WO2012050655A3 - Selecting an improved catalyst composition and hydrocarbon conversion process using same - Google Patents

Selecting an improved catalyst composition and hydrocarbon conversion process using same Download PDF

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Publication number
WO2012050655A3
WO2012050655A3 PCT/US2011/046587 US2011046587W WO2012050655A3 WO 2012050655 A3 WO2012050655 A3 WO 2012050655A3 US 2011046587 W US2011046587 W US 2011046587W WO 2012050655 A3 WO2012050655 A3 WO 2012050655A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst composition
kcal
mol
selecting
same
Prior art date
Application number
PCT/US2011/046587
Other languages
French (fr)
Other versions
WO2012050655A2 (en
Inventor
Yogesh V. Joshi
Pallassana S. Venkataraman
Terry E. Helton
C. Morris Smith
Jose G. Santiesteban
Matthew J. Vincent
Original Assignee
Exxonmobil Chemical Patents Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chemical Patents Inc. filed Critical Exxonmobil Chemical Patents Inc.
Priority to US13/704,443 priority Critical patent/US9217735B2/en
Priority to EP11832907.7A priority patent/EP2627446A2/en
Priority to CN201180049280.XA priority patent/CN103180042B/en
Priority to SG2013022793A priority patent/SG189126A1/en
Publication of WO2012050655A2 publication Critical patent/WO2012050655A2/en
Publication of WO2012050655A3 publication Critical patent/WO2012050655A3/en

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Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
    • G01N31/10—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using catalysis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

The present invention provides a method for selecting an improved catalyst composition comprising a crystalline molecular sieve material having a structure and properties whereby the catalyst composition has at least one active catalytic site with a Mono Alkylation Selectivity Factor (MASF) greater than or equal to 0 kcal/mol ± 0.5 kcal/mol, and optionally further at least one active catalytic site with an Olefin Oligomerization Suppression Factor (OOSF) greater than or equal to 5 kcal/mol ± 0.5 kcal/mol. Further, there is provided an improved process for conversion of hydrocarbon feedstock in the presence of said selected catalyst composition.
PCT/US2011/046587 2010-10-15 2011-08-04 Selecting an improved catalyst composition and hydrocarbon conversion process using same WO2012050655A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US13/704,443 US9217735B2 (en) 2010-10-15 2011-08-04 Selecting an improved catalyst composition and hydrocarbon conversion process using same
EP11832907.7A EP2627446A2 (en) 2010-10-15 2011-08-04 Selecting an improved catalyst composition and hydrocarbon conversion process using same
CN201180049280.XA CN103180042B (en) 2010-10-15 2011-08-04 Selecting an improved catalyst composition and hydrocarbon conversion process using same
SG2013022793A SG189126A1 (en) 2010-10-15 2011-08-04 Selecting an improved catalyst composition and hydrocarbon conversion process using same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US39365110P 2010-10-15 2010-10-15
US61/393,651 2010-10-15

Publications (2)

Publication Number Publication Date
WO2012050655A2 WO2012050655A2 (en) 2012-04-19
WO2012050655A3 true WO2012050655A3 (en) 2012-05-31

Family

ID=45938847

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/046587 WO2012050655A2 (en) 2010-10-15 2011-08-04 Selecting an improved catalyst composition and hydrocarbon conversion process using same

Country Status (6)

Country Link
US (1) US9217735B2 (en)
EP (1) EP2627446A2 (en)
CN (1) CN103180042B (en)
SG (1) SG189126A1 (en)
TW (1) TWI557099B (en)
WO (1) WO2012050655A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016030447A1 (en) 2014-08-28 2016-03-03 Sabic Global Technologies B.V. Process for producing alkylated aromatic hydrocarbons from a mixed hydrocarbon feedstream
EP3529609A2 (en) * 2016-10-21 2019-08-28 SABIC Global Technologies B.V. Stable catalysts for oxidative coupling of methane

