WO2012033504A1 - Thermal stress compensation in a curved tube vibrating flow meter - Google Patents
Thermal stress compensation in a curved tube vibrating flow meter Download PDFInfo
- Publication number
- WO2012033504A1 WO2012033504A1 PCT/US2010/052630 US2010052630W WO2012033504A1 WO 2012033504 A1 WO2012033504 A1 WO 2012033504A1 US 2010052630 W US2010052630 W US 2010052630W WO 2012033504 A1 WO2012033504 A1 WO 2012033504A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- case
- flow meter
- tube
- curved tube
- temperature
- Prior art date
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01F—MEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
- G01F1/00—Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow
- G01F1/76—Devices for measuring mass flow of a fluid or a fluent solid material
- G01F1/78—Direct mass flowmeters
- G01F1/80—Direct mass flowmeters operating by measuring pressure, force, momentum, or frequency of a fluid flow to which a rotational movement has been imparted
- G01F1/84—Coriolis or gyroscopic mass flowmeters
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01F—MEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
- G01F1/00—Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow
- G01F1/76—Devices for measuring mass flow of a fluid or a fluent solid material
- G01F1/78—Direct mass flowmeters
- G01F1/80—Direct mass flowmeters operating by measuring pressure, force, momentum, or frequency of a fluid flow to which a rotational movement has been imparted
- G01F1/84—Coriolis or gyroscopic mass flowmeters
- G01F1/845—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits
- G01F1/8468—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits vibrating measuring conduits
- G01F1/8472—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits vibrating measuring conduits having curved measuring conduits, i.e. whereby the measuring conduits' curved center line lies within a plane
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01F—MEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
- G01F1/00—Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow
- G01F1/76—Devices for measuring mass flow of a fluid or a fluent solid material
- G01F1/78—Direct mass flowmeters
- G01F1/80—Direct mass flowmeters operating by measuring pressure, force, momentum, or frequency of a fluid flow to which a rotational movement has been imparted
- G01F1/84—Coriolis or gyroscopic mass flowmeters
- G01F1/845—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits
- G01F1/8468—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits vibrating measuring conduits
- G01F1/8472—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits vibrating measuring conduits having curved measuring conduits, i.e. whereby the measuring conduits' curved center line lies within a plane
- G01F1/8477—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits vibrating measuring conduits having curved measuring conduits, i.e. whereby the measuring conduits' curved center line lies within a plane with multiple measuring conduits
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01F—MEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
- G01F1/00—Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow
- G01F1/76—Devices for measuring mass flow of a fluid or a fluent solid material
- G01F1/78—Direct mass flowmeters
- G01F1/80—Direct mass flowmeters operating by measuring pressure, force, momentum, or frequency of a fluid flow to which a rotational movement has been imparted
- G01F1/84—Coriolis or gyroscopic mass flowmeters
- G01F1/845—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits
- G01F1/8468—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits vibrating measuring conduits
- G01F1/8481—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits vibrating measuring conduits having loop-shaped measuring conduits, e.g. the measuring conduits form a loop with a crossing point
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01F—MEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
- G01F1/00—Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow
- G01F1/76—Devices for measuring mass flow of a fluid or a fluent solid material
- G01F1/78—Direct mass flowmeters
- G01F1/80—Direct mass flowmeters operating by measuring pressure, force, momentum, or frequency of a fluid flow to which a rotational movement has been imparted
- G01F1/84—Coriolis or gyroscopic mass flowmeters
- G01F1/845—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits
- G01F1/8468—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits vibrating measuring conduits
- G01F1/8481—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits vibrating measuring conduits having loop-shaped measuring conduits, e.g. the measuring conduits form a loop with a crossing point
- G01F1/8486—Coriolis or gyroscopic mass flowmeters arrangements of measuring means, e.g., of measuring conduits vibrating measuring conduits having loop-shaped measuring conduits, e.g. the measuring conduits form a loop with a crossing point with multiple measuring conduits
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01F—MEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
- G01F15/00—Details of, or accessories for, apparatus of groups G01F1/00 - G01F13/00 insofar as such details or appliances are not adapted to particular types of such apparatus
- G01F15/02—Compensating or correcting for variations in pressure, density or temperature
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01F—MEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
- G01F15/00—Details of, or accessories for, apparatus of groups G01F1/00 - G01F13/00 insofar as such details or appliances are not adapted to particular types of such apparatus
- G01F15/02—Compensating or correcting for variations in pressure, density or temperature
- G01F15/022—Compensating or correcting for variations in pressure, density or temperature using electrical means
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01F—MEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
- G01F15/00—Details of, or accessories for, apparatus of groups G01F1/00 - G01F13/00 insofar as such details or appliances are not adapted to particular types of such apparatus
- G01F15/02—Compensating or correcting for variations in pressure, density or temperature
- G01F15/022—Compensating or correcting for variations in pressure, density or temperature using electrical means
- G01F15/024—Compensating or correcting for variations in pressure, density or temperature using electrical means involving digital counting
Definitions
- the present invention relates to a curved tube vibrating flow meter, and more particularly, to thermal stress compensation in a curved tube vibrating flow meter.
- Vibrating tube sensors such as Coriolis mass flowmeters and vibrating densitometers, typically operate by detecting motion of a vibrating tube or tubes that contains a flowing material. Properties associated with the material in the tube, such as mass flow, density and the like, can be determined by processing measurement signals received from motion transducers associated with the conduit. The vibration modes of the vibrating material-filled system generally are affected by the combined mass, stiffness and damping characteristics of the containing conduit and the material contained therein.
- a typical Coriolis mass flowmeter includes one or more tubes that are connected inline in a pipeline or other transport system and convey material, e.g., fluids, slurries, emulsions, and the like, in the system.
- Each tube may be viewed as having a set of natural vibration modes, including for example, simple bending, torsional, radial, and coupled modes.
