WO2013185149A1 - Method for converting a hydrocarbonaceous material to a fluid hydrocarbon product comprising p-xylene - Google Patents

Method for converting a hydrocarbonaceous material to a fluid hydrocarbon product comprising p-xylene Download PDF

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Publication number
WO2013185149A1
WO2013185149A1 PCT/US2013/046077 US2013046077W WO2013185149A1 WO 2013185149 A1 WO2013185149 A1 WO 2013185149A1 US 2013046077 W US2013046077 W US 2013046077W WO 2013185149 A1 WO2013185149 A1 WO 2013185149A1
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WO
WIPO (PCT)
Prior art keywords
reactor
catalyst
method
seconds
preceding
Prior art date
Application number
PCT/US2013/046077
Other languages
English (en)
French (fr)
Inventor
George W. Huber
Yu-Ting Cheng
Zhuopeng Wang
Wei Fan
Original Assignee
University Of Massachusetts
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US201261655605P priority Critical
Priority to US61/655,605 priority
Priority to US13/628,258 priority
Priority to US13/628,258 priority patent/US20130324772A1/en
Application filed by University Of Massachusetts filed Critical University Of Massachusetts
Priority claimed from JP2015516286A external-priority patent/JP2015519377A/ja
Publication of WO2013185149A1 publication Critical patent/WO2013185149A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/14After treatment, characterised by the effect to be obtained to alter the inside of the molecular sieve channels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/32Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30Aromatics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels
    • Y02E50/14Bio-pyrolysis
PCT/US2013/046077 2012-06-05 2013-06-17 Method for converting a hydrocarbonaceous material to a fluid hydrocarbon product comprising p-xylene WO2013185149A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US201261655605P true 2012-06-05 2012-06-05
US61/655,605 2012-06-05
US13/628,258 2012-09-27
US13/628,258 US20130324772A1 (en) 2012-06-05 2012-09-27 Method for converting a hydrocarbonaceous material to a fluid hydrocarbon product comprising p-xylene

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
BR112014030260A BR112014030260A2 (pt) 2012-06-05 2013-06-17 método para converter um material hidrocarbonáceo em um produto de hidrocarboneto fluido que compreende p-xileno
EP20130742297 EP2855404A1 (en) 2012-06-05 2013-06-17 Method for converting a hydrocarbonaceous material to a fluid hydrocarbon product comprising p-xylene
KR20157000180A KR20150045995A (ko) 2012-06-05 2013-06-17 탄화수소성 물질을 p-자일렌을 포함하는 유체 탄화수소 생성물로 전환하는 방법
CA2875668A CA2875668A1 (en) 2012-06-05 2013-06-17 Method for converting a hydrocarbonaceous material to a fluid hydrocarbon product comprising p-xylene
JP2015516286A JP2015519377A (ja) 2012-09-27 2013-06-17 炭化水素系材料をp−キシレンを含んで成る流動性炭化水素生成物に転化するための方法

Publications (1)

Publication Number Publication Date
WO2013185149A1 true WO2013185149A1 (en) 2013-12-12

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/046077 WO2013185149A1 (en) 2012-06-05 2013-06-17 Method for converting a hydrocarbonaceous material to a fluid hydrocarbon product comprising p-xylene

Country Status (6)

Country Link
US (1) US20130324772A1 (tr)
EP (1) EP2855404A1 (tr)
KR (1) KR20150045995A (tr)
BR (1) BR112014030260A2 (tr)
CA (1) CA2875668A1 (tr)
WO (1) WO2013185149A1 (tr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015089442A1 (en) * 2013-12-14 2015-06-18 Anellotech, Inc. Catalysts and processes for producing p-xylene from biomass

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9249080B2 (en) 2012-10-17 2016-02-02 Anellotech, Inc. Chemical intermediates by catalytic fast pyrolysis process
US20150307418A1 (en) * 2014-04-23 2015-10-29 Uop Llc Methods and apparatuses for producing xylene from lignin
EP3197984A2 (en) * 2014-09-22 2017-08-02 Huntsman International LLC Process for the preparation of aromatic compounds
AU2015343509A1 (en) 2014-11-03 2017-04-27 Anellotech, Inc. Improved process for recovering carbon monoxide from catalytic fast pyrolysis product
EP3240868B1 (en) * 2014-12-29 2019-06-19 Shell International Research Maatschappij B.V. Process for production of aromatics via pyrolysis of lignin-comprising material
KR101600430B1 (ko) 2015-01-08 2016-03-07 한국화학연구원 이산화탄소가 풍부한 합성가스로부터 단환 방향족 화합물 및 장쇄올레핀 화합물의 직접 합성방법
US20160304788A1 (en) * 2015-04-16 2016-10-20 Anellotech, Inc. Biomass-derived chemical intermediates
US10000703B2 (en) * 2015-05-08 2018-06-19 Anellotech, Inc. Catalytic fast pyrolysis process
ES2618857B1 (es) * 2015-12-21 2018-07-27 Neoliquid Advanced Biofuels And Biochemicals, S.L. Procedimiento termoquímico, e instalación, para transformar materiales poliméricos
KR101725178B1 (ko) * 2016-03-25 2017-04-10 서울시립대학교 산학협력단 2단계 촉매 열분해를 통한 리그닌으로부터 바이오 오일의 생산

