WO2014189939A3 - Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides - Google Patents

Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides Download PDF

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Publication number
WO2014189939A3
WO2014189939A3 PCT/US2014/038799 US2014038799W WO2014189939A3 WO 2014189939 A3 WO2014189939 A3 WO 2014189939A3 US 2014038799 W US2014038799 W US 2014038799W WO 2014189939 A3 WO2014189939 A3 WO 2014189939A3
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WO
WIPO (PCT)
Prior art keywords
monomer
block
chain transfer
reversible addition
transfer polymerization
Prior art date
Application number
PCT/US2014/038799
Other languages
French (fr)
Other versions
WO2014189939A2 (en
Inventor
Eric W. COCHRAN
Ronald Christopher Williams
Nacu HERNANDEZ
Andrew Cascione
Original Assignee
Iowa State University Research Foundation, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to KR1020157034372A priority Critical patent/KR20160009583A/en
Priority to BR122017010545-0A priority patent/BR122017010545B1/en
Priority to SG11201509408UA priority patent/SG11201509408UA/en
Priority to EP14732720.9A priority patent/EP2999727B1/en
Application filed by Iowa State University Research Foundation, Inc. filed Critical Iowa State University Research Foundation, Inc.
Priority to JP2016515021A priority patent/JP2016528306A/en
Priority to AU2014268692A priority patent/AU2014268692B2/en
Priority to CA2910680A priority patent/CA2910680A1/en
Priority to EP19208355.8A priority patent/EP3632942A1/en
Priority to BR112015028368-3A priority patent/BR112015028368B1/en
Priority to CN201480029039.4A priority patent/CN105229045B/en
Priority to EA201592176A priority patent/EA201592176A1/en
Publication of WO2014189939A2 publication Critical patent/WO2014189939A2/en
Publication of WO2014189939A3 publication Critical patent/WO2014189939A3/en
Priority to PH12015502467A priority patent/PH12015502467A1/en
Priority to HK16108276.0A priority patent/HK1220219A1/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F122/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F122/10—Esters
    • C08F122/12—Esters of phenols or saturated alcohols
    • C08F122/20—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F242/00—Copolymers of drying oils with other monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L35/06—Copolymers with vinyl aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J135/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J135/06—Copolymers with vinyl aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/103—Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2555/00—Characteristics of bituminous mixtures
    • C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
    • C08L2555/80—Macromolecular constituents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2555/00—Characteristics of bituminous mixtures
    • C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
    • C08L2555/80—Macromolecular constituents
    • C08L2555/82—Macromolecular constituents from natural renewable resources, e.g. starch, cellulose, saw dust, straw, hair or shells

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

Abstract

The present invention relates to a thermoplastic block copolymer comprising at least one PA block and at least one PB block. The PA block represents a polymer block comprising one or more units of monomer A, and the PB block represents a polymer block comprising one or more units of monomer B, Monomer A is a vinyl, acrylic, diolefm, niirile, dinitrile, acrylonitrile monomer, a monomer with reactive functionality, or a crosslinking monomer. Monomer B is a radically polymerizable triglyceride or mixtures thereof, typically in the form of a plant or animal oil. The present invention aiso relates to a method of preparing a thermoplastic block copolymer or novel thermoplastic statistical copolymers by polymerizing a radically polymerizable monomer with a radically polymerizable triglyceride or mixtures thereof via reversible addition-fragmentation chain-transfer polymerization (RAFT), in the presence of an free radical initiator and a chain transfer agent.
PCT/US2014/038799 2013-05-20 2014-05-20 Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides WO2014189939A2 (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
AU2014268692A AU2014268692B2 (en) 2013-05-20 2014-05-20 Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides
SG11201509408UA SG11201509408UA (en) 2013-05-20 2014-05-20 Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides
EP14732720.9A EP2999727B1 (en) 2013-05-20 2014-05-20 Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides
EP19208355.8A EP3632942A1 (en) 2013-05-20 2014-05-20 Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides
JP2016515021A JP2016528306A (en) 2013-05-20 2014-05-20 Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides
BR122017010545-0A BR122017010545B1 (en) 2013-05-20 2014-05-20 statistical thermoplastic copolymer, its preparation method, its compositions and vehicle tire
CA2910680A CA2910680A1 (en) 2013-05-20 2014-05-20 Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides
KR1020157034372A KR20160009583A (en) 2013-05-20 2014-05-20 Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides
BR112015028368-3A BR112015028368B1 (en) 2013-05-20 2014-05-20 THERMOPLASTIC ELASTOMERS THROUGH POLYMERIZATION OF TRIGLYCERIDES BY REVERSIBLE FRAGMENTATION-ADDITION CHAIN TRANSFER
CN201480029039.4A CN105229045B (en) 2013-05-20 2014-05-20 The thermoplastic elastomer (TPE) polymerizeing via the reversible addion-fragmentation chain transfer of triglycerides
EA201592176A EA201592176A1 (en) 2013-05-20 2014-05-20 THERMOELASTOPLASTES, OBTAINED BY POLYMERIZATION OF TRIGLYCERIDES WITH REVERSIBLE TRANSFER OF CHAIN UNDER MECHANISM OF CONNECTION-FRAGMENTATION
PH12015502467A PH12015502467A1 (en) 2013-05-20 2015-10-26 Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides
HK16108276.0A HK1220219A1 (en) 2013-05-20 2016-07-14 Thermoplastic elastomers via reversible addition fragmentation chain transfer polymerization of triglycerides

