WO2014190321A1 - Falling bed reactor - Google Patents

Falling bed reactor Download PDF

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Publication number
WO2014190321A1
WO2014190321A1 PCT/US2014/039443 US2014039443W WO2014190321A1 WO 2014190321 A1 WO2014190321 A1 WO 2014190321A1 US 2014039443 W US2014039443 W US 2014039443W WO 2014190321 A1 WO2014190321 A1 WO 2014190321A1
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WO
WIPO (PCT)
Prior art keywords
flow
conduit
particulate
cross
pyrolysis
Prior art date
Application number
PCT/US2014/039443
Other languages
French (fr)
Other versions
WO2014190321A9 (en
Inventor
Zia Abdullah
Michael A. O'BRIAN
Slawomir Winecki
Kevin YUGULIS
Original Assignee
Battelle Memorial Institute
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Filing date
Publication date
Application filed by Battelle Memorial Institute filed Critical Battelle Memorial Institute
Priority to EP14732753.0A priority Critical patent/EP2999535A1/en
Priority to CA2913157A priority patent/CA2913157A1/en
Priority to US14/893,483 priority patent/US20160090535A1/en
Priority to AU2014268321A priority patent/AU2014268321A1/en
Publication of WO2014190321A1 publication Critical patent/WO2014190321A1/en
Publication of WO2014190321A9 publication Critical patent/WO2014190321A9/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B4/00Separating solids from solids by subjecting their mixture to gas currents
    • B07B4/02Separating solids from solids by subjecting their mixture to gas currents while the mixtures fall
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/16Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
    • C10B49/18Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form according to the "moving bed" type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/002Feeding of the particles in the reactor; Evacuation of the particles out of the reactor with a moving instrument
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/082Controlling processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/087Heating or cooling the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/12Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/38Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
    • B01J8/384Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only
    • B01J8/388Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only externally, i.e. the particles leaving the vessel and subsequently re-entering it
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B11/00Arrangement of accessories in apparatus for separating solids from solids using gas currents
    • B07B11/04Control arrangements
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B3/00Coke ovens with vertical chambers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/16Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00265Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00292Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00513Controlling the temperature using inert heat absorbing solids in the bed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00823Mixing elements
    • B01J2208/00831Stationary elements
    • B01J2208/0084Stationary elements inside the bed, e.g. baffles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