- a tube is excited in one or more vibration modes as a material flows through the tube, and motion of the tube is measured at points spaced along the tube. Excitation is typically provided by an actuator, e.g., an electromechanical device, such as a voice coil-type driver, that perturbs the conduit in a periodic fashion.
- Mass flow rate may be determined by measuring time delay or phase differences between motions at the transducer locations. Frequency of the vibrational response may be measured by a single transducer, wherein the frequency is used to determine the density of material in the meter.
- Two such transducers or pickoff sensors are typically employed in order to measure a vibrational response of the flow conduit or conduits, and are typically located at positions upstream and downstream of the actuator.
- the two pickoff sensors are connected to electronic instrumentation.
- the instrumentation receives signals from the two pickoff sensors and processes the signals in order to derive a mass flow rate measurement, among other things. Vibrating flow meters, including Coriolis mass flowmeters and densitometers, therefore employ one or more flow tubes that are vibrated in order to measure a fluid.
- Vibratory meters may be used with hot or cold flow materials.
- thermal stress is induced in a flow meter when the meter's flow tube or tubes are at a different temperature than other parts of the meter assembly.
- thermal shock when hot fluid is suddenly introduced into a cold meter, the flow tube tries to expand in length but is constrained by the (relatively) cold case. This situation is known as thermal shock.
- the fluid In the more common steady-state situation, the fluid is hot but the ambient environment is cold and a temperature gradient exists across portions of the meter as a result.
- the thermal expansion or contraction may be constrained or prevented by the design of the flowmeter.
- the thermal differences in the meter therefore create thermal stress on the flow tube or tubes of the meter.
- a tube's axial expansion or contraction may be constrained by the meter case.
- U.S. Patent No. 6,327,915 to Van Cleve discloses a straight tube Coriolis flowmeter including a balance bar and temperature sensors S1-S4.
- a single temperature sensor S4 is used to measure the temperature of the case.
- the network of temperature sensors provides temperature information that is used to perform thermal stress compensation, wherein temperature changes will cause compression or tension forces on the vibrating tube, affecting the resonant frequency of the straight flow tube.
- a straight tube vibrating meter due to its shape, does not have a bending stress, as is present in a curved tube meter.
- a straight tube vibrating meter does not require multiple case temperature measurements or case temperature measurements at specific locations which will affect a tube bending stress.
- Coriolis flow meters having dual-curved tubes are of the highest accuracy in terms of flow measurement. They are also of high accuracy in density measurement, but not as accurate as some currently produced densitometers having a single straight tube.
- Single straight tube densitometers achieve their accuracy in part by inclusion of a bellows at either end of the active flow tube, wherein the bellows allows thermal expansion and contraction of the flow meter assembly.
- the bellows therefore isolate the flow tube from the thermal stress that could otherwise change the frequency of the flow tube and thus impair the accuracy of the meter.
- Bellows have several disadvantages. First, they limit the fluid pressure rating of the meter. Second, they impair the ability of the meter to be rated as sanitary, as the bellows will trap and retain flow material after a flow is stopped. Third, the bellows require more expensive and complicated construction and therefore have a higher cost.
- a curved tube vibrating flow meter comprises: a flow tube temperature sensor T T affixed to one or more curved flow tubes of the curved tube vibrating flow meter, with the flow tube temperature sensor T T generating a flow tube temperature signal;
- case temperature sensors T c affixed to one or more case locations of a case of the curved tube vibrating flow meter and generating a case temperature signal, wherein a plurality of case temperature sensor resistances at the one or more case locations form a combined case resistance related to thermal importances of the one or more case locations;
- meter electronics configured to receive the flow tube temperature signal, receive the case temperature signal, and compensate the curved tube vibrating flow meter for thermal stress using the flow tube temperature signal and the case temperature signal.
- the curved tube vibrating flow meter comprises a single curved tube vibrating flow meter.
- the curved tube vibrating flow meter comprises a dual curved tube vibrating flow meter.
- the at least one case temperature sensor T c comprises multiple case temperature sensors T c that generate a representative case temperature signal.
- the one or more case locations comprises two or more case locations, wherein the plurality of case temperature sensors T c form a predetermined case resistance ratio related to thermal importances of each case location of the two or more case locations.
- the meter electronics are further configured to compensate the curved tube vibrating flow meter for a change in curved tube bending stress with a change in temperature, with the compensating using the flow tube temperature sensor signal and case temperature signal.
- the curved tube vibrating flow meter includes a manifold and a first case temperature sensor T c is located on the case substantially at the manifold.
- a second case temperature sensor T c is located substantially on the case between tube ends.
- a curved tube vibrating flow meter comprises: a flow tube temperature sensor T T affixed to one or more curved flow tubes of the curved tube vibrating flow meter, with the flow tube temperature sensor T T generating a flow tube temperature signal;
- case temperature sensors T c affixed to two or more case locations of a case of the curved tube vibrating flow meter and generating a case temperature signal, wherein a plurality of case temperature sensor resistances at the two or more case locations form a predetermined case resistance related to thermal importances of the two or more case locations,
- meter electronics configured to receive the flow tube temperature signal, receive the case temperature signal, and compensate the curved tube vibrating flow meter for thermal stress using the flow tube temperature signal and the case temperature signal.
- the curved tube vibrating flow meter comprises a single curved tube vibrating flow meter.
- the curved tube vibrating flow meter comprises a dual curved tube vibrating flow meter.
- the multiple case temperature sensors T c generate a representative case temperature signal.
- the meter electronics are further configured to compensate the curved tube vibrating flow meter for a change in curved tube bending stress with a change in temperature, with the compensating using the flow tube temperature signal and the case temperature signal.
- the curved tube vibrating flow meter includes a manifold and a first case temperature sensor T c is located on the case substantially at the manifold.
- a second case temperature sensor T c is located substantially on the case between tube ends.
- a thermal stress compensation method in a curved tube vibrating flow meter comprises:
- the curved tube vibrating flow meter comprises a single curved tube vibrating flow meter.
