WO2015104286A1 - Process for preparing a urea-sulphur fertiliser - Google Patents
Process for preparing a urea-sulphur fertiliser Download PDFInfo
- Publication number
- WO2015104286A1 WO2015104286A1 PCT/EP2015/050158 EP2015050158W WO2015104286A1 WO 2015104286 A1 WO2015104286 A1 WO 2015104286A1 EP 2015050158 W EP2015050158 W EP 2015050158W WO 2015104286 A1 WO2015104286 A1 WO 2015104286A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sulphur
- urea
- molten
- solid
- supplied
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C9/00—Fertilisers containing urea or urea compounds
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C9/00—Fertilisers containing urea or urea compounds
- C05C9/005—Post-treatment
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
Definitions
- the present invention provides a process for the preparation of a urea-sulphur fertiliser.
- Urea is commonly used as a fertiliser, supplying nitrogen to plants. Many soils also require sulphur as a plant nutrient, so fertilisers containing both urea and elemental sulphur have been developed. Desirably the elemental sulphur needs to be present as small dispersed particles to allow its oxidation in the soil to the plant available sulphate ion.
- US 3,100,698 discloses a urea-sulphur fertiliser that is made by combining molten urea and molten sulphur and subjecting the mixed melt to a prilling process.
- the mixed melt can also be prepared by adding solid urea prills to molten sulphur, or by adding solid sulphur to molten urea.
- Melting sulphur and melting urea can be an energy intensive and therefore costly process, and can require sizeable equipment. Additionally, if melting of urea is not done quickly and in a controlled manner (i.e. the temperature is controlled such that it does not
- Biuret is a phytotoxin (a material that is toxic to plants) and can be formed when urea is heated. Biuret interferes with nitrogen
- the present inventors have sought to provide an improved process for the preparation of urea-sulphur fertiliser which is desirably simpler and more energy efficient than known processes.
- the process will allow for rapid yet controlled melting of fertiliser constituents, thereby reducing the risk of impurity formation whilst enabling the size reduction of sulphur to yield finely dispersed sulphur particles in the final product .
- the present invention provides a process for preparing a urea-sulphur fertiliser
- solid sulphur, solid urea or solid urea-sulphur is supplied to the dispersion mill.
- urea or all of the sulphur that is supplied to the dispersion mill is solid urea, solid sulphur or solid urea-sulphur and indeed in many embodiments of the invention the majority of urea and/or sulphur will be supplied as molten urea and molten sulphur. However, in all embodiments of the invention, at least some of the urea or at least some of the sulphur is supplied as solid sulphur, solid urea or solid urea-sulphur.
- the dispersion mill is performing two functions: firstly it melts the solid sulphur, solid urea, or solid urea-sulphur, and secondly it mixes sulphur and urea to form a homogeneous
- the homogeneous dispersion is one of molten sulphur in molten urea.
- dispersion mill typically produces heat, and the process of the invention is able to use this heat to melt sulphur and/or urea. Further, the dispersion mill breaks down the solids fed to it, hence increasing their surface area and increasing their melting kinetics. The inventors believe that the energy requirements of the process are reduced compared to conventional processes. Additionally, by providing a process wherein one or more constituents can be melted as they are combined with sulphur, the
- inventors have enabled short residence times for melting and mixing the constituents, thereby reducing the need for separate melters and reducing the risk of impurity formation .
- urea and sulphur are supplied to a dispersion mill wherein a rotor turns within a slotted stator, thereby providing a dispersion of molten urea and molten sulphur.
- Solid sulphur, solid urea and/or solid urea-sulphur are supplied to the dispersion mill.
- the solid urea, solid sulphur and/or solid urea- sulphur are drawn by the rotation of the rotor into the rotor/stator assembly, and are accelerated and expelled radially through the openings in the slotted stator. With each pass through the rotor/stator assembly, the solid is subjected to a combination of mechanical and hydraulic shear such the particles of solid urea, solid sulphur or solid urea-sulphur are reduced in size.
- the solid urea, solid sulphur or solid urea-sulphur is also subjected to heating and will melt.
- the conventional action of the dispersion mill produces heat.
- further energy is supplied to the dispersion mill, e.g. the mill is jacketed and a fluid is passed through the jacket to heat the mill, or electrical heating is applied to the mill.
- the temperature in the dispersion mill is from 115 to 150°C, more preferably from 130 to 145°C and most preferably from 135 to 140°C.
- the preferred energy input for the mill is from 1 to 100 kWh/tonne product.
- a preferred dispersion mill has a slotted rotor inside a slotted stator. Suitable dispersion mills are described in US 5,522,553 and are available from Kady International, USA.
