WO2014110884A1 - Powdered solid fuel boiler and dry purification process system - Google Patents

Powdered solid fuel boiler and dry purification process system Download PDF

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Publication number
WO2014110884A1
WO2014110884A1 PCT/CN2013/075699 CN2013075699W WO2014110884A1 WO 2014110884 A1 WO2014110884 A1 WO 2014110884A1 CN 2013075699 W CN2013075699 W CN 2013075699W WO 2014110884 A1 WO2014110884 A1 WO 2014110884A1
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WIPO (PCT)
Prior art keywords
flue gas
solid fuel
fuel boiler
gas passage
heat
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PCT/CN2013/075699
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French (fr)
Chinese (zh)
Inventor
吴道洪
吴玉林
王胜美
陈琳
鲁光明
沈大平
Original Assignee
北京神雾环境能源科技集团股份有限公司
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Priority claimed from CN201310019500.5 external-priority
Priority claimed from CN201310018623.7A external-priority patent/CN103672942B/en
Priority claimed from CN201310019500.5A external-priority patent/CN103940275B/en
Priority claimed from CN2013200280713U external-priority patent/CN203131855U/en
Application filed by 北京神雾环境能源科技集团股份有限公司 filed Critical 北京神雾环境能源科技集团股份有限公司
Publication of WO2014110884A1 publication Critical patent/WO2014110884A1/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L15/00Heating of air supplied for combustion
    • F23L15/02Arrangements of regenerators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D19/00Regenerative heat-exchange apparatus in which the intermediate heat-transfer medium or body is moved successively into contact with each heat-exchange medium
    • F28D19/04Regenerative heat-exchange apparatus in which the intermediate heat-transfer medium or body is moved successively into contact with each heat-exchange medium using rigid bodies, e.g. mounted on a movable carrier
    • F28D19/041Regenerative heat-exchange apparatus in which the intermediate heat-transfer medium or body is moved successively into contact with each heat-exchange medium using rigid bodies, e.g. mounted on a movable carrier with axial flow through the intermediate heat-transfer medium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/40Alkaline earth metal or magnesium compounds
    • B01D2251/404Alkaline earth metal or magnesium compounds of calcium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/604Hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/20Sulfur; Compounds thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00Treatment devices
    • F23J2219/60Sorption with dry devices, e.g. beds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

Abstract

A powdered solid fuel boiler and a dry purification process system (100). The powdered solid fuel boiler (1) comprises: a hearth (11); a regenerative rotating commutating heater (2); a first fume passage (3), wherein an inlet end of the first fume passage (3) is communicated with a top portion of the hearth (11), and an outlet end of the first fume passage (3) is communicated with the regenerative rotating commutating heater (2), so that fume is delivered into one of at least paired accommodating portions (25) of a heat exchanger main body (21) and exchanges heat with a heat carrier (23) accommodated in the accommodating portion (25); an air passage (4), used for delivering air at least into the other one of the paired accommodating portions (25) of the heat exchanger main body (21), so that a heat carrier (23) accommodated in the accommodating portion (25) exchanges heat with air, and the air after heat exchange is supplied into the hearth (11); and a WCFB fume desulfurization device (5), wherein a part of the fume after desulfurization is re-circulated into a second fume passage (101). By means of the powdered solid fuel boiler and the dry purification process system, the fume exhaust temperature is reduced; the efficiency of the boiler, the desulfurization efficiency, and the fume purification rate are improved; and the influence of corrosion is lowered.

Description

粉状固体燃料锅炉及干法净化工艺系统  Powdered solid fuel boiler and dry purification process system
技术领域 Technical field
本发明涉及热交换技术领域, 尤其涉及一种粉状固体燃料锅炉及干法净化工艺系 统。 背景技术  The invention relates to the field of heat exchange technology, and in particular to a powdery solid fuel boiler and a dry purification process system. Background technique
回转式空气预热器是现在各大电厂锅炉上普遍采用的烟气尾端换热装置。 其性能直 接影响锅炉热效率。 传统的回转式空气预热器一般以金属作为传热介质, 只能够回收 500 °C以下烟气的热量, 通过预热助燃空气, 将烟气热量带回炉膛, 并且改善燃烧状况, 从而提高锅炉的效率。  Rotary air preheater is a flue gas end heat exchange device commonly used in boilers of major power plants. Its performance directly affects boiler thermal efficiency. The traditional rotary air preheater generally uses metal as the heat transfer medium, and can only recover the heat of the flue gas below 500 °C. By preheating the combustion air, the flue gas heat is brought back to the furnace, and the combustion condition is improved, thereby improving the boiler. s efficiency.
然而, 传统的回转式空气预热器多为金属波纹板, 但金属波纹板回转式空气预热器 运行中存在低温腐蚀, 且由于气体的流通渠道狭窄, 很容易造成积灰和堵灰。 回转式空 气预热器能够将烟气温度降至 13CTC左右, 因此烟气进入任何工艺的烟气净化系统后都 需要先喷水降温再处理, 对设备也会存在腐蚀影响, 而且工艺复杂、 设备投资较大、 运 行费用较高、 对占地和供水要求大。 发明内容  However, the conventional rotary air preheaters are mostly metal corrugated plates, but the metal corrugated plate rotary air preheaters have low temperature corrosion during operation, and due to the narrow circulation of gas, it is easy to cause ash and ash. The rotary air preheater can reduce the temperature of the flue gas to about 13CTC. Therefore, after entering the flue gas purification system of any process, the flue gas needs to be sprayed and cooled, and then treated, which will also have corrosion effects on the equipment, and the process is complicated and the equipment is complicated. Large investment, high operating costs, and large requirements for land occupation and water supply. Summary of the invention
本发明旨在至少解决现有技术中存在的技术问题之一。 为此, 本发明的一个目的在 于提出一种粉状固体燃料锅炉及干法净化工艺系统,该粉状固体燃料锅炉及干法净化工 艺系统的排烟温度低且消除腐蚀影响。  The present invention aims to solve at least one of the technical problems existing in the prior art. To this end, an object of the present invention is to provide a powdery solid fuel boiler and a dry purification process system which have a low exhaust gas temperature and eliminate corrosion effects.