- the curved tube vibrating flow meter comprises a dual curved tube vibrating flow meter.
- the plurality of case temperature sensors generate a representative case temperature signal.
- the one or more case locations comprise two or more case locations, wherein the two or more case temperature sensors form a predetermined case resistance ratio related to thermal importances of each case location of the two or more case locations.
- FIG. 1 shows a Coriolis flow meter comprising a meter assembly and meter electronics.
- FIG. 2 is a graph of thermal stress-induced error in the tube period squared ( ⁇ 2 ) versus the difference in temperature between the tube temperature and the combined case temperature.
- FIG. 3 is a cut-away view that shows the curved tube vibrating flowmeter according to the invention.
- FIG. 4 shows a case temperature sensor network of the curved tube vibrating flow meter according to another embodiment of the invention.
- FIG. 5 illustrates an example of a single curved tube vibrating flow meter comprising a sensor assembly and a balance structure.
- FIGS. 1-5 and the following description depict specific examples to teach those skilled in the art how to make and use the best mode of the invention. For the purpose of teaching inventive principles, some conventional aspects have been simplified or omitted. Those skilled in the art will appreciate variations from these examples that fall within the scope of the invention. Those skilled in the art will appreciate that the features described below can be combined in various ways to form multiple variations of the invention. As a result, the invention is not limited to the specific examples described below, but only by the claims and their equivalents.
- FIG. 1 shows a Coriolis flow meter 5 comprising a meter assembly 10 and meter electronics 20.
- Meter assembly 10 responds to mass flow rate and density of a process material.
- Meter electronics 20 is connected to meter assembly 10 via leads 100 to provide density, mass flow rate, and temperature information over path 26, as well as other information not relevant to the present invention.
- a Coriolis flow meter structure is described although it is apparent to those skilled in the art that the present invention could be practiced as a vibrating tube densitometer without the additional measurement capability provided by a Coriolis mass flow meter.
- Meter assembly 10 includes a pair of manifolds 150 and 150', flanges 103 and
- Flow tubes 130 and 130' have two essentially straight inlet legs 131 and 13 and outlet legs 134 and 134' which converge towards each other at flow tube mounting blocks 120 and 120'.
- Flow tubes 130 and 130' bend at two symmetrical locations along their length and are essentially parallel throughout their length.
- Brace bars 140 and 140' serve to define the axis W and W about which each flow tube oscillates.
- the side legs 131, 131' and 134, 134' of flow tubes 130 and 130' are fixedly attached to manifolds 150 and 150'. This provides a continuous closed material path through Coriolis meter assembly 10.
- Flow tubes 130 and 130' are selected and appropriately mounted to the flow tube mounting blocks 120 and 120' so as to have substantially the same mass distribution, moments of inertia and Young's modulus about bending axes W--W and W--W, respectively. These bending axes go through brace bars 140 and 140'.
- resistive temperature detector (RTD) 190 is mounted to flow tube 130', to continuously measure the temperature of the flow tube.
- the temperature of the flow tube and hence the voltage appearing across the RTD for a given current passing therethrough is governed by the temperature of the material passing through the flow tube.
- the temperature dependent voltage appearing across the RTD is used in a well known method by meter electronics 20 to compensate for the change in elastic modulus of flow tubes 130 and 130' due to any changes in flow tube temperature.
- the RTD is connected to meter electronics 20 by lead 195.
- Both flow tubes 130 and 130' are driven by driver 180 in opposite directions about their respective bending axes W and W and at what is termed the first out-of- phase bending mode of the flow meter.
- This drive mechanism 180 may comprise any one of many well known arrangements, such as a magnet mounted to flow tube 130' and an opposing coil mounted to flow tube 130 and through which an alternating current is passed for vibrating both flow tubes.
- a suitable drive signal is applied by meter electronics 20, via lead 185, to drive mechanism 180.
- Meter electronics 20 receives the RTD temperature signal on lead 195, and the left and right velocity signals appearing on leads 165L and 165R, respectively.
- Meter electronics 20 produces the drive signal appearing on lead 185 to drive element 180 and vibrate tubes 130 and 130'.
- Meter electronics 20 processes the left and right velocity signals and the RTD signal to compute the mass flow rate and the density of the material passing through meter assembly 10. This information, along with other information, is applied by meter electronics 20 over communication path 26.
- the communication path 26 provides an input and an output means that allows the meter electronics 20 to interface with an operator or with other electronic systems.
- FIG. 1 is provided merely as an example of the operation of a Coriolis flowmeter and is not intended to limit the teaching of the present invention.
- the flowtubes 103 A and 103B comprise substantially delta- shaped flowtubes, as shown.
- the flowtubes can comprise substantially U-shaped curved flowtubes.
- Other curved flowmeter shapes and/or configurations can be used and are within the scope of the description and claims.
- Curved tube flow meters do not suffer from the effects of thermal stress in the way straight tube flow meters do. Curved flow tubes, due to their shape, may expand and contract independently of their ends. While straight tubes experience high axial stresses that have a large effect on their frequency, curved tubes experience bending stress that has only a small effect on their frequency. Thus, current curved tube flowmeters use only the tube temperature to compensate for the Young's modulus shift of the flow tube, and do not compensate for thermal stress.
- FIG. 2 is a graph of thermal stress-induced error in the tube period squared ( ⁇ 2 ) versus the difference in temperature between the tube temperature and the combined case temperature.
- FIG. 2 shows that when temperature measurements are taken at the appropriate locations, there is a linear relationship between the temperature difference (between the tube temperature and the combined case temperature) and the tube period/density measurement.
- FIG. 3 is a cut-away view that shows the curved tube vibrating flowmeter 5 according to the invention.
- the curved tube vibrating flow meter 5 includes one or more curved flow tubes 131 , 13 , flanges 101 and 10 , and a case 300.