Definitions

  • Biomass pyrolysis is conventionally conducted using bubbling fluid beds, circulating fluid bed transport reactors, rotating cone reactors, ablative reactors or auger reactors.
  • Fluidized bed designs such as bubbling fluid bed reactors and circulating fluid bed reactors may provide high heat transfer rates to the substrate, e.g., biomass, and these high heat transfer rates may result in high yield of bio-oil.
  • a disadvantage of fluidized bed systems is that a significant flow rate of inert gas may be needed, which may lead to undesirable parasitic losses.
  • a falling bed reactor may include a reactor conduit defining a flow axis.
  • the falling bed reactor may include an inlet operatively coupled to receive a heat carrier particulate into the reactor conduit.
  • the falling bed reactor may also include an outlet operatively coupled to direct the heat carrier particulate out of the reactor conduit.
  • the falling bed reactor may also include one or more baffles mounted in the reactor conduit, e.g., a plurality of baffles.
  • a falling bed reactor is provided.
  • the falling bed reactor may include a reactor conduit defining a flow axis.
  • the falling bed reactor may include an inlet operatively coupled to receive a heat carrier particulate into the reactor conduit.
  • the falling bed reactor may also include an outlet operatively coupled to direct the heat carrier particulate out of the reactor conduit.
  • the falling bed reactor may further include a pyrolysis substrate inlet operatively coupled to receive a pyrolysis substrate into the reactor conduit.
  • the falling bed reactor may include a pyrolysis product outlet operatively coupled to direct a pyrolysis product out of the reactor conduit.
  • the falling bed reactor may also include one or more baffles mounted in the reactor conduit, e.g., a plurality of baffles. Each baffle in the one or more baffles may include a baffle surface. At least a portion of each baffle surface may be at an oblique angle with respect to the flow axis.
  • a pyrolysis system may include a falling bed reactor and a cross-flow classifier.
  • the falling bed reactor may include a reactor conduit defining a flow axis.
  • the falling bed reactor may include an inlet operatively coupled to receive a heat carrier particulate into the reactor conduit.
  • the falling bed reactor may also include an outlet operatively coupled to direct the heat carrier particulate out of the reactor conduit.
  • the falling bed reactor may further include a pyrolysis substrate inlet operatively coupled to receive a pyrolysis substrate into the reactor conduit.
  • the falling bed reactor may include a pyrolysis product outlet operatively coupled to direct a pyrolysis product out of the reactor conduit.
  • the falling bed reactor may also include one or more baffles mounted in the reactor conduit.
  • Each baffle in the one or more baffles may include a baffle surface. At least a portion of each baffle surface may be at an oblique angle with respect to the flow axis.
  • the cross-flow classifier may include a separator conduit.
  • the cross-flow classifier may also include a flow input and a flow output in fluidic communication with the separator conduit.
  • the separator conduit may extend between the flow input and the flow output to define a flow axis along at least a portion of the separator conduit.
  • the flow input may be located upstream of the flow output with respect to the flow axis.
  • the cross-flow classifier may include a cross-flow input and a cross-flow output in fluidic communication with the separator conduit between the flow input and the flow output.
  • the cross-flow input may be located upstream of the cross-flow output with respect to the flow axis.
  • the cross- flow input may define a cross-flow axis intersecting the flow axis at a cross-flow angle between about 70° and about 180° with respect to the flow axis.
  • the outlet of the falling bed reactor may be operatively coupled to the flow input of the cross-flow classifier.
  • the flow output of the cross-flow classifier may be operatively coupled to the inlet of the falling bed reactor.
  • a pyrolysis method may include feeding a heat carrier to a gravity-fed baffled conduit.
  • the pyrolysis method may include feeding a pyrolysis substrate to the gravity-fed baffled conduit such that the heat carrier and the pyrolysis substrate mix to form a pyrolysis mixture.
  • the pyrolysis method may include heating the heat carrier and/or the gravity-fed baffled conduit to pyrolyze the pyrolysis substrate in the pyrolysis mixture to form a pyrolysis product mixture.
  • the "gravity-fed baffled conduit" may include, for example, the falling bed reactor.
  • FIG. 1 depicts an example falling bed reactor
  • FIG. 2 depicts an example pyrolysis system that includes an example falling bed reactor and an example cross-flow particle classifier;
  • FIG. 3 is a block diagram of an example cross-flow particle classifier
  • FIG. 4 is a flow diagram of an example method for pyrolysis.
  • FIG. 1 depicts an example falling bed reactor 100.
  • Falling bed reactor 100 may include a reactor conduit 102 defining a flow axis 104.
  • Flow axis 104 may have a downstream end, indicated by the arrowhead, and an upstream end, indicated by the shaft end of the arrow.
  • Falling bed reactor 100 may include an inlet 106 operatively coupled to receive a heat carrier particulate into reactor conduit 102.
  • Falling bed reactor 100 may also include an outlet 108 operatively coupled to direct the heat carrier particulate out of reactor conduit 102.
  • Falling bed reactor 100 may further include a pyrolysis substrate inlet 110 operatively coupled to receive a pyrolysis substrate into reactor conduit 102.
  • Falling bed reactor 100 may include a pyrolysis product outlet 112 operatively coupled to direct a pyrolysis product out of reactor conduit 102.
  • Falling bed reactor 100 may also include one or more baffles 114, e.g., a plurality of baffles, mounted in reactor conduit 102.
  • Each baffle in one or more baffles 114 may include a baffle surface 116. At least a portion of each baffle surface 116 may be at an oblique angle 118 with respect to flow axis 104.
  • the "heat carrier” may be a particulate including one or more of: a metal, a glass, a ceramic, a mineral, or a polymeric composite.
  • the heat carrier may be sand.
  • the heat carrier may include a particulate catalyst.
  • the heat carrier may include a fluid catalytic cracking (FCC) catalyst.
  • the heat carrier may include a spent particulate catalyst.
  • the heat carrier may include a spent FCC catalyst.
  • the heat carrier may be in the form of metal shot, for example, steel shot.
  • the heat carrier when employed with the cross flow particle classifier, is of a density effective to provide separation between the heat carrier and the char to be separated in the cross flow particle classifier.
  • an "oblique angle” is any angle that is not an integer multiple of a right angle.
  • an oblique angle excludes 0°, 90°, and 180°, but includes angles between 0° and 90°, and angles between 90° and 180°.
  • falling bed reactor 100 may be configured to be mounted such that at least a portion of flow axis 104 is parallel or oblique to a vertically downward direction. Falling bed reactor 100 may be configured to be mounted such that at least a portion of each baffle surface 116 is at an oblique angle 118 with respect to the vertically downward direction. Falling bed reactor 100 may be mounted to orient flow axis 104 in a substantially vertically downward direction. In this manner, falling bed reactor 100 may be gravity-fed or gravity operated, at least in part.
  • the pyrolysis substrate may enter falling bed reactor 100 at pyrolysis substrate inlet 110, and the heat carrier particulate may enter falling bed reactor 100 at inlet 106 .
  • the pyrolysis substrate and the heat carrier particulate may fall through falling bed reactor 100, and may be intermittently diverted from flow axis 104 by one or more baffles 114, for example, as indicated by a path 105.
  • a cross section of reactor conduit 102 may include a shape that may be one of: polygonal, rounded polygonal, circular, elliptical, or a combination or composite thereof.
  • a cross section of reactor conduit 102 may include a shape that may be one of: rectangular, rounded rectangular, circular, elliptical, or a combination or composite thereof.
  • reactor conduit 102 may be square in cross section.
  • inlet 106 and outlet 108 may be substantially parallel with one or both of reactor conduit 102 and flow axis 104.
  • Inlet 106 may be operatively coupled to reactor conduit 102 upstream of outlet 108 with respect to flow axis 104.
  • falling bed reactor 100 may include a pyrolysis substrate inlet 110 operatively coupled to receive a pyrolysis substrate into reactor conduit 102.
  • Falling bed reactor 100 may include a pyrolysis product outlet 112 operatively coupled to direct a pyrolysis product out of reactor conduit 102.
  • Pyrolysis substrate inlet 110 may be operatively coupled to reactor conduit 102 upstream of pyrolysis product outlet 112 with respect to flow axis 104. Pyrolysis substrate inlet 110 may be operatively coupled to reactor conduit 102 upstream of pyrolysis product outlet 112 with respect to flow axis 104. Pyrolysis substrate inlet 110 may be operatively coupled to reactor conduit 102 at a same level or downstream of pyrolysis product outlet 112 with respect to flow axis 104. Pyrolysis substrate inlet 110 may be coincident with inlet 106. Pyrolysis product outlet 112 may be coincident with inlet 106 or outlet 108.
  • the one or more baffles 114 may extend from an inside wall 130 of the reactor conduit 102 into the reactor conduit 102.
  • the one or more baffles 114 may extend from the inside wall 130 to define a cantilevered geometry in the reactor conduit 102.
  • the one or more baffles 114 may extend across at least a portion of the reactor conduit 102 between a first portion of the inside wall 130 and a second portion of the inside wall 130.
  • Each of the one or more baffles 114 may include a form of one or more of a rod, a plate, a screen, or a protrusion.
  • Each of the one or more baffles 114 may include a form of a rod.
  • the rod may include a cross-sectional geometry that is at least in part polygonal, rounded polygonal, circular, elliptical, or a combination or composite thereof.
  • each of the one or more baffles 114 may include a baffle surface 116.
  • the baffle surface 116 may be positioned to intersect at least a portion of the reactor conduit 102 with respect to the flow axis 104.
  • At least a portion of the baffle surface 116 may include a geometry that is one or more of flat or convex.
  • At least a portion of the baffle surface 116 may be horizontal with respect to the flow axis 104.
  • At least a portion of the baffle surface 116 may be at an oblique angle 118 with respect to the flow axis 104.
  • one or more baffles 114 may be mounted to place at least the portion of each baffle surface 116 at oblique angle 118 with respect to flow axis 104 such that one or more baffles 114 may form a staggered or alternating pattern in reactor conduit 102.
  • Each baffle in one or more baffles 114 may be mounted to an inside wall 130 of reactor conduit 102 to define a free edge 120 of each baffle surface 116 and a mounted edge 122 of each baffle surface.
  • one or more baffles 114 may be configured as an alternating sequence of funnels and cones, the funnels aligned with the flow axis 104 and the cones aligned antiparallel to the flow axis 104, each of the funnels and cones may include a free edge 120 at a downstream extremity of each of the funnels and cones.
  • Each baffle surface 116 in one or more baffles 114 may be substantially at oblique angle 118 with respect to flow axis 104.
  • oblique angle 118 may be between about 30° and about 60° with respect to flow axis 104 such that for each baffle surface 116, a free edge 120 of baffle surface 116 may be further downstream along flow axis 104 compared to a mounted edge 122 of baffle surface 116.
  • falling bed reactor 100 may include an agitator mechanism 126 configured to agitate at least a portion of one or more baffles 114 effective to dislodge a particulate on at least a portion of one or more baffles 114.
  • Falling bed reactor 100 may include a heater 128. Heater 128 may be configured cause pyrolysis of a substrate in falling bed reactor 100 by heating one or both of falling bed reactor 100 and a heat carrier to be fed into falling bed reactor 100.
  • FIG. 2 depicts an example pyrolysis system 200. Pyrolysis system 200 may include falling bed reactor 100 and a cross-flow classifier 3100. Falling bed reactor 100 may include a reactor conduit 102 defining a flow axis 104.
  • Flow axis 104 may have a downstream end, indicated by the arrowhead, and an upstream end, indicated by the shaft end of the arrow.
  • Falling bed reactor 100 may include an inlet 106 operatively coupled to receive a heat carrier particulate into reactor conduit 102. Falling bed reactor 100 may also include an outlet 108 operatively coupled to direct the heat carrier particulate out of reactor conduit 102. Falling bed reactor 100 may further include a pyrolysis substrate inlet 110 operatively coupled to receive a pyrolysis substrate into reactor conduit 102. Falling bed reactor 100 may include a pyrolysis product outlet 112 operatively coupled to direct a pyrolysis product out of reactor conduit 102.
  • Falling bed reactor 100 may also include one or more baffles 114 mounted in reactor conduit 102.
  • Each baffle in one or more baffles 114 may include a baffle surface 116. At least a portion of each baffle surface 116 may be at an oblique angle 118 with respect to flow axis 104.
  • Cross-flow classifier 3100 may include a separator conduit 3102.
  • Cross-flow classifier 3100 may also include a flow input 3104 and a flow output 3106 in fluidic communication with separator conduit 3102.
  • Separator conduit 3102 may extend between flow input 3104 and flow output 3106 to define a flow axis 3108 along at least a portion of separator conduit 3102.
  • Flow input 3104 may be located upstream of flow output 3106 with respect to flow axis 3108.
  • Cross-flow classifier 3100 may include a cross-flow input 3114 and a cross-flow output 3116 in fluidic communication with separator conduit 3102 between flow input 3104 and flow output 3106.
  • Cross-flow input 3114 may be located upstream of cross-flow output 3116 with respect to flow axis 3108.
  • Cross-flow input 3114 may define a cross-flow axis 3118 intersecting flow axis 3108 at a cross-flow angle 3120 between about 70° and about 180° with respect to flow axis 3108. Further with respect to pyrolysis system 200, outlet 108 of falling bed reactor 100 may be operatively coupled to flow input 3104 of cross-flow classifier 3100. Also, flow output 3106 of cross-flow classifier 3100 may be operatively coupled to inlet 106 of falling bed reactor 100.
  • outlet 108 of falling bed reactor 100 may be operatively coupled to flow input 3104 of cross-flow classifier 3100 via an auger or conveyor 230.
  • Flow output 3106 of cross-flow classifier 3100 may be operatively coupled to inlet 106 of falling bed reactor 100 via an auger or conveyor 232.
  • pyrolysis system 200 may include a fine particulate separator 202.
  • An input 204 of fine particulate separator 202 may be operatively coupled to pyrolysis product outlet 112 of falling bed reactor 100.
  • Fine particulate separator 202 may include a particulate outlet 206 and a gas or vapor outlet 208.
  • fine particulate separator 202 may include one or more of: a settling chamber, a baffle chamber, a cyclonic particle separator, an electrostatic precipitator, a filter, or a scrubber
  • pyrolysis system 200 may include a coarse particulate separator 212.
  • An input 214 of coarse particulate separator 212 may be operatively coupled to cross-flow output 3116 of cross-flow classifier 3100.
  • Coarse particulate separator 212 may include a particulate outlet 216 and a gas outlet 218.
  • coarse particulate separator 212 may include one or more of: a settling chamber, a baffle chamber, a cyclonic particle separator, an electrostatic precipitator, a filter, or a scrubber
  • pyrolysis system 200 may include a gas recycle conduit 220.
  • Gas recycle conduit 220 may be operatively coupled to receive recycled gas from gas outlet 218.
  • Gas recycle conduit 220 may be operatively coupled to direct the recycled gas to cross-flow input 3114 of cross-flow classifier 3100.
  • gas recycle conduit 220 may include a fan 222. Fan 222 may be configured to draw the recycled gas from gas outlet 218 via gas recycle conduit 220. Fan 222 may be configured to flow the recycled gas to cross-flow input 3114 of cross-flow classifier 3100 via gas recycle conduit 220.
  • falling bed reactor 100 in pyrolysis system 200 may include any aspect of falling bed reactor 100 described herein.
  • FIGS. 3A and 3B depict aspects of cross-flow classifier 3100 that may be used in example pyrolysis system 200.
  • flow input 3114 and flow output 3116 may be substantially aligned with flow axis 3108 of separator conduit 3102.
  • cross-flow input 3114 may be operatively coupled to separator conduit 3102 substantially opposite to cross-flow output 3116 with respect to flow axis 3108.
  • cross-flow classifier 3100 may be mounted such that flow axis 3108 points downward at a flow angle 3110.
  • flow angle 3110 may be less than 90° from vertically downward. In some embodiments, flow angle 3110 may be less than 60° from vertically downward.
  • downward means any direction represented by a vector having a non-zero component parallel with respect to a local gravitational acceleration direction.
  • upward means any direction represented by a vector having a non-zero component antiparallel with respect to the local gravitational acceleration direction.
  • vertical means parallel or antiparallel with respect to the local gravitational acceleration direction.
  • Vertically downward means parallel with respect to the local gravitational acceleration direction, indicated in FIG. 1 by arrow 3101.
  • Vertical means antiparallel with respect to the local gravitational acceleration direction.
  • horizontal means perpendicular to the local gravitational acceleration direction.
  • separator conduit 3102 may include a first flow diameter 3122 between flow input 3104 and cross-flow input 3114. Separator conduit 3102 may include a second flow diameter 3124 downstream of cross-flow input 3114. First flow diameter 3122 may be greater than second flow diameter 3124. Separator conduit 3102 may include a transition 3126 between first flow diameter 3122 and second flow diameter 3124. Transition 3126 may be substantially aligned with cross-flow angle 3120. For example, transition 3126 may be substantially perpendicular with respect to flow axis 3108.
  • flow input 3104 may be configured to accept a plurality of particulates. At least a first particulate in the plurality of particulates may be characterized by a first average density. At least a second particulate in the plurality of particulates may be characterized by a second average density greater than the first average density.
  • Flow output 3106 may be configured to convey at least a portion of the first particulate characterized by the first density out of separator conduit 3102.
  • Cross-flow output 3116 may be configured to convey at least a portion of the second particulate characterized by the second density greater than the first density out of separator conduit 3102.
  • a "particulate” refers to a plurality, collection, or distribution of individual particles.
  • the individual particles in the particulate may have in common one or more characteristics, such as size, density, material composition, heat capacity, particle morphology, and the like.
  • the characteristics of the particles in the particulate may be the same among the particles, or may be characterized by a distribution.
  • particles in a particulate may all be made of the same composition, e.g., a ceramic, a metal, or the like.
  • particles in a particulate may be characterized by a distribution of particle sizes, for example, a Gaussian distribution.
  • cross-flow input 3114 may define a first convergent nozzle 3132.
