WO2012010096A1 - Device for synchronously removing nitrogen and phosphorus in mixed municipal sewage and fecal sewage by using a2/o-biomembrane and method thereof - Google Patents
Device for synchronously removing nitrogen and phosphorus in mixed municipal sewage and fecal sewage by using a2/o-biomembrane and method thereof Download PDFInfo
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- WO2012010096A1 WO2012010096A1 PCT/CN2011/077400 CN2011077400W WO2012010096A1 WO 2012010096 A1 WO2012010096 A1 WO 2012010096A1 CN 2011077400 W CN2011077400 W CN 2011077400W WO 2012010096 A1 WO2012010096 A1 WO 2012010096A1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/308—Biological phosphorus removal
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/08—Aerobic processes using moving contact bodies
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/12—Activated sludge processes
- C02F3/1236—Particular type of activated sludge installations
- C02F3/1268—Membrane bioreactor systems
- C02F3/1273—Submerged membrane bioreactors
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/005—Black water originating from toilets
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Definitions
- the invention relates to a wastewater treatment technology, in particular to an A 2 /O-biofilm synchronous nitrogen and phosphorus removal treatment device for urban sewage mixed fecal sewage and a process thereof.
- the present invention overcomes the above problems and invents an LED centralized DC power supply system.
- the A 2 /O process consists of an anaerobic zone, an anoxic zone, an aerobic zone, a sedimentation zone and two reflux systems. Its function is anaerobic phosphorus release, anoxic denitrification and denitrification, aerobic nitrification, and precipitation. After the muddy water is separated, the phosphorus is removed with the excess sludge, but the process has two major defects:
- Nitrifying bacteria are usually autotrophic obligate aerobic bacteria with a long generation. In winter, the generation of nitrifying bacteria can last for more than 30 days, even in the summer, when the mud age is less than The nitrification in the 5-day activated sludge process system is also very weak. Phosphorus-accumulating bacteria and denitrifying bacteria are mostly short-soil-aged microorganisms.
- the mud age is generally less than 10 days. The shorter the mud age, the faster the denitrification rate.
- the 4-day mud age is 8 days of mud age. 2.5 times.
- the mud age of the whole system has to be controlled in a narrow range.
- the system has the functions of nitrogen and phosphorus removal, but it can not make the two types of microorganisms exert their respective advantages and affect the effect of nitrogen and phosphorus removal.
- a 1 /OA 2 /O process and A 1 /A 2 /OO process have been developed for the conflict of mud age.
- This water treatment process has a limited solution to the mud age contradiction than the conventional A 2 /O process, but its water treatment process is further complicated, there is insufficient denitrification carbon source, and the nitrification sludge can not be reused. And so far, no better way has been seen to solve the problem of the conflict of mud age.
- the nitrate in the return sludge affects the phosphorus and nitrogen removal process of the process.
- the anaerobic zone is set a front, and the return sludge will inevitably bring a part of the nitrate into the zone, which will seriously affect the phosphorus release rate of the polyphosphate bacteria, especially when entering the water VFA.
- the presence of nitrate may even cause the phosphorus accumulating bacteria to directly absorb phosphorus.
- the manure sewage comes from the urban manure treatment station, which is the fecal filter liquid after the manure is filtered and desanded. It belongs to the high ammonia nitrogen high organic matter concentration sewage and must be treated harmlessly. Fecal sewage is rich in organic matter and nitrogen, phosphorus and other substances. If it is directly discharged, it will cause water pollution to emit harmful gases containing odorous components such as ammonia, hydrogen sulfide, mercaptans and thioethers, causing serious pollution to the environment.
- the main ways to deal with fecal sewage in China are as follows: 1 separate treatment, which is difficult to process, long in process flow, high in operating cost, complicated in operation management; 2 incorporation into urban sewage treatment plants.
- the main sources of fecal sewage are 2 One: the sanitation public toilets, except for some agricultural use, the rest are transported to the harmless treatment plant, after the slag treatment, into the sewage treatment plant; second, the social septic tank (except the sanitation public toilets, residential buildings, office buildings, The manure produced by the hotel and hotel septic tanks is discharged to the sewage pipe network after being treated to a harmless standard by three-stage septic treatment, and is sent to a sewage treatment plant for treatment. There is no relatively complete fecal harmless treatment plant in China, and some urban manure disposal stations have no feces.
- Sewage treatment facilities in order to maximize the use of existing facilities Because the fecal sewage has the characteristics of high organic matter concentration and high nitrogen content, the buffering, dilution and nutrient balance of the municipal sewage can be utilized to reduce the difficulty of treating the fecal sewage and improve the biodegradability of urban sewage treatment. Therefore, the urban sewage treatment plant is responsible for the treatment of fecal sewage and becomes a feasible technology for treating fecal sewage.
- the high-concentration water quality of the fecal liquid often has various adverse effects on the urban domestic sewage plant, and has a serious impact on the inhibition of nitrification, especially affecting The ammonia nitrogen and total nitrogen in the water are discharged, and the nitrogen removal rate is reduced.
- the object of the present invention is to overcome the disadvantages of the prior art and provide an overcoming of sludge expansion to solve the traditional AAO.
- Another object of the present invention is to provide a method for simultaneous nitrogen and phosphorus removal by municipal wastewater and fecal sewage A 2 /O-biofilm using the above apparatus.
- the invention adds suspended filler in the aeration tank of the traditional AAO process to provide a carrier for attaching the growth surface of the microorganism, and the adhesion phase and the suspension phase are simultaneously present in the aeration tank, thereby forming an A 2 /O-biofilm process.
- the invention improves the biomass in the gas pool, strengthens the conditions for the nitrification reaction, increases the treatment capacity of the wastewater, overcomes the sludge expansion, improves the stability of the operation, and improves the function of the nitrogen and phosphorus removal by the traditional activated sludge process. And solve the problem of the age difference of the traditional AAO process in the process of nitrogen and phosphorus removal.
- a 2 / O-biofilm synchronous nitrogen and phosphorus removal device for urban sewage and fecal sewage comprising anaerobic pool, anoxic tank, first aerobic tank, second aerobic tank and sedimentation tank connected in sequence; anaerobic a stirring paddle is arranged in the pool and the anoxic tank respectively, and an aeration head is respectively arranged at the bottom of the first aerobic pool and the second aerobic pool, and the two aeration heads are respectively connected with the two air compressors;
- the second aerobic tank passes The pipeline and the mixed liquid reflux pump are connected to the anoxic tank, and the sedimentation tank is connected to the anaerobic tank through the pipeline and the sludge return pump;
- the second aerobic tank of the first aerobic tank is dispersed with the suspended filler;
- the suspended filler is three-dimensional hollow
- the light porous ceramsite is calculated according to the total volume of the first aerobic tank and the second aerobic tank, and the dosing ratio of the suspended filler is 20% to 30%, wherein, by volume
- the anaerobic tank, the anoxic tank, the first aerobic tank and the second aerobic tank are preferably disposed in the same casing and separated by a partition.
- the suspension ratio of the first aerobic tank and the second aerobic tank is preferably 1 : 3 .
- the volume ratio of the first aerobic tank to the second aerobic tank is preferably 1:1.
- activated sludge can cultivate polyphosphate bacteria and denitrifying bacteria to increase the excess sludge removal.
