WO2011136835A1 - Ballasted sequencing batch reactor system and method for treating wastewater - Google Patents

Ballasted sequencing batch reactor system and method for treating wastewater Download PDF

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Publication number
WO2011136835A1
WO2011136835A1 PCT/US2011/000179 US2011000179W WO2011136835A1 WO 2011136835 A1 WO2011136835 A1 WO 2011136835A1 US 2011000179 W US2011000179 W US 2011000179W WO 2011136835 A1 WO2011136835 A1 WO 2011136835A1
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WIPO (PCT)
Prior art keywords
weighting agent
biological floes
subsystem
further including
sequencing batch
Prior art date
Application number
PCT/US2011/000179
Other languages
French (fr)
Inventor
Steven Woodard
Original Assignee
Cambridge Water Technology , Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cambridge Water Technology , Inc. filed Critical Cambridge Water Technology , Inc.
Priority to CN201180021491.2A priority Critical patent/CN102858693B/en
Priority to EP11775392.1A priority patent/EP2563729B8/en
Publication of WO2011136835A1 publication Critical patent/WO2011136835A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1278Provisions for mixing or aeration of the mixed liquor
    • C02F3/1284Mixing devices
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1263Sequencing batch reactors [SBR]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/34Treatment of water, waste water, or sewage with mechanical oscillations
    • C02F1/36Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/38Treatment of water, waste water, or sewage by centrifugal separation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/48Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/488Treatment of water, waste water, or sewage with magnetic or electric fields for separation of magnetic materials, e.g. magnetic flocculation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/12Inert solids used as ballast for improving sedimentation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Definitions

  • This invention relates to a ballasted sequencing batch reactor (SBR) system and method for treating wastewater.
  • SBR sequencing batch reactor
  • a typical conventional SBR system includes one or more SBRs which contain a large population of
  • SBR systems typically use four phases to treat wastewater: fill, react, settle, and decant.
  • the fill phase the SBR is filled with the influent wastewater and may be aerated, mixed without aeration, or not mixed and not aerated.
  • the react phase involves adding oxygen, mixing, or a combination thereof, to provide treatment by converting biochemical oxygen demand (BOD) to microorganisms to form biological floes.
  • BOD biochemical oxygen demand
  • the biological floes formed in the previous phases are allowed settle to the bottom of the SBR to form settled sludge.
  • the decant phase involves slowly decanting the clear water from the settled sludge to provide a treated effluent.
  • the biological floes are only marginally heavier than water and therefore settle very slowly.
  • the solids separation in the settle phase may be unreliable due to many types of settling problems that are caused by: overgrowth of filamentous organisms, viscous bulking caused by the overgrowth of either zoogleal organisms or exocellular polysaccharide material, pin floe, straggler floe, and the like. This may limit the capacity of a conventional SBR system and can compromise the quality of the treated effluent.
  • This invention features a ballasted sequencing batch reactor system for treating wastewater including one or more sequencing batch reactors.
  • a weighting agent impregnation subsystem is configured to mix biological floes and weighting agent to form weighted biological floes.
  • a weighting agent recovery subsystem is configured to recover weighting agent from the weighted biological floes and reintroduce the recovered weighting agent to the weighting agent impregnation subsystem.
  • the system may include a sludge storage tank configured to receive settled sludge from the one or more sequencing batch reactors, store the settled sludge therein, and regulate the flow of settled sludge to weighting agent recovery subsystem.
  • the weighting agent recovery subsystem may include a separator subsystem for separating the weighting agent from the weighted biological floes.
  • the separator subsystem may include a shear mill.
  • the separator subsystem may include a centrifugal separator.
  • the separator subsystem may include an ultrasonic separator.
  • the separator subsystem may include a shear mill and a wet drum magnetic separator.
  • the separator subsystem may include a shear mill and a centrifugal separator.
  • the separator subsystem may include an ultrasonic separator and a wet drum magnetic separator.
  • the separator subsystem may include an ultrasonic separator and a centrifugal separator.
  • the shear mill may include rotor and a stator, wherein the rotor and/or the stator include slots sized as to optimize separation of weighting agent from the weighted biological floes.
  • the weighting agent impregnation subsystem may include an impregnation tank and at least one mixer. The capacity of the system may be increased by reducing the duration of a settle phase.
  • the one or more sequencing batch reactors may be configured to decant clear effluent from settled sludge to provide a treated effluent.
  • the weighted biological floes may enhance the quality of the treated effluent by reducing the concentration of suspended solids and related contaminants therein.
  • the system may include a wasting subsystem for wasting settled sludge from the weighting agent recovery subsystem to control a population of microorganisms in a mixed liquor in the one or more sequencing batch reactors.
  • the capacity of the system may be increased by increasing the concentration of the mixed liquor in the one or more sequencing batch reactors by reducing the amount of settled sludge wasted by a wasting subsystem.
  • the capacity of the system may be increased by reducing the duration of a react phase.
  • the amount of settled sludge wasted by the wasting subsystem may be reduced to increase the concentration of mixed liquor suspended solids for enhancing nitrification and/or de-nitrification of ammonia in the mixed liquid.
  • Nitrification may be enhanced by increasing the amount of dissolved oxygen introduced into the one or more sequencing batch reactors.
  • a coagulant may be added to the one or more sequencing batch reactors for removing phosphorus by precipitation and/or coagulation.
  • a flocculant may be added to the one or more sequencing batch reactors for enhancing settling and thickening of the weighted biological floes and for providing agglomeration of non-impregnated biological floes and/or partially impregnated biological floes with weighted biological floes.
  • the weighting agent impregnation subsystem may include a venturi mixer/eductor.
  • a majority of the weighting agent may have a particle size less than about 100 ⁇ .
  • a majority of the weighting agent may have a particle size less than about 40 ⁇ .
  • a majority of the weighting agent may have a particle size less than about 20 ⁇ .
  • the weighting agent may include magnetite.
  • the system may include a mixer disposed in each of the one or more sequencing batch reactors for maintaining the suspended solids or the mixed liquor in suspension.
  • This invention also features a method for treating wastewater using one or more sequencing batch reactors, the method including the steps of: a) receiving influent wastewater in the one or more sequencing batch reactors, b) forming biological floes in the one or more sequencing batch reactors, c) impregnating weighting agent into the biological floes to form weighted biological floes, and d) recovering weighting agent from the weighted biological floes to reintroduce the weighting agent to step c).
  • the method may include the step of separating the weighting agent from the weighted biological floes.
  • the method may include the step of collecting the weighting agent and recycling the weighting agent to step c).
  • the method may include the step of providing weighting agent in which the majority of the weighting agent has a particle size less than about 100 ⁇ .
  • the method may include the step of providing weighting agent in which the majority of the weighting agent has a particle size less than about 40 ⁇ .
  • the method may include the step of providing weighting agent in which the majority of the weighting agent has a particle size less than about 20 ⁇ .
  • the method may include the step of introducing dissolved oxygen to a population of microorganisms to promote growth of biological floes in a mixed liquor defined by a concentration of mixed liquor suspended solids.
  • the method may include the step of introducing a flocculant to the mixed liquor to enhance settling and thickening of the weighted biological floes and to establish agglomeration of non-impregnated biological floes and/or partially impregnated biological floes with the weighted biological floes.
  • the method may include the step of separating and collecting the weighted biological floes from the mixed liquor in the one or more sequencing batch reactors to provide a secondary effluent and a settled sludge.
  • the method may include the step of recycling the majority of the settled sludge to step b).
  • the method may include the step of decanting the clean effluent from the settled sludge in the one or more sequencing batch reactors to provide a treated effluent.
  • the method may include the step of wasting the remaining settled sludge using a wasting subsystem to control the population of the microorganisms in the mixed liquor.
  • the method may include the step of increasing the capacity of the system by reducing the duration of a settle phase.
  • the method may include the step of enhancing the quality of the treated effluent by reducing suspended solids and related- contaminants therein.