- the case 300 can enclose all or part of the one or more curved flow tubes 131 , 131 '.
- the case 300 can be removably or permanently affixed to the flanges 101 and 101 '.
- a flow tube temperature sensor T T 190 is affixed to (or in thermal
- the flow tube temperature sensor T T 190 generates a corresponding flow tube temperature signal.
- Multiple flow tube temperature sensors may be employed in some embodiments. However, it should be understood that the tubes almost instantly acquire the temperature of the fluid, and thus multiple sensors on the flow tubes are unnecessary. The number of, and position of, the flow tube temperature sensors may be selected according to anticipated conditions and anticipated flow materials.
- the temperature of the one or more flow tubes 131, 13 ⁇ will closely track the temperature of the flow material. As a result, a single flow tube temperature sensor T x 190 may be sufficient for characterizing the temperature of the flow tube or tubes 131, 131 '. However, due to the distance between the case 300 and the one or more curved flow tubes 131, 13 , and the enclosing function of the case 300, the thermal response of the case 300 will differ from the thermal response of the one or more curved flow tubes 131, 131 '.
- a plurality of case temperature sensors T c 303 are affixed to (or in thermal communication with) the case 300 and are coupled to the meter electronics 20, such as the case temperature sensor T c 303A and the case temperature sensor T c 303B, shown.
- the plurality of case temperature sensors T c 303 generate a case temperature signal to the meter electronics 20.
- temperature sensors T c 303 may be selected according to anticipated conditions and anticipated flow materials. The number of, and position of, the individual case temperature sensors T c 303 may be selected according to the importance of the position to the thermal stress in the tube. For instance, the temperature of the flanges has no impact on the thermal stress of the flow tube or tubes, and therefore no temperature sensor may need to be put on the flanges.
- the manifold might have twice the impact as the case temperatures on thermal stress in the tubes, however, and therefore two temperature sensors could be affixed to the manifold and only a single case temperature sensor may need to be put on the case away from the manifold. These three sensors could be connected in series in order to generate a combined case temperature signal.
- the combined case temperature can include case temperature sensors on the case, manifolds, balance bars, or other non- flow-tube components of the flow meter 5.
- the representative case temperature can be formed using electrical circuit techniques such as series or parallel connections, so that a single combined temperature
- the at least one case temperature sensor T c 303 can comprise multiple case temperature sensors T c 303 that generate a representative case
- the plurality of case temperature sensors T c 303 can be affixed to one or more case locations, wherein a plurality of case temperature sensor resistances at the one or more case locations form a combined case resistance related to thermal importances of the one or more case locations.
- the one or more case locations comprise two or more case locations, wherein the plurality of case temperature sensors T c 303 form a predetermined case resistance ratio related to thermal
- the case 300 In operation, heat will be transferred into the case 300 mainly via the manifolds at the ends of the flow tubes. Temperature changes at the center of the case 300 will lag the temperature changes at the ends of the flow meter 5.
- the case of 300 will be formed of a material having a good heat transfer characteristic so that heat will spread relatively rapidly through the case 300.
- the temperature of the case 300 will have a different effect on flow meter measurements than the temperature of the one or more curved flow tubes 131, 13 ⁇ .
- Changing the temperature of the one or more flow tubes 131, 13 ⁇ (without changing the temperature of the case 300) will change the tube vibration frequency.
- the change in vibration frequency results from both a change in elastic modulus and from a change in thermal stress.
- the single flow tube temperature sensor is primarily used to compensate for modulus change due to temperature. Due to the curved shape of the one or more flow tubes 131, 131, the one or more flow tubes 131, 13 ⁇ can flex and absorb most of the relative case expansion or contraction with little tube stress or change in frequency. This is why curved tubes have not required thermal stress compensation in the past.
- a temperature change in the case 300 alone will change the vibration frequency by changing the thermal stress on the one or more flow tubes 131, 131 '.
- the frequency change may be relatively slight, but even a small change will negatively affect a density measurement. Compensation of the thermal stress in a curved tube flow meter will provide a more accurate density measurement.
- the temperature measurements can also be used to compensate the curved tube vibrating flow meter 5 for a change in curved tube bending stress with a change in temperature.
- the compensating operation can use the flow tube temperature signal and the case temperature signal. It should be understood that the temperature effects will have a different effect on a curved tube flow meter.
- the case 300 in the figure includes a first case temperature sensor T c 303A located substantially at an incoming meter flange 101, 10 ⁇ , and a second case temperature sensor T c 303B can be located substantially centered on the case 300, at a location between the ends of the flow meter 5.
- Multiple case temperature sensors can be included between the meter ends if desired.
- the curved tube vibrating flow meter 5 includes the manifolds 150 and 150'.
- the first case temperature sensor T c 303A is located substantially at one of the manifolds 150 and 150', near the flow tubes 131, 13 ⁇ in this embodiment.
- the first case temperature sensor T c 303 therefore is positioned to respond quickly to thermal shock, such as due to a significant change in temperature in the incoming flow material, for example.
- a second case temperature sensor T c 303B is located on the case 300 generally midway between the ends. As a result, the second case temperature sensor T c 303B is positioned to determine a substantially steady-state temperature condition in the case 300.
- the locations of the case temperature sensors T c 303 may be unique to a particular flow meter model.
- the optimal locations of the case temperature sensors T c 303 may be found through computer simulation and/or empirically-gathered data. If the temperature network of the case is properly designed, where the case may include manifolds, flanges, the case proper, a balance bar, and any other non-tube parts of the meter, then the single case temperature that is represented by the combination of the RTDs in the case temperature network, along with the tube temperature, will have a substantially known mathematical relationship with resonant frequency of the meter. Consequently, the resistance of an optimally designed resistive temperature sensor network will have a known mathematical relationship to the thermal effect. The difference between the tube temperature and the case temperature measured by the case temperature sensors T c 303 may be used to compensate the meter, using the known mathematical relationship discussed herein.
