WO2013024598A1 - ガスセンサ - Google Patents

ガスセンサ Download PDF

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Publication number
WO2013024598A1
WO2013024598A1 PCT/JP2012/005169 JP2012005169W WO2013024598A1 WO 2013024598 A1 WO2013024598 A1 WO 2013024598A1 JP 2012005169 W JP2012005169 W JP 2012005169W WO 2013024598 A1 WO2013024598 A1 WO 2013024598A1
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WO
WIPO (PCT)
Prior art keywords
outer cylinder
metal shell
gas sensor
rear end
cylinder member
Prior art date
Application number
PCT/JP2012/005169
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English (en)
French (fr)
Japanese (ja)
Inventor
渥美　尚勝
和裕 神前
Original Assignee
日本特殊陶業株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日本特殊陶業株式会社 filed Critical 日本特殊陶業株式会社
Priority to CN201280023949.2A priority Critical patent/CN103547916B/zh
Priority to JP2012548163A priority patent/JP5841066B2/ja
Publication of WO2013024598A1 publication Critical patent/WO2013024598A1/ja

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    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403—Cells and electrode assemblies
    • G01N27/406—Cells and probes with solid electrolytes
    • G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
    • G01N27/4078—Means for sealing the sensor element in a housing
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403—Cells and electrode assemblies
    • G01N27/406—Cells and probes with solid electrolytes
    • G01N27/4062—Electrical connectors associated therewith

Definitions

  • the present invention relates to a gas sensor suitable for use in detecting oxygen or the like contained in exhaust gas discharged from an internal combustion engine mounted on a vehicle such as a motorcycle or a passenger car.
  • a gas sensor for detecting the concentration of oxygen contained in exhaust gas a sensor provided with a gas detection element having oxygen ion conductivity, which is attached to an exhaust pipe of an internal combustion engine of a vehicle is known (for example, see Patent Documents 1 to 3).
  • the exhaust pipe is often arranged to extend rearward from the engine along the bottom surface of the vehicle, and the gas sensor attached to the exhaust pipe may also be arranged near the bottom surface of the vehicle.
  • the gas sensor is arranged near the bottom of the vehicle in this way, water splashed by the vehicle wheel may adhere to the gas sensor.
  • a water repellent filter or the like is disposed in a communication hole that guides the atmosphere serving as a reference when measuring the oxygen concentration of the exhaust gas to the inside of the gas sensor, and water is supplied. Uses a configuration that is difficult to put inside the gas sensor.
  • the gas detection element P1 is fixed in the metal shell P2 when the sensor (see FIG. 5) having the same configuration as the gas sensor described in Patent Document 1 or Patent Document 2 is described as an example.
  • the rear end side of the gas detection element P1 is covered with a metal outer cylinder P3 and a protective outer cylinder P4.
  • a separator P6 positioned on the rear end side of the outer cylinder P3 is disposed on the rear end side of the gas detection element P1, and a terminal fitting P8 is disposed in contact with the inner electrode P7. Further, the rear end side of the terminal fitting P8 is disposed in the through hole P9 of the separator P6, and is connected to the lead wire P10 for taking out the sensor output in the through hole P9.
  • the outer cylinder P3 and the protective outer cylinder P4 are provided with a communication hole P13 and a communication hole P14, respectively.
  • the communication hole P13 and the communication hole P14 are a space P11 on the rear end side of the gas detection element P1 in which air flows between the atmosphere side serving as an oxygen reference source, that is, between the outside of the gas sensor P5 and the internal space P12 of the gas detection element. Are communicated with each other.
  • a filter P15 that allows gas to pass and prevents water from passing is disposed between the outer cylinder P3 and the protective outer cylinder P4.
  • Corrosion of the cylindrical member leads to the formation of cracks and through-holes, and these cracks and through-holes become a path for water to enter the inside of the gas sensor, and the gas sensor cannot accurately detect the oxygen concentration contained in the exhaust gas. there is a possibility.
  • the magnitude of the ionization tendency of the metal material constituting the adjacent cylindrical member forming the gap is different, for example, when the cylindrical member made of stainless steel and the cylindrical member made of iron are adjacent, ionization Cylindrical members having a large tendency tend to corrode.
