WO2013127208A1 - Color filter and fabricating method thereof - Google Patents

Color filter and fabricating method thereof Download PDF

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Publication number
WO2013127208A1
WO2013127208A1 PCT/CN2012/085204 CN2012085204W WO2013127208A1 WO 2013127208 A1 WO2013127208 A1 WO 2013127208A1 CN 2012085204 W CN2012085204 W CN 2012085204W WO 2013127208 A1 WO2013127208 A1 WO 2013127208A1
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Prior art keywords
layer
photosensitive material
color filter
black matrix
sub
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PCT/CN2012/085204
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French (fr)
Chinese (zh)
Inventor
赵吉生
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京东方科技集团股份有限公司
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Publication of WO2013127208A1 publication Critical patent/WO2013127208A1/en

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • G02B5/201Filters in the form of arrays
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133512Light shielding layers, e.g. black matrix
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0005Production of optical devices or components in so far as characterised by the lithographic processes or materials used therefor
    • G03F7/0007Filters, e.g. additive colour filters; Components for display devices
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/09Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
    • G03F7/095Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers having more than one photosensitive layer
    • G03F7/0955Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers having more than one photosensitive layer one of the photosensitive systems comprising a non-macromolecular photopolymerisable compound having carbon-to-carbon double bonds, e.g. ethylenic compounds

Definitions

  • Liquid crystal display is a non-active light-emitting component.
  • the light source must be provided by an internal backlight. It can be combined with the driver IC and liquid crystal control to form a gray-scale display of black and white colors, and then pass the color filter ( Color Filter, CF )
  • Color Filter, CF The three color filters of red (R), green (G), and blue (B) form a color display. Therefore, color filters are key components for colorization of liquid crystal displays.
  • the quality of the system not only determines the pros and cons of the LCD, but also determines the yield of the subsequent process.
  • the color filter layer needs to have a partial overlap with the black matrix.
  • the purpose of this method is to avoid light leakage, because the color filter layer shrinks during baking, if the color filter is designed.
  • the layer does not overlap with the black matrix, which is highly susceptible to light leakage defects after baking.
  • this method avoids light leakage, the area where the color filter layer overlaps with the black matrix is higher than the sub-pixel area, which is called "segment difference".
  • the step difference has a detrimental effect on the subsequent process of the box, which disturbs the orientation of the liquid crystal. Therefore, a flat layer (OC) is formed in the production of the color filter, eliminating the step difference and adding a one-step manufacturing process.
  • An embodiment of the present invention provides a color filter, including: a black matrix layer defined on a substrate defining a plurality of sub-pixel regions, and a plurality of color filters formed in a plurality of sub-pixel regions defined by the black matrix layer a light layer, wherein a portion of the black matrix layer between two adjacent sub-pixel regions has a cross section of a large upper and lower small shape, and a color filter layer is formed to have a cross section having a corresponding shape of a lower large and small upper, the black matrix layer a portion having an overlap with the color filter layer, and a sum of thicknesses of the black matrix layer and the color filter layer in the overlap region is equal to a thickness of the black matrix layer or the color filter layer of the non-overlapping region Degree.
  • Another embodiment of the present invention provides a method of fabricating a color filter for manufacturing the color filter described above, comprising: applying a first type of photoresist layer in which a black pigment is dispersed on a surface of a substrate; dispersing therein A second type of photoresist layer having a black pigment is applied to the first type of photoresist layer, wherein the first type of photoresist layer is one of a positive photoresist and a negative photoresist, the second category
  • the photoresist layer is another one of a positive photoresist and a negative photoresist; the second type photoresist layer is exposed and developed by a mask; directly lithography is performed on the first category
  • the adhesive layer is exposed and developed to form a black matrix layer portion having a cross-sectional shape that is upper and lower, and a sub-pixel region having a cross-sectional shape that is smaller in size and smaller in size; and a color filter layer is formed in the sub-pixel region.
  • a further embodiment of the present invention provides a method of manufacturing a color filter, for manufacturing the color filter, comprising: applying a first photosensitive material layer of a black matrix layer to a surface of the substrate; and second sensing the black matrix layer
  • the material layer is coated on the first photosensitive material layer of the black matrix layer, the first photosensitive material layer and the second photosensitive material layer are positive photoresist, or the first photosensitive material layer and the second photosensitive material layer are negative photoresist,
  • the first photosensitive material layer and the second photosensitive material layer both comprise an alkali-soluble resin, and the content of the alkali-soluble resin of the first photosensitive material layer is greater than the content of the alkali-soluble resin of the second photosensitive material layer; a photosensitive material layer and a second photosensitive material layer are exposed and developed to form a black matrix layer having a cross-sectional shape that is upper and lower, and a sub-pixel region having a cross-sectional shape that is larger in size and smaller in size; formed in the sub-pixel region Color
  • FIG. 1 is a structural view of a color filter provided by the present invention.
  • FIG. 2 is a flow chart of a method for manufacturing a double exposure of a color filter provided by the present invention
  • FIG. 3 is a structural diagram of a color filter having a sub-pixel region provided by the present invention.
  • FIG. 4 is a flow chart of a method for manufacturing a single exposure of a color filter provided by the present invention. detailed description
  • One of the objects of the embodiments of the present invention overcomes the problem of the complicated process caused by the need to fabricate a flat layer in the process of manufacturing a color filter in the prior art.
  • An embodiment of the present invention provides a color filter, as shown in FIG. 1, including a black matrix layer 20 formed on a substrate 10, the black matrix layer 20 defining a plurality of sub-pixel regions; a plurality of color filter layers 30 in the sub-pixel regions, wherein the portion of the black matrix layer 20 between the two adjacent sub-pixel regions has a cross section of a large upper and lower small shape, and the color filter layer 30 has a larger size and a smaller size. The cross section of the shape.
  • the black matrix layer 20 and the color filter layer 30 overlap each other at the interface 40.
  • the region in a region where both a black matrix layer and a color filter layer are formed, the region may be referred to as an overlap region; and in a region where only a black matrix layer or a color filter layer is formed, the region may be called Is a non-overlapping area.
  • the sum of the thicknesses of the black matrix layer and the color filter layer of the overlap region 40 is equal to the thickness of the black matrix layer or the color filter layer of the non-overlapping region 41.
  • both the black matrix layer and the color filter layer may be formed to be complementary in shape.
  • the black matrix layer 20 has an inverted stepped cross-sectional shape at a portion between two adjacent sub-pixel regions, including a first sub-layer 21 having a lower width and a wider width at the upper portion. Two sub-layers 22.
  • the cross-sectional shape of the color filter layer 30 is a positive step shape.
  • the portion of the black matrix layer 20 between the two sub-pixel units has an inverted trapezoidal cross-sectional shape in which the upper base is longer and the lower base is shorter.
  • the portion of the black matrix layer 20 between the two sub-pixel units has an inverted triangular cross-sectional shape.
  • photoresist can be divided into two types: negative adhesive and positive adhesive.
  • the first sub-layer 21 and the second sub-layer 22 employ different types of photoresist.
  • the first photosensitive material of the first sub-layer 21 is a positive photoresist
  • the second photosensitive material of the second sub-layer 22 is a negative photoresist
  • the first photosensitive material of the first sub-layer 21 is a negative photoresist
  • the second sensitization of the second sub-layer The material is a positive photoresist.
  • the first sub-layer 21 and the second sub-layer 22 are made of a photoresist of the same nature, that is, the first photosensitive material and the second photosensitive material are both positive photoresists, or first Both the photosensitive material and the second photosensitive material are negative photoresists.
  • the first photosensitive material and the second photosensitive material are different in that the alkali-soluble resin contents of the two are different.
  • the content of the alkali-soluble resin of the first photosensitive material is greater than the content of the alkali-soluble resin of the second photosensitive material.
  • the first photosensitive material may have an alkali-soluble resin weight percentage of 5% to 79%
  • the second photosensitive material may have an alkali-soluble resin weight percentage of 0.05% to 30%.
  • the first photosensitive material comprises: 5% to 45% by weight of black pigment, 0.5% to 67% by weight of dispersant, 0.05% by weight, based on the following components and ratios; -30% dispersion resin, 5% to 79% by weight of alkali-soluble resin, 2% to 25% by weight of ethylenically unsaturated monomer, 0.05% to 10% by weight of epoxy resin, weight The percentage is from 20% to 80% of the solvent, from 0.05% to 10% by weight of the photoinitiator, and from 0.01% to 2% by weight of the surface tension-modifying additive.