根据本发明实施例的粉状固体燃料锅炉及干法净化工艺系统, 包括: 粉状固体燃料 锅炉, 所述粉状固体燃料锅炉限定有炉膛; 蓄热式旋转换向加热器, 所述蓄热式旋转换 向加热器包括: 换热器主体; 驱动装置, 所述驱动装置用于驱动所述换热器主体绕其中 心轴线旋转; 分隔件, 所述分隔件沿着所述中心轴线的方向设置在所述换热器主体内, 且将所述换热器主体分隔成至少一对容纳部分,所述每对容纳部分相对所述中心轴线成 径向相对设置; 热载体, 所述热载体分别容纳在所述容纳部分中, 所述热载体由非金属 固体材料所形成;第一烟气通路,所述第一烟气通路的入口端与所述炉膛的顶部相连通, 且出口端与所述蓄热式旋转换向加热器相连通,以将炉膛内产生的烟气通入至少所述成 对的所述容纳部分中的一个内并与其中容纳的所述热载体换热; 空气通路, 所述空气通 路用于将空气至少通入所述成对的所述容纳部分中的另一个内,以使得其中容纳的所述 热载体与所述空气进行换热; 以及 WCFB烟气脱硫设备, 经过所述蓄热式旋转换向加 热器换热后的烟气通过第二烟气通路流入所述 WCFB烟气脱硫设备。  A powdery solid fuel boiler and a dry purification process system according to an embodiment of the present invention, comprising: a powdery solid fuel boiler, the powdery solid fuel boiler defining a furnace; a regenerative rotary reversing heater, the heat storage The rotary reversing heater comprises: a heat exchanger body; a driving device, the driving device is configured to drive the heat exchanger body to rotate about a central axis thereof; a partitioning member, the partitioning member is oriented along the central axis Provided in the heat exchanger body, and partitioning the heat exchanger body into at least one pair of receiving portions, the pair of receiving portions being disposed diametrically opposite to the central axis; a heat carrier, the heat carrier Separably housed in the accommodating portion, the heat carrier is formed of a non-metallic solid material; a first flue gas passage, an inlet end of the first flue gas passage is in communication with a top of the furnace, and an outlet end is The regenerative rotary reversing heater is in communication to pass fumes generated in the furnace into at least one of the pair of the receiving portions and to accommodate the heat contained therein a heat exchange passage for introducing at least air into the other of the pair of the receiving portions to allow heat exchange between the heat carrier contained therein and the air; And the WCFB flue gas desulfurization device, the flue gas after the heat exchange of the regenerative rotary reversing heater flows into the WCFB flue gas desulfurization device through the second flue gas passage.
根据本发明实施例的粉状固体燃料锅炉及干法净化工艺系统, 通过设置蓄热式旋转 换向加热器和 WCFB烟气脱硫设备, 蓄热式旋转换向加热器可将高温烟气的温度大大 降低, 从而提高了锅炉系统的效率, 同时在后续烟气净化处理 WCFB烟气脱硫设备中 可以省去喷水装置, 既优化了工艺、 节约了成本又降低了腐蚀影响, 同时还有效解决了 喷水后的灰分贴壁等问题。 According to the powdered solid fuel boiler and the dry purification process system of the embodiment of the invention, the regenerative rotary reversing heater and the WCFB flue gas desulfurization device are provided, and the regenerative rotary reversing heater can set the temperature of the high temperature flue gas Greatly reduced, thereby improving the efficiency of the boiler system, and in the subsequent flue gas purification treatment WCFB flue gas desulfurization equipment The water spray device can be omitted, which not only optimizes the process, saves cost and reduces the corrosion effect, but also effectively solves the problem of ash adherence after water spray.
另外, 根据本发明的粉状固体燃料锅炉及干法净化工艺系统还可具有如下附加技术 特征:  Further, the powdery solid fuel boiler and the dry purification process system according to the present invention may have the following additional technical features:
根据本发明的一个实施例, 所述煤粉由无烟煤、 贫煤中的至少一种所形成。  According to an embodiment of the present invention, the pulverized coal is formed of at least one of anthracite coal and lean coal.
可选地, 从所述第一烟气通路的所述入口端朝向所述第一烟气通路的所述出口端依 次设置有屏式过热器、 包墙过热器和过热器。 由此, 通过设置过热器, 可有效提高整个 蒸汽动力装置的循环热效率。  Optionally, a screen superheater, a wall superheater and a superheater are arranged from the inlet end of the first flue gas passage toward the outlet end of the first flue gas passage. Thus, by providing a superheater, the cycle thermal efficiency of the entire steam power unit can be effectively improved.
进一步地, 在靠近所述第一烟气通路的所述出口端的所述第一烟气通路内设置有省 煤器。 由此, 通过设置省煤器, 可有效吸收烟气的热量, 降低排烟温度, 减少排烟损失, 从而节省燃料。  Further, a economizer is disposed in the first flue gas passage adjacent to the outlet end of the first flue gas passage. Thus, by providing the economizer, the heat of the flue gas can be effectively absorbed, the exhaust gas temperature can be lowered, and the smoke loss can be reduced, thereby saving fuel.
根据本发明的一个实施例, 从所述第一烟气通路进入所述蓄热式旋转换向加热器内 的烟气速度可调节。 由此, 有效地提高了待预热空气的温度。  According to an embodiment of the invention, the velocity of the flue gas entering the regenerative rotary reversing heater from the first flue gas passage is adjustable. Thereby, the temperature of the air to be preheated is effectively increased.
可选地, 所述热载体为 SiC或者陶瓷, 且具有小球状、 片状或者多孔状的结构。 由 此, 蓄热式旋转换向加热器可耐高温、 耐腐蚀且耐磨损。  Optionally, the heat carrier is SiC or ceramic and has a small spherical, sheet or porous structure. As a result, the regenerative rotary reversing heater is resistant to high temperatures, corrosion and wear.
可选地, 经过所述蓄热式旋转换向加热器换热后的烟气的温度为 65-75 °C。 在锅炉 排烟温度降低到 65~75 °C的同时, 对尾部的脱硫工艺需要产生重大变革。 即采用 WCFB 干法脱硫工艺, 从而使得尾部不需要喷水降温, 避免腐蚀问题, 烟气被降低到 65~75 °C 正好是 WCFB干法脱硫工艺的进口烟温,原来的 12CTC以上的排烟温度必须要喷水降温 到 65~75 °C, 这样节省了一道喷水工艺, 同时节能, 避免了喷水后灰贴壁的不利问题。 由此, 可回收烟气中部分气化潜热, 从而提高了锅炉的热效率, 同时进入后续 WCFB 烟气脱硫设备的烟气无需喷水降温。  Optionally, the temperature of the flue gas after heat exchange by the regenerative rotary commutation heater is 65-75 °C. While the boiler exhaust gas temperature has dropped to 65-75 °C, there is a major change in the tail desulfurization process. That is to use the WCFB dry desulfurization process, so that the tail does not need to spray water to cool down, to avoid corrosion problems, the flue gas is reduced to 65~75 °C, which is the inlet smoke temperature of the WCFB dry desulfurization process, and the original exhaust gas above 12CTC The temperature must be sprayed to cool down to 65~75 °C, which saves a water spray process and saves energy, avoiding the unfavorable problem of ash adherence after water spray. Thereby, part of the latent heat of vaporization in the flue gas can be recovered, thereby improving the thermal efficiency of the boiler, and at the same time, the flue gas entering the subsequent WCFB flue gas desulfurization equipment does not need to be sprayed and cooled.
根据本发明的一个实施例, 所述空气为富氧空气, 且所述空气经过所述蓄热式旋转 换向加热器换热后被加热至 300-650°C。 由此, 空气提升温度较高。  According to an embodiment of the invention, the air is oxygen-enriched air, and the air is heated to 300-650 ° C after heat exchange by the regenerative rotary commutation heater. As a result, the air lift temperature is higher.
根据本发明的一个实施例, 所述蓄热式旋转换向加热器进一步包括: 冷凝液体移除 装置, 所述冷凝液体移除装置设置在所述换热器主体的下方, 以移除换热过程中产生的 冷凝液体。  According to an embodiment of the present invention, the regenerative rotary reversing heater further includes: a condensed liquid removing device disposed under the heat exchanger body to remove heat exchange Condensed liquid produced during the process.
