WO2012082178A1 - Spoolable pipe with increased compressive strength and method of manufacture - Google Patents
Spoolable pipe with increased compressive strength and method of manufacture Download PDFInfo
- Publication number
- WO2012082178A1 WO2012082178A1 PCT/US2011/032988 US2011032988W WO2012082178A1 WO 2012082178 A1 WO2012082178 A1 WO 2012082178A1 US 2011032988 W US2011032988 W US 2011032988W WO 2012082178 A1 WO2012082178 A1 WO 2012082178A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- reinforcement
- laminates
- tape
- fibers
- fabric
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 85
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 25
- 230000002787 reinforcement Effects 0.000 claims abstract description 160
- 239000004744 fabric Substances 0.000 claims abstract description 98
- 239000000835 fiber Substances 0.000 claims abstract description 79
- 239000000463 material Substances 0.000 claims description 17
- 238000007596 consolidation process Methods 0.000 claims description 13
- 239000011159 matrix material Substances 0.000 claims description 13
- 238000004804 winding Methods 0.000 claims description 6
- 239000010410 layer Substances 0.000 description 121
- 239000000853 adhesive Substances 0.000 description 20
- 230000001070 adhesive effect Effects 0.000 description 20
- 238000012360 testing method Methods 0.000 description 10
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- 230000005855 radiation Effects 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
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- 238000013461 design Methods 0.000 description 4
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- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- -1 vinyl halide Chemical class 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
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- 229920000914 Metallic fiber Polymers 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229920003235 aromatic polyamide Polymers 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
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- 239000002346 layers by function Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 229920000271 Kevlar® Polymers 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 229920001893 acrylonitrile styrene Polymers 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000002224 dissection Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 229920005680 ethylene-methyl methacrylate copolymer Polymers 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003733 fiber-reinforced composite Substances 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000013305 flexible fiber Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000011900 installation process Methods 0.000 description 1
- 239000004761 kevlar Substances 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920006216 polyvinyl aromatic Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 229920006215 polyvinyl ketone Polymers 0.000 description 1
- 229920006214 polyvinylidene halide Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
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- 230000002441 reversible effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- 229920001187 thermosetting polymer Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
- B32B1/08—Tubular products
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
- F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
- F16L11/08—Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/14—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a face layer formed of separate pieces of material which are juxtaposed side-by-side
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/18—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by an internal layer formed of separate pieces of material which are juxtaposed side-by-side
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/0012—Mechanical treatment, e.g. roughening, deforming, stretching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/12—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/28—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer impregnated with or embedded in a plastic substance
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
- F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
- F16L11/08—Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall
- F16L11/088—Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall comprising a combination of one or more layers of a helically wound cord or wire with one or more braided layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/20—All layers being fibrous or filamentary
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
- B32B2260/023—Two or more layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/07—Parts immersed or impregnated in a matrix
- B32B2305/076—Prepregs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/10—Fibres of continuous length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/54—Yield strength; Tensile strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2597/00—Tubular articles, e.g. hoses, pipes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
Definitions
- the present disclosure relates to a spoolable pipe and method of manufacture.
- Spoolable pipe such as flexible fiber-reinforced pipe is used in natural resource deposit extraction.
- one type of spoolable pipe is unbonded flexible fiber-reinforced pipes that may be made with reinforcement stacks composed of fiber-reinforced composite tape and applied to form armor layers for the spoolable pipe.
- Inter-laminar adhesive may be applied to surfaces of the tapes to allow for bonding between the tapes to form a reinforcement stack of the armor layer.
- the reinforcement stack may be helically wrapped on a pipe and heated or subject to radiation, thereby allowing the inter-laminar adhesive to bond and strengthen the reinforcement stack.
- the tape of the reinforcement stack may be a unidirectional fibrous tape, providing high longitudinal strength to the stack, and, therefore, to the armor layer.
- the present disclosure relates to a method to manufacture an armor layer of a spoolable pipe.
- the method includes forming one or more laminates and wrapping the one or more laminates onto an underlying layer of the pipe.
- the one or more laminates are composed of at least one reinforcement tape and at least one fabric tape.
- the laminates may be bonded to an adjacent laminate, thereby forming a reinforcement stack.
- the present disclosure relates to a method to manufacture an armor layer of a spoolable pipe.
- the method includes providing a plurality of reinforcement tapes having fibers oriented in a first direction and disposing at least one fabric tape between at least two layers of the plurality of reinforcement tapes.