  • the second photosensitive material comprises: 5%-45% by weight of black pigment, 0.5%-67% by weight of dispersant, 0.05%-30% by weight of dispersion resin, 0.05%-30% by weight Alkali-soluble resin, 2%-25% by weight of ethylenically unsaturated monomer, 0.05%-10% by weight of epoxy resin, 20%-80% by weight of solvent, 0.05% by weight - 10% of the photoinitiator, 0.01% to 2% by weight of the agent to change the surface tension.
  • the additive that changes the surface tension may employ a leveling agent, a surface flow control, and a silane coupling agent.
  • the ethylenically unsaturated monomer is a polyfunctional acrylate monomer.
  • Another embodiment of the present invention provides a method of fabricating a color filter for fabricating a color filter as described above, as shown in FIG.
  • Step 101 Apply a positive photoresist layer in which a black pigment is dispersed to the surface of the substrate.
  • Step 102 Apply a negative photoresist layer in which a black pigment is dispersed on the positive photoresist layer.
  • Step 103 Exposing the negative photoresist layer with a mask and performing development.
  • Step 104 Directly exposing the positive photoresist layer and performing development to form a black matrix layer having a shape of a large upper and lower cross section and a sub-pixel region having a corresponding shape with a lower cross section and a smaller cross section.
  • Step 105 Form a color filter layer in each sub-pixel region.
  • the mask is placed on the negative photoresist.
  • the negative photoresist layer in the area that is desired to be preserved is exposed, and then the corresponding solvent is used for development. Since the negative photoresist is exposed to the corresponding solvent, an insoluble matter is formed, and the exposed region is not exposed. As a soluble material, the negative photoresist in the exposed region is thus developed to form a wider second sub-layer of the upper portion.
  • the second sub-layer is used as a mask to directly expose the positive photoresist layer and perform development, thereby, except for the area covered by the second sub-layer.
  • the positive photoresist layers in eg, sub-pixel regions
  • the positive light gel is exposed to form a soluble substance, while the unexposed areas are still insoluble.
  • a certain amount of illumination is inevitably received, so that the positive photoresist layer under the edge portion of the second sub-layer becomes soluble, thereby developing the positive light.
  • the area retained by the engraved layer is slightly smaller than the area retained by the negative photoresist layer.
  • the portion of the black matrix layer 20 having the upper and lower cross-sections and the corresponding sub-pixel region 31 having the upper and lower large shapes are formed on the substrate 10.
  • a color filter layer 30 is formed in the sub-pixel region.
  • a negative photoresist layer in which a black pigment is dispersed may be applied to the surface of the substrate, and in step 102, a positive light in which the black pigment is dispersed may be disposed.
  • the adhesive layer is applied to the negative photoresist layer.
  • the upper photoresist layer is exposed by a mask and developed.
  • the negative photoresist is directly exposed and developed to form a black matrix layer portion having a cross-sectional shape that is upper and lower, and a sub-pixel region having a cross-sectional shape that is larger and smaller.
  • Another embodiment of the present invention provides a method of fabricating a color filter for fabricating a color filter as described above, as shown in FIG.
  • Step 201 Apply a first photosensitive material layer of the black matrix layer to the surface of the substrate.
  • Step 202 Apply a second photosensitive material layer of the black matrix layer to the first photosensitive material layer.
  • Step 203 exposing the first photosensitive material layer and the second photosensitive material layer with a mask, and performing development to form a black matrix layer portion having a cross-sectional shape that is upper and lower, and a cross-sectional shape corresponding to a large upper and a lower Sub-pixel area.
  • Step 204 forming a color filter layer in the sub-pixel region.
  • the first photosensitive material layer is used to form a first sub-layer of the black matrix layer portion
  • the second photosensitive material layer is used to form a second sub-layer of the black matrix layer portion.
  • the first photosensitive material layer and the second photosensitive material layer are both positive photoresists, or both the first photosensitive material layer and the second photosensitive material layer are negative photoresists.
  • the first photosensitive material layer and the second photosensitive material layer each include, for example, an alkali-soluble resin, and the content of the alkali-soluble resin in the first photosensitive material layer is larger than the content of the alkali-soluble resin in the second photosensitive material layer.
  • the first photosensitive material layer and the second photosensitive material layer are exposed by a mask, and the mask is placed on the second photosensitive material film layer.
  • a region where it is desired to retain the first photosensitive material layer and the second photosensitive material layer is exposed, and then developed with a corresponding solvent. Since the negative photoresist becomes insoluble after exposure to the corresponding solvent, the negative photoresist in the unexposed region is still soluble, so that the negative photoresist in the exposed region is left after development to form a black matrix layer. .
  • the exposed areas of the first photosensitive material layer and the second photosensitive material layer are the same, because the content of the alkali-soluble resin of the first photosensitive material layer below is larger than the alkali-soluble resin of the upper second photosensitive material layer.
  • the content therefore, at the time of development, the lower portion of the first photosensitive material layer is removed more, and the portion of the upper second photosensitive material layer removed is less.
  • a black matrix layer 20 having a shape of a large upper and lower cross section and a corresponding sub-pixel region 31 of a large upper and lower large shape are formed on the substrate 10.
  • the color filter layer 30 is filled in the sub-pixel region.
  • the positive photoresist layer is applied to the surface of the substrate, pre-baking, and then the negative photoresist layer is applied on the positive photoresist layer. And do another pre-baking.
  • a color filter comprising: a black matrix layer defined on the substrate defining a plurality of sub-pixel regions; and a plurality of color filter layers formed in the plurality of sub-pixel regions defined by the black matrix layer, wherein the black a portion of the matrix layer between two adjacent sub-pixel regions having a cross section of a large upper and lower small shape, and a color filter layer formed into a cross section having a corresponding shape of a lower large and small upper, the black matrix layer portion and the color There are overlapping regions between the filter layers, and the sum of the thicknesses of the black matrix layer and the color filter layer in the overlap region is equal to the thickness of the black matrix layer or the color filter layer of the non-overlapping region.
  • a cross-sectional shape of the black matrix layer portion is complementary to a shape of a cross section of the color filter layer.
  • the black matrix layer portion has an inverted step shape, and includes a first sub-layer having a narrow lower width and a wider upper portion.
  • the second sub-layer, the cross-sectional shape of the color filter layer is a positive step shape.
  • the first photosensitive material of the first sub-layer is a negative photoresist
  • the second photosensitive material of the second sub-layer is a positive photoresist
  • the first photosensitive material further comprises: a black pigment having a weight percentage of 5% to 45%, a dispersant having a weight percentage of 0.5% to 67%, and a weight percentage of
  • the second photosensitive material further comprises: 5%-45% by weight of black pigment, the weight percentage is 0.5%-67% dispersant, 0.05%-30% by weight of dispersion resin, 2%-25% by weight of ethylglycolically unsaturated monomer, 0.05%-10% by weight of epoxy resin
  • the solvent is 20%-80% by weight
  • the photo-initiator is 0.05%-10% by weight
  • the surface tension-changing additive is 0.01%-2% by weight.
  • a method of producing a color filter comprising the color filter of any one of (1) to (8), comprising:
  • a method of producing a color filter comprising the color filter of any one of (1) to (8), comprising:
  • the material layer is a negative photoresist, wherein the first photosensitive material layer and the second photosensitive material layer both comprise an alkali-soluble resin, and the content of the alkali-soluble resin of the first photosensitive material layer is greater than that of the alkali-soluble resin of the second photosensitive material layer;
  • a color filter layer is formed in the sub-pixel region.
  • the black matrix layer and the color filter layer have overlapping regions, and the film thickness of the overlap region and the film thickness of the non-overlapping region are the same, it is not necessary to form a flat layer, and the manufacturing process is simple.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Optics & Photonics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Mathematical Physics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Engineering & Computer Science (AREA)
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  • Structural Engineering (AREA)
  • Liquid Crystal (AREA)
  • Optical Filters (AREA)

Abstract

Provided are a color filter and a fabricating method thereof. The color filter comprises a black matrix layer (20) formed on a substrate and defining multiple sub-pixel regions, and multiple color filter layers (30) formed in the multiple sub-pixel regions defined by the black matrix layer respectively, wherein the black matrix layer between two adjacent sub-pixel regions has such a shape that the upper side is wide and the lower side is narrow in the cross-section, the cross-section of the color filter layer has the corresponding shape that the lower side is wide and the upper side is narrow. An overlapped area (40) is provided between the black matrix layer and the color filter layer, and the overall thickness of the black matrix layer and the color filter layer in the overlapped area equals to the thickness of the black matrix layer or the color filter layer in the non-overlapped area (41).

