WO2012175098A1 - Verfahren und anlage zur dekontamination von phosphorsäurelösung - Google Patents
Verfahren und anlage zur dekontamination von phosphorsäurelösung Download PDFInfo
- Publication number
- WO2012175098A1 WO2012175098A1 PCT/EP2011/003102 EP2011003102W WO2012175098A1 WO 2012175098 A1 WO2012175098 A1 WO 2012175098A1 EP 2011003102 W EP2011003102 W EP 2011003102W WO 2012175098 A1 WO2012175098 A1 WO 2012175098A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- phosphoric acid
- iron
- acid solution
- decontamination
- bath
- Prior art date
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title claims abstract description 139
- 229910000147 aluminium phosphate Inorganic materials 0.000 title claims abstract description 70
- 238000000034 method Methods 0.000 title claims abstract description 30
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 58
- 238000005202 decontamination Methods 0.000 claims abstract description 37
- 230000003588 decontaminative effect Effects 0.000 claims abstract description 37
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910052742 iron Inorganic materials 0.000 claims abstract description 20
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 18
- VEPSWGHMGZQCIN-UHFFFAOYSA-H ferric oxalate Chemical compound [Fe+3].[Fe+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O VEPSWGHMGZQCIN-UHFFFAOYSA-H 0.000 claims abstract description 13
- -1 iron ion Chemical class 0.000 claims abstract description 10
- 238000004064 recycling Methods 0.000 claims abstract description 7
- 230000002285 radioactive effect Effects 0.000 claims abstract description 5
- 238000011109 contamination Methods 0.000 claims abstract 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 11
- 239000010802 sludge Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims 1
- 238000005352 clarification Methods 0.000 claims 1
- 150000003017 phosphorus Chemical class 0.000 claims 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N iron (II) ion Substances [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract description 7
- 238000010926 purge Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 19
- 238000004062 sedimentation Methods 0.000 description 9
- 239000003792 electrolyte Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 238000001149 thermolysis Methods 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229910000398 iron phosphate Inorganic materials 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000012857 radioactive material Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/13—Treatment of sludge; Devices therefor by de-watering, drying or thickening by heating
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/234—Purification; Stabilisation; Concentration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/234—Purification; Stabilisation; Concentration
- C01B25/237—Selective elimination of impurities
- C01B25/238—Cationic impurities, e.g. arsenic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5272—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using specific organic precipitants
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/001—Decontamination of contaminated objects, apparatus, clothes, food; Preventing contamination thereof
- G21F9/002—Decontamination of the surface of objects with chemical or electrochemical processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/28—Mechanical auxiliary equipment for acceleration of sedimentation, e.g. by vibrators or the like
- B01D21/283—Settling tanks provided with vibrators
Definitions
- the invention relates to a method according to the features of the first claim and a system according to the features of claim 7.
- the invention is applicable everywhere where in a chemical and / or
- Phosphoric acid solution is to be cleaned from the iron (II) ions, so that it can be used again for the decontamination of radioactive contaminated plant parts.
- the invention is particularly suitable for use in small and mobile plants in which the phosphoric acid in the decontamination bath is continuously cleaned and returned to the bath.
- Phosphoric acid electrolyte baths have long been used for electrochemical decontamination. After prolonged use, the iron content and the activity in the electrolyte solution increase. At a certain iron concentration in the phosphoric acid electrolyte bath, for example, 100 g Fe / per liter of the use of the electrolyte is uneconomical, because the decontamination successful and the time required is extremely high. Therefore, the electrolytes are discarded and disposed of. Another possibility is to use the aqueous phosphoric acid solution of
- the decontamination effect is that of a steel component by means of phosphoric acid, the surface about 0.03 mm deep ab- / dissolved.
- the dissolved steel or iron is not radioactive but only the one adhering to the surface
- thermolysis is a chemical reaction in which a starting material is decomposed by heating it into several products. In contrast to thermal decomposition (pyrolysis), the thermolysis is targeted to the representation of defined products or more reactive
- the solution according to the invention provides a method for the recycling of
- Phosphoric acid solution from a decontamination bath which is contaminated by radioactive content, wherein the spent phosphoric acid is diluted with aqueous oxalic acid solution to separate iron oxalate and the phosphoric acid solution for
- Decontamination bath continuously removed and measured. The continuous
- the iron (II) ions are relevant for the adjustment of the process parameters, since the iron (III) ions, which are also present in the liquid, are not precipitated and pass through the process unchanged.
- the continuous measurement can be done online, every minute, every hour or every day.
- phosphoric acid is continuously withdrawn from the decontamination bath and replaced with concentrated purified phosphoric acid, so that a certain concentration of dissolved iron is not exceeded.
- This iron concentration in the decontamination bath should be 40 to 120 g Fe / liter, preferably 75 to 95 g Fe / liter.
- oxalic acid solution to the phosphoric acid contaminated with dissolved iron.
- This can be stoichiometric or substoichiometric.