根据本发明的一个实施例, 所述 WCFB烟气脱硫设备包括: 吸收塔, 所述第二烟气 通路与所述吸收塔的底部相连通; 消石灰仓, 所述消石灰仓设置在所述吸收塔的上部, 用于将消石灰喷入所述吸收塔; 除尘器, 所述除尘器与所述吸收塔相连通, 用于对经过 消石灰吸收反应后的烟气进行除尘; 以及烟囱, 经过所述除尘器除尘后的烟气通过第三 烟气通路连通至所述烟肉, 所述第三烟气通路上设置有引风机, 以将所述烟气引至所述 烟囱。 由此, 通过设置吸收塔和消石灰仓, 烟气可在吸收塔中与消石灰仓喷入的消石灰 进行吸收反应, 通过设置除尘器, 脱硫后的烟气可进入除尘器中进行净化, 最后经由烟 囱排入大气。  According to an embodiment of the present invention, the WCFB flue gas desulfurization apparatus includes: an absorption tower, the second flue gas passage is in communication with a bottom of the absorption tower; a lime removal silo, the decalcification silo is disposed in the absorption tower The upper part is used for spraying slaked lime into the absorption tower; the dust remover is connected to the absorption tower for dedusting the flue gas after the slaked lime absorption reaction; and the chimney, after the dust removal The flue gas after the dust removal is connected to the bacon through a third flue gas passage, and the third flue gas passage is provided with an induced draft fan to introduce the flue gas to the chimney. Thus, by providing an absorption tower and a slaked lime tank, the flue gas can be absorbed and reacted with the slaked lime sprayed from the slaked lime tank in the absorption tower. By providing a dust remover, the flue gas after desulfurization can enter the dust collector for purification, and finally through the chimney. Discharge into the atmosphere.
进一步地, 所述 WCFB烟气脱硫设备进一步包括: 再循环管, 所述再循环管倾斜设 置且用于将所述除尘器底部的消石灰再循环至所述吸收塔内。 由此, 通过多次循环, 有 效地提高了消石灰的利用效率, 从而提高了脱硫效率。 Further, the WCFB flue gas desulfurization apparatus further includes: a recirculation pipe, and the recirculation pipe is inclined And used to recycle slaked lime at the bottom of the precipitator into the absorption tower. Thereby, the utilization efficiency of slaked lime is effectively improved by a plurality of cycles, thereby improving the desulfurization efficiency.
更进一步地, 进一步包括: 第四烟气通路, 所述第四烟气通路将所述第三烟气通路 中的一部分烟气再循环至所述第二烟气通路内。 由此, 进一步提高了烟气的净化率。  Further, the method further includes: a fourth flue gas passage that recirculates a portion of the flue gas in the third flue gas passage into the second flue gas passage. Thereby, the purification rate of the flue gas is further improved.
本发明的附加方面和优点将在下面的描述中部分给出, 部分将从下面的描述中变得 明显, 或通过本发明的实践了解到。 附图说明  The additional aspects and advantages of the invention will be set forth in part in the description which follows. DRAWINGS
本发明的上述和 /或附加的方面和优点从结合下面附图对实施例的描述中将变得明 显和容易理解, 其中:  The above and/or additional aspects and advantages of the present invention will become apparent and readily understood from
图 1是根据本发明一个实施例的粉状固体燃料锅炉及干法净化工艺系统的示意图; 图 2是根据本发明的一个实施例的粉状固体燃料锅炉中蓄热式旋转换向加热器的俯 视图。 具体实施方式  1 is a schematic view of a powdery solid fuel boiler and a dry purification process system according to an embodiment of the present invention; FIG. 2 is a regenerative rotary reversing heater in a powdery solid fuel boiler according to an embodiment of the present invention. Top view. detailed description
下面详细描述本发明的实施例, 所述实施例的示例在附图中示出, 其中自始至终相 同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附 图描述的实施例是示例性的, 仅用于解释本发明, 而不能理解为对本发明的限制。  The embodiments of the present invention are described in detail below, and the examples of the embodiments are illustrated in the drawings, wherein the same or similar reference numerals are used to refer to the same or similar elements or elements having the same or similar functions. The embodiments described below with reference to the drawings are intended to be illustrative only and not to limit the invention.
在本发明的描述中, 需要理解的是, 术语"中心"、 "上"、 "下"、 "前"、 "后"、 "左" 、 "右" 、 "竖直" 、 "水平" 、 "顶" 、 "底" 、 "内" 、 "外"等指示的方 位或位置关系为基于附图所示的方位或位置关系, 仅是为了便于描述本发明和简化描 述, 而不是指示或暗示所指的装置或元件必须具有特定的方位、 以特定的方位构造和操 作, 因此不能理解为对本发明的限制。 此外, 术语 "第一" 、 "第二 "仅用于描述目的, 而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。 由此, 限 定有 "第一" 、 "第二" 的特征可以明示或者隐含地包括一个或者更多个该特征。 在本 发明的描述中, 除非另有说明, "多个" 的含义是两个或两个以上。  In the description of the present invention, it is to be understood that the terms "center", "upper", "lower", "front", "back", "left", "right", "vertical", "horizontal", The orientation or positional relationship of the "top", "bottom", "inside", "outside" and the like is based on the orientation or positional relationship shown in the drawings, and is merely for the convenience of describing the present invention and simplifying the description, rather than indicating or implying The device or component referred to must have a particular orientation, configuration and operation in a particular orientation, and thus is not to be construed as limiting the invention. Moreover, the terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, features defining "first" and "second" may explicitly or implicitly include one or more of the features. In the description of the present invention, "multiple" means two or more unless otherwise stated.
在本发明的描述中, 需要说明的是, 除非另有明确的规定和限定, 术语 "安装" 、 "相连" 、 "连接 "应做广义理解, 例如, 可以是固定连接, 也可以是可拆卸连接, 或 一体地连接; 可以是机械连接, 也可以是电连接; 可以是直接相连, 也可以通过中间媒 介间接相连, 可以是两个元件内部的连通。 对于本领域的普通技术人员而言, 可以具体 情况理解上述术语在本发明中的具体含义。  In the description of the present invention, it should be noted that the terms "installation", "connected", and "connected" should be understood broadly, and may be fixed or detachable, for example, unless otherwise explicitly defined and defined. Connected, or connected integrally; can be mechanical or electrical; can be directly connected, or indirectly connected through an intermediate medium, can be the internal communication of the two components. The specific meaning of the above terms in the present invention can be understood in a specific case by those skilled in the art.
下面参考图 1 描述根据本发明实施例的粉状固体燃料锅炉及干法净化工艺系统 100。  A powdered solid fuel boiler and dry purification process system 100 in accordance with an embodiment of the present invention will now be described with reference to FIG.
