WO2014183036A1

WO2014183036A1 - Non-lithium metal ion battery electrode material architecture

Info

Publication number: WO2014183036A1
Application number: PCT/US2014/037502
Authority: WO
Inventors: Yan YAO; Yanliang LIANG
Original assignee: University of Houston System
Current assignee: University of Houston System
Priority date: 2013-05-10
Filing date: 2014-05-09
Publication date: 2014-11-13
Anticipated expiration: 2015-11-10
Also published as: US20140335407A1; US9745205B1; US9725331B2

Abstract

A method for configuring a non-lithium-intercalation electrode includes intercalating an insertion species between multiple layers of a stacked or layered electrode material. The method forms an electrode architecture with increased interlayer spacing for non-lithium metal ion migration. A laminate electrode material is constructed such that pillaring agents are intercalated between multiple layers of the stacked electrode material and installed in a battery.

Description

NON-LITHIUM METAL ION BATTERY ELECTRODE MATERIAL

ARCHITECTURE CROSS-REFERENCE TO RELATED APPLICATIONS

[0001] This application claims priority to U.S. Provisional Patent Application No. 61/822,109 filed on May 10, 2013 and titled "Non-Lithium Metal Ion Battery Electrode Material Architecture" incorporated herein by reference in its entirety.

STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT

[0002] Not applicable.

BACKGROUND

Field of the Disclosure

[0003] This disclosure relates to a secondary or rechargeable battery, specifically to modifying a battery's electrode matrix for use in non-lithium metal ion applications.

Background

[0004] Developing high energy, high power, and safe batteries is of great significance so as to address the society's energy needs, such as distributed power sources, electric vehicles, and devices that handle large amounts of power. Among current battery techniques, lithium-ion batteries featuring the highest energy and power density have dominated the portable electronics market. When lithium-ion batteries are to be scaled up, however, the availability of lithium will also become a limitation. The global production of lithium can presently only satisfy half the need to convert the annually produced >60 million cars into plug-in hybrid electric vehicles (EVs) which are powered by both combustion engines and rechargeable lithium batteries. With the continued adoption of EV's, the lithium supply deficit is expected to worsen because these vehicles carry several times more batteries onboard. Although lithium reserves in sea water are rich, exploitation from the sea is presently too expensive to constitute a significant portion of lithium production.

[0005] Recent efforts to develop scalable high-energy batteries have turned attention to non- lithium techniques such as room-temperature rechargeable magnesium and sodium batteries which work in a similar way as lithium-ion batteries. Magnesium and sodium are earth abundant elements and are cheaply produced in huge amounts as shown in Table 1.

[0006] TABLE 1 : Comparison of Key Parameters of Lithium, Magnesium, and Sodium

Lithium Magnesium Sodium

Gravimetric Capacity (mAh g ^l) 3861 2205 1166 Volumetric Capacity (mAh cm ³) 2066 3833 1128

Potential (V vs NHE) -3.04 -2.372 -2.71

Global Production (kg yr^"1) 2.5 x lO⁷ (very low) 6.3 xlO⁹ (high) 10¹⁰ (high)

Price (carbonate; $ ton^-1) 5000 600 200

Mⁿ⁺ Radius (A) 0.68 0.65 0.95

Polarization Strength (10⁵/pm^~2) 21.6 47.3 11.1

[0007] Generally, the electrodes based on light-weight multivalent metals such as magnesium and aluminum provide some advantages over the conventional lithium. For example, they may offer up to seven times higher volumetric specific capacity than lithium-ion battery anodes, including graphite and

In addition, their redox potentials are 0.7-1.4 V higher than lithium, implying potentially better safety; but not too high (e.g. the redox potential of aluminum is lower than the popular anode LLiTisO ) so that the theoretically achievable working potential is not compromised. Studies on the electrochemical deposition of magnesium showed that magnesium can be plated in a uniform dendrite-free manner and will serve as a safe anode material. Rechargeable magnesium batteries are therefore regarded as a potentially low-cost, ultra-high energy, and safe technology for energy storage.