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361825241P 2013-05-20 2013-05-20
US61/825,241 2013-05-20

Publications (2)

Publication Number Publication Date
WO2014189939A2 WO2014189939A2 (en) 2014-11-27
WO2014189939A3 true WO2014189939A3 (en) 2015-02-19

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PCT/US2014/038799 WO2014189939A2 (en) 2013-05-20 2014-05-20 Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides

Country Status (14)

Country Link
US (5) US9650463B2 (en)
EP (3) EP3327047A1 (en)
JP (1) JP2016528306A (en)
KR (1) KR20160009583A (en)
CN (3) CN108641054A (en)
AU (1) AU2014268692B2 (en)
BR (2) BR122017010545B1 (en)
CA (1) CA2910680A1 (en)
CL (1) CL2015003375A1 (en)
EA (1) EA201592176A1 (en)
HK (1) HK1220219A1 (en)
PH (1) PH12015502467A1 (en)
SG (3) SG10201606742UA (en)
WO (1) WO2014189939A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108503276A (en) * 2018-04-20 2018-09-07 万玉梅 A kind of function pavement conserving material and preparation method thereof

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2804882B1 (en) 2012-01-18 2021-12-22 Iowa State University Research Foundation, Inc. Thermoplastic elastomers via atom transfer radical polymerization of plant oil
CN108641054A (en) 2013-05-20 2018-10-12 爱荷华州立大学研究基金会有限公司 The thermoplastic elastomer (TPE) polymerizeing via the reversible addion-fragmentation chain transfer of triglycerides
US20180044528A1 (en) 2015-02-27 2018-02-15 Cargill, Incorporated Emulsions with polymerized oils & methods of manufacturing the same
DE102015208810A1 (en) 2015-05-12 2016-11-17 Continental Reifen Deutschland Gmbh RAFT agent, process for the polymerization, polymer and rubber mixture and their use
CN107922308A (en) * 2015-06-02 2018-04-17 日东药品工业株式会社 Three ester of glycerin and application thereof
US10323147B1 (en) 2016-05-26 2019-06-18 Marathon Petroleum Company Lp Asphalt composition containing ester bottoms
WO2018009753A1 (en) 2016-07-07 2018-01-11 Iowa State University Research Foundaton, Inc. Multiblock copolymer and method of making thereof
CN106433158B (en) * 2016-07-07 2018-12-04 交通运输部科学研究院 The preparation method of modification biological pitch and modification biological pitch and application thereof
WO2018009830A1 (en) 2016-07-07 2018-01-11 Iowa State University Research Foundation, Inc. Thiocarbonylthio compounds as chain transfer agents suitable for raft polymerization
WO2018031373A1 (en) 2016-08-12 2018-02-15 Iowa State University Research Foundation, Inc. Acrylated and acylated or acetalized polyol as a biobased substitute for hard, rigid thermoplastic and thermoplastic and thermoset materials
FR3058729A1 (en) * 2016-11-17 2018-05-18 Compagnie Generale Des Etablissements Michelin PNEUMATIC COMPRISING A TREAD COMPRISING A THERMOPLASTIC ELASTOMER AND A SULFUR-BASED SULFURING SYSTEM
FR3060588A1 (en) * 2016-12-20 2018-06-22 Compagnie Generale Des Etablissements Michelin RUBBER COMPOSITION COMPRISING A SPECIFIC RUBBER POWDER
WO2018183261A1 (en) * 2017-03-27 2018-10-04 Iowa State University Research Foundation, Inc. Macro-raft chain transfer agents as anionic polymerization terminators
US10316192B2 (en) 2017-08-25 2019-06-11 Cargill, Incorporated Emulsions with polymerized oils and methods of manufacturing the same
CN108084071B (en) * 2017-12-29 2019-11-22 云南铁峰矿业化工新技术有限公司 A kind of xanthate vacuum preparation facilities
EP3807252A4 (en) 2018-06-18 2022-03-02 Cornell University Systems and methods for n-halamine-dopamine copolymers for high-performance, low-cost, and easy-to-apply antimicrobial coatings
CN109679001A (en) * 2018-12-29 2019-04-26 锦州英诺威科技服务有限公司 It is a kind of to kill agent living for polypropylene production
US11814506B2 (en) 2019-07-02 2023-11-14 Marathon Petroleum Company Lp Modified asphalts with enhanced rheological properties and associated methods
CN112175555A (en) * 2020-09-29 2021-01-05 杭州英创新材料有限公司 Polar hot melt adhesive and preparation method thereof
WO2022212874A1 (en) * 2021-04-02 2022-10-06 Iowa State University Research Foundation, Inc. Thermoplastic graft elastomers via reactive compatibilization of polyacrylated epoxidized high oleic soybean oil and polydiene-containing copolymers
US20240199871A1 (en) * 2021-04-02 2024-06-20 Iowa State University Research Foundation, Inc. Impact modification of polyesters via reactive extrusion with polyacrylated epoxidized high oleic soybean oil
CN113214575B (en) * 2021-04-24 2022-03-25 温州市剑利鞋业有限公司 PVC sole and preparation process thereof
CN114605653B (en) * 2022-04-19 2023-07-04 东南大学 Preparation method and application of biological thermoplastic elastomer capable of replacing SBS
CN115160467B (en) * 2022-06-22 2023-10-03 东南大学 Preparation method and application of novel bio-based liquid modifier
CN115738133B (en) * 2022-11-10 2023-09-29 国网浙江省电力有限公司湖州供电公司 Be applied to electrochemical energy storage system's automatic fire extinguishing apparatus
CN116144165B (en) * 2022-12-27 2024-04-02 四川大学 Recoverable and repairable thermosetting polyurethane modified asphalt material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999021900A1 (en) * 1997-10-27 1999-05-06 Cara Plastics Inc. High modulus polymers and composites from plant oils
WO2001059008A1 (en) * 2000-02-08 2001-08-16 Waste Technology Transfer, Inc. Petroleum asphalts modified by liquefied biomass additives
US20120316309A1 (en) * 2009-11-12 2012-12-13 Ndsu Research Foundation Polymers Derived From Plant Oil
WO2013109878A1 (en) * 2012-01-18 2013-07-25 Iowa State University Research Foundation, Inc. Thermoplastic elastomers via atom transfer radical polymerization of plant oil