  • First convergent nozzle 3132 may include a first nozzle throat 3134.
  • a cross section of first nozzle throat 3134 may include at least two dissimilar axes.
  • first nozzle throat 3134 may include an elliptical cross section, a circular cross section, a rectangular cross section, a rounded corner rectangular cross section, a polygonal cross section, a composite or combination thereof, or the like.
  • the first nozzle throat 3134 may be operatively coupled to a nozzle exit zone. At least a portion of the nozzle exit zone may include a transition 3126 between a first flow diameter 3122 of flow conduit 3108 and first nozzle throat 3134. In some embodiments, at least a portion of the nozzle exit zone may include a second flow diameter 3124 of separator conduit 3108. Transition 3126 may be located at an upstream side of first nozzle throat 3134. Second flow diameter 3124 may be located at a downstream side of first nozzle throat 3134. First nozzle throat 3134 may be located at second flow diameter 3124 of separator conduit 3108.
  • convergent nozzle 3132 of cross-flow input 3114 may include a second nozzle throat 3138.
  • First nozzle throat 3134 may be located at cross-flow input 3114 between second nozzle throat 3138 and separator conduit 3108.
  • Cross-flow output 3116 may define a second convergent nozzle 3142.
  • second convergent nozzle 3142 may include a third nozzle throat 3144.
  • a cross section of third nozzle throat 3144 may include at least two dissimilar axes.
  • third nozzle throat 3144 may include an elliptical cross section, a circular cross section, a rectangular cross section, a rounded corner rectangular cross section, a polygonal cross section, a composite or combination thereof, or the like.
  • Third nozzle throat 3144 may be operatively coupled to a nozzle entrance zone 3146. At least a portion of nozzle entrance zone 3146 may include a transition 3148 between a second flow diameter 3124 of flow conduit 3108 and third nozzle throat 3144.
  • nozzle entrance zone 3146 may include an entrance vane 3150.
  • Entrance vane 3150 may extend into separator conduit 3102, for example, with respect to second flow diameter 3124. At least a portion of entrance vane 3150 may extend into separator conduit 3102 at least partly in an upstream direction with respect to flow axis 3108.
  • third nozzle throat 3144 may be operatively coupled through a nozzle collector zone to an exit conduit 3154.
  • One or both of the nozzle collector zone and conduit 3154 may include an elliptical cross section.
  • one or both of the nozzle collector zone and exit conduit 3154 may include a circular cross section.
  • Third nozzle throat 3144 may be operatively coupled to an exit conduit 3154.
  • Exit conduit 3154 may define an exit conduit axis 3156.
  • Exit conduit axis 3156 may intersect flow axis 3108 at an exit angle 3158.
  • Exit angle 3158 may be greater than 0° and less than 180°.
  • exit angle 3158 may be between about 90° and less than 180°.
  • exit conduit axis 3156 may be within about 30° of vertical.
  • FIG. 4 is a flow diagram describing an example pyrolysis method 400.
  • Pyrolysis method 400 may include feeding a heat carrier to a gravity-fed baffled conduit (step 402).
  • Pyrolysis method 400 may include feeding a pyrolysis substrate to the gravity-fed baffled conduit such that the heat carrier and the pyrolysis substrate mix to form a pyrolysis mixture (step 404).
  • Pyrolysis method 400 may include heating the heat carrier and/or the gravity-fed baffled conduit to pyrolyze the pyrolysis substrate in the pyrolysis mixture to form a pyrolysis product mixture (step 406).
  • the gravity-fed baffled conduit may include, for example, the falling bed reactor 100 described herein.
  • the pyrolysis product mixture may include a gas or vapor pyrolysis product and a fine char pyrolysis product.
  • the method may include directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit.
  • the pyrolysis product mixture may include the heat carrier and a coarse char pyrolysis product.
  • the method may further include directing the heat carrier and the coarse char pyrolysis product out of the gravity-fed baffled conduit.
  • the method may include directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit at the same level as the heat carrier and the coarse char pyrolysis product.
  • the method may include directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit upstream compared to the heat carrier and the coarse char pyrolysis product.
  • the method may include directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit downstream compared to the heat carrier and the coarse char pyrolysis product
  • the pyrolysis product mixture may include the heat carrier and a coarse char pyrolysis product.
  • the method may include directing the heat carrier and the coarse char pyrolysis product out of the gravity-fed baffled conduit.
  • feeding the heat carrier to the gravity-fed baffled conduit may include feeding the heat carrier and the pyrolysis substrate to the same level in the gravity-fed baffled conduit.
  • Feeding the heat carrier to the gravity-fed baffled conduit may include feeding the heat carrier to the gravity-fed baffled conduit upstream of the pyrolysis substrate.
  • Feeding the heat carrier to the gravity-fed baffled conduit may include feeding the heat carrier to the gravity-fed baffled conduit downstream of the pyrolysis substrate.
  • the pyrolysis product mixture may include a gas or vapor pyrolysis product and a fine char pyrolysis product.
  • the method may also include directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit.
  • the method may also include separating the gas or vapor pyrolysis product from the fine char pyrolysis product.
  • the pyrolysis product mixture may include the heat carrier and a coarse char pyrolysis product.
  • the method may include directing the heat carrier and the coarse char pyrolysis product out of the gravity-fed baffled conduit.
  • the method may also include separating the heat carrier from the coarse char pyrolysis product.
  • the method may include recycling the heat carrier to form a recycled heat carrier.
  • the method may also include feeding the recycled heat carrier to the gravity-fed baffled conduit.
  • separating the heat carrier from the coarse char pyrolysis product may include directing a flow comprising a plurality of particulates along a flow axis.
  • the method may also include separating at least a portion of a first particulate from the plurality of particulates to form a separated portion of the first particulate by directing a gas jet along a cross-flow axis, the cross-flow axis intersecting the flow axis at a cross-flow angle, the cross-flow angle being between about 70° and about 180°.
  • the plurality of particulates may include the heat carrier and the coarse char pyrolysis product.
  • the first particulate may include the coarse char pyrolysis product
  • the gas jet may include a gas temperature of between about 300 °C and about 700 °C.
  • the gas temperature may be a temperature in °C of about 300, 320, 340, 360, 380, 400, 420, 440, 460, 480, 500, 520, 540, 560, 580, 600, 620, 640, 660, 680, or 700, or any range between any two of the preceding temperature values.
  • the gas jet may include a gas density (in kilograms per cubic meter) of between about 0.4 and about 1.4.
  • the gas density may have a value (in kilograms per cubic meter) of about 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 1.1, 1.2, 1.3, or 1.4, or any range between any two of the preceding density values.
  • the gas jet may include a gas viscosity (in kilograms per meter-second) of between about lxlO "6 and about lxlO "4 .
  • the gas viscosity may have a value in 10 "5 kilograms per meter-second of about 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 1.2, 1.3, 1.4, 1.5, 1.6, 1.7, 1.8, 1.9, 2, 2.2, 2.4, 2.6, 2.8, 3, 3.25, 3.5, 3.75, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, or 10, or any range between any two of the preceding gas viscosity values.
  • the gas jet may include a gas flow rate of less than 25 cubic feet per minute.
  • the gas jet may include a gas pressure drop of less than 5 inches of for example, about 1.5 inches of water or less.
  • separating at least the portion of the first particulate from the plurality of particulates to form the separated portion of the first particulate further may include directing the separated portion of the first particulate away from the cross-flow axis to a surface of a separator conduit.
  • Method 400 may also include directing the separated portion of the first particulate along the surface for a distance. Directing the separated portion of the first particulate along the surface may include directing the separated portion of the first particulate substantially parallel to the first directional flow axis. Directing the separated portion of the first particulate along the surface may include using the Coanda effect.
  • Some embodiments may include diverting the separated portion of the first particulate along the surface away from the surface to a cross-flow output. Diverting the separated portion of the first particulate along the surface away from the surface and through the cross-flow output may include using the Coanda effect. Diverting the separated portion of the first particulate along the surface away from the surface and through the cross- flow output may include contacting the separated portion of the first particulate along the surface with an entrance vane. The entrance vane may be in fluidic communication with the cross-flow output.
  • separating at least the portion of the first particulate from the plurality of particulates may include substantially separating the first particulate from the plurality of particulates. Separating at least the portion of the first particulate from the plurality of particulates may include separating at least about 90%, 95%, 97%, 98%, 99%, 99.1%, 99.2%, 99.3%, 99.4%, 99.5%, 99.6%, 99.7%, 99.8%, 99.9%, 99.95%, 99.99%, 99.995%, or 99.999% by weight of the first particulate from the plurality of particulates. For example, separating at least the portion of the first particulate from the plurality of particulates may include separating at least about 99% by weight of the first particulate from the plurality of particulates.
  • the first particulate may include one or more of a biomass or a pyrolysis product, for example, a biomass pyrolysis product.
  • the first particulate may include char.
  • the first particulate may comprise a first average density (in kilograms per cubic meter) of between about 100 and about 2,000.
  • the first average density (in kilograms per cubic meter) may be about 100, 200, 300, 400, 500, 600, 700, 800, 900, 1000, 1 100, 1200, 1300, 1400, 1500, 1600, 1700, 1800, 1900, or 2000, or between any two of the preceding density values.
  • the first average density may be about 374 kilograms per cubic meter.
  • the first particulate may be characterized by a first average diameter (in millimeters) of between about 0.1 and about 10.
  • the first average diameter (in millimeters) may be about 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 1.2, 1.4, 1.6, 1.8, 2, 2.25, 2.5, 2.75, 3, 3.25, 3.5, 3.75, or 4, or between any two of the preceding average diameter values.
  • the first particulate may include an average flow rate (in kilograms per second) of between about 0.0012 and about 0.0023.
  • the average flow rate in kilograms per second
  • the average flow rate may be about 0.0012, 0.0013, 0.0014, 0.0015, 0.0016, 0.0017, 0.0018, 0.0019, 0.0020, 0.0021, 0.0022, or 0.0023, or between any two of the preceding flow rate values.
  • the first particulate may include a first average density and the plurality of particulates may include at least a second particulate.
  • the second particulate may be characterized by a second average density greater than the first average density.
  • the second particulate may be, for example, a heat carrier suitable for use in an auger pyrolyzer.
  • the second particulate may include one or more of a metal, a glass, a ceramic, a mineral, or a polymeric composite.
  • the second particulate may include one or more of: steel, stainless steel, cobalt (Co), molybdenum (Mo ), nickel (Ni), titanium (Ti), tungsten (W), zinc (Zn), antimony (Sb), bismuth (Bi), cerium (Ce), vanadium (V), niobium (Nb), tantalum (Ta), chromium (Cr), manganese (Ma), rhenium (Re), iron (Fe), platinum (Pt), iridium (Ir), palladium (Pd), osmium (Os), rhodium (Rh), ruthenium (Ru), nickel, copper impregnated zinc oxide (Cu/ZnO), copper impregnated chromium oxide (Cu/Cr), nickel aluminum oxide ( 1/AI2O 3 ), palladium aluminum oxide (PdA ⁇ C ⁇ ), cobalt molybdenum (C0M0), nickel molybdenum (NiMo), nickel mole
  • the second average density of the second particulate may be between about 3,000 and about 23,000, for example, about 3,000, 4,000, 5,000, 6,000, 7,000, 8,000, 9,000, 10,000, 1 1,000, 12,000, 13,000, 14,000, 15,000, 16,000, 17,000, 18,000, 19,000, 20,000, 21,000, 22,000, or 23,000, or between about any two of the preceding density values.
  • the second particulate may be steel or stainless steel at a density of about 7,500 kilograms per cubic meter.
  • the second average density of the second particulate divided by the first average density of the first particulate may be a ratio between about 1.5: 1 and about 230: 1.
  • the ratio may be about 1.5: 1, 2: 1, 5: 1, 10: 1, 15: 1, 20: 1, 25: 1, 50: 1, 75: 1, 100: 1, 125: 1, 150: 1, 175: 1, 200: 1, 225: 1, 230: 1, or a range between about any two of the preceding ratios.
  • the second particulate may be characterized by a first average diameter (in millimeters) of between about 0.1 and about 25, for example, about 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 1 1, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, or a range between about any two of the preceding average diameter values, for example, between about 1 mm and about 10 mm.
  • a first average diameter in millimeters
  • the second particulate may include a spherical, rounded, or ellipsoid morphology. In some embodiments, the second particulate may include a substantially spherical morphology.
  • the second particulate may include a flow rate (in kilograms per second per each ton per day of biomass processed) of about 0.4 to about 1.4, for example, about 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 1.1, 1.2, 1.3, 1.4, or a range between any two of the preceding flow rates.
  • the first particulate may be characterized by a first terminal velocity and the second particulate may be characterized by a second terminal velocity.
  • the first and second particulates may be characterized by a ratio of the second terminal velocity to the first terminal velocity of at least about 5: 1, 10: 1, 15: 1, 20: 1, 25: 1, 30: 1, or 35: 1.
  • method 400 may also include separating at least a portion of a second particulate in the plurality of particulates from the first particulate.
  • method 400 may include separating substantially all of a second particulate in the plurality of particulates from the first particulate.
  • Method 400 may include separating at least a portion of a second particulate in the plurality of particulates from the first particulate in a direction substantially aligned with the first directional flow axis.
  • the method may also include directing the flow axis downward at a flow angle.
  • the flow angle may be less than 90° from vertically downward.
  • the flow angle may be less than 60° from vertically downward.
  • method 400 may include forming the gas jet by flowing a gas through a first convergent nozzle.
  • the first convergent nozzle may include a first nozzle throat.
  • a cross section of the first nozzle throat may include at least two dissimilar axes.
  • the first nozzle throat may include an elliptical cross section, a circular cross section, a rectangular cross section, a rounded corner rectangular cross section, a polygonal cross section, a composite or combination thereof, or the like.
  • method 400 may also include adapting the flow upstream of the gas jet to a first flow diameter and adapting the flow downstream of the gas jet to a second flow diameter.
  • the first flow diameter may be greater than the second flow diameter.
  • the method may also include adapting the flow between the first flow diameter and the second flow diameter using a transition between the first flow diameter and the second flow diameter.
  • the transition may be substantially aligned with the cross-flow angle.
  • the transition may be substantially perpendicular with respect to the flow axis.
  • the transition may extend between at least a portion of the first flow diameter and at least a portion of the first nozzle throat.
  • At least a portion of the second flow diameter may coincide with at least a portion of the first nozzle throat.
  • the first nozzle throat may be located at the second flow diameter of the separator conduit.
  • forming the gas jet may also include flowing the gas through a second nozzle throat upstream of the first nozzle throat.
  • separating at least the portion of the first particulate from the plurality of particulates may also include extending an entrance vane into a portion of the flow defined by the second flow diameter.
  • the method may include extending at least a portion of the entrance vane into the flow at least partly in an upstream direction with respect to the first directional flow axis.
  • separating at least the portion of the first particulate from the plurality of particulates may include directing the separated portion of the first particulate away from the flow axis.
  • the method may include directing the separated portion of the first particulate away from the flow axis substantially opposite to the gas jet along the cross-flow axis with respect to the first directional flow axis.
  • method 400 may include directing a separated portion of the first particulate away from the flow axis through a third nozzle throat.
  • a cross section of the third nozzle throat may include at least two dissimilar axes.
  • the third nozzle throat may include an elliptical cross section, a circular cross section, a rectangular cross section, a rounded corner rectangular cross section, a polygonal cross section, a composite or combination thereof, or the like.
  • Separating at least the portion of the first particulate from the plurality of particulates may also include directing the separated portion of the first particulate away from the third nozzle throat through an elliptical cross section.
  • the method may include directing the separated portion of the first particulate away from the third nozzle throat through a circular cross section.
  • separating at least the portion of the first particulate from the plurality of particulates further may include directing the separated portion of the first particulate away from the third nozzle throat via an exit conduit axis.
  • the exit conduit axis may intersect the flow axis at an angle. The angle may be greater than 0° and less than 180°. For example, the angle may be between about 90° and less than 180°. In some examples, the exit conduit axis may be within about 30° of vertical.
  • Heated spherical steel shot may be added via inlet 106 into reactor conduit 102.
  • Ground particulate bio-mass e.g., a mixture of corn stover and wood particulate
  • the reactor conduit 102 and the steel shot may be heated to a desired pyrolysis temperature, e.g., 500 °C.
  • the heated steel shot and the bio-mass may fall through the one or more baffles 114 mounted in reactor conduit 102.
  • the heated steel shot and the bio-mass may mix, and the bio-mass may pyrolyze to form a pyrolysis mixture including gas or vapor of bio-oil, bio- char, and the heated steel shot.
  • a mixture of fine bio-char and the gas or vapor of bio-oil may be collected at pyrolysis product outlet 112.
  • a mixture of coarse bio-char and the steel shot may be collected at outlet 108.
  • the falling bed reactor described in this Example may exhibit effective mixing between the steel shot heat carrier and the bio-mass, similar to the mixing observed in fluidized bed reactors.
  • the falling bed reactor described in this Example may also operate without needing inert gas, similar to the operation of auger reactors.