- a substoichiometric addition is advantageous. Although this does not achieve optimal efficiency, it prevents oxalic acid from unnecessarily loading the entire process.
- the addition may be continuous, by a person or by an addition device.
- it is advantageous to carry out the mixing of dissolved with iron ions contaminated phosphoric acid and oxalic acid in a multi-stage mixing process. Suitable is a two- to four-stage mixing process. This mixing process can be carried out by means known to the process engineer. These are the
- the plant according to the invention for the recycling of phosphoric acid contaminated with iron ions consists of a decontamination bath with the contaminated one
- Phosphoric acid the container with oxalic acid and sedimentation tank.
- the plant is characterized by a continuously operated mixer in which oxalic acid and iron oxide contaminated phosphoric acid are mixed. Furthermore, a discharge device is arranged after the mixing chambers of the mixer, for example an overflow from the mixer to the settling tank, wherein Iron oxalate sludge and diluted phosphoric acid are continuously withdrawn from the sales basin.
- the plant according to the invention also has a belt furnace in which iron oxalate is continuously decomposed into iron oxide, CO 2 and CO.
- the system has a measuring device for the continuous measurement of the iron ion content in or on the decontamination bath.
- the system has a device for the continuous addition of concentrated phosphoric acid in the decontamination bath. This can be done for example by a metering device, for. As a controllable pump can be made.
- the system has a device for the continuous addition of oxalic acid in the mixer.
- mixers with mixing chambers and discharge devices between, for example, two to four mixers.
- pumps or valves can be used.
- the solution according to the invention has the advantage that in a plant for recycling a phosphoric acid solution from a decontamination bath, only small amounts of the phosphoric acid solution are in circulation, the required working volume in the plant tanks being considerably reduced. As a result, it is possible to purify phosphoric acid solution of iron (II) ions from the electrochemical
- the figure shows a plant for the decontamination of phosphoric acid solution 3b, consisting of the decontamination 4, in which phosphoric acid with dissolved iron (II) and iron (III) is located.
- This is supplied through the line and a pump to a multi-stage mixer 10, are arranged in the stirrer 20.
- oxalic acid 9 is pumped into the multi-stage mixer 10.
- the multi-stage mixer 10 overflows 16 are arranged.
- dilute phosphoric acid 3 which enters the sedimentation tank 11, in the thinned by a heel process phosphoric acid 3 and
- the heater is arranged, which is a belt furnace 2, wherein in the present case a plurality of heating elements 18 above a belt the moist
- Iron oxalate sludge dry and thermally decomposed, which can be discarded as iron oxide 5 and processed further.
- a filter 8 is arranged, are filtered out in the dusts.
- the dilute phosphoric acid 3 of the sedimentation tank 1 1 is pumped in the present example in a Nachschreibtank 12, in the residual amounts of
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Mechanical Engineering (AREA)
- Electrochemistry (AREA)
- Food Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Removal Of Specific Substances (AREA)
- Processing Of Solid Wastes (AREA)
- Compounds Of Iron (AREA)
- Thermal Sciences (AREA)
- Treatment Of Sludge (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/128,026 US20140197110A1 (en) | 2011-06-23 | 2011-06-23 | Process and plant for decontaminating phosphoric acid solution |
PCT/EP2011/003102 WO2012175098A1 (de) | 2011-06-23 | 2011-06-23 | Verfahren und anlage zur dekontamination von phosphorsäurelösung |
KR1020147001402A KR101646192B1 (ko) | 2011-06-23 | 2011-06-23 | 인산 용액의 오염 물질 제거 방법 및 플랜트 |
EP11734000.0A EP2723681B1 (de) | 2011-06-23 | 2011-06-23 | Verfahren und anlage zur dekontamination von phosphorsäurelösung |
JP2014516201A JP5764718B2 (ja) | 2011-06-23 | 2011-06-23 | リン酸溶液の除染方法および設備 |
CN201180071821.9A CN103648976B (zh) | 2011-06-23 | 2011-06-23 | 用于净化磷酸溶液的方法和设备 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2011/003102 WO2012175098A1 (de) | 2011-06-23 | 2011-06-23 | Verfahren und anlage zur dekontamination von phosphorsäurelösung |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2012175098A1 true WO2012175098A1 (de) | 2012-12-27 |