Family Cites Families (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2192090A (en) 1934-06-14 1940-02-27 Nolde & Horst Co Knitted fabric
US2190906A (en) * 1939-01-05 1940-02-20 Dow Chemical Co Styrene-tung oil copolymer
US3499857A (en) * 1967-04-17 1970-03-10 Cataphote Corp Thermoplastic resinous compositions,particularly using unsaturated triglycerides
JPS6049668B2 (en) * 1981-04-06 1985-11-02 大日本塗料株式会社 paint composition
JP2592622B2 (en) * 1987-11-12 1997-03-19 伊藤製油株式会社 Polyurethane manufacturing method
US6197905B1 (en) 1989-06-05 2001-03-06 Commonwealth Scientific & Industrial Resarch Organization Process for producing polymers or oligomers of controlled molecular weight and end group functionalities
US5932675A (en) 1989-06-05 1999-08-03 Commonwealth Scientific And Industrial Research Organisation Free-radical chain transfer polymerization process
FR2670497B1 (en) 1990-12-18 1994-05-13 Elf France BITUMEN / POLYMER COMPONENT FOR USE IN FORMING BITUMEN / POLYMER COMPOSITIONS WITH VERY LOW THERMAL SUSCEPTIBILITY APPLICABLE TO THE PRODUCTION OF COATINGS.
DE69225591T2 (en) 1991-02-06 1999-01-07 The Commonwealth Scientific And Industrial Research Organization, Campbell POLYMERIZATION CONTROL
GB9306517D0 (en) 1993-03-29 1993-05-19 Polyphalt Inc Stabilized bitumen compositions
US5763548A (en) 1995-03-31 1998-06-09 Carnegie-Mellon University (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
AUPN585595A0 (en) 1995-10-06 1995-11-02 Commonwealth Scientific And Industrial Research Organisation Control of molecular weight and end-group functionality in polymers
US5807937A (en) 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
ES2108646B1 (en) 1995-11-30 1998-07-01 Telefonica Nacional Espana Co STRUCTURE FOR AN ELECTRONIC INFORMATION SYSTEM.
CN1185797A (en) * 1996-03-26 1998-06-24 大赛璐化学工业株式会社 Styrene resin composition and molding thereof
KR100479628B1 (en) 1996-07-10 2005-04-06 이.아이,듀우판드네모아앤드캄파니 Polymerization with Living Characteristics
JP2001506423A (en) 1997-07-11 2001-05-15 ベーセー コンポネンツ ホールディングス ベー ヴェー High voltage resistance and high voltage power supply having such high voltage resistance
AU770550B2 (en) 1997-07-21 2004-02-26 Commonwealth Scientific And Industrial Research Organisation Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
NZ505654A (en) 1997-12-18 2002-03-28 John Chiefair Living polymerisation process whereby photo-initiators of polymerisation utilises a thermal process resulting in polymers of controlled molecular weight and low polydispersity
FR2785287B1 (en) * 1998-10-30 2000-12-29 De Chily Pierre Charlier PROCESS FOR THE POLYMERIZATION BY DIELECTRIC HEATING OF UNSATURATED FATTY ACIDS, UNSATURATED FATTY ACID ESTERS, UNSATURATED HYDROCARBONS, OR UNSATURATED DERIVATIVES THEREOF
US20020095007A1 (en) 1998-11-12 2002-07-18 Larock Richard C. Lewis acid-catalyzed polymerization of biological oils and resulting polymeric materials
DE19930770A1 (en) * 1999-07-03 2001-01-04 Cognis Deutschland Gmbh Process for the production of fiber composite materials
US6900261B2 (en) 2001-06-12 2005-05-31 The University Of Delaware Sheet molding compound resins from plant oils
JP2003012719A (en) * 2001-06-27 2003-01-15 Kanegafuchi Chem Ind Co Ltd Vinyl polymer containing alkenyl group and sulfur atom