Abstract

Methods and apparatuses are provided for pyrolysis using a falling bed reactor. The falling bed reactor may result in effective mixing between a heat carrier and biomass, and may reduce or eliminate inert gas requirements.

Description

FALLING BED REACTOR
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application claims priority from U.S. Provisional Patent Application No. 61/826,989, filed on May 23, 2013, which is incorporated by reference herein in its entirety.
BACKGROUND
[0002] Biomass pyrolysis is conventionally conducted using bubbling fluid beds, circulating fluid bed transport reactors, rotating cone reactors, ablative reactors or auger reactors. Fluidized bed designs such as bubbling fluid bed reactors and circulating fluid bed reactors may provide high heat transfer rates to the substrate, e.g., biomass, and these high heat transfer rates may result in high yield of bio-oil. A disadvantage of fluidized bed systems is that a significant flow rate of inert gas may be needed, which may lead to undesirable parasitic losses. Other designs, such as rotating cone reactors and auger reactors may not require significant inert gas flow, but mixing between the heat carrier and biomass may not be as effective as with fluidized beds, which may lead to lower reaction yields, e.g., of bio-oil from bio-mass pyrolysis. The present application appreciates that biomass pyrolysis may be a challenging endeavor.
SUMMARY
[0003] In one embodiment, a falling bed reactor is provided. The falling bed reactor may include a reactor conduit defining a flow axis. The falling bed reactor may include an inlet operatively coupled to receive a heat carrier particulate into the reactor conduit. The falling bed reactor may also include an outlet operatively coupled to direct the heat carrier particulate out of the reactor conduit. The falling bed reactor may also include one or more baffles mounted in the reactor conduit, e.g., a plurality of baffles. [0004] In another embodiment, a falling bed reactor is provided. The falling bed reactor may include a reactor conduit defining a flow axis. The falling bed reactor may include an inlet operatively coupled to receive a heat carrier particulate into the reactor conduit. The falling bed reactor may also include an outlet operatively coupled to direct the heat carrier particulate out of the reactor conduit. The falling bed reactor may further include a pyrolysis substrate inlet operatively coupled to receive a pyrolysis substrate into the reactor conduit. The falling bed reactor may include a pyrolysis product outlet operatively coupled to direct a pyrolysis product out of the reactor conduit. The falling bed reactor may also include one or more baffles mounted in the reactor conduit, e.g., a plurality of baffles. Each baffle in the one or more baffles may include a baffle surface. At least a portion of each baffle surface may be at an oblique angle with respect to the flow axis.
[0005] In one embodiment, a pyrolysis system is provided. The pyrolysis system may include a falling bed reactor and a cross-flow classifier. The falling bed reactor may include a reactor conduit defining a flow axis. The falling bed reactor may include an inlet operatively coupled to receive a heat carrier particulate into the reactor conduit. The falling bed reactor may also include an outlet operatively coupled to direct the heat carrier particulate out of the reactor conduit. The falling bed reactor may further include a pyrolysis substrate inlet operatively coupled to receive a pyrolysis substrate into the reactor conduit. The falling bed reactor may include a pyrolysis product outlet operatively coupled to direct a pyrolysis product out of the reactor conduit. The falling bed reactor may also include one or more baffles mounted in the reactor conduit. Each baffle in the one or more baffles may include a baffle surface. At least a portion of each baffle surface may be at an oblique angle with respect to the flow axis.
[0006] The cross-flow classifier may include a separator conduit. The cross-flow classifier may also include a flow input and a flow output in fluidic communication with the separator conduit. The separator conduit may extend between the flow input and the flow output to define a flow axis along at least a portion of the separator conduit. The flow input may be located upstream of the flow output with respect to the flow axis. The cross-flow classifier may include a cross-flow input and a cross-flow output in fluidic communication with the separator conduit between the flow input and the flow output. The cross-flow input may be located upstream of the cross-flow output with respect to the flow axis. The cross- flow input may define a cross-flow axis intersecting the flow axis at a cross-flow angle between about 70° and about 180° with respect to the flow axis. Further with respect to the pyrolysis system, the outlet of the falling bed reactor may be operatively coupled to the flow input of the cross-flow classifier. Also, the flow output of the cross-flow classifier may be operatively coupled to the inlet of the falling bed reactor.
[0007] In one embodiment, a pyrolysis method is provided. The pyrolysis method may include feeding a heat carrier to a gravity-fed baffled conduit. The pyrolysis method may include feeding a pyrolysis substrate to the gravity-fed baffled conduit such that the heat carrier and the pyrolysis substrate mix to form a pyrolysis mixture. The pyrolysis method may include heating the heat carrier and/or the gravity-fed baffled conduit to pyrolyze the pyrolysis substrate in the pyrolysis mixture to form a pyrolysis product mixture. The "gravity-fed baffled conduit" may include, for example, the falling bed reactor.
BRIEF DESCRIPTION OF THE DRAWINGS
[0008] The accompanying figures, which are incorporated in and constitute a part of the specification, illustrate example methods and apparatuses, and are used merely to illustrate example embodiments.
[0009] FIG. 1 depicts an example falling bed reactor; [0010] FIG. 2 depicts an example pyrolysis system that includes an example falling bed reactor and an example cross-flow particle classifier;
[0011] FIG. 3 is a block diagram of an example cross-flow particle classifier; and
[0012] FIG. 4 is a flow diagram of an example method for pyrolysis.
DETAILED DESCRIPTION
[0013] FIG. 1 depicts an example falling bed reactor 100. Falling bed reactor 100 may include a reactor conduit 102 defining a flow axis 104. Flow axis 104 may have a downstream end, indicated by the arrowhead, and an upstream end, indicated by the shaft end of the arrow. Falling bed reactor 100 may include an inlet 106 operatively coupled to receive a heat carrier particulate into reactor conduit 102. Falling bed reactor 100 may also include an outlet 108 operatively coupled to direct the heat carrier particulate out of reactor conduit 102. Falling bed reactor 100 may further include a pyrolysis substrate inlet 110 operatively coupled to receive a pyrolysis substrate into reactor conduit 102. Falling bed reactor 100 may include a pyrolysis product outlet 112 operatively coupled to direct a pyrolysis product out of reactor conduit 102. Falling bed reactor 100 may also include one or more baffles 114, e.g., a plurality of baffles, mounted in reactor conduit 102. Each baffle in one or more baffles 114 may include a baffle surface 116. At least a portion of each baffle surface 116 may be at an oblique angle 118 with respect to flow axis 104.
[0014] As used herein, the "heat carrier" may be a particulate including one or more of: a metal, a glass, a ceramic, a mineral, or a polymeric composite. For example, the heat carrier may be sand. The heat carrier may include a particulate catalyst. For example, the heat carrier may include a fluid catalytic cracking (FCC) catalyst. The heat carrier may include a spent particulate catalyst. For example, the heat carrier may include a spent FCC catalyst. The heat carrier may be in the form of metal shot, for example, steel shot. In various embodiments, the heat carrier, when employed with the cross flow particle classifier, is of a density effective to provide separation between the heat carrier and the char to be separated in the cross flow particle classifier.
[0015] As used herein, an "oblique angle" is any angle that is not an integer multiple of a right angle. For example, an oblique angle excludes 0°, 90°, and 180°, but includes angles between 0° and 90°, and angles between 90° and 180°.
[0016] In various embodiments, falling bed reactor 100 may be configured to be mounted such that at least a portion of flow axis 104 is parallel or oblique to a vertically downward direction. Falling bed reactor 100 may be configured to be mounted such that at least a portion of each baffle surface 116 is at an oblique angle 118 with respect to the vertically downward direction. Falling bed reactor 100 may be mounted to orient flow axis 104 in a substantially vertically downward direction. In this manner, falling bed reactor 100 may be gravity-fed or gravity operated, at least in part. For example, the pyrolysis substrate may enter falling bed reactor 100 at pyrolysis substrate inlet 110, and the heat carrier particulate may enter falling bed reactor 100 at inlet 106 . The pyrolysis substrate and the heat carrier particulate may fall through falling bed reactor 100, and may be intermittently diverted from flow axis 104 by one or more baffles 114, for example, as indicated by a path 105.
[0017] In some embodiments, a cross section of reactor conduit 102 may include a shape that may be one of: polygonal, rounded polygonal, circular, elliptical, or a combination or composite thereof. A cross section of reactor conduit 102 may include a shape that may be one of: rectangular, rounded rectangular, circular, elliptical, or a combination or composite thereof. For example, reactor conduit 102 may be square in cross section.
[0018] In several embodiments, one or both of inlet 106 and outlet 108 may be substantially parallel with one or both of reactor conduit 102 and flow axis 104. Inlet 106 may be operatively coupled to reactor conduit 102 upstream of outlet 108 with respect to flow axis 104.
[0019] In some embodiments, falling bed reactor 100 may include a pyrolysis substrate inlet 110 operatively coupled to receive a pyrolysis substrate into reactor conduit 102. Falling bed reactor 100 may include a pyrolysis product outlet 112 operatively coupled to direct a pyrolysis product out of reactor conduit 102.
[0020] Pyrolysis substrate inlet 110 may be operatively coupled to reactor conduit 102 upstream of pyrolysis product outlet 112 with respect to flow axis 104. Pyrolysis substrate inlet 110 may be operatively coupled to reactor conduit 102 upstream of pyrolysis product outlet 112 with respect to flow axis 104. Pyrolysis substrate inlet 110 may be operatively coupled to reactor conduit 102 at a same level or downstream of pyrolysis product outlet 112 with respect to flow axis 104. Pyrolysis substrate inlet 110 may be coincident with inlet 106. Pyrolysis product outlet 112 may be coincident with inlet 106 or outlet 108.
[0021] In various embodiments, the one or more baffles 114 may extend from an inside wall 130 of the reactor conduit 102 into the reactor conduit 102. For example, the one or more baffles 114 may extend from the inside wall 130 to define a cantilevered geometry in the reactor conduit 102. The one or more baffles 114 may extend across at least a portion of the reactor conduit 102 between a first portion of the inside wall 130 and a second portion of the inside wall 130. Each of the one or more baffles 114 may include a form of one or more of a rod, a plate, a screen, or a protrusion. Each of the one or more baffles 114 may include a form of a rod. The rod may include a cross-sectional geometry that is at least in part polygonal, rounded polygonal, circular, elliptical, or a combination or composite thereof.
[0022] In some embodiments, each of the one or more baffles 114 may include a baffle surface 116. The baffle surface 116 may be positioned to intersect at least a portion of the reactor conduit 102 with respect to the flow axis 104. At least a portion of the baffle surface 116 may include a geometry that is one or more of flat or convex. At least a portion of the baffle surface 116 may be horizontal with respect to the flow axis 104. At least a portion of the baffle surface 116 may be at an oblique angle 118 with respect to the flow axis 104.
[0023] In various embodiments, one or more baffles 114 may be mounted to place at least the portion of each baffle surface 116 at oblique angle 118 with respect to flow axis 104 such that one or more baffles 114 may form a staggered or alternating pattern in reactor conduit 102. Each baffle in one or more baffles 114 may be mounted to an inside wall 130 of reactor conduit 102 to define a free edge 120 of each baffle surface 116 and a mounted edge 122 of each baffle surface. In some embodiments, one or more baffles 114 may be configured as an alternating sequence of funnels and cones, the funnels aligned with the flow axis 104 and the cones aligned antiparallel to the flow axis 104, each of the funnels and cones may include a free edge 120 at a downstream extremity of each of the funnels and cones. In some embodiments, the staggered or alternating pattern of one or more baffles 114 intersecting flow axis 104 to provide a tortuous flow path through one or more baffles 114. Each baffle surface 116 in one or more baffles 114 may be substantially at oblique angle 118 with respect to flow axis 104. For example, oblique angle 118 may be between about 30° and about 60° with respect to flow axis 104 such that for each baffle surface 116, a free edge 120 of baffle surface 116 may be further downstream along flow axis 104 compared to a mounted edge 122 of baffle surface 116.
[0024] In several embodiments, falling bed reactor 100 may include an agitator mechanism 126 configured to agitate at least a portion of one or more baffles 114 effective to dislodge a particulate on at least a portion of one or more baffles 114. Falling bed reactor 100 may include a heater 128. Heater 128 may be configured cause pyrolysis of a substrate in falling bed reactor 100 by heating one or both of falling bed reactor 100 and a heat carrier to be fed into falling bed reactor 100. [0025] FIG. 2 depicts an example pyrolysis system 200. Pyrolysis system 200 may include falling bed reactor 100 and a cross-flow classifier 3100. Falling bed reactor 100 may include a reactor conduit 102 defining a flow axis 104. Flow axis 104 may have a downstream end, indicated by the arrowhead, and an upstream end, indicated by the shaft end of the arrow. Falling bed reactor 100 may include an inlet 106 operatively coupled to receive a heat carrier particulate into reactor conduit 102. Falling bed reactor 100 may also include an outlet 108 operatively coupled to direct the heat carrier particulate out of reactor conduit 102. Falling bed reactor 100 may further include a pyrolysis substrate inlet 110 operatively coupled to receive a pyrolysis substrate into reactor conduit 102. Falling bed reactor 100 may include a pyrolysis product outlet 112 operatively coupled to direct a pyrolysis product out of reactor conduit 102. Falling bed reactor 100 may also include one or more baffles 114 mounted in reactor conduit 102. Each baffle in one or more baffles 114 may include a baffle surface 116. At least a portion of each baffle surface 116 may be at an oblique angle 118 with respect to flow axis 104.
[0026] Cross-flow classifier 3100 may include a separator conduit 3102. Cross-flow classifier 3100 may also include a flow input 3104 and a flow output 3106 in fluidic communication with separator conduit 3102. Separator conduit 3102 may extend between flow input 3104 and flow output 3106 to define a flow axis 3108 along at least a portion of separator conduit 3102. Flow input 3104 may be located upstream of flow output 3106 with respect to flow axis 3108. Cross-flow classifier 3100 may include a cross-flow input 3114 and a cross-flow output 3116 in fluidic communication with separator conduit 3102 between flow input 3104 and flow output 3106. Cross-flow input 3114 may be located upstream of cross-flow output 3116 with respect to flow axis 3108. Cross-flow input 3114 may define a cross-flow axis 3118 intersecting flow axis 3108 at a cross-flow angle 3120 between about 70° and about 180° with respect to flow axis 3108. Further with respect to pyrolysis system 200, outlet 108 of falling bed reactor 100 may be operatively coupled to flow input 3104 of cross-flow classifier 3100. Also, flow output 3106 of cross-flow classifier 3100 may be operatively coupled to inlet 106 of falling bed reactor 100.
[0027] In various embodiments, outlet 108 of falling bed reactor 100 may be operatively coupled to flow input 3104 of cross-flow classifier 3100 via an auger or conveyor 230. Flow output 3106 of cross-flow classifier 3100 may be operatively coupled to inlet 106 of falling bed reactor 100 via an auger or conveyor 232.
[0028] In some embodiments, pyrolysis system 200 may include a fine particulate separator 202. An input 204 of fine particulate separator 202 may be operatively coupled to pyrolysis product outlet 112 of falling bed reactor 100. Fine particulate separator 202 may include a particulate outlet 206 and a gas or vapor outlet 208. For example, fine particulate separator 202 may include one or more of: a settling chamber, a baffle chamber, a cyclonic particle separator, an electrostatic precipitator, a filter, or a scrubber
[0029] In several embodiments, pyrolysis system 200 may include a coarse particulate separator 212. An input 214 of coarse particulate separator 212 may be operatively coupled to cross-flow output 3116 of cross-flow classifier 3100. Coarse particulate separator 212 may include a particulate outlet 216 and a gas outlet 218. For example, coarse particulate separator 212 may include one or more of: a settling chamber, a baffle chamber, a cyclonic particle separator, an electrostatic precipitator, a filter, or a scrubber
[0030] In various embodiments, pyrolysis system 200 may include a gas recycle conduit 220. Gas recycle conduit 220 may be operatively coupled to receive recycled gas from gas outlet 218. Gas recycle conduit 220 may be operatively coupled to direct the recycled gas to cross-flow input 3114 of cross-flow classifier 3100. In some embodiments, gas recycle conduit 220 may include a fan 222. Fan 222 may be configured to draw the recycled gas from gas outlet 218 via gas recycle conduit 220. Fan 222 may be configured to flow the recycled gas to cross-flow input 3114 of cross-flow classifier 3100 via gas recycle conduit 220.
[0031] In further embodiments, falling bed reactor 100 in pyrolysis system 200 may include any aspect of falling bed reactor 100 described herein.
[0032] FIGS. 3A and 3B depict aspects of cross-flow classifier 3100 that may be used in example pyrolysis system 200. For example, in various embodiments, one or both of flow input 3114 and flow output 3116 may be substantially aligned with flow axis 3108 of separator conduit 3102. In some embodiments, cross-flow input 3114 may be operatively coupled to separator conduit 3102 substantially opposite to cross-flow output 3116 with respect to flow axis 3108.
[0033] In some embodiments, cross-flow classifier 3100 may be mounted such that flow axis 3108 points downward at a flow angle 3110. For example, flow angle 3110 may be less than 90° from vertically downward. In some embodiments, flow angle 3110 may be less than 60° from vertically downward.
[0034] As used herein, "downward" means any direction represented by a vector having a non-zero component parallel with respect to a local gravitational acceleration direction. As used herein, "upward" means any direction represented by a vector having a non-zero component antiparallel with respect to the local gravitational acceleration direction. As used herein, "vertical" means parallel or antiparallel with respect to the local gravitational acceleration direction. "Vertically downward" means parallel with respect to the local gravitational acceleration direction, indicated in FIG. 1 by arrow 3101. "Vertically upward" means antiparallel with respect to the local gravitational acceleration direction. As used herein, "horizontal" means perpendicular to the local gravitational acceleration direction.
[0035] In several embodiments, separator conduit 3102 may include a first flow diameter 3122 between flow input 3104 and cross-flow input 3114. Separator conduit 3102 may include a second flow diameter 3124 downstream of cross-flow input 3114. First flow diameter 3122 may be greater than second flow diameter 3124. Separator conduit 3102 may include a transition 3126 between first flow diameter 3122 and second flow diameter 3124. Transition 3126 may be substantially aligned with cross-flow angle 3120. For example, transition 3126 may be substantially perpendicular with respect to flow axis 3108.
[0036] In various embodiments, flow input 3104 may be configured to accept a plurality of particulates. At least a first particulate in the plurality of particulates may be characterized by a first average density. At least a second particulate in the plurality of particulates may be characterized by a second average density greater than the first average density. Flow output 3106 may be configured to convey at least a portion of the first particulate characterized by the first density out of separator conduit 3102. Cross-flow output 3116 may be configured to convey at least a portion of the second particulate characterized by the second density greater than the first density out of separator conduit 3102.
[0037] As used herein, a "particulate" refers to a plurality, collection, or distribution of individual particles. The individual particles in the particulate may have in common one or more characteristics, such as size, density, material composition, heat capacity, particle morphology, and the like. The characteristics of the particles in the particulate may be the same among the particles, or may be characterized by a distribution. For example, particles in a particulate may all be made of the same composition, e.g., a ceramic, a metal, or the like. In another example, particles in a particulate may be characterized by a distribution of particle sizes, for example, a Gaussian distribution.
[0038] In some embodiments, cross-flow input 3114 may define a first convergent nozzle 3132. First convergent nozzle 3132 may include a first nozzle throat 3134. A cross section of first nozzle throat 3134 may include at least two dissimilar axes. For example, first nozzle throat 3134 may include an elliptical cross section, a circular cross section, a rectangular cross section, a rounded corner rectangular cross section, a polygonal cross section, a composite or combination thereof, or the like.
[0039] In several embodiments, the first nozzle throat 3134 may be operatively coupled to a nozzle exit zone. At least a portion of the nozzle exit zone may include a transition 3126 between a first flow diameter 3122 of flow conduit 3108 and first nozzle throat 3134. In some embodiments, at least a portion of the nozzle exit zone may include a second flow diameter 3124 of separator conduit 3108. Transition 3126 may be located at an upstream side of first nozzle throat 3134. Second flow diameter 3124 may be located at a downstream side of first nozzle throat 3134. First nozzle throat 3134 may be located at second flow diameter 3124 of separator conduit 3108.
[0040] In various embodiments, convergent nozzle 3132 of cross-flow input 3114 may include a second nozzle throat 3138. First nozzle throat 3134 may be located at cross-flow input 3114 between second nozzle throat 3138 and separator conduit 3108. Cross-flow output 3116 may define a second convergent nozzle 3142.