- RTDs Resistive Temperature Devices
- the case bottom temperature is twice as important as the case top temperature when using temperature measurements for flow meter temperature compensation
- twice as many temperature sensor elements can be affixed to the case bottom.
- temperature changes in the case bottom will have twice the effect on sensor electrical resistance as temperature changes in the case top.
- the resistance change of the three temperature sensors in series is then divided by three to give the weighted average temperature of the case 300.
- Multiple temperature sensors can also be put in parallel, or in other electrical network configurations, in order to match the thermal importance of regions of the meter 5.
- the compensation equation can comprise:
- the first compensation term ( ⁇ 1* ⁇ ⁇ ) is for modulus compensation of the flow tube or tubes.
- the second compensation term (K2*(T tu b e -T case )) is for thermal stress compensation.
- thermal stress generally only occurs with a difference in temperature between the case average temperature and the tube temperature.
- FIG. 4 shows a case temperature sensor network of the curved tube vibrating flow meter 5 according to another embodiment of the invention.
- the curved tube vibrating flow meter 5 includes the flow tube temperature sensor T T 190, a first case temperature sensor T c 303 A, and a second case temperature sensor T c 303B.
- the second case temperature sensor T c 303B does not comprise a standard RTD resistance value in this embodiment and instead the figure illustrates a custom temperature sensor that forms a desired thermal importance ratio for the case 300.
- a temperature importance ratio can be achieved by employing temperature sensors having predetermined resistance values.
- the first case temperature sensor T c 303A is chosen to have a resistance that is equivalent to a standard RTD and the second case temperature sensor T c 303B is chosen to have a resistance that is equivalent to four standard RTDs.
- Other resistance values can be selected and other resistance ratios can be constructed. Connecting these two case temperature sensors in series results in a network in which the total case resistance is five times that of a standard RTD resistance value.
- the case temperature sensor forms a resistance (and thermal importance) ratio, wherein the first case temperature sensor T c 303 A is only one-fifth of the total resistance of the case temperature sensor network. As a result, changes in temperature at the first case temperature sensor T c 303A will have much less impact on the overall case temperature measurement.
- the first case temperature sensor 303A may be located at or near the top of the case 300 and the second case temperature sensor 303B may be located at or near the bottom. Therefore, for a given case temperature change, the case bottom resistance change for a given temperature change will be about four times that of the case top resistance change. This would represent a condition where the temperature of the case bottom has four times the effect on the combined temperature as the temperature of the case top.
- This configuration illustrates one of the differences in the thermal compensation between straight tube meters and curved tube meters.
- the case In straight tube meters, the case is generally cylindrical and thus one side (or region) of such a cylindrical case has no more thermal importance than another.
- the lack of complete symmetry about the tube axis can necessitate multiple temperature sensors because, for example, the top of the case may have a different temperature than the bottom of the case. Furthermore, the lack of symmetry may cause one part of the case to impart more thermal stress on the flow tube than another part of the case.
- FIG. 5 illustrates an example of a single curved tube vibrating flow meter 5 comprising a sensor assembly 206 and a balance structure 208.
- the meter electronics 20 are connected to the sensor assembly 206 via leads 165L, 165R, 185, and 195.
- the sensor assembly 206 includes a single curved flow tube 131 that defines a flow path for receiving a flowing substance. When sensor assembly 206 is inserted into a pipeline system or assembly which carries the flowing substance, the substance enters sensor assembly 206 through an inlet flange and flows through the curved flow tube 131, where a characteristic of the flowing substance is measured.
- the sensor assembly 206 includes a driver 180.
- the driver 180 includes a first portion connected to a driven member 250 of the balance structure 208 and a second portion connected to the curved flow tube 131.
- the first and second portions may correspond to a drive coil and a drive magnet, for example.
- the driver 180 preferably drives the driven member 250 and curved flow tube 131 in phase opposition about a bending axis X, which is defined in part by the connectors 270, 271.
- the bending axis X corresponds to the inlet-outlet tube axis.
- the driven member 250 bends from the base 260 and thus does not have a stationary bending axis.
- the driver 180 may comprise one of many well known arrangements, including for example, and not limitation piezoelectric elements or an electromagnetic coil/magnet arrangement.
- the sensor assembly 206 includes at least one pick-off and in the present embodiment is shown provided with a pair of pick-offs 170L, 170R.
- the pick-offs 170L, 170R measure the motion of the curved flow tube 131.
- the pick-offs 170L, 170R include a first portion located on respective pick-off arms 280, 281 and a second portion located on the curved flow tube 131.
- the pick-off(s) may comprise one of many well known arrangements, including for example, and not limitation piezoelectric elements, capacitance elements, or an electromagnetic coil/magnet arrangement.
- the first portion of the pick-off may comprise a pick-off coil while the second portion of the pick-off may comprise a pick-off magnet.
- the motion of the curved flow tube 131 is related to certain characteristics of the flowing substance, for example, the mass flow rate or density of the flowing substance through the curved flow tube 131.
- the one or more meter electronics 20 receive the pick-off signals from the pick-offs 170L, 170R and provide a drive signal to the driver 180.
- the one or more electronics 20 can measure a characteristic of a flowing substance, such as, for example, density, mass flow rate, volume flow rate, totalized mass flow, temperature, and other information.
- the one or more electronics 20 may also receive one or more other signals from, for example, one or more temperature sensors 190 and one or more pressure sensors (not shown), and use this information to measure a characteristic of a flowing substance.
- the number and type of sensors will depend on the particular measured characteristic.
- the balance structure 208 is configured to at least partially balance the vibrations of the curved flow tube 131.
- the balance structure 208 is configured to at least partially balance the momentum of the curved flow tube 131.
- the balance structure 208 includes a base 260 connected to a driven member 250.
- the driven member 250 is preferably a cantilevered arm that extends generally orthogonal from the base 260.
