation Technologies, Llc | Process for producing fluorinated catalysts |
US6958306B2 (en) | 2003-08-28 | 2005-10-25 | Univation Technologies, Llc | Activated catalyst systems from substituted dialuminoxane complexes |
US20060019925A1 (en) | 2002-11-21 | 2006-01-26 | Kowa Co. Ltd. | Peritoneal dialysis method |
US6995109B2 (en) | 2001-11-30 | 2006-02-07 | Univation Technologies, Llc | Method of making a bimetallic catalyst with higher activity |
WO2006019494A1 (en) | 2004-07-14 | 2006-02-23 | Exxonmobil Chemical Patents Inc. | Polymer production at supercritical conditions |
US7129302B2 (en) | 2000-11-30 | 2006-10-31 | Univation Technologies, Llc | Bimetallic catalyst for producing polyethylene resins with bimodal molecular weight distribution, its preparation and use |
US7157531B2 (en) | 2004-06-21 | 2007-01-02 | Univation Technologies, Llc | Methods for producing polymers with control over composition distribution |
US7169864B2 (en) | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
US7179876B2 (en) | 2001-07-19 | 2007-02-20 | Univation Technologies, Llc | High tear films from hafnocene catalyzed polyethylenes |
WO2007024773A1 (en) | 2005-08-22 | 2007-03-01 | Chevron Phillips Chemical Co Lp | Polymerization catalysts and process for producing bimodal polymers in a single reactor |
US20070055028A1 (en) | 2004-01-07 | 2007-03-08 | Casty Gary L | Preparation of polymerization catalyst activators utilizing indole-modified silica supports |
US20100292418A1 (en) | 2007-12-31 | 2010-11-18 | Dow Global Technologies Inc. | Process for polymerizing olefin-based polymers |
WO2012041811A1 (en) * | 2010-09-28 | 2012-04-05 | Basell Polyolefine Gmbh | Method for feeding an antistatic compound to a polymerization reactor |
WO2012074709A1 (en) | 2010-11-30 | 2012-06-07 | Univation Technologies, Llc | Processes for the polymerization of olefins with extracted metal carboxylate salts |
EP2610269A1 (en) * | 2011-12-28 | 2013-07-03 | Saudi Basic Industries Corporation | Catalyst composition and method for preparing the same |
WO2014011357A1 (en) | 2012-07-13 | 2014-01-16 | Univation Technologies, Llc | Increased polymer melt flow ratio via feed of a supported catalyst saturated with a selected liquid agent |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BRPI0818563B1 (en) * | 2007-10-11 | 2019-10-01 | Univation Technologies, Llc | Catalyst composition, processes for polymerizing olefins, process for producing a catalyst composition and use of a polyoxo-metal carboxylate compound in a catalyst composition |
US8247588B2 (en) * | 2008-10-03 | 2012-08-21 | Univation Technologies, Llc | Catalyst and compositions and methods of making and using the same |
US8985104B2 (en) | 2010-05-19 | 2015-03-24 | Carefusion 207, Inc. | Fan assembly for a rebreathe system |
CA2704934C (en) * | 2010-05-21 | 2018-01-23 | Nova Chemicals Corporation | Supported phosphinimine catalysts for reduced reactor fouling |
BR112013012545B1 (en) * | 2010-11-30 | 2020-04-14 | Univation Tech Llc | catalyst composition, production process of a catalyst composition and polymerization process |
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Patent Citations (181)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3248179A (en) | 1962-02-26 | 1966-04-26 | Phillips Petroleum Co | Method and apparatus for the production of solid polymers of olefins |
US3221002A (en) | 1963-09-26 | 1965-11-30 | Cabot Corp | Process for polymerization utilizing a surface treated inorganic solid catalyst |
US3242099A (en) | 1964-03-27 | 1966-03-22 | Union Carbide Corp | Olefin polymerization catalysts |
US3231550A (en) | 1964-06-04 | 1966-01-25 | Union Carbide Corp | Olefin polymerization |
