WO2015026937A1 - Thermal barrier systems with improved adhesion - Google Patents
Thermal barrier systems with improved adhesion Download PDFInfo
- Publication number
- WO2015026937A1 WO2015026937A1 PCT/US2014/051883 US2014051883W WO2015026937A1 WO 2015026937 A1 WO2015026937 A1 WO 2015026937A1 US 2014051883 W US2014051883 W US 2014051883W WO 2015026937 A1 WO2015026937 A1 WO 2015026937A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coating
- aluminide
- oxide
- aluminum
- coatings
- Prior art date
Links
- 230000004888 barrier function Effects 0.000 title description 13
- 238000000576 coating method Methods 0.000 claims abstract description 231
- 239000011248 coating agent Substances 0.000 claims abstract description 158
- 229910000951 Aluminide Inorganic materials 0.000 claims abstract description 104
- 239000000758 substrate Substances 0.000 claims abstract description 47
- 239000012720 thermal barrier coating Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims description 86
- 229910052782 aluminium Inorganic materials 0.000 claims description 83
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 72
- 230000008569 process Effects 0.000 claims description 48
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 45
- 229910052735 hafnium Inorganic materials 0.000 claims description 29
- 229910045601 alloy Inorganic materials 0.000 claims description 24
- 239000000956 alloy Substances 0.000 claims description 24
- 229910052697 platinum Inorganic materials 0.000 claims description 21
- 239000001257 hydrogen Substances 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 18
- 239000012808 vapor phase Substances 0.000 claims description 18
- 239000012190 activator Substances 0.000 claims description 16
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 9
- 229910010293 ceramic material Inorganic materials 0.000 claims description 9
- 229910052804 chromium Inorganic materials 0.000 claims description 9
- 239000011651 chromium Substances 0.000 claims description 9
- 229910052717 sulfur Inorganic materials 0.000 claims description 9
- 239000011593 sulfur Substances 0.000 claims description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 8
- 230000001965 increasing effect Effects 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 238000007788 roughening Methods 0.000 claims description 4
- 239000012080 ambient air Substances 0.000 claims description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims 3
- 239000000919 ceramic Substances 0.000 abstract description 40
- 239000010410 layer Substances 0.000 description 69
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 60
- 230000003647 oxidation Effects 0.000 description 36
- 238000007254 oxidation reaction Methods 0.000 description 36
- 239000000463 material Substances 0.000 description 33
- 229910052786 argon Inorganic materials 0.000 description 30
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 28
- 238000005524 ceramic coating Methods 0.000 description 20
- 229910052751 metal Inorganic materials 0.000 description 20
- 239000002184 metal Substances 0.000 description 19
- 239000011253 protective coating Substances 0.000 description 17
- 239000007789 gas Substances 0.000 description 16
- 239000000203 mixture Substances 0.000 description 15
- 229910000601 superalloy Inorganic materials 0.000 description 15
- 238000009792 diffusion process Methods 0.000 description 14
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 12
- 150000004820 halides Chemical class 0.000 description 12
- 238000007792 addition Methods 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 11
- 238000011534 incubation Methods 0.000 description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 10
- 239000000470 constituent Substances 0.000 description 10
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 10
- 239000012071 phase Substances 0.000 description 10
- 238000012545 processing Methods 0.000 description 9
- 239000003570 air Substances 0.000 description 8
- 238000005229 chemical vapour deposition Methods 0.000 description 8
- 238000001816 cooling Methods 0.000 description 8
- 238000000151 deposition Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 239000011261 inert gas Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 239000010941 cobalt Substances 0.000 description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 7
- 238000005328 electron beam physical vapour deposition Methods 0.000 description 7
- 238000005422 blasting Methods 0.000 description 6
- -1 carbide Chemical class 0.000 description 6
- 229910017052 cobalt Inorganic materials 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 229910052727 yttrium Inorganic materials 0.000 description 6
- 229910003460 diamond Inorganic materials 0.000 description 5
- 239000010432 diamond Substances 0.000 description 5
- 238000011065 in-situ storage Methods 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 5
- 239000011241 protective layer Substances 0.000 description 5
- 241000894007 species Species 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- 230000000007 visual effect Effects 0.000 description 5
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 5
- 229910052726 zirconium Inorganic materials 0.000 description 5
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminium flouride Chemical compound F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 4
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 229910000449 hafnium oxide Inorganic materials 0.000 description 4
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 4
- 229910001026 inconel Inorganic materials 0.000 description 4
- 229910000907 nickel aluminide Inorganic materials 0.000 description 4
- 150000004767 nitrides Chemical class 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 101100004392 Arabidopsis thaliana BHLH147 gene Proteins 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 230000001143 conditioned effect Effects 0.000 description 3
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- 238000011161 development Methods 0.000 description 3
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- 230000006872 improvement Effects 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 229910052746 lanthanum Inorganic materials 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000005240 physical vapour deposition Methods 0.000 description 3
- 238000007750 plasma spraying Methods 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- 229910000943 NiAl Inorganic materials 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- 239000010953 base metal Substances 0.000 description 2
- 229910001570 bauxite Inorganic materials 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
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- 238000004140 cleaning Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
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- 150000002736 metal compounds Chemical class 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910052702 rhenium Inorganic materials 0.000 description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
- 238000005488 sandblasting Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004611 spectroscopical analysis Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910001011 CMSX-4 Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 241000287227 Fringillidae Species 0.000 description 1
- 229910004504 HfF4 Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910001005 Ni3Al Inorganic materials 0.000 description 1
- 229910000796 S alloy Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
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- 229910052796 boron Inorganic materials 0.000 description 1
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- 238000005266 casting Methods 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
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- 229910000765 intermetallic Inorganic materials 0.000 description 1
- NPURPEXKKDAKIH-UHFFFAOYSA-N iodoimino(oxo)methane Chemical compound IN=C=O NPURPEXKKDAKIH-UHFFFAOYSA-N 0.000 description 1
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 1
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- 238000000608 laser ablation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
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- 150000001247 metal acetylides Chemical class 0.000 description 1
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- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052755 nonmetal Chemical class 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
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- 238000010248 power generation Methods 0.000 description 1
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- 230000003716 rejuvenation Effects 0.000 description 1
- 229910001088 rené 41 Inorganic materials 0.000 description 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
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- 239000011780 sodium chloride Substances 0.000 description 1
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- 230000008685 targeting Effects 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/28—Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes
- C23C10/34—Embedding in a powder mixture, i.e. pack cementation
- C23C10/36—Embedding in a powder mixture, i.e. pack cementation only one element being diffused
- C23C10/48—Aluminising
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/02—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/60—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
- C23C28/321—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
- C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
- C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
- C23C28/3455—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer
Definitions
- the present invention relates to thermal barrier systems that help to protect metal-containing substrates in high temperature environments. More specifically, the present invention relates to thermal barrier coatings comprising an aluminum- containing base coat, an intermediate thermally grown oxide layer formed on the base coat, and a ceramic topcoat formed on the thermally grown oxide, wherein the thermal barrier system has improved durability and improved resistance to thermal degradation.
- the function of a gas turbine engine is to convert the energy in hydrocarbon fuel into useful work.
- the gas turbine accomplishes this by compression of ambient air, addition of fuel to the compressed air, and combustion of the fuel/air mixture to drive a turbine.
- Good design of the engine components promotes efficient conversion of the energy into useful work.
- component design influences efficiency and power output to some degree
- another primary factor affecting engine efficiency and power output is the difference between the ambient temperature of the incoming air and the combustion temperature.
- the correlation of efficiency and power output to this temperature difference is a principle of basic thermodynamics. This means that greater efficiency and more power generally result with increasing operating temperature of the gas directed to the turbine. In practical terms, this means that the high temperature performance of the turbine components
- Grain boundaries are a strengthening mechanism at room temperature but can be a source of failure at elevated temperatures in some current generation engines.
- Development of specialized casting techniques to control and/or reduce grain boundaries in turbine airfoils has lead to columnar grained and single crystal airfoils.
- the surfaces of the articles to be protected can be protected with an aluminum-containing protective coating whose surface oxidizes to form an aluminum oxide scale that inhibits further oxidation.
- the protective coating therefore is sufficiently rich in Al to promote thermal growth of this oxide scale.
- the scale is also referred to as a thermally grown oxide (TGO).
- a conventional bond coat is typically either an MCrAlY overlay (where M is Ni, Co, Fe, or combination of them) or a diffusion aluminide coating.
- An MCrAlY overlay is generally applied by Electron Beam Physical Vapor Deposition (EB- PVD), High Velocity Oxy-Fuel (HVOF), Low Pressure Plasma Spray (LPPS) or Vacuum Plasma Spray (VPS).
- EB- PVD Electron Beam Physical Vapor Deposition
- HVOF High Velocity Oxy-Fuel
- LPPS Low Pressure Plasma Spray
- VPS Vacuum Plasma Spray
- Diffusion aluminide coatings are generally formed by chemical vapor deposition (CVD), slurry coating, or by a diffusion process such as pack cementation, above-pack, or vapor (gas) phase deposition.
- Diffusion aluminide coatings have particularly found widespread use as protective coatings for superalloy components of gas turbine engines due to: (1) the diffusion process is not a line-of-sight process allowing components with complex geometry or with internal surfaces to be coated; and (2) the diffusion process is generally cost-effective as compared with overlay process.
- Refractory elements have been incorporated into aluminide coatings to improve the oxidation protection and adhesion properties provided by these coatings.
- refractory elements that have been proposed for aluminide compositions include Hf, Zr, Y, La and/or Ce. With small additions of refractory elements to aluminide coatings, the adherence of the protective oxide scale to the coatings/alloys and the oxidation resistance of the coatings/alloys at high temperature under aggressive atmospheres can be improved.
- hafnium decreases the propensity for rumpling when it diffuses into the coating and to the growing aluminum oxide increasing their creep resistance (Tolpygo et al, "Effect of Hf, Y and C in the underlying superalloy on the rumpling of diffusion aluminide coatings," Acta Materialia 56, Pages 489 ⁇ 499, 2008) as well as decreases the voids formed in the coating alloy at the metal-oxide interface during oxidation
- Pack cementation, CVD and vapor phase process are three potential industrial diffusion coating processes for forming Hf-modified aluminide diffusion coatings.
- the vapor phase process has the potential to offer many advantages.
- the others have drawbacks.
- pack cementation processes for both hafnium-modified aluminide and simple aluminide coatings share the same disadvantages, such as the need for an inert filler, the obstruction of cooling holes, and the embedded particles on the formed coating surface.
- a significant disadvantage of using a CVD process to form a hafnium-modified aluminide coating is the considerable equipment cost.
- alternative deposition methods such as vapor phase process, have been sought. .
- U.S. Pat. No. 6,332,931 to Das et al. disclosed a vapor phase coating process to produce aluminide-hafhide coatings by using Hf metal or Hf-containing metallic alloys as Hf donor materials; as a result, the synthesized coatings contain about 0.5 to about 60 weight percent hafnium and about 12 to about 38 weight percent aluminum.
- too high Hf content in aluminide coatings can lead to the formation of Hf-rich precipitated phases in the coating or on the coating surface, such as HfC, HfD 2 , andNi 2 AlHf etc, and furthermore, deteriorate the mechanical properties and the oxidation resistance of the aluminide coatings.
- the concept of increasing the operating temperature by changing the heat transfer characteristics of engine components also has been investigated.
- One strategy involves coating an additional layer onto the surface of a substrate, such as an air-cooled superalloy component, wherein the coating includes a material with a thermal conductivity less than that of the superalloy.
- Ceramic materials are examples of high temperature coating materials that have been used to modify heat transfer characteristics.
- a ceramic topcoat may be further applied over the aluminum-containing protective layer to help provide a thermal barrier that extends service life. Ceramic materials by nature have a lower thermal conductivity than metals. Surface metal temperature reductions of 250F to300F are theoretically possible with a .005" to .010" thick ceramic layer and use of internal cooling. In actual practice, temperature reductions of about 100F to 18 OF are more likely to be achieved.
- the protective coating also referred to as a bond coat
- the TGO layer, and the optional ceramic topcoat provide a thermal barrier coating system (TBC) to protect the coated article.
- TBC thermal barrier coating system
- CTE coefficient of thermal expansion
- the difference in CTE characteristics undermines the adhesion between a ceramic coating and a metal substrate.
- the difference in CTE between the metal and the ceramic will result in very high stresses along the bond interface as the temperature increases. Cooling also causes stresses at the interface, as the metal contracts faster than the ceramic. The stresses tend to cause the ceramic coating to spall, crack, delaminate, chip, or otherwise degrade.
- the TGO helps bond the ceramic topcoat to the protective coating.
- the spallation and cracking of the thickening TGO scale layer is another failure mechanism of conventional thermal barrier systems.
- improving the adhesion and integrity of the interfacial TGO scale is critical to the development of more reliable thermal barrier systems.
- the aluminum-containing protective coating should oxidize to form a slow-growing, non- or less "rumpling,” nonporous TGO layer that adhere well to the protective coating and the ceramic topcoat.
- the present invention provides strategies for making aluminide coatings and corresponding thermal barrier coating systems that protect metallic substrates in high temperature environments.
- the coatings show excellent adhesion to substrates as well as among layers of the coatings.
- the coatings generally include a first coating comprising an aluminide that is formed on the substrate. An oxide layer is formed on this first coating. A third coating comprising a ceramic is then formed on the oxide.
- An aspect of the present invention is that the oxide is at least partially and more preferably substantially fully formed before the ceramic topcoat is provided.
- the oxide will form in situ between the already existing first and third coatings and then act like a wedge to break the interface between the first and third coatings.
- vapor phase coating techniques optionally are used in manner that efficiently and consistently incorporate refractory element content into the aluminide coatings.
- the coatings show excellent adhesion to substrates as well as among layers of the coatings.
- the coatings generally include a first coating comprising an aluminide that is formed on the substrate.
- an oxide layer optionally is formed on this first coating.
- a third coating comprising a ceramic optionally is then formed on the oxide.
- the aluminide coating deposition desirably incorporates two heating stages.
