WO2013135642A1 - Method for manufacturing of supplementary cementitious materials (scms) - Google Patents

Method for manufacturing of supplementary cementitious materials (scms) Download PDF

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Publication number
WO2013135642A1
WO2013135642A1 PCT/EP2013/054907 EP2013054907W WO2013135642A1 WO 2013135642 A1 WO2013135642 A1 WO 2013135642A1 EP 2013054907 W EP2013054907 W EP 2013054907W WO 2013135642 A1 WO2013135642 A1 WO 2013135642A1
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WO
WIPO (PCT)
Prior art keywords
pozzolan
grinding
portland cement
mortar
pozzolans
Prior art date
Application number
PCT/EP2013/054907
Other languages
French (fr)
Inventor
Vladimir Ronin
Original Assignee
Procedo Enterprises Etablissement
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BR112014022661-0A priority Critical patent/BR112014022661B1/en
Priority to RS20160922A priority patent/RS55368B1/en
Priority to CA2903079A priority patent/CA2903079C/en
Priority to DK13712710.6T priority patent/DK2828217T3/en
Priority to AP2014007995A priority patent/AP2014007995A0/en
Priority to MEP-2016-248A priority patent/ME02542B/en
Priority to KR1020147027738A priority patent/KR102028229B1/en
Priority to SG11201405668WA priority patent/SG11201405668WA/en
Priority to JP2014561404A priority patent/JP6175081B2/en
Priority to EP13712710.6A priority patent/EP2828217B1/en
Application filed by Procedo Enterprises Etablissement filed Critical Procedo Enterprises Etablissement
Priority to CN201380013744.0A priority patent/CN104271528A/en
Priority to MX2014010815A priority patent/MX349905B/en
Priority to ES13712710.6T priority patent/ES2601230T3/en
Priority to SI201330353A priority patent/SI2828217T1/en
Priority to LTEP13712710.6T priority patent/LT2828217T/en
Publication of WO2013135642A1 publication Critical patent/WO2013135642A1/en
Priority to ZA2014/06618A priority patent/ZA201406618B/en
Priority to PH12014502028A priority patent/PH12014502028B1/en
Priority to IN7979DEN2014 priority patent/IN2014DN07979A/en
Priority to HRP20161432TT priority patent/HRP20161432T1/en
Priority to CY20161101114T priority patent/CY1118178T1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/06—Quartz; Sand
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/08—Diatomaceous earth
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/14—Minerals of vulcanic origin
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04—Waste materials; Refuse
    • C04B18/06—Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/08—Flue dust, i.e. fly ash
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/0076—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials characterised by the grain distribution
    • C04B20/008—Micro- or nanosized fillers, e.g. micronised fillers with particle size smaller than that of the hydraulic binder
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02—Treatment
    • C04B20/026—Comminuting, e.g. by grinding or breaking; Defibrillating fibres other than asbestos
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04—Portland cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00—Hydraulic cements
    • C04B7/12—Natural pozzuolanas; Natural pozzuolana cements; Artificial pozzuolanas or artificial pozzuolana cements other than those obtained from waste or combustion residues, e.g. burned clay; Treating inorganic materials to improve their pozzuolanic characteristics
    • C04B7/13—Mixtures thereof with inorganic cementitious materials, e.g. Portland cements
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