- the sulphur that is supplied to the dispersion mill can be obtained from any suitable source.
- the sulphur may be high purity (> 99.9% S) chemical sulphur as obtained from the Claus process.
- the process of the present invention can use sulphur of significantly lower purity than this.
- Examples of such sulphur sources are sulphur filter cake as obtained from sulphur melting and filtration operations and sulphur obtained from a various chemical and biological H 2 S gas removal processes.
- such sulphur sources may contain anywhere in the range of from 30 to 99.9 wt%, preferably from 50 to
- solid sulphur is supplied to the dispersion mill.
- the solid sulphur may be added as granules, pellets, slates, powder or any other solid form.
- at least 20wt% of the total sulphur supplied is supplied as solid sulphur;
- all of the sulphur supplied to the dispersion mill is solid sulphur and all of the urea supplied to the dispersion mill is molten urea.
- solid urea is supplied to the dispersion mill.
- the solid urea is preferably added as urea prills.
- it is preferred that some or all of the urea is supplied to the dispersion mill as solid urea, and that all of the sulphur supplied to the dispersion mill is molten sulphur.
- at least 2wt% of the total urea supplied is supplied as solid urea; preferably at least 5wt% and more preferably at least 10wt%.
- solid urea- sulphur is supplied to the dispersion mill.
- molten urea and molten sulphur are supplied to the dispersion mill and that in addition, solid urea-sulphur is supplied to the
- At least 20wt% of the total sulphur supplied is supplied as solid urea-sulphur;
- At least 50wt% and more preferably at least 80wt% preferably at least 50wt% and more preferably at least 80wt%.
- at least 2wt% of the total urea supplied is supplied as solid urea-sulphur; preferably at least 5wt% and more preferably at least 10wt%.
- So-called off-spec materials are suitably used as the solid urea, solid sulphur or solid urea-sulphur in the present invention.
- oversized granules and fines of the material are produced. These oversized granules and fines are typically re-melted and sent to the granulation section of the plant or redirected to the urea synthesis plant. Re-melting these oversized material and fines is energy intensive and can increase the content of unwanted impurities such as biuret .
- urea In the case of urea,
- the present invention enable the recycling of this off-spec material without having to separately remelt the product.
- the ratio of urea: sulphur in the urea-sulphur fertiliser product is preferably from 1:1 to 100:1.
- one or more surfactants is added during step (a) .
- the surfactants may help to further reduce the production of sulphur dust during fertiliser manufacture and may aid the formation of the fertiliser in step (b) .
- the surfactants could include cationic surfactants such as the ethylene oxide or propylene oxide adduct of an aliphatic amine, or could include anionic surfactants such as a lignosulphonate .
- the dispersion of molten urea and molten sulphur is supplied to a forming unit to provide the urea-sulphur fertiliser.
- the forming unit can suitably be a granulator unit, a prilling unit, a compaction unit, a tablet forming unit, or a compressing unit.
- the forming unit is a granulator unit.
- the term "granulator unit" is used to describe a device for forming granules of fertiliser product. Commonly used granulators are described in Perry's Chemical Engineers' Handbook, chapter 20 (1997) .
- Preferred granulators are drum granulators, paddle mixers (pug mills) or pan granulators.
- the forming unit can suitably be a granulator unit, a prilling unit, a compaction unit, a tablet forming unit, or a compressing unit.
- the forming unit is a granulator unit.
- dispersion is pumped and distributed on a rolling bed of material in a drum granulator.
- water and steam can be fed to the granulator to control the temperature of the granulation process as needed.
- recycled fertiliser particles may be added to the granulator unit.
- Recycled fertiliser particles add granulation and nucleating agents.
- step (a) manufacturing process to tailor the fertiliser products to their intended end-use.
- materials would be added during step (a) .
- Examples include plant micro-nutrients such as boron, potassium, sodium, zinc, manganese, iron, copper, molybdenum, cobalt, calcium, magnesium and combinations thereof. These nutrients may be supplied in elemental form or in the form of salts, for examples as sulphates, nitrates or halides.
- the amount of plant micronutrients depends on the type of fertiliser needed and is typically in the range of between 0.1 to 5%, based on the total weight of the fertiliser .
- phosphate rock could be added to the dispersion of molten urea and molten sulphur before it is supplied to the forming unit, thereby providing a urea-sulphur-phosphate rock
- potassium chloride could be added to the dispersion of molten urea and molten sulphur before it is supplied to the forming unit, thereby providing a urea-sulphur-KCl fertiliser.