- a first heating stage occurs in the presence of a reducing gas under conditions that significantly increase or otherwise favor the formation of refractory element-containing species in the vapor phase.
- the result is that surprisingly high levels of refractory element content can be incorporated into the resultant coatings in the second stage even when the donor materials contain relatively little refractory element content.
- refractory element donor materials are used so efficiently that donor materials that include under 1 weight percent of refractory element donor compounds based on the total weight of aluminum sources can provide coatings with over 5 weight percent of the refractory element.
- the process provides uniform coatings and is consistent from run to run.
- the present invention may be used to apply coatings that protect any articles from a hostile operating environment.
- the coatings protect against oxidation, hot corrosion, or other degradation in high temperature and/or chemically hostile environments.
- a wide range of articles can be protected by these coatings, including turbine engine hot zone components, blades, vanes, combustors transition pieces, and the like.
- the present invention relates to a method of forming a thermal barrier coating comprising:
- the present invention relates to a method of refurbishing a coated article comprising:
- FIG. 1 is a cross-sectional diagram of a metallic article with a thermal barrier coating of the present invention.
- FIG. 1 schematically shows a cross-section of a portion of a coated article 10 manufactured in accordance with principles of the present invention.
- article 10 is a constituent of a rocket, missile, aircraft, marine vessel, industrial facility, power utility, electric motor, chemical
- article 10 is a constituent of a gas turbine engine such as being all or a portion of a high pressure turbine nozzle, low pressure turbine nozzle, turbine shroud, turbine blade, turbine vanes, and/or the like.
- Article 10 can be a new part, a replacement part, or a repaired or refurbished part.
- the article 10 can be casted, molded, machined, directionally solidified (DS), fabricated from a single crystal (SX), and/or fabricated in any other desired method.
- the article 10 includes a body 11 that serves as a substrate for thermal barrier structure 12.
- Body 11 includes a metallic composition that may be a pure metal, an intermetallic composition, an alloy, combinations of these and the like.
- the body may contain a single phase or may contain multiple phases, e.g., an alloy matrix with intermetallic precipitates.
- Body 11 may be amorphous, crystalline, and/or the like.
- body 11 may also contain other constituents.
- body 11 may be a composite that includes a metallic matrix and fibers (not shown) or the like.
- body 11 includes nickel (Ni)-base, cobalt (Co)- base, titanium (Ti)-base, or iron (Fe)-base alloys.
- Ni-base alloy means that Ni is the dominant element in the alloy. That is, more Ni is present than any other individual metal element in the alloy.
- Co, Ti, and Fe are the dominant element in Co-base, Ti-base, and Fe-base alloys, respectively.
- the alloy may include one or more other alloying elements such as chromium, aluminum, titanium, molybdenum, iron, manganese, tungsten, boron, niobium, tantalum, cobalt, silicon, rhenium, platinum, hafnium, zirconium, yttrium, combinations of these and the like.
- alloys of nickel, cobalt, and/or nickel-iron are known as superalloys due to excellent mechanical strength, creep resistance and good surface stability at high
- WASPALOYTM WASPALOYTM
- RENETM e.g. RENE 41, RENE 80, RENE 95, and RENE 141
- HAYNES-188 HAYNES-L605, INCOLOYTM
- MP98T TMS
- X40 MAR-M-247
- CMSX-4 CMSX-6.
- body 11 may include one or more layers.
- a layer of platinum (not shown) may be deposited to form a surface layer on at least a portion of body 11.
- the platinum can diffuse and incorporate into the protective coating 13 so that such separate layer of platinum may have dissipated at least into coating 13 after some period of use.
- platinum can help to enhance the oxidation protection of body 11.
- the incorporation of platinum also can enhance the mechanical properties of the aluminide coatings.
- all or selected portion(s) of body 11 can be coated with a layer comprising Pt and heat treated.
- the platinum can be deposited by any suitable method.
- the platinum is deposited using an electroplating process and a suitable platinum source, such as a Pt P-salt with a formula of
- the surface 25 of body 11 optionally may be textured to enhance the bonding of layer 13 to body 11.
- the texture on surface 25 can be formed by a variety of techniques including molding the texture when body 11 is formed, embossing, chemical etching, sand blasting or otherwise abrading, laser ablation, combinations of these, and the like. When refurbishing components, sand blasting is a preferred technique to form the texture.
- Thermal barrier structure 12 is provided on body 11.
- Thermal barrier structure 12 includes protective coating 13, a thermally grown oxide layer 14, and a ceramic topcoat 15.
- Protective coating 13 helps to protect body 11 against oxidation, particularly in high temperature environments (e.g., environments in which the temperature is above about 450°C, preferably above about 650°C, more preferably above about 850°C).
- protective coating 13 comprises at least one aluminide.
- an aluminide refers to a metal compound comprising aluminum at and least one other more electropositive metal element.
- an aluminide is a metallic solid solution or an intermetallic composition. Examples of suitable aluminides include nickel aluminide, cobalt aluminide, combinations of these, and the like.
- the protective coating 13 may be a single phase or may include one or more additional phases.
- Aluminide compositions comprising at least (a) aluminum and (b) nickel and/or Co are preferred.
- nickel aluminides and/or cobalt aluminides containing from about 45 to about 70 atomic percent Ni and/or Co based on the total amount of nickel, cobalt, and aluminum are preferred.
- Such compositions provide a good balance between high temperature oxidation resistance and acceptable mechanical properties.
- refractory elements also may be incorporated into all or a portion of the aluminide content of coating 13 if desired.
- a refractory element refers to a metal element having a melting point greater than about 795°C, preferably greater than 1100°C, more preferably greater than 1850°C.
- suitable refractory elements include one or more of Hf, Zr, Y, La, Ce, rhenium, osmium, and combinations of these. Of these, hafnium (Hf), zirconium (Zr), yttrium (Y), lanthanum (La), cerium (Ce), and combinations of these are preferred.
- coating 13 comprises at least one of Hf, Zr, and/or Y, most preferably Hf.
- the refractory element content offers excellent oxidation protection by minimizing the amount of oxidized scale and enhancing the adherence of the scale to the protective coating system 12.
- the refractory elements may be present in coating 13 in a variety of forms including as metals, dopants, or non-metal compounds such as oxides, nitrides, carbides, combinations of these, or the like. These may be present in the same phase as other aluminide content or in separate phase(s).
- coatings 13 may incorporate from 0.01 to 30 weight percent, preferably 0.1 to 20 weight percent, and more preferably 1 to 15 weight percent of refractory element(s) present in the surface of a coating as determined using SEM EDS spectroscopy techniques described below.
- a refractory element is present in coating 13 as an oxide, halide, nitride, carbide, salt, or other compound, e.g., Hf(1 ⁇ 4 or the like
- the weight percent of refractory element in the coating is based on the amount of refractory element(s) that are present, not the compound(s) including the refractory element(s). For instance, if a particular coating includes 90 parts by weight of nickel aluminide and 10 parts by weight of Hf0 2 , the hafnium oxide content is 10% but the Hf content is 8.5% as determined by SEM EDS spectroscopy.
- the weight percent of the refractory element(s) in the coating is based upon the total weight of all elements within the surface areas analyzed using SEM EDS techniques.
- a JEOL model 6610 scanning electron microscope equipped for energy dispersive spectroscopy (EDS) is used to determine the amount of refractory element(s) (such as hafnium) present in the surface of a coating, expressed as a weight percent.
- EDS energy dispersive spectroscopy
- 3 areas of a substrate are scanned at 20Kv, 50X magnification for 30 seconds from a working distance of 12 mm.
- the weight percent of each area is then determined from the SEM EDS data.
- the weight percent is taken as an average from the 3 areas. Scans may be taken on flat, concave, or convex areas such as the concave and convex airfoil as well as the buttress.
- coating 13 As coating 13 is formed (described in more detail below for an illustrative embodiment), a portion of the material that forms coating 13 tends to form an outward-growth coating portion 7 generally over the surface of body 11. Another portion of the material will tend to interdiffuse into and with the material of body 11, forming an interdiffusion zone 9 that extends to some depth into body 11. At the same time, some of the constituents of body 11 may diffuse into the deposited coating 13. For purposes of the present invention, interdiffusion zone 9 is considered to be a portion of the coating 13 even though it extends downward into body 11.
- Protective coatings 13 of the invention may include refractory element content within the outward growth portion 7 and/or the interdiffusion zone 9 of coating 13. The coating 13 may have a thickness within a wide range.
- a suitable thickness for coating 13 is similar to the thickness of conventional industrial coatings, typically about 25 to 125 micrometers (about 0.001- 0.005 inch).
- Surface 27 of layer 13 optionally may be textured to enhance the adhesion of layer 13 to the oxide layer 14.
- the texture can be formed in a variety of ways. In some modes of practice, layer 13 is formed as a conformal coating over surface 25 so that the texture of surface 25 (if any) is telegraphed to some degree to surface 27 so that direct texturing of surface 27 after surface 27 is formed can be avoided. Such direct texturing creates a risk of abrading through layer 13, losing protection in those through-abraded regions. In other modes of practice, surface 27 can be texturized after surface 27 is initially formed if desired.
- protective coating 13 is formed using vapor phase coating techniques, including chemical (CVD) and/or physical (PVD) vapor deposition.
- CVD chemical
- PVD physical
- the process will be described in the context of preparing Hf-containing aluminide coatings in which Hf is obtained from one or more sources including an oxide, nitride, and/or carbide of Hf such as Hf0 2 . It will be understood that coatings including one or more of the other refractory elements could be prepared by replacing all or a portion of the Hf sources described herein with comparable sources of one or more of the other refractory elements.
- At least one substrate including at least body 11 is placed into a processing chamber and suitably supported so that contact between the substrate and generated vapors causes the desired coating to form under suitable conditions.
- suitable conditions include carrying out the process at suitable temperatures in the presence of a reducing gas such as hydrogen.
- a reducing gas such as hydrogen.
- One suitable process chamber is described in WO 2010/135144, the entirety of which is incorporated herein by reference for all purposes.
- the supports on which substrates are supported desirably are pre-conditioned in order to enhance coating
- Pre-conditioning involves subjecting the supports to the coating process one or more times in the absence of any substrate(s).
- the resultant aluminide coating may be heat treated to adjust the coating microstructure and composition distribution. Further background on using vapor phase coating techniques to form aluminide coatings are described in WO 2010/135144, the entirety of which is incorporated herein by reference for all purposes.
- the aluminide coatings of the present invention may be obtained from ingredients comprising at least one aluminum source, at least one non-halide compound of at last one refractory element, and a halide activator.
- ingredients may be supplied in any convenient form such as a fine powder, nuggets, pellets, granules, flakes, or the like. These can be supplied in any convenient shape, such as irregular, dendritic, acicular, cubic, spheroidal, fibrous, combinations of these, and the like.
- Aluminum used to form the aluminide content of coating 13 may be derived from a variety of sources.
- the aluminum is obtained from commercially pure aluminum powder that may be mixed with an inert material such as alumina for easier handling and to reduce the risk of sintering.
- an aluminum source includes 1.5 to 10 parts by weight of commercially pure aluminum powder per about 100 parts by weight of alumina.
- the aluminum and alumina are powders of a size large enough to avoid undue sintering while small enough to react well. In one mode of practice 200 mesh aluminum powder and 100 mesh alumina would be suitable.
- Aluminum sources include any aluminum containing material(s) suitable for use in physical or chemical vapor deposition in which an aluminum containing vapor is generated from the source and caused to form coating on the desired substrate.
- other aluminum sources include Al-rich alloys and/or intermetallic compositions optionally containing other elements such as those other metals and refractory elements described herein with respect to forming aluminide compositions. Examples include Cr, Co, Ni, Fe, Mo, W, Mn, Ti, Y, Zr, Pt, Hf, combinations of these, or the like.
- the Al content in such sources desirably is about 3 weight percent to about 99 weight percent, preferably from about 15 weight percent to about 50 weight percent based on the total weight of the source material. The remainder of the source may be one or more of the other elements described herein and/or compounds of such elements.
- An exemplary alloy source includes from about 25 weight percent to 35 weight percent aluminum.
- aluminum incorporated into aluminum sources desirably is obtained from natural resources containing very little if any sulfur in order to exclude sulfur as much as practical from coating 13. Sulfur may tend to segregate to surfaces and could then adversely impact the oxide layer to base metal adhesion.
- a superalloy such as the Mar M 247 alloy with less than 1 PPM bulk sulfur by weight tends to form a very adherent aluminum oxide just from the ⁇ 5.0% Al present for base material strength.
- Such a low sulfur alloy does not require the typical local enrichment of the component surface with aluminum using standard aluminide coating techniques.
- More preferred aluminum sources include sufficiently limited amounts of sulfur (if any) such that the resultant layer 13 includes less than 500 ppm, preferably less than 100 ppm, and even less than 10 ppm sulfur on a weight basis.
- Bauxite is a natural resource from which substantially sulfur-free aluminum can be obtained. Accordingly, aluminum sources derived from bauxite are preferred, particularly commercially pure aluminum powder.
- Chromium ores are largely sulfide type ores which often include substantial trace amounts of sulfur even after extensive refining.
- Aluminum donor materials containing chromium could include undue amounts of sulfur that could unduly contaminate the resultant aluminide coating.
- the amount of aluminum source materials desirably is about 0.3 kg to about 7 kg per cubic foot of the internal volume of the processing chamber, preferably from about 2 kg to about 4 kg per cubic foot of the internal volume of the chamber. This does not include diluent material, such as alumina, if included.
- the additional metal elements used to form the aluminide(s) may be introduced from one or more sources including from substrate body 11, from the aluminum source(s), and/or from one or more independent source(s). Such elements may then react with the aluminum to form one or more aluminides. For example, as aluminum is deposited onto body 11 to form layer 3, one or more metallic constituents of body 11 such as Ni may diffuse or otherwise be incorporated into layer 13. The nickel and aluminum react to form nickel aluminide. From one perspective, such a process can be viewed as enriching the surface of body 11 to form an aluminum rich region constituted by layer 13.
