WO2013025106A1 - Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up - Google Patents
Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up Download PDFInfo
- Publication number
- WO2013025106A1 WO2013025106A1 PCT/NL2012/050573 NL2012050573W WO2013025106A1 WO 2013025106 A1 WO2013025106 A1 WO 2013025106A1 NL 2012050573 W NL2012050573 W NL 2012050573W WO 2013025106 A1 WO2013025106 A1 WO 2013025106A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- solution
- acid
- carboxylic acid
- magnesium
- precipitation
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/03—Preparation from chlorides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/03—Preparation from chlorides
- C01B7/035—Preparation of hydrogen chloride from chlorides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/02—Magnesia
- C01F5/06—Magnesia by thermal decomposition of magnesium compounds
- C01F5/10—Magnesia by thermal decomposition of magnesium compounds by thermal decomposition of magnesium chloride with water vapour
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/26—Magnesium halides
- C01F5/30—Chlorides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C55/00—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
- C07C55/02—Dicarboxylic acids
- C07C55/10—Succinic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C55/00—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
- C07C55/02—Dicarboxylic acids
- C07C55/14—Adipic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/13—Dicarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/13—Dicarboxylic acids
- C07C57/15—Fumaric acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/235—Saturated compounds containing more than one carboxyl group
- C07C59/245—Saturated compounds containing more than one carboxyl group containing hydroxy or O-metal groups
- C07C59/265—Citric acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
Abstract
Description
Claims
Priority Applications (15)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/NL2012/050573 WO2013025106A1 (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
EA201490410A EA027342B1 (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acid from its magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
CN201280046341.1A CN103813978A (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
AU2012295626A AU2012295626B2 (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
EP12750877.8A EP2744746B1 (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
PL12750877T PL2744746T3 (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
US14/238,633 US9061986B2 (en) | 2011-08-16 | 2012-08-16 | Acid/salt separation |
ES12750877T ES2849298T3 (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acid from its magnesium salts by precipitation with hydrochloric acid, useful for making fermentation broths |
CA2844204A CA2844204C (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
BR112014003067A BR112014003067A2 (en) | 2011-08-16 | 2012-08-16 | recovery of carboxylic acid from magnesium salts thereof through precipitation using hydrochloric acid, useful for fermentation broth work |
JP2014525959A JP6275038B2 (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acids from their magnesium salts by precipitation with hydrochloric acid, useful for fermentation broth treatment |
EA201790354A EA039483B1 (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acid from magnesium salts thereof by precipitation using hydrochloric acid, useful for fermentation broth work-up |
KR1020147006791A KR101974904B1 (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
UAA201402155A UA114484C2 (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
ZA2014/01745A ZA201401745B (en) | 2011-08-16 | 2014-03-10 | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid,useful for fermentation broth work-up |
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11177633.2 | 2011-08-16 | ||
EP11177633 | 2011-08-16 | ||
US201161524353P | 2011-08-17 | 2011-08-17 | |