如图 1所示,根据本发明实施例的粉状固体燃料锅炉及干法净化工艺系统 100包括: 粉状固体燃料锅炉 1、蓄热式旋转换向加热器 2、第一烟气通路 3、空气通路 4以及 WCFB 烟气脱硫设备 5。 蓄热式旋转换向加热器 2用于将高温烟气和待预热空气进行热交换, 从而使待预热 空气的温度升高到某一定值。 蓄热式旋转换向加热器 2包括: 换热器主体 21、 驱动装 置、 分隔件 22和热载体 23, 如图 1、 2中所示。 其中, 驱动装置用于驱动换热器主体 21绕其中心轴线 24旋转。分隔件 22沿着中心轴线 24的方向设置在换热器主体 21内, 且将换热器主体 21分隔成至少一对容纳部分 25, 每对容纳部分 25相对中心轴线成径 向相对设置。 热载体 23分别容纳在容纳部分 25中, 热载体 23由非金属固体材料所形 成。 As shown in FIG. 1 , a powdery solid fuel boiler and a dry purification process system 100 according to an embodiment of the present invention include: a powdery solid fuel boiler 1, a regenerative rotary reversing heater 2, a first flue gas passage 3, Air passage 4 and WCFB flue gas desulfurization equipment 5. The regenerative rotary reversing heater 2 is used for exchanging heat between the high temperature flue gas and the air to be preheated, thereby raising the temperature of the air to be preheated to a certain value. The regenerative rotary reversing heater 2 comprises: a heat exchanger body 21, a driving device, a partition 22 and a heat carrier 23, as shown in Figs. Therein, the drive means is used to drive the heat exchanger body 21 to rotate about its central axis 24. The partition 22 is disposed in the heat exchanger body 21 in the direction of the central axis 24, and divides the heat exchanger body 21 into at least one pair of accommodating portions 25, each pair of accommodating portions 25 being disposed diametrically opposite to the central axis. The heat carriers 23 are respectively accommodated in the accommodating portion 25, and the heat carrier 23 is formed of a non-metallic solid material.
在本发明的其中一个示例中, 换热器主体 21可形成为中空的圆柱体, 分隔件 22可 大致呈板形, 该分隔间沿着换热器主体 21中心线轴线的方向延伸, 从而将换热器主体 21 分隔成一对容纳部分, 热载体分别设在两个容纳部分中, 热载体可由非金属固体材 料制成, 烟气和待预热空气分别通入两个容纳部分中, 然后通过驱动装置驱动换热器主 体 21旋转、 烟气和与其所在的容纳部分中的热载体进行热交换、 待预热空气和与其所 在的容纳部分中的热载体进行热交换, 从而使得待预热空气温度升高。  In one of the examples of the present invention, the heat exchanger body 21 may be formed as a hollow cylinder, and the partition 22 may be substantially plate-shaped, and the partition extends in the direction of the center line axis of the heat exchanger body 21, thereby The heat exchanger body 21 is partitioned into a pair of receiving portions, the heat carriers are respectively disposed in the two receiving portions, and the heat carrier can be made of a non-metallic solid material, and the flue gas and the air to be preheated are respectively introduced into the two receiving portions, and then passed through The driving device drives the heat exchanger main body 21 to rotate, the flue gas exchanges heat with the heat carrier in the accommodating portion in which it is located, heats the air to be preheated, and the heat carrier in the accommodating portion therewith, thereby causing the air to be preheated The temperature rises.
当然, 本发明不限于此, 在本发明的另一些示例中, 分隔件 22还可将换热器主体 21分隔成两对、 三对甚至多对容纳部分。  Of course, the invention is not limited thereto, and in other examples of the invention, the partition 22 may also divide the heat exchanger body 21 into two pairs, three pairs or even pairs of receiving portions.
在现有的气体换热系统中, 烟气在通过该气体换热器之后的出口温度是不能降低到 130°C以下, 因为这会导致硫酸析出, 从而导致对该气体换热器内由金属制造的部件的 严重腐蚀。 但是, 在本发明的上述蓄热式旋转换向加热器 2中 (针对例如含硫的高温烟 气),由于热载体由例如 SiC、陶瓷等的非金属固体材料所形成,从而不用顾虑硫在 130°C 存在露点所导致的腐蚀性问题,而可以把高温烟气的出口温度降低到硫的露点之下的温 度, 从而最大程度地进行换热, 根据本发明的一个实施例, 所述高温烟气离开所述气体 换热器的出口温度小于 130°C, 进一步地, 所述高温烟气离开所述气体换热器的出口温 度小于 70°C。 该温度在传统的气体换热系统中是几乎不可能实现的。 此外, 在将出口 温度降低到露点的温度之下,水蒸汽冷凝析出为液体水,释放了大量的潜热(水从 100°C 变为 10CTC的水蒸汽吸收的热量相当于水从 0°C升高至 100°C时所吸收热量的 3倍) 。 由于热载体由非金属固体材料所形成, 所以在硫沉积一定程度之后, 对该容纳部分中所 容纳的热载体清洗即可以继续使用,从而降低了传统的气体换热系统中所存在的零部件 替换所导致的成本增加的问题。 此外, 根据发明人使用该领域内的公认计算方法计算, 此外, 根据发明人的计算, 通过搭载蓄热式旋转换向加热器, 将冷风加热到热风利于燃 烧的同时, 将排烟温度降到 65~75°C, 有效的利用了燃料的余热, 并将锅炉的效率提高 In the existing gas heat exchange system, the outlet temperature of the flue gas after passing through the gas heat exchanger cannot be lowered below 130 ° C, because this causes the sulfuric acid to precipitate, resulting in the metal in the gas heat exchanger. Severe corrosion of the manufactured parts. However, in the above-described regenerative rotary commutation heater 2 of the present invention (for, for example, high-temperature flue gas containing sulfur), since the heat carrier is formed of a non-metallic solid material such as SiC or ceramic, there is no need to worry about sulfur. At 130 ° C, there is a problem of corrosion caused by the dew point, and the outlet temperature of the high-temperature flue gas can be lowered to a temperature below the dew point of sulfur to maximize heat exchange. According to an embodiment of the present invention, the high temperature The outlet temperature of the flue gas leaving the gas heat exchanger is less than 130 ° C. Further, the outlet temperature of the high temperature flue gas leaving the gas heat exchanger is less than 70 ° C. This temperature is almost impossible to achieve in a conventional gas heat exchange system. In addition, under the temperature at which the outlet temperature is lowered to the dew point, the water vapor condenses out as liquid water, releasing a large amount of latent heat (the amount of heat absorbed by the water vapor from 100 ° C to 10 CTC is equivalent to the water rising from 0 ° C. Up to 3 times the amount of heat absorbed at 100 ° C). Since the heat carrier is formed of a non-metallic solid material, after the sulfur deposition is performed to some extent, the heat carrier accommodated in the accommodating portion can be continuously used, thereby reducing the components existing in the conventional gas heat exchange system. The problem of increased costs caused by replacement. In addition, according to the inventors' calculation using the accepted calculation method in the field, according to the calculation by the inventor, by carrying the regenerative rotary reversing heater, the cold air is heated to the hot air to facilitate the combustion, and the exhaust gas temperature is lowered to 65~75°C, effectively utilizing the waste heat of the fuel and improving the efficiency of the boiler
3个百分点以上。 。 此外, 扩大了煤炭的适用范围, 即可以降低所使用的煤的品位, 进 一步地降低了生产成本。 More than 3 percentage points. . In addition, the scope of application of coal is expanded, that is, the grade of coal used can be lowered, and the production cost is further reduced.