Family
ID=44628762
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2011/003102 WO2012175098A1 (de) | 2011-06-23 | 2011-06-23 | Verfahren und anlage zur dekontamination von phosphorsäurelösung |
Country Status (6)
Country | Link |
---|---|
US (1) | US20140197110A1 (de) |
EP (1) | EP2723681B1 (de) |
JP (1) | JP5764718B2 (de) |
KR (1) | KR101646192B1 (de) |
CN (1) | CN103648976B (de) |
WO (1) | WO2012175098A1 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2833367A2 (de) | 2013-08-02 | 2015-02-04 | Babcock Noell GmbH | Anlage und Verfahren zur Bearbeitung von Reststoffen |
DE102021000011A1 (de) | 2021-01-06 | 2022-07-07 | Lean Corporation GmbH | Mobiles und digitales Bearbeitungszentrum für die Bearbeitung, Bemessung, Prüfung und Freigabe von aktivierten, kontaminierten und/oder nicht kontaminierten, nuklearen Reststoffen, bestehend aus dafür speziell entwickelten und per LKW transportierbaren Containern |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108693012B (zh) * | 2018-04-11 | 2021-12-21 | 欧频 | 水中锶-90核素放射化学分析水样品的浓集装置 |
CN111847444A (zh) * | 2020-06-22 | 2020-10-30 | 中国林科院林产化工研究所南京科技开发有限公司 | 一种去除活性炭制备过程中循环回用磷酸溶液中钙镁铁离子的方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4169882A (en) * | 1978-11-13 | 1979-10-02 | Tennessee Valley Authority | Purification of phosphoric acid with oxalic acid |
EP0261255A1 (de) | 1986-09-20 | 1988-03-30 | KGB Kernkraftwerke Gundremmingen Betriebsgesellschaft mbH | Verfahren zum Aufbereiten einer wässrigen Phosphorsäurelösung |
EP0327234A1 (de) * | 1988-02-01 | 1989-08-09 | Imc Fertilizer, Inc. | Entfernung von Eisen aus Phosphorsäure |
EP0638516A1 (de) * | 1993-08-14 | 1995-02-15 | Hoechst Aktiengesellschaft | Verfahren zur Entfernung von Blei und Cadmium aus Phosphorsäure |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5367958A (en) * | 1976-11-30 | 1978-06-16 | Stanley Electric Co Ltd | Method of treating fluorine-contained waste water in multiple stages |
GB9422539D0 (en) * | 1994-11-04 | 1995-01-04 | British Nuclear Fuels Plc | Decontamination processes |
AU6337700A (en) * | 1999-06-24 | 2001-01-09 | University Of Chicago, The | Method for the decontamination of metallic surfaces |
JP2005087988A (ja) * | 2003-08-11 | 2005-04-07 | Mitsubishi Materials Corp | 排水からクロムを除去する方法およびシステム |
US8585903B2 (en) * | 2007-02-14 | 2013-11-19 | Winner Water Services, Inc. | Water purification |
JP2009014227A (ja) * | 2007-07-02 | 2009-01-22 | Finesinter Co Ltd | 熱処理炉 |
CN101920946B (zh) * | 2010-07-27 | 2012-07-11 | 中国海洋石油总公司 | 一种降低湿法磷酸中铁铝离子的方法 |
-
2011
- 2011-06-23 KR KR1020147001402A patent/KR101646192B1/ko active IP Right Grant
- 2011-06-23 CN CN201180071821.9A patent/CN103648976B/zh active Active
- 2011-06-23 US US14/128,026 patent/US20140197110A1/en not_active Abandoned
- 2011-06-23 JP JP2014516201A patent/JP5764718B2/ja active Active
- 2011-06-23 WO PCT/EP2011/003102 patent/WO2012175098A1/de active Application Filing
- 2011-06-23 EP EP11734000.0A patent/EP2723681B1/de not_active Not-in-force
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4169882A (en) * | 1978-11-13 | 1979-10-02 | Tennessee Valley Authority | Purification of phosphoric acid with oxalic acid |
EP0261255A1 (de) | 1986-09-20 | 1988-03-30 | KGB Kernkraftwerke Gundremmingen Betriebsgesellschaft mbH | Verfahren zum Aufbereiten einer wässrigen Phosphorsäurelösung |
EP0327234A1 (de) * | 1988-02-01 | 1989-08-09 | Imc Fertilizer, Inc. | Entfernung von Eisen aus Phosphorsäure |
EP0638516A1 (de) * | 1993-08-14 | 1995-02-15 | Hoechst Aktiengesellschaft | Verfahren zur Entfernung von Blei und Cadmium aus Phosphorsäure |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2833367A2 (de) | 2013-08-02 | 2015-02-04 | Babcock Noell GmbH | Anlage und Verfahren zur Bearbeitung von Reststoffen |
DE102021000011A1 (de) | 2021-01-06 | 2022-07-07 | Lean Corporation GmbH | Mobiles und digitales Bearbeitungszentrum für die Bearbeitung, Bemessung, Prüfung und Freigabe von aktivierten, kontaminierten und/oder nicht kontaminierten, nuklearen Reststoffen, bestehend aus dafür speziell entwickelten und per LKW transportierbaren Containern |
Also Published As
Publication number | Publication date |
---|---|
KR101646192B1 (ko) | 2016-08-08 |
EP2723681B1 (de) | 2017-12-13 |
JP5764718B2 (ja) | 2015-08-19 |
CN103648976A (zh) | 2014-03-19 |
JP2014523529A (ja) | 2014-09-11 |
KR20140038532A (ko) | 2014-03-28 |
EP2723681A1 (de) | 2014-04-30 |
CN103648976B (zh) | 2017-03-15 |
US20140197110A1 (en) | 2014-07-17 |
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