- phosphoric acid could be could be added to the dispersion of molten urea and molten sulphur whilst it is hot and before it is supplied to the forming unit.
- the phosphoric acid would react with the urea, thereby providing a urea-phosphate-sulphur fertiliser.
- the dispersion of molten urea and molten sulphur can be combined with NPK fertilisers.
- Another material that could be incorporated into the urea-sulphur fertiliser is a clay such as bentonite .
- the clay could be added to the dispersion of molten urea and molten sulphur before it is supplied to the forming unit .
- the urea-sulphur fertiliser is sorted by size in a sorting unit to achieve a more uniform size distribution.
- oversized fertiliser is crushed and returned to the sorting unit while undersized fertiliser is returned to the granulator or may be added as solid urea-sulphur in step (a) .
- a preferred size range for the fertiliser is from 1.5 to 5.0 mm, more preferably from 2 to 4 mm, expressed as the average diameter of the fertiliser particles.
- the average of the four minimum measured emulsion temperatures and that of the four maximum emulsion temperatures are both higher than the individual average temperatures of the urea and sulphur feeds, showing that energy was generated inside the dispersion mill and transferred to the emulsion.
- the energy is expected to be mainly generated by friction between particles and mechanical forces within the mill. From the temperatures given in Table 1 we have calculated that 324 W/h are lost in the form of heat, of 2237 W/h available (applied from a 3 HP engine), yielding a 14% energy loss for the system.
- a closed continuous dispersion unit (a OCCF model dispersion mill from Kady International) was used. Molten urea and molten sulphur were fed to the mill. Conditions of the feeds are given in table 2:
- the energy contained in the product of the mill was calculated to be that of a homogeneous emulsion at the exit temperature of the mill, such that
- From 45-100wt% of the sulphur could have been supplied as solid sulphur and melted by the heat released in the mill; from 5.4-7.5wt% of the urea could have been supplied as solid urea and melted by the heat released in the mill .
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2015205676A AU2015205676B2 (en) | 2014-01-09 | 2015-01-07 | Process for preparing a urea-sulphur fertiliser |
BR112016015698-6A BR112016015698B1 (en) | 2014-01-09 | 2015-01-07 | PROCESS TO PREPARE A UREA-SULFUR FERTILIZER |
US15/110,239 US10464855B2 (en) | 2014-01-09 | 2015-01-07 | Process for preparing a urea-sulphur fertilizer |
EA201691398A EA031060B1 (en) | 2014-01-09 | 2015-01-07 | Process for preparing a urea-sulphur fertiliser |
EP15700057.1A EP3092210A1 (en) | 2014-01-09 | 2015-01-07 | Process for preparing a urea-sulphur fertiliser |
MX2016008489A MX2016008489A (en) | 2014-01-09 | 2015-01-07 | Process for preparing a urea-sulphur fertiliser. |
CN201580004188.XA CN106164021B (en) | 2014-01-09 | 2015-01-07 | Process for preparing urea-sulphur fertilizers |
CA2935921A CA2935921C (en) | 2014-01-09 | 2015-01-07 | Process for preparing a urea-sulphur fertiliser |
IL246244A IL246244B (en) | 2014-01-09 | 2016-06-15 | Process for preparing a urea-sulphur fertiliser |
SA516371461A SA516371461B1 (en) | 2014-01-09 | 2016-07-04 | Process for Preparing a Urea-Sulphur Fertilizer |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14150650 | 2014-01-09 | ||
EP14150650.1 | 2014-01-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2015104286A1 true WO2015104286A1 (en) | 2015-07-16 |
Family
ID=49943191
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2015/050158 WO2015104286A1 (en) | 2014-01-09 | 2015-01-07 | Process for preparing a urea-sulphur fertiliser |
Country Status (12)
Country | Link |
---|---|
US (1) | US10464855B2 (en) |
EP (1) | EP3092210A1 (en) |
CN (1) | CN106164021B (en) |
AR (1) | AR099049A1 (en) |
AU (1) | AU2015205676B2 (en) |
BR (1) | BR112016015698B1 (en) |
CA (1) | CA2935921C (en) |
EA (1) | EA031060B1 (en) |