  • the present invention has been made to solve the above-described problem, and suppresses salt water from accumulating in a gap between members constituting the outer shape such as a metal shell, and also prevents corrosion of the members constituting the outer shape due to the water pool.
  • An object of the present invention is to provide a gas sensor that can be used.
  • the gas sensor of the present invention is a gas sensor that is inserted into a flow path through which a gas to be measured flows, the sensor element extending along the axial direction, a metal shell that holds the sensor element, and the insertion direction of the metal shell.
  • An outer cylinder member that is spaced apart from the rear end facing surface in the axial direction, and a cylindrical water-repellent air filter disposed between the inner cylinder member and the outer cylinder member.
  • the ventilation filter is axially extended from the tip of the outer cylinder member. Towards protrude the tip of the vent filter, characterized by contacting at least a portion and said rear-facing face of the crimped portion of the metal shell.
  • the tip of the ventilation filter makes it difficult for salt water to collect between the inner cylinder member and the outer cylinder member and between the caulking portion of the metal shell and the inner cylinder member.
  • the ventilation filter disposed on the outer peripheral side of the inner cylinder member and on the inner peripheral side of the outer cylinder member has water repellency, and is disposed so as to protrude further toward the metal shell than the tip of the outer cylinder member. Yes.
  • a ventilation filter having water repellency is always disposed in a gap (gap in the radial direction) between the inner cylinder member and the outer cylinder member, and water does not easily accumulate.
  • the tip of the ventilation filter is disposed in contact with the caulking portion of the metal shell, water is blocked by the ventilation filter disposed radially outside the gap between the metal shell and the inner cylinder member.
  • the ventilation filter disposed radially outside the gap between the metal shell and the inner cylinder member.
  • salt water does not easily accumulate in the gap between the caulking portion and the cylinder portion, or the gap between the caulking portion and the collar portion.
  • the ventilation filter whose tip is in contact with the metal shell is exposed. It is difficult for salt water to collect in the gaps between them or in the vicinity thereof.
  • the front end of the ventilation filter is in contact with at least part of the surface facing the rear end of the crimping portion of the metal shell, and water enters between the front end of the ventilation filter and the rear end facing surface of the crimping portion. Desirably not.
  • the metal material forming the inner cylinder member and the metal material forming the outer cylinder member have different ionization tendency.
  • a member made of a metal material having a small ionization tendency and a member made of a metal material having a large ionization tendency are used in the gas sensor, a member made of a metal material having a large ionization tendency if salt water exists between the two members. Corrosion is more likely to occur.
  • the metal material constituting the metallic shell and the metal material constituting the outer cylinder member have different ionization tendency.
  • a member made of a metal material having a small ionization tendency and a member made of a metal material having a large ionization tendency are used in the gas sensor, a member made of a metal material having a large ionization tendency if salt water exists between the two members. Corrosion is more likely to occur.
  • salt water does not easily accumulate in the gap between the metal shell and the outer cylinder member due to the ventilation filter, so even if a metal material having a higher ionization tendency than the outer cylinder member is used for the metal shell, corrosion is not caused. Occurrence can be suppressed.
  • the rear end of the sensor element is positioned on the rear end side with respect to the rear end facing surface of the crimped portion, and the front end of the outer cylinder member is disposed on the front end side with respect to the rear end of the sensor element. It is desirable that
  • the gas sensor can be downsized in the axial direction by disposing the front end of the outer cylinder member closer to the front end side than the rear end of the sensor element and by partially overlapping the outer cylinder member and the sensor element. can do.
  • the engine head constituting the internal combustion engine is preferably provided with the exhaust passage, and the metal shell is preferably provided with an attachment portion for attachment to the engine head.
  • the gas sensor By attaching the gas sensor to the engine head in this way, it becomes easier to reduce the size of the gas sensor compared to the case where the gas sensor is attached to the exhaust pipe extending from the internal combustion engine. That is, the engine head of the internal combustion engine is provided with cooling means such as a water jacket for cooling the engine head. The temperature of the engine head is generally lower than that of an exhaust pipe not provided with such cooling means. Therefore, compared with the case where it is attached to the exhaust pipe, components that are easily affected by heat, such as a ventilation filter, can be disposed close to the engine head, and the gas sensor can be easily downsized in the axial direction.
  • the engine head may be called a cylinder head.