- the optional refractory element(s) may be provided by one or more sources wherein at least a portion of at least one source, preferably substantially all of the source, includes a non-halide compound of the element such as a salt, a metallic compound, an oxide, other oxygen-containing compound, nitride, carbide, and/or the like. Desirably, at least 25 weight percent, preferably at least aboiit 50 weight percent, more preferably substantially all of the refractory element source(s) are such compound(s). Oxide sources are preferred. In an illustrative embodiment, a preferred Hf source is HfO 2 .
- using an oxide of Hf as a source provides excellent control over the Hf activity when using vapor phase techniques for co-deposition of Hf and aluminum.
- the refractory element source(s) optionally may include one or more halides of a refractory element if desired.
- halides include chlorides and fluorides of one or more refractory elements, including HfC , HfF 4 , combinations of these, and the like.
- the amount of Hf source materials desirably is about 0.01 weight percent to about 10 weight percent, preferably about 0.05 weight percent to about 5 weight percent total amount of aluminum source materials, including diluent such as alumina, if any.
- the halide activator includes one or more halide containing compounds including covalent compounds and salts.
- One function of the activator is to provide a chemical species which acts to help transfer the aluminum and/or hafnium from the source materials to the target.
- the activator typically has a sufficiently high vapor pressure at typical coating temperatures that a reasonable reaction time can be achieved.
- Suitable halide activators include ALF 3 , A1C1 3 , NH F, NH 4 CI, NaF, NaCl, KF, KC1.
- Other activators include halide containing compounds such as CrF 2j one or more fluorinated polymers such as polytetrafluoroethylene (PTFE available from E. I. DuPont de Nemours under the trade designation TEFLON), or the like. These preferably are present as a powder within the coating chamber. Vapor phase halides such as HF also may be introduced during the coating process.
- AIF3 is a preferred activator that is preferably used in amounts of about 0.4 to 2.4 moles per cubic foot of the internal volume of chamber 31, preferably of about 1.0 mole to about 1.5 moles per cubic foot of the internal volume of chamber 31. If other halide activators such as those noted are substituted for AIF3, these would be used in amounts sufficient to achieve an equivalent level of activator activity.
- the activator materials are preferably supplied as fine powders having an average size less than 1 mm.
- constituents comprising the one or more aluminum sources, one or more halide activators are placed into the bottom of the processing chamber in trays. Desirably, these are pre-mixed powders. Then, one or more refractory element sources are provided as powders and sprinkled on top of the mixture.
- the aluminum source is obtained by mixing 5 parts by weight of commercially pure aluminum powder with 95 parts by weight of alumina. The aluminum source is pre-mixed with 3 to 10 parts by weight of A1F 3 per 100 parts by weight of aluminum powder and alumina. The refractory element source is 0.15 parts by weight of Hf0 2 powder per 100 parts by weight of aluminum powder and alumina.
- the substrate(s) to be coated are placed onto pre-conditioned supports such as a metal screen to that the substrates are out of contact with the solid coating materials during the coating process.
- the distance between the substrates and the solid coating materials can be changed to adjust the thickness of the resulting coatings.
- a typical distance is in the range from 9 cm to 20 cm.
- the surface 25 of body 11 can be appropriately cleaned, activated, or otherwise treated. For instance, if body 11 is an original or replacement part, the surface can be cleaned. If body 11 is a used part that is being repaired, then a stripping process can be used to remove previous coatings. Stripping can be followed by a suitable surface cleaning operation.
- the practice of the present invention removes at least some oxide from the surface(s) of body 11 during at least one incubation stage, as described below, and this helps to prepare body 11 as well.
- a flow of an inert gas such as argon or nitrogen is initiated and used to purge air from the process chamber prior to heating. After the purge, the flow of inert gas is continued as the process chamber is heated to a temperature that is above the auto ignition temperature of hydrogen. In one mode of practice, the process chamber is heated to 1450 F under a flow of the inert gas. Once this temperature is reached, a flow of hydrogen and/or one or more other suitable reducing gases is introduced into the process chamber. The flow of the inert gas may be continued, reduced, or stopped. In one mode of practice, the flow of inert gas is stopped and a flow of substantially pure hydrogen is established.
- an inert gas such as argon or nitrogen is initiated and used to purge air from the process chamber prior to heating. After the purge, the flow of inert gas is continued as the process chamber is heated to a temperature that is above the auto ignition temperature of hydrogen. In one mode of practice, the process chamber is heated to 1450 F under a flow of the inert gas. Once
- the water content of the hydrogen tends to impact the refractory element content of the resultant coating. Generally, more refractory element is incorporated into the coating when the hydrogen is drier. In many modes of practice, dry hydrogen is used to obtain coatings with higher refractory element content.
- the temperature regime used for the incubation selectively favors oxide removal and formation of reactive Hf species relative to coating formation. Indeed, during experiments, it is believed that little if any aluminide coating formation occurs during the incubation phase at one or more temperatures in the range from 1700 F to 1840 F.
- the time period of the incubation in the temperature range from 1700 F to 1850 F occurs for a time period sufficient to remove at least a portion of the residual oxide on the substrates and to prepare a vapor phase with an enhanced hafnium reactivity content.
- the incubation occurs for a time period from 15 minutes to 5 hours, preferably 30 minutes to 5 hours, more preferably 45 minutes to 5 hours, most preferably 1 hour to 3 hours. In one experiment, holding the sample at 1775°F +/- 25 F for 90 minutes was suitable.
- the process chamber is heated further to the desired coating temperature(s).
- a suitable temperature is in the range from 1900 F to 2100 F.
- the process chamber is held at such temperature(s) for sufficient time to produce a coating of the desired thickness.
- a suitable holding period for this stage is a time period in the range from 3 hours to 10 hours.
- the temperature was rapidly increased to 1975 F and then maintained at this temperature until the desired coating thickness was established.
- the weight percent of refractory elements) incorporated into the coating (based on the total weight of the coating) is greater than the weight percent of the refractory element constituents included in the constituent donor materials (based on the total weight of the aluminum sources).
- both heating and the flow of hydrogen gas is stopped and the process chamber is flushed with a flow of inert gas such as argon.
- the process chamber is cooled under the inert flow to room temperature.
- thermally grown oxide (TGO) layer 14 is provided on protective layer 13.
- the protective coating 13 is sufficiently rich in Al to form a layer 14 that is a protective oxide (TGO) scale of ⁇ - ⁇ 1 2 0 3 .
- the scale may be grown by any suitable oxidizing technique including growing the oxide thermally in an atmosphere including one or more oxidizing agents, chemically oxidizing the coating 13 via application of an oxidizing liquid, combinations of these, and the like.
- the oxide layer 14 helps bond the ceramic topcoat 15 to the protective coating 13.
- Layer 14 is formed by oxidizing layer 13 under conditions to form an oxide scale comprising aluminum oxide.
- a thermally grown oxide forms between a bond coat and a ceramic coat when the surface of the bond coat oxidizes.
- a portion of the thermally grown oxide may grow in situ as the ceramic layer is formed.
- the thermally grown oxide layer forms in situ between the formed bond coat and ceramic coating when the component bearing the bond and ceramic coatings is used in a high temperature environment in which an oxidizing agent is present.
- thermal barrier structure 12 is essentially fully formed before structure 12 is exposed to temperature cycling so that the displacement and stress effects caused by TGO growth between already existing bond coat and ceramic layers is avoided. Adhesion among the layers 13, 14, and 15 as well as between structure 12 and body 11 is substantially improved.
- the thermally grown oxide layer 14 can be formed in a variety of ways. According to one mode of practice, the protective layer 13 is formed on body 11. Then, before the ceramic topcoat is formed, the coated body 11 is placed into a furnace and heated under conditions effective to oxidize the layer 13 to form oxide coating 14. Aluminum oxide forms. Other metals present in layer 13 might also form oxides. The aluminum oxide is formed to a point of oxide saturation after which little to no additional aluminum oxide forms. At this stage, the surface of layer 13 is generally fully oxidized with an oxide coating that forms an impermeable barrier protecting the remainder of layer 13 as well as body 11 against further oxidation.
- the oxide layer 14 A variety of conditions may be used to form the oxide layer 14.
- the oxide generall is formed in the presence of an oxidizing agent.
- Oxygen in the ambient air is one suitable oxidizing agent.
- Other oxidizing agents include ozone, peroxide, combinations of these, and the like.
- An air furnace is an exemplary processing chamber useful for forming the oxide layer 14.
- the temperature used to form the oxide may be selected from a wide range of temperatures. In some modes of practice, using a temperature in the range from about 900 F to about 1500 F, preferably 1200 F to about 1500 F, more preferably 1300 F to 1400 F would be suitable.
- the processing time may occur over a wide range of time periods.
- the processing time occurs for a time period sufficient to fully oxidize the surface of layer 13. More desirably, the processing time occurs for a time period sufficient to reach a point of oxide saturation such that further processing yields little if any additional oxide growth. In some modes of practice, a time period from 2 minutes to 8 hours, preferably 5 minutes to 4 hours, more preferably from about 30 minutes to 2 hours, even more preferably about one hour would be suitable.
- Surface 29 of layer 14 is textured to enhance the adhesion of layer 14 to the ceramic layer 15.
- the texture can be formed in a variety of ways. In some modes of practice, layer 14 is formed as a conformal coating over surface 27 so that the texture of surface 27 is telegraphed to some degree to surface 29. This allows direct texturizing of surface 29 after surface 29 is formed can be avoided. Such direct texturizing creates a risk of abrading through layer 14, losing protection in those through-abraded regions. In other modes of practice, surface 29 can be texturized after surface 29 is initially formed if desired.
- Ceramic topcoat 15 helps to extend the service life of article 10 at least in part by reducing the surface temperature at the surface 17 of thermally grown oxide layer 14 relative to the surface 18 of the topcoat 15. In practice, it is believed that the temperature differential between surfaces 17 and 18 is above 100°C.
- the ceramic topcoat 1 can be formed from a wide variety of ceramic materials. Suitable ceramic materials have one or more of low thermal conductivity, high oxygen permeability, and a relatively high coefficient of thermal expansion.
- the topcoat 15 includes yttria-stabilized zirconia (YSZ) that contains about 2 to about 12 weight percent, preferably about 4 to about 8 weight percent yttrium oxide.
- the topcoat 15 can be formed in a variety of ways. In some embodiments, the topcoat may be applied either by plasma spraying or electron beam physical vapor deposition. Plasma spraying techniques, e.g., air plasma spraying, are preferred. In many embodiments, the topcoat has a thickness of about 100 microns to 400 microns. Because oxide layer 14 is substantially formed prior to formation of ceramic topcoat 15, ceramic topcoat can be formed in a wide variety of conditions, including under ambient conditions. In other modes of practice, ceramic topcoat 15 is formed in a protected environment comprising an inert gas and/or a reducing gas.
- TBC thermal barrier coating
- the coating system was an EBPVD type zirconia ceramic on a platinum aluminide bond coat applied to both X40 and Marm247 vane segments.
- the aluminide coating was present on both the external and internal surfaces of the vane segment with platinum present only on the gas path of the part.
- Aluminide coated vanes from Example 1 were used. The surfaces of the vanes were grit blasted to improve adherence of the plasma sprayed zirconia using 24 grit SiC at 15 PSI.
- One purpose of the roughening is to provide a mechanical lock for the zirconia.
- Grit blasting the aluminide coating is a standard procedure for preparation of the surface for the ceramic coating. Compared to a normal superalloy surface, the aluminide coating applied as a bondcoat is much more brittle and very thin. Therefore, special care was taken to roughen the aluminide surface sufficiently for the zirconia to adhere without completely removing the aluminide bond coat.
- An industry standard yttria stabilized zirconia coating was then applied to the surface of the vane segment using a robot.
- the quality of the ceramic coating was assessed visually.
- the ceramic coating adhered to the aluminide in certain areas of the part but visually flaked in others.
- a vane segment was metallurgical ly sectioned through the airfoil using a diamond saw and then mounted to examine the coating
- vane components were prepared differently than in Examples 1 and 2. Prior to aluminide coating, vane samples were grit blasted with 24 grit SiC at 15 PSI to produce a roughened surface. The aluminide coating was then applied to both the internal and external surfaces of the vanes as described in Example 2, except that the aluminide coatings were not grit blasted.
- the visual appearances of the external surfaces of the aluminide coated vanes showed a rougher surface than the grit-blasted aluminide surfaces of Example 2, although the aluminide coatings of the present example were not as rough as the grit blasted vane surfaces prior to aluminide coating.
- the aluminide coating followed the contours of the vane surface. This smoothed the high peaks, but the aluminide coating did not fill in the surfaces irregularities.
- Example 2 Using the same process as Example 2, the same yttria stabilized zirconia was coated onto the aluminide coated vane samples. Visually, the ceramic coating adhered to more areas of the part than in Example 1. This was attributed to the fact that the vane samples could be grit blasted more aggressively since grit blasting was done before aluminide coating. This avoided the concern that the alumide coating would be blasted off if the grit blasting were practiced too aggressively after aluminide coating. Optionally, the aluminide coatings could be lightly grit blasted or otherwise textured after aluminide coating if desired.
- the coated vane segments were sectioned through the airfoils with a diamond saw.
- the chipping on both the tension and compression sides was reduced relative to Example 2 but not eliminated.
- Metallurgical examination of the coating system microstructure showed the bond coat to be uniform and adequate in thickness. Examination of the interface layer between the oxide layer and the ceramic top coat showed non uniform adherence, however.
- an oxide layer forms on the bond coat during engine operation. If the oxide layer forms after the ceramic layer has been applied or during ceramic layer formation, the growth of the oxide layer introduces a strain which can impair the service life of the coating system. To avoid this, an oxide layer is deliberately thermally grown in the present example to the point of oxide saturation prior to applying the ceramic coating. That is, the oxide grows up to a certain point and then substantially stops growing even with further processing. This point of maximum oxide formation is the point of oxide saturation.
