WO2013135776A1 - Ruthenium-based metathesis catalysts and precursors for their preparation - Google Patents
Ruthenium-based metathesis catalysts and precursors for their preparation Download PDFInfo
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- WO2013135776A1 WO2013135776A1 PCT/EP2013/055160 EP2013055160W WO2013135776A1 WO 2013135776 A1 WO2013135776 A1 WO 2013135776A1 EP 2013055160 W EP2013055160 W EP 2013055160W WO 2013135776 A1 WO2013135776 A1 WO 2013135776A1
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0046—Ruthenium compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/54—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/54—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings
- C07C211/55—Diphenylamines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/20—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/46—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with hetero atoms directly attached to the ring nitrogen atom
- C07D207/48—Sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
- C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/40—Polymerisation processes
- C08G2261/41—Organometallic coupling reactions
- C08G2261/418—Ring opening metathesis polymerisation [ROMP]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/40—Polymerisation processes
- C08G2261/41—Organometallic coupling reactions
- C08G2261/419—Acyclic diene metathesis [ADMET]
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/385,100 US9108996B2 (en) | 2012-03-14 | 2013-03-13 | Ruthenium-based metathesis catalysts and precursors for their preparation |
EP13716968.6A EP2825522A1 (en) | 2012-03-14 | 2013-03-13 | Ruthenium-based metathesis catalysts and precursors for their preparation |
CN201380013530.3A CN104220418B (en) | 2012-03-14 | 2013-03-13 | Ruthenio metathesis catalyst and for its precursor prepared |
JP2014561439A JP6239535B2 (en) | 2012-03-14 | 2013-03-13 | Ruthenium-based metathesis catalysts and precursors for their production |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12159506.0A EP2639219B1 (en) | 2012-03-14 | 2012-03-14 | Ruthenium-based metathesis catalysts and precursors for their preparation |
EP12159506.0 | 2012-03-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2013135776A1 true WO2013135776A1 (en) | 2013-09-19 |
Family
ID=48139883
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2013/055160 WO2013135776A1 (en) | 2012-03-14 | 2013-03-13 | Ruthenium-based metathesis catalysts and precursors for their preparation |
Country Status (5)
Country | Link |
---|---|
US (1) | US9108996B2 (en) |
EP (2) | EP2639219B1 (en) |
JP (1) | JP6239535B2 (en) |
CN (1) | CN104220418B (en) |
WO (1) | WO2013135776A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017087846A1 (en) | 2015-11-18 | 2017-05-26 | Provivi, Inc. | Microorganisms for the production of insect pheromones and related compounds |
WO2017087710A2 (en) | 2015-11-18 | 2017-05-26 | Provivi, Inc. | Production of fatty olefin derivatives via olefin metathesis |
WO2018213554A1 (en) | 2017-05-17 | 2018-11-22 | Provivi, Inc. | Microorganisms for the production of insect pheromones and related compounds |
US11214818B2 (en) | 2016-06-06 | 2022-01-04 | Provivi, Inc. | Semi-biosynthetic production of fatty alcohols and fatty aldehydes |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113307830A (en) * | 2015-09-24 | 2021-08-27 | 优美科股份公司及两合公司 | Metal carbene olefin metathesis catalysts |
EP3219778A1 (en) * | 2016-03-15 | 2017-09-20 | Umicore AG & Co. KG | Biofuel and method for preparation by isomerizing metathesis |
KR20220007827A (en) * | 2020-07-10 | 2022-01-19 | 삼성디스플레이 주식회사 | Purifying method for light emitting device material and light emitting device with the material |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2011091980A1 (en) | 2010-01-29 | 2011-08-04 | Umicore Ag & Co. Kg | Process for preparation of ruthenium-based carbene catalysts with chelating alkylidene ligands |
Family Cites Families (10)
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US7329758B1 (en) | 1999-05-24 | 2008-02-12 | California Institute Of Technology | Imidazolidine-based metal carbene metathesis catalysts |
JP3943015B2 (en) * | 2000-08-10 | 2007-07-11 | トラスティーズ オブ ボストン カレッジ | Recyclable metathesis catalyst |
WO2003044060A2 (en) | 2001-11-15 | 2003-05-30 | Materia, Inc. | Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts |
PL199412B1 (en) * | 2002-10-15 | 2008-09-30 | Boehringer Ingelheim Int | Ruthenium new complexes as (pre) catalytic agents of permutation reaction, new derivatives of 2-alkoxy-5-nitrostyrene as intermediate compounds and method of their receiving |