[0008] Rechargeable batteries based on non-lithium metals share similar chemistry and fabrication techniques as those for rechargeable lithium batteries, while possessing the advantages of lower costs and better safety. However, most materials used for non-lithium metal storage have met with limited intercalation extent and inferior reversibility. A wide range of intercalation compounds have been screened for magnesium storage, including layered transition metal chalcogenides, transition metal oxides, and polyanionic magnesium salts. All these categories of compounds are established intercalation hosts for lithium battery cathodes. However, when they are directly used in the bulk form as cathodes, only Cheveral phase chalcogenides have exhibited practical magnesium intercalation. Currently, other compounds show continuous capacity fade after the initial activation stage. For oxides, no practical cycling stability has been reported and, to date, there is no cathode material exhibiting practical energy density and cyclability suitable for electrochemical storage of multivalent metal ions. For aluminum batteries, only V2O5 and T1O2 have been attempted as cathodes but, neither has exhibited practical energy density. Studies on sodium-ion batteries have also revealed intercalation chemistry that is different from their lithium-based counterparts. Many more plateaus are observed in the charge-discharge curves for electrochemical sodium intercalation, implying complex multi-phase reactions with frequent structural transformation which are detrimental to cycling stability.

[0009] Generally, the aforementioned disadvantages associated with the intercalation of non- lithium metal cations appear to be related to the fact that all these cations are larger or more polarizing than the Li⁺ ion. Compared to the Li⁺ ion, the Na⁺ ion has the same charge number but a significantly larger ionic radius (0.95 A, cf 0.68 A for Li⁺). As a result of steric effects, the Na⁺ ion exhibits sluggish intercalation/diffusion kinetics in frameworks commonly employed for Li storage. The Mg²⁺ ion has a similar ionic radius (0.65 A) to Li but double the charge number, hence exhibiting high polarizing ability. The strong interaction of the multivalent Mg²⁺ ion with the negatively charged atoms in the host material makes the diffusion of Mg²⁺ difficult.

SUMMARY

[0010] This disclosure relates to a non-lithium ion metal electrode matrix to increase the multivalent metal-ion batteries' performance. These batteries provide an ultra-high-density energy storage that is aimed at providing substantially higher volumetric energy densities relative to lithium-ion batteries. The intrinsic safety of these batteries adds to the flexibility in packaging battery system, for example in electric vehicle applications. Other applications include energy storage solutions for distributed power source, grid, and EV applications.

[0011] In exemplary instances, there is disclosed a method for modifying a battery electrode material comprising introducing insertion species into a composition of A_xM_yN_z and at least one non-lithium metal ion, delaminating the A_xM_yN_z , exposing the delaminated A_xM_yN_z to a solution containing the insertion species, and restacking the delaminated A_xM_yN_z around the insertion species.

[0012] Also, there is disclosed a battery electrode material architecture comprising a composition of A_xM_yN_z , a pillaring agent, and at least one non-lithium metal ion Xⁿ⁺. Configured thusly, A is at least one low-valence element chosen from the group consisting of H, alkaline, and alkaline earth metals, and 0≤ x≤ 1.5, M is at least one metal and 1≤ y≤ 2.5, and N is at least one non-metal element chosen from the group consisting of O, S, Se, Ν, P, Br, and I, and 1.8≤ z≤ 4.2. In instances, is at least one non-lithium metal ion chosen from the group consisting of Na, K, Mg, Ca, Al, Ga, and Y, and 1≤ n≤ 3. In further instances, the pillaring agent comprises at least one electrically neutral polymer containing O, N, F, and/or S atoms.

