WO2013003051A3 - Silane terminated polycarbonate-polyester copolymers for coating, adhesives, sealant and elastomer applications - Google Patents

Silane terminated polycarbonate-polyester copolymers for coating, adhesives, sealant and elastomer applications Download PDF

Info

Publication number
WO2013003051A3
WO2013003051A3 PCT/US2012/042357 US2012042357W WO2013003051A3 WO 2013003051 A3 WO2013003051 A3 WO 2013003051A3 US 2012042357 W US2012042357 W US 2012042357W WO 2013003051 A3 WO2013003051 A3 WO 2013003051A3
Authority
WO
WIPO (PCT)
Prior art keywords
polymer
sealant
adhesives
coating
reaction product
Prior art date
Application number
PCT/US2012/042357
Other languages
French (fr)
Other versions
WO2013003051A2 (en
Inventor
Kamesh R. VYAKARANAM
Harpreet Singh
Ling Zhang
William H. HEATH
Amarnath SINGH
William A. Koonce
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of WO2013003051A2 publication Critical patent/WO2013003051A2/en
Publication of WO2013003051A3 publication Critical patent/WO2013003051A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/64—Polyesters containing both carboxylic ester groups and carbonate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/8083—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen
    • C08G18/809—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/695—Polyesters containing atoms other than carbon, hydrogen and oxygen containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D169/00—Coating compositions based on polycarbonates; Coating compositions based on derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J169/00—Adhesives based on polycarbonates; Adhesives based on derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes

Abstract

Crosslinkable silyl group-containing polymers that may be made using polycarbonate-polyester copolymer polyols and methods for making the same are provided. The crosslinkable silane-terminated polymer is the reaction product of a polycarbonate-polyester copolymer polyol and an isocyanate capped hydrosilylated polymer. The isocyanate capped hydrosilylated polymer is the reaction product of at least one isocyanate and a hydrosilylated polymer. The hydrosilylated polymer is the reaction product of a polymer having at least one unsaturated group and at least one alcohol hydroxyl group in each molecule and a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule. The crosslinkable silane-terminated polymer exhibits improved viscosity properties, UV stability and weatherability.
PCT/US2012/042357 2011-06-30 2012-06-14 Silane terminated polycarbonate-polyester copolymers for coating, adhesives, sealant and elastomer applications WO2013003051A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161503525P 2011-06-30 2011-06-30
US61/503,525 2011-06-30

Publications (2)

Publication Number Publication Date
WO2013003051A2 WO2013003051A2 (en) 2013-01-03
WO2013003051A3 true WO2013003051A3 (en) 2013-06-06

Family

ID=46395723

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/042357 WO2013003051A2 (en) 2011-06-30 2012-06-14 Silane terminated polycarbonate-polyester copolymers for coating, adhesives, sealant and elastomer applications

Country Status (1)

Country Link
WO (1) WO2013003051A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3426710B1 (en) * 2016-03-10 2022-09-28 Momentive Performance Materials Inc. Moisture-curable silylated resin derived from polycarbonate diol and coating, sealant and adhesive compositions containing same
EP3645609B1 (en) * 2017-06-26 2021-04-21 Dow Silicones Corporation Isocyanate-functional silicone-polyether copolymer, silicone-polyether-urethane copolymer formed therewith, sealants comprising same, and related methods
CN108068176B (en) * 2017-12-26 2020-09-08 芜湖市长江起重设备制造有限公司 Preparation method of high-temperature-resistant polycarbonate type waterborne polyurethane-based plywood
US11760841B2 (en) 2018-12-21 2023-09-19 Dow Silicones Corporation Silicone-polycarbonate copolymer, sealants comprising same, and related methods
WO2020131708A2 (en) 2018-12-21 2020-06-25 Dow Silicones Corporation Silicone-organic copolymer, sealants comprising same, and related methods
CN110862797A (en) * 2019-11-01 2020-03-06 上海应用技术大学 Silane-terminated polyether sealant and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020013427A1 (en) * 2000-04-12 2002-01-31 Ryotaro Tsuji Method of producing crosslinkable silyl group-containing polyoxyalkylene polymers
JP2003246830A (en) * 2002-02-25 2003-09-05 Dainippon Ink & Chem Inc Highly durable solvent-free moisture-curing hot-melt urethane resin composition, foam and sheet structure using this
JP2009235257A (en) * 2008-03-27 2009-10-15 Konishi Co Ltd Aqueous silylated urethane-based resin composition
WO2012003187A1 (en) * 2010-06-30 2012-01-05 Dow Global Technologies Llc Silyl-terminated polymers

