WO2012067962A1 - Hard surface cleaners comprising low voc, low odor alkanolamines - Google Patents
Hard surface cleaners comprising low voc, low odor alkanolamines Download PDFInfo
- Publication number
- WO2012067962A1 WO2012067962A1 PCT/US2011/060399 US2011060399W WO2012067962A1 WO 2012067962 A1 WO2012067962 A1 WO 2012067962A1 US 2011060399 W US2011060399 W US 2011060399W WO 2012067962 A1 WO2012067962 A1 WO 2012067962A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- amino
- methyl
- alkyl
- cleaning composition
- surfactants
- Prior art date
Links
- 239000000203 mixture Substances 0.000 claims abstract description 122
- 238000004140 cleaning Methods 0.000 claims abstract description 85
- -1 builder Substances 0.000 claims abstract description 59
- 239000004094 surface-active agent Substances 0.000 claims abstract description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002904 solvent Substances 0.000 claims abstract description 22
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 claims abstract description 17
- AHZILZSKKSPIKM-UHFFFAOYSA-N 3-aminooctan-4-ol Chemical compound CCCCC(O)C(N)CC AHZILZSKKSPIKM-UHFFFAOYSA-N 0.000 claims abstract description 16
- WRIFCFZXLZGSGD-UHFFFAOYSA-N 1-(dimethylamino)-2-methylpropan-1-ol Chemical compound CC(C)C(O)N(C)C WRIFCFZXLZGSGD-UHFFFAOYSA-N 0.000 claims abstract description 9
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003755 preservative agent Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000003086 colorant Substances 0.000 claims abstract description 7
- 239000000975 dye Substances 0.000 claims abstract description 7
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000003139 biocide Substances 0.000 claims abstract description 3
- 239000003205 fragrance Substances 0.000 claims abstract description 3
- 230000002335 preservative effect Effects 0.000 claims abstract description 3
- 239000006254 rheological additive Substances 0.000 claims abstract description 3
- 230000003115 biocidal effect Effects 0.000 claims abstract 2
- IOAOAKDONABGPZ-UHFFFAOYSA-N 2-amino-2-ethylpropane-1,3-diol Chemical compound CCC(N)(CO)CO IOAOAKDONABGPZ-UHFFFAOYSA-N 0.000 claims description 7
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 claims description 6
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 4
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 claims description 3
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 claims description 3
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 claims description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 claims description 2
- 125000003158 alcohol group Chemical group 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 abstract description 7
- 125000000217 alkyl group Chemical group 0.000 description 38
- 125000004432 carbon atom Chemical group C* 0.000 description 28
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 24
- 150000001412 amines Chemical class 0.000 description 17
- 238000009472 formulation Methods 0.000 description 17
- 239000012855 volatile organic compound Substances 0.000 description 17
- 125000002091 cationic group Chemical group 0.000 description 16
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 15
- 235000019441 ethanol Nutrition 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 11
- 238000002156 mixing Methods 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- 150000008051 alkyl sulfates Chemical class 0.000 description 9
- 239000003945 anionic surfactant Substances 0.000 description 9
- 239000012141 concentrate Substances 0.000 description 9
- 235000014113 dietary fatty acids Nutrition 0.000 description 9
- 239000000194 fatty acid Substances 0.000 description 9
- 229930195729 fatty acid Natural products 0.000 description 9
- 150000004665 fatty acids Chemical class 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 8
- 125000001183 hydrocarbyl group Chemical group 0.000 description 8
- 108010077895 Sarcosine Proteins 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 7
- 125000002252 acyl group Chemical group 0.000 description 7
- 125000003342 alkenyl group Chemical group 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- 125000004429 atom Chemical group 0.000 description 6
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000000344 soap Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 229960004418 trolamine Drugs 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 241000350481 Pterogyne nitens Species 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 150000001450 anions Chemical class 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000003093 cationic surfactant Substances 0.000 description 5