Definitions

  • the present invention relates to a method for manufacturing of supplementary cementitious materials (SCMs), i.e
  • Fly ash is a supplementary cementitious material, which is useful for production of concretes, mortars and other mix ⁇ tures comprising cement. Fly ash is a by-product of coal burning power plants and is produced worldwide in large quan ⁇ tities each year.
  • Fly ash usually contains about 85% glassy, amorphous compo ⁇ nents in the form of cenosphere particles. According to ASTM C 618 fly ash is classified in two classes, Class C and Class F.
  • the Class F fly ash typically contains more than 70% by weight of silica, alumina, and ferric oxides, while Class C typically contains between 70% and 50%.
  • Class F is produced as a by product of the combustion of bituminous coal.
  • Class C fly ash has a higher calcium content and is produced as a by ⁇ product of the combustion of sub-bituminous coal.
  • Serious problems are also related to the stability of fly ash performance.
  • Natural pozzolans belong to materials of volcanic origin and sedimentary origin, such as diatomaceous earth. According to ASTM C 618 they are designated Class N pozzolans. The natural pozzolans are described in ACI 232.1R-00 as "Raw or
  • calcinated natural pozzolans that comply with the applicable requirements for the class herein, such as some diatomaceous earth; opaline chert and shales; tuffs and volcanic ashes or pumicites, any of which may or may not be processed calcina ⁇ tions; and various materials requiring calcination to induce satisfactory properties, such as some clays or shales.”
  • the microstructure of natural pozzolan particles is charac ⁇ terized by high porosity, which significantly increases water demand of concrete mixes containing natural pozzolans to achieve required flowability/workability of the concrete.
  • increases in water demand lead to unsatisfactory compressive strength development.
  • Chemically active miner ⁇ als usually contain amorphous materials (e.g. amorphous sili ⁇ con dioxide) , which react with calcium hydroxide released during Portland cement hydration (pozzolanic reaction) and form calcium-silicate-hydrate gel [C-H-S gel] - a product similar to the resulting product of Portland cement hydra ⁇ tion.
  • amorphous materials e.g. amorphous sili ⁇ con dioxide
  • the present invention solves the problem of using natural pozzolans in concrete.
  • the present invention thus refers to a method for manufactur ⁇ ing of supplementary cementitious materials for replacement of Portland cement in production of mortars and concretes, where the cementitious materials comprises natural pozzolans in the form of rocks and ashes and sedimentary origin, such as diatomaceous earth.
  • the invention is characterized in, that the said pozzolans in crushed state are subjected to a high energetic mechanical processing by means of grinding in a grinding equipment, whereby the pozzolan particles receive mechanical impulses, and in that the grinding is carried out for a predetermined time resulting in a compressive strength of a 2 inch side cube of mortar comprising 80 % Portland cement and 20 % natural pozzolan in a ratio of 1:2.75 to standard sand and in addition water required to obtain a flow of the mortar according to American standard ASTM C 109, which has been properly compacted under vibration and hardened at + 20 °C in sealed condition, which after 28 days is ⁇ 75 % of the compressive strength of a 2 inch side cube, treated as said cube, of a mortar comprising a ratio of Portland cement: sand of 1:2.75 and in addition water corresponding to 48.5 % of the weight of Portland cement.