Description

彩色滤光片及其制造方法 技术领域  Color filter and manufacturing method thereof
背景技术 Background technique
液晶显示器(Liquid Crystal Display, LCD )为非主动发光的元件, 必须 通过内部的背光源提供光源,搭配驱动 IC与液晶控制, 形成黑、 白两色的灰 阶显示, 再通过彩色滤光片 (Color Filter, CF ) 的红(R ) 、 绿(G ) 、 蓝 ( B )三种彩色滤光层形成彩色显示画面, 因此, 彩色滤光片为液晶显示器 彩色化的关键零部件。 本身质量不但决定液晶显示屏的优劣, 并且也决定后 续工艺的良率。  Liquid crystal display (LCD) is a non-active light-emitting component. The light source must be provided by an internal backlight. It can be combined with the driver IC and liquid crystal control to form a gray-scale display of black and white colors, and then pass the color filter ( Color Filter, CF ) The three color filters of red (R), green (G), and blue (B) form a color display. Therefore, color filters are key components for colorization of liquid crystal displays. The quality of the system not only determines the pros and cons of the LCD, but also determines the yield of the subsequent process.
在目前工艺制作彩色滤光片时, 彩色滤光层需要与黑矩阵有一部分重叠 区域, 该做法的目的是避免漏光, 由于彩色滤光层在烘烤时体积会收缩, 如 果设计时彩色滤光层不与黑矩阵重叠, 那在烘烤后极易造成漏光缺陷。 该做 法虽然避免了漏光, 但是彩色滤光层与黑矩阵重叠的区域要高于次像素区, 即所谓 "段差" 。 段差对后续的对盒工艺有很不利的影响, 会扰乱液晶的取 向, 因此在制作彩色滤光片时要制作平坦层(OC ) , 消除段差, 增加了一步 制作工艺。  In the current process of manufacturing color filters, the color filter layer needs to have a partial overlap with the black matrix. The purpose of this method is to avoid light leakage, because the color filter layer shrinks during baking, if the color filter is designed. The layer does not overlap with the black matrix, which is highly susceptible to light leakage defects after baking. Although this method avoids light leakage, the area where the color filter layer overlaps with the black matrix is higher than the sub-pixel area, which is called "segment difference". The step difference has a detrimental effect on the subsequent process of the box, which disturbs the orientation of the liquid crystal. Therefore, a flat layer (OC) is formed in the production of the color filter, eliminating the step difference and adding a one-step manufacturing process.
由此可见现有技术中存在, 在彩色滤光片的制作过程中需要制作平坦层 而导致的工艺复杂的问题。 发明内容  Thus, it can be seen that there is a problem in the prior art that a process of manufacturing a flat color layer is required in the process of manufacturing a color filter. Summary of the invention
本发明的一实施例提供彩色滤光片, 包括: 形成于基板上的限定出多个 次像素区域的黑矩阵层, 以及形成于黑矩阵层限定的多个次像素区域中的多 个彩色滤光层, 其中黑矩阵层在两个相邻次像素区域之间的部分具有上大下 小形状的截面, 和彩色滤光层形成为具有下大上小对应形状的截面, 所述黑 矩阵层部分与所述彩色滤光层之间具有重叠的区域, 且重叠区域内的黑矩阵 层与彩色滤光层的厚度之和等于非重叠区域的黑矩阵层或彩色滤光层的厚 度。 An embodiment of the present invention provides a color filter, including: a black matrix layer defined on a substrate defining a plurality of sub-pixel regions, and a plurality of color filters formed in a plurality of sub-pixel regions defined by the black matrix layer a light layer, wherein a portion of the black matrix layer between two adjacent sub-pixel regions has a cross section of a large upper and lower small shape, and a color filter layer is formed to have a cross section having a corresponding shape of a lower large and small upper, the black matrix layer a portion having an overlap with the color filter layer, and a sum of thicknesses of the black matrix layer and the color filter layer in the overlap region is equal to a thickness of the black matrix layer or the color filter layer of the non-overlapping region Degree.
本发明的另一实施例提供彩色滤光片的制造方法, 用于制造上述的彩色 滤光片, 包括: 将其中分散有黑颜料的第一类别光刻胶层涂于基板表面; 将 其中分散有黑颜料的第二类别光刻胶层涂于所述第一类别光刻胶层上, 其中 第一类别光刻胶层为正光刻胶和负光刻胶中的一种, 第二类别光刻胶层为正 光刻胶和负光刻胶中的另一种; 釆用掩模板对所述第二类别光刻胶层进行曝 光, 并进行显影; 直接对所述第一类别光刻胶层进行曝光, 并进行显影, 形 成截面为上大下小形状的黑矩阵层部分和, 和截面为下大上小对应形状的次 像素区域; 在次像素区域中形成彩色滤光层。  Another embodiment of the present invention provides a method of fabricating a color filter for manufacturing the color filter described above, comprising: applying a first type of photoresist layer in which a black pigment is dispersed on a surface of a substrate; dispersing therein A second type of photoresist layer having a black pigment is applied to the first type of photoresist layer, wherein the first type of photoresist layer is one of a positive photoresist and a negative photoresist, the second category The photoresist layer is another one of a positive photoresist and a negative photoresist; the second type photoresist layer is exposed and developed by a mask; directly lithography is performed on the first category The adhesive layer is exposed and developed to form a black matrix layer portion having a cross-sectional shape that is upper and lower, and a sub-pixel region having a cross-sectional shape that is smaller in size and smaller in size; and a color filter layer is formed in the sub-pixel region.
本发明的又一实施例提供彩色滤光片的制造方法, 用于制造上述彩色滤 光片, 包括: 将黑矩阵层的第一感光材料层涂于基板表面; 将黑矩阵层的第 二感光材料层涂于黑矩阵层的第一感光材料层上, 第一感光材料层和第二感 光材料层为正光刻胶, 或者第一感光材料层和第二感光材料层为负光刻胶, 其中第一感光材料层中和第二感光材料层中均包括碱可溶性树脂, 第一感光 材料层的碱可溶性树脂的含量大于第二感光材料层的碱可溶性树脂的含量; 釆用掩模板对第一感光材料层和第二感光材料层进行曝光, 并进行显影, 形 成截面为上大下小形状的黑矩阵层, 和截面为下大上小对应形状的次像素区 域; 在次像素区域中形成彩色滤光层。 附图说明  A further embodiment of the present invention provides a method of manufacturing a color filter, for manufacturing the color filter, comprising: applying a first photosensitive material layer of a black matrix layer to a surface of the substrate; and second sensing the black matrix layer The material layer is coated on the first photosensitive material layer of the black matrix layer, the first photosensitive material layer and the second photosensitive material layer are positive photoresist, or the first photosensitive material layer and the second photosensitive material layer are negative photoresist, Wherein the first photosensitive material layer and the second photosensitive material layer both comprise an alkali-soluble resin, and the content of the alkali-soluble resin of the first photosensitive material layer is greater than the content of the alkali-soluble resin of the second photosensitive material layer; a photosensitive material layer and a second photosensitive material layer are exposed and developed to form a black matrix layer having a cross-sectional shape that is upper and lower, and a sub-pixel region having a cross-sectional shape that is larger in size and smaller in size; formed in the sub-pixel region Color filter layer. DRAWINGS
为了更清楚地说明本发明实施例的技术方案, 下面将对实施例或现有技 术描述中所需要使用的附图作简单地介绍, 显而易见地, 下面描述中的附图 仅仅涉及本发明的一些实施例, 并非对本发明的限制。  In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings used in the embodiments or the prior art description will be briefly described below. Obviously, the drawings in the following description relate only to some of the present invention. The examples are not intended to limit the invention.
图 1为本发明提供的彩色滤光片结构图;  1 is a structural view of a color filter provided by the present invention;
图 2为本发明提供的彩色滤光片的两次曝光制造方法流程图;  2 is a flow chart of a method for manufacturing a double exposure of a color filter provided by the present invention;
图 3为本发明提供的具有次像素区域的彩色滤光片结构图;  3 is a structural diagram of a color filter having a sub-pixel region provided by the present invention;
图 4为本发明提供的彩色滤光片的一次曝光制造方法流程图。 具体实施方式  4 is a flow chart of a method for manufacturing a single exposure of a color filter provided by the present invention. detailed description
下面将结合附图,对本发明实施例中的技术方案进行清楚、完整地描述, 显然, 所描述的实施例仅仅是本发明一部分实施例, 而不是全部的实施例。 基于本发明中的实施例, 本领域普通技术人员在没有做出创造性劳动前提下 所获得的所有其他实施例, 都属于本发明保护的范围。 The technical solutions in the embodiments of the present invention will be clearly and completely described in the following with reference to the accompanying drawings. It is apparent that the described embodiments are only a part of the embodiments of the invention, and not all of the embodiments. All other embodiments obtained by a person of ordinary skill in the art based on the embodiments of the present invention without departing from the inventive scope are the scope of the present invention.