- the hydraulic retention time of the first aerobic tank and the second aerobic tank is 4-8h; After the urban sewage and fecal sewage are separated by mud water, the sludge volume is returned to the anaerobic zone at a ratio of 40-80%, and the excess sludge is discharged; the effluent is discharged from the sedimentation tank.
- the present invention has the following beneficial effects:
- the present invention provides a carrier for attaching a growth surface of a microorganism by suspending a suspension filler in the first aerobic tank and the second aerobic tank on the basis of the existing A 2 /O-biofilm process.
- Enriched nitrifying bacteria on the filler which better solves the contradiction of sludge age of biological nitrogen and phosphorus removal, so that the anaerobic pool avoids the interference of nitrate. It also increases the biomass in the aeration tank, increases the treatment capacity of the wastewater, overcomes the expansion of the sludge, and makes the adhes and the suspended phase simultaneously exist in the aeration tank, giving full play to the superiority of both.
- the invention alleviates the tension of the water source, and provides an economical, convenient, reasonable and feasible solution for the comprehensive treatment and disposal of the fecal sewage, because it does not need to occupy more land or increase the capital investment, which not only has great social benefits, but also has great social benefits. Bringing considerable economic and environmental benefits and promoting the development of wastewater treatment resources.
- the treatment process of the A 2 /O-biofilm simultaneous nitrogen and phosphorus removal process of the invention has the following effects on the removal of pollutants: the removal effect of COD and phosphorus is good, the effluent COD is below 40 mg/L, and the phosphorus effluent is at 0.35. Below mg/L; the effluent ammonia nitrogen is below 4mg/L. All effluent water quality indicators have met and exceeded the national emission standard level one standard.
- Figure 1 is a schematic view showing the structure of a synchronous denitrification and dephosphorization device for A 2 /O-biofilm of municipal sewage mixed fecal sewage;
- Figure 2 is a diagram showing the effect of removing the COD by the device of Figure 1;
- Figure 3 is a diagram showing the effect of removing the ammonia nitrogen from the device of Figure 1;
- Figure 4 is a diagram showing the effect of removing the total nitrogen from the apparatus of Figure 1;
- Figure 5 is a diagram showing the effect of removing the total phosphorus from the device of Figure 1.
- the municipal sewage mixed fecal sewage A 2 /O- biofilm simultaneous nitrogen and phosphorus removal device comprises an anaerobic tank 1 connected in sequence, an anoxic tank 2, a first aerobic tank 3, and a second aerobic tank.
- a stirring paddle 12 is respectively arranged in the anaerobic tank and the anoxic tank, and an aeration head is respectively arranged at the bottom of the first aerobic tank and the second aerobic tank, and the aeration head 13 is respectively connected with the air compressor 10
- the second aerobic tank is connected to the anoxic tank through the pipe 8 and the mixed liquid return pump 9, and the sedimentation tank 4 is connected to the anaerobic tank through the pipe 7 and the sludge return pump 14; the first aerobic tank and the second aerobic tank Dispersed with suspended filler 8 .
- Suspension packing 11 is a three-dimensional hollow lightweight porous ceramsite, the specification model is ⁇ 25 ⁇ 9mm, the density is less than water, 0.8g / cm 3 , and the suspended packing is in 2 aerobic tanks (first aerobic tank and second aerobic tank) The total volumetric ratio of the pool is 20% to 30%. Since the suspended filler 8 is a light porous ceramsite, the surface is easy to adhere to activated sludge, providing a carrier for the growth environment of the nitrifying bacteria in the activated sludge. Wherein the volume ratio of the suspended fillers added in the first aerobic tank III and the second aerobic tank IV is 1:1-3, that is, the dosing mode is 1:1-3, and the preferred dosing mode is 1:3. .
- the anaerobic tank, the anoxic tank, the first aerobic tank and the second aerobic tank are disposed in the same casing and are separated by a partition.
- the aerobic pool is divided into two pools before and after, which are the first aerobic tank and the second aerobic tank respectively.
- the process consists of anaerobic zone and anoxic zone, 2
- An aerobic feed area is formed.
- the anaerobic zone is at the head end, and the anoxic zone is in the anaerobic zone.
- the suspended filler is placed in the aerobic feed zone according to the water treatment requirements.
- the reflux sludge pump connects the anaerobic zone and the sedimentation tank, and the mixed liquid reflux pump will be short.
- the oxygen pool is connected to the aerobic packing tank.
- the urban sewage and fecal sewage and the return sludge When the device is working, the urban sewage and fecal sewage and the return sludge first enter the anaerobic tank to release phosphorus, and then enter the anoxic tank for denitrification dehydrogenation; then the urban sewage and fecal sewage enter the first aerobic tank and the second aerobic
- the pool is subjected to nitrification and phosphorus absorption in the activated sludge attached to the suspended sludge in the first aerobic tank and the second aerobic tank, and the purpose of adding the filler is to provide a carrier for the nitrifying bacteria growth environment.
- the suspended filler does not participate in the reflux, and the nitrifying bacteria with longer mud age can be grown thereon for nitrification and phosphorus uptake; More than 30d, but the mud age of polyphosphate and denitrifying bacteria is generally 10d Within, the nitrifying bacteria and polyphosphate bacteria have contradictions in the age of the mud.
- Activated sludge can be separately cultured with polyphosphate bacteria and denitrifying bacteria to increase the amount of excess sludge, which is also in line with the requirements of phosphorus removal by phosphorus sludge of short sludge age, which can solve the conflict of sludge age in sewage treatment process.
- the urban sewage and fecal sewage enter the sedimentation tank in turn, after the sludge is separated, the sludge is volume-by-volume.
- the proportion of 40% to 80% is returned to the anaerobic zone, and the excess sludge is discharged; the effluent 6 Exhausted from the sedimentation tank.
- the reflux sludge system connects the anaerobic tank and the sedimentation tank to ensure the good operation of the nitrification reaction; the mixed liquid reflux system connects the anoxic tank and the aerobic packing tank to improve the mixing efficiency of the aerobic packing pool and thereby increase the oxygen usage efficiency.
- the municipal sewage mixed fecal sewage A 2 /O- biofilm synchronous nitrogen and phosphorus removal device is a steel plate texture with a designed water volume of 500L / h, a total length of 2.9m, a width of 1.2m, a height of 1.3m, and an effective volume of about 3.8m. 3.
- the reaction cell is divided into an anaerobic tank, an anoxic tank, a first aerobic tank and a second aerobic tank through a partition, wherein the effective volume of the anaerobic tank is 0.5 m 3 ; the effective volume of the anoxic tank is 0.8 m 3 , and the two pools
- the stirring paddle 12 is installed, and the motor speed is 1390r/min.
- the first aerobic tank and the second aerobic tank have an effective volume of 2.5 m 3 , and the bottom is respectively provided with an aeration head, which can control the aeration amount through the valve, and the second aerobic tank is equipped with an online dissolved oxygen analyzer, in aerobic A mixed liquid return line is installed at the end of the tank.
- the end of the system is an advection sedimentation tank with an effective volume of 0.9 m 3 and a sludge discharge pipe and a sludge return pipe at the bottom. According to the actual operation, the reflux of the mixture and the flow rate of the sludge are bypassed, and the excess flow is partially returned to the end of the aerobic tank and the sedimentation tank by the branch pipe.