- the base 260 in the present embodiment is preferably relatively massive and immobile as compared to the driven member 250.
- the base 260 may be provided with a mass at least 5 times greater than that of the driven member 250.
- the base 260 may be provided with a mass at least 5 times greater than the mass of the curved flow tube 131. In some embodiments, these numbers may be greater, for example 14 and 8 times greater than the driven member 250 and the curved flow tube 131, respectively.
- the balance structure 208 in the present embodiment is coupled to the curved flow tube 131.
- the base 260 includes a pair of connectors 270, 271, which may be in the form of the plates shown or which may be provided with any other shape.
- the curved flow tube 131, the driven member 250, and the base 260 are configured to provide a balanced system. It should be appreciated that the system may not be absolutely balanced.
- the curved flow tube 131 and the driven member 250 act as two separate vibrating systems, which are driven at equal resonant frequencies, in phase opposition about the axis X.
- the sensor assembly 206 may also include a case 300 and case connects 290, 291.
- the case connects 290, 291 may comprise the only structures supporting the conduit between the connectors 270, 271.
- the flow meter 5 in this embodiment may include case temperature sensors T c 303 such as a first case temperature sensor T C1 located about twenty- five percent in from the end (or case connect), a second case temperature sensor T C2 located at the base of the driven member 250, and a third case temperature sensor T C3 located about halfway up the driven member 250.
- a second temperature sensor T C2 ' of twice the normal resistance could be substituted for the second case temperature sensor T C2 and the third case temperature sensor T C3 .
- the second temperature sensor T C2 ' could be located about twenty- five percent up the driven member 250, for example. It should be understood that the case temperature sensors and locations given above are merely examples and are not limiting. The sensor values and sensor locations can be varied as needed and remain within the scope of the description and claims.
- resistive temperature sensors any type of resistive sensor could be used in place of a temperature sensor.
- a strain gauge which indicates strain in the form of a variable resistance in place of one or more of the temperature sensors described herein.
- the present invention can be applied using any sensor that indicates a condition by changing its resistance. The essence of the present invention applies equally to any such a configuration.
- the curved tube vibrating flow meter according to the invention can be employed according to any of the embodiments in order to provide several advantages, if desired.
- the meter according to the invention provides a thermal stress compensated curved tube meter.
Landscapes
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- General Physics & Mathematics (AREA)
- Measuring Volume Flow (AREA)
Abstract
Description
Claims
Priority Applications (12)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013528178A JP5564621B2 (en) | 2010-09-09 | 2010-10-14 | Compensation of thermal stress in curved pipe vibration flowmeter |
CN201080069040.1A CN103109164B (en) | 2010-09-09 | 2010-10-14 | Thermal stress compensation in a curved tube vibrating flow meter |
US13/816,795 US9170142B2 (en) | 2010-09-09 | 2010-10-14 | Thermal stress compensation in a curved tube vibrating flow meter |
RU2013115749/28A RU2581436C2 (en) | 2010-09-09 | 2010-10-14 | Thermal stresses compensation in a curved tube vibrating flowmeter |
MX2013002141A MX2013002141A (en) | 2010-09-09 | 2010-10-14 | Thermal stress compensation in a curved tube vibrating flow meter. |
CA2808585A CA2808585C (en) | 2010-09-09 | 2010-10-14 | Thermal stress compensation in a curved tube vibrating flow meter |
SG2013017561A SG188480A1 (en) | 2010-09-09 | 2010-10-14 | Thermal stress compensation in a curved tube vibrating flow meter |
AU2010360278A AU2010360278B2 (en) | 2010-09-09 | 2010-10-14 | Thermal stress compensation in a curved tube vibrating flow meter |
EP10785242.8A EP2614339B1 (en) | 2010-09-09 | 2010-10-14 | Thermal stress compensation in a curved tube vibrating flow meter |
BR112013005600-2A BR112013005600B1 (en) | 2010-09-09 | 2010-10-14 | CURVED TUBE VIBRATORY FLOW METER AND THERMAL VOLTAGE COMPENSATION METHOD |
KR1020137008944A KR101649576B1 (en) | 2010-09-09 | 2010-10-14 | Thermal stress compensation in a curved tube vibrating flow meter |
ARP110103193A AR082863A1 (en) | 2010-09-09 | 2011-09-01 | THERMAL VOLTAGE COMPENSATION IN A CURVED TUBE VIBRATORY FLOW |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US38126010P | 2010-09-09 | 2010-09-09 | |
US61/381,260 | 2010-09-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2012033504A1 true WO2012033504A1 (en) | 2012-03-15 |
Family
ID=43585676
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2010/052630 WO2012033504A1 (en) | 2010-09-09 | 2010-10-14 | Thermal stress compensation in a curved tube vibrating flow meter |
Country Status (13)
Country | Link |
---|---|
US (1) | US9170142B2 (en) |
EP (1) | EP2614339B1 (en) |
JP (1) | JP5564621B2 (en) |
KR (1) | KR101649576B1 (en) |
CN (1) | CN103109164B (en) |
AR (1) | AR082863A1 (en) |
AU (1) | AU2010360278B2 (en) |
BR (1) | BR112013005600B1 (en) |