IL (1) | IL246244B (en) |
MX (1) | MX2016008489A (en) |
SA (1) | SA516371461B1 (en) |
WO (1) | WO2015104286A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016016150A1 (en) * | 2014-07-28 | 2016-02-04 | Shell Internationale Research Maatschappij B.V. | Process for preparing a urea-sulphur fertiliser |
US10464855B2 (en) | 2014-01-09 | 2019-11-05 | Shell Oil Company | Process for preparing a urea-sulphur fertilizer |
EP3581265A1 (en) | 2018-06-12 | 2019-12-18 | thyssenkrupp Fertilizer Technology GmbH | Spray nozzle for producing a urea-sulfur fertilizer |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4330319A (en) * | 1980-12-24 | 1982-05-18 | Cominco Ltd. | Manufacture of urea sulfur fertilizer |
WO2003106376A1 (en) * | 2002-06-17 | 2003-12-24 | Norsk Hydro Asa | Method for the production of a urea fertilizer with elemental sulphur and the product thereof |
WO2010086396A1 (en) * | 2009-01-29 | 2010-08-05 | Shell Internationale Research Maatschappij B.V. | Sulphur-containing fertilizers and process for the preparation thereof |
WO2010086395A1 (en) * | 2009-01-29 | 2010-08-05 | Shell Internationale Research Maatschappij B.V. | Sulphur-containing fertilizers and process for the preparation thereof |
WO2013098404A1 (en) * | 2011-12-29 | 2013-07-04 | Shell Internationale Research Maatschappij B.V. | Processes for the manufacture of sulphur-containing compositions and sulphur-containing fertilizer compositions |
WO2014009326A1 (en) * | 2012-07-09 | 2014-01-16 | Shell Internationale Research Maatschappij B.V. | Process for preparing an emulsion of elemental sulphur particles |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA811080A (en) | 1969-04-22 | Cominco Ltd. | Suspension fertilizer | |
US3100698A (en) * | 1960-09-23 | 1963-08-13 | Shell Oil Co | Urea-sulfur fertilizer composition and method for its production |
BE667331A (en) | 1964-07-24 | |||
US3697245A (en) | 1970-08-12 | 1972-10-10 | Joseph T Dilday | Coated fertilizer |
US3725029A (en) | 1971-09-27 | 1973-04-03 | Ga Pacific Corp | Preparation of ammonium sulfate fertilizer constituent |
US4372872A (en) | 1981-02-17 | 1983-02-08 | Union Oil Company Of California | Sulfur suspensions |
US4832728A (en) | 1981-09-25 | 1989-05-23 | Melamine Chemicals, Inc. | Fertilizer compositions, processes of making them, and pocesses of using them |
NZ213682A (en) | 1985-10-02 | 1988-11-29 | New Zealand Fertilizer Manufac | Dispersing sulphur in a liquid for use as a fertiliser |
US5082487A (en) | 1988-04-11 | 1992-01-21 | Allied-Signal Inc. | Solutions of ammonium sulfate, ammonium nitrate and urea, with high nitrogen and sulfur content, having low salt-out temperatures |
US5522553A (en) | 1994-09-29 | 1996-06-04 | Kady International | Method and apparatus for producing liquid suspensions of finely divided matter |
US6331193B1 (en) | 1998-04-17 | 2001-12-18 | Airborne Industrial Minerals Inc. | Wet granulation method generating sulfur granules |
AU2003304243A1 (en) | 2003-06-27 | 2005-01-13 | Melspring International B.V. | Process for the production of a fertilizer and fertilizer |
DE102007061408A1 (en) * | 2007-12-11 | 2009-06-18 | Sandvik Materials Technology Deutschland Gmbh | Method and drop former for producing pastilles and method for producing a sulfur-containing fertilizer |
CN101402532B (en) | 2008-10-06 | 2011-08-10 | 中国农业大学 | Novel particle zinc fertilizer |
CA2657531A1 (en) | 2009-03-09 | 2010-09-09 | Satish R. Iyer | Micronized sulphur powder and method of production of same |
CA2663119A1 (en) | 2009-04-16 | 2010-10-16 | Sulphur Solutions Inc. | Dispersible sulphur fertilizer pellets |
MX2011011823A (en) | 2009-05-07 | 2011-11-29 | Shell Int Research | Process for preparing an elemental sulphur-containing fertilizer. |
DE102009036230B4 (en) | 2009-08-05 | 2014-10-09 | Skw Stickstoffwerke Piesteritz Gmbh | New N / S liquid fertilizer with high nutritional content |
CN101967070B (en) | 2010-07-23 | 2013-01-02 | 中化重庆涪陵化工有限公司 | Sulfur, zinc, manganese and boron-containing phosphate ammoniate fertilizer and production method thereof |