[0013] Likewise, there is disclosed a battery having an electrolyte in contact with a battery electrode material architecture comprising a composition of A_xM_yN_z , a pillaring agent, and at least one non-lithium metal ion Xⁿ⁺. Configured thusly, A is at least one low-valence element chosen from the group consisting of H, alkaline, and alkaline earth metals, and 0≤ x≤ 1.5, M is at least one metal and 1≤ y≤ 2.5, and N is at least one non-metal element chosen from the group consisting of O, S, Se, Ν, P, Br, and I, and 1.8≤ z≤ 4.2. In instances, is at least one non-lithium metal ion chosen from the group consisting of Na, K, Mg, Ca, Al, Ga, and Y, and 1≤ n≤ 3. In further instances, the pillaring agent comprises at least one electrically neutral polymer containing O, N, F, and/or S atoms.

[0014] Additional features and characteristics of the disclosed embodiments e will be explained in the description which follows and will be apparent to those having ordinary skill in the art upon examination of the following discussion.

BRIEF DESCRIPTION OF THE DRAWINGS

[0015] For a detailed description of the disclosed embodiments, reference will now be made to the accompanying drawings in which:

[0016] FIGURE 1 schematically illustrates the diffusion of non-lithium metal ions in layered materials as facilitated with the increase of interlayer space according to an embodiment of the present disclosure;

[0017] FIGURE 2 illustrates the diffusion path of a Mg²⁺ in MoS₂ and compares the energy change along the diffusion path with two different interlayer distances;

[0018] FIGURE 3 illustrates a schematic of the method of constructing an electrode according to an embodiment of the present disclosure;

[0019] FIGURE 4 illustrates the energy barrier for the diffusion of Mg²⁺ in M0S₂ as a function of interlayer distance;

[0020] FIGURE 5 illustrates the X-ray diffraction pattern of M0S₂ samples with different interlayer distances;

[0021] FIGURE 6 illustrates the discharge-charge profile of magnesium intercalation in M0S2 samples with different interlayer distance at the tenth cycle;

[0022] FIGURE 7 illustrates the cycling stability of magnesium intercalation in M0S₂ samples with different interlayer distance;

[0023] FIGURE 8 illustrates the discharge-charge profile of sodium intercalation in M0S₂ samples with different interlayer distance at the second cycle;

[0024] FIGURE 9 illustrates the cycling stability of sodium intercalation in M0S₂ samples with different interlayer distance. DETAILED DESCRIPTION

[0025] OVERVIEW: The difficulty in intercalation/diffusion of metal cations in existing materials is induced by strong interactions between metal cations and host materials. These can be alleviated when the lattice of the host materials is enlarged by insertion of additional species including polymers, molecules, and inorganic and organometallic clusters. For example, as shown in Figure 1, fine-tuning the interlayer distance Di of layered materials according to the specific cation to be intercalated permits implementation of non-lithium metal cations. In Figure 1, the interlayer distance or spacing Di only permits the passage of lithium but, when expanded, the interlayer spacing shown as D2 and D3 no longer restricts the diffusion of non-lithium metal cations. The expansion of the lattice spacing by intercalation of pillaring agents is an efficient and general strategy to modify common electrode materials and matrices for efficient electrochemical storage of non-lithium metal cations. Electrode materials previously developed for lithium-ion batteries may be modified according to the present disclosure to meet the requirements for intercalation of non-lithium metals.

[0026] The electrode materials are configured for use in a battery. Generally, a battery comprises an enclosure having an electrolyte therein. The electrolyte may be any material that ionizes in response to an applied voltage, thus converting chemical energy to electrical energy. Further, the electrolyte may be a liquid, a gel, or a polymer electrolyte without limitation. The electrode materials extend into the enclosure and contact the electrolyte.. In instances, the electrode materials may be in electrical communication with an electric circuit external to the battery enclosure.