[0041] In some embodiments, second convergent nozzle 3142 may include a third nozzle throat 3144. A cross section of third nozzle throat 3144 may include at least two dissimilar axes. For example, third nozzle throat 3144 may include an elliptical cross section, a circular cross section, a rectangular cross section, a rounded corner rectangular cross section, a polygonal cross section, a composite or combination thereof, or the like. Third nozzle throat 3144 may be operatively coupled to a nozzle entrance zone 3146. At least a portion of nozzle entrance zone 3146 may include a transition 3148 between a second flow diameter 3124 of flow conduit 3108 and third nozzle throat 3144. In some embodiments, at least a portion of nozzle entrance zone 3146 may include an entrance vane 3150. Entrance vane 3150 may extend into separator conduit 3102, for example, with respect to second flow diameter 3124. At least a portion of entrance vane 3150 may extend into separator conduit 3102 at least partly in an upstream direction with respect to flow axis 3108.
[0042] In several embodiments, third nozzle throat 3144 may be operatively coupled through a nozzle collector zone to an exit conduit 3154. One or both of the nozzle collector zone and conduit 3154 may include an elliptical cross section. For example, one or both of the nozzle collector zone and exit conduit 3154 may include a circular cross section. Third nozzle throat 3144 may be operatively coupled to an exit conduit 3154. Exit conduit 3154 may define an exit conduit axis 3156. Exit conduit axis 3156 may intersect flow axis 3108 at an exit angle 3158. Exit angle 3158 may be greater than 0° and less than 180°. For example, exit angle 3158 may be between about 90° and less than 180°. In some embodiments, exit conduit axis 3156 may be within about 30° of vertical.
[0043] FIG. 4 is a flow diagram describing an example pyrolysis method 400.
Pyrolysis method 400 may include feeding a heat carrier to a gravity-fed baffled conduit (step 402). Pyrolysis method 400 may include feeding a pyrolysis substrate to the gravity-fed baffled conduit such that the heat carrier and the pyrolysis substrate mix to form a pyrolysis mixture (step 404). Pyrolysis method 400 may include heating the heat carrier and/or the gravity-fed baffled conduit to pyrolyze the pyrolysis substrate in the pyrolysis mixture to form a pyrolysis product mixture (step 406). The gravity-fed baffled conduit may include, for example, the falling bed reactor 100 described herein.
[0044] In various embodiments of pyrolysis method 400, the pyrolysis product mixture may include a gas or vapor pyrolysis product and a fine char pyrolysis product. The method may include directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit. The pyrolysis product mixture may include the heat carrier and a coarse char pyrolysis product. The method may further include directing the heat carrier and the coarse char pyrolysis product out of the gravity-fed baffled conduit. In some examples, the method may include directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit at the same level as the heat carrier and the coarse char pyrolysis product. The method may include directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit upstream compared to the heat carrier and the coarse char pyrolysis product. The method may include directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit downstream compared to the heat carrier and the coarse char pyrolysis product
[0045] In some embodiments, the pyrolysis product mixture may include the heat carrier and a coarse char pyrolysis product. The method may include directing the heat carrier and the coarse char pyrolysis product out of the gravity-fed baffled conduit.
[0046] In several embodiments, feeding the heat carrier to the gravity-fed baffled conduit may include feeding the heat carrier and the pyrolysis substrate to the same level in the gravity-fed baffled conduit. Feeding the heat carrier to the gravity-fed baffled conduit may include feeding the heat carrier to the gravity-fed baffled conduit upstream of the pyrolysis substrate. Feeding the heat carrier to the gravity-fed baffled conduit may include feeding the heat carrier to the gravity-fed baffled conduit downstream of the pyrolysis substrate.
[0047] In various embodiments, the pyrolysis product mixture may include a gas or vapor pyrolysis product and a fine char pyrolysis product. The method may also include directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit. The method may also include separating the gas or vapor pyrolysis product from the fine char pyrolysis product. The pyrolysis product mixture may include the heat carrier and a coarse char pyrolysis product. The method may include directing the heat carrier and the coarse char pyrolysis product out of the gravity-fed baffled conduit. The method may also include separating the heat carrier from the coarse char pyrolysis product. The method may include recycling the heat carrier to form a recycled heat carrier. The method may also include feeding the recycled heat carrier to the gravity-fed baffled conduit.
[0048] In several embodiments of the method, separating the heat carrier from the coarse char pyrolysis product may include directing a flow comprising a plurality of particulates along a flow axis. The method may also include separating at least a portion of a first particulate from the plurality of particulates to form a separated portion of the first particulate by directing a gas jet along a cross-flow axis, the cross-flow axis intersecting the flow axis at a cross-flow angle, the cross-flow angle being between about 70° and about 180°. As used herein, the plurality of particulates may include the heat carrier and the coarse char pyrolysis product. As used herein, the first particulate may include the coarse char pyrolysis product
[0049] In various embodiments, the gas jet may include a gas temperature of between about 300 °C and about 700 °C. The gas temperature may be a temperature in °C of about 300, 320, 340, 360, 380, 400, 420, 440, 460, 480, 500, 520, 540, 560, 580, 600, 620, 640, 660, 680, or 700, or any range between any two of the preceding temperature values.
[0050] In some embodiments, the gas jet may include a gas density (in kilograms per cubic meter) of between about 0.4 and about 1.4. The gas density may have a value (in kilograms per cubic meter) of about 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 1.1, 1.2, 1.3, or 1.4, or any range between any two of the preceding density values.
[0051] In several embodiments, the gas jet may include a gas viscosity (in kilograms per meter-second) of between about lxlO"6 and about lxlO"4. For example, the gas viscosity may have a value in 10"5 kilograms per meter-second of about 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 1.2, 1.3, 1.4, 1.5, 1.6, 1.7, 1.8, 1.9, 2, 2.2, 2.4, 2.6, 2.8, 3, 3.25, 3.5, 3.75, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, or 10, or any range between any two of the preceding gas viscosity values. [0052] In various embodiments, the gas jet may include a gas flow rate of less than 25 cubic feet per minute. The gas jet may include a gas pressure drop of less than 5 inches of for example, about 1.5 inches of water or less.
[0053] In several embodiments of method 400, separating at least the portion of the first particulate from the plurality of particulates to form the separated portion of the first particulate further may include directing the separated portion of the first particulate away from the cross-flow axis to a surface of a separator conduit. Method 400 may also include directing the separated portion of the first particulate along the surface for a distance. Directing the separated portion of the first particulate along the surface may include directing the separated portion of the first particulate substantially parallel to the first directional flow axis. Directing the separated portion of the first particulate along the surface may include using the Coanda effect. Some embodiments may include diverting the separated portion of the first particulate along the surface away from the surface to a cross-flow output. Diverting the separated portion of the first particulate along the surface away from the surface and through the cross-flow output may include using the Coanda effect. Diverting the separated portion of the first particulate along the surface away from the surface and through the cross- flow output may include contacting the separated portion of the first particulate along the surface with an entrance vane. The entrance vane may be in fluidic communication with the cross-flow output.
[0054] In various embodiments of method 400, separating at least the portion of the first particulate from the plurality of particulates may include substantially separating the first particulate from the plurality of particulates. Separating at least the portion of the first particulate from the plurality of particulates may include separating at least about 90%, 95%, 97%, 98%, 99%, 99.1%, 99.2%, 99.3%, 99.4%, 99.5%, 99.6%, 99.7%, 99.8%, 99.9%, 99.95%, 99.99%, 99.995%, or 99.999% by weight of the first particulate from the plurality of particulates. For example, separating at least the portion of the first particulate from the plurality of particulates may include separating at least about 99% by weight of the first particulate from the plurality of particulates.
[0055] In some embodiments, the first particulate may include one or more of a biomass or a pyrolysis product, for example, a biomass pyrolysis product. For example, the first particulate may include char. The first particulate may comprise a first average density (in kilograms per cubic meter) of between about 100 and about 2,000. For example, the first average density (in kilograms per cubic meter) may be about 100, 200, 300, 400, 500, 600, 700, 800, 900, 1000, 1 100, 1200, 1300, 1400, 1500, 1600, 1700, 1800, 1900, or 2000, or between any two of the preceding density values. For example, the first average density may be about 374 kilograms per cubic meter.
[0056] In several embodiments, the first particulate may be characterized by a first average diameter (in millimeters) of between about 0.1 and about 10. For example, the first average diameter (in millimeters) may be about 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 1.2, 1.4, 1.6, 1.8, 2, 2.25, 2.5, 2.75, 3, 3.25, 3.5, 3.75, or 4, or between any two of the preceding average diameter values.
[0057] In various embodiments, the first particulate may include an average flow rate (in kilograms per second) of between about 0.0012 and about 0.0023. For example, the average flow rate (in kilograms per second) may be about 0.0012, 0.0013, 0.0014, 0.0015, 0.0016, 0.0017, 0.0018, 0.0019, 0.0020, 0.0021, 0.0022, or 0.0023, or between any two of the preceding flow rate values.
[0058] In some embodiments, the first particulate may include a first average density and the plurality of particulates may include at least a second particulate. The second particulate may be characterized by a second average density greater than the first average density. The second particulate may be, for example, a heat carrier suitable for use in an auger pyrolyzer. The second particulate may include one or more of a metal, a glass, a ceramic, a mineral, or a polymeric composite. For example, the second particulate may include one or more of: steel, stainless steel, cobalt (Co), molybdenum (Mo ), nickel (Ni), titanium (Ti), tungsten (W), zinc (Zn), antimony (Sb), bismuth (Bi), cerium (Ce), vanadium (V), niobium (Nb), tantalum (Ta), chromium (Cr), manganese (Ma), rhenium (Re), iron (Fe), platinum (Pt), iridium (Ir), palladium (Pd), osmium (Os), rhodium (Rh), ruthenium (Ru), nickel, copper impregnated zinc oxide (Cu/ZnO), copper impregnated chromium oxide (Cu/Cr), nickel aluminum oxide ( 1/AI2O3), palladium aluminum oxide (PdA^C^), cobalt molybdenum (C0M0), nickel molybdenum (NiMo), nickel molybdenum tungsten (NiMoW), sulfided cobalt molybdenum (C0M0), sulfided nickel molybdenum (NiMo ), or a metal carbide.
[0059] In several embodiments, the second average density of the second particulate (in kilograms per cubic meter) may be between about 3,000 and about 23,000, for example, about 3,000, 4,000, 5,000, 6,000, 7,000, 8,000, 9,000, 10,000, 1 1,000, 12,000, 13,000, 14,000, 15,000, 16,000, 17,000, 18,000, 19,000, 20,000, 21,000, 22,000, or 23,000, or between about any two of the preceding density values. For example, the second particulate may be steel or stainless steel at a density of about 7,500 kilograms per cubic meter.
[0060] In various embodiments, the second average density of the second particulate divided by the first average density of the first particulate may be a ratio between about 1.5: 1 and about 230: 1. For example, the ratio may be about 1.5: 1, 2: 1, 5: 1, 10: 1, 15: 1, 20: 1, 25: 1, 50: 1, 75: 1, 100: 1, 125: 1, 150: 1, 175: 1, 200: 1, 225: 1, 230: 1, or a range between about any two of the preceding ratios.
[0061] In some embodiments, the second particulate may be characterized by a first average diameter (in millimeters) of between about 0.1 and about 25, for example, about 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 1 1, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, or a range between about any two of the preceding average diameter values, for example, between about 1 mm and about 10 mm.
[0062] In some embodiments, the second particulate may include a spherical, rounded, or ellipsoid morphology. In some embodiments, the second particulate may include a substantially spherical morphology.
[0063] In several embodiments, the second particulate may include a flow rate (in kilograms per second per each ton per day of biomass processed) of about 0.4 to about 1.4, for example, about 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 1.1, 1.2, 1.3, 1.4, or a range between any two of the preceding flow rates.
[0064] In some embodiments, the first particulate may be characterized by a first terminal velocity and the second particulate may be characterized by a second terminal velocity. The first and second particulates may be characterized by a ratio of the second terminal velocity to the first terminal velocity of at least about 5: 1, 10: 1, 15: 1, 20: 1, 25: 1, 30: 1, or 35: 1.
[0065] In various embodiments, method 400 may also include separating at least a portion of a second particulate in the plurality of particulates from the first particulate. For example, method 400 may include separating substantially all of a second particulate in the plurality of particulates from the first particulate. Method 400 may include separating at least a portion of a second particulate in the plurality of particulates from the first particulate in a direction substantially aligned with the first directional flow axis. The method may also include directing the flow axis downward at a flow angle. The flow angle may be less than 90° from vertically downward. The flow angle may be less than 60° from vertically downward.
[0066] In several embodiments, method 400 may include forming the gas jet by flowing a gas through a first convergent nozzle. The first convergent nozzle may include a first nozzle throat. A cross section of the first nozzle throat may include at least two dissimilar axes. For example, the first nozzle throat may include an elliptical cross section, a circular cross section, a rectangular cross section, a rounded corner rectangular cross section, a polygonal cross section, a composite or combination thereof, or the like.
[0067] In various embodiments, method 400 may also include adapting the flow upstream of the gas jet to a first flow diameter and adapting the flow downstream of the gas jet to a second flow diameter. The first flow diameter may be greater than the second flow diameter. The method may also include adapting the flow between the first flow diameter and the second flow diameter using a transition between the first flow diameter and the second flow diameter. The transition may be substantially aligned with the cross-flow angle. For example, the transition may be substantially perpendicular with respect to the flow axis. The transition may extend between at least a portion of the first flow diameter and at least a portion of the first nozzle throat. At least a portion of the second flow diameter may coincide with at least a portion of the first nozzle throat. The first nozzle throat may be located at the second flow diameter of the separator conduit.
[0068] In some embodiments, forming the gas jet may also include flowing the gas through a second nozzle throat upstream of the first nozzle throat.
[0069] In several embodiments, separating at least the portion of the first particulate from the plurality of particulates may also include extending an entrance vane into a portion of the flow defined by the second flow diameter. The method may include extending at least a portion of the entrance vane into the flow at least partly in an upstream direction with respect to the first directional flow axis.
[0070] In various embodiments of method 400, separating at least the portion of the first particulate from the plurality of particulates may include directing the separated portion of the first particulate away from the flow axis. The method may include directing the separated portion of the first particulate away from the flow axis substantially opposite to the gas jet along the cross-flow axis with respect to the first directional flow axis.
[0071] In several embodiments, method 400 may include directing a separated portion of the first particulate away from the flow axis through a third nozzle throat. A cross section of the third nozzle throat may include at least two dissimilar axes. For example, the third nozzle throat may include an elliptical cross section, a circular cross section, a rectangular cross section, a rounded corner rectangular cross section, a polygonal cross section, a composite or combination thereof, or the like. Separating at least the portion of the first particulate from the plurality of particulates may also include directing the separated portion of the first particulate away from the third nozzle throat through an elliptical cross section. For example, the method may include directing the separated portion of the first particulate away from the third nozzle throat through a circular cross section.
[0072] In some embodiments, separating at least the portion of the first particulate from the plurality of particulates further may include directing the separated portion of the first particulate away from the third nozzle throat via an exit conduit axis. The exit conduit axis may intersect the flow axis at an angle. The angle may be greater than 0° and less than 180°. For example, the angle may be between about 90° and less than 180°. In some examples, the exit conduit axis may be within about 30° of vertical.
PROPHETIC EXAMPLE
[0073] Heated spherical steel shot, about 1 mm in diameter, may be added via inlet 106 into reactor conduit 102. Ground particulate bio-mass (e.g., a mixture of corn stover and wood particulate) may be added via pyrolysis substrate inlet 110 into reactor conduit 102. The reactor conduit 102 and the steel shot may be heated to a desired pyrolysis temperature, e.g., 500 °C. The heated steel shot and the bio-mass may fall through the one or more baffles 114 mounted in reactor conduit 102. The heated steel shot and the bio-mass may mix, and the bio-mass may pyrolyze to form a pyrolysis mixture including gas or vapor of bio-oil, bio- char, and the heated steel shot. A mixture of fine bio-char and the gas or vapor of bio-oil may be collected at pyrolysis product outlet 112. A mixture of coarse bio-char and the steel shot may be collected at outlet 108. The falling bed reactor described in this Example may exhibit effective mixing between the steel shot heat carrier and the bio-mass, similar to the mixing observed in fluidized bed reactors. The falling bed reactor described in this Example may also operate without needing inert gas, similar to the operation of auger reactors.
[0074] To the extent that the term "includes" or "including" is used in the specification or the claims, it is intended to be inclusive in a manner similar to the term "comprising" as that term is interpreted when employed as a transitional word in a claim. Furthermore, to the extent that the term "or" is employed (e.g., A or B) it is intended to mean "A or B or both." When the applicants intend to indicate "only A or B but not both" then the term "only A or B but not both" will be employed. Thus, use of the term "or" herein is the inclusive, and not the exclusive use. See Bryan A. Garner, A Dictionary of Modern Legal Usage 624 (2d. Ed. 1995). Also, to the extent that the terms "in" or "into" are used in the specification or the claims, it is intended to additionally mean "on" or "onto." To the extent that the term "selectively" is used in the specification or the claims, it is intended to refer to a condition of a component wherein a user of the apparatus may activate or deactivate the feature or function of the component as is necessary or desired in use of the apparatus. To the extent that the terms "coupled" or "operatively connected" are used in the specification or the claims, it is intended to mean that the identified components are connected in a way to perform a designated function. To the extent that the term "substantially" is used in the specification or the claims, it is intended to mean that the identified components have the relation or qualities indicated with degree of error as would be acceptable in the subject industry. [0075] As used in the specification and the claims, the singular forms "a," "an," and "the" include the plural unless the singular is expressly specified. For example, reference to "a compound" may include a mixture of two or more compounds, as well as a single compound.
[0076] As used herein, the term "about" in conjunction with a number is intended to include ± 10% of the number. In other words, "about 10" may mean from 9 to 1 1.
[0077] As used herein, the terms "optional" and "optionally" mean that the subsequently described circumstance may or may not occur, so that the description includes instances where the circumstance occurs and instances where it does not.
[0078] In addition, where features or aspects of the disclosure are described in terms of Markush groups, those skilled in the art will recognize that the disclosure is also thereby described in terms of any individual member or subgroup of members of the Markush group. As will be understood by one skilled in the art, for any and all purposes, such as in terms of providing a written description, all ranges disclosed herein also encompass any and all possible sub-ranges and combinations of sub-ranges thereof. Any listed range can be easily recognized as sufficiently describing and enabling the same range being broken down into at least equal halves, thirds, quarters, fifths, tenths, and the like. As a non-limiting example, each range discussed herein can be readily broken down into a lower third, middle third and upper third, and the like. As will also be understood by one skilled in the art all language such as "up to," "at least," "greater than," "less than," include the number recited and refer to ranges which can be subsequently broken down into sub-ranges as discussed above. Finally, as will be understood by one skilled in the art, a range includes each individual member. For example, a group having 1-3 cells refers to groups having 1, 2, or 3 cells. Similarly, a group having 1-5 cells refers to groups having 1, 2, 3, 4, or 5 cells, and so forth. While various aspects and embodiments have been disclosed herein, other aspects and embodiments will be apparent to those skilled in the art.
[0079] As stated above, while the present application has been illustrated by the description of embodiments thereof, and while the embodiments have been described in considerable detail, it is not the intention of the applicants to restrict or in any way limit the scope of the appended claims to such detail. Additional advantages and modifications will readily appear to those skilled in the art, having the benefit of the present application. Therefore, the application, in its broader aspects, is not limited to the specific details, illustrative examples shown, or any apparatus referred to. Departures may be made from such details, examples, and apparatuses without departing from the spirit or scope of the general inventive concept.
[0080] The various aspects and embodiments disclosed herein are for purposes of illustration and are not intended to be limiting, with the true scope and spirit being indicated by the following claims.