  • the method may include the step of wasting settled sludge from the weighting agent recovery subsystem to control a population of microorganisms in a mixed liquor in the one or more sequencing batch reactors.
  • the method may include the step of increasing the capacity of the system by increasing the concentration of the mixed liquor in the one or more sequencing batch reactors by reducing the amount of settled sludge wasted by a wasting subsystem.
  • the method may include the step of increasing the capacity of the system by reducing the duration of a react phase.
  • the method may include the step of reducing the amount of settled sludge wasted by the wasting subsystem to increase the concentration of mixed liquor suspended solids which enhances nitrification and/or de-nitrification of ammonia in the mixed liquid.
  • the method may include the step of enhancing nitrification by increasing the amount of dissolved oxygen introduced into the one or more sequencing batch reactors.
  • the weighting agent may be impregnated into the biological floes in step b) by mixing the mixed liquor and the biological floes at a predetermined energy level.
  • Fig. 1 is a schematic block diagram of one embodiment of the SBR system for treating wastewater in accordance with this invention
  • Fig. 2 is a microscopic view showing one example of weighting agent impregnated in biological floes using the weighting agent impregnation system shown in Fig. 1;
  • Fig. 3 is a schematic block diagram showing another embodiment of the SBR system for treating wastewater of this invention.
  • Fig. 4 is a schematic side-view of another embodiment of the impregnation subsystem shown in Figs. 1 and 3;
  • Fig. 5A is a schematic side-view of one embodiment of the separator shown in Figs. 1 and 3;
  • Fig. 5B is a schematic top view showing one example of slots in the rotor and stator of the shear mill shown in Fig. 5 A;
  • Fig. 5C is a three-dimensional view of one embodiment of the shear mill in Fig. 5A;
  • Fig. 6 is a three-dimensional front- view of another embodiment of the separator shown in Figs. 1 and 3;
  • Fig. 7 is a three-dimensional front- view of yet another embodiment of the separator shown in Fig. 1.
  • System 10 includes at least one SBR 12 which receives a flow of influent wastewater 14 by line 16.
  • SBR 12 preferably introduces air bubbles 18 by line 20 exposed to ambient air 22.
  • Air bubbles 18 introduce dissolved oxygen to a population of microorganisms in SBR 12 to promote growth of biological fiocs
  • Mixed liquor 24 as used herein means a combination of influent wastewater 14 and biological floes 23.
  • System 10 also includes weighting agent impregnation subsystem 26 which, in one embodiment, includes impregnation tank 28 and mixer 30 which receives mixed liquor 24 from SBR 12 by line 32.
  • impregnation tank 28 preferably receives virgin weighting agent 33, e.g., from feed hopper 34 by line 36, and/or recycled weighting agent 38 from weighting agent recovery subsystem 74 (discussed below).
  • Weighting agent impregnation subsystem 26 mixes mixed liquor
  • Fig. 2 shows one example of weighting agent 33, 38 impregnated into biological floes 23 to form weighted biological floes 25.
  • the weighted biological floes impregnated with the weighting agent are then sent back to SBR 12, Fig. 1, by line 37.
  • the weighting agent may be magnetite, or any similar type weighting agent or magnetically separable inorganic material known to those skilled in the art which increases the density of the biological floes.
  • the majority of the weighting agent particles may have a size less than about 100 ⁇ . In other examples, the majority of the weighting agent particles may have a size less than about 40 ⁇ , or, the majority of the weighting agent may have a particle size less than about 20 ⁇ .
  • Weighting agent recovery subsystem 74 which receives settled sludge from bottom 39 of SBR 12 by line 76 typically after the settle and decant phases are complete.
  • Weighting agent recovery subsystem 74 preferably includes separator 78 which recovers the weighting agent from the weighted biological floes in the settled sludge in line 76 and reintroduces (recycles) the weighting agent to weighting agent impregnation subsystem 26 by line 79.
  • Weighting agent recovery subsystem 74 may include recovery subsystem 83, discussed below.
  • system 10 includes sludge storage tank 88 which stores settled sludge output from SBR 12 by line 76 typically after the decant phase is complete.
  • SBR 12 is filled with influent wastewater 14 via line 16 and seeded with a large population of microorganisms that ingest contaminants in influent wastewater 14 to form biological floes 23.
  • dissolved oxygen via air bubbles 18 may be introduced to mixed liquor 24 to promote growth of biological floes 23.
  • system 10 undergoes a react phase.
  • weighting agent impregnation subsystem 26 receives the mixed liquor by line 32, or settled sludge by line 77 via sludge storage tank 88 and line 76 and/or via lines 76 and 81, and impregnates the biological floes therein with virgin weighting agent 33 and/or recycled weighting agent 38 using mixer 30.
  • the mixed liquor or settled sludge having weighted biological floes is then sent back to SBR 12 by line 37.
  • the react phase is followed by the settling phase where the weighted biological floes settle to bottom 39 of SBR 12 to form settled sludge.
  • the times for the fill, react, settle, and decant phases vary as known by those skilled in the art.
  • the clear effluent is decanted by line 52 to provide treated effluent 50.
  • some of the settled sludge at bottom 39 of SBR 12 may be sent to sludge storage tank 88 via line 76.
  • Sludge storage tank 88 stores sludge from SBR 12 and regulates the flow thereof to weighting agent recovery subsystem 74.
  • Weighting agent recovery subsystem 74 then recovers the weighting agent from the weighted biological floes as discussed above and recycles the weighting agent to weighting agent impregnation subsystem 26 as recovered weighting agent 38.
  • the weighted biological floes in SBR 12 have a greater specific gravity than non-impregnated biological floes, they settle faster than non-impregnated biological floes utilized in a typical conventional SBR system. Thus, the time needed for the settling phase of system 10 is reduced. This alleviates settling problems associated with a conventional SBR system, such as overgrowth of filamentous organisms, viscous bulking caused by the overgrowth of either zoogleal organisms or exocellular polysaccharide material, pin floe, straggler floe, and the like. The result is the capacity of system 10 to treat wastewater may be increased while providing high quality treated effluent 50.
  • system 10 may also allow more time for the react phase, which further increases the quality of treated effluent 50.
  • the weighted biological floes also enhance the quality of the treated effluent by reducing the concentration of suspended solids and related contaminants therein.
  • the weighted biological floes also facilitate higher mixed liquor suspended solids (MLSS) concentrations. Operating at higher MLSS concentrations provides additional advantages, including additional increased treatment capacity, enhanced nitrogen removal, enhanced phosphorus removal, and the like.
  • weighting agent recovery subsystem 74 recovers and recycles the weighting agent, the operational costs of system 10 are significantly reduced.
  • System 10' includes at least two SBRs 12' and 12".
  • SBR 12' is filled with influent wastewater 14 by line 16 by opening valve 62 and closing valve 64. Once SBR 12' is filled, valve 62 is closed and valve 64 is open. SBR 12" is then similarly filled with influent wastewater 14.
  • System 10' allows a continuous flow of influent wastewater 14 to either SBR 12' or SBR 12" for continuous operation.
  • System 10 is not limited to two SBRs, as any number of SBRs may be utilized to accommodate the flow rate of influent wastewater 14. In one example, after SBR 12' is filled and SBR 12" is in the fill phase, SBR 12' undergoes the react, settle, and decant phases.
  • SBR 12' when SBR 12' is in the fill phase, SBR 12" typically undergoes the react, settle, and decant phases.
  • System 10' may include sludge storage tank 88' which receives some of the settled sludge from SBR 12' via line 90 and some of the settled sludge from SBR 12" via line 92 during or after the decant phase in each respective SBR 12', 12".
  • System 10' also includes weighting agent impregnation subsystem 26' which, in this embodiment, is located downstream from sludge storage tank 88'.
  • impregnation tank 28 and mixer 30 receives settled sludge from sludge storage tank 88' by line 100.
  • Impregnation tank 28 also preferably receives virgin weighting agent 33, e.g., from feed hopper 34 by line 36, and/or recycled weighting agent 38 from weighting agent recovery subsystem 74.