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 125000006850 spacer group Chemical group 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 102100032373 Coiled-coil domain-containing protein 85B Human genes 0.000 description 4
- 101000868814 Homo sapiens Coiled-coil domain-containing protein 85B Proteins 0.000 description 4
- 239000000872 buffer Substances 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 4
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 229940071089 sarcosinate Drugs 0.000 description 4
- 229940043230 sarcosine Drugs 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- 150000003505 terpenes Chemical class 0.000 description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 3
- 229940035437 1,3-propanediol Drugs 0.000 description 3
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 3
- XRIBIDPMFSLGFS-UHFFFAOYSA-N 2-(dimethylamino)-2-methylpropan-1-ol Chemical compound CN(C)C(C)(C)CO XRIBIDPMFSLGFS-UHFFFAOYSA-N 0.000 description 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- SEQKRHFRPICQDD-UHFFFAOYSA-N N-tris(hydroxymethyl)methylglycine Chemical compound OCC(CO)(CO)[NH2+]CC([O-])=O SEQKRHFRPICQDD-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical class [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 125000005907 alkyl ester group Chemical group 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 3
- 239000006172 buffering agent Substances 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000013522 chelant Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 150000002169 ethanolamines Chemical class 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 3
- 235000013772 propylene glycol Nutrition 0.000 description 3
- 229960004063 propylene glycol Drugs 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 235000010356 sorbitol Nutrition 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 2
- LORVPHHKJFSORQ-UHFFFAOYSA-N 1-[1-(1-butoxypropan-2-yloxy)propan-2-yloxy]propan-2-ol Chemical compound CCCCOCC(C)OCC(C)OCC(C)O LORVPHHKJFSORQ-UHFFFAOYSA-N 0.000 description 2
- NGOZDSMNMIRDFP-UHFFFAOYSA-N 2-[methyl(tetradecanoyl)amino]acetic acid Chemical compound CCCCCCCCCCCCCC(=O)N(C)CC(O)=O NGOZDSMNMIRDFP-UHFFFAOYSA-N 0.000 description 2
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- LVDKZNITIUWNER-UHFFFAOYSA-N Bronopol Chemical compound OCC(Br)(CO)[N+]([O-])=O LVDKZNITIUWNER-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229920000388 Polyphosphate Chemical class 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 2
- 229960001231 choline Drugs 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- 229940043276 diisopropanolamine Drugs 0.000 description 2
- 150000002171 ethylene diamines Chemical class 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 125000003506 n-propoxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
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- 235000011176 polyphosphates Nutrition 0.000 description 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 108700004121 sarkosyl Proteins 0.000 description 2
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 2
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 2
- 150000005846 sugar alcohols Chemical class 0.000 description 2
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- 238000010998 test method Methods 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
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- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
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- LNFLHXZJCVGTSO-UHFFFAOYSA-N 1-(3-butoxypropoxy)propan-1-ol Chemical compound CCCCOCCCOC(O)CC LNFLHXZJCVGTSO-UHFFFAOYSA-N 0.000 description 1
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- SERLAGPUMNYUCK-DCUALPFSSA-N 1-O-alpha-D-glucopyranosyl-D-mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O SERLAGPUMNYUCK-DCUALPFSSA-N 0.000 description 1
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- URBCOZYCCAFMJK-UHFFFAOYSA-M sodium;2-[methyl(octadecanoyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)N(C)CC([O-])=O URBCOZYCCAFMJK-UHFFFAOYSA-M 0.000 description 1
- KHCOJQDJOCNUGV-UHFFFAOYSA-M sodium;2-[methyl(tetradecanoyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCCC(=O)N(C)CC([O-])=O KHCOJQDJOCNUGV-UHFFFAOYSA-M 0.000 description 1