Claims

1. A falling bed reactor 100, comprising: a reactor conduit 102 defining a flow axis 104; an inlet 106 operatively coupled to receive a heat carrier particulate into the reactor conduit 102; an outlet 108 operatively coupled to direct the heat carrier particulate out of the reactor conduit 102; one or more baffles 114 mounted in the reactor conduit 102.
2. The falling bed reactor 100 of claim 1, comprising: the reactor conduit 102 defining the flow axis 104; the inlet 106 operatively coupled to receive the heat carrier particulate into the reactor conduit 102; the outlet 108 operatively coupled to direct the heat carrier particulate out of the reactor conduit 102; a pyrolysis substrate inlet 110 operatively coupled to receive a pyrolysis substrate into the reactor conduit 102; a pyrolysis product outlet 112 operatively coupled to direct a pyrolysis product out of the reactor conduit 102; and the one or more baffles 114 mounted in the reactor conduit 102, each baffle in the one or more baffles 114 comprising a baffle surface 116, at least a portion of each baffle surface 116 being at an oblique angle 118 with respect to the flow axis 104.
3. The falling bed reactor 100 of claim 1, configured to be mounted such that at least a portion of the flow axis 104 is parallel or oblique to a vertically downwards direction.
4. The falling bed reactor 100 of claim 2, configured to be mounted such that at least a portion of the flow axis 104 is parallel or oblique to a vertically downwards direction, and at least a portion of each baffle surface 116 is at the oblique angle 118 with respect to the vertically downwards direction.
5. The falling bed reactor 100 of claim 1, mounted to orient the flow axis 104 in a substantially vertically downwards direction.
6. The falling bed reactor 100 of claim 1, a cross section of the reactor conduit 102 comprising a shape that is one of: polygonal, rounded polygonal, elliptical, circular, or a combination or composite thereof.
7. The falling bed reactor 100 of claim 1, a cross section of the reactor conduit 102 comprising a shape that is one of: rectangular, rounded rectangular, elliptical, circular, or a combination or composite thereof.
8. The falling bed reactor 100 of claim 1, a cross section of the reactor conduit 102 being square.
9. The falling bed reactor 100 of claim 1, one or both of the inlet 106 and the outlet 108 being substantially parallel with one or both of the reactor conduit 102 and the flow axis 104.
10. The falling bed reactor 100 of claim 1, the inlet 106 being operatively coupled to the reactor conduit 102 upstream of the outlet 108 with respect to the flow axis 104.
11. The falling bed reactor 100 of claim 1, the inlet 106 being operatively coupled to receive a pyro lysis substrate into the reactor conduit 102.
12. The falling bed reactor 100 of claim 1, the outlet 108 being operatively coupled to direct a pyrolysis product out of the reactor conduit 102.
13. The falling bed reactor 100 of claim 1, further comprising: a pyrolysis substrate inlet 110 operatively coupled to receive a pyrolysis substrate into the reactor conduit 102; and a pyrolysis product outlet 112 operatively coupled to direct a pyrolysis product out of the reactor conduit 102.
14. The falling bed reactor 100 of claim 13, further comprising a fine particulate separator 202, an input 204 of the fine particulate separator 202 operatively coupled to the pyrolysis product outlet 112 of the falling bed reactor 100 and the fine particulate separator 202 comprising a particulate outlet 206 and a gas or vapor outlet 208.
15. The falling bed reactor 100 of claim 14, the fine particulate separator 202 comprising one or more of: a settling chamber, a baffle chamber, a cyclonic particle separator, an electrostatic precipitator, a filter, or a scrubber.
16. The falling bed reactor 100 of claim 13, the pyrolysis substrate inlet 110 being operatively coupled to the reactor conduit 102 upstream of the pyrolysis product outlet 112 with respect to the flow axis 104.
17. The falling bed reactor 100 of claim 13, the pyrolysis substrate inlet 110 being operatively coupled to the reactor conduit 102 upstream of the pyrolysis product outlet 112 with respect to the flow axis 104.
18. The falling bed reactor 100 of claim 13, the pyrolysis substrate inlet 110 being operatively coupled to the reactor conduit 102 at a same level or downstream of the pyrolysis product outlet 112 with respect to the flow axis 104.
19. The falling bed reactor 100 of claim 13, the pyrolysis substrate inlet 110 being coincident with the inlet 106.
20. The falling bed reactor 100 of claim 13, the pyrolysis product outlet 112 being coincident with the inlet 106 or the outlet 108.
21. The falling bed reactor 100 of claim 1, the one or more baffles 114 extending from an inside wall 130 of the reactor conduit 102 into the reactor conduit 102.
22. The falling bed reactor 100 of claim 21, the one or more baffles 114 extending from the inside wall 130 to define a cantilevered geometry in the reactor conduit 102.
23. The falling bed reactor 100 of claim 21, the one or more baffles 114 extending across at least a portion of the reactor conduit 102 between a first portion of the inside wall 130 and a second portion of the inside wall 130.
24. The falling bed reactor 100 of claim 21, each of the one or more baffles 114 comprising a form of one or more of a rod, a plate, a funnel, a cone, a screen, or a protrusion.
25. The falling bed reactor 100 of claim 21, each of the one or more baffles 114 comprising a form of a rod, the rod having a cross-sectional geometry that is at least in part polygonal, rounded polygonal, circular, elliptical, or a combination or composite thereof.
26. The falling bed reactor 100 of claim 21, each of the one or more baffles 114 comprising a baffle surface 116 positioned to intersect at least a portion of the reactor conduit 102 with respect to the flow axis 104, at least a portion of the baffle surface 116 comprising a geometry that is one or more of flat or convex.
27. The falling bed reactor 100 of claim 21, each of the one or more baffles 114 comprising a baffle surface 116, at least a portion of the baffle surface 116 being horizontal with respect to the flow axis 104.
28. The falling bed reactor 100 of claim 21, each of the one or more baffles 114 comprising a baffle surface 116, at least a portion of the baffle surface 116 being at an oblique angle 118 with respect to the flow axis 104.
29. The falling bed reactor 100 of claim 28, the one or more baffles 114 being mounted to place at least the portion of each baffle surface 116 at the oblique angle 118 with respect to the flow axis 104 such that the one or more baffles 114 form a staggered or alternating pattern in the reactor conduit 102.
30. The falling bed reactor 100 of claim 29, the staggered or alternating pattern of the one or more baffles 114 intersecting the flow axis 104 to provide a tortuous flow path through the one or more baffles 114.
31. The falling bed reactor 100 of claim 21, each baffle in the one or more baffles 114 being mounted to an inside wall 130 of the reactor conduit 102 to define a free edge 120 of each baffle surface 116 and a mounted edge 122 of each baffle surface 116.
32. The falling bed reactor 100 of claim 21, each baffle surface 116 in the one or more baffles 114 is substantially at the oblique angle 118 with respect to the flow axis 104.
33. The falling bed reactor 100 of claim 21, the oblique angle 118 being between about 30° and about 60° with respect to the flow axis 104 such that for each baffle surface 116, a free edge 120 of the baffle surface 116 is further downstream along the flow axis 104 compared to a mounted edge 122 of the baffle surface 116.
34. The falling bed reactor 100 of claim 21, further comprising an agitator mechanism 126 configured to agitate at least a portion of the one or more baffles 114 effective to dislodge a particulate on at least a portion of the one or more baffles 114.
35. The falling bed reactor 100 of claim 1, further comprising a heater 128 configured to cause pyrolysis of a substrate in the falling bed reactor 100 by heating one or both of the falling bed reactor 100 and a heat carrier to be fed into the falling bed reactor 100.
36. The falling bed reactor 100 of claim 1, being configured to employ the heat carrier comprising one or more of: a metal, a glass, a ceramic, a mineral, or a polymeric composite.
37. The falling bed reactor 100 of claim 1, being configured to employ sand as the heat carrier.
38. The falling bed reactor 100 of claim 1, being configured to employ a particulate catalyst as the heat carrier.
39. A pyrolysis system 200, comprising: a falling bed reactor 100, comprising: a reactor conduit 102 defining a flow axis 104; an inlet 106 operatively coupled to receive a heat carrier particulate into the reactor conduit 102; an outlet 108 operatively coupled to direct the heat carrier particulate out of the reactor conduit 102; one or more baffles 114 mounted in the reactor conduit 102; and a cross-flow classifier 3100, comprising: a separator conduit 3102; a flow input 3104 and a flow output 3106 in fluidic communication with the separator conduit 3102, the separator conduit 3102 extending between the flow input 3104 and the flow output 3106 to define a flow axis 3108 along at least a portion of the separator conduit 3102, the flow input 3104 being located upstream of the flow output 3106 with respect to the flow axis 3108; and a cross-flow input 3114 and a cross-flow output 3116 in fluidic communication with the separator conduit 3102 between the flow input 3104 and the flow output 3106, the cross-flow input 3114 being located upstream of the cross-flow output 3116 with respect to the flow axis 3108, the cross-flow input 3114 defining a cross-flow axis 3118 intersecting the flow axis 3108 at a cross-flow angle 3120 between about 70° and about 180° with respect to the flow axis 3108, wherein: the outlet 108 of the falling bed reactor 100 is operatively coupled to the flow input 3104 of the cross-flow classifier 3100; and the flow output 3106 of the cross-flow classifier 3100 is operatively coupled to the inlet 108 of the falling bed reactor 100.
40. The pyrolysis system 200 of claim 39, comprising: the falling bed reactor 100, comprising: the reactor conduit 102 defining a flow axis 104; the inlet 106 operatively coupled to receive a heat carrier particulate into the reactor conduit 102; the outlet 108 operatively coupled to direct the heat carrier particulate out of the reactor conduit 102; a pyrolysis substrate inlet 110 operatively coupled to receive a pyrolysis substrate into the reactor conduit 102; a pyrolysis product outlet 112 operatively coupled to direct a pyrolysis product out of the reactor conduit 102; the one or more baffles 114 mounted in the reactor conduit 102, each baffle in the one or more baffles 114 comprising a baffle surface 116, at least a portion of each baffle surface 116 being at an oblique angle 118 with respect to the flow axis 104; and the cross-flow classifier 3100, comprising: the separator conduit 3102; the flow input 3104 and the flow output 3106 in fluidic communication with the separator conduit 3102, the separator conduit 3102 extending between the flow input 3104 and the flow output 3106 to define the flow axis 3108 along at least a portion of the separator conduit 3102, the flow input 3104 being located upstream of the flow output 3106 with respect to the flow axis 3108; and the cross-flow input 3114 and the cross-flow output 3116 in fluidic communication with the separator conduit 3102 between the flow input 3104 and the flow output 3106, the cross-flow input 3114 being located upstream of the cross-flow output 3116 with respect to the flow axis 3108, the cross-flow input 3114 defining the cross-flow axis 3118 intersecting the flow axis 3108 at a cross-flow angle 3120 between about 70° and about 180° with respect to the flow axis 3108, wherein: the outlet 108 of the falling bed reactor 100 is operatively coupled to the flow input 3104 of the cross-flow classifier 3100; and the flow output 3106 of the cross-flow classifier 3100 is operatively coupled to the inlet 108 of the falling bed reactor 100.
41. The pyrolysis system 200 of claim 39, the outlet 108 of the falling bed reactor 100 being operatively coupled to the flow input 3104 of the cross-flow classifier 3100 via an auger or conveyor 230.
42. The pyrolysis system 200 of claim 39, the flow output 3106 of the cross-flow classifier 3100 being operatively coupled to the inlet 108 of the falling bed reactor 100 via an auger or conveyor 232.
43. The pyrolysis system 200 of claim 39, further comprising a fine particulate separator 202, an input 204 of the fine particulate separator 202 operatively coupled to the pyrolysis product outlet 112 of the falling bed reactor 100 and the fine particulate separator 202 comprising a particulate outlet 206 and a gas or vapor outlet 208.
44. The pyrolysis system 200 of claim 43, the fine particulate separator 202 comprising one or more of: a settling chamber, a baffle chamber, a cyclonic particle separator, an electrostatic precipitator, a filter, or a scrubber.
45. The pyrolysis system 200 of claim 39, further comprising a coarse particulate separator 212, an input 214 of the coarse particulate separator 212 operatively coupled to the cross-flow output 3116 of the cross-flow classifier 3100 and the coarse particulate separator 212 comprising a particulate outlet 216 and a gas outlet 218.
46. The pyrolysis system 200 of claim 45, the coarse particulate separator 212 comprising one or more of: a settling chamber, a baffle chamber, a cyclonic particle separator, an electrostatic precipitator, a filter, or a scrubber.
47. The pyrolysis system 200 of claim 39, further comprising a gas recycle conduit 220, the gas recycle conduit operatively coupled to receive recycled gas from the gas outlet 218 and the gas recycle conduit 220 operatively coupled to direct the recycled gas to the cross- flow input 3114 of the cross-flow classifier 3100.
48. The pyrolysis system 200 of claim 47, the gas recycle conduit comprising a fan 222, the fan 222 configured to draw the recycled gas from the gas outlet 218 via the gas recycle conduit 220 and the fan 222 configured to flow the recycled gas to the cross-flow input 3114 of the cross-flow classifier 3100 via the gas recycle conduit 220.
49. The pyrolysis system 200 of claim 39, the falling bed reactor 100 comprising the falling bed reactor of any of claims 1-38.
50. The pyrolysis system 200 of claim 39, one or both of the flow input 3114 and the flow output 3116 being substantially aligned with the flow axis 3108 of the separator conduit 3102.
51. The pyrolysis system 200 of claim 39, the cross-flow input 3114 being operatively coupled to the separator conduit 3102 substantially opposite to the cross-flow output 3116 with respect to the flow axis 3108.
52. The pyrolysis system 200 of claim 39, being mounted such that the flow axis 3108 points downward at a flow angle 3110.
53. The pyrolysis system 200 of claim 52, the flow angle 3110 being less than 60° from vertically down.
54. The pyrolysis system 200 of claim 39, the separator conduit 3102 comprising a first flow diameter 3122 between the flow input 3104 and the cross-flow input 3114, and the separator conduit 3102 comprising a second flow diameter 3124 downstream of the cross- flow input 3114, the first flow diameter 3122 being greater than the second flow diameter 3124.
55. The pyrolysis system 200 of claim 54, the separator conduit 3102 comprising a transition 3126 between the first flow diameter 3122 and the second flow diameter 3124, the transition 3126 being substantially aligned with the cross-flow angle 3120.
56. The pyrolysis system 200 of claim 54, the separator conduit 3102 comprising a transition 3126 between the first flow diameter 3122 and the second flow diameter 3124, the transition 3126 being substantially perpendicular with respect to the flow axis 3108.
57. The pyrolysis system 200 of claim 39, the flow input 3104 being configured to accept a plurality of particulates, at least a first particulate in the plurality of particulates being characterized by a first average density and at least a second particulate in the plurality of particulates being characterized by a second average density greater than the first average density.
58. The pyrolysis system 200 of claim 57, the flow output 3106 being configured to convey at least a portion of the first particulate characterized by the first density out of the separator conduit 3102.
59. The pyrolysis system 200 of claim 58, the cross-flow output 3116 being configured to convey at least a portion of the second particulate characterized by the second density greater than the first density out of the separator conduit 3102.
60. The pyrolysis system 200 of claim 39, the cross-flow input 3114 defining a first convergent nozzle 3132 comprising a first nozzle throat 3134.
61. The pyrolysis system 200 of claim 60, a cross section of the first nozzle throat 3134 comprising at least two dissimilar axes.
62. The pyrolysis system 200 of claim 61, the first nozzle throat 3134 comprising an elliptical cross section, a circular cross section, a rectangular cross section, or a rounded corner rectangular cross section.
63. The pyrolysis system 200 of claim 60, the first nozzle throat 3134 being operatively coupled to a nozzle exit zone, at least a portion of the nozzle exit zone comprising a transition 3126 between a first flow diameter 3122 of the flow conduit 3108 and the first nozzle throat 3134.
64. The pyrolysis system 200 of claim 63, at least a portion of the nozzle exit zone comprising a second flow diameter 3124 of the separator conduit 3108, the transition 3126 being located at an upstream side of the first nozzle throat 3134 and the second flow diameter 3124 being located at a downstream side of the first nozzle throat 3134.
65. The pyrolysis system 200 of claim 64, the first nozzle throat 3134 being located at the second flow diameter 3124 of the separator conduit 3108.
66. The pyrolysis system 200 of claim 60, the convergent nozzle 3132 of the cross-flow input 3114 comprising a second nozzle throat 3138, the first nozzle throat 3134 being located at the cross-flow input 3114 between the second nozzle throat 3138 and the separator conduit 3108.