- the first aerobic tank and the second aerobic tank are dispersed with suspended fillers 11 (the suspended filler is a three-dimensional hollow lightweight porous ceramsite, the specification is ⁇ 25 ⁇ 9mm, the density is less than water, 0.8g / cm 3 , the volume of the suspended filler The ratio of dosing is 20% to 30%).
- Influent 5 is pumped directly from the grit chamber by a submersible pump and bypassed for flow control.
- the effluent 7 is discharged from the sedimentation tank V.
- the average ammonia nitrogen concentration of municipal sewage mixed fecal sewage is 23.29mg/L
- the average influent total nitrogen concentration is 24.33mg/L
- the average influent total phosphorus concentration is 3.15mg/L
- the average influent COD concentration is 134.81mg/L.
- the results of the treatment process of A 2 /O-biofilm simultaneous nitrogen and phosphorus removal were investigated.
- the total volumetric ratio of suspended filler in the two aerobic tanks was 20% to 30%.
- the volume ratio of suspended fillers in aerobic tank III and second aerobic tank IV is 1:3, that is, the dosing mode is 1:3; the aerobic tank hydraulic retention time is 4h; the reflux ratio of the mixture is 120%;
- the sludge reflux ratio was 40%, and the four conditions were comprehensively applied.
- the effect of the simultaneous treatment of A 2 /O-biofilm on nitrogen and phosphorus removal was investigated.
- the reaction cycle is 30 days.
- denitrifying denitrifying bacteria belong to heterotrophic facultative anaerobic bacteria.
- organic carbon is used as electron supply.
- the body and nutrient source are subjected to denitrification.
- Phosphorus-producing bacteria that achieve phosphorus removal need to actively absorb the acetic acid which is converted into organic matter by anaerobic fermentation of acid-producing bacteria, which also consumes carbon sources.
- the growth of microorganisms also requires the conversion of organic matter in the sewage into components of their own cells.
- the total effluent nitrogen is generally below 15mg/L, and the lowest concentration of effluent is 11.03mg / L, the highest concentration of effluent was 14.36mg / L, an average of 12.9mg / L Within the scope of emission standards, it is mainly due to the system's efficient and stable nitrification effect, which ensures the nitrogen removal effect of the system.
- Fig. 5 It can be seen from Fig. 5 that it can be seen that the treatment process of simultaneous denitrification and dephosphorization of A 2 /O-biofilm has a good removal effect on total phosphorus.
- the fluctuation of the total phosphorus concentration is relatively large.
- the minimum concentration of influent TP is 1.66mg/L, the highest concentration is 6.26mg/L, and the average concentration is 3.15mg/L.
- the effluent TP is generally below 0.5mg/L, with an average of 0.35mg/L. .
- the TP removal rate is above 75%, the highest is 96.72%, and the average removal rate is 88.79%.
- the removal process of the A 2 /O-biofilm simultaneous nitrogen and phosphorus removal process of the present invention has the following effects on the removal of pollutants: the removal effect of COD and phosphorus is good, and the effluent COD is
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Abstract
Description
技术领域Technical field
本发明涉及废水处理技术,特别是涉及一种城市污水混合粪便污水 A2/O- 生物膜同步脱氮除磷处理装置及其工艺。 The invention relates to a wastewater treatment technology, in particular to an A 2 /O-biofilm synchronous nitrogen and phosphorus removal treatment device for urban sewage mixed fecal sewage and a process thereof.
背景技术Background technique
目前广泛采用的 LED 驱动都是采用几百瓦以下的电源,且每套 LED 灯具集成了一个独立的电源和一个 LED 灯,如图 1 所示。这种供电方式带来以下问题:一是灯具设计要考虑电源的位置和散热,体积大、灯具设计受到电源限制,且成本提高;二是电源一旦损坏,整个灯具同时报废,成本高、寿命短;三是多个 LED 的统一调光控制不易实现。 Currently widely used LED drivers are powered by several hundred watts or less, and each LED luminaire integrates a separate power supply and an LED. Light, as shown in Figure 1. Shown. This kind of power supply brings the following problems: First, the design of the luminaire should consider the position and heat dissipation of the power supply, the volume is large, the design of the luminaire is limited by the power supply, and the cost is increased. Second, once the power supply is damaged, the entire luminaire is scrapped at the same time, and the cost is high and the life is short. ; three is more than Uniform dimming control of LEDs is not easy to achieve.
针对以上的不足,本发明克服了以上的问题,发明了 一种 LED 集中式直流供电系统。 In view of the above deficiencies, the present invention overcomes the above problems and invents an LED centralized DC power supply system.
现有的污水及废水生物处理过程中,氮磷的脱除比碳素的去除要复杂得多,要涉及氮的硝化、反硝化,微生物的释磷和吸磷等过程,上述每一个过程的目的不一样,对微生物组成,基质类型以及环境条件的要求也不一样。怎样在一个水处理装置中把各种恰当的反应条件有机地结合在一起,是一个有重要意义的课题。 In the existing biological treatment of sewage and wastewater, the removal of nitrogen and phosphorus is much more complicated than the removal of carbon. It involves nitrogen nitrification, denitrification, microbial phosphorus release and phosphorus uptake, and each of the above processes. The purpose is different, and the requirements for microbial composition, matrix type and environmental conditions are also different. How to organically combine various appropriate reaction conditions in a water treatment device is an important issue.
从 1932 年 Wuhrmann 利用微生物内源建立了后置反硝化工艺去除城市污水中的氮素以来,经过半个多世纪的改良和发展,在 1984 年由 Deakyne , Patel 和 Krichten 提出了目前水处理工程上应用最普遍、工艺最简洁 A1(Anaerobic)A2(anoxic)O(Oxygen) 脱氮除磷工艺,简称 A1A2O 工艺或称 A2/O 工艺。Since 1929, Wuhrmann established a post-denitrification process to remove nitrogen from municipal wastewater using microbial endogenous sources. After more than half a century of improvement and development, in 1984, Deakyne, Patel and Krichten proposed the current water treatment project. The most common application, the most simple process A 1 (Anaerobic) A 2 (anoxic) O (Oxygen) Denitrification and dephosphorization process, referred to as A 1 A 2 O process or A 2 /O process.