- VLKIFCBXANYYCK-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enoyl]amino]acetate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CC([O-])=O VLKIFCBXANYYCK-GMFCBQQYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000000979 synthetic dye Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 231100000440 toxicity profile Toxicity 0.000 description 1
- ZCIHMQAPACOQHT-ZGMPDRQDSA-N trans-isorenieratene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/c1c(C)ccc(C)c1C)C=CC=C(/C)C=Cc2c(C)ccc(C)c2C ZCIHMQAPACOQHT-ZGMPDRQDSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- 125000002264 triphosphate group Chemical class [H]OP(=O)(O[H])OP(=O)(O[H])OP(=O)(O[H])O* 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2011329230A AU2011329230A1 (en) | 2010-11-16 | 2011-11-11 | Hard surface cleaners comprising low VOC, low odor alkanolamines |
CN2011800550928A CN103221525A (en) | 2010-11-16 | 2011-11-11 | Hard surface cleaners comprising low VOC, low odor alkanolamines |
EP11791680.9A EP2640816A1 (en) | 2010-11-16 | 2011-11-11 | Hard surface cleaners comprising low voc, low odor alkanolamines |
CA2816718A CA2816718A1 (en) | 2010-11-16 | 2011-11-11 | Hard surface cleaners comprising low voc, low odor alkanolamines |
US13/878,907 US20130196893A1 (en) | 2010-11-16 | 2011-11-11 | Hard Surface Cleaners Comprising Low VOC, Low Odor Alkanolamines |
BR112013010673A BR112013010673A2 (en) | 2010-11-16 | 2011-11-11 | hard surface cleaning composition |
JP2013539917A JP2014500356A (en) | 2010-11-16 | 2011-11-11 | Hard surface cleaner containing low VOC, low odor alkanolamine |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US41405810P | 2010-11-16 | 2010-11-16 | |
US61/414,058 | 2010-11-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2012067962A1 true WO2012067962A1 (en) | 2012-05-24 |
Family
ID=45099176
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2011/060399 WO2012067962A1 (en) | 2010-11-16 | 2011-11-11 | Hard surface cleaners comprising low voc, low odor alkanolamines |
Country Status (8)
Country | Link |
---|---|
US (1) | US20130196893A1 (en) |
EP (1) | EP2640816A1 (en) |
JP (1) | JP2014500356A (en) |
CN (1) | CN103221525A (en) |
AU (1) | AU2011329230A1 (en) |
BR (1) | BR112013010673A2 (en) |
CA (1) | CA2816718A1 (en) |
WO (1) | WO2012067962A1 (en) |
Cited By (11)
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JP2015531811A (en) * | 2012-08-31 | 2015-11-05 | ダウ グローバル テクノロジーズ エルエルシー | Glycol dilevulinate as a binder in cleaning formulations |
WO2016064967A1 (en) * | 2014-10-22 | 2016-04-28 | Rohm And Haas Company | Liquid laundry detergent containing amine additives |
WO2016064968A1 (en) * | 2014-10-22 | 2016-04-28 | Rohm And Haas Company | Laundry detergent containing amine additives |
WO2020200803A1 (en) * | 2019-04-03 | 2020-10-08 | Chemetall Gmbh | Improved method for purging paint circuits and waterborne purge cleaner |
WO2020251393A1 (en) * | 2019-06-14 | 2020-12-17 | Demidov Ivan Sergeevich | Radio frequency identification sheet material |
WO2022026349A1 (en) * | 2020-07-31 | 2022-02-03 | Dow Silicones Corporation | A hard surface cleaning concentrate packet |
WO2022076252A1 (en) * | 2020-10-05 | 2022-04-14 | Entegris, Inc. | Microelectronic device cleaning composition |
US20220162526A1 (en) * | 2020-11-25 | 2022-05-26 | Ecolab Usa Inc. | Multipurpose alkaline compositions and methods of use |
EP3325594B1 (en) * | 2015-07-17 | 2023-10-04 | S.C. Johnson & Son, Inc. | Non-corrosive, highly alkaline cleaning composition |
EP4269549A3 (en) * | 2017-04-10 | 2023-12-27 | Kao Corporation | Skin cleansing compositions |
RU2818528C2 (en) * | 2019-04-03 | 2024-05-02 | Хеметалл Гмбх | Improved method of washing paint outlines and water-based cleaning solution for washing |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2864462B1 (en) | 2012-06-22 | 2018-11-28 | The Procter and Gamble Company | Low voc hard surface cleaning composition |
US9790456B2 (en) * | 2012-12-20 | 2017-10-17 | Ecolab Usa Inc. | Citrate salt bathroom cleaners |
US9534190B2 (en) * | 2012-12-20 | 2017-01-03 | Ecolab Usa Inc. | Citrate salt bathroom cleaners |
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US10767137B2 (en) * | 2014-04-23 | 2020-09-08 | Sageway Solutions, Llc | Cleaning formulations for chemically sensitive individuals: compositions and methods |
WO2016175932A1 (en) * | 2015-04-30 | 2016-11-03 | Dow Global Technologies Llc | Aminoalcohol salts of alkylbenzene sulfonic acids and their use in detergent formulations |
JP6645873B2 (en) * | 2016-03-04 | 2020-02-14 | Atシリカ株式会社 | Polishing composition |