  • Mixer 30 mixes the settled sludge and virgin weighting agent 33 and/or the recycled weighting agent 38 in impregnation tank 28 to impregnate the weighting agent into the biological floes suspended in the settled sludge to form weighted biological floes, similarly as discussed with reference to Fig. 1.
  • Weighting agent recovery subsystem 74' also includes weighting agent recovery subsystem 74' which receives the sludge from sludge storage tank 88'.
  • Weighting agent recovery subsystem 74' preferably includes separator 78, which in this embodiment, is located downstream from sludge storage tank 88' and upstream from weighting agent impregnation subsystem 26. Separator 78 recovers the weighting agent from the weighted biological floes in the settled sludge in line 95 from sludge storage tank 88' and reintroduces (recycles) the recovered weighting agent 38 to weighting agent impregnation subsystem 26 via line79.
  • Weighting agent recovery subsystem 74' may include recovery subsystem 83, Fig. 3, e.g., a wet drum magnetic separator or similar type device, which is typically located downstream from separator 78.
  • valve 62 is opened and valve 64 is closed to fill SBR 12' (SBR #1) with influent wastewater 14. Then valve 62 is closed and valve 64 is opened to fill SBR 12" (SBR #2). While SBR 12" is being filled, SBR 12' undergoes the react, settle, and decant phases as discussed above. During or after the decant phase in SBR 12', excess (waste) settled sludge at the bottom of SBR 12' is pumped to sludge storage tank 88' via line 90.
  • Some of the settled sludge in sludge storage tank 88 may be directed via line 100 to weighting agent impregnation tank 28 of weighting agent impregnation subsystem 26' and some of the sludge in sludge storage tank 88 may be directed to separator 78 via line 95.
  • Weighting agent impregnation subsystem 26' impregnates virgin weighting agent 33 and/or recovered weighting agent 38 into the biological floes in the settled sludge in impregnation tank 28 using mixer 30.
  • Weighting agent recovery subsystem 74' then sends the settled sludge having weighted biological floes therein to line 16 via line 76.
  • SBR 12" SBR #2
  • valve 62 is opened and valve 64 is closed so that the mixture of influent wastewater 14 and the settled sludge having weighted biological floes therein is directed to fill SBR 12' (SBR #1).
  • SBR 12" is undergoing the react, settle, and decant phases. Similar, as discussed above, during or after decant phase, some of the settled sludge at the bottom of SBR 12" is pumped to sludge storage tank 88' via line 92.
  • This settled sludge is processed by weighting agent impregnation subsystem 26' as discussed above to form weighted biological floes in the settled sludge in impregnation mixing tank 28.
  • Weighting agent recovery subsystem 74' then directs the settled sludge with the weighted biological floes therein to line 16, as discussed above.
  • Valve 62 is closed and valve 64 is open to fill SBR 12" with the mixture of influent wastewater and settled sludge having weighted biological floes. The process of switching between SBR 12' and SBR 12" continues when ever system 10' is operational.
  • ilocculant 62 may be added to mixed liquor 24 in SBR 12', 12" to enhance settling and thickening of the weighted biological floes suspended in mixed liquor 24 in SBR 12 and establishes
  • the weighted biological floes also provide a cleaner treated effluent, with fewer suspended solids and related contaminants.
  • Coagulant 64 may also be added to SBR 12', 12" for removing phosphorus from mixed liquor 24 by precipitation and/or coagulation, as known by those skilled in the art.
  • Mixer 40 and/or air bubbles 18 may be used to maintain biological floes 23 in suspension in mixed liquor 24 and to mix the ilocculant and/or the coagulant with mixed liquor 24 in SBR 12', 12".
  • weighting agent impregnation subsystem 26' may receive mixed liquor 24 directly from SBR 12' or directly from SBR 12". Similar as discussed above with reference to Fig. 1, weighting agent impregnation tank 28 mixes mixed liquor 24 and virgin weighting agent 33 and/or recovered weighting agent 38 from separator 78 and/or recovery subsystem 83 to impregnate the weighting agent into biological floes suspended in the mixed liquor to form weighted biological floes. The weighted biological floes are then sent back to SBR 12' or to SBR 12".
  • system 10' can impregnate the biological floes either by impregnating the biological floes in the mixed liquor in SBRs 12', 12", or by impregnating the biological floes in the settled sludge output by SBRs 12', 12", or using a combination of both methods.
  • Weighting agent impregnation subsystem 26" includes venturi mixer/eductor 27 having nozzle 31 and funnel 45 which receives virgin weighting agent 33, e.g., from tank 34 by line 36, and/or recycled weighting agent 38 from separator 78 or recovery subsystem 83, Figs. 1 and 3.
  • Venturi mixer/eductor 27 preferably receives mixed liquor by line 32, Fig. 1, or settled sludge by line 77, or settled sludge by line 100, Fig. 3.
  • the velocity of mixed liquor in line 32, Fig. 1, or the settled sludge in line 77, or line 100, Fig. 3, is increased through nozzle 31, Fig. 4.
  • Virgin weighting agent 33 and/or recycled weighting agent 38 in funnel 45 enters nozzle 31 by line 39 and travels downstream to line 37.
  • the widening of line 37 at 41 induces intimate mixing and entrainment, as shown at 43.
  • This impregnates the virgin and/or recycled weighting agent into the biological floes to form weighted biological floes.
  • the weighted biological floes are then returned to SBR 12, Fig. 1, by line 37, or SBR 12', 12", Fig. 3, by lines 76 and 16.
  • separator subsystem 78, Figs. 1 and 3 may be configured as shear mill 112, Fig. 5A, which shears the sludge in line 76, Fig. 1, or line 95, Fig. 3, to separate the weighting agent from the weighted biological floes.
  • Shear mill 112 ideally includes rotor 80 and stator 82.
  • the settled sludge in line 76, Fig. 1 or 95, Fig. 3 enters shear mill 112 and flows in the direction of arrows 180 and enters rotor 80 and then stator 82.
  • Shear mill 112 is designed such that there is a close tolerance between rotor 80, Fig, 5B and stator 82, as shown at 93.
  • Rotor 80 is preferably driven at high rotational speeds, e.g., greater than about 1,000 r.p.m., to form a mixture of weighting agent and obliterated floes in area 181, Fig. 5 A, of shear mill 112.
  • the mixture of weighting agent and obliterated floes exits shear mill 1 12 by line 79, as shown by arrows 184.
  • Fig. 5C shows in further detail the structure of one embodiment of shear mill 112.
  • rotor 80, Figs. 5A-5C, and/or stator 82 includes slots which function as a centrifugal pump to draw the settled sludge from above and below rotor 80 and stator 82, as shown by paths 182, Fig.
  • rotor 80 may include slots 186
  • stator 82 may include slots 188.
  • Slots 186 in rotor 80 and/or slots 188 in stator 82 are preferably optimized to increase shear energy to efficiently separate the weighting agent from the weighted biological floes.
  • the shear developed by rotor 80 and stator 82 depends on the width of slots 186 and 188, the tolerance between rotor 80 and stator 82, and the rotor tip speed. The result is shear mill 112 provides a shearing effect which effectively and efficiently separates the weighting agent from the weighted biological floes to facilitate recovery of the weighting agent.
  • separator subsystem 78 may be configured as ultrasonic separator 116, Fig. 6, where like parts have been given like numbers.
  • Ultrasonic separator 116 typically includes one or more ultrasonic transducers, e.g., ultrasonic transducer 262, 264, 266, 268, and/or 270, available from
  • separator subsystem 78 may be configured as centrifugal separator 118.
  • Centrifugal separator 114 typically includes cylindrical section 302 located at the top of hydrocyclone 300 and conical base 304 located below section 302. The settled sludge in line 76, Fig. 1 or line 100, Fig. 3, is fed tangentially into cylindrical section 302 via port 303. Smaller exit port 306 (underflow or reject port) is located at the bottom of conical section 304 and larger exit port 308 (overflow or accept port) is located at the top of cylindrical section 302.