- the fibers of the at least one fabric tape may be oriented in at least a second direction.
- the present disclosure relates to an armor layer of a spoolable pipe.
- the armor layer includes a plurality of reinforcement tapes having fibers oriented in a first direction and at least one fabric tape disposed between at least two tapes of the plurality of reinforcement tapes.
- the at least one fabric tape comprises fibers oriented in at least a second direction.
- the present disclosure relates to an armor layer of a spoolable pipe.
- the armor layer includes a plurality of reinforcement tapes comprising fibers oriented in a first direction, in which at least one of the plurality of reinforcement tapes comprises a plurality of fibers woven within the at least one reinforcement tape.
- the woven fibers of the at least one reinforcement tape are oriented in at least a second direction.
- the present disclosure relates to a method to manufacture an armor layer of a spoolable pipe.
- the method includes providing a plurality of reinforcement tapes having fibers oriented in a first direction and interweaving a plurality of fibers within at least one of the plurality of reinforcement tapes in a second direction.
- Figure 1A is an isometric view of a spoolable pipe in accordance with one or more embodiments of the present disclosure.
- Figure IB is a cross-sectional view of a spoolable pipe in accordance with one or more embodiments of the present disclosure.
- Figure 2 is a schematic of forming laminates in accordance with one or more embodiments of the present disclosure.
- Figure 3 is a process of forming laminates in accordance with one or more embodiments of the present disclosure.
- Figure 4 shows a schematic of a cassette in accordance with one or more embodiments of the present disclosure.
- Figure 5 is a schematic of a primary winder in accordance with one or more embodiments of the present disclosure.
- Figure 6 is a process of forming a spoolable pipe in accordance with one or more embodiments of the present disclosure.
- Figure 7 is a schematic view of a bonding apparatus in accordance with one or more embodiments of the present disclosure.
- Figure 8 is a schematic view of an alternate bonding apparatus in accordance with one or more embodiments of the present disclosure.
- Figure 9 is a plot of fiber failure criterion for the design of a reinforcement stack.
- Figure 10 is a finite element model of reinforcement stacks.
- Figure 11 is a plot of fiber failure criterion of reinforcement stacks in accordance with one or more embodiments of the present disclosure.
- Spoolable pipe for example, flexible pipe, such as unbonded Flexible Fiber Reinforced Pipe (FFRP®) as developed by DeepFlex, Inc., may be constructed from extruded polymer fluid barrier layers and metallic or composite armor layers.
- FFRP® unbonded Flexible Fiber Reinforced Pipe
- the unique design of bonding multiple thin reinforcement tapes or laminates to form reinforcement stacks with interlaminar adhesive allows the reinforcement material to provide resistance to internal and external pressure and axial tension and compression loads experienced by the spoolable pipe.
- the higher axial compression capacity of the flexible pipe structure laminated reinforcement stack may overcome challenges faced in previous composite armored flexible pipe designs which employ multiple thin fiber reinforced polymer tapes.
- a liner 102 may be wrapped with one or more armor layers and additional structural and/or functional layers.
- armor layer 106 composed of reinforcement stacks comprising stacks of laminates helically wrapped in a first orientation
- armor layer 108 composed of reinforcement stacks comprising stacks of laminates helically wrapped in a second orientation
- one or more armor layers 104 composed of helically wrapped reinforcement stacks comprising stacks of laminates, may be wrapped at different, for example higher, lay-angles to form additional armor layers with different functional characteristics.
- Anti-wear layers may be disposed between armor layers 104, 106, and 108 and one or more anti-extrusion layers 120 and 122 may be disposed between inner most armor layer 104 and liner 102.
- a jacket 110 may cover the armor layers and other elements of the pipe 100 to provide external protection.
- a liner 152 may be wrapped with one or more armor layers and additional structural and/or functional layers.
- armor layers 154, 156, and 158 may be provided as structural layers of pipe 150.
- Armor layers 154, 156, and 158 may be composed of stacks of laminates and/or tape 180.
- Anti-wear layers 165 may be disposed between armor layers 156 and 158 and/or between armor layer 154 and a membrane 175.
- one or more anti-extrusion layers 170 and 172 may be disposed between inner most armor layer 154 and liner 152.
- a jacket 160 may cover the armor layers and other elements of the pipe 150 to provide external protection.
- Figures 1A and IB depict pipe structures 100 and 150 of a spoolable pipe, these are merely for example only, and those skilled in the art will appreciate that a spoolable pipe may include additional and/or different layers, without departing from the scope of the present disclosure.