A2/O 工艺由厌氧区、缺氧区、好氧区、沉淀区和二个回流系统组成,其功能是厌氧释磷,缺氧反硝化脱氮,好氧硝化吸磷,经沉淀、泥水分离后,随剩余污泥排出除磷,但该工艺存在两大缺陷:The A 2 /O process consists of an anaerobic zone, an anoxic zone, an aerobic zone, a sedimentation zone and two reflux systems. Its function is anaerobic phosphorus release, anoxic denitrification and denitrification, aerobic nitrification, and precipitation. After the muddy water is separated, the phosphorus is removed with the excess sludge, but the process has two major defects:
第一,泥龄矛盾影响着脱氮除磷的效果。硝化菌通常都属于自养型专性好氧细菌,世代时间长。在冬天,硝化菌繁殖所需世代时间可长达 30 天以上,即使在夏天,在泥龄小于 5 天的活性污泥法系统中硝化作用也十分微弱。聚磷菌和脱氮菌多为短泥龄微生物,泥龄一般在 10 天以内,泥龄越短,比反硝化速度越快, 4 天泥龄是 8 天泥龄的 2.5 倍。另有报道,在美国 Hyperion 污水厂,当水温在 22~24°C 时,除磷系统的泥龄短达 3.1 天,而出水磷仅为 0.4mg/L 。这说明聚磷菌的世代时间确实很短。此外生物除磷的唯一渠道是排除剩余污泥,也要求短泥龄,才能有更多的磷随剩余污泥排除。显然,硝化菌和聚磷菌在泥龄上存在着矛盾,由两类微生物共同用一个回流排泥系统时,整个系统的泥龄不得不控制在一个很窄的范围,这种调和虽然可使系统具备脱氮除磷功能,却不能使两类微生物发挥各自的优势,影响脱氮除磷的效果。 First, the conflict of mud age affects the effect of nitrogen and phosphorus removal. Nitrifying bacteria are usually autotrophic obligate aerobic bacteria with a long generation. In winter, the generation of nitrifying bacteria can last for more than 30 days, even in the summer, when the mud age is less than The nitrification in the 5-day activated sludge process system is also very weak. Phosphorus-accumulating bacteria and denitrifying bacteria are mostly short-soil-aged microorganisms. The mud age is generally less than 10 days. The shorter the mud age, the faster the denitrification rate. The 4-day mud age is 8 days of mud age. 2.5 times. It is also reported that in the Hyperion wastewater treatment plant in the United States, when the water temperature is 22~24 °C, the phosphorus removal system has a sludge age of 3.1 days, while the effluent phosphorus is only 0.4 mg/L. . This shows that the generation time of polyphosphate bacteria is indeed very short. In addition, the only way for biological phosphorus removal is to eliminate excess sludge, and also require short mud age to allow more phosphorus to be removed with excess sludge. Obviously, there is a contradiction between the nitrifying bacteria and the polyphosphate bacteria in the mud age. When the two types of microorganisms use a reflux sludge system together, the mud age of the whole system has to be controlled in a narrow range. The system has the functions of nitrogen and phosphorus removal, but it can not make the two types of microorganisms exert their respective advantages and affect the effect of nitrogen and phosphorus removal.
针对泥龄矛盾,人们又开发了 A1/O-A2/O 工艺和 A1/A2/O-O 工艺。这个水处理工艺比常规 A2/O 工艺有限地解决了泥龄矛盾,但其水处理流程则进一步复杂化,存在反硝化碳源不足,硝化污泥不能再利用。且迄今未止,尚未见到更好的方法来解决泥龄矛盾问题。A 1 /OA 2 /O process and A 1 /A 2 /OO process have been developed for the conflict of mud age. This water treatment process has a limited solution to the mud age contradiction than the conventional A 2 /O process, but its water treatment process is further complicated, there is insufficient denitrification carbon source, and the nitrification sludge can not be reused. And so far, no better way has been seen to solve the problem of the conflict of mud age.
第二,回流污泥中的硝酸盐影响工艺的除磷脱氮的效果。在常规 A2/O 工艺中,厌氧区设在前,回流污泥不可避免地会将一部分硝酸盐带入该区,会严重影响聚磷菌的释磷速度,尤其是当进水中 VFA 较少,污泥含磷量又不高时,硝酸盐的存在甚至会导致聚磷菌直接吸磷,所以在常规 A2/O 工艺的框架下,如何避免硝酸盐进入厌氧区干扰聚磷菌释磷,成为研究热点,解决硝酸盐问题的关键是如何在回流污泥进入厌氧区之前,设法将其携带的硝酸盐耗掉。围绕这一问题人们提出了, JHB 工艺, EASC 工艺 , UCT 工艺等 . 近年来有学者提出倒置 AAO 工艺的设想。通过以 100%~200% 的污泥回流来代替常规 AAO 工艺的混合液回流,该工艺将缺氧池前置,使脱氮效果得到提高,也使厌氧池避免了硝酸盐的干扰。Second, the nitrate in the return sludge affects the phosphorus and nitrogen removal process of the process. In the conventional A 2 /O process, the anaerobic zone is set a front, and the return sludge will inevitably bring a part of the nitrate into the zone, which will seriously affect the phosphorus release rate of the polyphosphate bacteria, especially when entering the water VFA. Less, when the phosphorus content of the sludge is not high, the presence of nitrate may even cause the phosphorus accumulating bacteria to directly absorb phosphorus. Therefore, under the framework of the conventional A 2 /O process, how to prevent the nitrate from entering the anaerobic zone to interfere with the polyphosphate The release of phosphorus from bacteria has become a research hotspot. The key to solving the problem of nitrate is how to recover the nitrates carried by the return sludge before it enters the anaerobic zone. Around this issue, people have proposed, JHB process, EASC process, UCT process, etc. In recent years, some scholars have proposed the idea of inverting the AAO process. By replacing the mixed liquid reflux of the conventional AAO process with 100%~200% sludge reflux, the process pre-empts the anoxic tank to improve the denitrification effect and also avoids the interference of nitrate by the anaerobic tank.
粪便污水来自城市粪便处理站,是粪便经过滤与除砂后的粪便过滤液,属于高氨氮高有机物浓度污水,须做无害化处理。粪便污水含有丰富的机物和氮、磷等物质,若直接排放,会造成水体污染散发含氨、硫化氢、硫醇和硫醚等恶臭成分的有害气体,对环境造成严重污染。国内处理粪便污水的途径主要有:①单独处理,该方式处理难度较大,工艺流程长,运行成本高,操作管理复杂;②并入城市污水厂处理。粪便污水的来源主要有 2 个:一是环卫公厕的便,除部分农用外,其余统一运往无害化处理厂,经隔渣处理后进入污水厂处理;二是社会化粪池(除环卫公厕外的住宅、办公楼、宾馆、酒店的化粪池)产生的粪便,经过三级化粪处理达到无害化标准后排至污水管网,输送至污水厂进行处理。我国还没有较为完善的粪便无害化处理厂,有的城市粪便处理站没有粪便 污水的处理设施 ,为了最大限度地利用已建设施 ,并且由于粪便污水具有有机物浓度高和高含氮的特点,可利用城市污水对粪便污水的缓冲、稀释和营养物质的均衡作用,降低粪便污水处理难度和提高城市污水处理的可生化性。所以城市污水处理厂承担粪便污水的处理,成为处理粪便污水的一种可行技术。但实际运行中城市污水与来自无害化处理厂的粪便污水合并处理后,粪便液的高浓度水质往往对城市生活污水厂带来各种不利的影响,对硝化抑制性影响严重,特别影响出水中氨氮和总氮的达标排放,脱氮率下降。 The manure sewage comes from the urban manure treatment station, which is the fecal filter liquid after the manure is filtered and desanded. It belongs to the high ammonia nitrogen high organic matter concentration sewage and must be treated harmlessly. Fecal sewage is rich in organic matter and nitrogen, phosphorus and other substances. If it is directly discharged, it will cause water pollution to emit harmful gases containing odorous components such as ammonia, hydrogen sulfide, mercaptans and thioethers, causing serious pollution to the environment. The main ways to deal with fecal sewage in China are as follows: 1 separate treatment, which is difficult to process, long in process flow, high in operating cost, complicated in operation management; 2 incorporation into urban sewage treatment plants. The main sources of fecal sewage are 2 One: the sanitation public toilets, except for some agricultural use, the rest are transported to the harmless treatment plant, after the slag treatment, into the sewage treatment plant; second, the social septic tank (except the sanitation public toilets, residential buildings, office buildings, The manure produced by the hotel and hotel septic tanks is discharged to the sewage pipe network after being treated to a harmless standard by three-stage septic treatment, and is sent to a sewage treatment plant for treatment. There is no relatively complete fecal harmless treatment plant in China, and some urban manure disposal stations have no feces. Sewage treatment facilities in order to maximize the use of existing facilities Because the fecal sewage has the characteristics of high organic matter concentration and high nitrogen content, the buffering, dilution and nutrient balance of the municipal sewage can be utilized to reduce the difficulty of treating the fecal sewage and improve the biodegradability of urban sewage treatment. Therefore, the urban sewage treatment plant is responsible for the treatment of fecal sewage and becomes a feasible technology for treating fecal sewage. However, after the actual operation of urban sewage and the sewage from the harmless treatment plant are combined, the high-concentration water quality of the fecal liquid often has various adverse effects on the urban domestic sewage plant, and has a serious impact on the inhibition of nitrification, especially affecting The ammonia nitrogen and total nitrogen in the water are discharged, and the nitrogen removal rate is reduced.