US4115639A (en) | 1971-06-24 | 1978-09-19 | Union Carbide Corporation | Ethylene polymerization with ether modified catalyst |
US4124532A (en) | 1975-03-28 | 1978-11-07 | Montedison S.P.A. | Catalysts for polymerizing olefins |
US4077904A (en) | 1976-06-29 | 1978-03-07 | Union Carbide Corporation | Olefin polymerization process and catalyst therefor |
US4159965A (en) | 1976-09-28 | 1979-07-03 | Asahi Kasei Kogyo Kabushiki Kaisha | Catalyst useful for polymerizing olefins |
US4302565A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization |
US4302566A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Preparation of ethylene copolymers in fluid bed reactor |
US4154701A (en) | 1978-05-01 | 1979-05-15 | Standard Oil Company (Indiana) | Olefin polymerization catalyst |
US4210559A (en) | 1978-10-30 | 1980-07-01 | Standard Oil Company (Indiana) | Catalyst for the preparation of polyalpha-olefins having broad molecular weight distributions |
US4271060A (en) | 1979-09-17 | 1981-06-02 | Phillips Petroleum Company | Solution polymerization process |
US4482687A (en) | 1979-10-26 | 1984-11-13 | Union Carbide Corporation | Preparation of low-density ethylene copolymers in fluid bed reactor |
US4263422A (en) | 1979-12-31 | 1981-04-21 | The Dow Chemical Company | Polymerization of olefins with dual, independently supported catalysts |
US4325837A (en) | 1980-08-12 | 1982-04-20 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
GB2105355A (en) | 1981-08-24 | 1983-03-23 | Exxon Research Engineering Co | Gas phase method for producing copolymers of ethylene and higher alpha-olefins |
US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
US4721763A (en) | 1982-06-24 | 1988-01-26 | Bp Chemicals Limited | Process for the polymerization and copolymerization of alpha-olefins in fluidized bed |
US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
US4935474A (en) | 1983-06-06 | 1990-06-19 | Exxon Research & Engineering Company | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
US4564605A (en) | 1983-11-23 | 1986-01-14 | Bp Chemicals Limited | Catalyst and process for polymerizing olefins |
US4672096A (en) | 1984-04-04 | 1987-06-09 | Mobil Oil Corporation | Catalyst composition for polymerizing alpha-olefins |
US4613484A (en) | 1984-11-30 | 1986-09-23 | Phillips Petroleum Company | Loop reactor settling leg system for separation of solid polymers and liquid diluent |
US4665208A (en) | 1985-07-11 | 1987-05-12 | Exxon Chemical Patents Inc. | Process for the preparation of alumoxanes |
US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US5124418A (en) | 1985-11-15 | 1992-06-23 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US5183867A (en) | 1986-09-09 | 1993-02-02 | Exxon Chemical Patents Inc. | Polymerization process using a new supported polymerization catalyst |
US5077255A (en) | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
EP0594218A1 (en) | 1986-09-24 | 1994-04-27 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing olefins |
US5204419A (en) | 1986-11-20 | 1993-04-20 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing olefins |
US4879359A (en) | 1986-12-29 | 1989-11-07 | Bp Chemicals Limited | Process for polymerising ethylene using a chromium oxide catalyst |
US5241025A (en) | 1987-01-30 | 1993-08-31 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
EP0277004A1 (en) | 1987-01-30 | 1988-08-03 | Exxon Chemical Patents Inc. | Catalysts, method of preparing these catalysts and method of using said catalysts |
EP0277003A1 (en) | 1987-01-30 | 1988-08-03 | Exxon Chemical Patents Inc. | Catalysts, method of preparing these catalysts, and polymerization processes wherein these catalysts are used |
US5384299A (en) | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