- a spoolable pipe structure may include various combinations of liners, carcasses, hoop-strength or pressure armor layers, anti-wear layers, lubricating layers, tensile armor layers, anti-extrusion layers, membranes, and/or any other layers as may be included in a spoolable and/or flexible pipe, without departing from the scope of the present disclosure.
- armor layers 104, 106, 108 may provide various structural protection and/or strength to spoolable pipe 100.
- the reinforcement stacks of armor layer 104 may be configured and oriented to form a hoop-strength armor layer and the reinforcement stacks of armor layers 106 and 108 may be configured and oriented to form tensile armor layers.
- an armor layer may be a tensile armor layer, a hoop-strength armor layer, or other reinforcement and/or structural armor layer of a spoolable or flexible pipe and may be composed of one or more stacks of laminates and/or reinforcement tape, as discussed hereinafter.
- the reinforcement stacks of armor layers 104, 106, and 108 may be composed of stacks of laminates.
- the laminates may be made of one or more stacked fiber- reinforced tapes (reinforcement tapes) that may be laminated and bonded together with an interlaminate layer or tape or may be a single structural member.
- the reinforcement tapes of the laminates may be unidirectional tape and/or other structural and/or reinforced tape.
- the reinforcement tape may include unidirectional, longitudinally, oriented fibers, providing strength in the longitudinal direction of the tape.
- the individual reinforcement tapes may be composed of the unidirectional fibers laminated, or bonded, by a material, such as a matrix material, that may provide strength in the width direction of the stack, thereby increasing the compressive capacity of the reinforcement tape.
- the laminates or reinforcement tapes may be formed from fibers encapsulated in polymers, and bonding between adjacent laminates in a reinforcement stack may require heat, radiation, or normal force to bond the laminates to adjacently stacked laminates to achieve appropriate operational properties.
- the reinforcement stacks may be chemically resistant, thermally insulated, strong enough to provide support, flexible enough to provide relative movement and/or sliding, flexible enough to allow the pipe to bend, and/or configured to any other necessary and/or required operational properties.
- the laminates may be fiber-reinforced tapes.
- the laminates may be composed of composite matrix materials and/or polymers, including, but not limited to polyphenylene sulfide, polyetheretherketone, polyvinylidene halide, vinyl halide polymer, vinyl halide copolymer, polyvinyl ketone, polyvinyl ether, vinyl ester, hybrid epoxy vinyl ester, polyvinyl methyl ether, polyvinyl aromatic, silicone, acrylic polymer, acrylic copolymer, polybutylmethacrylate, polyacrylonitrile, acrylonitrile- styrene copolymer, ethylene-methyl methacrylate copolymer, polyamide, polyimide, polyether, polyhedral oligomeric silsesquioxane epoxy hybrid, epoxy resin, polyurethane, and/or polyoxymethylene and/or combinations thereof.
- the composite matrix materials and/or polymers that compose the fiber reinforced tapes may be partially or fully cured or hardened.
- the fibers of the laminate may be unidirectional in orientation, allowing for maximum longitudinal strength when a reinforcement stack is formed.
- Laminates with unidirectional fibers may be formed using a pultrusion process.
- the fibers of the fiber reinforced tapes may be made of materials such as aramids, aromatics, ceramics, polyolefin, carbon fiber, graphite fiber, fiberglass, E-glass, chemical resistant E-glass, S-glass, metallic fibers, and/or any other fibrous material and/or any combinations thereof.
- the laminates may be gathered, collected, and/or consolidated to form a reinforcement stack at the time of installation of the reinforcement stacks onto the surface of the pipe when forming an armor layer, or the laminates may be formed in segments and stored for later application onto a pipe structure.
- a bonding material to bond adjacent laminates in a reinforcement stack such as an inter-laminar adhesive
- the bonding material may be any suitable thermoset or thermoplastic material that provides sufficient bonding strength to keep the laminates from delaminating in service.
- the bonding provided by the interlaminar adhesive may be reversible, such as described in U.S. Patent No. 7,842,149 issued to Kristian Glejb l, on November 30, 2010 and entitled "Method of Manufacturing a Reinforcement Element for a Flexible Pipeline,” incorporated in its entirety herein by reference.
- a laminate is a tape structure or element of a reinforcement stack.
- a laminate may be a single reinforcement tape or may be a reinforcement tape with additional properties or elements within and/or attached thereto.