US61/524,353 | 2011-08-17 | ||
PCT/NL2012/050573 WO2013025106A1 (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2013025106A1 true WO2013025106A1 (en) | 2013-02-21 |
Family
ID=50263170
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/NL2012/050573 WO2013025106A1 (en) | 2011-08-16 | 2012-08-16 | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
Country Status (13)
Country | Link |
---|---|
US (1) | US9061986B2 (en) |
EP (1) | EP2744746B1 (en) |
JP (1) | JP6275038B2 (en) |
KR (1) | KR101974904B1 (en) |
CN (1) | CN103813978A (en) |
AU (1) | AU2012295626B2 (en) |
BR (1) | BR112014003067A2 (en) |
CA (1) | CA2844204C (en) |
EA (2) | EA039483B1 (en) |
PL (1) | PL2744746T3 (en) |
UA (1) | UA114484C2 (en) |
WO (1) | WO2013025106A1 (en) |
ZA (1) | ZA201401745B (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL2011027C2 (en) * | 2013-06-24 | 2014-12-29 | Univ Delft Tech | Process for the preparation of 2,5-furandicarboxylic acid. |
EP2821368A1 (en) | 2013-07-03 | 2015-01-07 | PURAC Biochem BV | Method for processing magnesium chloride solutions |
WO2016146752A1 (en) | 2015-03-17 | 2016-09-22 | Purac Biochem Bv | Method for manufacturing furan-2,5-dicarboxylic acid (fdca) from a solid salt |
US9550712B2 (en) | 2011-08-16 | 2017-01-24 | Purac Biochem B.V. | Acid/salt separation |
CN108473331A (en) * | 2016-01-19 | 2018-08-31 | 普拉克生化公司 | The method for handling the improved method of magnesium chloride solution and preparing carboxylic acid |
WO2021214025A1 (en) | 2020-04-20 | 2021-10-28 | Purac Biochem B.V. | Process for manufacturing high-purity magnesium oxide |
US11261467B2 (en) | 2014-04-01 | 2022-03-01 | Purac Biochem B.V. | Thermal decomposition of magnesium chloride |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2020045349A (en) * | 2011-08-16 | 2020-03-26 | ピュラック バイオケム ビー. ブイ. | Recovery of carboxylic acids from magnesium salts thereof through precipitation using hydrochloric acid, useful for fermentation broth processing |
MY181005A (en) * | 2011-08-16 | 2020-12-15 | Purac Biochem Bv | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
DE102014015958A1 (en) | 2014-10-31 | 2016-05-04 | Sig Technology Ag | Device, in particular for closing a head region of a food container, of a laminate with peeled and folded edge region |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6660505B2 (en) * | 2000-06-22 | 2003-12-09 | Cognis Corporation | Isolation of carboxylic acids from fermentation broth |
KR20100122773A (en) * | 2009-05-13 | 2010-11-23 | 삼성석유화학(주) | Process for separating and purifying succinic acid from fermentation broth |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IL8722A (en) * | 1954-12-08 | Joseph Jacob Aman | a method for the thermal decomposition of metallic chlorides and sulphates to their corresponding oxides and acids | |
IL126264A0 (en) * | 1998-09-17 | 1999-05-09 | Tami Inst For Research & Dev L | Process for preparing lactic acid |
AU1738101A (en) * | 1999-10-25 | 2001-05-08 | Nedmag Industries Mining And Manufacturing B.V. | Magnesium oxide, a mixture of metal oxides, methods for preparation thereof and the use of the materials as frac proppant |
US6670505B1 (en) * | 2000-03-07 | 2003-12-30 | Eastman Chemical Company | Process for the recovery of organic acids from aqueous solutions |
JP4631706B2 (en) | 2003-09-30 | 2011-02-16 | 味の素株式会社 | Method for purifying succinic acid from fermentation broth |
US8431372B2 (en) * | 2009-06-19 | 2013-04-30 | Mbi International | Fermentation method using a magnesium compound containing oxygen |
CN101748161B (en) * | 2010-01-19 | 2012-06-06 | 南京工业大学 | Succinic acid purification process through anaerobic fermentation |
US8829237B2 (en) * | 2011-03-03 | 2014-09-09 | The Michigan Biotechnology Institute | Production of carboxylic acid and salt co-products |
AU2012295627B2 (en) * | 2011-08-16 | 2016-05-12 | Purac Biochem B.V. | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