  • the invention refers to a method for manufacturing of supple ⁇ mentary cementitious materials for replacement of Portland cement in production of mortars and concretes, where the cementitious materials comprises natural pozzolans in the form of rocks and ashes of volcanic origin and sedimentary origin, such as diatomaceous earth.
  • the said pozzolans in a crushed state are subjected to a high energetic mechanical processing by means of grinding in a grinding equipment, whereby the pozzolan particles receive mechanical impulses.
  • the grinding leads to modification of its surface properties in the form of surface porosity reduction and improvement of its chemical reactivity with alkaline medium produced by hydrating cement. It has been observed that the treatment of the pozzolan particles gives that there occurs local melting of the surface of the particals, whereby zones with a high degree of amorphization are created. By this treatment it has shown that natural pozzolans show a surprisingly good effect when the so treated natural pozzolans replace Some of the amount of Portland cement in a cement paste, mortar and con ⁇ crete comprising Portland cement, pozzolans, sand and water.
  • the grinding is carried out for a predetermined time resulting in a compressive strength of a 2 inch side cube of mortar comprising 80 % Portland cement and 20 % natural pozzolan in a ratio of 1:2.75 to standard sand and in addition water required to obtain a flow of the mortar according to American standard ASTM C 109, which has been properly compacted under vibration and hardened at + 20 °C in sealed condition, which after 28 days is ⁇ 75 % of the compressive strength of a 2 inch side cube, treated as said cube, of a mortar comprising a ratio of Portland cement: sand of 1:2.75 and in addition water corre ⁇ sponding to 48.5 % of the weight of Portland cement.
  • the amount of water required to obtain a flow of the mortar according to ASTM C 109 may vary, but is approximately
  • the compressive strength when using natural pozzolan corre ⁇ sponds to the strength which is obtained when fly ash is used together with Portland cement.
  • the present invention can be realized with the use of differ ⁇ ent types of grinding equipment such as media milling equip ⁇ ment, e.g. stirred, centrifugal, tumbling ball or non-media milling equipment, e.g. jet, impact, roller with dominating shear mechanical impulses applied to the particles subjected to processing and combined with air classification.
  • the pozzolan can be subjected to grinding in a grinding equipment, which is adopted to the open or closed circuit for material being grinded.
  • a preferred particle size distribution is:
  • Portland cement, fly ash Class F or C, fine quartz, granite quarry fines, fine frac ⁇ tions of recycled concrete or blast furnace slag or its blends are added to the said pozzolan during or after said processing of the pozzolan.
  • Portland cement, fly ash Class F or C, fine quartz, granite quarry fines, fine fractions of recycled concrete or blast furnace slag or its blends are subjected to pregriding to achieve fineness with a retention on the sieve of 45 microns which is less than 5%.
  • water reduc ⁇ ing agents, set time regulators, and strength accelerating admixtures in powder form are added to the said pozzolan during or after said grinding of the pozzolan.
  • replacement of Portland cement by the said pozzolan in concrete or mortar is from 15 to about 70%.
  • the pozzolans is subjected to grinding in said grinding equipment to a fineness of the final product with a retention on a sieve 30 microns being less than 5%.