- a laminate may be a modified reinforcement tape that includes cross-woven fibers, or weft fibers, that may be configured with the longitudinal fibers of the reinforcement tape prior to lamination of the fibers to form the tape.
- a laminate may be two tapes bonded together.
- a laminate may be a reinforcement tape bonded with a fibrous tape in which the fibers of the fibrous tape may be configured at one or more different angles from the direction of the longitudinal fibers of the reinforcement tape.
- a fabric tape may be bonded to a reinforcement tape to form a laminate.
- laminates may be formed in any manner and incorporate any known elements without departing from the scope of the present disclosure.
- the fibers that are cross-woven, in the fibrous or fabric tape may be substantially perpendicular to the fibers of the reinforcement tape. Although described herein as perpendicular, those skilled in the art will appreciate that the fibers of the cross-weave, fibrous tape, or fabric tape may be any angle or assortment of angles with respect to the fibers of the reinforcement tape, without departing from the scope of the present disclosure.
- the reinforcement stacks may be partially bonded.
- the tape layers that may form the laminates of the reinforcement stacks may be partially cured or hardened or fully cured or hardened at the time of applying the reinforcement stacks to the pipe.
- An inter-laminar adhesive may provide bonding between adjacent laminates stacked in the reinforcement stack, and may also provide additional strength to the reinforcement stack.
- one or more embodiments of the present disclosure may provide an increased compressive strength through application of an inter-laminar adhesive and a fiber tape with fibers oriented, at least, substantially perpendicular to the fibers of the reinforcement tape.
- the reinforcement stacks may be formed by placing a fabric tape between each layer of reinforcement tape that may be collected (or stacked) to form the reinforcement stack.
- the fabric tape may be combined with a reinforcement tape to form a laminate of the reinforcement stack.
- the bonding between adjacent reinforcement tapes may be provided by fabric tapes that may be interleaved with the reinforcement tapes.
- the interleaving may be completed by alternating fabric tapes with the reinforcement tapes, or multiple layers of fabric tape may be stacked between reinforcement tapes in any combination.
- the fabric tape may include glass, aramid, carbon, steel, or other non-metallic or metallic fibers, including those discussed above with respect to the reinforcement tapes, and may be a pre- impregnated tape ("prepreg").
- prepreg pre- impregnated tape
- the fabric tape may provide both an inter- laminar adhesive and provide additional strength to the reinforcement stacks.
- Prepreg tape is a pre-impregnated material having fibers distributed within or on a bonding matrix material.
- the fibers of the prepreg may be unidirectional, woven, non-woven, matt, chopped matt, random, or may have any other orientation of fibers.
- the fibers of the prepreg may be bonded by the matrix material and may also allow for a bonding process to bond the prepreg material with other elements, such as the reinforcement tapes.
- the matrix material may be asymmetrically distributed through the thickness of the prepreg so that it may be substantially tackier, or more adhesive, on one side than the other.
- the tackier side of the fabric tape may have a backer to prevent the adhesive from bonding to other elements or equipment during a manufacturing process and the backer may be removed when the fabric tape is to be bonded to or combined with another element, such as when forming a laminate.
- the less tacky side, or the side with no tack at all may not bond to adjacent material until the prepreg matrix material is activated by heat, radiation, or other process.
- the interleaved fabric tapes may be optimized for higher strength in the width direction rather than in the longitudinal direction or may be configured to provide strength both in the width direction and longitudinally.
- the longitudinal strength of a laminate may be provided by the unidirectional fibers of the reinforcement tape and the width direction strength may be provided by the fibers of the fabric tape.
- weft fibers may be woven with the longitudinal fibers prior to pultrusion of a resin onto the fibers during manufacture of the reinforcement tape, such that the reinforcement tapes may have strength in the width direction in addition to the longitudinal direction, obviating or reducing the requirement for the interleaved fabric tape.
- R is the safety factor
- ⁇ is the normal stress in the direction
- Qij is the shear stress in the ij direction
- ⁇ u is the characteristic tensile strength in the direction
- £7 ic is the characteristic compressive strength in the i direction
- ⁇ j ij is the characteristic shear strength in the ij direction.
- a typical failure envelope with unidirectional reinforcement tape without interleaved fabric, based on tensile strength in the circumferential (hoop) direction and compressive strength in the through thickness (radial) direction provides a failure envelope, as shown in Figure 9, based on the 2-D Tsai-Wu failure theory.
- Figure 10 illustrates typical finite element analysis results.