其中, 粉状固体燃料锅炉 1限定有炉膛 11。 第一烟气通路 3的入口端与炉膛 11的 顶部相连通, 且出口端与蓄热式旋转换向加热器 2相连通, 以将炉膛 11内产生的烟气 通入至少成对的蓄热式旋转换向加热器 2的容纳部分中的一个内,并与容纳部分中容纳 的热载体换热。空气通路 4用于将空气至少通入成对的容纳部分中的另一个内, 以使得 容纳部分中容纳的热载体与空气进行换热,经过换热后的空气被供给至炉膛 11的内部。 经过蓄热式旋转换向加热器 2换热后的烟气通过第二烟气通路 101流入 WCFB烟气脱 硫设备 5。 Among them, the powdery solid fuel boiler 1 is defined with a furnace 11. The inlet end of the first flue gas passage 3 communicates with the top of the furnace 11 and the outlet end communicates with the regenerative rotary reversing heater 2 to pass the flue gas generated in the furnace 11 into at least a pair of heat storage. Rotating one of the accommodating portions of the reversing heater 2 and exchanging heat with the heat carrier accommodated in the accommodating portion. The air passage 4 is for introducing at least air into the other of the pair of receiving portions, such that The heat carrier accommodated in the accommodating portion exchanges heat with the air, and the air after the heat exchange is supplied to the inside of the furnace 11. The flue gas after heat exchange by the regenerative rotary reversing heater 2 flows into the WCFB flue gas desulfurization device 5 through the second flue gas passage 101.
在下面的描述中, 以换热器主体 21 逆时针转动, 且烟气沿着中心轴线的右侧通入 换热器主体 21内, 待预热空气沿着中心轴线的左侧通入换热器主体 21为例进行说明。  In the following description, the heat exchanger body 21 is rotated counterclockwise, and the flue gas is introduced into the heat exchanger body 21 along the right side of the central axis, and the preheated air is introduced into the heat exchanger along the left side of the central axis. The main body 21 will be described as an example.
如图 1所示, 粉状固体燃料锅炉 1 内限定出炉膛 11 以用于容纳煤粉, 烟气通道 3 的一端与炉膛 11相通, 其另一端与蓄热式旋转换向加热器 2相通, 以将炉膛 11内产生 的烟气通入蓄热式旋转换向加热器 2的第一容纳部分 211中(例如为图 1中所示的蓄热 式旋转换向加热器 2的右侧) , 蓄热式旋转换向加热器 2的第二容纳部分 212中 (例如 为图 1中所示的蓄热式旋转换向加热器 2的左侧)用于通入待预热空气, 在换热器主体 21处于未旋转状态时, 烟气和第一容纳部分 211 中的热载体换热以使热载体的温度升 高, 热载体吸收热量后, 换热器主体 21逆时针旋转, 第一容纳部分 211旋转到中心轴 线的左侧, 第二容纳部分 212旋转到中心轴线的右侧, 旋转到左侧的第一容纳部分 211 内的热载体与待加热空气进行换热以使带加热空气温度升, 同时, 烟气对旋转到右侧的 第二容纳部分 212内的热载体进行加热。  As shown in FIG. 1, the powdery solid fuel boiler 1 defines a furnace 11 for accommodating pulverized coal, and one end of the flue gas passage 3 communicates with the furnace 11 and the other end thereof communicates with the regenerative rotary reversing heater 2. The flue gas generated in the furnace 11 is introduced into the first accommodating portion 211 of the regenerative rotary reversing heater 2 (for example, the right side of the regenerative rotary reversing heater 2 shown in FIG. 1), The second accommodating portion 212 of the regenerative rotary reversing heater 2 (for example, the left side of the regenerative rotary reversing heater 2 shown in FIG. 1) is used to pass the air to be preheated, in the heat exchange When the main body 21 is in an unrotated state, the flue gas exchanges heat with the heat carrier in the first accommodating portion 211 to raise the temperature of the heat carrier, and after the heat carrier absorbs heat, the heat exchanger main body 21 rotates counterclockwise, the first accommodating The portion 211 is rotated to the left side of the central axis, the second receiving portion 212 is rotated to the right side of the central axis, and the heat carrier rotated into the first receiving portion 211 on the left side exchanges heat with the air to be heated to bring the heated air temperature Lit, at the same time, the smoke is rotating The heat carrier in the second accommodating portion 212 on the right side is heated.
换热器主体 21继续逆时针转动, 此时第一容纳部分 211被旋转回到中心轴线的右 侧, 第二容纳部分 212 被旋转回到中心轴线的左侧, 旋转回左侧的第二容纳部分 212 内的热载体与待加热空气进行热交换,烟气对旋转回右侧的第一容纳部分 211内的热载 体进行加热, 如此循环重复, 以完成对待预热空气的加热。  The heat exchanger body 21 continues to rotate counterclockwise, at which time the first receiving portion 211 is rotated back to the right side of the central axis, the second receiving portion 212 is rotated back to the left side of the central axis, and rotated back to the second accommodation on the left side. The heat carrier in the portion 212 exchanges heat with the air to be heated, and the flue gas heats the heat carrier in the first accommodating portion 211 which is rotated back to the right side, and the cycle is repeated to complete the heating of the preheated air.
在本发明的其中一个示例中, 待预热空气加热到一定温度后可从粉状固体燃料锅炉 In one of the examples of the present invention, the preheated air is heated to a certain temperature and can be obtained from a powdery solid fuel boiler.
1的底部供入炉膛 11内, 从而与煤粉在炉膛 π内进行高温氧化燃烧。 The bottom of 1 is supplied into the furnace 11 to perform high-temperature oxidation combustion with the pulverized coal in the furnace π.
可选地, 煤粉由无烟煤、 贫煤中的至少一种所形成。  Alternatively, the pulverized coal is formed of at least one of anthracite and lean coal.
与待预热空气进行换热后的烟气通过第二烟气通路 101进入 WCFB烟气脱硫设备 5 以进行净化。  The flue gas after heat exchange with the preheated air enters the WCFB flue gas desulfurization apparatus 5 through the second flue gas passage 101 for purification.
根据本发明实施例的粉状固体燃料锅炉及干法净化工艺系统 100, 通过设置蓄热式 旋转换向加热器 2和 WCFB烟气脱硫设备 5,蓄热式旋转换向加热器 2可将高温烟气的 温度大大降低, 从而提高了锅炉系统的效率, 同时在后续烟气净化处理 WCFB烟气脱 硫设备 5中可以省去喷水装置, 既优化了工艺、 节约了成本又降低了腐蚀影响, 同时还 有效解决了喷水后的灰分贴壁等问题。  According to the powdered solid fuel boiler and the dry purification process system 100 of the embodiment of the present invention, the regenerative rotary reversing heater 2 and the WCFB flue gas desulfurization device 5 are provided, and the regenerative rotary reversing heater 2 can set the high temperature. The temperature of the flue gas is greatly reduced, thereby improving the efficiency of the boiler system, and at the same time, the sprinkler device can be omitted in the subsequent flue gas purification treatment WCFB flue gas desulfurization device 5, which not only optimizes the process, saves cost and reduces corrosion effects. At the same time, it also effectively solves the problem of ash adherence after water spray.