Citations (6)

* Cited by examiner, † Cited by third party
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US5034563A (en) * 1990-04-06 1991-07-23 Mobil Oil Corporation Naphthalene alkylation process
US5191135A (en) * 1991-03-25 1993-03-02 Mobil Oil Corporation Aromatics alkylation process
US7038100B2 (en) * 2001-04-30 2006-05-02 Exxonmobil Chemical Patents, Inc. Aromatics alkylation
US20070179329A1 (en) * 2006-01-31 2007-08-02 Clark Michael C Alkylaromatics production
US20080154080A1 (en) * 2006-12-21 2008-06-26 Mohan Kalyanoraman Catalyst composition, the method of manufacturing and the process of use thereof in aromatics alkylation
US7655824B2 (en) * 2006-10-30 2010-02-02 Uop Llc Processes for producing alkylbenzenes over solid acid catalyst at low benzene to olefin ratios and low heavies make

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US4016218A (en) 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
US4547605A (en) 1983-09-28 1985-10-15 Mobil Oil Corporation Catalyst for alkylation of aromatic hydrocarbons
US4549426A (en) 1983-10-28 1985-10-29 Smith Meter, Inc. Compact flow prover
IT1205681B (en) 1987-05-26 1989-03-31 Eniricerche Spa SYNTHETIC POROUS CRYSTALLINE MATERIAL CONTAINING SILICON AND BORON OXIDES
US4891458A (en) 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
US5003119A (en) 1988-05-09 1991-03-26 Lummus Crest, Inc. Manufacture of alkylbenzenes
US4992606A (en) 1988-10-06 1991-02-12 Mobil Oil Corp. Process for preparing short chain alkyl aromatic compounds
US5334795A (en) 1990-06-28 1994-08-02 Mobil Oil Corp. Production of ethylbenzene
US5362697A (en) 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
US5600050A (en) 1994-12-14 1997-02-04 Chinapetro-Chemical Corp. Zeolite catalyst for the liquid phase alkylation and transalkylation of benzene
US5600048A (en) 1994-12-27 1997-02-04 Mobil Oil Corporation Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation
DE69725319T2 (en) 1996-05-29 2004-07-22 Exxonmobil Chemical Patents Inc., Baytown METHOD FOR CONVERTING AROMATIC HYDROCARBONS, AND ZEOLITIC CATALYST TO BE USED THEREOF
CA2269554C (en) 1996-10-02 2006-11-21 The Dow Chemical Company A zeolite-based ethylbenzene process adaptable to an aluminum chloride-based ethylbenzene plant
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US5034563A (en) * 1990-04-06 1991-07-23 Mobil Oil Corporation Naphthalene alkylation process
US5191135A (en) * 1991-03-25 1993-03-02 Mobil Oil Corporation Aromatics alkylation process
US7038100B2 (en) * 2001-04-30 2006-05-02 Exxonmobil Chemical Patents, Inc. Aromatics alkylation
US20070179329A1 (en) * 2006-01-31 2007-08-02 Clark Michael C Alkylaromatics production
US7655824B2 (en) * 2006-10-30 2010-02-02 Uop Llc Processes for producing alkylbenzenes over solid acid catalyst at low benzene to olefin ratios and low heavies make
US20080154080A1 (en) * 2006-12-21 2008-06-26 Mohan Kalyanoraman Catalyst composition, the method of manufacturing and the process of use thereof in aromatics alkylation

Also Published As

Publication number Publication date
US9217735B2 (en) 2015-12-22
TW201229005A (en) 2012-07-16
CN103180042A (en) 2013-06-26
SG189126A1 (en) 2013-05-31
TWI557099B (en) 2016-11-11
EP2627446A2 (en) 2013-08-21
US20130253246A1 (en) 2013-09-26
WO2012050655A2 (en) 2012-04-19
CN103180042B (en) 2015-07-22

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