本发明实施例的目的之一克服现有技术中存在的在彩色滤光片的制作过 程中需要制作平坦层而导致的工艺复杂的问题。  One of the objects of the embodiments of the present invention overcomes the problem of the complicated process caused by the need to fabricate a flat layer in the process of manufacturing a color filter in the prior art.
本发明的一个实施例提供一种彩色滤光片, 如图 1所示, 包括, 形成于 基板 10上的黑矩阵层 20, 该黑矩阵层 20限定出多个次像素区域; 以及形成 于多个次像素区域中的多个彩色滤光层 30, 其中黑矩阵层 20在两个相邻次 像素区域之间的部分具有上大下小形状的截面,彩色滤光层 30具有下大上小 形状的截面。 所述黑矩阵层 20与所述彩色滤光层 30在交界处 40相互重叠。 这里, 在一区域中形成有黑矩阵层和彩色滤光层两者, 则该区域可称为重叠 区域; 而在一区域中仅形成有黑矩阵层或者彩色滤光层, 则该区域可称为非 重叠区域。在本实施例中,重叠区域 40的黑矩阵层与彩色滤光层的厚度之和 等于非重叠区域 41的黑矩阵层或彩色滤光层的厚度。在重叠区域中,黑矩阵 层和彩色滤光层两者可形成为形状互补。  An embodiment of the present invention provides a color filter, as shown in FIG. 1, including a black matrix layer 20 formed on a substrate 10, the black matrix layer 20 defining a plurality of sub-pixel regions; a plurality of color filter layers 30 in the sub-pixel regions, wherein the portion of the black matrix layer 20 between the two adjacent sub-pixel regions has a cross section of a large upper and lower small shape, and the color filter layer 30 has a larger size and a smaller size. The cross section of the shape. The black matrix layer 20 and the color filter layer 30 overlap each other at the interface 40. Here, in a region where both a black matrix layer and a color filter layer are formed, the region may be referred to as an overlap region; and in a region where only a black matrix layer or a color filter layer is formed, the region may be called Is a non-overlapping area. In the present embodiment, the sum of the thicknesses of the black matrix layer and the color filter layer of the overlap region 40 is equal to the thickness of the black matrix layer or the color filter layer of the non-overlapping region 41. In the overlap region, both the black matrix layer and the color filter layer may be formed to be complementary in shape.
由图 1可知由于重叠的区域 40和非重叠区域 41的膜层厚度相同, 从而 无需制作平坦层, 简化了制造工艺。  It can be seen from Fig. 1 that since the overlapping layers 40 and the non-overlapping regions 41 have the same film thickness, it is not necessary to form a flat layer, which simplifies the manufacturing process.
在本发明的一个实施例中,黑矩阵层 20在两个相邻次像素区域之间的部 分具有倒台阶形截面形状,包括下部宽度较窄的第一子层 21和上部宽度较宽 的第二子层 22。 彩色滤光层 30的截面形状为正台阶形。  In one embodiment of the present invention, the black matrix layer 20 has an inverted stepped cross-sectional shape at a portion between two adjacent sub-pixel regions, including a first sub-layer 21 having a lower width and a wider width at the upper portion. Two sub-layers 22. The cross-sectional shape of the color filter layer 30 is a positive step shape.
在本发明的另一实施例中,黑矩阵层 20在两个次像素单元之间的部分具 有上底边较长下底边较短的倒梯形截面形状。  In another embodiment of the present invention, the portion of the black matrix layer 20 between the two sub-pixel units has an inverted trapezoidal cross-sectional shape in which the upper base is longer and the lower base is shorter.
在本发明的一个实施例中,黑矩阵层 20在两个次像素单元之间的部分具 有倒三角形截面形状。  In one embodiment of the invention, the portion of the black matrix layer 20 between the two sub-pixel units has an inverted triangular cross-sectional shape.
光刻胶根据其化学反应机理和显影原理, 可分负性胶和正性胶两类。 经  According to its chemical reaction mechanism and development principle, photoresist can be divided into two types: negative adhesive and positive adhesive. By
一个实施例中, 第一子层 21和第二子层 22釆用不同类型的光刻胶。 例如, 第一子层 21的第一感光材料为正光刻胶, 而第二子层 22的第二感光材料是 负光刻胶,第一子层 21的第一感光材料为负光刻胶,则第二子层的第二感光 材料就是正光刻胶。 In one embodiment, the first sub-layer 21 and the second sub-layer 22 employ different types of photoresist. For example, the first photosensitive material of the first sub-layer 21 is a positive photoresist, and the second photosensitive material of the second sub-layer 22 is a negative photoresist, and the first photosensitive material of the first sub-layer 21 is a negative photoresist. , the second sensitization of the second sub-layer The material is a positive photoresist.
在本发明的一个实施例中, 第一子层 21和第二子层 22釆用相同性质的 光刻胶, 就是说第一感光材料和第二感光材料均为正光刻胶, 或者第一感光 材料和第二感光材料均为负光刻胶。 在此情况下, 第一感光材料和第二感光 材料的不同之处是, 两者的碱可溶性树脂含量不同。 例如, 第一感光材料的 碱可溶性树脂的含量大于第二感光材料的碱可溶性树脂的含量。 例如, 第一 感光材料的碱可溶性树脂重量百分比为 5%-79%, 第二感光材料的碱可溶性 树脂重量百分比为 0.05%-30%。 这样在显影时, 釆用相同的碱溶剂可以较容 易的得到截面较窄的第一子层 21和截面较宽的第二子层 22, 从而得到截面 为上大下小形状的黑矩阵层 20。 在一个实施例中, 釆用如下的组分及比例, 第一感光材料包括: 重量百分比为 5%-45%的黑颜料、 重量百分比为 0.5%-67%的分散剂、 重量百分比为 0.05%-30%的分散树脂、 重量百分比为 5%-79%的碱可溶性树脂、 重量百分比为 2%-25%的乙烯基不饱和单体、 重量 百分比为 0.05%-10%的环氧树脂、 重量百分比为 20%-80%的溶剂、 重量百分 比为 0.05%-10%的光起始剂、 重量百分比为 0.01%-2%的改变表面张力的添 加剂。 第二感光材料包括: 重量百分比为 5%-45%的黑颜料、 重量百分比为 0.5%-67%的分散剂、 重量百分比为 0.05%-30%的分散树脂、 重量百分比为 0.05%-30%的碱可溶性树脂、 重量百分比为 2%-25%的乙烯基不饱和单体、 重量百分比为 0.05%-10%的环氧树脂、 重量百分比为 20%-80%的溶剂、 重量 百分比为 0.05%-10%的光起始剂、 重量百分比为 0.01%-2%的改变表面张力 的添力 p剂。  In one embodiment of the present invention, the first sub-layer 21 and the second sub-layer 22 are made of a photoresist of the same nature, that is, the first photosensitive material and the second photosensitive material are both positive photoresists, or first Both the photosensitive material and the second photosensitive material are negative photoresists. In this case, the first photosensitive material and the second photosensitive material are different in that the alkali-soluble resin contents of the two are different. For example, the content of the alkali-soluble resin of the first photosensitive material is greater than the content of the alkali-soluble resin of the second photosensitive material. For example, the first photosensitive material may have an alkali-soluble resin weight percentage of 5% to 79%, and the second photosensitive material may have an alkali-soluble resin weight percentage of 0.05% to 30%. Thus, during development, the first sub-layer 21 having a narrow cross section and the second sub-layer 22 having a wide cross-section can be easily obtained by using the same alkali solvent, thereby obtaining a black matrix layer 20 having a cross-sectional shape that is upper and lower. . In one embodiment, the first photosensitive material comprises: 5% to 45% by weight of black pigment, 0.5% to 67% by weight of dispersant, 0.05% by weight, based on the following components and ratios; -30% dispersion resin, 5% to 79% by weight of alkali-soluble resin, 2% to 25% by weight of ethylenically unsaturated monomer, 0.05% to 10% by weight of epoxy resin, weight The percentage is from 20% to 80% of the solvent, from 0.05% to 10% by weight of the photoinitiator, and from 0.01% to 2% by weight of the surface tension-modifying additive. The second photosensitive material comprises: 5%-45% by weight of black pigment, 0.5%-67% by weight of dispersant, 0.05%-30% by weight of dispersion resin, 0.05%-30% by weight Alkali-soluble resin, 2%-25% by weight of ethylenically unsaturated monomer, 0.05%-10% by weight of epoxy resin, 20%-80% by weight of solvent, 0.05% by weight - 10% of the photoinitiator, 0.01% to 2% by weight of the agent to change the surface tension.