- Example 3 because the aluminide surfaces of Example 3 were already roughened to improve the mechanical adherence, it was proposed to evaluate a coating system using a thermally grown oxide on the roughened, aluminide bond coat surface prior to applying a plasma sprayed yttria stabilized zirconia. This was done because the oxide layer would form subsequently anyway, and it was theorized that an oxide to oxide adhesion would be better than metal to oxide adhesion if the strain effects could be reduced or avoided.
- test vanes were grit blasted and aluminide coated in accordance with Example 3. Following aluminide coating, the parts were heat treated in an air circulating furnace to deliberately create an oxide coating that would form during engine operation between the bond coat and the ceramic coat.
- the vane segments were plasma sprayed to form a ceramic coating on the thermally grown oxide in accordance with Examples 2 and 3. Visually, the ceramic coating was continuously formed and there was no evidence of adherence issues on the samples oxidized at the higher temperatures from 1300F to HOOF anywhere on the parts.
- the vane segments were cut with a diamond saw exposing the coating to both compressive and tensile loads. No chipping was observed on any tension edges. Even when cut in tension, the coatings showed almost no chipping.
- Example 4 The process of Example 4 was repeated multiple times using vane samples in which the thermally grown oxide resulted from oxidation at both 1 50 F and 1400 F. Multiple sections were taken with the diamond saw to verify the eddy current thickness readings with actual thicknesses. Visual evaluation of the coating adherence was excellent and consistent across all samples. Metallurgical inspection of the coating adherence between the bond coat and ceramic top coat validated the excellent visual adherence.
- the substrates included Co-based and Ni-based superalloys.
- the aluminum source included 5 lbs of aluminum powder mixed with 95 lbs of alumina powder. This was mixed with 10 weight percent of A1F 3 based on the total weight of the aluminum source.
- the mixture was placed into a process chamber in trays. Depending upon the run, 0.15 to 0.50 weight percent of H1D2 powder was sprinkled on top of the mixture. The percentage of the hafnium oxide was based on the total weight of the aluminum source and the A1F 3 .
- the substrate was placed into the process chamber and supported on a pre-conditioned mesh above the donor materials.
- the process chamber was purged with argon. Maintaining the flow of argon, the temperature in the process chamber was increased to 1450 F. At this point, a flow of hydrogen was established and maintained while the flow of argon stopped. The temperature was then further increased to 1750°F. At this stage, the temperature ramp rate was substantially reduced so that the sample incubated at 1775°F +/- 25°F for 90 minutes. In accordance with principles of the present invention, it is believed that a substantial portion of the hafma was reduced to one or more reduced species during this time period in this temperature range.
- the process chamber was maintained at 1975 F or 2000 F under a flow of hydrogen for about 6 hours (Ni-based alloy substrates) or about 1 hours (Co-based alloy substrates to complete the formation of the coating on the substrate.
- heating and the flow of hydrogen was stopped, and a flow of argon was established to purge the chamber.
- the chamber contents were cooled to room temperature under the flow of argon. This temperature is suitable when the substrate includes a nickel-based superalloy. For a substrate including a Co-based superalloy, coating temperatures approximately 25°F higher would be more suitable.
- hafnium to exist as discrete particles of hafnium containing compound(s).
- the benefits of hafnium additions of this type to improve the oxidation resistance are well established.
- the weight percent A1F 3 is based on the total weight of the aluminum source.
- the weight percent of the HfO 2 based on the total weight of the aluminum source and A1F 3 .
- hafnium contents in the range from 5 to 39.9 weight percent were achieved using donor materials that included no more than 0.50 weight percent of hafnium oxide.
- conventional vapor phase coating strategies selectively favor aluminum over Hf deposition even when using higher amounts of Hf donor materials are used, the present invention in practical effect reverses this co- deposition selectivity to transfer the Hf consistently and efficiently when co- deposited with aluminum.
- Oxidation resistance at high temperature also was assessed qualitatively. It is known that Hf facilitates oxidation resistance up to a certain level of
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Abstract
The present invention provides strategies for making thermal barrier coating systems that protect metallic substrates in high temperature environments. The coatings show excellent adhesion to substrates as well as among layers of the coatings. The coatings generally include a first coating comprising an aluminide that is formed on the substrate. An oxide layer is formed on this first coating. A third coating comprising a ceramic is then formed on the oxide. An aspect of the present invention is that the oxide is at least partially and more preferably substantially fully formed before the ceramic topcoat is provided.
Description
THERMAL BARRIER SYSTEMS WITH IMPROVED ADHESION
Cross-Reference to Related Application
This application claims the benefit of priority to U.S. Provisional application no. 61/868,877 filed August 22, 2013 entitled "THERMAL BARRIER SYSTEMS WITH IMPROVED ADHESION" the entire disclosure of which is incorporated herein by reference for all purposes.
Field of the Invention
The present invention relates to thermal barrier systems that help to protect metal-containing substrates in high temperature environments. More specifically, the present invention relates to thermal barrier coatings comprising an aluminum- containing base coat, an intermediate thermally grown oxide layer formed on the base coat, and a ceramic topcoat formed on the thermally grown oxide, wherein the thermal barrier system has improved durability and improved resistance to thermal degradation.
Background of the Invention
The function of a gas turbine engine is to convert the energy in hydrocarbon fuel into useful work. The gas turbine accomplishes this by compression of ambient air, addition of fuel to the compressed air, and combustion of the fuel/air mixture to drive a turbine. Good design of the engine components promotes efficient conversion of the energy into useful work. Although component design influences efficiency and power output to some degree, another primary factor affecting engine efficiency and power output is the difference between the ambient temperature of the incoming air and the combustion temperature. The correlation of efficiency and power output to this temperature difference is a principle of basic thermodynamics. This means that greater efficiency and more power generally result with increasing operating temperature of the gas directed to the turbine. In practical terms, this means that the high temperature performance of the turbine components
(combustors, blades and vane segments, for example) is a major factor in increasing engine efficiency and power output of the engine.
The drive to improve engine combustion efficiency and reducing emissions has resulted in a significant increase of the Turbine Inlet Temperatures within gas-
turbine engines since the 1940s. Presently, the high-pressure turbine blades and vanes exposed to hot gases in commercial aeronautical engines typically experience metal surface temperatures of about 1000°C, with short-term peaks as high as 1100°C. In this service environment, significant advances in high temperature capabilities have been achieved through the development of iron, nickel and cobalt- based superalloys and the use of oxidation-resistant environmental coatings capable of protecting the superalloys from oxidation, hot corrosion, etc. The superalloy substrate often provides the basic strength of the component and carries the loads. Further improvements in operating temperature have been achieved through enhancements in cooling schemes such as internal cooling, film cooling, and even transpiration cooling. Grain boundaries are a strengthening mechanism at room temperature but can be a source of failure at elevated temperatures in some current generation engines. Development of specialized casting techniques to control and/or reduce grain boundaries in turbine airfoils has lead to columnar grained and single crystal airfoils.
With the improved cooling, improved crystal structure, and improved alloy chemistry, a limiting factor in turbine performance shifted from the material strength to oxidation life of the components. For instance, the surfaces of the articles to be protected can be protected with an aluminum-containing protective coating whose surface oxidizes to form an aluminum oxide scale that inhibits further oxidation.
The protective coating therefore is sufficiently rich in Al to promote thermal growth of this oxide scale. The scale is also referred to as a thermally grown oxide (TGO).
A conventional bond coat is typically either an MCrAlY overlay (where M is Ni, Co, Fe, or combination of them) or a diffusion aluminide coating. An MCrAlY overlay is generally applied by Electron Beam Physical Vapor Deposition (EB- PVD), High Velocity Oxy-Fuel (HVOF), Low Pressure Plasma Spray (LPPS) or Vacuum Plasma Spray (VPS). Diffusion aluminide coatings are generally formed by chemical vapor deposition (CVD), slurry coating, or by a diffusion process such as pack cementation, above-pack, or vapor (gas) phase deposition. Diffusion aluminide coatings have particularly found widespread use as protective coatings for superalloy components of gas turbine engines due to: (1) the diffusion process is not a line-of-sight process allowing components with complex geometry or with internal
surfaces to be coated; and (2) the diffusion process is generally cost-effective as compared with overlay process.
Refractory elements have been incorporated into aluminide coatings to improve the oxidation protection and adhesion properties provided by these coatings. Examples of refractory elements that have been proposed for aluminide compositions include Hf, Zr, Y, La and/or Ce. With small additions of refractory elements to aluminide coatings, the adherence of the protective oxide scale to the coatings/alloys and the oxidation resistance of the coatings/alloys at high temperature under aggressive atmospheres can be improved.
The significant improvement of oxidation resistance due to Hf addition has been indicated in many cases, such as Hf addition to β-NiAl cast alloys (Pint et al., "Effect of quaternary additions on the oxidation behavior of Hf-doped NiAl,"
Oxidation of Metals, Vol.59, Pages 257-283, 2003), and Hf addition to MCrAlY coatings materials (Giggins Jr., et al., U.S. Patent 3,993,454, and Gupta et al., U.S. Patent 4,585,481). In addition, Hf addition has also been proved that hafnium decreases the propensity for rumpling when it diffuses into the coating and to the growing aluminum oxide increasing their creep resistance (Tolpygo et al, "Effect of Hf, Y and C in the underlying superalloy on the rumpling of diffusion aluminide coatings," Acta Materialia 56, Pages 489^499, 2008) as well as decreases the voids formed in the coating alloy at the metal-oxide interface during oxidation
(Provenzano et al., "Void formation and suppression during high temperature oxidation of MCrAlY-type coatings," Surface and Coatings Technology, 36, Pages 61-74, 1988).
Recently, U.S. Patent No. 7,273,662 to Gleeson et al. taught two-phase γ-Ni + γ' Ni3Al alloy compositions with a purpose of reducing the progressive roughening or "rumpling" of the bond coat surface during thermal exposure.
Due to the significant beneficial effect of Hf addition, diffusion coating processes to incorporate Hf into diffusion aluminide coatings have been studied for several decades. As early as the 1970s, U.S. Pat. No. 3,951,642 and U.S. Pat. No. 3,996,021 to Chang et al. disclosed a pack cementation process to produce Hf modified aluminide coatings. Later, U.S. Pat. No. 5,989,733, U.S. Pat. No.
6, 136,451, U.S. Pat. No. 6,689,422 to Warnes et al. and U.S. Pat. No. 6,602,356 to
Nagaraj et al. disclosed a CVD process to produce Platinum (Pt)-aluminide coatings with or without Hf addition. U.S. Pat. No. 6,514,629 and U.S. Pat. No. 6,582,772 to Rigney et al. taught Hf-Si-modified Pt-aluminide coatings formed by the steps of providing a substrate, depositing layers containing the platinum, aluminum, hafnium, and silicon, and heating the layers so that the aluminum, hafnium, and silicon diffuse into the layer of platinum to form a protective layer.
Pack cementation, CVD and vapor phase process are three potential industrial diffusion coating processes for forming Hf-modified aluminide diffusion coatings. Among them, the vapor phase process has the potential to offer many advantages. The others have drawbacks. Though used with some successes, pack cementation processes for both hafnium-modified aluminide and simple aluminide coatings share the same disadvantages, such as the need for an inert filler, the obstruction of cooling holes, and the embedded particles on the formed coating surface. While avoiding these shortcomings, a significant disadvantage of using a CVD process to form a hafnium-modified aluminide coating is the considerable equipment cost. In view of these disadvantages of pack and CVD processes, alternative deposition methods, such as vapor phase process, have been sought. .
U.S. Pat. No. 6,332,931 to Das et al. disclosed a vapor phase coating process to produce aluminide-hafhide coatings by using Hf metal or Hf-containing metallic alloys as Hf donor materials; as a result, the synthesized coatings contain about 0.5 to about 60 weight percent hafnium and about 12 to about 38 weight percent aluminum. However, too high Hf content in aluminide coatings can lead to the formation of Hf-rich precipitated phases in the coating or on the coating surface, such as HfC, HfD2, andNi2AlHf etc, and furthermore, deteriorate the mechanical properties and the oxidation resistance of the aluminide coatings. Therefore, there is a need to develop low Hf content aluminide coatings whose application on turbine engine components, as either environmental coatings or the bond coat in a thermal barrier coating system, can significantly improve the gas-turbine performance. Due to the difficulty on the control over Hf and Al codeposition and the complex process parameters of the diffusion coating process, even though Hf modified aluminide coatings have been investigated for several decades, very limited information of Hf- modified aluminide diffusion coatings for industrial applications has been reported.
A significant obstacle to the use of vapor phase processes has been the inability to adequately and efficiently control the co-deposition of aluminum and refractory elements, such as Hf, from suitable sources to the article to be coated. Unfortunately, many known vapor phase processes inefficiently and inconsistently use refractory elements. This is a significant drawback not only for performance of the resultant coated articles, but also due to the relative high expense of the refractory elements. Therefore, there is a strong desire and need in the industry to be able to use vapor phase coating techniques in a way that offers improved control over the co-transfer of aluminum and refractory element(s) such as Hf.
The concept of increasing the operating temperature by changing the heat transfer characteristics of engine components also has been investigated. One strategy involves coating an additional layer onto the surface of a substrate, such as an air-cooled superalloy component, wherein the coating includes a material with a thermal conductivity less than that of the superalloy. Ceramic materials are examples of high temperature coating materials that have been used to modify heat transfer characteristics. A ceramic topcoat may be further applied over the aluminum-containing protective layer to help provide a thermal barrier that extends service life. Ceramic materials by nature have a lower thermal conductivity than metals. Surface metal temperature reductions of 250F to300F are theoretically possible with a .005" to .010" thick ceramic layer and use of internal cooling. In actual practice, temperature reductions of about 100F to 18 OF are more likely to be achieved. The protective coating (also referred to as a bond coat), the TGO layer, and the optional ceramic topcoat provide a thermal barrier coating system (TBC) to protect the coated article.