EP1384729A1 (en) 2002-07-25 2004-01-28 Dutch Polymer Institute Process for the radical coplymerisation of alpha-olefins with vinyl monomers
FR2848556B1 (en) 2002-12-13 2006-06-16 Bio Merieux CONTROLLED RADICAL POLYMERIZATION PROCESS
JP2007522262A (en) 2003-06-26 2007-08-09 シミックス・テクノロジーズ・インコーポレイテッド Photoresist polymer
EP1641849A1 (en) 2003-06-26 2006-04-05 Symyx Technologies, Inc. Photoresist polymers and compositions having acrylic- or methacrylic-based polymeric resin prepared by a living free radical process
IL156870A0 (en) 2003-07-10 2004-02-08 Carmel Olefines Ltd Process for making thermoplastic vulcanizates
US7807755B2 (en) 2004-05-12 2010-10-05 Commonwealth Scientific And Industrial Research Organisation Method for removing sulfur-containing end groups
US7553919B2 (en) 2005-05-06 2009-06-30 Board Of Trustees Of Michigan State University Starch-vegetable oil graft copolymers and their biofiber composites, and a process for their manufacture
JP2009515139A (en) 2005-07-12 2009-04-09 ザ リーズ ティーチング ホスピタルズ エヌエイチエス トラスト Measurement of gastric acid secretion
US8283436B2 (en) 2006-02-23 2012-10-09 Commonwealth Scientific And Industrial Research Organisation Process for synthesizing thiol terminated polymers
FI119431B (en) 2006-03-06 2008-11-14 Upm Kymmene Oyj Natural fatty acid based acrylate hybrid polymer and process for its preparation
ATE431368T1 (en) * 2006-08-17 2009-05-15 Rhodia Operations BLOCK COPOLYMERS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE IN EMULSIONS
US20080153982A1 (en) * 2006-12-20 2008-06-26 John Ta-Yuan Lai Vinyl-Thiocarbonate and Polyol Containing Block Copolymers
US7501479B2 (en) 2007-05-07 2009-03-10 Pittsburg State University Cationic polymerization of biological oils with superacid catalysts
CN101225141B (en) * 2007-12-28 2011-06-01 沈阳工业大学 Preparation of degradable polymer by using soybean oil as raw material
MX2010009223A (en) 2008-02-22 2010-09-28 Alm Holding Company Processing bituminous mixtures for paving at reduced temperatures.
CN101230020B (en) * 2008-02-26 2013-05-22 北京市丰信德科技发展有限公司 Method for synthesizing macromonomer for polymer polyol by plant oil and uses thereof
US7994107B2 (en) 2008-05-06 2011-08-09 Archer-Daniels-Midland Company Lubricant additives
WO2010051346A1 (en) * 2008-10-30 2010-05-06 E. I. Du Pont De Nemours And Company Process for preparing aqueous copolymer dispersions
RU2560722C2 (en) * 2008-12-31 2015-08-20 Бриджстоун Корпорейшн Core-shell nanoparticles, method for synthesis and use thereof
CN102459458B (en) 2009-05-07 2015-05-20 国际壳牌研究有限公司 Binder composition and asphalt mixture
FR2961503B1 (en) 2010-06-16 2012-07-27 Commissariat Energie Atomique USE OF NANOPARTICLES FOR LONG-TERM "DRY" STORAGE OF PEROXIDIC RADICALS.
CN102295718B (en) 2011-05-26 2014-01-01 北京化工大学 Bio-based high-branched polyester and preparation method thereof
WO2013003887A1 (en) * 2011-07-04 2013-01-10 Commonwealth Scientific And Industrial Research Organisation Nucleic acid complex
EP2604661B1 (en) 2011-12-12 2017-01-25 Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. Corrosion inhibiting pigments and methods for preparing the same
CN108641054A (en) 2013-05-20 2018-10-12 爱荷华州立大学研究基金会有限公司 The thermoplastic elastomer (TPE) polymerizeing via the reversible addion-fragmentation chain transfer of triglycerides