MY181005A (en) * | 2011-08-16 | 2020-12-15 | Purac Biochem Bv | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
-
2012
- 2012-08-16 EA EA201790354A patent/EA039483B1/en unknown
- 2012-08-16 BR BR112014003067A patent/BR112014003067A2/en not_active Application Discontinuation
- 2012-08-16 CA CA2844204A patent/CA2844204C/en active Active
- 2012-08-16 US US14/238,633 patent/US9061986B2/en active Active
- 2012-08-16 EP EP12750877.8A patent/EP2744746B1/en active Active
- 2012-08-16 JP JP2014525959A patent/JP6275038B2/en active Active
- 2012-08-16 CN CN201280046341.1A patent/CN103813978A/en active Pending
- 2012-08-16 EA EA201490410A patent/EA027342B1/en not_active IP Right Cessation
- 2012-08-16 WO PCT/NL2012/050573 patent/WO2013025106A1/en active Application Filing
- 2012-08-16 PL PL12750877T patent/PL2744746T3/en unknown
- 2012-08-16 AU AU2012295626A patent/AU2012295626B2/en not_active Ceased
- 2012-08-16 KR KR1020147006791A patent/KR101974904B1/en active IP Right Grant
- 2012-08-16 UA UAA201402155A patent/UA114484C2/en unknown
-
2014
- 2014-03-10 ZA ZA2014/01745A patent/ZA201401745B/en unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6660505B2 (en) * | 2000-06-22 | 2003-12-09 | Cognis Corporation | Isolation of carboxylic acids from fermentation broth |
KR20100122773A (en) * | 2009-05-13 | 2010-11-23 | 삼성석유화학(주) | Process for separating and purifying succinic acid from fermentation broth |
Non-Patent Citations (1)
Title |
---|
DATABASE WPI Derwent World Patents Index; AN 2010-Q37198 * |
Cited By (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10508069B2 (en) | 2011-08-16 | 2019-12-17 | Purac Biochem B.V. | Acid/salt separation |
US9550712B2 (en) | 2011-08-16 | 2017-01-24 | Purac Biochem B.V. | Acid/salt separation |
US10071948B2 (en) | 2011-08-16 | 2018-09-11 | Purac Biochem B.V. | Acid/salt separation |
US10017446B2 (en) | 2011-08-16 | 2018-07-10 | Purac Biochem B.V. | Acid/salt separation |
NL2011027C2 (en) * | 2013-06-24 | 2014-12-29 | Univ Delft Tech | Process for the preparation of 2,5-furandicarboxylic acid. |
WO2014209112A1 (en) * | 2013-06-24 | 2014-12-31 | Technische Universiteit Delft | Process for the preparation of 2,5-furandicarboxylic acid |
US9938547B2 (en) | 2013-06-24 | 2018-04-10 | Technische Universiteit Delft | Process for the preparation of 2,5-furandicarboxylic acid |
CN107955821B (en) * | 2013-07-03 | 2021-07-16 | 普拉克生化公司 | Process for producing carboxylic acid |
US10106821B2 (en) | 2013-07-03 | 2018-10-23 | Purac Biochem B.V. | Method for processing magnesium chloride solutions |
CN107955821A (en) * | 2013-07-03 | 2018-04-24 | 普拉克生化公司 | The method for preparing carboxylic acid |
JP2018083753A (en) * | 2013-07-03 | 2018-05-31 | ピュラック バイオケム ビー. ブイ. | Method of processing magnesium chloride solution |
EP3330225A1 (en) | 2013-07-03 | 2018-06-06 | Purac Biochem bv | Method for manufacturing a carboxylic acid |
EP2821368A1 (en) | 2013-07-03 | 2015-01-07 | PURAC Biochem BV | Method for processing magnesium chloride solutions |
CN105358484A (en) * | 2013-07-03 | 2016-02-24 | 普拉克生化公司 | Method for processing magnesium chloride solutions |
WO2015000956A1 (en) | 2013-07-03 | 2015-01-08 | Purac Biochem Bv | Method for processing magnesium chloride solutions |
KR101875378B1 (en) * | 2013-07-03 | 2018-07-06 | 푸락 바이오켐 비.브이. | Method for processing magnesium chloride solutions |
US11261467B2 (en) | 2014-04-01 | 2022-03-01 | Purac Biochem B.V. | Thermal decomposition of magnesium chloride |
US11326188B2 (en) | 2014-04-01 | 2022-05-10 | Purac Biochem Bv | Thermal decomposition of magnesium chloride |
US11326189B2 (en) | 2014-04-01 | 2022-05-10 | Purac Biochem Bv | Thermal decomposition of magnesium chloride |
CN107406401A (en) * | 2015-03-17 | 2017-11-28 | 普拉克生化公司 | Method for manufacturing the dioctyl phthalate of furans 2,5 (FDCA) by solid salt |
US10118908B2 (en) | 2015-03-17 | 2018-11-06 | Purac Biochem B.V. | Method for manufacturing furan-2,5-dicarboxylic acid (FDCA) from a solid salt |