Abstract

Method for manufacturing of supplementary cementitious materials for replacement of Portland cement in production of mortars and concretes, where the cementitious materials comprises natural pozzolans in the form of rocks and ashes. The invention is characterized in, that the said pozzolans in crushed state are subjected to a high energetic mechanical processing by means of grinding in a grinding equipment, whereby the pozzolan particles receive mechanical impulses, and in that the grinding is carried out for a predetermined time resulting in a compressive strength of a 2 inch side cube of mortar comprising 80 % Portland cement and 20 % natural pozzolan in a ratio of 1:2.75 to standard sand and in addition water required to obtain a flow of the mortar according to American standard ASTM C 109, which has been properly compacted under vibration and hardened at + 20 °C in sealed condition, which after 28 days is ≥ 75 % of the compressive strength of a 2 inch side cube, treated as said cube, of a mortar comprising a ratio of Portland cement: sand of 1:2.75 and in addition water corresponding to 48.5 % of the weight of Portland cement.

Description

Method for manufacturing of Supplementary Cementitious Materials (SCMs)
The present invention relates to a method for manufacturing of supplementary cementitious materials (SCMs), i.e
pozzolans .
Fly ash is a supplementary cementitious material, which is useful for production of concretes, mortars and other mix¬ tures comprising cement. Fly ash is a by-product of coal burning power plants and is produced worldwide in large quan¬ tities each year.
In the Swedish patent No 532790 a method is described which eliminates fluctuations in the fly ash quality due to varia¬ tions in the coal chemical compositions and parameters of coal burning processes. Processing of pozzolans, i.e. fly ashes according to the patented method significantly improves performance of the concrete and provides higher level of replacement of Standard Portland cement, which leads to sig¬ nificant economical and environmental benefits.
Fly ash usually contains about 85% glassy, amorphous compo¬ nents in the form of cenosphere particles. According to ASTM C 618 fly ash is classified in two classes, Class C and Class F. The Class F fly ash typically contains more than 70% by weight of silica, alumina, and ferric oxides, while Class C typically contains between 70% and 50%. Class F is produced as a by product of the combustion of bituminous coal. Class C fly ash has a higher calcium content and is produced as a by¬ product of the combustion of sub-bituminous coal.
Comprehensive research has demonstrated that a high volume fly ash concretes, where Portland cement has been replaced by fly ash to a level over 50% showed a higher long term
strength development, a lower water and a gas permeability, a high chloride ion resistance, etc. in comparison with Port¬ land cement concretes without fly ash.
At the same time a high volume fly ash concrete has signifi¬ cant drawbacks. One drawback is long setting times and unsat¬ isfactory slow strength development during the period 0 to 28 days. These negative effects significantly reduce the level of fly ash used for replacement of Portland cement, e.g.
about 15% in the US.
Serious problems are also related to the stability of fly ash performance. Usually variations in the chemical composition of coal and frequent changes in operating parameters of power plants cause, among others, formation of crystalline and quasi-crystalline phases, so called scoria, which leads to reduction in fly ash reactivity, so called pozzolanic activi¬ ty.
Historically limestone-pozzolan mixes have been used for 2000 years ago by ancient Romans and a lot of ancient buildings as e. g. Coliseum are still in a good shape. At the same time despite the fact that according to the US Geological Survey billions of tons of natural pozzolan can be found in Western USA and in most other regions of the world, of the usage of natural pozzolans in concrete in the modern building industry is very limited.
Natural pozzolans belong to materials of volcanic origin and sedimentary origin, such as diatomaceous earth. According to ASTM C 618 they are designated Class N pozzolans. The natural pozzolans are described in ACI 232.1R-00 as "Raw or
calcinated natural pozzolans that comply with the applicable requirements for the class herein, such as some diatomaceous earth; opaline chert and shales; tuffs and volcanic ashes or pumicites, any of which may or may not be processed calcina¬ tions; and various materials requiring calcination to induce satisfactory properties, such as some clays or shales."
The reason why the use of natural pozzolans is very limited can be explained by the following.
The microstructure of natural pozzolan particles is charac¬ terized by high porosity, which significantly increases water demand of concrete mixes containing natural pozzolans to achieve required flowability/workability of the concrete. However, increases in water demand lead to unsatisfactory compressive strength development.
Additinally, , uneven distribution of active minerals i.e. amorphous materials, e.g. due to weathering has a further and unacceptablenegative impact on negative strength development of concrete with natural pozzolan content. Optimized natural pozzolan particle size distribution is required in order to achieve consistent performance of high pozzolan containing concrete. An optimized particle distribu¬ tion is such that there are fine and coarse fractions pre- sent.
According to the Report of American Concrete Institute ACI 232.1R-00 "Use of raw or processed natural pozzolans in con¬ crete", properties of natural pozzolans can vary considera¬ bly, depending on their origin and therefore variable propor- tions of chemically active minerals. Chemically active miner¬ als usually contain amorphous materials (e.g. amorphous sili¬ con dioxide) , which react with calcium hydroxide released during Portland cement hydration (pozzolanic reaction) and form calcium-silicate-hydrate gel [C-H-S gel] - a product similar to the resulting product of Portland cement hydra¬ tion.