Citations (5)

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US4090981A (en) 1976-09-23 1978-05-23 Mobile Oil Corporation Catalyst for selective production of para dialkyl substituted benzenes
US5243117A (en) 1990-06-05 1993-09-07 Mobil Oil Corp. Catalyst and process for the selective production of para-dialkyl substituted benzenes
US5403800A (en) 1993-05-28 1995-04-04 Mobil Oil Corp. Multiple impregnation technique for the preparation of ex situ selectivated zeolite catalysts
US5659098A (en) 1993-05-28 1997-08-19 Beck; Jeffrey S. High conversion touluene disproportionation with ex situ selectivated zeolite catalysts
WO2009110402A1 (ja) * 2008-03-03 2009-09-11 東レ株式会社 パラキシレンの製造方法

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US4002697A (en) * 1973-12-03 1977-01-11 Mobil Oil Corporation Selective production of para-xylene

Patent Citations (5)

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US4090981A (en) 1976-09-23 1978-05-23 Mobile Oil Corporation Catalyst for selective production of para dialkyl substituted benzenes
US5243117A (en) 1990-06-05 1993-09-07 Mobil Oil Corp. Catalyst and process for the selective production of para-dialkyl substituted benzenes
US5403800A (en) 1993-05-28 1995-04-04 Mobil Oil Corp. Multiple impregnation technique for the preparation of ex situ selectivated zeolite catalysts
US5659098A (en) 1993-05-28 1997-08-19 Beck; Jeffrey S. High conversion touluene disproportionation with ex situ selectivated zeolite catalysts
WO2009110402A1 (ja) * 2008-03-03 2009-09-11 東レ株式会社 パラキシレンの製造方法

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"Kirk-Othmer Encyclopedia of Chemical Technology", vol. 11, 2001, WILEY INTERSCIENCE, pages: 791 - 825
"Kirk-Othmer Encyclopedia of Chemical Technology", vol. 5, 2001, WILEY-INTERSCIENCE, pages: 255 - 322
"Perry's Chemical Engineers'Handbook", 2008, MCGRAW-HILL, article "Heat Transfer Equipment"
C. D. COOPER; F. C. ALLEY: "Prospect Heights", 1994, WAVELAND PRESS, INC., article "Air Pollution Control, A Design Approach", pages: 127 - 149, XP009056164
COOK, M.; CONNCR, W. C.: "How big arc the pores of zcolitcs?", PROCEEDINGS OF THE INTERNATIONAL ZEOLITE CONFERENCE, 12TH, vol. 1, 5 July 1999 (1999-07-05), pages 409 - 414
COOK, M.; CONNER, W. C.: "How big are the pores of zeolites?", PROCEEDINGS OF THE INTERNATIONAL ZEOLITE CONFERENCE, 12TH, vol. 1, 5 July 1998 (1998-07-05), pages 409 - 414
GREGG, S. J.: "Adsorption, Surface Area and Porosity", 1982, ACADEMIC PRESS INC.
MAGEE, J.S. ET AL.: "Fluid Catalytic Cracking: Science and Technology", 1 July 1993, ELSEVIER PUBLISHING COMPANY, pages: 185 - 195
MAGEE, J.S.: "Fluid Catalytic Cracking: Science and Technology", 1 July 1993, ELSEVIER PUBLISHING COMPANY, pages: 185 - 195
PECHARSKY, V.K. ET AL.: "Fundamentals of Powder Diffraction and Structural Characterization of Materials", 2005, SPRINGER SCIENCE+BUSINESS MEDIA, INC.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015089442A1 (en) * 2013-12-14 2015-06-18 Anellotech, Inc. Catalysts and processes for producing p-xylene from biomass

Also Published As

Publication number Publication date
US20130324772A1 (en) 2013-12-05
CA2875668A1 (en) 2013-12-12
BR112014030260A2 (pt) 2017-09-12
KR20150045995A (ko) 2015-04-29
EP2855404A1 (en) 2015-04-08

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