- the through thickness compressive stress distribution on the stacks 1002 and 1004 at 10,000 psi internal pressure is shown.
- a through thickness compressive stress distribution is shown at the highest concentration at the upper surface and corners 1006 of the two adjacent stacks 1002 and 1004.
- FIG. 1A Various tests conducted demonstrated that the model predicted the burst pressure and burst failure mode.
- One example test is a mid-scale test, where a pipe sample is built with the liner 102, the anti-extrusion layers 120 and 122, and hoop strength armor layer 104, as shown in Figure 1A, only. An end cap load due to internal pressure, which is normally resisted by the tensile layers, is reacted against a test frame, so that the pipe does not extend axially. Dissection results after failure of the stacks of the armor layers indicated through thickness compressive failure of the reinforcement stack at the corner interfacing with the anti-extrusion layer, such as the high pressure areas 1006 shown in Figure 10.
- Figure 11 illustrates how the Tsai- Wu failure envelope is expanded with use of embodiments of the present disclosure.
- Figure 11 shows expansion of the Tsai-Wu failure envelope, demonstrating increase in burst pressure with the addition of interleaved fabric into the reinforcement stacks of the hoop strength armor layer.
- the inner most envelope 1102 represents the failure envelope of a control armor layer, one having no interleaved fabric layer, similar to the failure envelope of Figure 9.
- Envelope 1104 represents the failure envelope of a control layer with the addition of a fabric layer having a thickness of 0.01 inches (0.2540 mm) and comprising glass fibers.
- Envelope 1106 represents the failure envelope of a control layer with the addition of a fabric layer having a thickness of 0.014 inches (0.3356 mm) and comprising glass fibers.
- Envelope 1108 represents the failure envelope of a control layer with the addition of a fabric layer having a thickness of 0.01 inches (0.2540 mm) and comprising Kevlar fabric.
- Figures 9-11 merely represent testing of various embodiments of the present disclosure and that other compositions and dimensions of the fabric layer(s) may be used without departing from the present disclosure and/or may be used in other armor layers of a spoolable pipe.
- the analysis presented herein demonstrates an increased strength in the hoop layer 104, similar analyses demonstrate improved performance of the tensile armor layer.
- the improved stacks in accordance with one or more embodiments of the present disclosure may contribute to providing internal pressure load resistance, or may improve performance where contact pressure from adjacent layers is compressively loading the tensile armor in the through thickness direction.
- the advantages of the interleaved fabric layer, with fibers substantially perpendicular to the longitudinal fibers of the reinforcement tape may apply to both the hoop armor layer 104 and the tensile armor layers 106 and 108. This is particularly true for high pressure and high tension capacity spoolable pipe designs that may be employed in deep water operations.
- reinforcement tape and fabric tape may be bonded and/or wound together to form segments of laminates.
- the laminate may be a single structural tape with a layer of reinforcement tape and a layer of fabric tape. Where the fabric tape is a prepreg, the tackier or higher adhesive side may be adhered to the reinforcement tape to form the laminate, and the non-tacky or less tacky side may be the other side of the fabric tape. Thus, the laminate may not substantially adhere to adjacent laminate wraps when spooled into a segment.
- a laminate formation apparatus in accordance with one or more embodiments of the present disclosure is shown in Figure 2, and a laminate formation process in accordance with one or more embodiments of the present disclosure is shown in Figure 3.
- the segments may be stacked to form reinforcement stacks and may be applied to underlying layers of a pipe thereby forming an armor layer of the pipe.
- Figure 4 shows alternate views of a cassette of segments of laminate in accordance with one or more embodiments of the present disclosure.
- Figure 5 shows a primary winder in accordance with one or more embodiments of the present disclosure.
- Figure 6 shows a process of manufacturing a spoolable pipe in accordance with one or more embodiments of the present disclosure.
- a spool 202 may store a winding of reinforcement tape 201.
- Spool 202 may be configured to dispense reinforcement tape 201 from a payoff 204 and reinforcement tape 201 may be unspooled and fed to an accumulator/tensioner 206.
- Reinforcement tape 201 may then be fed through a web control 208, and then to a consolidator 230, where the reinforcement tape 201 may be combined with a fabric tape 251 to form a laminate 231.
- fabric tape 251 may be fed from a spool
- a backer of the fabric tape may be removed by backer removal apparatus 260, exposing a side of the fabric tape having an adhesive.
- the fabric tape 251 , without the backer, and the reinforcement tape 201 may then be combined at consolidator 230 to form laminate 231.