  • the centrifugal force created by the tangential feed of the sludge by port 303 causes the denser weighting agent to be separated from the biological floes in the settled sludge.
  • the separated weighting agent is expelled against wall 308 of conical section 304 and exits at port 306. This effectively separates the weighting agent from the weighted biological floes.
  • the recovered weighting agent 38 exits via port 306 and may be deposited to weighting agent impregnation system 26, 26', or 26", Figs. 1, 3, and 4.
  • the less dense biological floes remain in the sludge and exit via port 308 through tube 310 extending slightly into the body of the center of centrifugal separator 118.
  • separator subsystem 78 may be configured as a shear mill, an ultrasonic separator, or a centrifugal separator, this is not a necessary limitation of this invention. In other designs, separator subsystem 78 may be configured as a tubular bowl, a chamber bowl, an imperforate basket, a disk stack separator, and the like, as known by those skilled in the art.
  • a wet drum magnetic separator or centrifugal separator 118, Fig. 7 may be used to recover the weighting agent therefrom e.g., recycled weighting agent 38, Figs. 1 and 3, delivered to weighting agent impregnation subsystem 26 by line 79 and/or recycled weighting agent 38, Fig. 7, delivered to weighting agent impregnation subsystem 26 via port 306.
  • separator subsystem 78, Fig. 6, is configured as an ultrasonic separator 116 to create the mixture of weighting agent and obliterated biological floes
  • a wet drum magnetic separator or centrifugal separator 118, Fig. 7 may be used to recover the weighting agent therefrom, e.g., recycled weighting agent 38, Figs. 1 and 3, delivered to weighting agent impregnation subsystem 26 by line 79 and/or recycled weighting agent 38, Fig. 7, delivered to weighting agent
  • System 10, 10', Figs. 1 and 3 may also include wasting subsystem 85 coupled to separator 78 and/or recovery subsystem 85 which wastes the remaining settled sludge output by separator subsystem 78 and/or recovery subsystem 83 to control the population of the microorganisms in mixed liquor 24 in SBR 12, Fig. 1, or SBR 12', 12", Fig. 3.
  • the capacity of system 10, 10', Figs. 1 and 3 to process wastewater 14 may be increased by increasing the concentration of the mixed liquor suspended solids (MLSS) in SBR 12, Fig. 1, or SBR 12', 12", Fig. 3, by reducing the amount of settled sludge wasted by wasting subsystem 85. Increasing the concentration of the MLSS may reduce the duration of the react phase.
  • MLSS mixed liquor suspended solids
  • the amount of settled sludge wasted by wasting subsystem 85 may also be reduced to increase the concentration of MLSS to enhance nitrification and/or de-nitrification of ammonia in mixed liquor 24.
  • the nitrification process may also be further enhanced by increasing the amount of dissolved oxygen introduced to SBR 12, 12', 12" via bubbles 18.

Abstract

A ballasted sequencing batch reactor system for treating wastewater including one or more sequencing batch reactors. A weighting agent impregnation subsystem is configured to mix biological floes and weighting agent to form weighted biological floes. A weighting agent recovery subsystem is configured to recover weighting agent from the weighted biological floes and reintroduce the recovered weighting agent to the weighting agent impregnation subsystem.

Description

BALLASTED SEQUENCING BATCH REACTOR SYSTEM
AND METHOD FOR TREATING WASTEWATER
FIELD OF THE INVENTION
This invention relates to a ballasted sequencing batch reactor (SBR) system and method for treating wastewater.
BACKGROUND OF THE INVENTION SBR systems are used to treat wastewater. A typical conventional SBR system includes one or more SBRs which contain a large population of
microorganisms that ingest contaminants in the influent wastewater to form biological floes and treat the wastewater. SBR systems typically use four phases to treat wastewater: fill, react, settle, and decant. During the fill phase, the SBR is filled with the influent wastewater and may be aerated, mixed without aeration, or not mixed and not aerated. The react phase involves adding oxygen, mixing, or a combination thereof, to provide treatment by converting biochemical oxygen demand (BOD) to microorganisms to form biological floes. During the settle phase, the biological floes formed in the previous phases are allowed settle to the bottom of the SBR to form settled sludge. The decant phase involves slowly decanting the clear water from the settled sludge to provide a treated effluent.
However, during the settling phase of a typical conventional SBR system, the biological floes are only marginally heavier than water and therefore settle very slowly. Moreover, the solids separation in the settle phase may be unreliable due to many types of settling problems that are caused by: overgrowth of filamentous organisms, viscous bulking caused by the overgrowth of either zoogleal organisms or exocellular polysaccharide material, pin floe, straggler floe, and the like. This may limit the capacity of a conventional SBR system and can compromise the quality of the treated effluent.
BRIEF SUMMARY OF THE INVENTION
This invention features a ballasted sequencing batch reactor system for treating wastewater including one or more sequencing batch reactors. A weighting agent impregnation subsystem is configured to mix biological floes and weighting agent to form weighted biological floes. A weighting agent recovery subsystem is configured to recover weighting agent from the weighted biological floes and reintroduce the recovered weighting agent to the weighting agent impregnation subsystem.
In one embodiment, the system may include a sludge storage tank configured to receive settled sludge from the one or more sequencing batch reactors, store the settled sludge therein, and regulate the flow of settled sludge to weighting agent recovery subsystem. The weighting agent recovery subsystem may include a separator subsystem for separating the weighting agent from the weighted biological floes. The separator subsystem may include a shear mill. The separator subsystem may include a centrifugal separator. The separator subsystem may include an ultrasonic separator. The separator subsystem may include a shear mill and a wet drum magnetic separator. The separator subsystem may include a shear mill and a centrifugal separator. The separator subsystem may include an ultrasonic separator and a wet drum magnetic separator. The separator subsystem may include an ultrasonic separator and a centrifugal separator. The shear mill may include rotor and a stator, wherein the rotor and/or the stator include slots sized as to optimize separation of weighting agent from the weighted biological floes. The weighting agent impregnation subsystem may include an impregnation tank and at least one mixer. The capacity of the system may be increased by reducing the duration of a settle phase. The one or more sequencing batch reactors may be configured to decant clear effluent from settled sludge to provide a treated effluent. The weighted biological floes may enhance the quality of the treated effluent by reducing the concentration of suspended solids and related contaminants therein. The system may include a wasting subsystem for wasting settled sludge from the weighting agent recovery subsystem to control a population of microorganisms in a mixed liquor in the one or more sequencing batch reactors. The capacity of the system may be increased by increasing the concentration of the mixed liquor in the one or more sequencing batch reactors by reducing the amount of settled sludge wasted by a wasting subsystem. The capacity of the system may be increased by reducing the duration of a react phase. The amount of settled sludge wasted by the wasting subsystem may be reduced to increase the concentration of mixed liquor suspended solids for enhancing nitrification and/or de-nitrification of ammonia in the mixed liquid. Nitrification may be enhanced by increasing the amount of dissolved oxygen introduced into the one or more sequencing batch reactors. A coagulant may be added to the one or more sequencing batch reactors for removing phosphorus by precipitation and/or coagulation. A flocculant may be added to the one or more sequencing batch reactors for enhancing settling and thickening of the weighted biological floes and for providing agglomeration of non-impregnated biological floes and/or partially impregnated biological floes with weighted biological floes. The weighting agent impregnation subsystem may include a venturi mixer/eductor. A majority of the weighting agent may have a particle size less than about 100 μηι. A majority of the weighting agent may have a particle size less than about 40 μηι. A majority of the weighting agent may have a particle size less than about 20 μιη. The weighting agent may include magnetite. The system may include a mixer disposed in each of the one or more sequencing batch reactors for maintaining the suspended solids or the mixed liquor in suspension.