CA (1) | CA2808585C (en) |
MX (1) | MX2013002141A (en) |
RU (1) | RU2581436C2 (en) |
SG (1) | SG188480A1 (en) |
WO (1) | WO2012033504A1 (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102014103430A1 (en) | 2014-03-13 | 2015-09-17 | Endress + Hauser Flowtec Ag | Converter device and thus formed measuring system |
DE102014103427A1 (en) | 2014-03-13 | 2015-09-17 | Endress + Hauser Flowtec Ag | Converter device and thus formed measuring system |
CN107014453A (en) * | 2016-01-20 | 2017-08-04 | 克洛纳测量技术有限公司 | Method and the Coriolis mass and flow measuring instrument to this for running Coriolis mass and flow measuring instrument |
DE102016112600A1 (en) | 2016-07-08 | 2018-01-11 | Endress + Hauser Flowtec Ag | measuring system |
DE102016112599A1 (en) | 2016-07-08 | 2018-01-11 | Endress + Hauser Flowtec Ag | measuring system |
DE102017106209A1 (en) | 2016-12-29 | 2018-07-05 | Endress+Hauser Flowtec Ag | Vibronic measuring system for measuring a mass flow rate |
WO2018121930A1 (en) | 2016-12-29 | 2018-07-05 | Endress+Hauser Flowtec Ag | Vibronic measuring system for measuring a mass flow rate |
WO2018121929A1 (en) | 2016-12-29 | 2018-07-05 | Endress+Hauser Flowtec Ag | Vibronic measuring system for measuring a mass flow rate |
WO2019029942A1 (en) | 2017-08-09 | 2019-02-14 | Endress+Hauser Flowtec Ag | Sensor assembly |
DE102018102379A1 (en) * | 2018-02-02 | 2019-08-08 | Endress + Hauser Flowtec Ag | Coriolis sensor and Coriolis meter |
DE102020120054A1 (en) | 2020-07-29 | 2022-02-03 | Endress + Hauser Flowtec Ag | Method for determining a fluid temperature and measuring system for it |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2826870C (en) * | 2011-02-23 | 2017-02-07 | Micro Motion, Inc. | Vibrating flow meter and method for measuring temperature |
CN110727294A (en) * | 2018-07-17 | 2020-01-24 | 北京七星华创流量计有限公司 | Fluid sensor and mass flow controller |
DE102018132672A1 (en) * | 2018-12-18 | 2020-06-18 | Endress+Hauser Flowtec Ag | Vibronic sensor with at least two temperature sensors |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5796011A (en) * | 1993-07-20 | 1998-08-18 | Endress + Hauser Flowtech Ag | Coriolis-type mass flow sensor |
WO2001071290A1 (en) * | 2000-03-22 | 2001-09-27 | Micro Motion, Inc. | A method and apparatus for operating coriolis flowmeters at cryogenic temperatures |
US6327915B1 (en) | 1999-06-30 | 2001-12-11 | Micro Motion, Inc. | Straight tube Coriolis flowmeter |
WO2008039203A1 (en) | 2006-09-28 | 2008-04-03 | Micro Motion, Inc. | Meter electronics and methods for geometric thermal compensation in a flow meter |
WO2009051588A1 (en) * | 2007-10-15 | 2009-04-23 | Micro Motion, Inc. | Vibratory flow meter and method for determining a fluid temperature of a flow material |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5295084A (en) | 1991-10-08 | 1994-03-15 | Micromotion, Inc. | Vibrating tube densimeter |
JPH09113433A (en) * | 1995-10-20 | 1997-05-02 | Tokico Ltd | Densitometer |
JP3656947B2 (en) | 1999-10-05 | 2005-06-08 | 株式会社オーバル | Coriolis mass flow meter |
RU2344376C1 (en) * | 2004-09-17 | 2009-01-20 | Эмерсон Электрик Ко. | Method and device for compensating coriolis flow meter |
EP1963793B1 (en) * | 2005-12-22 | 2018-07-18 | Endress + Hauser Flowtec AG | Vibratory measuring transducer |
US7549319B2 (en) * | 2006-11-16 | 2009-06-23 | Halliburton Energy Services, Inc. | High pressure resonant vibrating-tube densitometer |
CA2826870C (en) * | 2011-02-23 | 2017-02-07 | Micro Motion, Inc. | Vibrating flow meter and method for measuring temperature |
-
2010
- 2010-10-14 EP EP10785242.8A patent/EP2614339B1/en active Active
- 2010-10-14 WO PCT/US2010/052630 patent/WO2012033504A1/en active Application Filing
- 2010-10-14 CN CN201080069040.1A patent/CN103109164B/en active Active
- 2010-10-14 JP JP2013528178A patent/JP5564621B2/en active Active
- 2010-10-14 SG SG2013017561A patent/SG188480A1/en unknown
- 2010-10-14 BR BR112013005600-2A patent/BR112013005600B1/en active IP Right Grant
- 2010-10-14 MX MX2013002141A patent/MX2013002141A/en active IP Right Grant
- 2010-10-14 US US13/816,795 patent/US9170142B2/en active Active
- 2010-10-14 CA CA2808585A patent/CA2808585C/en active Active
- 2010-10-14 AU AU2010360278A patent/AU2010360278B2/en active Active
- 2010-10-14 RU RU2013115749/28A patent/RU2581436C2/en active
- 2010-10-14 KR KR1020137008944A patent/KR101649576B1/en active IP Right Grant
-
2011
- 2011-09-01 AR ARP110103193A patent/AR082863A1/en active IP Right Grant
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5796011A (en) * | 1993-07-20 | 1998-08-18 | Endress + Hauser Flowtech Ag | Coriolis-type mass flow sensor |
US6327915B1 (en) | 1999-06-30 | 2001-12-11 | Micro Motion, Inc. | Straight tube Coriolis flowmeter |
WO2001071290A1 (en) * | 2000-03-22 | 2001-09-27 | Micro Motion, Inc. | A method and apparatus for operating coriolis flowmeters at cryogenic temperatures |
WO2008039203A1 (en) | 2006-09-28 | 2008-04-03 | Micro Motion, Inc. | Meter electronics and methods for geometric thermal compensation in a flow meter |
WO2009051588A1 (en) * | 2007-10-15 | 2009-04-23 | Micro Motion, Inc. | Vibratory flow meter and method for determining a fluid temperature of a flow material |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102014103430A1 (en) | 2014-03-13 | 2015-09-17 | Endress + Hauser Flowtec Ag | Converter device and thus formed measuring system |