JP2007530706A (en) * | 2004-03-29 | 2007-11-01 | カリフォルニア インスティテュート オブ テクノロジー | Highly active latent olefin metathesis catalyst containing N-heterocyclic carbene ligand |
WO2008000644A1 (en) * | 2006-06-30 | 2008-01-03 | F. Hoffmann-La Roche Ag | New ruthenium complexes as catalysts for metahesis reactions |
DE102007039526A1 (en) * | 2007-08-21 | 2009-02-26 | Lanxess Deutschland Gmbh | Catalyst systems and their use for metathesis reactions |
EP2143489A1 (en) * | 2008-07-08 | 2010-01-13 | Lanxess Deutschland GmbH | Catalyst systems and their use in metathesis reactions |
WO2011079439A1 (en) | 2009-12-30 | 2011-07-07 | Zannan Scitech Co., Ltd. | Highly active metathesis catalysts selective for romp and rcm reactions |
WO2013056463A1 (en) * | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
-
2012
- 2012-03-14 EP EP12159506.0A patent/EP2639219B1/en active Active
-
2013
- 2013-03-13 EP EP13716968.6A patent/EP2825522A1/en not_active Withdrawn
- 2013-03-13 CN CN201380013530.3A patent/CN104220418B/en active Active
- 2013-03-13 US US14/385,100 patent/US9108996B2/en active Active
- 2013-03-13 JP JP2014561439A patent/JP6239535B2/en active Active
- 2013-03-13 WO PCT/EP2013/055160 patent/WO2013135776A1/en active Application Filing
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011091980A1 (en) | 2010-01-29 | 2011-08-04 | Umicore Ag & Co. Kg | Process for preparation of ruthenium-based carbene catalysts with chelating alkylidene ligands |
Non-Patent Citations (8)
Title |
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DIESENDRUCK, C. E.; TZUR, E.; BEN-ASULY, A.; GOLDBERG, I.; STRAUB, B. F.; LEMCOFF, N. G., INORG. CHEM., vol. 48, 2009, pages 10819 - 10825 |
MERVYN K. COOPER, DARRYL W. YANIUK: "Preparation and characterization of chelating monoolefin-aniline ligands and their platinum(II)complexes", J. ORGANOMETALLIC CHEM., vol. 221, 1981, pages 231 - 247, XP002681926 * |
SLUGOVC, C.; BUTSCHER, D.; STELZER, F.; MEREITER, K., ORGANOMETALLICS, vol. 24, 2005, pages 2255 - 2258 |
SZADKOWSKA, A.; GSTREIN, X.; BURTSCHER, D.; JARZEMBSKA, K.; WOZNIAK, K.; SLUGOVC, C.; GRELA, K., ORGANOMETALLICS, vol. 29, 2010, pages 117 - 124 |
TZUR, E.; SZADKOWSKA, A.; BEN-ASULY, A.; MAKAL, A.; GOLDBERG, I.; WOZNIAK, K.; GRELA, K.; LEMCOFF, N. G., CHEM. EUR. J., vol. 16, 2010, pages 8726 - 8737 |
VORFALT, T.; WANNOWIUS, K. J.; PLENIO, H., ANGEW. CHEM., INT. ED., vol. 49, 2010, pages 5533 - 5536 |
ZUKOWSKA, K.; SZADKOWSKA, A.; PAZIO, A. E.; WOZNIAK, K.; GRELA, K., ORGANOMETALLICS, vol. 31, 2012, pages 462 - 469 |
ZUKOWSKA, K.; SZADKOWSKA, A.; PAZIO, A. E.; WOZNIAK, K.; GRELA, K.: "Thermal Switchability of N-Chelating Hoveyda-type Catalyst Containing a Decondary Amine Ligand", ORGANOMETALLICS, vol. 31, 9 January 2012 (2012-01-09), pages 462 - 469, XP002681927 * |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017087846A1 (en) | 2015-11-18 | 2017-05-26 | Provivi, Inc. | Microorganisms for the production of insect pheromones and related compounds |
WO2017087710A2 (en) | 2015-11-18 | 2017-05-26 | Provivi, Inc. | Production of fatty olefin derivatives via olefin metathesis |
US10308962B1 (en) | 2015-11-18 | 2019-06-04 | Provivi, Inc. | Microorganisms for the production of insect pheromones and related compounds |
EP3868890A1 (en) | 2015-11-18 | 2021-08-25 | Provivi, Inc. | Microorganisms for the production of insect pheromones and related compounds |
US11109596B2 (en) | 2015-11-18 | 2021-09-07 | Provivi, Inc. | Microorganisms for the production of insect pheromones and related compounds |
EP4234522A2 (en) | 2015-11-18 | 2023-08-30 | Provivi, Inc. | Production of fatty olefin derivatives via olefin metathesis |
US11844353B2 (en) | 2015-11-18 | 2023-12-19 | Provivi, Inc. | Microorganisms for the production of insect pheromones and related compounds |
US11214818B2 (en) | 2016-06-06 | 2022-01-04 | Provivi, Inc. | Semi-biosynthetic production of fatty alcohols and fatty aldehydes |
WO2018213554A1 (en) | 2017-05-17 | 2018-11-22 | Provivi, Inc. | Microorganisms for the production of insect pheromones and related compounds |
US11104921B2 (en) | 2017-05-17 | 2021-08-31 | Provivi, Inc. | Microorganisms for the production of insect pheromones and related compounds |
US11866760B2 (en) | 2017-05-17 | 2024-01-09 | Provivi, Inc. | Microorganisms for the production of insect pheromones and related compounds |
Also Published As
Publication number | Publication date |
---|---|
US9108996B2 (en) | 2015-08-18 |
US20150045558A1 (en) | 2015-02-12 |
EP2639219B1 (en) | 2016-08-10 |
EP2639219A1 (en) | 2013-09-18 |
EP2825522A1 (en) | 2015-01-21 |
CN104220418A (en) | 2014-12-17 |
JP6239535B2 (en) | 2017-11-29 |
CN104220418B (en) | 2016-08-17 |
JP2015516868A (en) | 2015-06-18 |
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