This invention also features a method for treating wastewater using one or more sequencing batch reactors, the method including the steps of: a) receiving influent wastewater in the one or more sequencing batch reactors, b) forming biological floes in the one or more sequencing batch reactors, c) impregnating weighting agent into the biological floes to form weighted biological floes, and d) recovering weighting agent from the weighted biological floes to reintroduce the weighting agent to step c).
In one embodiment, the method may include the step of separating the weighting agent from the weighted biological floes. The method may include the step of collecting the weighting agent and recycling the weighting agent to step c). The method may include the step of providing weighting agent in which the majority of the weighting agent has a particle size less than about 100 μηι. The method may include the step of providing weighting agent in which the majority of the weighting agent has a particle size less than about 40 μηι. The method may include the step of providing weighting agent in which the majority of the weighting agent has a particle size less than about 20 μπι. The method may include the step of introducing dissolved oxygen to a population of microorganisms to promote growth of biological floes in a mixed liquor defined by a concentration of mixed liquor suspended solids. The method may include the step of introducing a flocculant to the mixed liquor to enhance settling and thickening of the weighted biological floes and to establish agglomeration of non-impregnated biological floes and/or partially impregnated biological floes with the weighted biological floes. The method may include the step of separating and collecting the weighted biological floes from the mixed liquor in the one or more sequencing batch reactors to provide a secondary effluent and a settled sludge. The method may include the step of recycling the majority of the settled sludge to step b). The method may include the step of decanting the clean effluent from the settled sludge in the one or more sequencing batch reactors to provide a treated effluent. The method may include the step of wasting the remaining settled sludge using a wasting subsystem to control the population of the microorganisms in the mixed liquor. The method may include the step of increasing the capacity of the system by reducing the duration of a settle phase. The method may include the step of enhancing the quality of the treated effluent by reducing suspended solids and related- contaminants therein. The method may include the step of wasting settled sludge from the weighting agent recovery subsystem to control a population of microorganisms in a mixed liquor in the one or more sequencing batch reactors. The method may include the step of increasing the capacity of the system by increasing the concentration of the mixed liquor in the one or more sequencing batch reactors by reducing the amount of settled sludge wasted by a wasting subsystem. The method may include the step of increasing the capacity of the system by reducing the duration of a react phase. The method may include the step of reducing the amount of settled sludge wasted by the wasting subsystem to increase the concentration of mixed liquor suspended solids which enhances nitrification and/or de-nitrification of ammonia in the mixed liquid. The method may include the step of enhancing nitrification by increasing the amount of dissolved oxygen introduced into the one or more sequencing batch reactors. The weighting agent may be impregnated into the biological floes in step b) by mixing the mixed liquor and the biological floes at a predetermined energy level.
The subject invention, however, in other embodiments, need not achieve all these objectives and the claims hereof should not be limited to structures or methods capable of achieving these objectives.
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
Other objects, features and advantages will occur to those skilled in the art from the following description of a preferred embodiment and the accompanying drawings, in which:
Fig. 1 is a schematic block diagram of one embodiment of the SBR system for treating wastewater in accordance with this invention;
Fig. 2 is a microscopic view showing one example of weighting agent impregnated in biological floes using the weighting agent impregnation system shown in Fig. 1;
Fig. 3 is a schematic block diagram showing another embodiment of the SBR system for treating wastewater of this invention;
Fig. 4 is a schematic side-view of another embodiment of the impregnation subsystem shown in Figs. 1 and 3;
Fig. 5A is a schematic side-view of one embodiment of the separator shown in Figs. 1 and 3;
Fig. 5B is a schematic top view showing one example of slots in the rotor and stator of the shear mill shown in Fig. 5 A;
Fig. 5C is a three-dimensional view of one embodiment of the shear mill in Fig. 5A;
Fig. 6 is a three-dimensional front- view of another embodiment of the separator shown in Figs. 1 and 3; and
Fig. 7 is a three-dimensional front- view of yet another embodiment of the separator shown in Fig. 1.
DETAILED DESCRIPTION OF THE INVENTION
Aside from the preferred embodiment or embodiments disclosed below, this invention is capable of other embodiments and of being practiced or being carried out in various ways. Thus, it is to be understood that the invention is not limited in its application to the details of construction and the arrangements of components set forth in the following description or illustrated in the drawings. If only one embodiment is described herein, the claims hereof are not to be limited to that embodiment.
Moreover, the claims hereof are not to be read restrictively unless there is clear and convincing evidence manifesting a certain exclusion, restriction, or disclaimer.
There is shown in Fig. 1, one embodiment of SBR system 10 for treating wastewater of this invention. System 10 includes at least one SBR 12 which receives a flow of influent wastewater 14 by line 16. SBR 12 preferably introduces air bubbles 18 by line 20 exposed to ambient air 22. Air bubbles 18 introduce dissolved oxygen to a population of microorganisms in SBR 12 to promote growth of biological fiocs
23 in mixed liquor 24. Mixed liquor 24 as used herein means a combination of influent wastewater 14 and biological floes 23.
System 10 also includes weighting agent impregnation subsystem 26 which, in one embodiment, includes impregnation tank 28 and mixer 30 which receives mixed liquor 24 from SBR 12 by line 32. In one embodiment, impregnation tank 28 preferably receives virgin weighting agent 33, e.g., from feed hopper 34 by line 36, and/or recycled weighting agent 38 from weighting agent recovery subsystem 74 (discussed below). Weighting agent impregnation subsystem 26 mixes mixed liquor
24 or settled sludge received by line 77 and virgin weighting agent 33 and/or the recycled weighting agent 38 in impregnation tank 28 to impregnate the weighting agent into biological floes 23 suspended in mixed liquor 24 or settled sludge by line 77 via sludge storage tank 88 and line 76 and/or via lines 76 and 81 to form weighted biological floes. Mixer 30 utilizes a mixing energy which is sufficient to impregnate the weighting agent into biological floes suspended in a mixed liquor to form weighted biological floes. Fig. 2 shows one example of weighting agent 33, 38 impregnated into biological floes 23 to form weighted biological floes 25. The weighted biological floes impregnated with the weighting agent are then sent back to SBR 12, Fig. 1, by line 37. The weighting agent may be magnetite, or any similar type weighting agent or magnetically separable inorganic material known to those skilled in the art which increases the density of the biological floes. In one example, the majority of the weighting agent particles may have a size less than about 100 μηι. In other examples, the majority of the weighting agent particles may have a size less than about 40 μιη, or, the majority of the weighting agent may have a particle size less than about 20 μιη.
System 10 also includes weighting agent recovery subsystem 74 which receives settled sludge from bottom 39 of SBR 12 by line 76 typically after the settle and decant phases are complete. Weighting agent recovery subsystem 74 preferably includes separator 78 which recovers the weighting agent from the weighted biological floes in the settled sludge in line 76 and reintroduces (recycles) the weighting agent to weighting agent impregnation subsystem 26 by line 79. Weighting agent recovery subsystem 74 may include recovery subsystem 83, discussed below.
In one embodiment, system 10 includes sludge storage tank 88 which stores settled sludge output from SBR 12 by line 76 typically after the decant phase is complete.
In one exemplary operation of SBR system 10, SBR 12 is filled with influent wastewater 14 via line 16 and seeded with a large population of microorganisms that ingest contaminants in influent wastewater 14 to form biological floes 23. During a fill phase, dissolved oxygen via air bubbles 18 may be introduced to mixed liquor 24 to promote growth of biological floes 23. Once filled, system 10 undergoes a react phase. During the fill and/or react phases, weighting agent impregnation subsystem 26 receives the mixed liquor by line 32, or settled sludge by line 77 via sludge storage tank 88 and line 76 and/or via lines 76 and 81, and impregnates the biological floes therein with virgin weighting agent 33 and/or recycled weighting agent 38 using mixer 30. The mixed liquor or settled sludge having weighted biological floes is then sent back to SBR 12 by line 37. The react phase is followed by the settling phase where the weighted biological floes settle to bottom 39 of SBR 12 to form settled sludge. The times for the fill, react, settle, and decant phases vary as known by those skilled in the art. Then, the clear effluent is decanted by line 52 to provide treated effluent 50. During or after the decant phase, some of the settled sludge at bottom 39 of SBR 12 may be sent to sludge storage tank 88 via line 76. Sludge storage tank 88 stores sludge from SBR 12 and regulates the flow thereof to weighting agent recovery subsystem 74. Weighting agent recovery subsystem 74 then recovers the weighting agent from the weighted biological floes as discussed above and recycles the weighting agent to weighting agent impregnation subsystem 26 as recovered weighting agent 38.