EP0279586B1 (en) | 1987-02-14 | 1994-05-04 | Mitsui Petrochemical Industries, Ltd. | Finely divided aluminoxane, process for producing same and its use |
US4952540A (en) | 1987-02-14 | 1990-08-28 | Mitsui Petrochemical Industries, Ltd. | Finely divided aluminoxane, process for producing same and its use |
US4874734A (en) | 1987-04-03 | 1989-10-17 | Mitsui Petrochemical Industries, Ltd. | Process for producing solid catalyst for polymerization of olefins |
US5206199A (en) | 1987-04-20 | 1993-04-27 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
US5093415A (en) | 1987-05-19 | 1992-03-03 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing stereoregular polymers having a narrow molecular weight distribution |
US5198400A (en) | 1987-05-20 | 1993-03-30 | Quantum Chemical Corporation | Mixed chromium catalysts and polymerizations utilizing same |
US4918038A (en) | 1987-10-29 | 1990-04-17 | Union Carbide Chemicals And Plastics Company Inc. | Process for the production of polyethylene with a broad and/or bimodal molecular weight distribution |
US5408015A (en) | 1987-12-29 | 1995-04-18 | Mobil Oil Corporation | Mixed chromium catalyst,and alkene and alkyl aluminum hydride-modified ziegler catalyst for multimodal HDPE |
US4960741A (en) | 1988-03-03 | 1990-10-02 | Bp Chemicals Limited | Ziegler-Natta catalyst |
US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
US5028670A (en) | 1988-07-15 | 1991-07-02 | Bp Chemicals Limited | Process for the gas-phase polymerization of olefins in a fluidized-bed reactor |
US5091352A (en) | 1988-09-14 | 1992-02-25 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins |
US5041584A (en) | 1988-12-02 | 1991-08-20 | Texas Alkyls, Inc. | Modified methylaluminoxane |
US4908463A (en) | 1988-12-05 | 1990-03-13 | Ethyl Corporation | Aluminoxane process |
US5103031A (en) | 1989-02-21 | 1992-04-07 | Ethyl Corporation | Falling film aluminoxane process |
US4968827A (en) | 1989-06-06 | 1990-11-06 | Ethyl Corporation | Alkylaluminoxane process |
US4924018A (en) | 1989-06-26 | 1990-05-08 | Ethyl Corporation | Alkylaluminoxane process |
US5763723A (en) | 1989-08-10 | 1998-06-09 | Phillips Petroleum Company | Chromium compounds and uses thereof |
US5703187A (en) | 1989-08-31 | 1997-12-30 | The Dow Chemical Company | Pseudo-random copolymers formed by use of constrained geometry addition polymerization catalysts |
EP0416815A2 (en) | 1989-08-31 | 1991-03-13 | The Dow Chemical Company | Constrained geometry addition polymerization catalysts, processes for their preparation, precursors therefor, methods of use, and novel polymers formed therewith |
EP0420436A1 (en) | 1989-09-13 | 1991-04-03 | Exxon Chemical Patents Inc. | Olefin polymerization catalysts |
US5026798A (en) | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
US6265338B1 (en) | 1989-09-13 | 2001-07-24 | Exxon Chemical Patents, Inc. | Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin copolymer production catalysts |
US5066741A (en) | 1990-03-22 | 1991-11-19 | The Dow Chemical Company | Process for preparation of syndiotactic vinyl aromatic polymers |
US5283278A (en) | 1990-04-11 | 1994-02-01 | Bp Chemicals Limited | Gas phase olefin polymerization process |
EP0500944B1 (en) | 1990-07-24 | 1998-10-07 | Mitsui Chemicals, Inc. | Catalyst for alpha-olefin polymerization and production of poly-alpha-olefin therewith |
US5237025A (en) | 1990-10-09 | 1993-08-17 | Phillips Petroleum Company | Process for making bimodal polyolefins using two independent particulate catalysts |
US5318935A (en) | 1990-12-27 | 1994-06-07 | Exxon Chemical Patents Inc. | Amido transition metal compound and a catalyst system for the production of isotatic polypropylene |
EP0495375A2 (en) | 1991-01-16 | 1992-07-22 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