  • the tip of the outer cylinder member may approach the metal shell, and in such a case, salt water tends to accumulate in the gap between the tip of the outer cylinder member and the metal shell, As a result, there is a risk of inducing corrosion, but in the gap between the tip of the outer cylinder member and the metal shell, the ventilation filter whose tip is in contact with the metal shell is exposed. Since salt water hardly accumulates in the gap between the metal fittings, such a fear can be eliminated.
  • the tip of the outer cylinder member is in contact with the ventilation filter.
  • the air filter is disposed between the inner cylinder member and the outer cylinder member, and then fixed by caulking from the radial direction. At this time, the caulking is performed in the middle of the outer cylinder member. And the tip of the outer cylinder member may be lifted, and a gap may be formed between the ventilation filter and the tip of the outer cylinder member. Water tends to be drawn into the gap, and once the water is drawn and accumulated, a large water droplet will form, and it will stay for a long time in the gap between the metal shell and the outer cylinder member or in the vicinity thereof. At least one of the outer cylinder members may corrode.
  • the tip of the outer cylinder member is brought into close contact with the ventilation filter, for example, through a process such as punching, with respect to the tip of the outer cylinder member after crimping, the tip of the outer cylinder member and the ventilation filter come into contact with no gap, Since the contact pressure and ground contact area of the filter with respect to the metal shell increase, it becomes difficult for salt water to accumulate in the gap between the outer tube member and the metal shell and in the vicinity thereof, and the occurrence of corrosion of the metal shell and the outer tube member can be suppressed. it can.
  • the front end of the ventilation filter is in contact with the rear end-facing surface of the caulking portion of the metal shell, and therefore between the inner cylinder member and the outer cylinder member, and the caulking portion of the metal shell.
  • the salt water is less likely to collect between the inner cylinder member and the corrosion of the metal shell and the like due to the water pool can be suppressed.
  • FIG. 2 is a partially exploded perspective view illustrating the configuration of a separator, a blocking member, a protective outer cylinder, and the like in FIG. 1. It is a partial expanded sectional view explaining the contact with the metal shell of FIG. 1, and a filter. It is sectional drawing explaining the whole structure of the conventional gas sensor.
  • FIG. 1 is a cross-sectional view illustrating the overall configuration of the gas sensor 1 according to the present embodiment.
  • the gas sensor of the present invention is fastened to an engine head of an internal combustion engine mounted on a vehicle such as a passenger car, for example, and a front end portion of the gas sensor protrudes into an exhaust passage formed in the engine head. Therefore, description will be made by applying to an oxygen sensor for measuring the oxygen concentration in the exhaust gas.
  • the side on which the protector 60 is attached is referred to as the front end side, and the opposite side is described as the rear end side.
  • the gas sensor 1 of the present embodiment is a so-called heaterless sensor that does not include a heater for heating the gas detection element 10 described later, and is activated by heating the gas detection element 10 with the heat of the exhaust gas. It measures the oxygen concentration inside.
  • the gas sensor 1 mainly includes a gas detection element (sensor element) 10, a separator 20, a closing member 30, a terminal fitting 40, and a lead wire 45.
  • a metal shell 50 covering the periphery, a protector 60, an outer cylinder (inner cylinder member) 70, a protective outer cylinder (outer cylinder member) 80, and the like are provided.
  • FIG. 2 is a diagram illustrating the configuration of the gas detection element 10 of FIG. 1, and the gas detection element 10 is formed from a solid electrolyte having oxygen ion conductivity.
  • the gas detection element 10 is mainly composed of an element body 11 which is formed in a cylindrical shape extending in the direction of the axis O and whose end 12 on the front end side is closed. On the outer periphery of the element body 11, a flange portion 13 that protrudes radially outward is provided in the circumferential direction.
  • the gas detection element 10 is described as being applied to an example in which the gas detection element 10 is formed in a cylindrical shape.
  • the gas detection element 10 is not limited to being formed in a cylindrical shape, but is formed in a plate shape. There is no particular limitation.
  • a typical example of the solid electrolyte constituting the element body 11 is ZrO 2 in which Y 2 O 3 or CaO is dissolved.
  • a solid electrolyte which is a solid solution of an alkaline earth metal or rare earth metal oxide and ZrO 2 may be used.