可选地, 从第一烟气通路 3的入口端朝向第一烟气通路 3的出口端依次设置有屏式 过热器 6、 包墙过热器 7和过热器。 例如在图 1的示例中, 屏式过热器 6和包墙过热器 7邻近第一烟气通路 3的入口端设置, 且在左右方向上相互间隔开设置, 过热器邻近第 一烟气通路 3的出口端设置。 由此, 通过设置过热器, 可有效提高整个蒸汽动力装置的 循环热效率。  Optionally, a screen superheater 6, a wall superheater 7 and a superheater are disposed in order from the inlet end of the first flue gas passage 3 toward the outlet end of the first flue gas passage 3. For example, in the example of FIG. 1, the screen superheater 6 and the wall superheater 7 are disposed adjacent to the inlet end of the first flue gas passage 3, and are spaced apart from each other in the left-right direction, and the superheater is adjacent to the first flue gas passage 3. The exit side is set. Thus, by providing a superheater, the cycle thermal efficiency of the entire steam power unit can be effectively improved.
进一步地, 在靠近第一烟气通路 3的出口端的第一烟气通路 3内设置有省煤器 9。 例如在图 1的示例中, 省煤器 9设在过热器的下方, 且与过热器在上下方向上间隔开一 定距离。 由此, 通过设置省煤器 9, 可有效吸收烟气的热量, 降低排烟温度, 减少排烟 损失, 从而节省燃料。 Further, an economizer 9 is disposed in the first flue gas passage 3 near the outlet end of the first flue gas passage 3. For example, in the example of FIG. 1, the economizer 9 is disposed below the superheater and is spaced apart from the superheater in the up and down direction. Set the distance. Thus, by providing the economizer 9, the heat of the flue gas can be effectively absorbed, the exhaust gas temperature can be lowered, and the exhaust gas loss can be reduced, thereby saving fuel.
在本发明的一个实施例中, 从第一烟气通路 3进入蓄热式旋转换向加热器 2内的烟 气速度可调节。 由此, 有效地提高了待预热空气的温度。  In one embodiment of the invention, the flue gas velocity entering the regenerative rotary commutation heater 2 from the first flue gas passage 3 is adjustable. Thereby, the temperature of the air to be preheated is effectively increased.
可选地, 热载体为 SiC或者陶瓷, 且具有小球状、 片状或者多孔状的结构。 由此, 蓄热式旋转换向加热器 2可耐高温、 耐腐蚀且耐磨损。  Alternatively, the heat carrier is SiC or ceramic and has a small spherical, sheet-like or porous structure. Thus, the regenerative rotary reversing heater 2 is resistant to high temperatures, corrosion, and wear.
可选地, 经过蓄热式旋转换向加热器 2换热后的烟气的温度为 65-75 °C。 在锅炉排 烟温度必须要喷水降温到 65~75 °C, 这样节省了一道喷水工艺, 同时节能, 避免了喷水 后灰贴壁的不利问题。 由此, 可回收烟气中部分气化潜热, 从而提高了锅炉的热效率, 同时进入后续 WCFB烟气脱硫设备 5的烟气无需喷水降温。  Alternatively, the temperature of the flue gas after heat exchange by the regenerative rotary commutation heater 2 is 65-75 °C. In the boiler exhaust temperature, it is necessary to spray water to cool down to 65~75 °C, which saves a water spray process and saves energy, avoiding the unfavorable problem of ash adherence after water spray. Thereby, part of the latent heat of vaporization in the flue gas can be recovered, thereby improving the thermal efficiency of the boiler, and at the same time, the flue gas entering the subsequent WCFB flue gas desulfurization device 5 does not need to be sprayed and cooled.
可选地, 空气为富氧空气, 且空气经过蓄热式旋转换向加热器 2 换热后被加热至 300-650°C。 由此, 空气提升温度较高。  Alternatively, the air is oxygen-enriched air, and the air is heated to 300-650 ° C after heat exchange through the regenerative rotary commutation heater 2 . As a result, the air lift temperature is higher.
在本发明的一个实施例中, 蓄热式旋转换向加热器 2进一步包括: 冷凝液体移除装 置, 冷凝液体移除装置设置在换热器主体的下方, 以移除换热过程中产生的冷凝液体。  In an embodiment of the present invention, the regenerative rotary reversing heater 2 further includes: a condensed liquid removing device disposed under the heat exchanger body to remove the heat generating process Condensing liquid.
在本发明的一个实施例中, WCFB烟气脱硫设备 5包括: 吸收塔 51、 消石灰仓 52、 除尘器 53以及烟囱 55。 其中, 第二烟气通路 101与吸收塔 51的底部相连通。 消石灰 仓 52设置在吸收塔 51 的上部, 用于将消石灰喷入吸收塔 51。 除尘器 53与吸收塔 51 相连通, 用于对经过消石灰吸收反应后的烟气进行除尘。 经过除尘器 53除尘后的烟气 通过第三烟气通路 102连通至烟肉 55, 第三烟气通路 102上设置有引风机 1021, 以将 烟气引至烟囱 55。 由此, 通过设置吸收塔 51和消石灰仓 52, 烟气可在吸收塔 51中与 消石灰仓 52喷入的消石灰进行吸收反应, 通过设置除尘器 53, 脱硫后的烟气可进入除 尘器 53中进行净化, 最后经由烟肉 55排入大气。  In one embodiment of the invention, the WCFB flue gas desulfurization apparatus 5 comprises: an absorption tower 51, a lime removal compartment 52, a dust collector 53 and a chimney 55. The second flue gas passage 101 communicates with the bottom of the absorption tower 51. A slaked lime tank 52 is disposed at an upper portion of the absorption tower 51 for injecting slaked lime into the absorption tower 51. The dust remover 53 is connected to the absorption tower 51 for dust removal of the flue gas after the slaked lime absorption reaction. The flue gas after the dust removal by the dust remover 53 is communicated to the bacon 55 through the third flue gas passage 102, and the third flue gas passage 102 is provided with an induced draft fan 1021 to guide the flue gas to the chimney 55. Thus, by providing the absorption tower 51 and the slaked lime tank 52, the flue gas can be absorbed and reacted with the slaked lime sprayed from the slaked lime silo 52 in the absorption tower 51. By providing the dust remover 53, the flue gas after desulfurization can enter the dust remover 53. Purification is carried out and finally discharged into the atmosphere via bacon 55.
在图 1的示例中, 第二烟气通路 101的一端与蓄热式旋转换向加热器 2相通, 其另 一端与吸收塔 51的底部相通, 从而将蓄热式旋转换向加热器 2中温度降低的烟气通入 吸收塔 51中,烟气上升到吸收塔 51的上部与消石灰仓 52喷入的消石灰进行吸收反应, 然后进入除尘器 53除尘, 脱硫后的净化烟气离开除尘器 53进入第三烟气通路 102, 第 三烟气通路 102上设有引风机, 最后烟气在引风机 1021的作用下由烟肉 55排入大气。  In the example of FIG. 1, one end of the second flue gas passage 101 communicates with the regenerative rotary reversing heater 2, and the other end thereof communicates with the bottom of the absorption tower 51, thereby regeneratively rotating the reversing heater 2 The temperature-reduced flue gas is introduced into the absorption tower 51, and the flue gas rises to the upper portion of the absorption tower 51 to absorb the slaked lime sprayed from the slaked lime silo 52, and then enters the dust remover 53 for dust removal, and the desulfurized purified flue gas leaves the dust remover 53. The third flue gas passage 102 is entered, and the third flue gas passage 102 is provided with an induced draft fan. Finally, the flue gas is discharged into the atmosphere by the bacon 55 under the action of the induced draft fan 1021.