CN106367229A (en) * | 2016-08-26 | 2017-02-01 | 广西棕海园林工程有限公司 | Efficient tile surface detergent as well as preparation method and use method thereof |
MX2019006174A (en) | 2016-11-28 | 2019-08-12 | Johnson & Son Inc S C | Hard surface cleaners including fluorosurfactants. |
US10767077B2 (en) | 2017-01-30 | 2020-09-08 | Otis Elevator Company | Load-bearing member surface treatment |
WO2018190266A1 (en) * | 2017-04-10 | 2018-10-18 | 花王株式会社 | Skin cleanser composition |
US20200155434A1 (en) * | 2017-04-10 | 2020-05-21 | Kao Corporation | Skin cleansing composition |
JP6835409B2 (en) * | 2017-05-15 | 2021-02-24 | 花王株式会社 | Manufacturing method of toner for electrophotographic |
US11499118B2 (en) | 2017-10-06 | 2022-11-15 | Castrol Limited | Metal working fluid additive composition |
CN114836266A (en) | 2017-11-07 | 2022-08-02 | 埃科莱布美国股份有限公司 | Cleaning compositions and methods for removing cosmetic stains from the lips |
CA3101928A1 (en) | 2017-12-07 | 2019-06-13 | Ecolab Usa Inc. | Compositions and methods for removing lipstick using branched polyamines |
EP3572492A1 (en) | 2018-05-24 | 2019-11-27 | The Procter & Gamble Company | Fine mist hard surface cleaning spray |
EP3572491A1 (en) | 2018-05-24 | 2019-11-27 | The Procter & Gamble Company | Spray container comprising a detergent composition |
EP3572490A1 (en) * | 2018-05-24 | 2019-11-27 | The Procter & Gamble Company | Spray container comprising a detergent composition |
EP4225882A1 (en) * | 2020-10-05 | 2023-08-16 | Entegris, Inc. | Post cmp cleaning compositions |
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US4259217A (en) | 1978-03-07 | 1981-03-31 | The Procter & Gamble Company | Laundry detergent compositions having enhanced greasy and oily soil removal performance |
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2011
- 2011-11-11 JP JP2013539917A patent/JP2014500356A/en not_active Withdrawn
- 2011-11-11 AU AU2011329230A patent/AU2011329230A1/en not_active Abandoned
- 2011-11-11 CA CA2816718A patent/CA2816718A1/en not_active Abandoned
- 2011-11-11 WO PCT/US2011/060399 patent/WO2012067962A1/en active Application Filing
- 2011-11-11 US US13/878,907 patent/US20130196893A1/en not_active Abandoned
- 2011-11-11 BR BR112013010673A patent/BR112013010673A2/en not_active IP Right Cessation
- 2011-11-11 CN CN2011800550928A patent/CN103221525A/en active Pending
- 2011-11-11 EP EP11791680.9A patent/EP2640816A1/en not_active Withdrawn
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2015531811A (en) * | 2012-08-31 | 2015-11-05 | ダウ グローバル テクノロジーズ エルエルシー | Glycol dilevulinate as a binder in cleaning formulations |
WO2016064967A1 (en) * | 2014-10-22 | 2016-04-28 | Rohm And Haas Company | Liquid laundry detergent containing amine additives |
WO2016064968A1 (en) * | 2014-10-22 | 2016-04-28 | Rohm And Haas Company | Laundry detergent containing amine additives |
AU2015335977B2 (en) * | 2014-10-22 | 2019-05-30 | Rohm And Haas Company | Liquid laundry detergent containing amine additives |
EP3325594B1 (en) * | 2015-07-17 | 2023-10-04 | S.C. Johnson & Son, Inc. | Non-corrosive, highly alkaline cleaning composition |
EP4269549A3 (en) * | 2017-04-10 | 2023-12-27 | Kao Corporation | Skin cleansing compositions |
CN113646395A (en) * | 2019-04-03 | 2021-11-12 | 凯密特尔有限责任公司 | Method for flushing painting lines and aqueous flushing cleaner |
WO2020200803A1 (en) * | 2019-04-03 | 2020-10-08 | Chemetall Gmbh | Improved method for purging paint circuits and waterborne purge cleaner |
RU2818528C2 (en) * | 2019-04-03 | 2024-05-02 | Хеметалл Гмбх | Improved method of washing paint outlines and water-based cleaning solution for washing |
WO2020251393A1 (en) * | 2019-06-14 | 2020-12-17 | Demidov Ivan Sergeevich | Radio frequency identification sheet material |
WO2022026349A1 (en) * | 2020-07-31 | 2022-02-03 | Dow Silicones Corporation | A hard surface cleaning concentrate packet |
WO2022076252A1 (en) * | 2020-10-05 | 2022-04-14 | Entegris, Inc. | Microelectronic device cleaning composition |
US20220162526A1 (en) * | 2020-11-25 | 2022-05-26 | Ecolab Usa Inc. | Multipurpose alkaline compositions and methods of use |
Also Published As
Publication number | Publication date |
---|---|
CN103221525A (en) | 2013-07-24 |
AU2011329230A1 (en) | 2013-05-23 |
JP2014500356A (en) | 2014-01-09 |
CA2816718A1 (en) | 2012-05-24 |
EP2640816A1 (en) | 2013-09-25 |
US20130196893A1 (en) | 2013-08-01 |
BR112013010673A2 (en) | 2019-09-24 |
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