- Laminate 231 may then be wound on a segment on segment winder 232 for storage or pre-pipe fabrication holding.
- laminate 231 may be applied directly to a pipe structure during manufacturing of the pipe after being consolidated or applied to the pipe structure at the point/time of consolidation. Accordingly, the laminates may be consolidated and immediately stacked on a pipe to form the reinforcement stacks of an armor layer.
- FIG. 3 a process 300 of forming a laminate in accordance with one or more embodiments of the present disclosure is shown.
- the laminate may be formed from a layer of fabric tape and a layer of reinforcement tape.
- a fabric tape may be provided on a bobbin or other storage device, and a reinforcement tape may be provided on a bobbin or other storage device, each to be fed to a consolidation means for combining the two tapes to form a single laminate.
- a fabric tape and reinforcement tape may be provided from any feeders and/or other sources known in the art without departing from the scope of the present disclosure.
- the fabric tape may be unspooled or provided from a payoff, such as a bobbin payoff.
- the fabric layer may then be fed through an accumulator and/or tensioner at step 304.
- a web control may be provided at step 306.
- the accumulators, tensioners, and web controls, at steps 304 and 306, may allow for the tape to have proper tension, alignment, and position at a point of consolidation, touchdown, or application.
- a backer of the fabric tape may be removed.
- the fabric tape has two sides, one of which may have adhesive for bonding with a reinforcement tape.
- the adhesive side may have a backer to allow for proper storage of the fabric tape and to prevent the fabric tape from sticking to itself or accumulators, tensioners, web controls, and/or other elements and/or equipment during processing. After the backer is removed, the fabric tape may be fed to a consolidator at step 320.
- reinforcement tape may be provided from a payoff, such as a bobbin payoff.
- the reinforcement tape may also be fed through accumulators and/or tensioners at step 314 and fed through a web control at step 316. Because the reinforcement tape does not have an adhesive coating, the step of backer removal is not necessary for the reinforcement tape.
- the reinforcement tape may have the adhesive and backer, and a backer removal may be used with the reinforcement tape, prior to consolidation, or both tapes may have adhesive and/or backers to be removed, without departing from the scope of the present disclosure.
- the reinforcement tape may then be fed to the consolidator at step 320.
- the fabric tape and the reinforcement tape may be consolidated.
- the consolidation allows for the fabric tape and the reinforcement tape to form a single structural element, a laminate.
- the tackiness or adhesive on one side of the fabric tape may allow for proper consolidation of the two tapes to form the laminate, bonding the fabric tape to the reinforcement tape.
- the consolidation at step 320 may be made by rollers or another device to apply a normal force to the laminate.
- heat or radiation may be applied to consolidate the laminate, or other known means of combining two tapes such that the two tapes are aligned and form a single laminate after consolidation.
- the laminate may then be wound onto a segment using a segment winder, cassette, or other structure at step 322.
- a cassette is a collection of segments that are grouped together for the purpose of constructing a reinforcement stack of an armor layer when applied to the surface of a pipe during construction, see Figure 4 and discussion below.
- the wound laminates may form segments of laminate material and may be stored, for example, on cassettes that may be used for feeding the segments to form a reinforcement stack of an armor layer of a spoolable pipe.
- the laminates may be fed onto a segment winder or cassette and then fed directly to form an armor layer of a spoolable pipe, without the need to be stored.
- the consolidation may occur at the time of pipe assembly at step 330, eliminating the need for cassettes and/or storage.
- cassettes may be installed on a primary winder to allow for formation of reinforcement stacks during manufacture of a spoolable pipe.
- a primary winder 500 is shown.
- Primary winder 500 may be installed with one or more cassettes 502.
- a process 600 of constructing a spoolable pipe in accordance with one or more embodiments is shown.
- the laminate may be formed in segments, or merely consolidated at the time of manufacture, depending on the preferred process. If consolidation is used to form segments on cassettes or other storage means, the segments may then be stored on a cassette at step 604.
- One or more segments of laminates may be stored on a single cassette. If more than one segment is wrapped on a single cassette, two sequential laminates may be bonded together to form a single, longer segment. Alternatively, the segments may not necessarily need to be bonded at the time of winding the segments on the cassettes; the non-bonded or joined segments may be bonded together during a bonding process of the pipe or at any other time without departing from the scope of the present disclosure.
- one or more cassettes may be installed on a primary winder configured to pay off the segments from each of the cassettes installed on the primary winder.