在一个实施例中, 改变表面张力的添加剂可以釆用流平剂、 表面流动控 制剂和硅烷偶联剂。 乙婦基不饱和单体为多官能团丙烯酸酯单体。  In one embodiment, the additive that changes the surface tension may employ a leveling agent, a surface flow control, and a silane coupling agent. The ethylenically unsaturated monomer is a polyfunctional acrylate monomer.
本发明的另一个实施例提供一种彩色滤光片的制造方法, 用于制造如前 述的彩色滤光片, 如图 2所示, 包括:  Another embodiment of the present invention provides a method of fabricating a color filter for fabricating a color filter as described above, as shown in FIG.
步骤 101、 将其中分散有黑颜料的正光刻胶层涂于基板表面。  Step 101: Apply a positive photoresist layer in which a black pigment is dispersed to the surface of the substrate.
步骤 102、 将其中分散有黑颜料的负光刻胶层涂于正光刻胶层上。  Step 102: Apply a negative photoresist layer in which a black pigment is dispersed on the positive photoresist layer.
步骤 103、 釆用掩模板对上述负光刻胶层进行曝光, 并进行显影。  Step 103: Exposing the negative photoresist layer with a mask and performing development.
步骤 104、 直接对上述正光刻胶层进行曝光, 并进行显影, 形成截面为 上大下小形状的黑矩阵层以及截面为下大上小对应形状的次像素区域。 步骤 105、 在各个次像素区域中分别形成彩色滤光层。 Step 104: Directly exposing the positive photoresist layer and performing development to form a black matrix layer having a shape of a large upper and lower cross section and a sub-pixel region having a corresponding shape with a lower cross section and a smaller cross section. Step 105: Form a color filter layer in each sub-pixel region.
在本发明的一个实施例中, 由于基板上面涂有正光刻胶层, 在正光刻胶 层上涂有负光刻胶层, 因此在步骤 103中, 将掩模板置于负光刻胶层上, 对 希望保留下来的区域内的负光刻胶层进行曝光,再釆用相应的溶剂进行显影, 由于对于相应的溶剂, 负光刻胶曝光后形成不可溶性物质, 而没有曝光的区 域为可溶性物质, 这样进行显影后曝光区的负光刻胶被保留从而形成上部的 较宽的第二子层。 在步骤 104中, 不使用另外的掩模板, 而是釆用第二子层 作为掩模板直接对正光刻胶层进行曝光, 并进行显影, 因此, 除第二子层覆 盖的区域以外的区域(例如, 次像素区域) 中的正光刻胶层均被曝光。 正光 刻胶曝光后形成可溶性物质, 而没有曝光的区域仍然是不可溶性物质。 同时 由于第二子层的边缘部分的下方, 不可避免的会受到一定的光照, 因此第二 子层的边缘部分的下方的正光刻胶层也会变得可溶, 由此显影后正光刻胶层 保留的区域就会略小于负光刻胶层保留的区域。 结果, 如图 3所示, 在基板 10上形成黑矩阵层 20的截面为上大下小形状的部分以及对应的上小下大形 状的次像素区域 31。 最后如图 1所示,在次像素区域形成彩色滤光层 30。 为 了保证正光刻胶层和负光刻胶层不会相互渗透, 将正光刻胶层涂于基板表面 后, 进行前烘烤, 之后将负光刻胶层涂于正光刻胶上并再进行一次前烘烤。  In one embodiment of the present invention, since the substrate is coated with a positive photoresist layer and a negative photoresist layer is coated on the positive photoresist layer, in step 103, the mask is placed on the negative photoresist. On the layer, the negative photoresist layer in the area that is desired to be preserved is exposed, and then the corresponding solvent is used for development. Since the negative photoresist is exposed to the corresponding solvent, an insoluble matter is formed, and the exposed region is not exposed. As a soluble material, the negative photoresist in the exposed region is thus developed to form a wider second sub-layer of the upper portion. In step 104, instead of using a separate mask, the second sub-layer is used as a mask to directly expose the positive photoresist layer and perform development, thereby, except for the area covered by the second sub-layer. The positive photoresist layers in (eg, sub-pixel regions) are all exposed. The positive light gel is exposed to form a soluble substance, while the unexposed areas are still insoluble. At the same time, due to the underside of the edge portion of the second sub-layer, a certain amount of illumination is inevitably received, so that the positive photoresist layer under the edge portion of the second sub-layer becomes soluble, thereby developing the positive light. The area retained by the engraved layer is slightly smaller than the area retained by the negative photoresist layer. As a result, as shown in Fig. 3, the portion of the black matrix layer 20 having the upper and lower cross-sections and the corresponding sub-pixel region 31 having the upper and lower large shapes are formed on the substrate 10. Finally, as shown in Fig. 1, a color filter layer 30 is formed in the sub-pixel region. In order to ensure that the positive photoresist layer and the negative photoresist layer do not penetrate each other, after the positive photoresist layer is applied to the surface of the substrate, pre-baking is performed, and then the negative photoresist layer is coated on the positive photoresist. Make another pre-baking.
在本发明的另一实施例中, 在步骤 101中, 也可以是将其中分散有黑颜 料的负光刻胶层涂于基板表面, 而在步骤 102中, 将其中分散有黑颜料的正 光刻胶层涂于负光刻胶层上。 在步骤 103中, 釆用掩模板对上层的正光刻胶 层进行曝光, 并进行显影。 在步骤 104中直接对负光刻胶进行曝光, 并进行 显影, 形成截面为上大下小形状的黑矩阵层部分以及截面为下大上小对应形 状的次像素区域。  In another embodiment of the present invention, in step 101, a negative photoresist layer in which a black pigment is dispersed may be applied to the surface of the substrate, and in step 102, a positive light in which the black pigment is dispersed may be disposed. The adhesive layer is applied to the negative photoresist layer. In step 103, the upper photoresist layer is exposed by a mask and developed. In step 104, the negative photoresist is directly exposed and developed to form a black matrix layer portion having a cross-sectional shape that is upper and lower, and a sub-pixel region having a cross-sectional shape that is larger and smaller.
本发明的另一个实施例提供一种彩色滤光片的制造方法, 用于制造如前 述的彩色滤光片, 如图 4所示, 包括:  Another embodiment of the present invention provides a method of fabricating a color filter for fabricating a color filter as described above, as shown in FIG.
步骤 201、 将黑矩阵层的第一感光材料层涂于基板表面。  Step 201: Apply a first photosensitive material layer of the black matrix layer to the surface of the substrate.
步骤 202、 将黑矩阵层的第二感光材料层涂于第一感光材料层上。  Step 202: Apply a second photosensitive material layer of the black matrix layer to the first photosensitive material layer.
步骤 203、 釆用掩模板对第一感光材料层和第二感光材料层进行曝光, 并进行显影, 以形成截面为上大下小形状的黑矩阵层部分, 和截面为下大上 小对应形状的次像素区域。 步骤 204、 在次像素区域形成彩色滤光层。 Step 203: exposing the first photosensitive material layer and the second photosensitive material layer with a mask, and performing development to form a black matrix layer portion having a cross-sectional shape that is upper and lower, and a cross-sectional shape corresponding to a large upper and a lower Sub-pixel area. Step 204, forming a color filter layer in the sub-pixel region.