Several challenges exist in applying a ceramic material to a metallic substrate. One challenge is the significant difference in coefficient of thermal expansion (CTE) between the two classes of materials. The difference in CTE characteristics undermines the adhesion between a ceramic coating and a metal substrate. The difference in CTE between the metal and the ceramic will result in very high stresses along the bond interface as the temperature increases. Cooling also causes stresses at the interface, as the metal contracts faster than the ceramic. The stresses tend to cause the ceramic coating to spall, crack, delaminate, chip, or
otherwise degrade. In addition to imparting oxidation resistance, the TGO helps bond the ceramic topcoat to the protective coating.
The spallation and cracking of the thickening TGO scale layer is another failure mechanism of conventional thermal barrier systems. Thus, improving the adhesion and integrity of the interfacial TGO scale is critical to the development of more reliable thermal barrier systems. Ideally, when exposed to high temperatures, the aluminum-containing protective coating should oxidize to form a slow-growing, non- or less "rumpling," nonporous TGO layer that adhere well to the protective coating and the ceramic topcoat.
Summary of the Invention
The present invention provides strategies for making aluminide coatings and corresponding thermal barrier coating systems that protect metallic substrates in high temperature environments.
The coatings show excellent adhesion to substrates as well as among layers of the coatings. The coatings generally include a first coating comprising an aluminide that is formed on the substrate. An oxide layer is formed on this first coating. A third coating comprising a ceramic is then formed on the oxide. An aspect of the present invention is that the oxide is at least partially and more preferably substantially fully formed before the ceramic topcoat is provided.
Otherwise, the oxide will form in situ between the already existing first and third coatings and then act like a wedge to break the interface between the first and third coatings.
The improvement in adhesion is dramatic. When practicing principles of the present invention, a coating can be severely stressed by sectioning with a diamond saw. Even though sectioning like this causes cut edges to be under compression or tensile stresses, very little if any chipping can be visually observed on the sectioned edges in preferred embodiments. In contrast, without practicing the principles of the present invention, sectioning causes significant chipping, cracking, and delamination in coatings in which the oxide is allowed to form later
In some preferred embodiments, vapor phase coating techniques optionally are used in manner that efficiently and consistently incorporate refractory element content into the aluminide coatings. The coatings show excellent adhesion to
substrates as well as among layers of the coatings. The coatings generally include a first coating comprising an aluminide that is formed on the substrate. In some embodiments, an oxide layer optionally is formed on this first coating. In some embodiments, a third coating comprising a ceramic optionally is then formed on the oxide.
In this preferred aspect of the present invention, the aluminide coating deposition desirably incorporates two heating stages. A first heating stage occurs in the presence of a reducing gas under conditions that significantly increase or otherwise favor the formation of refractory element-containing species in the vapor phase. The result is that surprisingly high levels of refractory element content can be incorporated into the resultant coatings in the second stage even when the donor materials contain relatively little refractory element content. For example, refractory element donor materials are used so efficiently that donor materials that include under 1 weight percent of refractory element donor compounds based on the total weight of aluminum sources can provide coatings with over 5 weight percent of the refractory element. The process provides uniform coatings and is consistent from run to run.
The present invention may be used to apply coatings that protect any articles from a hostile operating environment. In preferred modes of practice, the coatings protect against oxidation, hot corrosion, or other degradation in high temperature and/or chemically hostile environments. A wide range of articles can be protected by these coatings, including turbine engine hot zone components, blades, vanes, combustors transition pieces, and the like.
In one aspect, the present invention relates to a method of forming a thermal barrier coating comprising:
(a) providing a substrate comprising at least one metallic surface;
(b) roughening at least a portion of the metallic surface
(c) forming a coatingon at least a portion of the roughened surface of the substrate, wherein the coating comprises at least one aluminide; and (d) treating the aluminide coating under conditions effective to form an oxide coating on the aluminide coating;
(e) after forming the oxide coating, forming a third coating on the oxide coating, said third coating comprising at least one ceramic material. In another aspect, the present invention relates to a method of refurbishing a coated article comprising:
(a) providing an article having a metallic surface an a coating on at least a portion of the metallic surface;
(b) treating the article under conditions effective to remove at least a portion of the coating from the metallic surface, wherein said treatment roughens at least a portion of the metallic surface from which the coating is removed;;
(c) forming a coating on at least a portion of the roughened surface, said coating comprising at least one aluminide;
(d) treating the aluminide coating under conditions effective to form an oxide coating on the aluminide coating;
(e) after forming the oxide coating, forming a third coating on the oxide coating, said third coating comprising at least one ceramic material.
Brief Description of the Drawings
The above mentioned and other advantages of the present invention, and the manner of attaining them, will become more apparent and the invention itself will be better understood by reference to the following description of the embodiments of the invention taken in conjunction with the accompanying drawings, wherein:
FIG. 1 is a cross-sectional diagram of a metallic article with a thermal barrier coating of the present invention.
Detailed Description of the Presently Preferred Embodiments
The embodiments of the present invention described below are not intended to be exhaustive or to limit the invention to the precise forms disclosed in the following detailed description. Rather the embodiments are chosen and described so that others skilled in the art may appreciate and understand the principles and practices of the present invention.
FIG. 1 schematically shows a cross-section of a portion of a coated article 10 manufactured in accordance with principles of the present invention. In
representative embodiments, article 10 is a constituent of a rocket, missile, aircraft,
marine vessel, industrial facility, power utility, electric motor, chemical
manufacturing facility, heat exchanger, and/or the like. The principles of the present invention are desirably practiced in such applications where protection against oxidation in a high temperature environment, e.g., above about 450°C, preferably above about 650°C, more preferably above about 850°C, is desired. In preferred embodiments, article 10 is a constituent of a gas turbine engine such as being all or a portion of a high pressure turbine nozzle, low pressure turbine nozzle, turbine shroud, turbine blade, turbine vanes, and/or the like. Article 10 can be a new part, a replacement part, or a repaired or refurbished part. The article 10 can be casted, molded, machined, directionally solidified (DS), fabricated from a single crystal (SX), and/or fabricated in any other desired method.
The article 10 includes a body 11 that serves as a substrate for thermal barrier structure 12. Body 11 includes a metallic composition that may be a pure metal, an intermetallic composition, an alloy, combinations of these and the like. The body may contain a single phase or may contain multiple phases, e.g., an alloy matrix with intermetallic precipitates. Body 11 may be amorphous, crystalline, and/or the like. In addition to metal and/or intermetallic constituents, body 11 may also contain other constituents. For instance, body 11 may be a composite that includes a metallic matrix and fibers (not shown) or the like.
In preferred embodiments, body 11 includes nickel (Ni)-base, cobalt (Co)- base, titanium (Ti)-base, or iron (Fe)-base alloys. The term "Ni-base alloy" means that Ni is the dominant element in the alloy. That is, more Ni is present than any other individual metal element in the alloy. Similarly, Co, Ti, and Fe are the dominant element in Co-base, Ti-base, and Fe-base alloys, respectively. The alloy may include one or more other alloying elements such as chromium, aluminum, titanium, molybdenum, iron, manganese, tungsten, boron, niobium, tantalum, cobalt, silicon, rhenium, platinum, hafnium, zirconium, yttrium, combinations of these and the like. In some embodiments, alloys of nickel, cobalt, and/or nickel-iron (with or without other alloying elements) are known as superalloys due to excellent mechanical strength, creep resistance and good surface stability at high
temperatures. Examples of superalloys are available under trade designations including HASTELLOY X, INCONEL 738, INCONEL 100, INCONEL 713,
INCONEL 792, INCONEL 792-DS, INCONEL 792-SX, INCO EL 939,
WASPALOY™, RENE™ (e.g. RENE 41, RENE 80, RENE 95, and RENE 141), HAYNES-188, HAYNES-L605, INCOLOY™, MP98T, TMS, X40, MAR-M-247, CMSX-4, and CMSX-6.
Optionally, body 11 may include one or more layers. For instance, in some instances, a layer of platinum (not shown) may be deposited to form a surface layer on at least a portion of body 11. At high temperatures, the platinum can diffuse and incorporate into the protective coating 13 so that such separate layer of platinum may have dissipated at least into coating 13 after some period of use. In many embodiments, platinum can help to enhance the oxidation protection of body 11. The incorporation of platinum also can enhance the mechanical properties of the aluminide coatings. Optionally, all or selected portion(s) of body 11 can be coated with a layer comprising Pt and heat treated. The platinum can be deposited by any suitable method. Preferably, the platinum is deposited using an electroplating process and a suitable platinum source, such as a Pt P-salt with a formula of
Pt(NH3)2(N02)2 or Pt Q-salt with a formula of [Pt(NH3)4]HP04. However, due to the extra expense, using a platinum layer may not be cost effective in .some modes of practice.
The surface 25 of body 11 optionally may be textured to enhance the bonding of layer 13 to body 11. The texture on surface 25 can be formed by a variety of techniques including molding the texture when body 11 is formed, embossing, chemical etching, sand blasting or otherwise abrading, laser ablation, combinations of these, and the like. When refurbishing components, sand blasting is a preferred technique to form the texture.
Thermal barrier structure 12 is provided on body 11. Thermal barrier structure 12 includes protective coating 13, a thermally grown oxide layer 14, and a ceramic topcoat 15. Protective coating 13 helps to protect body 11 against oxidation, particularly in high temperature environments (e.g., environments in which the temperature is above about 450°C, preferably above about 650°C, more preferably above about 850°C). In the practice of the present invention, protective coating 13 comprises at least one aluminide. As used herein, an aluminide refers to a metal compound comprising aluminum at and least one other more electropositive
metal element. In many forms, an aluminide is a metallic solid solution or an intermetallic composition. Examples of suitable aluminides include nickel aluminide, cobalt aluminide, combinations of these, and the like. The protective coating 13 may be a single phase or may include one or more additional phases.
Aluminide compositions comprising at least (a) aluminum and (b) nickel and/or Co are preferred. In the present invention, nickel aluminides and/or cobalt aluminides containing from about 45 to about 70 atomic percent Ni and/or Co based on the total amount of nickel, cobalt, and aluminum are preferred. Such compositions provide a good balance between high temperature oxidation resistance and acceptable mechanical properties.
One or more refractory elements also may be incorporated into all or a portion of the aluminide content of coating 13 if desired. As used herein, a refractory element refers to a metal element having a melting point greater than about 795°C, preferably greater than 1100°C, more preferably greater than 1850°C. Examples of suitable refractory elements include one or more of Hf, Zr, Y, La, Ce, rhenium, osmium, and combinations of these. Of these, hafnium (Hf), zirconium (Zr), yttrium (Y), lanthanum (La), cerium (Ce), and combinations of these are preferred. In more preferred embodiments, coating 13 comprises at least one of Hf, Zr, and/or Y, most preferably Hf. Advantageously, the refractory element content offers excellent oxidation protection by minimizing the amount of oxidized scale and enhancing the adherence of the scale to the protective coating system 12. The refractory elements may be present in coating 13 in a variety of forms including as metals, dopants, or non-metal compounds such as oxides, nitrides, carbides, combinations of these, or the like. These may be present in the same phase as other aluminide content or in separate phase(s).
The amount of refractory elements) incorporated into coating 13 may vary over a wide range. If the content is too low, the content may not enhance oxidation resistance and/or adhesion as much as might be desired. If the content is too high, i.e. >15%, then oxidation resistance may not be further enhanced and may even be reduced. Balancing such concerns, coatings 13 may incorporate from 0.01 to 30 weight percent, preferably 0.1 to 20 weight percent, and more preferably 1 to 15
weight percent of refractory element(s) present in the surface of a coating as determined using SEM EDS spectroscopy techniques described below.
If a refractory element is present in coating 13 as an oxide, halide, nitride, carbide, salt, or other compound, e.g., Hf(¼ or the like, the weight percent of refractory element in the coating is based on the amount of refractory element(s) that are present, not the compound(s) including the refractory element(s). For instance, if a particular coating includes 90 parts by weight of nickel aluminide and 10 parts by weight of Hf02, the hafnium oxide content is 10% but the Hf content is 8.5% as determined by SEM EDS spectroscopy.
The weight percent of the refractory element(s) in the coating is based upon the total weight of all elements within the surface areas analyzed using SEM EDS techniques. In the practice of the present invention, a JEOL model 6610 scanning electron microscope equipped for energy dispersive spectroscopy (EDS) is used to determine the amount of refractory element(s) (such as hafnium) present in the surface of a coating, expressed as a weight percent. To determine such weight percents, 3 areas of a substrate are scanned at 20Kv, 50X magnification for 30 seconds from a working distance of 12 mm. The weight percent of each area is then determined from the SEM EDS data. The weight percent is taken as an average from the 3 areas. Scans may be taken on flat, concave, or convex areas such as the concave and convex airfoil as well as the buttress.
As coating 13 is formed (described in more detail below for an illustrative embodiment), a portion of the material that forms coating 13 tends to form an outward-growth coating portion 7 generally over the surface of body 11. Another portion of the material will tend to interdiffuse into and with the material of body 11, forming an interdiffusion zone 9 that extends to some depth into body 11. At the same time, some of the constituents of body 11 may diffuse into the deposited coating 13. For purposes of the present invention, interdiffusion zone 9 is considered to be a portion of the coating 13 even though it extends downward into body 11. Protective coatings 13 of the invention may include refractory element content within the outward growth portion 7 and/or the interdiffusion zone 9 of coating 13.
The coating 13 may have a thickness within a wide range. The thickness mentioned here is the total thickness of the outward growth portion 7 and the interdiffusion zone 9. In many embodiments, a suitable thickness for coating 13 is similar to the thickness of conventional industrial coatings, typically about 25 to 125 micrometers (about 0.001- 0.005 inch).
Surface 27 of layer 13 optionally may be textured to enhance the adhesion of layer 13 to the oxide layer 14. The texture can be formed in a variety of ways. In some modes of practice, layer 13 is formed as a conformal coating over surface 25 so that the texture of surface 25 (if any) is telegraphed to some degree to surface 27 so that direct texturing of surface 27 after surface 27 is formed can be avoided. Such direct texturing creates a risk of abrading through layer 13, losing protection in those through-abraded regions. In other modes of practice, surface 27 can be texturized after surface 27 is initially formed if desired.