US5420090A (en) | 1991-01-18 | 1995-05-30 | The Dow Chemical Company | Silica supported transition metal catalysts |
US5206197A (en) | 1991-03-04 | 1993-04-27 | The Dow Chemical Company | Catalyst composition for preparation of syndiotactic vinyl aromatic polymers |
US5236998A (en) | 1991-03-07 | 1993-08-17 | Occidental Chemical Corporation | Process for the manufacture of linear polyethylene containing α-alkene commonomers |
EP0516476A2 (en) | 1991-05-29 | 1992-12-02 | Se-Kure Controls, Inc. | Anti-theft sensor |
EP0520732A1 (en) | 1991-06-24 | 1992-12-30 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by ligand abstraction with lewis acids |
US5308815A (en) | 1991-07-26 | 1994-05-03 | Ethyl Corporation | Heterogeneous methylaluminoxane catalyst system |
US5157137A (en) | 1991-07-26 | 1992-10-20 | Ethyl Corporation | Method of making gel free alkylaluminoxane solutions |
US5395810A (en) | 1991-09-30 | 1995-03-07 | Fina Technology, Inc. | Method of making a homogeneous-heterogenous catalyst system for olefin polymerization |
US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
WO1993008221A2 (en) | 1991-10-15 | 1993-04-29 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
US5359015A (en) | 1991-11-07 | 1994-10-25 | Exxon Chemical Patents Inc. | Metallocene catalysts and their production and use |
US5281679A (en) | 1991-11-07 | 1994-01-25 | Exxon Chemical Patents Inc. | Catalyst and method of broadening polymer molecular weight distribution and increasing polymer tensile impact strength and products made thereof |
US5453410A (en) | 1992-01-06 | 1995-09-26 | The Dow Chemical Company | Catalyst composition |
US5391660A (en) | 1992-01-14 | 1995-02-21 | Nippon Oil Company, Limited | Process for preparing polyolefines |
US5329032A (en) | 1992-03-18 | 1994-07-12 | Akzo Chemicals Inc. | Polymethylaluminoxane of enhanced solution stability |
EP0586665B1 (en) | 1992-03-18 | 1998-09-16 | Albemarle Corporation | Method of removing gel forming materials from methylaluminoxanes |
EP0561476A1 (en) | 1992-03-18 | 1993-09-22 | Akzo Nobel N.V. | Polymethylaluminoxane of enhanced solution stability |
US5235081A (en) | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
EP0570982A1 (en) | 1992-05-22 | 1993-11-24 | Tosoh Corporation | Catalysts and process for producing olefin polymers |
EP0573120A1 (en) | 1992-06-05 | 1993-12-08 | SOLVAY (Société Anonyme) | Process for producing a catalyst system, process for the (co)polymerization of olefins and (co)polymers of at least one olefin |
US5473202A (en) | 1992-06-05 | 1995-12-05 | Brian Platner | Control unit for occupancy sensor switching of high efficiency lighting |
US5502124A (en) | 1992-07-01 | 1996-03-26 | Exxon Chemical Patents Inc. | Transition metal olefin polymerization processes |
US5248801A (en) | 1992-08-27 | 1993-09-28 | Ethyl Corporation | Preparation of methylaluminoxanes |
WO1994007928A1 (en) | 1992-10-02 | 1994-04-14 | The Dow Chemical Company | Supported homogeneous catalyst complexes for olefin polymerization |
US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
WO1994010180A1 (en) | 1992-11-02 | 1994-05-11 | Akzo N.V. | Aryloxyaluminoxanes |
US5391793A (en) | 1992-11-02 | 1995-02-21 | Akzo Nobel N.V. | Aryloxyaluminoxanes |
US5939346A (en) | 1992-11-02 | 1999-08-17 | Akzo Nobel N.V. | Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group |
US5391529A (en) | 1993-02-01 | 1995-02-21 | Albemarle Corporation | Siloxy-aluminoxane compositions, and catalysts which include such compositions with a metallocene |
EP0615981B1 (en) | 1993-02-12 | 1998-05-06 | TARGOR GmbH | Supported catalyst system, its preparation and its use in olefin polymerisation |
US5719241A (en) | 1993-04-07 | 1998-02-17 | Fina Research, S.A. | Process for producing polyolefins and polyolefin catalyst |