- the primary winder may pay off the segments from the cassettes onto the surface of a spoolable pipe to form one or more reinforcement stacks composed of helical stacks of the segments of laminates.
- the laminates may be applied to the underlying layer in one or more helical stacks of laminates.
- Each stack of laminates may form a reinforcement stack of an armor layer of the spoolable pipe.
- laminates forming a first armor layer may be applied to an underlying layer such as an anti- extrusion layer that is wrapped around a core or liner of the spoolable pipe, as shown in Figure 1 A and Figure IB.
- the laminates may be applied directly to a liner or other interior element, or may be applied to an anti-wear layer or other layer of the spoolable pipe.
- Subsequently applied armor layers may each be applied to an underlying layer which may be any layer of the spoolable pipe.
- the spoolable pipe may be passed through an oven to bond the laminates.
- the bonding process may allow for the prepreg matrix material in the fabric tape to bond adjacent laminates. Heating the prepreg in the laminate may result in the matrix material wetting the fabric in the prepreg more uniformly. Further, the wetting may wet adjacent reinforcement tape surfaces so that additional heating or radiation and/or subsequent cooling may harden the matrix material and may bond the one or more fabric tapes and reinforcement tapes into a single structural reinforcement stack of the armor layer.
- the reinforcement tapes may be bonded into reinforcement stacks to form the armor layers.
- the bonding process may allow for the laminates of the armor layers to bond and impart the necessary structural characteristics to the armor layer.
- Various bonding processes may be used without departing from the scope of the present disclosure, including, but not limited to, modular hydrothermal curing and steam curing. Further, alternative bonding processes are disclosed in Patent Application No. PCT/US 11/27010 filed on March 3, 2010 and entitled “Radiation Cured Reinforcement Stacks,” incorporated in its entirety herein by reference.
- the spoolable pipe 701 may pass through cure units 704 and 706.
- Each of the cure units 704 and 706 may be water-filled and heated to curing temperatures.
- Cure units 704 and 706 may each be composed of a clamshell.
- the clamshell structure may allow for curing of segments of spoolable pipe 701.
- the clamshells of cure units 704 and 706 may include a low-friction flexible membrane 703 configured to isolate and seal the hydrothermal fluid within cure units 704 and 706.
- the module hydrothermal cure units 704 and 706 may be designed to be used end-to-end to provide required curing temperatures and residency time. Multiple cure units may be used and set to different temperatures to produce controlled temperature ramping rates and cooling of the spoolable pipe 701.
- the low-friction flexible membrane may allow for the spoolable pipe 701 to move through the cure units at production rates, thereby allowing the pipe to pass through the units without impeding the speed of production.
- each cure unit may be equipped with an individual temperature controller or may be controlled by a master control unit, such as a programmable logic controller. Further, the cure units may be configured such that external recirculating and various heating systems may be used.
- the spoolable pipe may be cured using steam curing.
- a spoolable pipe 801 may pass through a steam curing unit 800 along a conveyance means 803.
- Flexible seals 808 may be configured at either end of the steam curing unit 800 such that a proper fluid seal is created, and proper curing temperatures may be maintained.
- Steam may be provided to the steam cure unit 800 from an external boiler unit and may be controlled by solenoid valves. Alternatively, other methods of steam production and/or supply may be used without departing from the scope of the present disclosure.
- the reinforcement stack may have tension stress in the fiber direction (along the length of the reinforcement stack) and have compressive stress through the thickness direction when under internal pressure load.
- the compressive stress through the thickness generates a tensile stress across the width of the stacks of the armor layer.
- the tensile capacity across the width may be controlled by the tensile capacity of the matrix material bonding the fibers of the reinforcement tapes, and, in accordance with one or more embodiments of the present disclosure, the tensile capacity may be increased by including a fabric tape in the formation of the laminates of the stacks of the armor layer.
- armor layers including hoop strength and tensile strength armor layers, may have increased compressive strength in the reinforcement stacks that may comprise the armor layers.
- Prepreg materials in a fabric tape may provide fibers in a width direction, in addition to the longitudinal fibers of the reinforcement tape. The width direction fibers may increase the compressive strength of the laminates and the reinforcement stacks they form.
- prepreg material may reduce the thickness and cost of production by automating the adhesive application process and allowing a minimalistic fabric layer to provide substantial compressive strength increases.
- flexible pipe as disclosed herein, may be ideal for deepwater and ultra-deepwater service.