进一步地, WCFB烟气脱硫设备 5进一步包括: 再循环管 54, 再循环管 54倾斜设 置且用于将除尘器 53底部的消石灰再循环至吸收塔 51 内。 如图 1所示, 再循环管 54 的一端与除尘器 53的底部相通, 其另一端与吸收塔 51相通, 从再循环管 54返回到吸 收塔 51的含消石灰颗粒再次与进入吸收塔 51的低温烟气反应。 由此, 通过多次循环, 有效地提高了消石灰的利用效率, 从而提高了脱硫效率。  Further, the WCFB flue gas desulfurization apparatus 5 further includes: a recirculation pipe 54, a recirculation pipe 54 disposed obliquely and for recycling the slaked lime at the bottom of the precipitator 53 into the absorption tower 51. As shown in Fig. 1, one end of the recirculation pipe 54 communicates with the bottom of the precipitator 53, and the other end thereof communicates with the absorption tower 51, and the slaked granules returned from the recirculation pipe 54 to the absorption tower 51 are again entered into the absorption tower 51. Low temperature flue gas reaction. Thereby, the utilization efficiency of slaked lime is effectively improved by a plurality of cycles, thereby improving the desulfurization efficiency.
在本发明的其中一个示例中, 再循环管 54 的底部还可设有至少一个流化风机 541 以起到顺利返料的作用。 在图 1的示例中示出了两个流化风机 541, 两个流化风机 541 在左右方向上间隔开设置。可以理解的是,流化风机 541的数量可以根据实际要求设置, 以更好地满足实际要求。 更进一步地, 进一步包括: 第四烟气通路 103, 第四烟气通路 103将第三烟气通路 102中的一部分烟气再循环至第二烟气通路 101内。 例如在图 1的示例中, 第四烟气通 路 103的一端与第三烟气通路 102相通且第四烟气通路 103的一端与引风机之后的第三 烟气通路 102相通, 其另一端与第二烟气通路 101相通。 由此, 进一步提高了烟气的净 化率。 In one of the examples of the present invention, at least one fluidizing fan 541 may be provided at the bottom of the recirculation pipe 54 to function as a smooth return. Two fluidizing fans 541 are shown in the example of Fig. 1, and two fluidizing fans 541 are spaced apart in the left-right direction. It can be understood that the number of fluidizing fans 541 can be set according to actual requirements to better meet actual requirements. Further, the method further includes: a fourth flue gas passage 103, and the fourth flue gas passage 103 recirculates a part of the flue gas in the third flue gas passage 102 into the second flue gas passage 101. For example, in the example of FIG. 1, one end of the fourth flue gas passage 103 communicates with the third flue gas passage 102 and one end of the fourth flue gas passage 103 communicates with the third flue gas passage 102 after the induced draft fan, and the other end thereof The second flue gas passage 101 communicates. Thereby, the purification rate of the flue gas is further improved.
综上, 根据本发明的粉状固体燃料锅炉及干法净化工艺系统 100搭载了蓄热式旋转 换向加热器。 根据发明人的计算, 通过搭载蓄热式旋转换向加热器, 将冷风加热到热风 利于燃烧的同时, 将排烟温度降到 65~75°C, 有效的利用了燃料的余热, 并将锅炉的效 率提高 3个百分点以上。 此外, 由于在锅炉排烟温度降低到 65~75 °C的同时, 对尾部的 脱硫工艺需要产生重大变革。 即采用 WCFB干法脱硫工艺, 从而使得尾部不需要喷水 降温, 避免腐蚀问题, 同时节省了一道喷水工艺, 起到节能的作用, 避免了喷水后灰贴 壁的不利问题。  In summary, the powdery solid fuel boiler and the dry purification process system 100 according to the present invention are equipped with a regenerative rotary reversing heater. According to the calculation by the inventor, by carrying a regenerative rotary reversing heater, the cold air is heated to the hot air to facilitate combustion, and the exhaust gas temperature is lowered to 65 to 75 ° C, and the waste heat of the fuel is effectively utilized, and the boiler is used. The efficiency is increased by more than 3 percentage points. In addition, due to the fact that the boiler exhaust gas temperature is lowered to 65-75 °C, the tail desulfurization process needs to undergo major changes. That is to use the WCFB dry desulfurization process, so that the tail does not need to spray water to cool down, avoid corrosion problems, and save a water spray process, which can save energy and avoid the unfavorable problem of gray plastering after water spray.
在本说明书的描述中, 参考术语 "一个实施例"、 "一些实施例"、 "示意性实施例"、 "示 例"、 "具体示例"、 或 "一些示例"等的描述意指结合该实施例或示例描述的具体特征、 结 构、 材料或者特点包含于本发明的至少一个实施例或示例中。 在本说明书中, 对上述术语 的示意性表述不一定指的是相同的实施例或示例。 而且, 描述的具体特征、 结构、 材料或 者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。  In the description of the present specification, the description of the terms "one embodiment", "some embodiments", "illustrative embodiment", "example", "specific example", or "some examples", etc. Particular features, structures, materials or features described in the examples or examples are included in at least one embodiment or example of the invention. In the present specification, the schematic representation of the above terms does not necessarily mean the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in a suitable manner in any one or more embodiments or examples.
尽管已经示出和描述了本发明的实施例, 本领域的普通技术人员可以理解: 在不脱 离本发明的原理和宗旨的情况下可以对这些实施例进行多种变化、 修改、 替换和变型, 本发明的范围由权利要求及其等同物限定。  While the embodiments of the present invention have been shown and described, the embodiments of the invention may The scope of the invention is defined by the claims and their equivalents.