因此 , 混合污水稳定、高效脱氮是实现粪便污水与城市污水同时处理同时达标的关键和需首要解决的问题 , 该技术的提出对于妥善处理粪便污水 , 减轻水环境污染具有十分重要的现实意义。 Therefore, the stable and high-efficiency nitrogen removal of mixed sewage is the key to achieving the simultaneous treatment of fecal sewage and urban sewage, and the primary problem to be solved. The proposal of this technology is of great practical significance for properly handling fecal sewage and reducing water pollution.
发明内容Summary of the invention
本发明的目的是在于克服现有技术的缺点,提供一种克服污泥膨胀, 解决传统 AAO 工艺在脱氮除磷过程中的泥龄矛盾问题 的城市污水混合粪便污水 A2/O- 生物膜同步脱氮除磷装置。 The object of the present invention is to overcome the disadvantages of the prior art and provide an overcoming of sludge expansion to solve the traditional AAO. Process in the process of nitrogen and phosphorus removal, the problem of mud age contradiction, urban sewage mixed fecal sewage A2 / O - biofilm synchronous nitrogen and phosphorus removal device.
本发明的另一目的在提供应用上述装置的城市污水和粪便污水 A2/O- 生物膜同步脱氮除磷方法。Another object of the present invention is to provide a method for simultaneous nitrogen and phosphorus removal by municipal wastewater and fecal sewage A 2 /O-biofilm using the above apparatus.
本发明在 传统 AAO 工艺 的曝气池中投加悬浮填料,提供微生物附着生长表面的载体,曝气池中同时存在附着相和悬浮相,从而形成了 A2 /O- 生物膜工艺 。本发明提高了气池内的生物量,并 强化了发生硝化反应的条件, 增加废水的处理能力,克服污泥膨胀,提高运行的稳定性, 提高传统的活性污泥法工艺脱氮除磷的功能,并解决传统 AAO 工艺在脱氮除磷过程中的泥龄矛盾问题。The invention adds suspended filler in the aeration tank of the traditional AAO process to provide a carrier for attaching the growth surface of the microorganism, and the adhesion phase and the suspension phase are simultaneously present in the aeration tank, thereby forming an A 2 /O-biofilm process. The invention improves the biomass in the gas pool, strengthens the conditions for the nitrification reaction, increases the treatment capacity of the wastewater, overcomes the sludge expansion, improves the stability of the operation, and improves the function of the nitrogen and phosphorus removal by the traditional activated sludge process. And solve the problem of the age difference of the traditional AAO process in the process of nitrogen and phosphorus removal.
本发明的第一目的通过如下技术方案实现: The first object of the present invention is achieved by the following technical solutions:
一种城市污水和粪便污水 A2/O- 生物膜同步脱氮除磷装置,包括依次连接的厌氧池、缺氧池、第一好氧池、第二好氧池和沉淀池;厌氧池和缺氧池内分别设有搅拌桨,第一好氧池和第二好氧池底部分别设有曝气头,两曝气头分别与两空气压缩机连接;所述第二好氧池通过管道和混合液回流泵与缺氧池连接,沉淀池通过管道和污泥回流泵与厌氧池连接;所述第一好氧池第二好氧池内分散有悬浮填料; 悬浮填料为立体中空的轻质多孔陶粒,按照 第一好氧池和第二好氧池的总容积计算, 悬浮填料 的投配比为 20% ~ 30% ,其中,以 体积计, 第一好氧池和第二好氧池的 悬浮填料 投配比为 1 : 1-3 。A 2 / O-biofilm synchronous nitrogen and phosphorus removal device for urban sewage and fecal sewage, comprising anaerobic pool, anoxic tank, first aerobic tank, second aerobic tank and sedimentation tank connected in sequence; anaerobic a stirring paddle is arranged in the pool and the anoxic tank respectively, and an aeration head is respectively arranged at the bottom of the first aerobic pool and the second aerobic pool, and the two aeration heads are respectively connected with the two air compressors; the second aerobic tank passes The pipeline and the mixed liquid reflux pump are connected to the anoxic tank, and the sedimentation tank is connected to the anaerobic tank through the pipeline and the sludge return pump; the second aerobic tank of the first aerobic tank is dispersed with the suspended filler; the suspended filler is three-dimensional hollow The light porous ceramsite is calculated according to the total volume of the first aerobic tank and the second aerobic tank, and the dosing ratio of the suspended filler is 20% to 30%, wherein, by volume, the first aerobic pool and the second The suspension loading ratio of the aerobic tank is 1:1-3.
所述厌氧池、缺氧池、第一好氧池和第二好氧池优选设置在同一壳体内,通过隔板分隔。 The anaerobic tank, the anoxic tank, the first aerobic tank and the second aerobic tank are preferably disposed in the same casing and separated by a partition.
所述第一好氧池和第二好氧池的 悬浮填料 投配比优选为 1 : 3 。 The suspension ratio of the first aerobic tank and the second aerobic tank is preferably 1 : 3 .
所述第一好氧池和第二好氧池的体积比优选为 1 : 1 。 The volume ratio of the first aerobic tank to the second aerobic tank is preferably 1:1.
本发明的另一目的通过如下技术方案实现: Another object of the present invention is achieved by the following technical solutions:
应用上述装置的城市污水和粪便污水 A2/O- 生物膜同步脱氮除磷方法:城市污水和粪便污水以及回流污泥首先进入厌氧池释磷,再进入缺氧池进行反硝化脱氢;然后城市污水和粪便污水依次进入第一好氧池和第二好氧池,在第一好氧池和第二好氧池内悬浮填料上的硝化细菌作用下,进行硝化吸磷,硝化细菌生长在悬浮填料的活性污泥上,活性污泥可分别培养聚磷菌和反硝化细菌增加剩余污泥的排除量,第一好氧池和第二好氧池的水力停留时间为 4-8h ;城市污水和粪便污水经泥水分离后,污泥体积以 40-80% 的比例回流到厌氧区,剩余污泥排出;出水从沉淀池排出。Urban sewage and fecal sewage A 2 /O- biofilm simultaneous nitrogen and phosphorus removal method using the above device: urban sewage and fecal sewage and return sludge first enter the anaerobic tank to release phosphorus, and then enter the anoxic tank for denitrification dehydrogenation Then, the municipal sewage and fecal sewage enter the first aerobic tank and the second aerobic tank in turn, and under the action of nitrifying bacteria on the suspended filler in the first aerobic tank and the second aerobic tank, the nitrifying phosphorus is absorbed, and the nitrifying bacteria grow. On the activated sludge of suspended filler, activated sludge can cultivate polyphosphate bacteria and denitrifying bacteria to increase the excess sludge removal. The hydraulic retention time of the first aerobic tank and the second aerobic tank is 4-8h; After the urban sewage and fecal sewage are separated by mud water, the sludge volume is returned to the anaerobic zone at a ratio of 40-80%, and the excess sludge is discharged; the effluent is discharged from the sedimentation tank.