DE102014103427A1 (en) | 2014-03-13 | 2015-09-17 | Endress + Hauser Flowtec Ag | Converter device and thus formed measuring system |
CN107014453A (en) * | 2016-01-20 | 2017-08-04 | 克洛纳测量技术有限公司 | Method and the Coriolis mass and flow measuring instrument to this for running Coriolis mass and flow measuring instrument |
CN107014453B (en) * | 2016-01-20 | 2019-12-20 | 克洛纳测量技术有限公司 | Method for operating a coriolis mass flow measuring device and coriolis mass flow measuring device for this purpose |
DE102016112599A1 (en) | 2016-07-08 | 2018-01-11 | Endress + Hauser Flowtec Ag | measuring system |
CN109477746A (en) * | 2016-07-08 | 2019-03-15 | 恩德斯+豪斯流量技术股份有限公司 | Measuring system |
WO2018007176A1 (en) | 2016-07-08 | 2018-01-11 | Endress+Hauser Flowtec Ag | Vibration-type fluid flow-rate measuring system having temperature compensation |
US11573111B2 (en) | 2016-07-08 | 2023-02-07 | Endress + Hauser Flowtec Ag | Flow measuring system having transducer temperatures that deviate from measuring point temperatures |
DE102016112600A1 (en) | 2016-07-08 | 2018-01-11 | Endress + Hauser Flowtec Ag | measuring system |
WO2018007185A1 (en) | 2016-07-08 | 2018-01-11 | Endress+Hauser Flowtec Ag | Measuring system |
DE102017106211A1 (en) | 2016-12-29 | 2018-07-05 | Endress+Hauser Flowtec Ag | Vibronic measuring system for measuring a mass flow rate |
WO2018121929A1 (en) | 2016-12-29 | 2018-07-05 | Endress+Hauser Flowtec Ag | Vibronic measuring system for measuring a mass flow rate |
WO2018121930A1 (en) | 2016-12-29 | 2018-07-05 | Endress+Hauser Flowtec Ag | Vibronic measuring system for measuring a mass flow rate |
DE102017106209A1 (en) | 2016-12-29 | 2018-07-05 | Endress+Hauser Flowtec Ag | Vibronic measuring system for measuring a mass flow rate |
WO2019029942A1 (en) | 2017-08-09 | 2019-02-14 | Endress+Hauser Flowtec Ag | Sensor assembly |
DE102017118109A1 (en) | 2017-08-09 | 2019-02-14 | Endress + Hauser Flowtec Ag | sensor assembly |
US11428578B2 (en) | 2017-08-09 | 2022-08-30 | Endress+Hauser Flowtec Ag | Sensor assembly |
DE102018102379A1 (en) * | 2018-02-02 | 2019-08-08 | Endress + Hauser Flowtec Ag | Coriolis sensor and Coriolis meter |
DE102018102379B4 (en) | 2018-02-02 | 2023-02-02 | Endress + Hauser Flowtec Ag | Coriolis measuring sensor of a Coriolis measuring device with a temperature measuring device integrated in the vibration exciter or vibration sensor and such a Coriolis measuring device |
DE102020120054A1 (en) | 2020-07-29 | 2022-02-03 | Endress + Hauser Flowtec Ag | Method for determining a fluid temperature and measuring system for it |
WO2022022890A1 (en) | 2020-07-29 | 2022-02-03 | Endress+Hauser Flowtec Ag | Method for ascertaining the temperature of a substance to be measured, and measuring system for this purpose |
Also Published As
Publication number | Publication date |
---|---|
KR20130140661A (en) | 2013-12-24 |
CA2808585C (en) | 2017-01-24 |
RU2013115749A (en) | 2014-10-20 |
AU2010360278B2 (en) | 2014-06-05 |
BR112013005600B1 (en) | 2020-03-31 |
CN103109164B (en) | 2017-04-19 |
JP5564621B2 (en) | 2014-07-30 |
US9170142B2 (en) | 2015-10-27 |
EP2614339A1 (en) | 2013-07-17 |
RU2581436C2 (en) | 2016-04-20 |
AR082863A1 (en) | 2013-01-16 |
KR101649576B1 (en) | 2016-08-22 |
EP2614339B1 (en) | 2019-03-27 |
CN103109164A (en) | 2013-05-15 |
CA2808585A1 (en) | 2012-03-15 |
AU2010360278A1 (en) | 2013-03-21 |
SG188480A1 (en) | 2013-04-30 |
JP2013537305A (en) | 2013-09-30 |
MX2013002141A (en) | 2013-04-03 |
BR112013005600A2 (en) | 2016-05-03 |
US20130139613A1 (en) | 2013-06-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AU2010360278B2 (en) | Thermal stress compensation in a curved tube vibrating flow meter | |
US11029183B2 (en) | Vibratory flowmeter and method for meter verification | |
AU2011360248B2 (en) | Vibrating flow meter and method for measuring temperature | |
JP5060557B2 (en) | Flow meter with 3 pick-off sensors | |
EP2069728B1 (en) | Meter electronics and methods for geometric thermal compensation in a flow meter | |
CA2623191C (en) | Meter electronics and methods for determining one or more of a stiffness coefficient or a mass coefficient | |
US9395224B2 (en) | Coriolis flowmeter and method with improved meter zero | |
CN106233099B (en) | Flowmeter manifold with indexing boss | |
JP7313516B2 (en) | How to compensate for mass flow using known density |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 201080069040.1 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 10785242 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 13816795 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: 2808585 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: MX/A/2013/002141 Country of ref document: MX |
|
ENP | Entry into the national phase |
Ref document number: 2013528178 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2010785242 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 2010360278 Country of ref document: AU Date of ref document: 20101014 Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 20137008944 Country of ref document: KR Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 2013115749 Country of ref document: RU Kind code of ref document: A |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112013005600 Country of ref document: BR |
|
ENP | Entry into the national phase |
Ref document number: 112013005600 Country of ref document: BR Kind code of ref document: A2 Effective date: 20130308 |