Claims

权利要求书 Claim
1、 一种粉状固体燃料锅炉及干法净化工艺系统, 其特征在于, 包括: A powdery solid fuel boiler and a dry purification process system, characterized in that it comprises:
粉状固体燃料锅炉, 所述粉状固体燃料锅炉限定有炉膛;  a powdery solid fuel boiler, the powdered solid fuel boiler is defined with a furnace;
蓄热式旋转换向加热器, 所述蓄热式旋转换向加热器包括:  a regenerative rotary reversing heater, the regenerative rotary reversing heater comprising:
换热器主体;  Heat exchanger body;
驱动装置, 所述驱动装置用于驱动所述换热器主体绕其中心轴线旋转; 分隔件, 所述分隔件沿着所述中心轴线的方向设置在所述换热器主体内, 且将 所述换热器主体分隔成至少一对容纳部分,所述每对容纳部分相对所述中心轴线成径向 相对设置;  a driving device, the driving device is configured to drive the heat exchanger body to rotate about a central axis thereof; a partitioning member, the partitioning member is disposed in the heat exchanger body along a direction of the central axis, and The heat exchanger body is partitioned into at least one pair of receiving portions, the pair of receiving portions being disposed diametrically opposite to the central axis;
热载体, 所述热载体分别容纳在所述容纳部分中, 所述热载体由非金属固体材 料所形成;  a heat carrier, the heat carrier being respectively accommodated in the accommodating portion, the heat carrier being formed of a non-metallic solid material;
第一烟气通路, 所述第一烟气通路的入口端与所述炉膛的顶部相连通, 且出口端与 所述蓄热式旋转换向加热器相连通,以将炉膛内产生的烟气通入至少所述成对的所述容 纳部分中的一个内并与其中容纳的所述热载体换热;  a first flue gas passage, an inlet end of the first flue gas passage is in communication with a top of the furnace, and an outlet end is connected to the regenerative rotary reversing heater to generate flue gas generated in the furnace Passing into at least one of the pair of the receiving portions and exchanging heat with the heat carrier housed therein;
空气通路, 所述空气通路用于将空气至少通入所述成对的所述容纳部分中的另一个 内, 以使得其中容纳的所述热载体与所述空气进行换热; 以及  An air passage for introducing at least air into the other of the pair of the receiving portions to allow the heat carrier accommodated therein to exchange heat with the air;
WCFB烟气脱硫设备, 经过所述蓄热式旋转换向加热器换热后的烟气通过第二烟气 通路流入所述 WCFB烟气脱硫设备。  The WCFB flue gas desulfurization device, the flue gas after heat exchange by the regenerative rotary reversing heater flows into the WCFB flue gas desulfurization device through the second flue gas passage.
2、 根据权利要求 1 所述的粉状固体燃料锅炉及干法净化工艺系统, 其特征在于, 所述煤粉由无烟煤、 贫煤中的至少一种所形成。  2. The powdery solid fuel boiler and dry purification process system according to claim 1, wherein the pulverized coal is formed of at least one of anthracite and lean coal.
3、 根据权利要求 1 所述的粉状固体燃料锅炉及干法净化工艺系统, 其特征在于, 从所述第一烟气通路的所述入口端朝向所述第一烟气通路的所述出口端依次设置有屏 式过热器、 包墙过热器和过热器。  3. The powdered solid fuel boiler and dry purification process system according to claim 1, wherein the outlet from the first flue gas passage faces the outlet of the first flue gas passage The screen is provided with a screen superheater, a wall superheater and a superheater in sequence.
4、 根据权利要求 3 所述的粉状固体燃料锅炉设备, 其特征在于, 在靠近所述第一 烟气通路的所述出口端的所述第一烟气通路内设置有省煤器。  A powdery solid fuel boiler apparatus according to claim 3, wherein an economizer is disposed in said first flue gas passage adjacent said outlet end of said first flue gas passage.
5、 根据权利要求 1 所述的粉状固体燃料锅炉及干法净化工艺系统, 其特征在于, 从所述第一烟气通路进入所述蓄热式旋转换向加热器内的烟气速度可调节。  The powdery solid fuel boiler and the dry purification process system according to claim 1, wherein the flue gas velocity entering the regenerative rotary reversing heater from the first flue gas passage is Adjustment.
6、 根据权利要求 1 所述的粉状固体燃料锅炉及干法净化工艺系统, 其特征在于, 所述热载体为 SiC或者陶瓷。  The powdery solid fuel boiler and dry purification process system according to claim 1, wherein the heat carrier is SiC or ceramic.
7、 根据权利要求 1 所述的粉状固体燃料锅炉及干法净化工艺系统, 其特征在于, 经过所述蓄热式旋转换向加热器换热后的烟气的温度为 65-75 °C。  7. The powdery solid fuel boiler and dry purification process system according to claim 1, wherein the temperature of the flue gas after heat exchange by the regenerative rotary commutation heater is 65-75 ° C .
8、 根据权利要求 1 所述的粉状固体燃料锅炉及干法净化工艺系统, 其特征在于, 所述空气为富氧空气, 且所述空气经过所述蓄热式旋转换向加热器换热后被加热至 300-650°C。 9、 根据权利要求 1 所述的粉状固体燃料锅炉及干法净化工艺系统, 其特征在于, 所述蓄热式旋转换向加热器进一步包括: 8. The powdery solid fuel boiler and dry purification process system according to claim 1, wherein the air is oxygen-enriched air, and the air passes through the regenerative rotary commutation heater for heat exchange. It is then heated to 300-650 °C. The pulverized solid fuel boiler and the dry cleaning process system according to claim 1, wherein the regenerative rotary reversing heater further comprises:
冷凝液体移除装置, 所述冷凝液体移除装置设置在所述换热器主体的下方, 以移除 换热过程中产生的冷凝液体。  A condensed liquid removal device is disposed below the heat exchanger body to remove condensed liquid generated during heat exchange.
10、 根据权利要求 1所述的粉状固体燃料锅炉及干法净化工艺系统, 其特征在于, 所述 WCFB烟气脱硫设备包括:  The powdery solid fuel boiler and the dry purification process system according to claim 1, wherein the WCFB flue gas desulfurization device comprises:
吸收塔, 所述第二烟气通路与所述吸收塔的底部相连通;  An absorption tower, wherein the second flue gas passage is in communication with a bottom of the absorption tower;
消石灰仓,所述消石灰仓设置在所述吸收塔的上部,用于将消石灰喷入所述吸收塔; 除尘器, 所述除尘器与所述吸收塔相连通, 用于对经过消石灰吸收反应后的烟气进 行除尘; 以及  a slaked lime silo, wherein the slaked lime silo is disposed at an upper portion of the absorption tower for injecting slaked lime into the absorption tower; and the dust remover is connected to the absorption tower for use in absorbing the slaked lime Flue gas for dust removal;
烟囱, 经过所述除尘器除尘后的烟气通过第三烟气通路连通至所述烟肉, 所述第三 烟气通路上设置有引风机, 以将所述烟气引至所述烟囱。  The chimney, the flue gas after being dusted by the dust collector is connected to the bacon through a third flue gas passage, and the third flue gas passage is provided with an induced draft fan to introduce the flue gas to the chimney.
11、 根据权利要求 10所述的粉状固体燃料锅炉及干法净化工艺系统, 其特征在于, 所述 WCFB烟气脱硫设备进一步包括:  The powdery solid fuel boiler and the dry purification process system according to claim 10, wherein the WCFB flue gas desulfurization apparatus further comprises:
再循环管, 所述再循环管倾斜设置且用于将所述除尘器底部的消石灰再循环至所述 吸收塔内。  A recirculation pipe, the recirculation pipe being disposed obliquely and for recycling slaked lime at the bottom of the precipitator into the absorption tower.
12、 根据权利要求 11所述的粉状固体燃料锅炉及干法净化工艺系统, 其特征在于, 进一步包括:  The powdery solid fuel boiler and the dry purification process system according to claim 11, further comprising:
第四烟气通路, 所述第四烟气通路将所述第三烟气通路中的一部分烟气再循环至所 述第二烟气通路内。  a fourth flue gas passage, the fourth flue gas passage recirculating a portion of the flue gas in the third flue gas passage into the second flue gas passage.
PCT/CN2013/075699 2013-01-18 2013-05-16 Powdered solid fuel boiler and dry purification process system WO2014110884A1 (en)

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