WO2012118532A1 (en) | 2011-02-28 | 2012-09-07 | Schutt Steven R | A tri amino releasing fulvate |
WO2015017329A2 (en) | 2013-07-31 | 2015-02-05 | Heart Of Nature Llc | Mineral complex, compositions, methods of making, and uses therein |
CA2936029C (en) | 2014-01-09 | 2022-08-30 | Shell Internationale Research Maatschappij B.V. | Fertiliser having reduced biuret content |
CA2935921C (en) | 2014-01-09 | 2022-08-02 | Shell Internationale Research Maatschappij B.V. | Process for preparing a urea-sulphur fertiliser |
WO2015104296A1 (en) | 2014-01-09 | 2015-07-16 | Shell Internationale Research Maatschappij B.V. | Urea fertiliser having improved hardness |
-
2015
- 2015-01-07 CA CA2935921A patent/CA2935921C/en active Active
- 2015-01-07 AU AU2015205676A patent/AU2015205676B2/en active Active
- 2015-01-07 BR BR112016015698-6A patent/BR112016015698B1/en active IP Right Grant
- 2015-01-07 MX MX2016008489A patent/MX2016008489A/en unknown
- 2015-01-07 CN CN201580004188.XA patent/CN106164021B/en active Active
- 2015-01-07 WO PCT/EP2015/050158 patent/WO2015104286A1/en active Application Filing
- 2015-01-07 EP EP15700057.1A patent/EP3092210A1/en not_active Withdrawn
- 2015-01-07 EA EA201691398A patent/EA031060B1/en not_active IP Right Cessation
- 2015-01-07 US US15/110,239 patent/US10464855B2/en active Active
- 2015-01-08 AR ARP150100040A patent/AR099049A1/en active IP Right Grant
-
2016
- 2016-06-15 IL IL246244A patent/IL246244B/en active IP Right Grant
- 2016-07-04 SA SA516371461A patent/SA516371461B1/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4330319A (en) * | 1980-12-24 | 1982-05-18 | Cominco Ltd. | Manufacture of urea sulfur fertilizer |
WO2003106376A1 (en) * | 2002-06-17 | 2003-12-24 | Norsk Hydro Asa | Method for the production of a urea fertilizer with elemental sulphur and the product thereof |
WO2010086396A1 (en) * | 2009-01-29 | 2010-08-05 | Shell Internationale Research Maatschappij B.V. | Sulphur-containing fertilizers and process for the preparation thereof |
WO2010086395A1 (en) * | 2009-01-29 | 2010-08-05 | Shell Internationale Research Maatschappij B.V. | Sulphur-containing fertilizers and process for the preparation thereof |
WO2013098404A1 (en) * | 2011-12-29 | 2013-07-04 | Shell Internationale Research Maatschappij B.V. | Processes for the manufacture of sulphur-containing compositions and sulphur-containing fertilizer compositions |
WO2014009326A1 (en) * | 2012-07-09 | 2014-01-16 | Shell Internationale Research Maatschappij B.V. | Process for preparing an emulsion of elemental sulphur particles |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10464855B2 (en) | 2014-01-09 | 2019-11-05 | Shell Oil Company | Process for preparing a urea-sulphur fertilizer |
WO2016016150A1 (en) * | 2014-07-28 | 2016-02-04 | Shell Internationale Research Maatschappij B.V. | Process for preparing a urea-sulphur fertiliser |
US10221106B2 (en) | 2014-07-28 | 2019-03-05 | Shell Oil Company | Process for preparing a urea-sulphur fertiliser |
EP3581265A1 (en) | 2018-06-12 | 2019-12-18 | thyssenkrupp Fertilizer Technology GmbH | Spray nozzle for producing a urea-sulfur fertilizer |
WO2019238570A1 (en) | 2018-06-12 | 2019-12-19 | Thyssenkrupp Fertilizer Technology Gmbh | Spray nozzle for producing a urea-sulfur fertilizer |
Also Published As
Publication number | Publication date |
---|---|
CN106164021A (en) | 2016-11-23 |
AU2015205676B2 (en) | 2017-08-24 |
BR112016015698A2 (en) | 2017-08-08 |
CA2935921C (en) | 2022-08-02 |
US20160332923A1 (en) | 2016-11-17 |
EP3092210A1 (en) | 2016-11-16 |
MX2016008489A (en) | 2016-09-13 |
AU2015205676A1 (en) | 2016-06-30 |
IL246244B (en) | 2020-07-30 |
EA031060B1 (en) | 2018-11-30 |
EA201691398A1 (en) | 2016-11-30 |
IL246244A0 (en) | 2016-07-31 |
BR112016015698B1 (en) | 2022-01-11 |
SA516371461B1 (en) | 2021-03-11 |
CA2935921A1 (en) | 2015-07-16 |
US10464855B2 (en) | 2019-11-05 |
CN106164021B (en) | 2019-12-17 |
AR099049A1 (en) | 2016-06-29 |
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