In illustrative modes of practice, protective coating 13 is formed using vapor phase coating techniques, including chemical (CVD) and/or physical (PVD) vapor deposition. For purposes of illustration, the process will be described in the context of preparing Hf-containing aluminide coatings in which Hf is obtained from one or more sources including an oxide, nitride, and/or carbide of Hf such as Hf02. It will be understood that coatings including one or more of the other refractory elements could be prepared by replacing all or a portion of the Hf sources described herein with comparable sources of one or more of the other refractory elements.
As an overview of one such process, at least one substrate including at least body 11 is placed into a processing chamber and suitably supported so that contact between the substrate and generated vapors causes the desired coating to form under suitable conditions. These conditions include carrying out the process at suitable temperatures in the presence of a reducing gas such as hydrogen. One suitable process chamber is described in WO 2010/135144, the entirety of which is incorporated herein by reference for all purposes. The supports on which substrates are supported desirably are pre-conditioned in order to enhance coating
performance, e.g., improving the uniformity and consistency of the coating process. Pre-conditioning involves subjecting the supports to the coating process one or more times in the absence of any substrate(s). Optionally, the resultant aluminide
coating may be heat treated to adjust the coating microstructure and composition distribution. Further background on using vapor phase coating techniques to form aluminide coatings are described in WO 2010/135144, the entirety of which is incorporated herein by reference for all purposes.
In more detail, the aluminide coatings of the present invention may be obtained from ingredients comprising at least one aluminum source, at least one non-halide compound of at last one refractory element, and a halide activator. These ingredients may be supplied in any convenient form such as a fine powder, nuggets, pellets, granules, flakes, or the like. These can be supplied in any convenient shape, such as irregular, dendritic, acicular, cubic, spheroidal, fibrous, combinations of these, and the like.
Aluminum used to form the aluminide content of coating 13 may be derived from a variety of sources. In one mode of practice, the aluminum is obtained from commercially pure aluminum powder that may be mixed with an inert material such as alumina for easier handling and to reduce the risk of sintering. In an exemplary mode of practice, an aluminum source includes 1.5 to 10 parts by weight of commercially pure aluminum powder per about 100 parts by weight of alumina. The aluminum and alumina are powders of a size large enough to avoid undue sintering while small enough to react well. In one mode of practice 200 mesh aluminum powder and 100 mesh alumina would be suitable.
Other aluminum sources include any aluminum containing material(s) suitable for use in physical or chemical vapor deposition in which an aluminum containing vapor is generated from the source and caused to form coating on the desired substrate. For example, other aluminum sources include Al-rich alloys and/or intermetallic compositions optionally containing other elements such as those other metals and refractory elements described herein with respect to forming aluminide compositions. Examples include Cr, Co, Ni, Fe, Mo, W, Mn, Ti, Y, Zr, Pt, Hf, combinations of these, or the like. The Al content in such sources desirably is about 3 weight percent to about 99 weight percent, preferably from about 15 weight percent to about 50 weight percent based on the total weight of the source material. The remainder of the source may be one or more of the other elements
described herein and/or compounds of such elements. An exemplary alloy source includes from about 25 weight percent to 35 weight percent aluminum.
In some modes of practice, aluminum incorporated into aluminum sources desirably is obtained from natural resources containing very little if any sulfur in order to exclude sulfur as much as practical from coating 13. Sulfur may tend to segregate to surfaces and could then adversely impact the oxide layer to base metal adhesion. In contrast, a superalloy such as the Mar M 247 alloy with less than 1 PPM bulk sulfur by weight tends to form a very adherent aluminum oxide just from the ~5.0% Al present for base material strength. Such a low sulfur alloy does not require the typical local enrichment of the component surface with aluminum using standard aluminide coating techniques. More preferred aluminum sources include sufficiently limited amounts of sulfur (if any) such that the resultant layer 13 includes less than 500 ppm, preferably less than 100 ppm, and even less than 10 ppm sulfur on a weight basis. Bauxite is a natural resource from which substantially sulfur-free aluminum can be obtained. Accordingly, aluminum sources derived from bauxite are preferred, particularly commercially pure aluminum powder.
Consequently, it also is desirable to minimize or avoid using aluminum donor materials which are alloyed with chromium. Chromium ores are largely sulfide type ores which often include substantial trace amounts of sulfur even after extensive refining. Aluminum donor materials containing chromium could include undue amounts of sulfur that could unduly contaminate the resultant aluminide coating. In many embodiments, therefore, it is preferred that chromium also is excluded from aluminum sources, and hence coating 13, as much as possible. Therefore, it is desirable that layer 13 includes less than 500 ppm, preferably less than 100 ppm, and even less than 10 ppm chromium on a weight basis.
When using a process chamber such as that described in PCT Patent Publication WO 2010/135144 (the entirety of which is incorporated herein by reference for all purposes), the amount of aluminum source materials desirably is about 0.3 kg to about 7 kg per cubic foot of the internal volume of the processing chamber, preferably from about 2 kg to about 4 kg per cubic foot of the internal volume of the chamber. This does not include diluent material, such as alumina, if included.
The additional metal elements (e.g, platinum, palladium, nickel, cobalt, titanium, chromium, silicon, combinations of these, and the like) used to form the aluminide(s) may be introduced from one or more sources including from substrate body 11, from the aluminum source(s), and/or from one or more independent source(s). Such elements may then react with the aluminum to form one or more aluminides. For example, as aluminum is deposited onto body 11 to form layer 3, one or more metallic constituents of body 11 such as Ni may diffuse or otherwise be incorporated into layer 13. The nickel and aluminum react to form nickel aluminide. From one perspective, such a process can be viewed as enriching the surface of body 11 to form an aluminum rich region constituted by layer 13.
The optional refractory element(s) may be provided by one or more sources wherein at least a portion of at least one source, preferably substantially all of the source, includes a non-halide compound of the element such as a salt, a metallic compound, an oxide, other oxygen-containing compound, nitride, carbide, and/or the like. Desirably, at least 25 weight percent, preferably at least aboiit 50 weight percent, more preferably substantially all of the refractory element source(s) are such compound(s). Oxide sources are preferred. In an illustrative embodiment, a preferred Hf source is HfO2. Advantageously, using an oxide of Hf as a source provides excellent control over the Hf activity when using vapor phase techniques for co-deposition of Hf and aluminum.
The refractory element source(s) optionally may include one or more halides of a refractory element if desired. Examples of such halides include chlorides and fluorides of one or more refractory elements, including HfC , HfF4, combinations of these, and the like.
In illustrative modes of practice, the amount of Hf source materials desirably is about 0.01 weight percent to about 10 weight percent, preferably about 0.05 weight percent to about 5 weight percent total amount of aluminum source materials, including diluent such as alumina, if any.
The halide activator includes one or more halide containing compounds including covalent compounds and salts. One function of the activator is to provide a chemical species which acts to help transfer the aluminum and/or hafnium from the source materials to the target. The activator typically has a sufficiently high
vapor pressure at typical coating temperatures that a reasonable reaction time can be achieved. Suitable halide activators include ALF3, A1C13, NH F, NH4CI, NaF, NaCl, KF, KC1. Other activators include halide containing compounds such as CrF2j one or more fluorinated polymers such as polytetrafluoroethylene (PTFE available from E. I. DuPont de Nemours under the trade designation TEFLON), or the like. These preferably are present as a powder within the coating chamber. Vapor phase halides such as HF also may be introduced during the coating process.
AIF3 is a preferred activator that is preferably used in amounts of about 0.4 to 2.4 moles per cubic foot of the internal volume of chamber 31, preferably of about 1.0 mole to about 1.5 moles per cubic foot of the internal volume of chamber 31. If other halide activators such as those noted are substituted for AIF3, these would be used in amounts sufficient to achieve an equivalent level of activator activity. The activator materials are preferably supplied as fine powders having an average size less than 1 mm.
According to one methodology, constituents comprising the one or more aluminum sources, one or more halide activators are placed into the bottom of the processing chamber in trays. Desirably, these are pre-mixed powders. Then, one or more refractory element sources are provided as powders and sprinkled on top of the mixture. In one mode of practice, the aluminum source is obtained by mixing 5 parts by weight of commercially pure aluminum powder with 95 parts by weight of alumina. The aluminum source is pre-mixed with 3 to 10 parts by weight of A1F3 per 100 parts by weight of aluminum powder and alumina. The refractory element source is 0.15 parts by weight of Hf02 powder per 100 parts by weight of aluminum powder and alumina.
The substrate(s) to be coated are placed onto pre-conditioned supports such as a metal screen to that the substrates are out of contact with the solid coating materials during the coating process. The distance between the substrates and the solid coating materials can be changed to adjust the thickness of the resulting coatings. A typical distance is in the range from 9 cm to 20 cm. Optionally, the surface 25 of body 11 can be appropriately cleaned, activated, or otherwise treated. For instance, if body 11 is an original or replacement part, the surface can be cleaned. If body 11 is a used part that is being repaired, then a stripping process can
be used to remove previous coatings. Stripping can be followed by a suitable surface cleaning operation. The practice of the present invention removes at least some oxide from the surface(s) of body 11 during at least one incubation stage, as described below, and this helps to prepare body 11 as well.
A flow of an inert gas such as argon or nitrogen is initiated and used to purge air from the process chamber prior to heating. After the purge, the flow of inert gas is continued as the process chamber is heated to a temperature that is above the auto ignition temperature of hydrogen. In one mode of practice, the process chamber is heated to 1450 F under a flow of the inert gas. Once this temperature is reached, a flow of hydrogen and/or one or more other suitable reducing gases is introduced into the process chamber. The flow of the inert gas may be continued, reduced, or stopped. In one mode of practice, the flow of inert gas is stopped and a flow of substantially pure hydrogen is established.
The water content of the hydrogen tends to impact the refractory element content of the resultant coating. Generally, more refractory element is incorporated into the coating when the hydrogen is drier. In many modes of practice, dry hydrogen is used to obtain coatings with higher refractory element content.
After the flow of hydrogen and/or other reducing gas is established, the flow is maintained. The process chamber is further heated to increase the temperature as rapidly as practical to a temperature in the range from about 1700 F to about 1850F. The substrate(s) are then held in this temperature range for an extended period. The reason for doing this is that, in this temperature range, it is believed that equilibria tend to favor that the aluminum trifluoride reacts with hydrogen to form HF. HF is a strong oxide reducer that helps to remove residual oxides on the surface of the substrates. Mixtures of hydrogen and hydrogen fluoride have been used in the past to remove residual oxides and is referred to as in situ fluoride ion cleaning (FIC). However, it is believed that FIC has not been practiced to make aluminide coatings in the presence of nonhalide compounds of refractory elements such as Hf oxide.
At the same time, and without wishing to be bound by theory, it is believed that the HF (and/or other reaction product(s) of the halide activator and hydrogen) reacts with the hafnium oxide in a manner that significantly increases the amount of reactive Hf-containing species in the vapor phase to form the coatings. In practical
effect, incubation in this first heating stage occurs under conditions effective to form one or more reaction products from one or more of the donor constituents in a manner that favors more efficient incorporation of refractory elements into the coating. Experiments have shown that carrying out this incubation in the presence of hydrogen and the oxide significantly increases the Hf content of the resultant coating than if the process were to be carried out in an inert gas or in a reducing gas without incubation. Remarkably, coatings including 8 to 14 weight percent of Hf based on the total weight of the coating can be made from donor materials that include only 0.15 weight percent of Hf oxide based on the total weight of aluminum and alumina sources.
In contrast, using a conventional approach without reducing gas and the incubation yields coatings with only 0.35 weight percent Hf from donor sources including 4.5 weight percent Hf oxide. The present invention uses less Hf content in the sources and yet provides significantly more Hf in the coating by one to two orders of magnitude! The present invention significantly improves the efficiency of vapor phase deposition of hafnium and aluminum compared to what has been accomplished previously.
It is also believed that the temperature regime used for the incubation selectively favors oxide removal and formation of reactive Hf species relative to coating formation. Indeed, during experiments, it is believed that little if any aluminide coating formation occurs during the incubation phase at one or more temperatures in the range from 1700 F to 1840 F.
The time period of the incubation in the temperature range from 1700 F to 1850 F occurs for a time period sufficient to remove at least a portion of the residual oxide on the substrates and to prepare a vapor phase with an enhanced hafnium reactivity content. In exemplary modes of practice, the incubation occurs for a time period from 15 minutes to 5 hours, preferably 30 minutes to 5 hours, more preferably 45 minutes to 5 hours, most preferably 1 hour to 3 hours. In one experiment, holding the sample at 1775°F +/- 25 F for 90 minutes was suitable.
After the incubation, the process chamber is heated further to the desired coating temperature(s). A suitable temperature is in the range from 1900 F to 2100 F. The process chamber is held at such temperature(s) for sufficient time to
produce a coating of the desired thickness. A suitable holding period for this stage is a time period in the range from 3 hours to 10 hours. In an exemplary experiment, the temperature was rapidly increased to 1975 F and then maintained at this temperature until the desired coating thickness was established. Although the coating reaction proceeds at a suitable rate during this stage, it is believed that the reaction to produce additional reactive Hf species may still be occurring. The weight percent of refractory elements) incorporated into the coating (based on the total weight of the coating) is greater than the weight percent of the refractory element constituents included in the constituent donor materials (based on the total weight of the aluminum sources).
To stop the coating reaction, both heating and the flow of hydrogen gas is stopped and the process chamber is flushed with a flow of inert gas such as argon. The process chamber is cooled under the inert flow to room temperature.
Referring again to Fig. 1, thermally grown oxide (TGO) layer 14 is provided on protective layer 13. Desirably, the protective coating 13 is sufficiently rich in Al to form a layer 14 that is a protective oxide (TGO) scale of α-Α1203. The scale may be grown by any suitable oxidizing technique including growing the oxide thermally in an atmosphere including one or more oxidizing agents, chemically oxidizing the coating 13 via application of an oxidizing liquid, combinations of these, and the like. In addition to imparting oxidation resistance, the oxide layer 14 helps bond the ceramic topcoat 15 to the protective coating 13.
