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WO2014188376A1 - Stabilized photoactive composition and use thereof - Google Patents

Stabilized photoactive composition and use thereof

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Publication number
WO2014188376A1
WO2014188376A1 PCT/IB2014/061633 IB2014061633W WO2014188376A1 WO 2014188376 A1 WO2014188376 A1 WO 2014188376A1 IB 2014061633 W IB2014061633 W IB 2014061633W WO 2014188376 A1 WO2014188376 A1 WO 2014188376A1
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WO
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Patent type
Prior art keywords
groups
photoactive
selected
alkyl
composition
Prior art date
Application number
PCT/IB2014/061633
Other languages
English (en)
French (fr)
Inventor
Giorgio Giannotta
Antonio Papagni
COGHI Paolo SAUL
Vincenzo Malatesta
Original Assignee
Eni S.P.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date

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    • HELECTRICITY
    • H01BASIC ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H01L51/00Solid state devices using organic materials as the active part, or using a combination of organic materials with other materials as the active part; Processes or apparatus specially adapted for the manufacture or treatment of such devices, or of parts thereof
    • H01L51/0032Selection of organic semiconducting materials, e.g. organic light sensitive or organic light emitting materials
    • H01L51/0034Organic polymers or oligomers
    • H01L51/0035Organic polymers or oligomers comprising aromatic, heteroaromatic, or arrylic chains, e.g. polyaniline, polyphenylene, polyphenylene vinylene
    • H01L51/0036Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUSE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
    • C08K3/00Use of inorganic ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • C08K3/045Fullerenes
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; MISCELLANEOUS COMPOSITIONS; MISCELLANEOUS APPLICATIONS OF MATERIALS
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/06Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
    • HELECTRICITY
    • H01BASIC ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H01L51/00Solid state devices using organic materials as the active part, or using a combination of organic materials with other materials as the active part; Processes or apparatus specially adapted for the manufacture or treatment of such devices, or of parts thereof
    • H01L51/0032Selection of organic semiconducting materials, e.g. organic light sensitive or organic light emitting materials
    • H01L51/0034Organic polymers or oligomers
    • H01L51/0035Organic polymers or oligomers comprising aromatic, heteroaromatic, or arrylic chains, e.g. polyaniline, polyphenylene, polyphenylene vinylene
    • HELECTRICITY
    • H01BASIC ELECTRIC ELEMENTS
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    • H01L51/00Solid state devices using organic materials as the active part, or using a combination of organic materials with other materials as the active part; Processes or apparatus specially adapted for the manufacture or treatment of such devices, or of parts thereof
    • H01L51/0032Selection of organic semiconducting materials, e.g. organic light sensitive or organic light emitting materials
    • H01L51/0034Organic polymers or oligomers
    • H01L51/0035Organic polymers or oligomers comprising aromatic, heteroaromatic, or arrylic chains, e.g. polyaniline, polyphenylene, polyphenylene vinylene
    • H01L51/0039Polyeflurorene and derivatives
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    • H01L51/0032Selection of organic semiconducting materials, e.g. organic light sensitive or organic light emitting materials
    • H01L51/0034Organic polymers or oligomers
    • H01L51/0043Copolymers
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    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10Definition of the polymer structure
    • C08G2261/12Copolymers
    • C08G2261/124Copolymers alternating
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    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10Definition of the polymer structure
    • C08G2261/18Definition of the polymer structure conjugated
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    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3241Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more nitrogen atoms as the only heteroatom, e.g. carbazole
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    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3243Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more sulfur atoms as the only heteroatom, e.g. benzothiophene
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    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3246Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing nitrogen and sulfur as heteroatoms
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    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
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    • C08G2261/34Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain
    • C08G2261/344Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing heteroatoms
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    • C08G2261/30Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/36Oligomers, i.e. comprising up to 10 repeat units
    • C08G2261/364Oligomers, i.e. comprising up to 10 repeat units containing hetero atoms
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    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/90Applications
    • C08G2261/91Photovoltaic applications
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08K3/00Use of inorganic ingredients
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    • C09K2211/00Chemical nature of organic luminescent or tenebrescent compounds
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    • C09K2211/00Chemical nature of organic luminescent or tenebrescent compounds
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    • C09K2211/00Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/14Macromolecular compounds
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    • C09K2211/00Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/14Macromolecular compounds
    • C09K2211/1441Heterocyclic
    • C09K2211/1483Heterocyclic containing nitrogen and sulfur as heteroatoms
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    • H01LSEMICONDUCTOR DEVICES; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H01L51/00Solid state devices using organic materials as the active part, or using a combination of organic materials with other materials as the active part; Processes or apparatus specially adapted for the manufacture or treatment of such devices, or of parts thereof
    • H01L51/42Solid state devices using organic materials as the active part, or using a combination of organic materials with other materials as the active part; Processes or apparatus specially adapted for the manufacture or treatment of such devices, or of parts thereof specially adapted for sensing infra-red radiation, light, electro-magnetic radiation of shorter wavelength or corpuscular radiation and adapted for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation using organic materials as the active part, or using a combination of organic materials with other material as the active part; Multistep processes for their manufacture
    • H01L51/424Solid state devices using organic materials as the active part, or using a combination of organic materials with other materials as the active part; Processes or apparatus specially adapted for the manufacture or treatment of such devices, or of parts thereof specially adapted for sensing infra-red radiation, light, electro-magnetic radiation of shorter wavelength or corpuscular radiation and adapted for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation using organic materials as the active part, or using a combination of organic materials with other material as the active part; Multistep processes for their manufacture comprising organic semiconductor-organic semiconductor hetero-junctions
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    • Y02E10/54Material technologies
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PCT/IB2014/061633 2013-05-23 2014-05-22 Stabilized photoactive composition and use thereof WO2014188376A1 (en)