  • a solid electrolyte containing HfO 2 in a solid solution of an alkaline earth metal or rare earth metal oxide and ZrO 2 may be used.
  • the outer electrode 14 is an electrode in which Pt or a Pt alloy (hereinafter referred to as “Pt or the like”) is formed porous on the end 12 of the gas detection element 10.
  • the vertical lead portion 15 is a conductive portion extending in the axial direction from the outer electrode 14 and is made of Pt or the like.
  • the annular lead portion 16 is a conductive portion that is formed in an annular shape on the lower surface side (downward in FIG. 2) of the flange portion 13 and is electrically connected to the vertical lead portion 15 and is formed of Pt or the like.
  • An inner electrode 17 in which Pt or the like is formed in a porous shape is formed on the inner peripheral surface of the element body 11.
  • FIG. 3 is a partially exploded perspective view illustrating the configuration of the separator 20, the closing member 30, the protective outer cylinder 80, and the like of FIG. 1.
  • the separator 20 includes a gas detection element as shown in FIGS. 1 and 3. 10 and the closing member 30.
  • the separator 20 is a cylindrical member made of an electrically insulating material such as alumina, and a through hole 21 through which the lead wire 45 is inserted is formed at the center of the separator 20.
  • the closing member 30 is a cylindrical sealing member made of an elastic material such as fluorine rubber, and is a member disposed at the rear end of the gas sensor 1.
  • a through hole 31 through which the lead wire 45 is inserted is formed at the axial center of the closing member 30.
  • the front end side of the closing member 30 is in airtight contact with the rear end side of the separator 20, and the outer periphery on the rear end side is in airtight contact with the inner peripheral surface of the outer cylinder 70 and the inner peripheral surface of the protective outer cylinder 80.
  • the closing member 30 hermetically separates the inside and the outside of the gas sensor 1. That is, the rear end side of the gas sensor 1 is airtightly closed by the closing member 30.
  • the terminal metal fitting 40 is a metal fitting formed from a nickel alloy (for example, Inconel 750, manufactured by Inconel, UK) and is a member formed in a substantially cylindrical shape for taking out the sensor output to the outside.
  • the terminal fitting 40 is connected to the lead wire 45 so as to be conductive, and is disposed in contact with the inner electrode 17 of the gas detection element 10.
  • three flange pieces 41 extending radially outward are provided at equal intervals in the circumferential direction. In other words, a gap extending in the circumferential direction is formed between the three flange pieces 41.
  • the metal shell 50 is a member formed of iron, and is a member formed in a substantially cylindrical shape.
  • the metal shell 50 is provided with a step portion 51 that supports the flange portion 13 of the gas detection element 10 so as to protrude from the inner peripheral surface toward the radially inner side in the circumferential direction.
  • the outer surface of the metal shell 50 is preliminarily plated with Ni to form a thin Ni plating layer (not shown).
  • a screw part (attachment part) 52 for attaching the gas sensor 1 to an engine head (not shown) of the internal combustion engine and an attachment tool for screwing the screw part 52 into the engine head are provided on the outer peripheral surface on the front end side of the metal shell 50.
  • the metal shell 50 is arranged in the order of the screw portion 52 and the hexagonal portion 53 from the front end to the rear end.
  • a cylindrical portion 54 is provided at a position adjacent to the rear end side of the metal shell 50, in other words, the rear end side of the hexagonal portion 53.
  • the protector 60 is a member made of stainless steel (for example, JIS standard SUS310S), and is a protective member that covers the tip of the gas detection element 10.
  • the protector 60 is a cylindrical member extending in the axial direction, and is formed in a shape with a closed end. The rear end edge of the protector 60 is sandwiched and fixed between the flange portion 13 of the gas detection element 10 and the step portion 51 of the metal shell 50. Between the metal shell 50 and the gas detection element 10, a ceramic powder 65 made of talc and a ceramic sleeve 66 made of alumina are arranged in this order from the tip side.
  • the outer cylinder 70 is a member formed of iron, and is inserted into the metal shell 50 and is disposed adjacent to the rear end side of the ceramic sleeve 66.
  • the outer cylinder 70 has a cylindrical portion 71 formed in a cylindrical shape extending along the axial direction, a flange 72 extending radially outward from the distal end side of the cylindrical portion 71, and a penetration formed in the cylindrical portion 71.