- traditional steel flexible pipe may have insufficient tension capacity at a hang-off location during deployment in deepwater and ultra-deepwater service.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Laminated Bodies (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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EP11847942.7A EP2652380A4 (en) | 2010-12-14 | 2011-04-19 | Spoolable pipe with increased compressive strength and method of manufacture |
US13/994,575 US20130312862A1 (en) | 2010-12-14 | 2011-04-19 | Spoolable pipe with increased compressive strength and method of manufacture |
CN201180060345.0A CN103299116B (en) | 2010-12-14 | 2011-04-19 | A kind of wound form pipe and manufacture method increasing compression strength |
BR112013015197A BR112013015197A2 (en) | 2010-12-14 | 2011-04-19 | coiled tube with increased compressive strength and manufacturing method |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US42292210P | 2010-12-14 | 2010-12-14 | |
US61/422,922 | 2010-12-14 |
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WO2012082178A1 true WO2012082178A1 (en) | 2012-06-21 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2011/032988 WO2012082178A1 (en) | 2010-12-14 | 2011-04-19 | Spoolable pipe with increased compressive strength and method of manufacture |
Country Status (5)
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US (1) | US20130312862A1 (en) |
EP (1) | EP2652380A4 (en) |
CN (1) | CN103299116B (en) |
BR (1) | BR112013015197A2 (en) |
WO (1) | WO2012082178A1 (en) |
Cited By (3)
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WO2019186099A1 (en) * | 2018-03-29 | 2019-10-03 | Ge Oil & Gas Uk Limited | Flexible pipe body and method |
WO2019221913A1 (en) | 2018-05-15 | 2019-11-21 | Illumina, Inc. | Flow cell with flexible connection |
EP3628025A4 (en) * | 2018-05-15 | 2020-04-01 | Illumina Inc. | Flow cell with flexible connection |
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US7886775B2 (en) * | 2007-04-10 | 2011-02-15 | Netafim, Ltd. | Irrigation pipe |
US20130319571A1 (en) * | 2012-06-01 | 2013-12-05 | Todd A. Volker | Composite pipe |
US10184594B1 (en) | 2012-06-01 | 2019-01-22 | Todd A. Volker | Composite pipe |
FR2991747B1 (en) * | 2012-06-08 | 2016-07-01 | 3X Eng | DEVICE AND METHOD FOR REPAIRING A LONGILINE BODY |
WO2015028025A1 (en) * | 2013-09-02 | 2015-03-05 | National Oilwell Varco Denmark I/S | A flexible pipe |
US20160111183A1 (en) * | 2014-10-14 | 2016-04-21 | Oceaneering International, Inc. | Composite Wrapped Steel Tubes for Use in Umbilicals |
FR3059073B1 (en) * | 2016-11-21 | 2019-08-16 | Technip France | UNLATCHED FLEXIBLE CONDUIT FOR TRANSPORTING ABRASIVE MATERIAL, METHOD AND USE THEREOF |
CN106585040B (en) * | 2016-12-23 | 2018-11-16 | 江苏玖尚新材料有限公司 | A kind of external protection sheet production device |
CN108621501B (en) * | 2018-02-26 | 2019-05-31 | 南京良龙电力科技有限公司 | A kind of PVC pipe processing unit (plant) |
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- 2011-04-19 CN CN201180060345.0A patent/CN103299116B/en not_active Expired - Fee Related
- 2011-04-19 EP EP11847942.7A patent/EP2652380A4/en not_active Withdrawn
- 2011-04-19 WO PCT/US2011/032988 patent/WO2012082178A1/en active Application Filing
- 2011-04-19 BR BR112013015197A patent/BR112013015197A2/en not_active IP Right Cessation
- 2011-04-19 US US13/994,575 patent/US20130312862A1/en not_active Abandoned
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AU2019270818B2 (en) * | 2018-05-15 | 2021-07-08 | Illumina, Inc. | Flow cell with flexible connection |
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US12064761B2 (en) | 2018-05-15 | 2024-08-20 | Illumina, Inc. | Flow cell with flexible connection |
Also Published As
Publication number | Publication date |
---|---|
US20130312862A1 (en) | 2013-11-28 |
EP2652380A1 (en) | 2013-10-23 |
BR112013015197A2 (en) | 2018-06-26 |
CN103299116A (en) | 2013-09-11 |
CN103299116B (en) | 2016-04-27 |
EP2652380A4 (en) | 2015-04-01 |
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