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ITMI2013A000840 2013-05-23
ITMI20130840 2013-05-23

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Citations (14)

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US5721299A (en) * 1989-05-26 1998-02-24 International Business Machines Corporation Electrically conductive and abrasion/scratch resistant polymeric materials, method of fabrication thereof and uses thereof
US20030204038A1 (en) * 2002-04-16 2003-10-30 Steven Xiao Hybrid organic-inorganic light emitting polymers
JP2003330145A (ja) * 2002-05-14 2003-11-19 Konica Minolta Holdings Inc 熱現像写真材料
WO2006093936A2 (en) 2005-03-01 2006-09-08 Rwe Schott Solar Inc. Solar encapsulants with protective additives
KR20060102415A (ko) * 2005-03-23 2006-09-27 동양제철화학 주식회사 폴리플루오렌계 공액 고분자와 이 고분자를 발광물질로포함하는 전기발광소자
US20070138483A1 (en) * 2005-12-19 2007-06-21 Lee Tae-Woo Conducting polymer composition and electronic device including layer obtained using the conducting polymer composition
US20070295390A1 (en) 2006-05-05 2007-12-27 Nanosolar, Inc. Individually encapsulated solar cells and solar cell strings having a substantially inorganic protective layer
WO2009006550A1 (en) * 2007-07-05 2009-01-08 Nitto Denko Corporation Light emitting devices and compositions
WO2009064661A1 (en) * 2007-11-15 2009-05-22 Nitto Denko Corporation Light emitting devices and compositions
WO2010006698A1 (en) 2008-06-30 2010-01-21 Eni S.P.A. Conjugated low band-gap copolymers and relative preparation process
WO2010046114A2 (en) 2008-10-22 2010-04-29 Eni S.P.A. π-CONJUGATED LOW-BAND-GAP COPOLYMERS CONTAINING BENZOTRIAZOLE UNITS
WO2011066954A1 (en) 2009-12-04 2011-06-09 Eni S.P.A. π-CONJUGATED POLYMERS CONTAINING FLUOROARYLVINYLEDENE UNITS AND RELATIVE PREPARATION PROCESS
WO2011072876A1 (en) 2009-12-18 2011-06-23 Eni S.P.A. Copolymers for solar cells based on acridonic units
WO2012017048A1 (de) 2010-08-04 2012-02-09 Johnson Controls Gmbh Befestigungsvorrichtung und schwenkvorrichtung für einen fahrzeugsitz und fahrzeugsitz

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US5721299A (en) * 1989-05-26 1998-02-24 International Business Machines Corporation Electrically conductive and abrasion/scratch resistant polymeric materials, method of fabrication thereof and uses thereof
US20030204038A1 (en) * 2002-04-16 2003-10-30 Steven Xiao Hybrid organic-inorganic light emitting polymers
JP2003330145A (ja) * 2002-05-14 2003-11-19 Konica Minolta Holdings Inc 熱現像写真材料
WO2006093936A2 (en) 2005-03-01 2006-09-08 Rwe Schott Solar Inc. Solar encapsulants with protective additives
KR20060102415A (ko) * 2005-03-23 2006-09-27 동양제철화학 주식회사 폴리플루오렌계 공액 고분자와 이 고분자를 발광물질로포함하는 전기발광소자
US20070138483A1 (en) * 2005-12-19 2007-06-21 Lee Tae-Woo Conducting polymer composition and electronic device including layer obtained using the conducting polymer composition
US20070295390A1 (en) 2006-05-05 2007-12-27 Nanosolar, Inc. Individually encapsulated solar cells and solar cell strings having a substantially inorganic protective layer
WO2009006550A1 (en) * 2007-07-05 2009-01-08 Nitto Denko Corporation Light emitting devices and compositions
WO2009064661A1 (en) * 2007-11-15 2009-05-22 Nitto Denko Corporation Light emitting devices and compositions
WO2010006698A1 (en) 2008-06-30 2010-01-21 Eni S.P.A. Conjugated low band-gap copolymers and relative preparation process
WO2010046114A2 (en) 2008-10-22 2010-04-29 Eni S.P.A. π-CONJUGATED LOW-BAND-GAP COPOLYMERS CONTAINING BENZOTRIAZOLE UNITS
WO2011066954A1 (en) 2009-12-04 2011-06-09 Eni S.P.A. π-CONJUGATED POLYMERS CONTAINING FLUOROARYLVINYLEDENE UNITS AND RELATIVE PREPARATION PROCESS
WO2011072876A1 (en) 2009-12-18 2011-06-23 Eni S.P.A. Copolymers for solar cells based on acridonic units
WO2012017048A1 (de) 2010-08-04 2012-02-09 Johnson Controls Gmbh Befestigungsvorrichtung und schwenkvorrichtung für einen fahrzeugsitz und fahrzeugsitz

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Title
CHEN: "Development of Novel Conjugated Donor Polymers for High-Efficiency Bulk-Heterojunction Photovoltaic Device", ACCOUNTS OF CHEMICAL RESEARCH, vol. 42, no. 11, 2009, pages 1709 - 1718

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