US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
US5405922A (en) | 1993-04-26 | 1995-04-11 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
US5849852A (en) | 1993-05-17 | 1998-12-15 | Solvay Polyolefins Europe--Belgium (Societe Anonyme) | Support for catalysts, process for the manufacture of a precursor gel of a support for catalysts, catalyst for the polymerization of olefins and process for the polymerization of olefins by means of this catalyst |
EP0802202A1 (en) | 1993-05-20 | 1997-10-22 | BP Chemicals Limited | Fluidized bed polymerization reactor |
US5668228A (en) | 1993-05-20 | 1997-09-16 | Bp Chemicals Limited | Polymerization process |
EP0634421B1 (en) | 1993-07-13 | 1997-10-08 | Mitsui Petrochemical Industries, Ltd. | Process for gas phase polymerization of olefin |
US5470811A (en) | 1993-08-06 | 1995-11-28 | Exxon Chemical Patents Inc. | Polymerization catalysts, their production and use |
WO1995014044A1 (en) | 1993-11-19 | 1995-05-26 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
US5859653A (en) | 1993-11-25 | 1999-01-12 | Canon Kabushiki Kaisha | Ink jet recording apparatus for maintaining constant distance between recording head and recording medium |
US5648310A (en) | 1993-12-23 | 1997-07-15 | Union Carbide Chemicals & Plastics Technology Corporation | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture |
US5691264A (en) | 1994-07-08 | 1997-11-25 | Spherilene S.P.A. | Components and catalysts for the polymerization of olefins |
US5453471B1 (en) | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
US5453471A (en) | 1994-08-02 | 1995-09-26 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization process |
EP0781299B1 (en) | 1994-09-12 | 1998-09-09 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
WO1996011961A1 (en) | 1994-10-13 | 1996-04-25 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
US5770755A (en) | 1994-11-15 | 1998-06-23 | Phillips Petroleum Company | Process to prepare polymeric metallocenes |
WO1996023010A2 (en) | 1995-01-24 | 1996-08-01 | E.I. Du Pont De Nemours And Company | α-OLEFINS AND OLEFIN POLYMERS AND PROCESSES THEREFOR |
US5942459A (en) | 1995-02-21 | 1999-08-24 | Mitsubishi Chemical Corporation | Catalysts for olefin polymerization and a process for preparing olefin polymers therewith |
US5616661A (en) | 1995-03-31 | 1997-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling particle growth during production of sticky polymers |
US5767031A (en) | 1995-06-07 | 1998-06-16 | Fina Technology, Inc. | Ziegler-Natta catalysts modified with metallocenes |
US5869723A (en) | 1995-06-08 | 1999-02-09 | Showa Denko K.K. | Ionic compound and olefin polymerization catalyst containing the same |
US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
US5731253A (en) | 1995-07-27 | 1998-03-24 | Albemarle Corporation | Hydrocarbylsilloxy - aluminoxane compositions |
US5723399A (en) | 1995-09-14 | 1998-03-03 | Showa Denko K.K. | Ethylenic polymerization catalyst |
US5693838A (en) | 1995-11-13 | 1997-12-02 | Albemarle Corporation | Aluminoxane process and product |
US5688880A (en) | 1995-12-11 | 1997-11-18 | The Dow Chemical Company | Readily supportable metal complexes |
WO1997022635A1 (en) | 1995-12-19 | 1997-06-26 | Exxon Chemical Patents Inc. | High temperature olefin polymerization process |
US5856256A (en) | 1996-02-20 | 1999-01-05 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
EP0794200A2 (en) | 1996-03-05 | 1997-09-10 | Union Carbide Chemicals & Plastics Technology Corporation | Staged reactor polymerisation process |
US5665818A (en) | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