AU2016232142B2 (en) * | 2015-03-17 | 2018-09-27 | Purac Biochem Bv | Method for manufacturing furan-2,5-dicarboxylic acid (FDCA) from a salt solution |
US10577339B2 (en) | 2015-03-17 | 2020-03-03 | Purac Biochem Bv | Method for manufacturing furan-2,5-dicarboxylic acid (FDCA) from a salt solution |
CN107406401B (en) * | 2015-03-17 | 2021-04-02 | 普拉克生化公司 | Process for the manufacture of furan-2, 5-dicarboxylic acid (FDCA) from solid salts |
CN107896493A (en) * | 2015-03-17 | 2018-04-10 | 普拉克生化公司 | Method for manufacturing the dioctyl phthalate of furans 2,5 (FDCA) by salting liquid |
WO2016146753A1 (en) * | 2015-03-17 | 2016-09-22 | Purac Biochem Bv | Method for manufacturing furan-2,5-dicarboxylic acid (fdca) from a salt solution |
WO2016146752A1 (en) | 2015-03-17 | 2016-09-22 | Purac Biochem Bv | Method for manufacturing furan-2,5-dicarboxylic acid (fdca) from a solid salt |
US10850990B2 (en) | 2016-01-19 | 2020-12-01 | Purac Biochem Bv | Method for processing magnesium chloride solutions and method for manufacturing carboxylic acids |
CN108473331B (en) * | 2016-01-19 | 2021-03-12 | 普拉克生化公司 | Improved method for treating magnesium chloride solution and method for preparing carboxylic acid |
CN108473331A (en) * | 2016-01-19 | 2018-08-31 | 普拉克生化公司 | The method for handling the improved method of magnesium chloride solution and preparing carboxylic acid |
WO2021214025A1 (en) | 2020-04-20 | 2021-10-28 | Purac Biochem B.V. | Process for manufacturing high-purity magnesium oxide |
Also Published As
Publication number | Publication date |
---|---|
EA027342B1 (en) | 2017-07-31 |
AU2012295626B2 (en) | 2016-05-12 |
CA2844204A1 (en) | 2013-02-21 |
AU2012295626A1 (en) | 2014-03-20 |
BR112014003067A2 (en) | 2017-02-21 |
CA2844204C (en) | 2020-01-28 |
UA114484C2 (en) | 2017-06-26 |
JP2014531408A (en) | 2014-11-27 |
EA039483B1 (en) | 2022-02-01 |
AU2012295626A8 (en) | 2014-10-23 |
PL2744746T3 (en) | 2021-06-14 |
EP2744746B1 (en) | 2020-12-02 |
EA201790354A3 (en) | 2017-10-31 |
ZA201401745B (en) | 2015-09-30 |
KR20140057607A (en) | 2014-05-13 |
CN103813978A (en) | 2014-05-21 |
EA201790354A2 (en) | 2017-09-29 |
US9061986B2 (en) | 2015-06-23 |
US20140357877A1 (en) | 2014-12-04 |
EA201490410A1 (en) | 2014-07-30 |
JP6275038B2 (en) | 2018-02-07 |
EP2744746A1 (en) | 2014-06-25 |
KR101974904B1 (en) | 2019-05-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AU2012295626B2 (en) | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up | |
US10508069B2 (en) | Acid/salt separation | |
CA2843696C (en) | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up | |
JP6994540B2 (en) | Recovery of carboxylic acids from their magnesium salts by precipitation with hydrochloric acid, useful for fermentation broth treatment | |
KR102046785B1 (en) | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up | |
JP2020045349A (en) | Recovery of carboxylic acids from magnesium salts thereof through precipitation using hydrochloric acid, useful for fermentation broth processing |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 12750877 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2844204 Country of ref document: CA |
|
ENP | Entry into the national phase |
Ref document number: 2014525959 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 201490410 Country of ref document: EA |
|
ENP | Entry into the national phase |
Ref document number: 20147006791 Country of ref document: KR Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: A201402155 Country of ref document: UA |
|
ENP | Entry into the national phase |
Ref document number: 2012295626 Country of ref document: AU Date of ref document: 20120816 Kind code of ref document: A |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112014003067 Country of ref document: BR |
|
WWE | Wipo information: entry into national phase |
Ref document number: 14238633 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: 112014003067 Country of ref document: BR Kind code of ref document: A2 Effective date: 20140210 |