[0027] MATRIX: The structural expansion of the electrode materials according to the present disclosure is effective for multiple classes of intercalation hosts and more specifically applicable to layered compounds. In some configurations, the electrode materials have a formula A_xM_yN_z, (0≤ x≤ 1.5, 1≤ y≤ 2.5, 1.8≤ z≤ 4.2). In these configurations, A is one of or a mixture of low-valence elements including but not limited to H (hydrogen), and alkaline and alkaline earth metals. Exemplary alkaline and alkaline earth metals include at least one element chosen from Li, Na, K, Mg, and Ca, without limitation. Further, M is at least one metal chosen from Ti, Zr, V, Ta, Cr, Mo, W, Mn, Fe, Co, Ni, Cu, Zn, Cd, Ga, In, Sn, Pb, Sb, Bi, and Te, without limation. Also, N is at least one element chosen from O, S, Se, Ν, P, Br or I, without limitation

[0028] INSERTION SPECIES: A controlled amount of electrically neutral pillaring agents is inserted into the lattice spacing of the electrode material intercalation hosts to obtain and stabilize a predetermined interlayer lattice parameter. As used herein, the terms "insertion species," "intercalation species," and "pillaring agents" are used interchangeably and have the same meaning. Therefore, as disclosed, insertion species, intercalation species, and pillaring agents may be inserted in the interlayer spaces of a layered electrode material, for example having the formula A_xM_yN_z discussed hereinabove. Further, the distance of interlayer lattice parameter is determined at least partially by the specific cation to be intercalated and thus, the amount of pillaring agents is likewise determined. Pillaring agents comprise polymers containing O, N, F, and/or S atoms such as poly(ethylene oxide), poly(propylene glycol), poly(vinylpyrrolidinone), methyl cellulose, polyethyleneimine, poly(aniline), and polypyrrole and molecules containing O, N, F, and/or S atoms such as alkylamines comprising diethylamine, dibutylamine, dipentylamine, N- isopropylcyclohexylamine, and dicyclohexylamine and glymes comprising diglyme, triglyme, and tetraglyme. Upon insertion, the pillaring agents show a characteristic lattice expansion of 1-300% in at least one dimension of the layered composite electrode material. Without limitation by any particular theory, controlling the size and amount of the intercalated species likewise controls the interlayer distance of all composites, and thusly can be continuously tuned for the metal ion.

[0029] COMPOSITE FORMATION: The disclosed composite electrode materials are synthesized by a general delamination-adsorption-restacking procedure. This electrode material synthesis method 100 is illustrated in Figure 3. The method 100 comprises the steps of delaminating the host material 1 10, adsorbing the insertion species 120, and restacking the host material 130. In the method 100, delaminating the host material 110 comprises at least one approach including physical exfoliation, electrochemical reduction/oxidation, chemical reduction/oxidation, or combinations thereof. Without limitation, the host material A_xM_yN_z may be considered delaminated, exfoliated, or opened such that individual layers are not associated. Delaminating the host material 110 further comprises dispersing the exfoliated A_xMyN_z host material in one or a combination of solvents. In some instances, any inorganic or organic solvent may be used and in certain instances, water may be used as a solvent. Subsequently, adsorbing the insertion species 120 comprises exposing the delaminated host material to a solution containing the insertion species. In certain instances, the insertion species may be dispersed in the solvent for adsorbing the insertion species 120. Further, the insertion species may be agitated or mixed such that the surfaces of the delaminated host materials are coated in the species. Restacking the host material 130 comprises reforming the layered structure comprising the host material around the insertion species. Generally, restacking the host material 130 comprises solvent extraction. Exemplary solvent extractions may include at least one of the processes chosen from filtration, centrifugation, drying, or combinations thereof. In some instances, restacking the host material 130 comprises a temperature ranging from -80 °C to 150 °C. In certain instances, the process for restacking the host material may be predetermined by the solvent used during delaminating the host material 110.

[0030] ELECTRODE ARCHITECTURE: The present disclosure relates to expanding the interlayer spacing of intercalation hosts as a general strategy for electrode materials for storage of non-lithium metal cations. The structural expansion is applicable to various intercalation hosts, however the current disclosure specifically relates to layered materials. Layered metal chalcogenides (LMCs) such as M0S₂ is used as a model system because of its established intercalation chemistry and wide deployment as cathode materials in rechargeable lithium batteries. LMCs are typical two-dimensional materials held by strong covalent metal- sulfur bonds within a layer but weak van der Waals force between the layers. Into the weakly held LMC interlayers a range of species including ions, molecules, polymers, and even nanoclusters can be intercalated to form interlayer-expanded composites. By controlling the size and amount of the intercalated species, the interlayer distance is readily tuned.