US5627242A (en) | 1996-03-28 | 1997-05-06 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling gas phase fluidized bed polymerization reactor |
EP0802203A1 (en) | 1996-04-18 | 1997-10-22 | Repsol Quimica S.A. | Process for obtaining a catalytic system for the polymerization of alpha-olefins in suspension, in gas phase at low and high temperature or in a mass at high pressure and high or low temperature |
US5731451A (en) | 1996-07-12 | 1998-03-24 | Akzo Nobel Nv | Modified polyalkylauminoxane composition formed using reagent containing aluminum trialkyl siloxide |
WO1998007515A1 (en) | 1996-08-19 | 1998-02-26 | Northwestern University | Use of group 13 metal perfluoroaryl fluoro anions in metallocene catalysts for olefin polymerization |
US5854166A (en) | 1996-08-19 | 1998-12-29 | Northwestern University | Synthesis and use of (perfluoroaryl) fluoro-aluminate anion |
WO1998009996A1 (en) | 1996-09-06 | 1998-03-12 | Hyundai Petrochemical Co., Ltd. | Catalyst system for (co)polymerization of olefins and process for the preparation of olefin (co)polymers using the catalyst system |
US5847177A (en) | 1996-10-10 | 1998-12-08 | Albemarle Corporation | Production of hydrocarbon-soluble hydrocarbylaluminoxanes |
US5744656A (en) | 1996-10-25 | 1998-04-28 | Boulder Scientific Company | Conversion of hexafluorobenzene to bromopentafluorobenzene |
US5747406A (en) | 1997-01-10 | 1998-05-05 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for the production of olefin polymers |
WO1998030603A1 (en) | 1997-01-14 | 1998-07-16 | Dsm N.V. | A process for polymerizing olefins |
WO1998030602A1 (en) | 1997-01-14 | 1998-07-16 | Dsm N.V. | A process for polymerizing olefins |
WO1998032775A1 (en) | 1997-01-28 | 1998-07-30 | Borealis A/S | New activator system for metallocene compounds |
EP0893454A1 (en) | 1997-02-07 | 1999-01-27 | Mitsui Chemicals, Inc. | Olefin polymerization catalyst and process for the production of olefin polymers |
WO1998043983A1 (en) | 1997-04-03 | 1998-10-08 | Colorado State University Research Foundation | Polyhalogenated monoheteroborane anion compositions |
US5889128A (en) | 1997-04-11 | 1999-03-30 | Massachusetts Institute Of Technology | Living olefin polymerization processes |
US6309997B1 (en) | 1997-04-25 | 2001-10-30 | Mitsui Chemicals, Inc. | Olefin polymerization catalysts, transition metal compounds, processes for olefin polymerization, and α-olefin/conjugated diene copolymers |
WO1999001460A1 (en) | 1997-07-02 | 1999-01-14 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
EP0891990A2 (en) | 1997-07-15 | 1999-01-20 | Phillips Petroleum Company | High solids slurry polymerization |
WO1999015534A1 (en) | 1997-09-19 | 1999-04-01 | The Dow Chemical Company | Modified alumoxane catalyst activator |
WO1999018135A1 (en) | 1997-10-06 | 1999-04-15 | Targor Gmbh | Catalyst system |
US6069213A (en) | 1997-12-16 | 2000-05-30 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed catalyst system |
US6608153B2 (en) | 1998-07-10 | 2003-08-19 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
WO2000002930A1 (en) * | 1998-07-10 | 2000-01-20 | Univation Technologies Llc | A catalyst composition and methods for its preparation and use in a polymerization process |
US6300436B1 (en) | 1998-07-10 | 2001-10-09 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
US6333389B2 (en) | 1998-12-18 | 2001-12-25 | Univation Technologies, Llc | Olefin polymerization catalysts, their production and use |
US6271325B1 (en) | 1999-05-17 | 2001-08-07 | Univation Technologies, Llc | Method of polymerization |
WO2000069922A2 (en) | 1999-05-17 | 2000-11-23 | Univation Technologies, Llc | Method of polymerization |
WO2001030861A1 (en) | 1999-10-22 | 2001-05-03 | Univation Technologies, Llc | Catalyst compositions, methods of polymerization, and polymers therefrom |