在本发明的一个实施例中, 第一感光材料层用于形成黑矩阵层部分的第 一子层, 第二感光材料层用于形成黑矩阵层部分的第二子层。 第一感光材料 层和第二感光材料层均为正光刻胶, 或者第一感光材料层和第二感光材料层 均为负光刻胶。 第一感光材料层中和第二感光材料层中例如均包括碱可溶性 树脂, 第一感光材料层中的碱可溶性树脂的含量大于第二感光材料层中的碱 可溶性树脂的含量。以第一感光材料层和第二感光材料层均为负光刻胶为例 , 釆用掩模板对第一感光材料层和第二感光材料层进行曝光, 掩模板置于第二 感光材料膜层上方, 对希望保留第一感光材料层和第二感光材料层的的区域 (例如, 次像素区域之间的区域)进行曝光, 再釆用相应的溶剂进行显影。 由于对于相应的溶剂, 负光刻胶曝光后变得不可溶, 而没有曝光的区域的负 光刻胶仍为可溶, 这样进行显影后曝光区的负光刻胶被保留从而形成黑矩阵 层。 在本实施例中, 第一感光材料层和第二感光材料层的曝光区相同, 由于 下面的第一感光材料层的碱可溶性树脂的含量, 大于上面的第二感光材料层 的碱可溶性树脂的含量, 因此在显影时, 下面的第一感光材料层被去除的部 分的较多, 而上面的第二感光材料层被去除的部分较少。 结果,如图 3所示, 在基板 10上形成截面为上大下小形状的黑矩阵层 20以及对应的上小下大形 状的次像素区域 31。 最后如图 1所示, 在次像素区域中填充彩色滤光层 30。 为了保证正光刻胶层和负光刻胶层不会相互渗透, 将正光刻胶层涂于基板表 面后, 进行前烘烤, 之后将负光刻胶层涂于正光刻胶层上并再进行一次前烘 烤。  In one embodiment of the invention, the first photosensitive material layer is used to form a first sub-layer of the black matrix layer portion, and the second photosensitive material layer is used to form a second sub-layer of the black matrix layer portion. The first photosensitive material layer and the second photosensitive material layer are both positive photoresists, or both the first photosensitive material layer and the second photosensitive material layer are negative photoresists. The first photosensitive material layer and the second photosensitive material layer each include, for example, an alkali-soluble resin, and the content of the alkali-soluble resin in the first photosensitive material layer is larger than the content of the alkali-soluble resin in the second photosensitive material layer. Taking the first photosensitive material layer and the second photosensitive material layer as negative photoresists as an example, the first photosensitive material layer and the second photosensitive material layer are exposed by a mask, and the mask is placed on the second photosensitive material film layer. Above, a region where it is desired to retain the first photosensitive material layer and the second photosensitive material layer (for example, a region between sub-pixel regions) is exposed, and then developed with a corresponding solvent. Since the negative photoresist becomes insoluble after exposure to the corresponding solvent, the negative photoresist in the unexposed region is still soluble, so that the negative photoresist in the exposed region is left after development to form a black matrix layer. . In this embodiment, the exposed areas of the first photosensitive material layer and the second photosensitive material layer are the same, because the content of the alkali-soluble resin of the first photosensitive material layer below is larger than the alkali-soluble resin of the upper second photosensitive material layer. The content, therefore, at the time of development, the lower portion of the first photosensitive material layer is removed more, and the portion of the upper second photosensitive material layer removed is less. As a result, as shown in Fig. 3, a black matrix layer 20 having a shape of a large upper and lower cross section and a corresponding sub-pixel region 31 of a large upper and lower large shape are formed on the substrate 10. Finally, as shown in Fig. 1, the color filter layer 30 is filled in the sub-pixel region. In order to ensure that the positive photoresist layer and the negative photoresist layer do not penetrate each other, the positive photoresist layer is applied to the surface of the substrate, pre-baking, and then the negative photoresist layer is applied on the positive photoresist layer. And do another pre-baking.
( 1 )彩色滤光片, 包括形成于基板上的限定出多个次像素区域的黑矩阵 层, 以及形成于黑矩阵层限定的多个次像素区域中的多个彩色滤光层, 其中 黑矩阵层在两个相邻次像素区域之间的部分具有上大下小形状的截面, 和彩 色滤光层形成为具有下大上小对应形状的截面, 所述黑矩阵层部分与所述彩 色滤光层之间具有重叠的区域, 且重叠区域内的黑矩阵层与彩色滤光层的厚 度之和等于非重叠区域的黑矩阵层或彩色滤光层的厚度。 (1) a color filter comprising: a black matrix layer defined on the substrate defining a plurality of sub-pixel regions; and a plurality of color filter layers formed in the plurality of sub-pixel regions defined by the black matrix layer, wherein the black a portion of the matrix layer between two adjacent sub-pixel regions having a cross section of a large upper and lower small shape, and a color filter layer formed into a cross section having a corresponding shape of a lower large and small upper, the black matrix layer portion and the color There are overlapping regions between the filter layers, and the sum of the thicknesses of the black matrix layer and the color filter layer in the overlap region is equal to the thickness of the black matrix layer or the color filter layer of the non-overlapping region.
( 2 )根据(1 ) 的彩色滤光片, 其中, 所述黑矩阵层部分的截面形状与 所述彩色滤光层的截面的形状互补。 ( 3 )才艮据( 1 )或( 2 )的彩色滤光片, 其中, 所述黑矩阵层部分的截面 形状为倒台阶形,包括下部宽度较窄的第一子层和上部宽度较宽的第二子层, 彩色滤光层的截面形状为正台阶形。 (2) The color filter according to (1), wherein a cross-sectional shape of the black matrix layer portion is complementary to a shape of a cross section of the color filter layer. (3) The color filter according to (1) or (2), wherein the black matrix layer portion has an inverted step shape, and includes a first sub-layer having a narrow lower width and a wider upper portion. The second sub-layer, the cross-sectional shape of the color filter layer is a positive step shape.
( 4 )根据(3 ) 的彩色滤光片, 其中第一子层的第一感光材料为正光刻 胶, 第二子层的第二感光材料为负光刻胶; 或者  (4) The color filter according to (3), wherein the first photosensitive material of the first sub-layer is a positive photoresist, and the second photosensitive material of the second sub-layer is a negative photoresist; or
第一子层的第一感光材料为负光刻胶, 第二子层的第二感光材料为正光 刻胶。  The first photosensitive material of the first sub-layer is a negative photoresist, and the second photosensitive material of the second sub-layer is a positive photoresist.
( 5 )根据(3 ) 的彩色滤光片, 其中第一子层的第一感光材料中和第二 子层的第二感光材料中均包括碱可溶性树脂, 第一感光材料的碱可溶性树脂 的含量大于第二感光材料的碱可溶性树脂的含量, 第一感光材料和第二感光 材料均为正光刻胶, 或第一感光材料和第二感光材料均为负光刻胶。  (5) The color filter according to (3), wherein the first photosensitive material of the first sub-layer and the second photosensitive material of the second sub-layer each comprise an alkali-soluble resin, and the alkali-soluble resin of the first photosensitive material The content of the alkali-soluble resin is greater than that of the second photosensitive material, the first photosensitive material and the second photosensitive material are both positive photoresists, or the first photosensitive material and the second photosensitive material are both negative photoresists.
( 6 )根据(5 ) 的彩色滤光片, 其中第一感光材料的碱可溶性树脂重量 百分比为 5%-79%,第二感光材料的碱可溶性树脂重量百分比为 0.05%-30%。  (6) The color filter according to (5), wherein the alkali photosensitive resin of the first photosensitive material is from 5% to 79% by weight, and the alkali-soluble resin of the second photosensitive material is from 0.05% to 30% by weight.
( 7 )根据(6 ) 的彩色滤光片, 其中, 第一感光材料还包括: 重量百分 比为 5%-45%的黑颜料、 重量百分比为 0.5%-67%的分散剂、 重量百分比为 (7) The color filter according to (6), wherein the first photosensitive material further comprises: a black pigment having a weight percentage of 5% to 45%, a dispersant having a weight percentage of 0.5% to 67%, and a weight percentage of
0.05%-30%的分散树脂、 重量百分比为 2%-25%的乙烯基不饱和单体、 重量 百分比为 0.05%-10%的环氧树脂、 重量百分比为 20%-80%的溶剂、 重量百分 比为 0.05%-10%的光起始剂、 重量百分比为 0.01%-2%的改变表面张力的添 加剂, 第二感光材料还包括: 重量百分比为 5%-45%的黑颜料、 重量百分比 为 0.5%-67%的分散剂、 重量百分比为 0.05%-30%的分散树脂、 重量百分比 为 2%-25%的乙婦基不饱和单体、 重量百分比为 0.05%-10%的环氧树脂、 重 量百分比为 20%-80%的溶剂、 重量百分比为 0.05%-10%的光起始剂、 重量百 分比为 0.01 %-2%的改变表面张力的添加剂。 0.05%-30% dispersion resin, 2%-25% by weight of ethylenically unsaturated monomer, 0.05%-10% by weight of epoxy resin, 20%-80% by weight of solvent, weight The percentage of 0.05%-10% of the photoinitiator, 0.01%-2% by weight of the surface tension-modifying additive, the second photosensitive material further comprises: 5%-45% by weight of black pigment, the weight percentage is 0.5%-67% dispersant, 0.05%-30% by weight of dispersion resin, 2%-25% by weight of ethylglycolically unsaturated monomer, 0.05%-10% by weight of epoxy resin The solvent is 20%-80% by weight, the photo-initiator is 0.05%-10% by weight, and the surface tension-changing additive is 0.01%-2% by weight.