67. The pyrolysis system 200 of claim 39, the cross-flow output 3116 defining a second convergent nozzle 3142 comprising a third nozzle throat 3144.
68. The pyrolysis system 200 of claim 67, a cross section of the third nozzle throat 3144 comprising at least two dissimilar axes.
69. The pyrolysis system 200 of claim 68, the third nozzle throat 3144 comprising an elliptical cross section, a circular cross section, a rectangular cross section, or a rounded corner rectangular cross section.
70. The pyrolysis system 200 of claim 68, the third nozzle throat 3144 being operatively coupled to a nozzle entrance zone 3146, at least a portion of the nozzle entrance zone 3146 comprising a transition 3148 between a second flow diameter 3124 of the flow conduit 3108 and the third nozzle throat 3144.
71. The pyrolysis system 200 of claim 68, at least a portion of the nozzle entrance zone 3146 comprising an entrance vane 3150, the entrance vane 3150 extending into the separator conduit 3102 with respect to the second flow diameter 3124.
72. The pyrolysis system 200 of claim 71, at least a portion of the entrance vane 3150 extending into the separator conduit 3102 at least partly in an upstream direction with respect to the flow axis 3108.
73. The pyrolysis system 200 of claim 68, the third nozzle throat 3144 being operatively coupled through a nozzle collector zone to an exit conduit 3154, one or both of the nozzle collector zone and the conduit 3154 comprising an elliptical cross section.
74. The pyrolysis system 200 of claim 68, the third nozzle throat 3144 being operatively coupled through a nozzle collector zone to an exit conduit 3154, one or both of the nozzle collector zone and the exit conduit 3154 comprising a circular cross section.
75. The pyrolysis system 200 of claim 68, the third nozzle throat 3144 being operatively coupled to an exit conduit 3154, the exit conduit 3154 defining an exit conduit axis 3156, the exit conduit axis 3156 intersecting the flow axis 3108 at an exit angle 3158, the exit angle 3158 being greater than 0° and less than 180°.
76. The pyrolysis system 200 of claim 75, the exit angle 3158 being between about 90° and less than 180°.
77. The pyrolysis system 200 of claim 76, the exit conduit axis 3156 being within about 30° of vertical.
78. A method 400 for pyrolyzing a substrate, comprising: 402 feeding a heat carrier to a gravity-fed baffled conduit; 404 feeding a pyrolysis substrate to the gravity-fed baffled conduit such that the heat carrier and the pyrolysis substrate mix to form a pyrolysis mixture; and
406 heating the heat carrier and/or the gravity-fed baffled conduit to pyrolyze the pyrolysis substrate in the pyrolysis mixture to form a pyrolysis product mixture.
79. The method of claim 78, the pyrolysis product mixture comprising a gas or vapor pyrolysis product and a fine char pyrolysis product, further comprising directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit.
80. The method of claim 79, the pyrolysis product mixture comprising the heat carrier and a coarse char pyrolysis product, further comprising directing the heat carrier and the coarse char pyrolysis product out of the gravity-fed baffled conduit.
81. The method of claim 80, further comprising directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit at the same level as the heat carrier and the coarse char pyrolysis product.
82. The method of claim 81, further comprising directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit upstream compared to the heat carrier and the coarse char pyrolysis product.
83. The method of claim 81, further comprising directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit downstream compared to the heat carrier and the coarse char pyrolysis product.
84. The method of claim 78, the pyrolysis product mixture comprising the heat carrier and a coarse char pyrolysis product, further comprising directing the heat carrier and the coarse char pyrolysis product out of the gravity-fed baffled conduit.
85. The method of claim 78, feeding the heat carrier to the gravity-fed baffled conduit comprises feeding the heat carrier and the pyrolysis substrate to the same level in the gravity- fed baffled conduit.
86. The method of claim 78, feeding the heat carrier to the gravity-fed baffled conduit comprises feeding the heat carrier to the gravity-fed baffled conduit upstream of the pyrolysis substrate.
87. The method of claim 78, feeding the heat carrier to the gravity-fed baffled conduit comprises feeding the heat carrier to the gravity-fed baffled conduit downstream of the pyrolysis substrate.
88. The method of claim 78, the pyrolysis product mixture comprising a gas or vapor pyrolysis product and a fine char pyrolysis product, the method further comprising: directing the gas or vapor pyrolysis product and the fine char pyrolysis product out of the gravity-fed baffled conduit; and separating the gas or vapor pyrolysis product from the fine char pyrolysis product
89. The method of claim 78, the pyrolysis product mixture comprising the heat carrier and a coarse char pyrolysis product, the method further comprising: directing the heat carrier and the coarse char pyrolysis product out of the gravity-fed baffled conduit; and separating the heat carrier from the coarse char pyrolysis product.
90. The method of claim 78, further comprising: recycling the heat carrier to form a recycled heat carrier; and feeding the recycled heat carrier to the gravity-fed baffled conduit.
91. The method of claim 78, wherein separating the heat carrier from the coarse char pyro lysis product comprises: directing a flow comprising a plurality of particulates along a flow axis; and separating at least a portion of a first particulate from the plurality of particulates to form a separated portion of the first particulate by directing a gas jet along a cross-flow axis, the cross-flow axis intersecting the flow axis at a cross-flow angle, the cross-flow angle being between about 70° and about 180°, wherein: the plurality of particulates comprises the heat carrier and the coarse char pyro lysis product; and the first particulate comprises the coarse char pyrolysis product
92. The method of claim 91, the cross-flow angle being between about 80° and about 100°.
93. The method of claim 91 , the cross-flow axis and the flow axis being substantially perpendicular.
94. The method of claim 91, the gas jet comprising a gas temperature of between about 300 °C and about 700 °C.
95. The method of claim 91, the gas jet comprising a gas density in kilograms per cubic meter of between about 0.4 and about 1.4.
96. The method of claim 91, the gas jet comprising a gas viscosity in kilograms per meter-second of between about lxlO"6 and about lxlO"4.
97. The method of claim 91, the gas jet comprising a gas flow rate of less than 25 cubic feet per minute.
98. The method of claim 91, the gas jet comprising a gas pressure drop of less than 5 inches of water.
99. The method of claim 91, wherein separating at least the portion of the first particulate from the plurality of particulates to form the separated portion of the first particulate further comprises: directing the separated portion of the first particulate away from the cross-flow axis to a surface of a separator conduit; and directing the separated portion of the first particulate along the surface for a distance.
100. The method of claim 99, wherein directing the separated portion of the first particulate along the surface comprises directing the separated portion of the first particulate substantially parallel to the flow axis.
101. The method of claim 99, wherein directing the separated portion of the first particulate along the surface comprises using the Coanda effect.
102. The method of claim 91, further comprising diverting the separated portion of the first particulate along the surface away from the surface to a cross-flow output.
103. The method of claim 102, wherein diverting the separated portion of the first particulate along the surface away from the surface and through the cross-flow output comprises using the Coanda effect.
104. The method of claim 102, wherein diverting the separated portion of the first particulate along the surface away from the surface and through the cross-flow output comprises contacting the separated portion of the first particulate along the surface with an entrance vane, the entrance vane being in fluidic communication with the cross-flow output.
105. The method of claim 91, wherein separating at least the portion of the first particulate from the plurality of particulates comprises substantially separating the first particulate from the plurality of particulates.
106. The method of claim 91, wherein separating at least the portion of the first particulate from the plurality of particulates comprises separating at least about 99% by weight of the first particulate from the plurality of particulates.
107. The method of claim 91, the first particulate comprising a pyrolysis product.
108. The method of claim 91, the first particulate comprising one or more of a biomass or a biomass pyrolysis product.
109. The method of claim 91, the first particulate comprising char.
110. The method of claim 91, the first particulate being characterized by a first average density in kilograms per cubic meter of between about 100 and about 2,000.
11 1. The method of claim 91, the first particulate being characterized by a first average diameter in millimeters of between about 0.1 and about 10.
112. The method of claim 91, the first particulate comprising an average flow rate in kilograms per second of between about 0.0012 and about 0.0023.
113. The method of claim 91 , the first particulate being characterized by a first average density and the plurality of particulates comprising at least a second particulate characterized by a second average density greater than the first average density.
114. The method of claim 1 13, the second particulate comprising one or more of a metal, a glass, a ceramic, a mineral, or a polymeric composite.
115. The method of claim 1 13, the second particulate comprising one or more of: steel, stainless steel, cobalt (Co), molybdenum (Mo ), nickel (Ni), titanium (Ti), tungsten (W), zinc (Zn), antimony (Sb), bismuth (Bi), cerium (Ce), vanadium (V), niobium (Nb), tantalum (Ta), chromium (Cr), manganese (Mn), rhenium (Re), iron (Fe), platinum (Pt), iridium (Ir), palladium (Pd), osmium (Os), rhodium (Rh), ruthenium (Ru), nickel, copper impregnated zinc oxide (Cu/ZnO), copper impregnated chromium oxide (Cu/Cr), nickel aluminum oxide (Ni/A1203), palladium aluminum oxide (PdA1203), cobalt molybdenum (CoMo), nickel molybdenum (NiMo), nickel molybdenum tungsten (NiMoW), sulfided cobalt molybdenum (CoMo), sulfided nickel molybdenum (NiMo ), or a metal carbide.
116. The method of claim 113, the second average density of the second particulate in kilograms per cubic meter being between about 3,000 and about 23,000.
117. The method of claim 113, the second average density of the second particulate divided by the first average density of the first particulate being a ratio between about 1.5: 1 and about 230: 1.
118. The method of claim 1 13, the second particulate being characterized by a first average diameter in millimeters of between about 1 and about 10.
119. The method of claim 1 13, the second particulate comprising a spherical, rounded or ellipsoid morphology
120. The method of claim 1 13, the second particulate comprising a flow rate in kilograms per second of about 0.4 to about 1.4 per each ton per day of biomass processed.
121. The method of claim 1 13, the first particulate having a first terminal velocity and the second particulate having a second terminal velocity, the first and second particulates being characterized by a ratio of second terminal velocity to first terminal velocity of at least about 5: 1.
122. The method of claim 1 13, the first particulate having a first terminal velocity and the second particulate having a second terminal velocity, the first and second particulates being characterized by a ratio of second terminal velocity to first terminal velocity of at least about 10: 1.
123. The method of claim 1 13, the first particulate having a first terminal velocity and the second particulate having a second terminal velocity, the first and second particulates being characterized by a ratio of second terminal velocity to first terminal velocity of at least about 20: 1.
124. The method of claim 91, further comprising separating at least a portion of a second particulate in the plurality of particulates from the first particulate.
125. The method of claim 91, further comprising separating substantially all of a second particulate in the plurality of particulates from the first particulate.
126. The method of claim 91, further comprising separating at least a portion of a second particulate in the plurality of particulates from the first particulate in a direction substantially aligned with the flow axis.
127. The method of claim 91, further comprising directing the flow axis downward at a flow angle.
128. The method of claim 127, the flow angle being less than 90° from vertically downward.
129. The method of claim 127, the flow angle being less than 60° from vertically downward.
130. The method of claim 91, further comprising forming the gas jet by flowing a gas through a first convergent nozzle comprising a first nozzle throat.
131. The method of claim 91, a cross section of the first nozzle throat comprising at least two dissimilar axes.
132. The method of claim 91, the first nozzle throat comprising an elliptical cross section, a circular cross section, a rectangular cross section, or a rounded corner rectangular cross section.
133. The method of claim 91, further comprising: adapting the flow upstream of the gas jet to a first flow diameter; and
adapting the flow downstream of the gas jet to a second flow diameter,
the first flow diameter being greater than the second flow diameter.
134. The method of claim 133, further comprising adapting the flow between the first flow diameter and the second flow diameter using a transition between the first flow diameter and the second flow diameter, the transition being substantially aligned with the cross-flow angle.
135. The method of claim 134, further comprising adapting the flow using a transition between the first flow diameter and the second flow diameter, the transition being substantially perpendicular with respect to the flow axis.
136. The method of claim 134, further comprising adapting the flow using a transition between the first flow diameter and the second flow diameter, the transition extending between at least a portion of the first flow diameter and at least a portion of the first nozzle throat.
137. The method of claim 134, at least a portion of the second flow diameter coinciding with at least a portion of the first nozzle throat.
138. The method of claim 137, the first nozzle throat being located at the second flow diameter of the separator conduit.
139. The method of claim 134, forming the gas jet further comprises flowing the gas through a second nozzle throat upstream of the first nozzle throat.
140. The method of claim 134, separating at least the portion of the first particulate from the plurality of particulates further comprises extending an entrance vane into a portion of the flow defined by the second flow diameter.
141. The method of claim 140, further comprising extending at least a portion of the entrance vane into the flow at least partly in an upstream direction with respect to the flow axis.
142. The method of claim 91, wherein separating at least the portion of the first particulate from the plurality of particulates comprises directing the separated portion of the first particulate away from the flow axis substantially opposite to the gas jet along the cross-flow axis with respect to the flow axis.
143. The method of claim 91, wherein separating at least the portion of the first particulate from the plurality of particulates comprises directing the separated portion of the first particulate away from the flow axis substantially opposite to the gas jet along the cross-flow axis with respect to the flow axis.
144. The method of claim 91, wherein separating at least the portion of the first particulate from the plurality of particulates further comprises directing a separated portion of the first particulate away from the flow axis through a third nozzle throat.
145. The method of claim 144, a cross section of the third nozzle throat comprising at least two dissimilar axes.
146. The method of claim 144, the third nozzle throat comprising an elliptical cross section, a circular cross section, a rectangular cross section, or a rounded corner rectangular cross section.
147. The method of claim 144, wherein separating at least the portion of the first particulate from the plurality of particulates further comprises directing the separated portion of the first particulate away from the third nozzle throat through an elliptical cross section.
148. The method of claim 144, wherein separating at least the portion of the first particulate from the plurality of particulates further comprises directing the separated portion of the first particulate away from the third nozzle throat through a circular cross section.
149. The method of claim 144, wherein separating at least the portion of the first particulate from the plurality of particulates further comprises directing the separated portion of the first particulate away from the third nozzle throat via an exit conduit axis, the exit conduit axis intersecting the flow axis at an exit angle, the exit angle being greater than 0° and less than 180°.
PCT/US2014/039443 2013-05-23 2014-05-23 Falling bed reactor WO2014190321A1 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015179794A1 (en) * 2014-05-23 2015-11-26 Battelle Memorial Institute Dual bed pyrolysis system and method
WO2015179798A1 (en) * 2014-05-23 2015-11-26 Battelle Memorial Institute Downflow reactor systems for pyrolysis
WO2016141367A3 (en) * 2015-03-05 2016-11-03 Battelle Memorial Institute Pre-processing bio-oil before hydrotreatment
CN107619674A (en) * 2017-10-27 2018-01-23 煤炭科学技术研究院有限公司 The Z-path moving bed pyrolysis fluidized gasification coupling device and method of solid fuel