WO2001030860A1 (en) | 1999-10-22 | 2001-05-03 | Univation Technologies, Llc | Catalyst systems and their use in a polymerization process |
US7129302B2 (en) | 2000-11-30 | 2006-10-31 | Univation Technologies, Llc | Bimetallic catalyst for producing polyethylene resins with bimodal molecular weight distribution, its preparation and use |
WO2002046246A2 (en) | 2000-12-04 | 2002-06-13 | Univaton Technologies, Llc | Polimerization process |
US6689847B2 (en) | 2000-12-04 | 2004-02-10 | Univation Technologies, Llc | Polymerization process |
WO2002050088A1 (en) | 2000-12-18 | 2002-06-27 | Univation Technologies, Llc | Preparation of polymerization catalysts |
WO2002050133A2 (en) * | 2000-12-18 | 2002-06-27 | Univation Technologies, Llc | A method for preparing a supported catalyst system and its use in a polymerization process |
US7179876B2 (en) | 2001-07-19 | 2007-02-20 | Univation Technologies, Llc | High tear films from hafnocene catalyzed polyethylenes |
US6995109B2 (en) | 2001-11-30 | 2006-02-07 | Univation Technologies, Llc | Method of making a bimetallic catalyst with higher activity |
US6884748B2 (en) | 2002-09-04 | 2005-04-26 | Univation Technologies, Llc | Process for producing fluorinated catalysts |
WO2004026921A1 (en) | 2002-09-20 | 2004-04-01 | Exxonmobil Chemical Patents Inc. | Polymer production at supercritical conditions |
US20060019925A1 (en) | 2002-11-21 | 2006-01-26 | Kowa Co. Ltd. | Peritoneal dialysis method |
US6958306B2 (en) | 2003-08-28 | 2005-10-25 | Univation Technologies, Llc | Activated catalyst systems from substituted dialuminoxane complexes |
US20070055028A1 (en) | 2004-01-07 | 2007-03-08 | Casty Gary L | Preparation of polymerization catalyst activators utilizing indole-modified silica supports |
US7157531B2 (en) | 2004-06-21 | 2007-01-02 | Univation Technologies, Llc | Methods for producing polymers with control over composition distribution |
WO2006019494A1 (en) | 2004-07-14 | 2006-02-23 | Exxonmobil Chemical Patents Inc. | Polymer production at supercritical conditions |
US7169864B2 (en) | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
WO2007024773A1 (en) | 2005-08-22 | 2007-03-01 | Chevron Phillips Chemical Co Lp | Polymerization catalysts and process for producing bimodal polymers in a single reactor |
US20100292418A1 (en) | 2007-12-31 | 2010-11-18 | Dow Global Technologies Inc. | Process for polymerizing olefin-based polymers |
WO2012041811A1 (en) * | 2010-09-28 | 2012-04-05 | Basell Polyolefine Gmbh | Method for feeding an antistatic compound to a polymerization reactor |
WO2012074709A1 (en) | 2010-11-30 | 2012-06-07 | Univation Technologies, Llc | Processes for the polymerization of olefins with extracted metal carboxylate salts |
EP2610269A1 (en) * | 2011-12-28 | 2013-07-03 | Saudi Basic Industries Corporation | Catalyst composition and method for preparing the same |
WO2014011357A1 (en) | 2012-07-13 | 2014-01-16 | Univation Technologies, Llc | Increased polymer melt flow ratio via feed of a supported catalyst saturated with a selected liquid agent |
Non-Patent Citations (7)
Title |
---|
"HAWLEY'S CONDENSED CHEMICAL DICTIONARY", 1997, JOHN WILEY & SONS, INC. |
CHEM REV, vol. 100, 2000, pages 1253 |
J AM CHEM SOC, vol. 123, 2001, pages 6847 |
J MOL CATAL A, vol. 213, 2004, pages 141 |
MACROMOL CHEM PHYS, vol. 206, 2005, pages 1847 |
MITSUI, CHEM EUR. J., vol. 12, 2006, pages 7546 |
RESCONI, CHEM REV, vol. 103, 2003, pages 283 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019182746A3 (en) * | 2018-03-23 | 2019-11-14 | Univation Technologies, Llc | Catalyst formulations |
US11518825B2 (en) | 2018-03-23 | 2022-12-06 | Univation Technologies, Llc | Catalyst formulations |
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