[0031] In some instances, poly(ethyleneoxide) (PEO) is utilized in a configuration of this electrode architecture. The crystal structure and definite chemical composition of a range of LMC-PEO intercalate composite allow for a precise tuning of the interlayer distance over a wide range. In a nonlimiting exemplary configuration using M0S₂, the interlayer spacings may be controlled in a distance of about 6.1 A to about 16 A. Contrary to conventional inert intercalating agents which block the entrance and diffusion of the target cations, the PEO is a solid-state cation conductor that facilitates ion transport within layers. Also, the flexible and mobile segments of PEO also make room for ingressing cations. Recognizing that PEO itself is the major component of solid-state polymer electrolytes, the intercalated PEO may increase the weight to the electrode. However its capability for ion transport lowers the required amount of additional electrolyte, thereby maintaining or improving the energy density of the whole cell.

[0032] M0S₂-PEO intercalate composites with tunable interlayer distances are synthesized following a lithiation-delamination-restacking procedure. Synthetic parameters including particle size of the pristine M0S2, molecular weight of PEO, and the mass ratio of M0S2 to PEO are controlled towards desired lattice spacing of the resulted composite architectures. Electrochemical intercalation of non-lithium ions in these modified M0S₂ are then measured in three-/two-electrode cells. [0033] FURTHER DISCUSSION: Through the analysis of the intercalation behavior non- lithium cations in expanded structures of M0S₂, the relationship between interlayer distance of the host and the intercalation kinetics of cations is identified herein. Theoretical modeling has confirmed that as the interlayer space of M0S₂ increases, the energy barrier for Mg²⁺ cation diffusion within the host decreases as shown in FIGURE 4. The improved intercalation properties of the host results in increased capacity and/or cycling stability. The unmodified M0S₂ shows a negligible capacity (~9 mAh/g) in a Mg-ion cell. The insertion of PEO in the lattice increase the capacity by 8 folds to ~70 mAh/g and stably cycle at a reasonable current density of 33 mA/g as shown in FIGURE 7. This result represents an example that even materials which are usually considered not capable of Mg intercalation can be transformed into a capable material by the interlayer engineering strategy disclosed herein. In another case, M0S₂ with different interlayer distances exhibit comparable initial capacities during sodium (de-)intercalation, but the cycling stability is considerably different, i.e. the larger the interlayer distance is, the better the capacity retention is. This observation can be rationalized as that a more open crystal gallery is less susceptible to structural damage during the (de-)intercalation of large cations and thus makes more suitable intercalation host. The modified M0S₂ represent a new high-performance electrode material for rechargeable magnesium/sodium batteries. Further, the modification of M0S₂ can be readily applied to other LMCs (e.g. T1S₂ and VS₂) which feature higher energy densities. Importantly, the interlayer expansion method according to the present disclosure could be extended to other layered materials such as transition metal oxides, leading to a large family of electrode materials.

[0034] To further illustrate various exemplary embodiments of the present invention, the following examples are provided.

EXAMPLES

[0035] Example 1: Theoretical demonstration of enhanced Mg²⁺ in modified M0S₂ with increased interlayer spacing. FIGURE 2 shows that regardless of the interlayer distance, the Mg²⁺ migrates first from an O_h-site to a T_h-site then to the other O_h site. The binding energy for the Mg-MoS₂ intercalate, defined as the difference between the energy of Mg-intercalated M0S₂ and the sum of those of M0S₂ and Mg atom, changes along the diffusion path. To migrate between two O_h-sites, Mg²⁺ should first overcome an energy barrier, or diffusion barrier, to diffuse from the more stable Oh-site to a semi-stable Th-site, and then overcome another smaller barrier to reach another O_h-site. The energy barrier for the diffusion process is 1.12 eV and 0.22 eV for an interlayer distance of 6.75 A and 9 A, respectively. This five-fold difference in diffusion barrier that occurred with a merely ~2 A increase in interlayer distance indicates that the spacing expansion in the interlayer can effectively improve the Mg²⁺ diffusion kinetics. A complete picture of the correlation between diffusion barrier and M0S2 interlayer distance is shown in FIGURE 4.