Because the weighted biological floes in SBR 12 have a greater specific gravity than non-impregnated biological floes, they settle faster than non-impregnated biological floes utilized in a typical conventional SBR system. Thus, the time needed for the settling phase of system 10 is reduced. This alleviates settling problems associated with a conventional SBR system, such as overgrowth of filamentous organisms, viscous bulking caused by the overgrowth of either zoogleal organisms or exocellular polysaccharide material, pin floe, straggler floe, and the like. The result is the capacity of system 10 to treat wastewater may be increased while providing high quality treated effluent 50. Because the time needed in the settling phase is reduced, system 10 may also allow more time for the react phase, which further increases the quality of treated effluent 50. The weighted biological floes also enhance the quality of the treated effluent by reducing the concentration of suspended solids and related contaminants therein. The weighted biological floes also facilitate higher mixed liquor suspended solids (MLSS) concentrations. Operating at higher MLSS concentrations provides additional advantages, including additional increased treatment capacity, enhanced nitrogen removal, enhanced phosphorus removal, and the like. Moreover, because weighting agent recovery subsystem 74 recovers and recycles the weighting agent, the operational costs of system 10 are significantly reduced.
System 10', Fig. 3, where like parts have been given like numbers, includes at least two SBRs 12' and 12". In this example, SBR 12' is filled with influent wastewater 14 by line 16 by opening valve 62 and closing valve 64. Once SBR 12' is filled, valve 62 is closed and valve 64 is open. SBR 12" is then similarly filled with influent wastewater 14. Thus, system 10' allows a continuous flow of influent wastewater 14 to either SBR 12' or SBR 12" for continuous operation. System 10 is not limited to two SBRs, as any number of SBRs may be utilized to accommodate the flow rate of influent wastewater 14. In one example, after SBR 12' is filled and SBR 12" is in the fill phase, SBR 12' undergoes the react, settle, and decant phases.
Similarly, when SBR 12' is in the fill phase, SBR 12" typically undergoes the react, settle, and decant phases.
System 10' may include sludge storage tank 88' which receives some of the settled sludge from SBR 12' via line 90 and some of the settled sludge from SBR 12" via line 92 during or after the decant phase in each respective SBR 12', 12".
System 10' also includes weighting agent impregnation subsystem 26' which, in this embodiment, is located downstream from sludge storage tank 88'. In this example, impregnation tank 28 and mixer 30 receives settled sludge from sludge storage tank 88' by line 100. Impregnation tank 28 also preferably receives virgin weighting agent 33, e.g., from feed hopper 34 by line 36, and/or recycled weighting agent 38 from weighting agent recovery subsystem 74. Mixer 30 mixes the settled sludge and virgin weighting agent 33 and/or the recycled weighting agent 38 in impregnation tank 28 to impregnate the weighting agent into the biological floes suspended in the settled sludge to form weighted biological floes, similarly as discussed with reference to Fig. 1.
System 10', Fig.3, also includes weighting agent recovery subsystem 74' which receives the sludge from sludge storage tank 88'. Weighting agent recovery subsystem 74' preferably includes separator 78, which in this embodiment, is located downstream from sludge storage tank 88' and upstream from weighting agent impregnation subsystem 26. Separator 78 recovers the weighting agent from the weighted biological floes in the settled sludge in line 95 from sludge storage tank 88' and reintroduces (recycles) the recovered weighting agent 38 to weighting agent impregnation subsystem 26 via line79. Weighting agent recovery subsystem 74' may include recovery subsystem 83, Fig. 3, e.g., a wet drum magnetic separator or similar type device, which is typically located downstream from separator 78.
In one exemplary operation of system 10', valve 62 is opened and valve 64 is closed to fill SBR 12' (SBR #1) with influent wastewater 14. Then valve 62 is closed and valve 64 is opened to fill SBR 12" (SBR #2). While SBR 12" is being filled, SBR 12' undergoes the react, settle, and decant phases as discussed above. During or after the decant phase in SBR 12', excess (waste) settled sludge at the bottom of SBR 12' is pumped to sludge storage tank 88' via line 90. Some of the settled sludge in sludge storage tank 88 may be directed via line 100 to weighting agent impregnation tank 28 of weighting agent impregnation subsystem 26' and some of the sludge in sludge storage tank 88 may be directed to separator 78 via line 95. Weighting agent impregnation subsystem 26' impregnates virgin weighting agent 33 and/or recovered weighting agent 38 into the biological floes in the settled sludge in impregnation tank 28 using mixer 30.
Weighting agent recovery subsystem 74' then sends the settled sludge having weighted biological floes therein to line 16 via line 76. At this point, SBR 12" (SBR #2) has been filled so valve 62 is opened and valve 64 is closed so that the mixture of influent wastewater 14 and the settled sludge having weighted biological floes therein is directed to fill SBR 12' (SBR #1). At this point, SBR 12" is undergoing the react, settle, and decant phases. Similar, as discussed above, during or after decant phase, some of the settled sludge at the bottom of SBR 12" is pumped to sludge storage tank 88' via line 92. This settled sludge is processed by weighting agent impregnation subsystem 26' as discussed above to form weighted biological floes in the settled sludge in impregnation mixing tank 28. Weighting agent recovery subsystem 74' then directs the settled sludge with the weighted biological floes therein to line 16, as discussed above. Valve 62 is closed and valve 64 is open to fill SBR 12" with the mixture of influent wastewater and settled sludge having weighted biological floes. The process of switching between SBR 12' and SBR 12" continues when ever system 10' is operational.
Similar as discussed above, the weighted biological floes introduced to mixed liquor 24 in SBRs 12', 12" settle faster to reduce the time needed for their respective settling phases. This increases the capacity system 10' to treat wastewater and alleviates the problems associated with conventional SBR systems discussed above and provides a cleaner treated effluent 50', 50".
Similar as discussed above, ilocculant 62, Fig. 3, may be added to mixed liquor 24 in SBR 12', 12" to enhance settling and thickening of the weighted biological floes suspended in mixed liquor 24 in SBR 12 and establishes
agglomeration of non-impregnated biological floes and/or partially impregnated biological floes with the weighted biological floes in SBR 12', 12". The weighted biological floes also provide a cleaner treated effluent, with fewer suspended solids and related contaminants.
Coagulant 64 may also be added to SBR 12', 12" for removing phosphorus from mixed liquor 24 by precipitation and/or coagulation, as known by those skilled in the art. Mixer 40 and/or air bubbles 18 may be used to maintain biological floes 23 in suspension in mixed liquor 24 and to mix the ilocculant and/or the coagulant with mixed liquor 24 in SBR 12', 12".
In another embodiment, weighting agent impregnation subsystem 26' may receive mixed liquor 24 directly from SBR 12' or directly from SBR 12". Similar as discussed above with reference to Fig. 1, weighting agent impregnation tank 28 mixes mixed liquor 24 and virgin weighting agent 33 and/or recovered weighting agent 38 from separator 78 and/or recovery subsystem 83 to impregnate the weighting agent into biological floes suspended in the mixed liquor to form weighted biological floes. The weighted biological floes are then sent back to SBR 12' or to SBR 12".
Thus, system 10' can impregnate the biological floes either by impregnating the biological floes in the mixed liquor in SBRs 12', 12", or by impregnating the biological floes in the settled sludge output by SBRs 12', 12", or using a combination of both methods.