  • a vent hole 73 that is a hole is provided.
  • the outer surface of the outer cylinder 70 is preliminarily plated with Ni to form a thin Ni plating layer (not shown).
  • the cylinder portion 71 is a member in which the rear end of the gas detection element 10, the separator 20, and the front end of the closing member 30 are disposed. Furthermore, when the protective outer cylinder 80 is crimped, the cylindrical portion 71 is simultaneously deformed radially inward, and the inner peripheral surface is in close contact with the outer peripheral surface of the closing member 30.
  • the flange portion 72 is arranged such that the surface on the front end side is in contact with the ceramic sleeve 66, and the metal ring 67 made of iron plated with Ni is arranged on the surface on the rear end side.
  • the metal shell 50 is provided with a caulking portion 55 for fixing the outer cylinder 70 to the metal shell 50 at the rear end of the cylindrical portion 54.
  • the caulking portion 55 is a portion that is deformed toward the radially inner side by applying a force to the rear end of the tubular portion 54 that extends in a tubular shape.
  • the caulking portion 55 presses the metal ring 67, the collar portion 72, the ceramic sleeve 66, the ceramic powder 65, and the like toward the distal end side along the axial direction. Note that a gap may be formed between the caulking portion 55 and the tube portion 71 of the outer tube 70, or the caulking portion 55 may be in contact with the tube portion 71.
  • the gap is formed narrower than the thickness of the outer cylinder 70 or the filter 75. Note that the Ni plating layer on the caulking portion 55 of the metal shell 50 may crack during the caulking process. At this time, if a water droplet stays in the crack for a long time, the metal shell may be corroded.
  • a water repellent filter (aeration filter) 75 formed in a cylindrical shape using, for example, PTFE (polytetrafluoroethylene) is disposed.
  • PTFE polytetrafluoroethylene
  • the end of the filter 75 on the front end side is in contact with the crimped portion 55 of the metal shell 50 over the circumferential direction.
  • the rear end of the filter 75 extends to the same position as the rear end of the outer cylinder 70.
  • the filter 75 can be ventilated but can prevent moisture from entering.
  • the filter 75 may be in direct contact with the caulking portion 55 of the metal shell 50, or may be in contact with the caulking portion 55 via another member, in other words, caulking. It may be in direct contact with another member that contacts the portion 55, and is not particularly limited. Moreover, although it is desirable to contact over the perimeter, it should just be contacting at least in part.
  • the filter 75 formed in the above-described cylindrical shape is obtained by winding the filter 75 formed in a sheet shape more than once, in other words, by winding a part of the filter 75.
  • the overlap is also included.
  • the outer periphery of the filter 75 is provided with a protective outer cylinder 80 formed in a generally cylindrical shape using stainless steel (for example, SUS304L) different from the metal shell 50.
  • the protective outer cylinder 80 is clamped from the outer peripheral side to sandwich and hold the filter 75 with the outer cylinder 70.
  • the rear end of the protective outer cylinder 80 is formed with a smaller diameter than the front end, and the rear end of the closing member 30 is fitted into the rear end of the protective outer cylinder 80. Since it is crimped from the outer peripheral side in this state, the protective outer cylinder 80 can fix the closing member 30 to the rear end of the outer cylinder 70.
  • the protective outer cylinder 80 is provided with a vent hole 81 which is a through hole at a position corresponding to the vent hole 73 of the outer cylinder 70.
  • the ventilation hole 73 and the ventilation hole 81 communicate the atmosphere and the inside of the gas sensor 1, specifically, the internal space 18 on the inner electrode 17 side of the gas detection element 10 so that air can flow.
  • the protector 60 and the gas detection element 10 are inserted into the through hole formed in the metal shell 50 from the rear end side toward the front end side.
  • the ceramic powder 65 and the ceramic sleeve 66 are disposed in the space between the metal shell 50 and the gas detection element 10.
  • the outer cylinder 70 is disposed on the rear end side of the ceramic sleeve 66 so that the collar portion 72 is in contact, and the metal ring 67 is disposed on the rear end surface of the collar portion 72.