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4633021A (en) 1985-11-29 1986-12-30 National Distillers And Chemical Corporation Olefin hydroformylation
US4731486A (en) 1986-11-18 1988-03-15 Union Carbide Corporation Hydroformylation using low volatile phosphine ligands
KR100589300B1 (en) 1998-04-27 2006-06-14 에섹스 스페시얼티 프로덕츠, 인코오포레이티드 Method of bonding a window to a substrate using a silane functional adhesive composition
WO2004096744A2 (en) 2003-04-25 2004-11-11 Dow Global Technolgies Inc. Aldehyde and alcohol compositions derived from seed oils
WO2009009271A2 (en) 2007-07-06 2009-01-15 Dow Global Technologies Inc. Purification of hydroformylated and hydrogenated fatty alkyl ester compositions

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020013427A1 (en) * 2000-04-12 2002-01-31 Ryotaro Tsuji Method of producing crosslinkable silyl group-containing polyoxyalkylene polymers
JP2003246830A (en) * 2002-02-25 2003-09-05 Dainippon Ink & Chem Inc Highly durable solvent-free moisture-curing hot-melt urethane resin composition, foam and sheet structure using this
JP2009235257A (en) * 2008-03-27 2009-10-15 Konishi Co Ltd Aqueous silylated urethane-based resin composition
WO2012003187A1 (en) * 2010-06-30 2012-01-05 Dow Global Technologies Llc Silyl-terminated polymers

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KANEKAW, YOSHINORI ET AL: "Solvent-free moisture-curable hot-melt urethane compositions, cured foams therefrom, and artificial leather sheets therewith", XP002689895, retrieved from STN Database accession no. 139:215499 *
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KASHIRO, SHOHEI ET AL: "Aqueous silylated urethane coating compositions with good solvent resistance", XP002689896, retrieved from STN Database accession no. 151:450603 *

Also Published As

Publication number Publication date
WO2013003051A2 (en) 2013-01-03

Similar Documents

Publication Publication Date Title
WO2013003051A3 (en) Silane terminated polycarbonate-polyester copolymers for coating, adhesives, sealant and elastomer applications
WO2007037833A3 (en) Moisture curable silylated polymer containing free polyols for coating, adhesive and sealant application
JP5228041B2 (en) Method for adhering thermoplastic elastomer member to glass substrate
WO2010099254A3 (en) Electrically isolating polymer composition
WO2011031558A3 (en) Toughened polyhydroxyalkanoate compositions
WO2011059994A3 (en) Polymeric compositions and method of making and articles thereof
WO2006071772A3 (en) Crosslinkable saccharide-siloxane compositions, and networks, coatings and articles formed therefrom
MX2012006864A (en) Hydrophilic coating.
WO2009011777A3 (en) Curable silicon-containing compositions possessing high translucency
WO2007050355A3 (en) Solvent resistant polyurethane adhesive compositions
WO2009137715A8 (en) Versatile biodegradable elastic polymers featured with dual crosslinking mechanism for biomedical applications
WO2011034838A8 (en) Crosslinked, melt-shaped articles and compositions for producing same
WO2011090643A3 (en) Moisture-curable siloxane-containing and fluorocarbon-containing compounds and polymers formed therefrom
WO2011090759A3 (en) A flexible tubing material and method of forming the material
JP6101362B2 (en) Multilayer film having an adhesive layer
WO2007099239A3 (en) Modification of solid surfaces by means of polymer combinations
WO2011000843A3 (en) Curable composition having a silane-modified reactive thinner
WO2012099366A3 (en) Photosensitive resin composition, and photosensitive material comprising same
WO2011032651A3 (en) Hydrophilic polyurethane urea dispersions
WO2013062630A3 (en) Flexible scratch resistance film for display devices
MX362884B (en) High performance hotmelt window sealant.
MX2013004646A (en) Elastomeric block copolymers with a star-shaped molecular architecture, said star-shaped molecular architecture having at least two different star arms.
WO2011051100A3 (en) Aqueous two-component dispersion adhesive
IN2012DN02388A (en)
WO2012174500A3 (en) Hybrid sealant composition

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12730326

Country of ref document: EP

Kind code of ref document: A2

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
122 Ep: pct application non-entry in european phase

Ref document number: 12730326

Country of ref document: EP

Kind code of ref document: A2