[0036] Example 2: Synthesis of (PEO-)MoS2 composites with different interlayer distance. M0S2 was soaked in the solution of an excess of w-butyllithium in hexane to form lithiated LiJVIoS2. The lithiated product was exfoliated in water to form a form a quasi-stable suspension of single-layed M0S2 sheets. A controlled amount of PEO, 0-200% w/w relative to M0S2, was added to the suspension. The mixture was centrifuged, washed with water, and dried to afford the restacked M0S2 composites with different interlayer distance. FIGURE 5 shows the X-ray diffraction patterns of the modified M0S2 composties as well as a commercial sample without any modification. Among the various PEO-M0S2 ratios studied (0-2), three ratios, namely 0, 0.25, and 1, are shown as representatives of PEO-M0S2 composites with zero, one, and two layers of PEO intercalated within two slabs of M0S2 sheets, respectively. The diffraction peak corresponding to the interlayer spacing shifts to lower angles as the amount of intercalated PEO increases. With the aid of Bragg equation, the interlayer distances of samples are calculated to be 6.14 A (pristine M0S2, or com-MoS2), 6.22 A (exfoliated M0S2 restacked in the absence of PEO, or e -MoS2), 11.42 A (M0S2-PEO composite with one layer of intercalated PEO, or peo(\ )-MoS₂), and 15.8 A (MoS₂-PEO with two layers of PEO, or peo(2L)-MoS2), confirming that efficient tuning of the interlayer spacing of M0S2 is achieved.

[0037] Example 3: M0S2 composites with different interlayer distance as intercalation host for Mg-ion. The electrochemical performance of M0S2 composites as intercalation host materials for Mg-ion was demonstrated with three-electrode cells. A slurry of the desired M0S2 composite (70 wt.%), Super-P carbon (20 wt.%), and polyvinylidene fluoride (10 wt.%) dispersed in N-methyl-2-pyrrolidone was spread on a piece of stainless steel mesh and dried to form the working electrode. Freshly polished magnesium foil was used as both the counter and reference electrodes. A solution of 0.25 M [Mg₂Cl₃]⁺[AlPh₂Cl2]^~ in tetrahydrofuran served as the electrolyte. Three M0S2 samples, including the commercially available unmodified M0S2 (com-MoS2), the exfoliated M0S2 restacked without the addition of PEO (e -MoS2), and a M0S2 composite obtained with the addition of 27 wt.% of PEO (relative to the weight of M0S2; peo-MoS2) were compared in this configuration. At the same charge-discharge current density of 33 mA/g, all three samples allow for reversible Mg²⁺ (de-)intercalation and exhibit similar cycling stability, but the capacities vary significantly (FIGURES 6 & 7). The unmodified M0S2 delivers a low specific capacity of ~9 mAh/g. A slight increase in the interlayer distance from 6.14 A (com-MoS₂) to 6.22 A (ex -MoS₂) leads to a three-time increase in capacity to ~35 mAh/g. The peo-MoS₂ composite containing PEO achieves the highest capacity of ~70 mAh/g, which is double of that of ex -MoS₂. The higher capacity for M0S₂ composites with larger interlayer spacing indicates more accessible intercalation sites in the lattice. The high capacity and reversibility observed for the peo-MoS₂ composite confirm that the presence of PEO does not impede but facilitate the intercalation and diffusion of non- lithium cations.