Layer 14 is formed by oxidizing layer 13 under conditions to form an oxide scale comprising aluminum oxide. Under conventional practices, a thermally grown oxide forms between a bond coat and a ceramic coat when the surface of the bond coat oxidizes. Conventionally, a portion of the thermally grown oxide may grow in situ as the ceramic layer is formed. In other practices, the thermally grown oxide layer forms in situ between the formed bond coat and ceramic coating when the component bearing the bond and ceramic coatings is used in a high temperature environment in which an oxidizing agent is present.
In contrast, in the practice of the present invention, at least a majority of, preferably substantially all of, the thermally grown oxide layer 14 is formed in situ on protective layer 13 before the ceramic topcoat layer 15 is formed. In this way,
thermal barrier structure 12 is essentially fully formed before structure 12 is exposed to temperature cycling so that the displacement and stress effects caused by TGO growth between already existing bond coat and ceramic layers is avoided. Adhesion among the layers 13, 14, and 15 as well as between structure 12 and body 11 is substantially improved.
The thermally grown oxide layer 14 can be formed in a variety of ways. According to one mode of practice, the protective layer 13 is formed on body 11. Then, before the ceramic topcoat is formed, the coated body 11 is placed into a furnace and heated under conditions effective to oxidize the layer 13 to form oxide coating 14. Aluminum oxide forms. Other metals present in layer 13 might also form oxides. The aluminum oxide is formed to a point of oxide saturation after which little to no additional aluminum oxide forms. At this stage, the surface of layer 13 is generally fully oxidized with an oxide coating that forms an impermeable barrier protecting the remainder of layer 13 as well as body 11 against further oxidation.
A variety of conditions may be used to form the oxide layer 14. The oxide generall is formed in the presence of an oxidizing agent. Oxygen in the ambient air is one suitable oxidizing agent. Other oxidizing agents include ozone, peroxide, combinations of these, and the like. An air furnace is an exemplary processing chamber useful for forming the oxide layer 14. The temperature used to form the oxide may be selected from a wide range of temperatures. In some modes of practice, using a temperature in the range from about 900 F to about 1500 F, preferably 1200 F to about 1500 F, more preferably 1300 F to 1400 F would be suitable. The processing time may occur over a wide range of time periods.
Desirably, the processing time occurs for a time period sufficient to fully oxidize the surface of layer 13. More desirably, the processing time occurs for a time period sufficient to reach a point of oxide saturation such that further processing yields little if any additional oxide growth. In some modes of practice, a time period from 2 minutes to 8 hours, preferably 5 minutes to 4 hours, more preferably from about 30 minutes to 2 hours, even more preferably about one hour would be suitable.
Surface 29 of layer 14 is textured to enhance the adhesion of layer 14 to the ceramic layer 15. The texture can be formed in a variety of ways. In some modes of
practice, layer 14 is formed as a conformal coating over surface 27 so that the texture of surface 27 is telegraphed to some degree to surface 29. This allows direct texturizing of surface 29 after surface 29 is formed can be avoided. Such direct texturizing creates a risk of abrading through layer 14, losing protection in those through-abraded regions. In other modes of practice, surface 29 can be texturized after surface 29 is initially formed if desired.
Ceramic topcoat 15 helps to extend the service life of article 10 at least in part by reducing the surface temperature at the surface 17 of thermally grown oxide layer 14 relative to the surface 18 of the topcoat 15. In practice, it is believed that the temperature differential between surfaces 17 and 18 is above 100°C.
The ceramic topcoat 1 can be formed from a wide variety of ceramic materials. Suitable ceramic materials have one or more of low thermal conductivity, high oxygen permeability, and a relatively high coefficient of thermal expansion. In a representative embodiment, the topcoat 15 includes yttria-stabilized zirconia (YSZ) that contains about 2 to about 12 weight percent, preferably about 4 to about 8 weight percent yttrium oxide.
The topcoat 15 can be formed in a variety of ways. In some embodiments, the topcoat may be applied either by plasma spraying or electron beam physical vapor deposition. Plasma spraying techniques, e.g., air plasma spraying, are preferred. In many embodiments, the topcoat has a thickness of about 100 microns to 400 microns. Because oxide layer 14 is substantially formed prior to formation of ceramic topcoat 15, ceramic topcoat can be formed in a wide variety of conditions, including under ambient conditions. In other modes of practice, ceramic topcoat 15 is formed in a protected environment comprising an inert gas and/or a reducing gas.
The principles of the present invention will now be described with respect to the following illustrative examples.
Example 1
Alumiiiide coated vaae segments
Several first stage vane segments of a Rolls Royce 50 IK engine was removed for evaluation and replacement of the thermal barrier coating (TBC). The 50 IK engine is a variant of a 4000 SHP gas turbine developed for aircraft propulsion in the mid 1950's known as the T56. The current version of the T56, the T56-A-15,
utilizes many of the same components as the 50 IK. While the T56 is a flight engine which experiences relatively frequent cycling, the version of the 50 IK engine of interest is used for power generation. With a conventional thermal barrier coating (TBC) system on the first stage vanes, the engine operates approximately 18,000 hours running 24/7 with a shutdown for inspection about every 4 months or 2500 hours of running time. A current limitation to time between overhauls is adherence of the thermal barrier coating on the first stage vane segments.
Analysis of the vane segments showed that the coating system was an EBPVD type zirconia ceramic on a platinum aluminide bond coat applied to both X40 and Marm247 vane segments. The aluminide coating was present on both the external and internal surfaces of the vane segment with platinum present only on the gas path of the part.
Based on the type of application, the use of the highly strain compliant EBPVD type ceramic does not appear necessary given the roughly 2500 hour duration cycle. In fact, it would appear that based on cost and intended usage, an air plasma sprayed ceramic coating would be more cost effective and protect the substrate more effectively due to the lower thermal conductivity of the plasma sprayed versus EBPVD structure. > To evaluate the potential of use of the plasma sprayed structure versus the EBPVD zirconia, a vapor phase coating process to coat the internal and external surfaces of the 50 IK first stage vane was used to coat the vane segment with an aluminide coating. The aluminide coated vane segments were then used in the experiments described below in Examples 2, 3, and 4. A group of test parts was coated targeting about 2.5 to 3.0 mils of aluminide coating with a basic chemistry similar to current industry standards except in this case there was no precoat platinum additions via electroplating.
Example 2
Applying ceramic coating directly to grit blasted aluminide coating Aluminide coated vanes from Example 1 were used. The surfaces of the vanes were grit blasted to improve adherence of the plasma sprayed zirconia using 24 grit SiC at 15 PSI. One purpose of the roughening is to provide a mechanical
lock for the zirconia. Grit blasting the aluminide coating is a standard procedure for preparation of the surface for the ceramic coating. Compared to a normal superalloy surface, the aluminide coating applied as a bondcoat is much more brittle and very thin. Therefore, special care was taken to roughen the aluminide surface sufficiently for the zirconia to adhere without completely removing the aluminide bond coat. An industry standard yttria stabilized zirconia coating was then applied to the surface of the vane segment using a robot.
The quality of the ceramic coating was assessed visually. The ceramic coating adhered to the aluminide in certain areas of the part but visually flaked in others.
Additionally, a vane segment was metallurgical ly sectioned through the airfoil using a diamond saw and then mounted to examine the coating
microstructure. Visual examination of the cut edge of the airfoil showed areas where the ceramic coating had adhered when cut in compression. However, in areas where the ceramic coating was in tension, the ceramic coating was substantially chipped off of the vane. Metallurgical examination of the coating microstructure showed the aluminide bond coat to be thin and varying in thickness due to the grit blasting with the 24 grit SiC. Adherence between the aluminide bond coat and ceramic coating was not continuous and correlated with the visual appearance of the vane segment.
Example 3
Applying aluminide and ceramic coatings to grit blasted vane segment
To avoid thinning the aluminide bond coat by grit blasting with SiC prior to application of the ceramic and yet still get the roughened surface desirable for the ceramic to adhere, vane components were prepared differently than in Examples 1 and 2. Prior to aluminide coating, vane samples were grit blasted with 24 grit SiC at 15 PSI to produce a roughened surface. The aluminide coating was then applied to both the internal and external surfaces of the vanes as described in Example 2, except that the aluminide coatings were not grit blasted.
The visual appearances of the external surfaces of the aluminide coated vanes showed a rougher surface than the grit-blasted aluminide surfaces of Example
2, although the aluminide coatings of the present example were not as rough as the grit blasted vane surfaces prior to aluminide coating. The aluminide coating followed the contours of the vane surface. This smoothed the high peaks, but the aluminide coating did not fill in the surfaces irregularities.
Using the same process as Example 2, the same yttria stabilized zirconia was coated onto the aluminide coated vane samples. Visually, the ceramic coating adhered to more areas of the part than in Example 1. This was attributed to the fact that the vane samples could be grit blasted more aggressively since grit blasting was done before aluminide coating. This avoided the concern that the alumide coating would be blasted off if the grit blasting were practiced too aggressively after aluminide coating. Optionally, the aluminide coatings could be lightly grit blasted or otherwise textured after aluminide coating if desired.
The coated vane segments were sectioned through the airfoils with a diamond saw. The chipping on both the tension and compression sides was reduced relative to Example 2 but not eliminated. Metallurgical examination of the coating system microstructure showed the bond coat to be uniform and adequate in thickness. Examination of the interface layer between the oxide layer and the ceramic top coat showed non uniform adherence, however.
Example 4
Applying aluminide coating, growing thermal oxide, and then applying ceramic coatings to grit blasted vane segment
Based on knowledge of EBPVD applied ceramic thermal barrier coatings, it was known that between the bond coat and the ceramic top coat, an oxide layer forms on the bond coat during engine operation. If the oxide layer forms after the ceramic layer has been applied or during ceramic layer formation, the growth of the oxide layer introduces a strain which can impair the service life of the coating system. To avoid this, an oxide layer is deliberately thermally grown in the present example to the point of oxide saturation prior to applying the ceramic coating. That is, the oxide grows up to a certain point and then substantially stops growing even with further processing. This point of maximum oxide formation is the point of oxide saturation.
Further, because the aluminide surfaces of Example 3 were already roughened to improve the mechanical adherence, it was proposed to evaluate a coating system using a thermally grown oxide on the roughened, aluminide bond coat surface prior to applying a plasma sprayed yttria stabilized zirconia. This was done because the oxide layer would form subsequently anyway, and it was theorized that an oxide to oxide adhesion would be better than metal to oxide adhesion if the strain effects could be reduced or avoided.
To test this theory, test vanes were grit blasted and aluminide coated in accordance with Example 3. Following aluminide coating, the parts were heat treated in an air circulating furnace to deliberately create an oxide coating that would form during engine operation between the bond coat and the ceramic coat.
Temperatures of 1125F, 1300F, 1350F and HOOF were used to deliberately form the oxide layer on vane segments, respectively. The color of the oxide formed depending on the temperature. The oxide conditions allowed the oxide to grow to the point of oxide saturation.
Following oxidation, the vane segments were plasma sprayed to form a ceramic coating on the thermally grown oxide in accordance with Examples 2 and 3. Visually, the ceramic coating was continuously formed and there was no evidence of adherence issues on the samples oxidized at the higher temperatures from 1300F to HOOF anywhere on the parts. The vane segments were cut with a diamond saw exposing the coating to both compressive and tensile loads. No chipping was observed on any tension edges. Even when cut in tension, the coatings showed almost no chipping.
Metallurgical examination of the airfoil sections showed the following:
• The aluminide bond coat showed adequate thickness in all areas of .0022" to .0025".
• The thickness and distribution of the ceramic topcoat was within typical thicknesses for this application.
• There was a thin, thermally grown oxide present between the bond coat and the ceramic top coat over the entire surface of the vane segment.
• The adherence between the aluminide bondcoat and ceramic top coat was exceptional and uniform over the whole part. The test parts
oxidized at 1350F and 1400F had the best adherence evaluated metallurgically.
Example 5
Applying aluminide coating, growing thermal oxide, and then applying ceramic coatings to grit blasted vane segment
The process of Example 4 was repeated multiple times using vane samples in which the thermally grown oxide resulted from oxidation at both 1 50 F and 1400 F. Multiple sections were taken with the diamond saw to verify the eddy current thickness readings with actual thicknesses. Visual evaluation of the coating adherence was excellent and consistent across all samples. Metallurgical inspection of the coating adherence between the bond coat and ceramic top coat validated the excellent visual adherence.
Further confirmation of the adherence of the thermal barrier coating system is provided by the fact that the removal of the zirconia layer was performed to reuse samples which were not destructively evaluated. This was done by grit blasting the coated vanes using aluminum oxide at a variety of pressures. As the process was modified from Example 2 through Example 4, it became more difficult and time consuming to prepare parts for future trials.
Example 6
Several aluminide coatings were formed on cleaned superalloy substrates. The substrates included Co-based and Ni-based superalloys. In each experiment, the aluminum source included 5 lbs of aluminum powder mixed with 95 lbs of alumina powder. This was mixed with 10 weight percent of A1F3 based on the total weight of the aluminum source. The mixture was placed into a process chamber in trays. Depending upon the run, 0.15 to 0.50 weight percent of H1D2 powder was sprinkled on top of the mixture. The percentage of the hafnium oxide was based on the total weight of the aluminum source and the A1F3. The substrate was placed into the process chamber and supported on a pre-conditioned mesh above the donor materials.
The process chamber was purged with argon. Maintaining the flow of argon, the temperature in the process chamber was increased to 1450 F. At this point, a flow of hydrogen was established and maintained while the flow of argon stopped.
The temperature was then further increased to 1750°F. At this stage, the temperature ramp rate was substantially reduced so that the sample incubated at 1775°F +/- 25°F for 90 minutes. In accordance with principles of the present invention, it is believed that a substantial portion of the hafma was reduced to one or more reduced species during this time period in this temperature range.