  • the rear end of the cylindrical portion 54 of the metal shell 50 is crimped, and specifically, the crimped portion 55 is formed by plastic deformation from the radially outer side to the inner side.
  • the caulking portion 55 presses the outer cylinder 70 against the ceramic sleeve 66 through the metal ring 67 and fixes the outer cylinder 70 to the metal shell 50.
  • the filter 75 is arranged so as to cover the outer periphery of the outer cylinder 70 in the circumferential direction.
  • the end portion on the front end side of the filter 75 is abutted against the caulking portion 55 of the metal shell 50 and is arranged so as to cover the boundary between the caulking portion 55 and the cylindrical portion 71 of the outer cylinder 70 in the circumferential direction. ing.
  • the lead wire 45 is passed through the through hole 21 of the separator 20, the through hole 31 of the closing member 30, and the protective outer cylinder 80, and the terminal fitting 40 is fixed to the tip of the lead wire 45.
  • this is referred to as a composite member 91.
  • the formed composite member 91 is inserted into the outer cylinder 70, and as shown in FIG. 1, the tip of the terminal fitting 40 is inserted into the internal space 18 of the gas detection element 10, and the terminal fitting 40 and the inner electrode 17 are brought into contact with each other. Let At this time, the terminal fitting 40 is inserted and positioned until the flange piece 41 contacts the rear end of the gas detection element 10.
  • the separator 20 and the closing member 30 are disposed on the distal end side in the outer cylinder 70, and the separator 20, the closing member 30 and the protective outer cylinder 80 are pressed toward the distal end side.
  • a protective outer cylinder 80 is fitted on the outer peripheral side of the filter 75.
  • the end portion on the front end side of the protective outer cylinder 80 is disposed at a position closer to the metal shell 50 than the rear end of the gas detection element 10, as shown in FIGS.
  • the end portion on the front end side of the protective outer cylinder 80 is separated from the crimping portion 55 of the metal shell 50, the end portion on the front end side of the filter 75 is joined to the end portion on the front end side of the protective outer cylinder 80. It is exposed between the fastening part 55.
  • the protective outer cylinder 80 and the outer cylinder 70 are integrally fixed by caulking the protective outer cylinder 80 from the radially outer side to the inner side.
  • the caulking is performed at a position other than the position where the vent hole 73 and the vent hole 81 are formed.
  • the gas sensor 1 is completed.
  • Samples 1 to 6 were prepared in which the clearance between the filter 75 and the metal shell 50 was divided as shown in Table 1.
  • evaluation evaluated the salt spray test 10 pieces about each sample, and showed it as the ratio of the rust generation
  • the clearance from the tip of the filter 75 to the metal shell 50 is 0 mm, that is, no rust occurs in the abutting sample 1, and there is a clearance from the filter 75 to the metal shell 50.
  • samples 2 and 3 rust was generated.
  • the end portion on the front end side of the protective outer cylinder 80 extends at least to the end on the front end side of the caulking position performed on the front end side or a position closer to the metal shell 50 than the caulking position. Is desirable.
  • salt water hardly accumulates between the outer cylinder 70 and the protective outer cylinder 80 and between the caulking portion 55 of the metal shell 50 and the outer cylinder 70 due to the tip of the filter 75.
  • the filter 75 disposed on the outer peripheral side of the outer cylinder 70 and on the inner peripheral side of the protective outer cylinder 80 has water repellency and protrudes further toward the metal shell 50 than the tip of the protective outer cylinder 80. Has been placed. Therefore, a filter 75 having water repellency is always disposed in a gap (diameter gap) between the outer cylinder 70 and the protective outer cylinder 80, and water does not easily accumulate.
  • the tip of the filter 75 is disposed in contact with the caulking portion 55 of the metal shell 50, the water is disposed outside the gap between the metal shell 50 and the outer cylinder 70 in the radial direction. This makes it difficult to enter the gap between the metal shell 50 and the outer cylinder 70, and it is difficult to accumulate. More specifically, salt water does not easily accumulate in the gap between the crimping portion 55 and the cylinder portion 71 or the gap between the crimping portion 55 and the flange portion 72. Further, in the gap between the front end of the protective outer cylinder 80 and the metal shell 50 (gap in the axial direction), the filter 75 whose end is in contact with the metal shell 50 is exposed. Salt water does not easily accumulate in the gap between the metal shell 50 and the metal shell 50 or in the vicinity thereof.