The present invention solves the problem of using natural pozzolans in concrete. The present invention thus refers to a method for manufactur¬ ing of supplementary cementitious materials for replacement of Portland cement in production of mortars and concretes, where the cementitious materials comprises natural pozzolans in the form of rocks and ashes and sedimentary origin, such as diatomaceous earth.
The invention is characterized in, that the said pozzolans in crushed state are subjected to a high energetic mechanical processing by means of grinding in a grinding equipment, whereby the pozzolan particles receive mechanical impulses, and in that the grinding is carried out for a predetermined time resulting in a compressive strength of a 2 inch side cube of mortar comprising 80 % Portland cement and 20 % natural pozzolan in a ratio of 1:2.75 to standard sand and in addition water required to obtain a flow of the mortar according to American standard ASTM C 109, which has been properly compacted under vibration and hardened at + 20 °C in sealed condition, which after 28 days is ≥ 75 % of the compressive strength of a 2 inch side cube, treated as said cube, of a mortar comprising a ratio of Portland cement: sand of 1:2.75 and in addition water corresponding to 48.5 % of the weight of Portland cement.
This test corresponds to the American standard ASTM C 109. The present invention will be described in more detail below.
The invention refers to a method for manufacturing of supple¬ mentary cementitious materials for replacement of Portland cement in production of mortars and concretes, where the cementitious materials comprises natural pozzolans in the form of rocks and ashes of volcanic origin and sedimentary origin, such as diatomaceous earth.
According to the invention the said pozzolans in a crushed state are subjected to a high energetic mechanical processing by means of grinding in a grinding equipment, whereby the pozzolan particles receive mechanical impulses.
The grinding leads to modification of its surface properties in the form of surface porosity reduction and improvement of its chemical reactivity with alkaline medium produced by hydrating cement. It has been observed that the treatment of the pozzolan particles gives that there occurs local melting of the surface of the particals, whereby zones with a high degree of amorphization are created. By this treatment it has shown that natural pozzolans show a surprisingly good effect when the so treated natural pozzolans replace Some of the amount of Portland cement in a cement paste, mortar and con¬ crete comprising Portland cement, pozzolans, sand and water.
Further according to the invention, the grinding is carried out for a predetermined time resulting in a compressive strength of a 2 inch side cube of mortar comprising 80 % Portland cement and 20 % natural pozzolan in a ratio of 1:2.75 to standard sand and in addition water required to obtain a flow of the mortar according to American standard ASTM C 109, which has been properly compacted under vibration and hardened at + 20 °C in sealed condition, which after 28 days is ≥ 75 % of the compressive strength of a 2 inch side cube, treated as said cube, of a mortar comprising a ratio of Portland cement: sand of 1:2.75 and in addition water corre¬ sponding to 48.5 % of the weight of Portland cement.
The amount of water required to obtain a flow of the mortar according to ASTM C 109 may vary, but is approximately
40% - 50% of the weight of Portland cement and the pozzolan.
The compressive strength when using natural pozzolan corre¬ sponds to the strength which is obtained when fly ash is used together with Portland cement. The present invention can be realized with the use of differ¬ ent types of grinding equipment such as media milling equip¬ ment, e.g. stirred, centrifugal, tumbling ball or non-media milling equipment, e.g. jet, impact, roller with dominating shear mechanical impulses applied to the particles subjected to processing and combined with air classification.
The pozzolan can be subjected to grinding in a grinding equipment, which is adopted to the open or closed circuit for material being grinded. A preferred particle size distribution is:
< 5 microns 15-50%,
< 10 microns 30-65%,
< 30 microns 90-95 %.
According to a preferred embodiment Portland cement, fly ash Class F or C, fine quartz, granite quarry fines, fine frac¬ tions of recycled concrete or blast furnace slag or its blends are added to the said pozzolan during or after said processing of the pozzolan.
According to another preferred embodiment Portland cement, fly ash Class F or C, fine quartz, granite quarry fines, fine fractions of recycled concrete or blast furnace slag or its blends are subjected to pregriding to achieve fineness with a retention on the sieve of 45 microns which is less than 5%.
According to still another preferred embodiment water reduc¬ ing agents, set time regulators, and strength accelerating admixtures in powder form are added to the said pozzolan during or after said grinding of the pozzolan.
It is preferred that replacement of Portland cement by the said pozzolan in concrete or mortar is from 15 to about 70%.
It is also preferred that the pozzolans is subjected to grinding in said grinding equipment to a fineness of the final product with a retention on a sieve 30 microns being less than 5%.
Several embodiments of the invention have been described above. However, the present invention is not restricted to the exemplifying embodiments described above, but can be varied within the scope of the claims.