[0038] Example 4: M0S2 composites with different interlayer distance as intercalation host for Na-ion. The electrochemical performance of M0S₂ composites as intercalation host materials for Na-ion was demonstrated with two-electrode cells. Working electrodes were fabricated with the same method as for those electrodes used in Mg-ion cells. Freshly sliced metallic sodium was used as both the counter and reference electrode. A solution of 1 M NaC10₄ in dimethoxyethane served as the electrolyte. At the same charge-discharge current density of 84 mA/g, the three M0S2, i.e. com-MoS2, e -MoS2, and peo-MoS2, deliver comparable first discharge capacity of 126, 151, and 132 mAh/g, respectively shown in FIGURE 8. All samples experience capacity reduction over cycling but at different rate. The capacity for com-MoS₂ was halved over 2 cycles, while the same degree of fading for e /-MoS₂ and peo-MoS₂ took 8 and 44 cycles to complete, respectively FIGURE 9, indicating improved reversibility of the intercalation process in the host with larger interlayer distance.

[0039] Where numerical ranges or limitations are expressly stated in the disclosure of the exemplary embodiments contained herein, such express ranges or limitations should be understood to include iterative ranges or limitations of like magnitude falling within the expressly stated ranges or limitations (e.g., from about 1 to about 10 includes, 2, 3, 4, etc.; greater than 0.10 includes 0.11, 0.12, 0.13, etc.). For example, whenever a numerical range with a lower limit, Ri, and an upper limit, R_u, is disclosed, any number falling within the range is specifically disclosed. In particular, the following numbers within the range are specifically disclosed: R=Ri + k (R_u-Ri), wherein k is a variable ranging from 1 percent to 100 percent with a 1 percent increment, i.e., k is 1 percent, 2 percent, 3 percent, 4 percent, 5 percent, 50 percent, 51 percent, 52 percent... 95 percent, 96 percent, 97 percent, 98 percent, 99 percent, or 100 percent. Moreover, any numerical range defined by two R numbers as defined in the above is also specifically disclosed. Use of the term "optionally" with respect to any element of a claim means that the element is required, or alternatively, the element is not required, both alternatives being within the scope of the claim. Use of broader terms such as "comprises", "includes", and "having" means "including but not limited to" and should be understood to also provide support for narrower terms such as "consisting of, "consisting essentially of, and "comprised substantially of. Accordingly, the scope of protection is not limited by the description set out above but is defined by the claims that follow, that scope including all equivalents of the subject matter of the claims. Each and every claim is incorporated into the specification as further disclosure, and the claims are each an embodiment of the present invention. The discussion of a reference in the disclosure is not an admission that it is prior art, especially any reference that has a publication date after the priority date of this application. The disclosure of all patents, patent applications, and publications cited in the disclosure are hereby incorporated by reference, to the extent that they provide exemplary, procedural or other details supplementary to the disclosure.

Claims

CLAIMS We claim:

1. A battery electrode material architecture comprising:

a composition of A_xM_yN_z , a pillaring agent, and at least one non-lithium metal ion

Xⁿ⁺,

wherein:

A is at least one low- valence element chosen from the group consisting of H, alkaline, and alkaline earth metals, and 0≤ x≤ 1.5;

M is at least one metal and 1≤ y≤ 2.5;

N is at least one non-metal element chosen from the group consisting of O, S, Se, Ν, P, Br, and I, and 1.8≤ z≤ 4.2; and

X is at least one non-lithium metal ion chosen from the group consisting of Na, K, Mg, Ca, Al, Ga, and Y, and 1≤ n≤ 3.

2. The battery electrode material architecture of claim 1, wherein a low-valence element further comprises at least one chosen from the group consisting of Li, Na, K, Mg, and Ca.

3. The battery electrode material architecture of claim 1 wherein a metal comprises a metal chosen from the group consisting of Ti, Zr, V, Ta, Cr, Mo, W, Mn, Fe, Ni, Co, Cu, Zn, Cd, Ga, In, Sn, Pb, Sb, Bi, and Te

4. The battery electrode material architecture of claim 1, wherein the pillaring agent comprises at least one electrically neutral polymer containing O, N, F, and/or S atoms.