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108384560B (en) * 2018-03-09 2020-10-02 同济大学 Large-scale biomass and waste pyrolysis furnace
CN108587658A (en) * 2018-04-28 2018-09-28 常州大学 a kind of biomass pyrolysis device
US11545343B2 (en) 2019-04-22 2023-01-03 Board Of Trustees Of Michigan State University Rotary plasma reactor
CN113122295A (en) * 2021-04-19 2021-07-16 山东理工大学 Self-heating type solid heat carrier circulation downcomer combined pyrolysis device
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4619738A (en) * 1983-09-21 1986-10-28 The United States Of America As Represented By The United States Department Of Energy Apparatus for oil shale retorting
US4948495A (en) * 1988-07-26 1990-08-14 The United States Of America As Represented By The United States Department Of Energy High liquid yield process for retorting various organic materials including oil shale
JP2000042494A (en) * 1998-07-31 2000-02-15 Ricoh Co Ltd Air-current classification
US20060144304A1 (en) * 2003-03-07 2006-07-06 Prigmore Robert M Gasification apparatus and method
US7335847B2 (en) * 2004-04-27 2008-02-26 Hauni Primary Gmbh Method and apparatus for foreign-body separation from a material flow
US20110206571A1 (en) * 2010-01-25 2011-08-25 Kenneth Micheal Skinner Cascading planar baffle reactor

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4619738A (en) * 1983-09-21 1986-10-28 The United States Of America As Represented By The United States Department Of Energy Apparatus for oil shale retorting
US4948495A (en) * 1988-07-26 1990-08-14 The United States Of America As Represented By The United States Department Of Energy High liquid yield process for retorting various organic materials including oil shale
JP2000042494A (en) * 1998-07-31 2000-02-15 Ricoh Co Ltd Air-current classification
US20060144304A1 (en) * 2003-03-07 2006-07-06 Prigmore Robert M Gasification apparatus and method
US7335847B2 (en) * 2004-04-27 2008-02-26 Hauni Primary Gmbh Method and apparatus for foreign-body separation from a material flow
US20110206571A1 (en) * 2010-01-25 2011-08-25 Kenneth Micheal Skinner Cascading planar baffle reactor

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
BRYAN A. GARNER: "A Dictionary of Modern Legal Usage", 1995, pages: 624

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015179794A1 (en) * 2014-05-23 2015-11-26 Battelle Memorial Institute Dual bed pyrolysis system and method
WO2015179798A1 (en) * 2014-05-23 2015-11-26 Battelle Memorial Institute Downflow reactor systems for pyrolysis
WO2016141367A3 (en) * 2015-03-05 2016-11-03 Battelle Memorial Institute Pre-processing bio-oil before hydrotreatment
CN107619674A (en) * 2017-10-27 2018-01-23 煤炭科学技术研究院有限公司 The Z-path moving bed pyrolysis fluidized gasification coupling device and method of solid fuel

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US20160090535A1 (en) 2016-03-31
WO2014190321A9 (en) 2015-10-15

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