Claims

Claims :
1. Method for manufacturing of supplementary cementitious materials for replacement of Portland cement in production of mortars and concretes, where the cementitious materials com- prises natural pozzolans in the form of rocks and ashes, characterized in, that the said pozzolans in crushed state are subjected to a high energetic mechanical processing by means of grinding in a grinding equipment, whereby the pozzolan particles receive mechanical impulses, and in that the grinding is carried out for a predetermined time, in, that final product of the pozzolan after grinding has the following particle size distribution:
< 5 microns 15-50%,
< 10 microns 30-65%, < 30 microns 90-95 % in, that a mixture of ground pozzolans, protland cement and water is resulting in a compressive strength of a 2 inch side cube of mortar comprising 80 % Portland cement and 20 % natural pozzolan in a ratio of 1:2.75 to standard sand and in addition water required to obtain a flow of the mortar according to American standard ASTM C 109, which has been properly compacted under vibration and hardened at + 20 °C in sealed condition, which after 28 days is ≥ 75 % of the compressive strength of a 2 inch side cube, treated as said cube, of a mortar comprising a ratio of Portland cement: sand of 1:2.75 and in addition water corresponding to 48.5 % of the weight of Portland cement.
2. Method according to claim 1, characterized in, that Port¬ land cement, fly ash Class F or C, fine quartz, granite quar¬ ry fines, fine fractions of recycled concrete or blast fur¬ nace slag or its blends are added to the said pozzolan during or after said processing of the pozzolan.
3. Method according to claim 1 or 3, characterized in, that Portland cement, fly ash Class F or C, fine quartz, granite quarry fines, fine fractions of recycled concrete or blast furnace slag or its blends are subjected to pregriding to achieve fineness with a retention on the sieve of 45 microns which is less than 5%.
4. Method according to claims any of the claims 1 - 3, char¬ acterized in, that water reducing agents, set time regula¬ tors, and strength accelerating admixtures in powder form are added to the said pozzolan during or after said grinding of the pozzolan.
5. Method according to any of claims 1-4, characterized in, that replacement of Portland cement by the said pozzolan in concrete or mortar is from 15 to about 70%.
6. Method according to any of the preceeding claims, charac¬ terized in, that the pozzolans is subjected to grinding in said grinding equipment to a fineness of the final product with a retention on a sieve 30 microns being less than 5%.
7. Method according to any of the proceeding claims, charac¬ terized in, that pozzolan is subjected by grinding in a grinding equipment, which is adopted to open or closed cir¬ cuit for material being grinded
PCT/EP2013/054907 2012-03-12 2013-03-11 Method for manufacturing of supplementary cementitious materials (scms) WO2013135642A1 (en)

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Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX349820B (en) * 2010-10-14 2017-08-15 Instituto Nac De Investigaciones Nucleares Method and device for treating diatomaceous earth waste and other waste in order to obtain construction materials.
CN103864335B (en) * 2014-01-25 2015-08-19 陈军 A kind of take diatomite as the preparation method of the adulterant of main raw material
US11746048B2 (en) 2015-10-23 2023-09-05 Roman Cement, Llc Cement-SCM compositions and methods and systems for their manufacture
US11655186B2 (en) 2015-10-23 2023-05-23 Roman Cement, Llc Activitation of natural pozzolans
US10494298B1 (en) * 2015-10-23 2019-12-03 Roman Cement Llc Cement-SCM compositions and methods and systems for their manufacture
CN107337197A (en) * 2016-04-28 2017-11-10 香港理工大学深圳研究院 The method that CNT is scattered in cement matrix
PH12016000174A1 (en) * 2016-05-06 2017-11-27 Bigboss Cement Inc An additive and a method for producing a cement composition
CN107855206B (en) * 2017-11-03 2019-05-21 福建兴旺建设发展有限公司 A kind of sub- disintegrating equipment of construction sand
AT520755B1 (en) * 2018-07-17 2019-07-15 Markus Fleischanderl Binder for the production of a hard stone-based free surface covering with cement
CN114555539A (en) 2019-08-13 2022-05-27 加州理工学院 Process for producing calcium oxide or ordinary portland cement from calcium-containing rocks and minerals
US11124455B2 (en) 2019-11-01 2021-09-21 King Fahd University Of Petroleum And Minerals Nanozeolite-modified green concrete