与已有技术相比, 本 发明 具有如下有益效果: Compared with the prior art, the present invention has the following beneficial effects:
( 1 ) 本发明在 A2/O- 生物膜工艺在现有的基础上,通过在第一好氧池和第二好氧池中增设投加悬浮填料,提供微生物附着生长表面的载体,悬浮填料上富集硝化菌,较好的解决了生物脱氮除磷的泥龄矛盾,使厌氧池避免了硝酸盐的干扰。也提高曝气池内的生物量,增加废水的处理能力,克服污泥膨胀,使曝气池中同时存在附着相和悬浮相,充分发挥两者的优越性。(1) The present invention provides a carrier for attaching a growth surface of a microorganism by suspending a suspension filler in the first aerobic tank and the second aerobic tank on the basis of the existing A 2 /O-biofilm process. Enriched nitrifying bacteria on the filler, which better solves the contradiction of sludge age of biological nitrogen and phosphorus removal, so that the anaerobic pool avoids the interference of nitrate. It also increases the biomass in the aeration tank, increases the treatment capacity of the wastewater, overcomes the expansion of the sludge, and makes the adhes and the suspended phase simultaneously exist in the aeration tank, giving full play to the superiority of both.
( 2 ) 本发明缓解水源紧张的同时,为粪便污水的综合处理处置提供经济、便捷、合理、可行的解决办法,因不需占用更多的土地,也不增加基建投资,不但具有巨大的社会效益,同时带来可观的经济效益及环境效益,并推动污水处理资源化发展。 ( 2 ) The invention alleviates the tension of the water source, and provides an economical, convenient, reasonable and feasible solution for the comprehensive treatment and disposal of the fecal sewage, because it does not need to occupy more land or increase the capital investment, which not only has great social benefits, but also has great social benefits. Bringing considerable economic and environmental benefits and promoting the development of wastewater treatment resources.
( 3 )本发明 A2 /O- 生物膜同步脱氮除磷的处理工艺对污染物的去除效果如下:对 COD 、和磷的去除效果好,出水 COD 在 40mg/L 以下,磷出水在 0.35mg/L 以下;出水氨氮在 4mg/L 以下。各项出水水质指标均达到并优于国家排放标准一级标准。(3) The treatment process of the A 2 /O-biofilm simultaneous nitrogen and phosphorus removal process of the invention has the following effects on the removal of pollutants: the removal effect of COD and phosphorus is good, the effluent COD is below 40 mg/L, and the phosphorus effluent is at 0.35. Below mg/L; the effluent ammonia nitrogen is below 4mg/L. All effluent water quality indicators have met and exceeded the national emission standard level one standard.
附图说明 DRAWINGS
图 1 为城市污水混合粪便污水 A2/O- 生物膜同步脱氮除磷装置结构示意图;Figure 1 is a schematic view showing the structure of a synchronous denitrification and dephosphorization device for A 2 /O-biofilm of municipal sewage mixed fecal sewage;
图 2 为应用图 1 装置 对 COD 的去除效果图; Figure 2 is a diagram showing the effect of removing the COD by the device of Figure 1;
图 3 为应用图 1 装置 对 氨氮的去除效果图; Figure 3 is a diagram showing the effect of removing the ammonia nitrogen from the device of Figure 1;
图 4 为应用图 1 装置 对 总氮的去除效果图; Figure 4 is a diagram showing the effect of removing the total nitrogen from the apparatus of Figure 1;
图 5 为应用图 1 装置 对总磷的去除效果图。 Figure 5 is a diagram showing the effect of removing the total phosphorus from the device of Figure 1.
具体实施方式 detailed description
以下结合附图和实施例对本发明作进一步说明,但本发明所要求保护的范围并不局限于具体实施方式中所描述的范围。 The invention is further described below in conjunction with the accompanying drawings and embodiments, but the scope of the invention is not limited to the scope described in the specific embodiments.
如图 1 所示,城市污水混合粪便污水 A2/O-
生物膜同步脱氮除磷装置包括依次连接的厌氧池 1 、缺氧池 2 、第一好氧池 3 、第二好氧池 15 和沉淀池 4 ;厌氧池和缺氧池内分别设有搅拌桨 12
,第一好氧池和第二好氧池底部分别设有曝气头,曝气头 13 分别与空气压缩机 10 连接,第二好氧池通过管道 8 和混合液回流泵 9 与缺氧池连接,沉淀池 4
通过管道 7 和污泥回流泵 14 与厌氧池连接;第一好氧池和第二好氧池内分散有悬浮填料 8 。 悬浮填料 11 为立体中空的轻质多孔陶粒, 规格型号为
ø25×9mm ,密度小于水,为 0.8g /cm3 ,悬浮填料在 2 个好氧池(第一好氧池和第二好氧池)中总容积投配比为 20% ~
30% ,由于悬浮填料 8 是轻质多孔陶粒,表面易附着活性污泥,为活性污泥中的硝化细菌群提供了生长环境的载体。其中在第一好氧池 Ⅲ 和第二好氧池 Ⅳ
中投加的悬浮填料的体积比为 1 : 1-3 ,即投配方式为 1 : 1-3 ,优选投配方式为 1 : 3
。厌氧池、缺氧池、第一好氧池和第二好氧池设置在同一壳体内,通过隔板分隔形成。好氧池隔成前后两个池,分别为第一好氧池和第二好氧池 。As shown in Figure 1, the municipal sewage mixed fecal sewage A 2 /O- biofilm simultaneous nitrogen and phosphorus removal device comprises an anaerobic tank 1 connected in sequence, an
本工艺由厌氧区、缺氧区, 2 个好氧投料区构成。其中厌氧区在首端,缺氧区在厌氧区后,在好氧投料区内根据水处理要求投放悬浮填料,回流污泥泵将厌氧区和沉淀池连通,混合液回流泵将缺氧池和好氧填料池连通。 The process consists of anaerobic zone and anoxic zone, 2 An aerobic feed area is formed. The anaerobic zone is at the head end, and the anoxic zone is in the anaerobic zone. The suspended filler is placed in the aerobic feed zone according to the water treatment requirements. The reflux sludge pump connects the anaerobic zone and the sedimentation tank, and the mixed liquid reflux pump will be short. The oxygen pool is connected to the aerobic packing tank.