After this first stage of incubation, heating continued up to 1975 F for the samples having Ni-based alloy substrates and up to 2000 F for the samples having Co-based alloy substrates. At that point the process chamber was maintained at 1975 F or 2000 F under a flow of hydrogen for about 6 hours (Ni-based alloy substrates) or about 1 hours (Co-based alloy substrates to complete the formation of the coating on the substrate. After this, heating and the flow of hydrogen was stopped, and a flow of argon was established to purge the chamber. The chamber contents were cooled to room temperature under the flow of argon. This temperature is suitable when the substrate includes a nickel-based superalloy. For a substrate including a Co-based superalloy, coating temperatures approximately 25°F higher would be more suitable.
Metallurgical evaluation showed the hafnium to exist as discrete particles of hafnium containing compound(s). The benefits of hafnium additions of this type to improve the oxidation resistance are well established.
The aluminum and hafnium contents of each sample were measured using SEM EDS. The results are shown in the following table.
Run no.. Rejuvenation T-t cvcle, Results. AVE. Results. Oxidation Oxidation Test
Data Coating Thk EDS Test Results,
Flows finches) Cvcle, Qualitative
Material Total weieht- Surface Comments
"4-auadrant %A1, T-t dee Metallocranhic: basis" bv EDS
T-t dee.
Surface £
%Hf
by EDS
1 10.0% A1F3 2000F+/- 0.0023" 27.5% 2050F-47 Excellent;
5.0%A1 25F-24 Al hr No spikes no
X-40, 0.15% Hf hrs, H2 1120C47 growth
Co base atm 5.4% hr
68.0 lb basis Then: Hf
Flows:
80cfh H2
2 10.0% A1F3 1975F+/- 0.0075" 28.2% 2050F-47 Excellent;
5.0%A1 25F--12 Al hr Very little
Mar-m- 0.15% Hf brs, H2 1120C-47 growth; No
247, Ni atm 10.8% hr spikes base 69.0 lb basis Then: Hf
1975F+/-
25F-3
hrs in
Argon
Flows:
56 cfli
Argon
and H2
3 10.0% A1F3 2000F+/- 0.0028 25.4% 2050F-47 Excellent;
5.0%A1 25F-24 Al hr Very little
X-40, 0.15% Hf hrs, H2 1120C-47 growth; No
Co base atm 14.0% hr spikes
67.2.0 lb Then: Hf
basis 200F+/-
25F-3
hrs in
Argon
Flows:
80 cfh
Argon
and H2
4 5.0% AIF3 1975F+/- 0.0050 32% Al 2050F-47 Excellent;
2.5% Al 25F-6 hr Very little
Mar-m- 0.275% hrs, H2 6.7% 1120C-47 growth; No
247, Ni Hf02 atm Hf hr spikes base Then:
54.4 lb basis 1975F+/-
25F-2
hrs in
Argon
Flows:
70 cfh
Argou
and H2
5 8.0% A1F3 2000F+/- 0.0033" 22.3% 2050F-47 Fair not
4.0% Al 25F-32 Al hr Excellent;
X-40, 0.15% H102 hrs, H2 1120C-47 Avg attack
Co base atm 27.2% hr 0.0007"
S5.0 lb basis Then: Hf
200F+/-
25F-8
hrs in
Argon
Flows:
80 cfh
Argon
and H2
6 3.0% A1F3 1975F+/- 0.0040" 32% Al 2050F-47 Excellent;
1.5% Al 25F--6 hr Some growth;
Mar-m- 0.10% Η1Ό2 hrs, H2 (too thick) 8.2% 1120C-47 No spikes
247, Ni atm Hf hr
Base 57.6 lb basis Then:
1975F+/-
25F-2
hrs in
Argon
Flows:
50 cfh
Argon
and H2
7 7,5% A1F3 2000F+/- 0.0028" 33% Al 2050F-47 Excellent;
3.75% Al 25F-21 OXIDATION hr Some growth;
X-40 0.15% Hf02 hrs, H2 IN COATING <2% 1120C-47 No spikes but atm Hf hr underlying
60.8 lb basis Incoming oxidation
H2 dew probably point arising from issue original bond
Then: coat issues
2000F+/-
25F-3
hrs in
Argon
Flows:
56 cfh
Argon
and H2
8 7.5% A1F3 2000F+/- 0.0027" 32% Al 2050F-23 Excellent;
3.75% Al 25F-21 hr Some growth to
X-40 0.17% Hf02 hrs, H2 <2% 1120C-23 0.0032»; No atm Hf nr spikes
60.0 lb basis Then:
200F+/-
25F-4
hrs in
Argon
Flows:
56 cfh
Argon
and H2
9 7.5% A1F3 2000F+/- 0.0029" 33% Al 2050F-47 Excellent;
3.75% Al 25F-17.5 hr Very little
X-40 0.17% Hf02 hrs, H2 5% Hf 1120C-47 growth; No atm hr spikes
56.8 lb basis Then:
2000F+/-
25F-4.5
hrs in
Argon
Flows:
56 cth
Argon
and H2
10 7.5% A1F3 0.00245" 20.3% 20S0F-47 Fair, not
3.75% Al 2000F+/- Al hr Excellent;
X-40 0.17% Hf02 25F-18 Many oxide 1120C-47 Some growth;
hrs, H2 inclusions at 28.6% hr No spikes but
57.6 lb basis atm additive Hf underlying
Then: layer/diffusion oxidation
2000F+/- zone interface, probably
25F-3 i.e., original arising from hrs in base metal original bond
Argon, surface coat issues
Incoming
112 dew
point
issue
Flows:
56 cfh
Argon
and 112
11 7.5% A1F3 2000F+/- 0.0028" 15.5% 2050F-47 Fair, not
3.75% AI 25F-15 Al hr Excellent; Some
X-40, 0.75% HfD2 hrs, H2 1120C-47 growth to
Co base atm 39.9% 0.00032; No
57.6 lb basis Then: Hf spikes; 0.0007"
2000F+/- max attack
25F-2
hrs in
Argon
Flows:
56 cfh
Argon
and H2
12 7.5% A1F3 2000F+/- 0.0029" Cvx 2050F-47 Fair, not
3.75% Al 25F-15 TE: hrs ExcellentSome
X-40, 0.15% Η1Ό2 hrs, H2 15% Al 1120C-47 growth to
Co base atm 40.3 Hf hrs 0.00038"; No
58.4 lb basis Then: spikes; 0.0010"
2000F+A CcvTE: max attack
25F-2 16% Al
hrs in 41.2 Hf
Argon
Flows:
56 cfh
Argon
and H2
13 7,5% A1F3 2000F+/- 0.0031" Cvx 2050F-47 Fair, not
3.75% Al 25F-15 TE: hrs Excellent; Some
X-40, 0.15% Hf02 hrs, H2 19% Al 1120C-47 growth to
Co base atm 26.2 Hf hrs 0.00036; No
57.6 lb basis Then: spikes; 0.0009"
2000F+/- CcvTE: max attack
25F-2 25% Al
hrs in 9.2 Hf
Argon
Flows:
56 cfh
Argon
and H2
Note that the weight percent A1F3 is based on the total weight of the aluminum source. The weight percent of the HfO2 based on the total weight of the aluminum source and A1F3.
Remarkably, hafnium contents in the range from 5 to 39.9 weight percent were achieved using donor materials that included no more than 0.50 weight percent of hafnium oxide. Whereas conventional vapor phase coating strategies selectively favor aluminum over Hf deposition even when using higher amounts of Hf donor materials are used, the present invention in practical effect reverses this co- deposition selectivity to transfer the Hf consistently and efficiently when co- deposited with aluminum.
Oxidation resistance at high temperature also was assessed qualitatively. It is known that Hf facilitates oxidation resistance up to a certain level of
incorporation. Beyond a certain level, it is known that additional amounts of Hf content may not help oxidation resistance and may even lower it. This was in fact observed. Samples including 5.4 to 14.2 weight percent Hf showed good and excellent levels of oxidation resistance. The samples including 29 and 39.9 weight percent Hf showed fair oxidation resistance. Although the present invention allows such high Hf content to be achieved using very little Hf in the donor materials, using so much Hf might not be suitable when high temperature oxidation resistance is desired.
A number of embodiments of the invention have been described.
Nevertheless, it will be understood that various modifications may be made without departing from the spirit and scope of the invention. Accordingly, other embodiments are within the scope of the following claims.
Claims
1. A method of forming a thermal barrier coating comprising:
(a) providing a substrate comprising at least one metallic surface;
(b) roughening at least a portion of the metallic surface
(c) forming a coating on at least a portion of the roughened surface of the substrate, wherein the coating comprises at least one aluminide; and
(d) treating the aluminide coating under conditions effective to form an oxide coating on the aluminide coating;
(e) after forming the oxide coating, forming a third coating on the oxide coating, said third coating comprising at least one ceramic material.
2. The method of claim 1, wherein step (c) comprises forming an aluminide coating comprising a refractory element.
3. The method of claim 2, wherein the refractory element is Hf.
4. The method of claim 1, wherein step (a) comprises providing a coating comprising platinum on the substrate surface.
5. The method of claim 1, wherein step (c) comprises using a vapor phase to form the coating comprising the at least one aluminide.
6. The method of claim 1, wherein the aluminide comprises platinum.
7. The method of claim 1, wherein the substrate comprises a Ni-based alloy.
8. The method of claim 1, wherein the substrate comprises a Co-based alloy.
9. The method of claim 1 , wherein the substrate comprises an alloy comprising Ni and Fe.
10. The method of claim 1, wherein step (a) occurs in the presence of an activator.
11. The method of claim 10, wherein the activator comprises A1F3.
12. The method of claim 10 or 11, wherein step (c) comprises the steps of
(1) providing an aluminum source, a refractory element source, and the activator in a process chamber;
(ii) introducing a flow of hydrogen into the process chamber;
(iii) increasing the temperature of the process chamber to a temperature in the range of 1700 F to 1850 F and holding the temperature in this range for a time period in the range from 15 minutes to 5 hours; and
(iv) in the presence of hydrogen, maintaining the process chamber in a temperature range from 1900 F to 2100 F for a time period in the range from 3 hours to 10 hours.
13. The method of claim 10 or 11, wherein step (c) comprises the steps of:
(i) providing an aluminum source, a refractory element source, and the activator in a process chamber;
(ii) introducing a flow of hydrogen into the process chamber;
(iii) in the presence of hydrogen, holding the process chamber in a temperature range from 1700 F to 1850F; and
(iv) in the presence of hydrogen, holding the process chamber in a temperature range from 1900 F to 2100F.
14. The method of claim 1, wherein step (c) comprises providing an oxide of hafnium.
15. The method of claim 1, wherein step (c) comprises providing an aluminum source, wherein the aluminum source comprises less than 500 ppm sulfur on a weight basis.
16. The method of claim 1, wherein step (c) comprises providing an aluminum source, wherein the aluminum source comprises less than 500 ppm chromium on a weight basis.
17. The method of claim 1, wherein step (c) comprises providing an aluminum source, wherein the aluminum source comprises aluminum powder and alumina.
18. The method of claim 1, wherein step (d) comprises heating the coating comprising at least one aluminide in the presence of ambient air.
1 . The method of claim 1, wherein step (d) comprises heating the coating comprising at least one aluminide in the presence of ozone.
20. A method of refurbishing a coated article comprising:
(a) providing an article having a metallic surface and a coating on at least a portion of the metallic surface;
(b) treating the article under conditions effective to remove at least a portion of the coating from the metallic surface, wherein said treatment roughens at least a portion of the metallic surface from which the coating is removed;
(c) forming a coating on at least a portion of the roughened surface, said coating comprising at least one aluminide;
(d) treating the aluminide coating under conditions effective to form an oxide coating on the aluminide coating;
(e) after forming the oxide coating, forming a third coating on the oxide coating, said third coating comprising at least one ceramic material.
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4321311A (en) * | 1980-01-07 | 1982-03-23 | United Technologies Corporation | Columnar grain ceramic thermal barrier coatings |
US5624721A (en) * | 1995-05-08 | 1997-04-29 | Alliedsignal Inc. | Method of producing a superalloy article |
US5658614A (en) * | 1994-10-28 | 1997-08-19 | Howmet Research Corporation | Platinum aluminide CVD coating method |
US6103386A (en) * | 1994-11-18 | 2000-08-15 | Allied Signal Inc | Thermal barrier coating with alumina bond inhibitor |
US6458473B1 (en) * | 1997-01-21 | 2002-10-01 | General Electric Company | Diffusion aluminide bond coat for a thermal barrier coating system and method therefor |
US20050191516A1 (en) * | 2003-04-30 | 2005-09-01 | Nagaraj Bangalore A. | Method for applying or repairing thermal barrier coatings |
US20090136664A1 (en) * | 2007-08-02 | 2009-05-28 | United Technologies Corporation | Method for forming aluminide diffusion coatings |
-
2014
- 2014-08-20 WO PCT/US2014/051883 patent/WO2015026937A1/en active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4321311A (en) * | 1980-01-07 | 1982-03-23 | United Technologies Corporation | Columnar grain ceramic thermal barrier coatings |
US5658614A (en) * | 1994-10-28 | 1997-08-19 | Howmet Research Corporation | Platinum aluminide CVD coating method |
US6103386A (en) * | 1994-11-18 | 2000-08-15 | Allied Signal Inc | Thermal barrier coating with alumina bond inhibitor |
US5624721A (en) * | 1995-05-08 | 1997-04-29 | Alliedsignal Inc. | Method of producing a superalloy article |
US6458473B1 (en) * | 1997-01-21 | 2002-10-01 | General Electric Company | Diffusion aluminide bond coat for a thermal barrier coating system and method therefor |
US20050191516A1 (en) * | 2003-04-30 | 2005-09-01 | Nagaraj Bangalore A. | Method for applying or repairing thermal barrier coatings |
US20090136664A1 (en) * | 2007-08-02 | 2009-05-28 | United Technologies Corporation | Method for forming aluminide diffusion coatings |
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