  • salt water is less likely to accumulate in the gap between the outer cylinder 70 and the protective outer cylinder 80, the gap between the metal shell 50 and the outer cylinder 70, and the gap between the protective outer cylinder 80 and the metal shell 50.
  • the occurrence of corrosion of the metal shell 50, the outer cylinder 70, and the protective outer cylinder 80 can be suppressed.
  • the gas sensor 1 is disposed.
  • the size can be reduced in the axial direction.
  • the gas sensor 1 By attaching the gas sensor 1 to the engine head, the gas sensor 1 can be easily downsized as compared with the case where the gas sensor is attached to the exhaust pipe extending from the internal combustion engine. That is, the engine head of the internal combustion engine is provided with cooling means such as a water jacket for cooling the engine head. The temperature of the engine head is generally lower than that of an exhaust pipe not provided with such cooling means. Therefore, compared with the case where it is attached to the exhaust pipe, a part formed from a resin that is easily affected by heat, such as the filter 75, can be disposed close to the engine head, and the gas sensor 1 is disposed in the axial direction. It becomes easy to miniaturize.
  • the tip of the protective outer cylinder 80 may approach the metal shell 50, and in such a case, salt water is generated in the gap between the tip of the protective outer cylinder 80 and the metal shell 50.
  • the filter 75 whose tip is in contact with the metallic shell 50 is exposed in the gap between the distal end of the protective outer cylinder 80 and the metallic shell 50. The salt water is unlikely to collect in the gap between the tip of the protective outer cylinder 80 and the metal shell 50.
  • the metal shell 50 and the outer cylinder 70 are formed from iron, and the protective outer cylinder 80 is applied to an example formed from stainless steel having a different ionization tendency from iron.
  • the outer cylinder 70 and the protective outer cylinder 80 may be formed from stainless steel, and are not particularly limited. In this case, when the ionization tendency is different between the stainless steel forming the metal shell 50 and the outer cylinder 70 and the stainless steel forming the protective outer cylinder 80 (for example, when the stainless steel part number is different), Although the metal shell 50 and the outer cylinder 70 are easily corroded, the corrosion of the metal shell 50 and the outer cylinder 70 can be suppressed by adopting the configuration of the present embodiment.
  • the tip of the protective outer cylinder 80 is in contact with the filter 75.
  • the filter 75 is disposed between the outer cylinder 70 and the protective outer cylinder 80 and then fixed by caulking from the radial direction.
  • the tip of the protective outer cylinder 80 is lifted, and a gap may be formed between the filter 75 and the tip of the protective outer cylinder 80. Water is easily drawn into the gap, and once the water is drawn and accumulated, a large water droplet is formed, and the water stays in the gap between the metal shell 50 and the protective outer cylinder 80 or in the vicinity thereof. At least one of the metal fitting 50 and the protective outer cylinder 80 may corrode.
  • the tip of the protective outer cylinder 80 when the tip of the protective outer cylinder 80 is brought into close contact with the filter 75 through a process such as punching, for example, with respect to the tip of the protective outer cylinder 80 after caulking, the tip of the protective outer cylinder 80 and the filter 75 come into contact with no gap.
  • the ground pressure and the ground contact area of the filter 75 with respect to the metal shell 50 increase, so that salt water does not easily accumulate in the gap between the protective outer tube 80 and the metal shell 50 or in the vicinity thereof. The occurrence of corrosion can be suppressed.
  • SYMBOLS 1 Gas sensor, 10 ... Gas detection element (sensor element), 50 ... Metal fitting, 52 ... Screw part (attachment part), 55 ... Clamping part, 70 ... Outer cylinder (inner cylinder member), 71 ... Cylinder part, 72 ... buttocks, 75 ... filter (ventilation filter), 80 ... protective outer cylinder (outer cylinder member)

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
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  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
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  • Immunology (AREA)
  • Pathology (AREA)
  • Measuring Oxygen Concentration In Cells (AREA)
PCT/JP2012/005169 2011-08-17 2012-08-16 ガスセンサ WO2013024598A1 (ja)

Priority Applications (2)

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CN201280023949.2A CN103547916B (zh) 2011-08-17 2012-08-16 气体传感器
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