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999021900A1 (en) * 1997-10-27 1999-05-06 Cara Plastics Inc. High modulus polymers and composites from plant oils
WO2001059008A1 (en) * 2000-02-08 2001-08-16 Waste Technology Transfer, Inc. Petroleum asphalts modified by liquefied biomass additives
US20120316309A1 (en) * 2009-11-12 2012-12-13 Ndsu Research Foundation Polymers Derived From Plant Oil
WO2013109878A1 (en) * 2012-01-18 2013-07-25 Iowa State University Research Foundation, Inc. Thermoplastic elastomers via atom transfer radical polymerization of plant oil

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
ALEMDAR N ET AL: "Production of oil-based binder by RAFT polymerization technique", PROGRESS IN ORGANIC COATINGS, ELSEVIER BV, NL, vol. 69, no. 4, 1 December 2010 (2010-12-01), pages 522 - 526, XP027457210, ISSN: 0300-9440, [retrieved on 20101013], DOI: 10.1016/J.PORGCOAT.2010.09.009 *
CASCIONE ANDREW A, COCHRAN ERIC W, HERNÁNDEZ NACÚ B, CHRISTOPHER, HERNÁNDEZ: "Development of Bio-Based Polymers for Use in Asphalt Recommended Citation", INTRANS PROJECT REPORTS. PAPER, 1 February 2014 (2014-02-01), Iowa State University Digital Repository @ Iowa State University, Institute for Transportation, XP002728265, Retrieved from the Internet <URL:http://lib.dr.iastate.edu/intrans_reports/29/> [retrieved on 20140806] *
JAMIE DZICZKOWSKI ET AL: "Route to co-acrylic modified alkyd resins via a controlled polymerization technique", PROGRESS IN ORGANIC COATINGS, vol. 73, no. 4, 1 April 2012 (2012-04-01), pages 355 - 365, XP055133698, ISSN: 0300-9440, DOI: 10.1016/j.porgcoat.2011.03.003 *
SAITHAI PIMCHANOK ET AL: "Synthesis and Characterization of Triglyceride-based Copolymer from Soybean Oil", MATERIALS SCIENCE FORUM, TRANS TECH PUBLICATIONS LTD- SWITZERLAND, CH, vol. 695, 1 January 2011 (2011-01-01), pages 320 - 323, XP003031275, ISSN: 0255-5476 *
SHU WANG ET AL: "Sustainable Thermoplastic Elastomers Derived from Fatty Acids", MACROMOLECULES, vol. 46, no. 18, 24 September 2013 (2013-09-24), pages 7202 - 7212, XP055133693, ISSN: 0024-9297, DOI: 10.1021/ma4011846 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108503276A (en) * 2018-04-20 2018-09-07 万玉梅 A kind of function pavement conserving material and preparation method thereof

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