5. The battery electrode material architecture of claim 4, wherein at least one electrically neutral polymer comprises at least one polymer chosen from the group consisting of poly(ethylene oxide), poly(propylene glycol), poly(vinylpyrrolidinone), methyl cellulose, poly(methyl acrylate), polyacrylonitrile, polyethyleneimine, poly(aniline), and polypyrrole.

6. The battery electrode material architecture of claim 4, wherein electrically neutral polymer comprises at least one chosen from the group consisting of alkylamines and glymes

7. The battery electrode material architecture of claim 6, wherein the alkylamines comprise of at least one molecule chosen from the group consisting of diethylamine, dibutylamine, dipentylamine, N-isopropylcyclohexylamine, and dicyclohexylamine.

8. The battery electrode material architecture of claim 6, wherein the glymes consist of at least one molecule chosen from the group consisting of diglyme, triglyme, and tetraglyme.

9. The battery electrode material architecture of claim 1, wherein the non-lithium metal ion is positioned within the lattice spacing of A_xM_yN_z.

10. The battery electrode material architecture of claim 9, wherein the polymers and non- lithium metal ion in the lattice spacing of A_xM_yN_z induce a lattice expansion of 1-300% in at least one dimension.

1 1. A method for modifying A_xM_yN_z electrode material comprising:

delaminating A_xM_yN_z electrode material,

exposing the delaminated A_xM_yN_z to a solution containing the insertion species, such that the insertion species intercalate A_xM_yN_z layers; and

restacking the delaminated A_xM_yN_z around the insertion species.

12. The method of claim 11, wherein the delaminating A_xM_yN_z electrode material comprises at least one method chosen from the group consisting of physical exfoliation, electrochemical reduction/oxidation, and chemical reduction/oxidation.

13. The method of claim 1 1, wherein the restacking the delaminated A_xM_yN_z around the insertion species comprises at least one method chosen from the group consisting of filtration, centrifugation, drying, or combinations thereof at a temperature ranging from -80 °C to 150 °C.

14. The method of claim 11, wherein the non-lithium metal ions comprise a formula Xⁿ⁺, wherein X is at least one non-lithium metal chosen from the group consisting of Na, K, Mg, Ca, Al, Ga, and Y, and 1≤ n≤ 3.

15. A battery comprising: an electrolyte; and

at least one electrode material architecture comprising a composition of A_xM_yN_z , a pillaring agent, and at least one non-lithium metal ion Xⁿ⁺,

wherein:

M is at least one metal and 1≤ y≤ 2.5;

16. The battery of claim 15, wherein a low-valence element further comprises at least one chosen from the group consisting of Li, Na, K, Mg, and Ca.

17. The battery of claim 15, wherein at least one metal comprises a metal chosen from the group consisting of Ti, Zr, V, Ta, Cr, Mo, W, Mn, Fe, Co, Ni, Cu, Zn, Cd, Ga, In, Sn, Pb, Sb, Bi, and Te

18. The battery of claim 15, wherein the pillaring agent comprises at least one electrically neutral polymer containing O, N, F, and/or S atoms chosen from the group consisting of poly(ethylene oxide), poly(propylene glycol), poly(vinylpyrrolidinone), methyl cellulose, poly(methyl acrylate), polyacrylonitrile, polyethyleneimine, poly(aniline), and polypyrrole.

19. The battery of claim 15, wherein the pillaring agent comprises at least one electrically neutral molecule containing O, N, F, and/or S atoms chosen from the group consisting of alkylamines and glymes.

20. The battery of claim 20, wherein the alkylamines comprise at least one molecule chosen from the group consisting of diethylamine, dibutylamine, dipentylamine, N- isopropylcyclohexylamine, and dicyclohexylamine.

21. The battery of claim 20, wherein the glymes consist of at least one molecule chosen from the group consisting of diglyme, triglyme, and tetraglyme.

22. The battery of claim 15, wherein the non-lithium metal ions are positioned within the lattice spacing of A_xM_yN_z and induce a lattice expansion of 1-300% in at least one dimension.