装置工作时,城市污水和粪便污水以及回流污泥首先进入厌氧池释磷,再进入缺氧池进行反硝化脱氢;然后城市污水和粪便污水依次进入第一好氧池和第二好氧池,在第一好氧池和第二好氧池内悬浮填料上附着的活性污泥中硝化细菌作用下,进行硝化吸磷,投加填料的目的是用来提供硝化菌群生长环境的载体。在第一好氧池和第二好氧池内,悬浮填料不参加回流,其上能生长泥龄较长的硝化细菌,进行硝化吸磷;由于硝化菌泥龄长达 30d 以上,但聚磷菌和脱氮菌的泥龄一般在 10d 以内,硝化菌和聚磷菌在泥龄上存在着矛盾。活性污泥可分别培养聚磷菌和反硝化细菌增加剩余污泥的排除量,这样也符合短泥龄的聚磷菌除磷的要求,可解决污水处理过程的泥龄矛盾。然后城市污水和粪便污水依次进入沉淀池,经泥水分离后,污泥按体积比的 40% ~ 80% 的比例回流到厌氧区,剩余污泥排出;出水 6 从沉淀池排出。回流污泥系统将厌氧池和沉淀池连通,可以保证硝化反应的良好运行;混合液回流系统将缺氧池和好氧填料池连通,可以起到提高好氧填料池混合效率,进而提高氧利用效率。 When the device is working, the urban sewage and fecal sewage and the return sludge first enter the anaerobic tank to release phosphorus, and then enter the anoxic tank for denitrification dehydrogenation; then the urban sewage and fecal sewage enter the first aerobic tank and the second aerobic The pool is subjected to nitrification and phosphorus absorption in the activated sludge attached to the suspended sludge in the first aerobic tank and the second aerobic tank, and the purpose of adding the filler is to provide a carrier for the nitrifying bacteria growth environment. In the first aerobic tank and the second aerobic tank, the suspended filler does not participate in the reflux, and the nitrifying bacteria with longer mud age can be grown thereon for nitrification and phosphorus uptake; More than 30d, but the mud age of polyphosphate and denitrifying bacteria is generally 10d Within, the nitrifying bacteria and polyphosphate bacteria have contradictions in the age of the mud. Activated sludge can be separately cultured with polyphosphate bacteria and denitrifying bacteria to increase the amount of excess sludge, which is also in line with the requirements of phosphorus removal by phosphorus sludge of short sludge age, which can solve the conflict of sludge age in sewage treatment process. Then the urban sewage and fecal sewage enter the sedimentation tank in turn, after the sludge is separated, the sludge is volume-by-volume. The proportion of 40% to 80% is returned to the anaerobic zone, and the excess sludge is discharged; the effluent 6 Exhausted from the sedimentation tank. The reflux sludge system connects the anaerobic tank and the sedimentation tank to ensure the good operation of the nitrification reaction; the mixed liquid reflux system connects the anoxic tank and the aerobic packing tank to improve the mixing efficiency of the aerobic packing pool and thereby increase the oxygen usage efficiency.
实施例 Example
城市污水混合粪便污水 A2/O- 生物膜同步脱氮除磷装置为钢板质地,设计处理水量
500L /h ,总长为 2.9m ,宽为 1.2m ,高为 1.3m ,有效体积约为 3.8m3
,反应池通过隔板分为厌氧池、缺氧池、第一好氧池和第二好氧池,其中厌氧池有效体积 0.5m3 ;缺氧池有效体积
0.8m3 ,两池均安装搅拌桨 12 ,电动机转速为 1390r/min 。第一好氧池和第二好氧池有效体积
2.5m3
,底部分别设有曝气头,可以通过阀门控制曝气量,第二好氧池中装有在线溶解氧测定仪,在好氧池末端装有混合液回流管。系统末端是平流式沉淀池,有效体积
0.9m3
,底部有排泥管和污泥回流管。根据实际运行混合液回流和污泥回流流量均采取旁路控制,多余流量部分由支管分别返回好氧池末端和沉淀池。第一好氧池和第二好氧池内分散有悬浮填料
11 ( 悬浮填料为立体中空的轻质多孔陶粒, 规格为 ø25×9mm ,密度小于水,为 0.8g /cm3 ,悬浮填料的体积投配比为
20% ~ 30% )。进水 5 由潜水泵直接从沉砂池抽取,通过旁路来进行流量控制。出水 7 从沉淀池 Ⅴ 排出。The municipal sewage mixed fecal sewage A 2 /O- biofilm synchronous nitrogen and phosphorus removal device is a steel plate texture with a designed water volume of 500L / h, a total length of 2.9m, a width of 1.2m, a height of 1.3m, and an effective volume of about 3.8m. 3. The reaction cell is divided into an anaerobic tank, an anoxic tank, a first aerobic tank and a second aerobic tank through a partition, wherein the effective volume of the anaerobic tank is 0.5 m 3 ; the effective volume of the anoxic tank is 0.8 m 3 , and the two pools The stirring
城市污水混合粪便污水的平均氨氮浓度为 23.29mg/L ,平均进水总氮浓度为在 24.33mg/L ,平均进水总磷浓度为 3.15mg/L ,平均进水 COD 浓度为 134.81mg/L 。分别考察各个因素, A2 /O- 生物膜同步脱氮除磷的处理工艺的效果,考察时间为 4d 。单因素实验结果如下:The average ammonia nitrogen concentration of municipal sewage mixed fecal sewage is 23.29mg/L, the average influent total nitrogen concentration is 24.33mg/L, the average influent total phosphorus concentration is 3.15mg/L, and the average influent COD concentration is 134.81mg/L. . The effects of various factors, A 2 /O-biofilm simultaneous nitrogen and phosphorus removal treatment were investigated, and the investigation time was 4d. The results of the single factor experiment are as follows:
(1) 当填料投配方式为 1 : 3 时,氨氮平均去除率是 92.73% ;总氮平均去除率 72.16% ;总磷平均去除率为 88.02% ; COD 平均去除率为 74.51% 。 (1) When the filling method is 1: 3, the average removal rate of ammonia nitrogen is 92.73%; the average removal rate of total nitrogen is 72.16%. The average removal rate of total phosphorus was 88.02%; the average removal rate of COD was 74.51%.
(2) 当好氧池水力停留时间为 4h 时,氨氮平均去除率为 92.73% ;总氮平均去除率为 72.16% ; COD 平均去除率为 74.51% 。 (2) When the aerobic tank hydraulic retention time is 4h, the average removal rate of ammonia nitrogen is 92.73%; the average removal rate of total nitrogen is 72.16%. The average COD removal rate was 74.51%.
(3) 当混合液回流比为 120% ,氨氮平均去除率为 82.02% ;总氮平均去除率为 64.87% ;总磷平均去除率为 89.3% ; COD 平均去除率为 71.77% 。 (3) When the reflux ratio of the mixture is 120%, the average removal rate of ammonia nitrogen is 82.02%; the average removal rate of total nitrogen is 64.87%. The average removal rate of total phosphorus was 89.3%; the average removal rate of COD was 71.77%.
(4) 当污泥回流比为 40% ,氨氮平均去除率为 76.45% ;总氮平均去除率为 57.35% ;总磷平均去除率为 88.36% ; COD 平均去除率为 71.76% 。 (4) When the sludge reflux ratio is 40%, the average removal rate of ammonia nitrogen is 76.45%; the average removal rate of total nitrogen is 57.35%. The average removal rate of total phosphorus was 88.36%; the average removal rate of COD was 71.76%.