System 10, Fig. 1, and/or system 10', Fig. 3, may also utilize weighting agent impregnation subsystem 26", Fig. 4, where like parts have been given like numbers. Weighting agent impregnation subsystem 26" includes venturi mixer/eductor 27 having nozzle 31 and funnel 45 which receives virgin weighting agent 33, e.g., from tank 34 by line 36, and/or recycled weighting agent 38 from separator 78 or recovery subsystem 83, Figs. 1 and 3. Venturi mixer/eductor 27 preferably receives mixed liquor by line 32, Fig. 1, or settled sludge by line 77, or settled sludge by line 100, Fig. 3.
In operation, the velocity of mixed liquor in line 32, Fig. 1, or the settled sludge in line 77, or line 100, Fig. 3, is increased through nozzle 31, Fig. 4. Virgin weighting agent 33 and/or recycled weighting agent 38 in funnel 45 enters nozzle 31 by line 39 and travels downstream to line 37. The widening of line 37 at 41 induces intimate mixing and entrainment, as shown at 43. This impregnates the virgin and/or recycled weighting agent into the biological floes to form weighted biological floes. The weighted biological floes are then returned to SBR 12, Fig. 1, by line 37, or SBR 12', 12", Fig. 3, by lines 76 and 16.
In one design, separator subsystem 78, Figs. 1 and 3 may be configured as shear mill 112, Fig. 5A, which shears the sludge in line 76, Fig. 1, or line 95, Fig. 3, to separate the weighting agent from the weighted biological floes. Shear mill 112 ideally includes rotor 80 and stator 82. In operation, the settled sludge in line 76, Fig. 1 or 95, Fig. 3, enters shear mill 112 and flows in the direction of arrows 180 and enters rotor 80 and then stator 82. Shear mill 112 is designed such that there is a close tolerance between rotor 80, Fig, 5B and stator 82, as shown at 93. Rotor 80 is preferably driven at high rotational speeds, e.g., greater than about 1,000 r.p.m., to form a mixture of weighting agent and obliterated floes in area 181, Fig. 5 A, of shear mill 112. The mixture of weighting agent and obliterated floes exits shear mill 1 12 by line 79, as shown by arrows 184. Fig. 5C shows in further detail the structure of one embodiment of shear mill 112. Preferably, rotor 80, Figs. 5A-5C, and/or stator 82 includes slots which function as a centrifugal pump to draw the settled sludge from above and below rotor 80 and stator 82, as shown by paths 182, Fig. 5 A, and then hurl the materials off the slot tips at a very high speed to break the weighted biological floes into the mixture of weighting agent and obliterated floes. For example, rotor 80, Fig. 5B, may include slots 186, and stator 82 may include slots 188. Slots 186 in rotor 80 and/or slots 188 in stator 82 are preferably optimized to increase shear energy to efficiently separate the weighting agent from the weighted biological floes. The shear developed by rotor 80 and stator 82 depends on the width of slots 186 and 188, the tolerance between rotor 80 and stator 82, and the rotor tip speed. The result is shear mill 112 provides a shearing effect which effectively and efficiently separates the weighting agent from the weighted biological floes to facilitate recovery of the weighting agent.
In another design, separator subsystem 78, Figs. 1 and 3, may be configured as ultrasonic separator 116, Fig. 6, where like parts have been given like numbers.
Ultrasonic separator 116 typically includes one or more ultrasonic transducers, e.g., ultrasonic transducer 262, 264, 266, 268, and/or 270, available from
Hielscher Ultrasonics GmbH, Stuttgart, Germany, which generates fluctuations of pressure and cavitation in the settled sludge in line 76, Fig. 1 or line 95, Fig. 3. This results in microturbulences that produce a shearing effect, to create a mixture of weighting agent and obliterated floes to effectively separate the weighting agent from the weighted biological floes in the settled sludge. The resulting mixture of weighting agent and obliterated floes exits ultrasonic separator 1 16 by line 79.
In yet another design, separator subsystem 78, Fig. 7, where like parts have been given like numbers, may be configured as centrifugal separator 118. Centrifugal separator 114 typically includes cylindrical section 302 located at the top of hydrocyclone 300 and conical base 304 located below section 302. The settled sludge in line 76, Fig. 1 or line 100, Fig. 3, is fed tangentially into cylindrical section 302 via port 303. Smaller exit port 306 (underflow or reject port) is located at the bottom of conical section 304 and larger exit port 308 (overflow or accept port) is located at the top of cylindrical section 302.
In operation, the centrifugal force created by the tangential feed of the sludge by port 303 causes the denser weighting agent to be separated from the biological floes in the settled sludge. The separated weighting agent is expelled against wall 308 of conical section 304 and exits at port 306. This effectively separates the weighting agent from the weighted biological floes. The recovered weighting agent 38 exits via port 306 and may be deposited to weighting agent impregnation system 26, 26', or 26", Figs. 1, 3, and 4. The less dense biological floes remain in the sludge and exit via port 308 through tube 310 extending slightly into the body of the center of centrifugal separator 118.
Although as discussed above, separator subsystem 78 may be configured as a shear mill, an ultrasonic separator, or a centrifugal separator, this is not a necessary limitation of this invention. In other designs, separator subsystem 78 may be configured as a tubular bowl, a chamber bowl, an imperforate basket, a disk stack separator, and the like, as known by those skilled in the art.
In the example above where a separator 78, Figs. 5A-5C, is configured as shear mill 112 to create the mixture of weighting agent and obliterated biological floes, a wet drum magnetic separator or centrifugal separator 118, Fig. 7, may be used to recover the weighting agent therefrom e.g., recycled weighting agent 38, Figs. 1 and 3, delivered to weighting agent impregnation subsystem 26 by line 79 and/or recycled weighting agent 38, Fig. 7, delivered to weighting agent impregnation subsystem 26 via port 306.
In the example where separator subsystem 78, Fig. 6, is configured as an ultrasonic separator 116 to create the mixture of weighting agent and obliterated biological floes, a wet drum magnetic separator or centrifugal separator 118, Fig. 7, may be used to recover the weighting agent therefrom, e.g., recycled weighting agent 38, Figs. 1 and 3, delivered to weighting agent impregnation subsystem 26 by line 79 and/or recycled weighting agent 38, Fig. 7, delivered to weighting agent
impregnation subsystem 26 via port 306.
The result of recovering and recycling the weighting agent as discussed above with reference to Figs. 5A-7 significantly reduces the operating costs of wastewater treatment system 10.
System 10, 10', Figs. 1 and 3, may also include wasting subsystem 85 coupled to separator 78 and/or recovery subsystem 85 which wastes the remaining settled sludge output by separator subsystem 78 and/or recovery subsystem 83 to control the population of the microorganisms in mixed liquor 24 in SBR 12, Fig. 1, or SBR 12', 12", Fig. 3. The capacity of system 10, 10', Figs. 1 and 3 to process wastewater 14 may be increased by increasing the concentration of the mixed liquor suspended solids (MLSS) in SBR 12, Fig. 1, or SBR 12', 12", Fig. 3, by reducing the amount of settled sludge wasted by wasting subsystem 85. Increasing the concentration of the MLSS may reduce the duration of the react phase. The amount of settled sludge wasted by wasting subsystem 85 may also be reduced to increase the concentration of MLSS to enhance nitrification and/or de-nitrification of ammonia in mixed liquor 24. The nitrification process may also be further enhanced by increasing the amount of dissolved oxygen introduced to SBR 12, 12', 12" via bubbles 18.
Aside from the preferred embodiment or embodiments disclosed below, this invention is capable of other embodiments and of being practiced or being carried out in various ways. Thus, it is to be understood that the invention is not limited in its application to the details of construction and the arrangements of components set forth in the following description or illustrated in the drawings. If only one embodiment is described herein, the claims hereof are not to be limited to that embodiment.
Moreover, the claims hereof are not to be read restrictively unless there is clear and convincing evidence manifesting a certain exclusion, restriction, or disclaimer.