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1263021A (en) * 1960-07-22 1961-06-05 Process for manufacturing quality pozzolanic cement, by grinding with great fineness and possible addition of crystalline seeds of hydrated aluminous cement
US20030131764A1 (en) * 1999-05-12 2003-07-17 Paul C. Lessard Mechanical activation granitic powders
WO2009064244A1 (en) * 2007-11-12 2009-05-22 Procedo Enterprises Etablissement Method for processing of pozzolans.
US20100243771A1 (en) * 2009-03-31 2010-09-30 Staker & Parson Companies Systems and methods for reducing the particle size of a pozzolan

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE501511C2 (en) * 1993-04-30 1995-03-06 Vladimir P Ronin Process for making cement
US5656075A (en) * 1995-05-10 1997-08-12 W. R. Grace & Co.-Conn. Control of expansion in concrete due to alkali silica reaction
CN1436745A (en) * 2002-02-06 2003-08-20 刘雁鸿 Production process of mixed cement material with industrial slag
SE524154C2 (en) * 2002-11-07 2004-07-06 Procedo Entpr Ets Process for producing mixed cement with reducing carbon dioxide emissions
SE524393C2 (en) * 2002-11-07 2004-08-03 Procedo Entpr Ets Method of treatment of fly ash
ES2224877B1 (en) * 2003-08-22 2006-03-01 Asociacion De Investigacion De Industrias De La Construccion Aidico. MORZOLOGICAL DESIGN PROCESS OF PUZOLANAS FOR THE CONTROL OF THE TECHNICAL CHARACTERISTICS OF THE CEMENTS TO WHICH THEY ADD.
ES2304875B1 (en) * 2007-03-16 2009-11-11 Asoc. De Investigacion De Industrias De La Construccion Aidico-Instituto Tecnologico De Construccion ADDITIONED PORTLAND CEMENT WITH TEXTURIZED PUZOLANS.
CN101157527A (en) * 2007-09-26 2008-04-09 腾冲县华辉石材有限公司 Basalt lava ash powder
CN101293766A (en) * 2008-06-11 2008-10-29 中国水利水电第三工程局 Only volcanic ash doped roller compacted concrete and preparation method thereof
EP2145868A1 (en) * 2008-07-18 2010-01-20 Lafarge Aqueous formulations
US7799128B2 (en) * 2008-10-10 2010-09-21 Roman Cement, Llc High early strength pozzolan cement blends
US8496750B2 (en) * 2009-03-31 2013-07-30 Staker & Parson Companies Method for reducing the particle size of a pozzolan

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1263021A (en) * 1960-07-22 1961-06-05 Process for manufacturing quality pozzolanic cement, by grinding with great fineness and possible addition of crystalline seeds of hydrated aluminous cement
US20030131764A1 (en) * 1999-05-12 2003-07-17 Paul C. Lessard Mechanical activation granitic powders
WO2009064244A1 (en) * 2007-11-12 2009-05-22 Procedo Enterprises Etablissement Method for processing of pozzolans.
SE532790C2 (en) 2007-11-12 2010-04-13 Procedo Entpr Etablissement Method of treating pozzolanes
US20100243771A1 (en) * 2009-03-31 2010-09-30 Staker & Parson Companies Systems and methods for reducing the particle size of a pozzolan

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 99, 1 January 1983, Columbus, Ohio, US; abstract no. 9903y, Z.A.JUHASZ: "Hydraulic binder from mechanochemically activated pumicite" XP001325829 *
PAVLIDOU E: "Systematic analysis of natural pozzolans from Greece suitable for repair mortars", JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, KLUWER ACADEMIC PUBLISHERS, DORDRECHT, NL, vol. 108, no. 2, 20 November 2011 (2011-11-20), pages 671 - 675, XP035041489, ISSN: 1572-8943, DOI: 10.1007/S10973-011-2039-Y *
PERIOD. POLYTECH., CIV.ENG., vol. 26, no. 1-2, 1 January 1982 (1982-01-01), pages 41 - 59 *

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