( 8 )根据(7 )的彩色滤光片, 其中, 改变表面张力的添加剂为流平剂、 表面流动控制剂和硅烷偶联剂。  (8) The color filter according to (7), wherein the additive that changes the surface tension is a leveling agent, a surface flow controlling agent, and a silane coupling agent.
( 9 )根据(7 )所述的彩色滤光片, 其中, 乙烯基不饱和单体为多官能 团丙烯酸酯单体。  (9) The color filter according to (7), wherein the ethylenically unsaturated monomer is a polyfunctional acrylate monomer.
( 10 )彩色滤光片的制造方法, 用于制造(1 )至(8 ) 中任一项的彩色 滤光片, 包括:  (10) A method of producing a color filter, comprising the color filter of any one of (1) to (8), comprising:
将其中分散有黑颜料的第一类别光刻胶层涂于基板表面; 将其中分散有黑颜料的第二类别光刻胶层涂于所述第一类别光刻胶层 上, 其中第一类别光刻胶层为正光刻胶和负光刻胶中的一种, 第二类别光刻 胶层为正光刻胶和负光刻胶中的另一种; Applying a first type of photoresist layer in which a black pigment is dispersed to the surface of the substrate; Applying a second type of photoresist layer in which a black pigment is dispersed, to the first type of photoresist layer, wherein the first type of photoresist layer is one of a positive photoresist and a negative photoresist, The second type of photoresist layer is another one of a positive photoresist and a negative photoresist;
釆用掩模板对所述第二类别光刻胶层进行曝光, 并进行显影;  Exposing the second type of photoresist layer with a mask and performing development;
直接对所述第一类别光刻胶层进行曝光, 并进行显影, 形成截面为上大 下小形状的黑矩阵层部分和, 和截面为下大上小对应形状的次像素区域; 在次像素区域中形成彩色滤光层。  Exposing the first type of photoresist layer directly, and performing development to form a black matrix layer portion having a cross-sectional shape that is upper and lower, and a sub-pixel region having a cross-sectional shape that is larger in size and smaller in size; A color filter layer is formed in the area.
( 11 )根据 ( 10 ) 的彩色滤光片的制造方法, 还包括, 将所述第一类别 光刻胶层涂于基板表面后, 进行一次前烘烤, 以及将所述第二类别光刻胶层 涂于第一类别光刻胶层上之后并再进行一次前烘烤。  (11) The method of manufacturing a color filter according to (10), further comprising: applying a first type of photoresist layer to the surface of the substrate, performing a pre-baking, and photolithography of the second category After the adhesive layer is applied to the first type of photoresist layer, a pre-baking is performed.
( 12 )彩色滤光片的制造方法, 用于制造(1 )至(8 )任一项的彩色滤 光片, 包括:  (12) A method of producing a color filter, comprising the color filter of any one of (1) to (8), comprising:
将黑矩阵层的第一感光材料层涂于基板表面;  Coating a first photosensitive material layer of the black matrix layer on the surface of the substrate;
将黑矩阵层的第二感光材料层涂于黑矩阵层的第一感光材料层上, 第一 感光材料层和第二感光材料层为正光刻胶, 或者第一感光材料层和第二感光 材料层为负光刻胶, 其中第一感光材料层中和第二感光材料层中均包括碱可 溶性树脂, 第一感光材料层的碱可溶性树脂的含量大于第二感光材料层的碱 可溶性树脂的含量;  Applying a second photosensitive material layer of the black matrix layer to the first photosensitive material layer of the black matrix layer, the first photosensitive material layer and the second photosensitive material layer being positive photoresist, or the first photosensitive material layer and the second photosensitive material The material layer is a negative photoresist, wherein the first photosensitive material layer and the second photosensitive material layer both comprise an alkali-soluble resin, and the content of the alkali-soluble resin of the first photosensitive material layer is greater than that of the alkali-soluble resin of the second photosensitive material layer; Content
釆用掩模板对第一感光材料层和第二感光材料层进行曝光,并进行显影, 形成截面为上大下小形状的黑矩阵层, 和截面为下大上小对应形状的次像素 区域;  Exposing the first photosensitive material layer and the second photosensitive material layer with a mask, and performing development to form a black matrix layer having a cross-sectional shape that is upper and lower, and a sub-pixel region having a correspondingly large and small cross-sectional shape;
在次像素区域中形成彩色滤光层。  A color filter layer is formed in the sub-pixel region.
( 13 )根据 ( 12 ) 的彩色滤光片的制造方法, 还包括将黑矩阵层的第一 感光材料层涂于基板表面后, 进行一次前烘烤, 以及将黑矩阵层的第二感光 材料层涂于黑矩阵层的第一感光材料层上之后再进行一次前烘烤。  (13) The method of manufacturing a color filter according to (12), further comprising: applying a first photosensitive material layer of the black matrix layer to the surface of the substrate, performing a pre-baking, and a second photosensitive material of the black matrix layer; A layer of pre-baking is performed after the layer is applied to the first photosensitive material layer of the black matrix layer.
在本申请的实施例中, 由于黑矩阵层和彩色滤光层具有重叠的区域, 且 重叠区域的膜层厚度和非重叠区域的膜层厚度相同, 从而无需制作平坦层, 制造工艺简单。  In the embodiment of the present application, since the black matrix layer and the color filter layer have overlapping regions, and the film thickness of the overlap region and the film thickness of the non-overlapping region are the same, it is not necessary to form a flat layer, and the manufacturing process is simple.
虽然上文中已经用一般性说明及具体实施方式, 对本发明作了详尽的描 述, 但在本发明基础上, 可以对之作一些修改或改进, 这对本领域技术人员 而言是显而易见的。 因此, 在不偏离本发明精神的基础上所做的这些修改或 改进, 均属于本发明要求保护的范围。 Although the present invention has been described in detail above with reference to the preferred embodiments and specific embodiments, the invention may be modified or modified by those skilled in the art. It is obvious. Therefore, such modifications or improvements made without departing from the spirit of the invention are intended to be within the scope of the invention.

Claims

权利要求书 Claim
1.彩色滤光片,包括形成于基板上的限定出多个次像素区域的黑矩阵层, 以及形成于黑矩阵层限定的多个次像素区域中的多个彩色滤光层, 其中黑矩 阵层在两个相邻次像素区域之间的部分具有上大下小形状的截面, 和彩色滤 光层形成为具有下大上小对应形状的截面, 所述黑矩阵层部分与所述彩色滤 光层之间具有重叠的区域, 且重叠区域内的黑矩阵层与彩色滤光层的厚度之 和等于非重叠区域的黑矩阵层或彩色滤光层的厚度。 A color filter comprising: a black matrix layer defined on a substrate defining a plurality of sub-pixel regions, and a plurality of color filter layers formed in a plurality of sub-pixel regions defined by the black matrix layer, wherein the black matrix a portion of the layer between two adjacent sub-pixel regions having a cross section of a large upper and lower small shape, and a color filter layer formed to have a cross section having a corresponding shape of a lower large and small upper, the black matrix layer portion and the color filter There are overlapping regions between the light layers, and the sum of the thicknesses of the black matrix layer and the color filter layer in the overlapping region is equal to the thickness of the black matrix layer or the color filter layer of the non-overlapping region.
2. 根据权利要求 1所述的彩色滤光片, 其中, 所述黑矩阵层部分的截面 形状与所述彩色滤光层的截面的形状互补。  The color filter according to claim 1, wherein a cross-sectional shape of the black matrix layer portion is complementary to a shape of a cross section of the color filter layer.
3. 根据权利要求 1或 2所述的彩色滤光片, 其中, 所述黑矩阵层部分的 截面形状为倒台阶形, 包括下部宽度较窄的第一子层和上部宽度较宽的第二 子层, 彩色滤光层的截面形状为正台阶形。  The color filter according to claim 1 or 2, wherein a cross-sectional shape of the black matrix layer portion is an inverted step shape, including a first sub-layer having a lower width and a second width having a wider upper portion The sub-layer, the cross-sectional shape of the color filter layer is a positive step shape.