实施效果 Implementation Effect
根据以上单因素实验考察 A2 /O- 生物膜同步脱氮除磷的处理工艺的实施 结果,采用悬浮填料在 2 个好氧池中总容积投配比为 20% ~ 30% ,在第一好氧池 Ⅲ 和第二好氧池 Ⅳ 中投加的悬浮填料的体积比为 1 : 3 ,即投配方式为 1:3 ;好氧池水力停留时间 4h ;混合液的回流比 120% ;污泥回流比 40% ,将这四种条件综合应用,考察了 A2 /O- 生物膜同步脱氮除磷的处理工艺的实施效果。反应周期为 30 天。According to the above single factor experiment, the results of the treatment process of A 2 /O-biofilm simultaneous nitrogen and phosphorus removal were investigated. The total volumetric ratio of suspended filler in the two aerobic tanks was 20% to 30%. The volume ratio of suspended fillers in aerobic tank III and second aerobic tank IV is 1:3, that is, the dosing mode is 1:3; the aerobic tank hydraulic retention time is 4h; the reflux ratio of the mixture is 120%; The sludge reflux ratio was 40%, and the four conditions were comprehensively applied. The effect of the simultaneous treatment of A 2 /O-biofilm on nitrogen and phosphorus removal was investigated. The reaction cycle is 30 days.
- COD 的去除效果 COD removal effect
由附图 2 可以看出 A2 /O- 生物膜同步脱氮除磷的处理工艺对 COD 有很好的去除效果。 进入中试装置的混合污水 COD 浓度变化较大,而且总体上进水 COD 浓度比较低。出水 COD 浓度也比较低,说明有机污染物已经被充分利用。平均进水 COD 在 134.81mg/L 左右,而出水 COD 一般在 40mg/L 以下。 COD 去除率最高可达 88.37 %,平均去除率可达 70.41 %。 COD 是污水处理工艺中微生物生长的碳源,在进行污水的脱氮除磷作用时,反硝化脱氮菌属于异养型兼性厌氧菌,在无氧条件时,以有机碳为电子供体和营养源进行反硝化反应。而实现除磷作用的聚磷菌需要主动吸收由厌氧发酵产酸菌转化水中有机物成为的乙酸苷,这也会消耗碳源。同时微生物的生长也需要消耗污水中的有机物转化成自身细胞的组成部分。It can be seen from Fig. 2 that the treatment process of A 2 /O-biofilm simultaneous nitrogen and phosphorus removal has a good removal effect on COD. The COD concentration of the mixed sewage entering the pilot plant varies greatly, and the COD concentration of the influent water is generally low. The effluent COD concentration is also relatively low, indicating that organic pollutants have been fully utilized. The average influent COD is around 134.81 mg/L, while the effluent COD is generally below 40 mg/L. The COD removal rate is up to 88.37% and the average removal rate is up to 70.41%. COD is the carbon source for microbial growth in wastewater treatment. When denitrifying and dephosphorizing the sewage, denitrifying denitrifying bacteria belong to heterotrophic facultative anaerobic bacteria. When anaerobic conditions are used, organic carbon is used as electron supply. The body and nutrient source are subjected to denitrification. Phosphorus-producing bacteria that achieve phosphorus removal need to actively absorb the acetic acid which is converted into organic matter by anaerobic fermentation of acid-producing bacteria, which also consumes carbon sources. At the same time, the growth of microorganisms also requires the conversion of organic matter in the sewage into components of their own cells.
2 、氨氮和总氮的去除效果 2, ammonia nitrogen and total nitrogen removal effect
由附图 3 和附图 4 可以看出,进入中试装置的混合污水总体上总氮浓度比较低,但由于粪便污水高含氮和瞬间混入导致波动比较大,其中,进水最低 TN 浓度在 20mg/L 以上,进水最高 TN 浓度在 38.63mg/L ,平均进水 TN 在 24.33mg/L ,经过微生物的反硝化脱氮作用,出水总氮一般在 15mg/L 以下,出水最低浓度为 11.03mg/L ,出水最高浓度为 14.36mg/L ,平均为 12.9mg/L ,在排放标准范围以内,主要是由于系统具有高效稳定的硝化效果,保证了系统的脱氮效果。 Figure 3 and Figure 4 It can be seen that the total nitrogen concentration in the mixed sewage entering the pilot plant is relatively low, but the fluctuation of the high nitrogen content and instantaneous mixing of the manure sewage is relatively large. Among them, the minimum TN concentration of the influent water is above 20 mg/L, and the maximum water inflow is highest. The concentration of TN is 38.63mg/L, and the average influent TN is 24.33mg/L. After denitrifying denitrification by microorganisms, the total effluent nitrogen is generally below 15mg/L, and the lowest concentration of effluent is 11.03mg / L, the highest concentration of effluent was 14.36mg / L, an average of 12.9mg / L Within the scope of emission standards, it is mainly due to the system's efficient and stable nitrification effect, which ensures the nitrogen removal effect of the system.
3 、总磷的去除效果 3, the removal effect of total phosphorus
由附图 5 可以看出,可以看出 A2 /O- 生物膜同步脱氮除磷的处理工艺对总磷有很好的去除效果。 进入总磷浓度的波动比较大。其中进水 T-P 最低浓度 1.66mg/L ,最高浓度在 6.26mg/L ,平均浓度为 3.15mg/L ,经过微生物的除磷作用,出水 T-P 一般在 0.5mg/L 以下,平均为 0.35mg/L 。 T-P 去除率在 75 %以上,最高可达 96.72 %,平均去除率可达 87.89 %。It can be seen from Fig. 5 that it can be seen that the treatment process of simultaneous denitrification and dephosphorization of A 2 /O-biofilm has a good removal effect on total phosphorus. The fluctuation of the total phosphorus concentration is relatively large. The minimum concentration of influent TP is 1.66mg/L, the highest concentration is 6.26mg/L, and the average concentration is 3.15mg/L. After dephosphorylation by microorganisms, the effluent TP is generally below 0.5mg/L, with an average of 0.35mg/L. . The TP removal rate is above 75%, the highest is 96.72%, and the average removal rate is 88.79%.
综合上述实验,本发明 A2 /O- 生物膜同步脱氮除磷的处理工艺对污染物的去除效果如下:对 COD 、和磷的去除效果好,出水 COD 在Combining the above experiments, the removal process of the A 2 /O-biofilm simultaneous nitrogen and phosphorus removal process of the present invention has the following effects on the removal of pollutants: the removal effect of COD and phosphorus is good, and the effluent COD is
40mg/L 以下,磷出水在 0.35mg/L 以下;出水氨氮在 4mg/L 以下。各项出水水质指标均达到并优于国家一级排放标准。 Below 40mg/L, phosphorus effluent is below 0.35mg/L; effluent ammonia nitrogen is at 4mg/L the following. All effluent water quality indicators have met and exceeded national first-level emission standards.
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| CN2010102321282A CN101935132B (en) | 2010-07-20 | 2010-07-20 | A2/O-biofilm synchronous denitrification and phosphorus removal device and method for urban sewage mixed fecal sewage |
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| CN101935132A (en) | 2011-01-05 |
| CN101935132B (en) | 2012-08-08 |
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