Although specific features of the invention are shown in some drawings and not in others, this is for convenience only as each feature may be combined with any or all of the other features in accordance with the invention. The words "including", "comprising", "having", and "with" as used herein are to be interpreted broadly and comprehensively and are not limited to any physical interconnection. Moreover, any embodiments disclosed in the subject application are not to be taken as the only possible embodiments. Other embodiments will occur to those skilled in the art and are within the following claims.
In addition, any amendment presented during the prosecution of the patent application for this patent is not a disclaimer of any claim element presented in the application as filed: those skilled in the art cannot reasonably be expected to draft a claim that would literally encompass all possible equivalents, many equivalents will be unforeseeable at the time of the amendment and are beyond a fair interpretation of what is to be surrendered (if anything), the rationale underlying the amendment may bear no more than a tangential relation to many equivalents, and/or there are many other reasons the applicant cannot be expected to describe certain insubstantial substitutes for any claim element amended.
What is claimed is:

Claims

1. A ballasted sequencing batch reactor system for treating wastewater comprising:
one or more sequencing batch reactors;
a weighting agent impregnation subsystem configured to mix biological floes and weighting agent to form weighted biological floes;
a weighting agent recovery subsystem configured to recover weighting agent from the weighted biological floes and reintroduce the recovered weighting agent to the weighting agent impregnation subsystem.
2. The system of claim 1 further including a sludge storage tank configured to receive settled sludge from the one or more sequencing batch reactors, store the settled sludge therein, and regulate the flow of settled sludge to weighting agent recovery subsystem.
3. The system of claim 1 in which the weighting agent recovery subsystem includes a separator subsystem for separating the weighting agent from the weighted biological floes.
4. The system of claim 3 in which the separator subsystem includes a shear mill.
5. The system of claim 3 in which the separator subsystem includes a centrifugal separator.
6. The system of claim 3 in which the separator subsystem includes an ultrasonic separator.
7. The system of claim 3 in which the separator subsystem includes a shear mill and a wet drum magnetic separator.
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8. The system of claim 3 in which the separator subsystem includes a shear mill and a centrifugal separator.
9. The system of claim 3 in which the separator subsystem includes an ultrasonic separator and a wet drum magnetic separator.
10. The system of claim 3 in which the separator subsystem includes an ultrasonic separator and a centrifugal separator.
11. The system of claim 4 in which the shear mill includes a rotor and a stator, wherein the rotor and/or the stator include slots sized as to optimize separation of weighting agent from the weighted biological floes.
12. The system of claim 1 in which the weighting agent impregnation subsystem includes an impregnation tank and at least one mixer.
13. The system of claim 1 in which the capacity of the system is increased by reducing the duration of a settle phase.
14. The system of claim 1 in which the one or more sequencing batch reactors are configured to decant clear effluent from settled sludge to provide a treated effluent.
15. The system of claim 14 in which the weighted biological floes enhance the quality of the treated effluent by reducing the concentration of suspended solids and related contaminants therein.
16. The system of claim 1 further including a wasting subsystem for wasting settled sludge from the weighting agent recovery subsystem to control a population of microorganisms in a mixed liquor in the one or more sequencing batch reactors.
17. The system of claim 16 in which the capacity of the system is increased by increasing the concentration of the mixed liquor in the one or more sequencing batch reactors by reducing the amount of settled sludge wasted by a wasting subsystem.
18. The system of claim 17 in which the capacity of the system is increased by reducing the duration of a react phase.
19. The system of claim 17 in which the amount of settled sludge wasted by the wasting subsystem is reduced to increase the concentration of mixed liquor suspended solids for enhancing nitrification and/or de-nitrification of ammonia in the mixed liquid.
20. The system of claim 19 in which nitrification is enhanced by increasing the amount of dissolved oxygen introduced into the one or more sequencing batch reactors.
21. The system of claim 1 in which a coagulant is added to the one or more sequencing batch reactors for removing phosphorus by precipitation and/or coagulation.
22. The system of claim 1 in which a flocculant is added to the one or more sequencing batch reactors for enhancing settling and thickening of the weighted biological floes and for providing agglomeration of non-impregnated biological floes and/or partially impregnated biological floes with weighted biological floes.
23. The system of claim 1 in which the weighting agent impregnation subsystem includes a venturi mixer/eductor.
24. The system of claim 1 in which a majority of the weighting agent has a particle size less than about 100 μιη.
25. The system of claim 1 in which a majority of the weighting agent has a particle size less than about 40 μπι.
26. The system of claim 1 in which a majority of the weighting agent has a particle size less than about 20 μπι.
27. The system of claim 1 in which the weighting agent includes magnetite.
28. The system of claim 1 further including a mixer disposed in each of the one or more sequencing batch reactors for maintaining the suspended solids or the mixed liquor in suspension.
29. A method for treating wastewater using one or more sequencing batch reactors, the method comprising:
a) receiving influent wastewater in the one or more sequencing batch reactors;
b) forming biological floes in the one or more sequencing batch reactors;
c) impregnating weighting agent into the biological floes to form weighted biological floes; and
d) recovering weighting agent from the weighted biological floes to reintroduce the weighting agent to step c).
30. The method of claim 29 further including the step of separating the weighting agent from the weighted biological floes.
31. The method of claim 29 further including the step of collecting the weighting agent and recycling the weighting agent to step c).
32. The method of claim 29 further including the step of providing weighting agent in which the majority of the weightmg agent has a particle size less than about 100 μπι.
33. The method of claim 29 further including the step of providing weighting agent in which the majority of the weighting agent has a particle size less than about 40 μηι.
34. The method of claim 29 further including the step of providing weighting agent in which the majority of the weighting agent has a particle size less than about 20 μιη.
35. The method of claim 29 further including the step of introducing dissolved oxygen to a population of microorganisms to promote growth of biological floes in a mixed liquor defined by a concentration of mixed liquor suspended solids.
36. The method of claim 35 further including the step of introducing a flocculant to the mixed liquor to enhance settling and thickening of the weighted biological floes and to establish agglomeration of non-impregnated biological floes and/or partially impregnated biological floes with the weighted biological floes.
37. The method of claim 35 further including the step of separating and collecting the weighted biological floes from the mixed liquor in the one or more sequencing batch reactors to provide a secondary effluent and a settled sludge.
38. The method of claim 37 further including the step of recycling the majority of the settled sludge to step b).
39. The method of claim 37 further including the step of decanting the clean effluent from the settled sludge in the one or more sequencing batch reactors to provide a treated effluent.
40. The method of claim 37 further including the step of wasting the remaining settled sludge using a wasting subsystem to control the population of the microorganisms in the mixed liquor.
41. The method of claim 29 further including the step of increasing the capacity of the system by reducing the duration of a settle phase.
42. The method of claim 39 further including the step of enhancing the quality of the treated effluent by reducing the concentration of suspended solids and related contaminants therein.
43. The method of claim 27 further including the step of wasting settled sludge from the weighting agent recovery subsystem to control a population of microorganisms in a mixed liquor in the one or more sequencing batch reactors.
44. The method of claim 43 further including the step of increasing the capacity of the system by increasing the concentration of the mixed liquor in the one or more sequencing batch reactors by reducing the amount of settled sludge wasted by a wasting subsystem.
45. The method of claim 44 further including the step of increasing the capacity of the system by reducing the duration of a react phase.
46. The method of claim 43 further including the step of reducing the amount of settled sludge wasted by the wasting subsystem to increase the
concentration of mixed liquor suspended solids which enhances nitrification and/or de-nitrification of ammonia in the mixed liquid.
47. The method of claim 35 further including the step of enhancing nitrification by increasing the amount of dissolved oxygen introduced into the one or more sequencing batch reactors.
48. The method of claim 29 in which the weighting agent is impregnated into the biological floes in step b) by mixing the mixed liquor and the biological floes at a predetermined energy level.
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US8540877B2 (en) 2013-09-24
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US10023486B2 (en) 2018-07-17
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