4.根据权利要求 3所述的彩色滤光片,其中第一子层的第一感光材料为 正光刻胶, 第二子层的第二感光材料为负光刻胶; 或者  4. The color filter according to claim 3, wherein the first photosensitive material of the first sub-layer is a positive photoresist, and the second photosensitive material of the second sub-layer is a negative photoresist; or
第一子层的第一感光材料为负光刻胶, 第二子层的第二感光材料为正光 刻胶。  The first photosensitive material of the first sub-layer is a negative photoresist, and the second photosensitive material of the second sub-layer is a positive photoresist.
5.根据权利要求 3所述的彩色滤光片,其中第一子层的第一感光材料中 和第二子层的第二感光材料中均包括碱可溶性树脂, 第一感光材料的碱可溶 性树脂的含量大于第二感光材料的碱可溶性树脂的含量, 第一感光材料和第 二感光材料均为正光刻胶, 或第一感光材料和第二感光材料均为负光刻胶。  The color filter according to claim 3, wherein an alkali-soluble resin, an alkali-soluble resin of the first photosensitive material, is included in the first photosensitive material of the first sub-layer and the second photosensitive material of the second sub-layer The content of the alkali-soluble resin is greater than that of the second photosensitive material, the first photosensitive material and the second photosensitive material are both positive photoresists, or the first photosensitive material and the second photosensitive material are both negative photoresists.
6.根据权利要求 5所述的彩色滤光片,其中第一感光材料的碱可溶性树 脂重量百分比为 5%-79% , 第二感光材料的碱可溶性树脂重量百分比为 0.05%-30%。  The color filter according to claim 5, wherein the first photosensitive material has an alkali-soluble resin weight percentage of 5% to 79%, and the second photosensitive material has an alkali-soluble resin weight percentage of 0.05% to 30%.
7. 根据权利要求 6所述的彩色滤光片, 其中, 第一感光材料还包括: 重 量百分比为 5%-45%的黑颜料、 重量百分比为 0.5%-67%的分散剂、 重量百分 比为 0.05%-30%的分散树脂、 重量百分比为 2%-25%的乙烯基不饱和单体、 重量百分比为 0.05%-10%的环氧树脂、 重量百分比为 20%-80%的溶剂、 重量 百分比为 0.05%-10%的光起始剂、 重量百分比为 0.01%-2%的改变表面张力 的添加剂, 第二感光材料还包括: 重量百分比为 5%-45%的黑颜料、 重量百 分比为 0.5%-67%的分散剂、 重量百分比为 0.05%-30%的分散树脂、 重量百 分比为 2%-25%的乙婦基不饱和单体、重量百分比为 0.05%-10%的环氧树脂、 重量百分比为 20%-80%的溶剂、 重量百分比为 0.05%-10%的光起始剂、 重量 百分比为 0.01%-2%的改变表面张力的添加剂。 The color filter according to claim 6, wherein the first photosensitive material further comprises: 5% to 45% by weight of a black pigment, 0.5% to 67% by weight of a dispersant, and a weight percentage of 0.05%-30% dispersion resin, 2%-25% by weight of ethylenically unsaturated monomer, 0.05%-10% by weight of epoxy resin, 20%-80% by weight of solvent, weight The percentage is from 0.05% to 10% of the photoinitiator, and the weight percentage is from 0.01% to 2% of the additive for changing the surface tension. The second photosensitive material further comprises: 5% to 45% by weight of black pigment, and 100% by weight. a dispersant in a ratio of 0.5% to 67%, a dispersion resin in a weight percentage of 0.05% to 30%, an ethyl ester-based unsaturated monomer in an amount of 2% to 25% by weight, and a weight percentage of 0.05% to 10%. Epoxy resin, 20%-80% by weight of solvent, 0.05%-10% by weight of photoinitiator, 0.01%-2% by weight of surface tension-modifying additive.
8. 根据权利要求 7所述的彩色滤光片, 其中, 改变表面张力的添加剂为 流平剂、 表面流动控制剂和硅烷偶联剂。  The color filter according to claim 7, wherein the additive that changes the surface tension is a leveling agent, a surface flow controlling agent, and a silane coupling agent.
9. 根据权利要求 7所述的彩色滤光片, 其中, 乙烯基不饱和单体为多官 能团丙烯酸酯单体。  The color filter according to claim 7, wherein the ethylenically unsaturated monomer is a polyfunctional acrylate monomer.
10. 彩色滤光片的制造方法, 用于制造如权利要求 1至 8中任一项所述 的彩色滤光片, 包括:  A method of manufacturing a color filter for manufacturing the color filter according to any one of claims 1 to 8, comprising:
将其中分散有黑颜料的第一类别光刻胶层涂于基板表面;  Applying a first type of photoresist layer in which a black pigment is dispersed to the surface of the substrate;
将其中分散有黑颜料的第二类别光刻胶层涂于所述第一类别光刻胶层 上, 其中第一类别光刻胶层为正光刻胶和负光刻胶中的一种, 第二类别光刻 胶层为正光刻胶和负光刻胶中的另一种;  Applying a second type of photoresist layer in which a black pigment is dispersed, to the first type of photoresist layer, wherein the first type of photoresist layer is one of a positive photoresist and a negative photoresist, The second type of photoresist layer is another one of a positive photoresist and a negative photoresist;
釆用掩模板对所述第二类别光刻胶层进行曝光, 并进行显影;  Exposing the second type of photoresist layer with a mask and performing development;
直接对所述第一类别光刻胶层进行曝光, 并进行显影, 形成截面为上大 下小形状的黑矩阵层部分, 和截面为下大上小对应形状的次像素区域;  Exposing the first type of photoresist layer directly, and performing development to form a black matrix layer portion having a cross-sectional shape that is upper and lower, and a sub-pixel region having a cross-sectional shape that is larger in size and smaller in size;
在次像素区域中形成彩色滤光层。  A color filter layer is formed in the sub-pixel region.
11. 根据权利要求 10所述的彩色滤光片的制造方法, 还包括, 将所述第 一类别光刻胶层涂于基板表面后, 进行一次前烘烤, 以及将所述第二类别光 刻胶层涂于第一类别光刻胶层上之后并再进行一次前烘烤。  11. The method of manufacturing a color filter according to claim 10, further comprising: applying a first type of photoresist layer to the surface of the substrate, performing a pre-baking, and applying the second type of light After the adhesive layer is applied to the first type of photoresist layer, a pre-baking is performed.
12. 彩色滤光片的制造方法, 用于制造如权利要求 1至 8中任一项所述 的彩色滤光片, 包括:  A method of manufacturing a color filter, for manufacturing the color filter according to any one of claims 1 to 8, comprising:
将黑矩阵层的第一感光材料层涂于基板表面;  Coating a first photosensitive material layer of the black matrix layer on the surface of the substrate;
将黑矩阵层的第二感光材料层涂于黑矩阵层的第一感光材料层上, 第一 感光材料层和第二感光材料层为正光刻胶, 或者第一感光材料层和第二感光 材料层为负光刻胶, 其中第一感光材料层中和第二感光材料层中均包括碱可 溶性树脂, 第一感光材料层的碱可溶性树脂的含量大于第二感光材料层的碱 可溶性树脂的含量;  Applying a second photosensitive material layer of the black matrix layer to the first photosensitive material layer of the black matrix layer, the first photosensitive material layer and the second photosensitive material layer being positive photoresist, or the first photosensitive material layer and the second photosensitive material The material layer is a negative photoresist, wherein the first photosensitive material layer and the second photosensitive material layer both comprise an alkali-soluble resin, and the content of the alkali-soluble resin of the first photosensitive material layer is greater than that of the alkali-soluble resin of the second photosensitive material layer; Content
釆用掩模板对第一感光材料层和第二感光材料层进行曝光,并进行显影, 形成截面为上大下小形状的黑矩阵层部分, 和截面为下大上小对应形状的次 像素区域; Exposing the first photosensitive material layer and the second photosensitive material layer with a mask and developing the film Forming a black matrix layer portion having a cross-sectional shape that is upper and lower, and a sub-pixel region having a cross-sectional shape that is larger in size and smaller in size;
在次像素区域中形成彩色滤光层。  A color filter layer is formed in the sub-pixel region.
13. 根据权利要求 12所述的彩色滤光片的制造方法,还包括将黑矩阵层 的第一感光材料层涂于基板表面后, 进行一次前烘烤, 以及将黑矩阵层的第 二感光材料层涂于黑矩阵层的第一感光材料层上之后再进行一次前烘烤。  13. The method of manufacturing a color filter according to claim 12, further comprising: applying a first photosensitive material layer of the black matrix layer to the surface of the substrate, performing a pre-baking, and second sensitizing the black matrix layer. The material layer is applied to the first photosensitive material layer of the black matrix layer and then pre-baked.
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