WO2011079527A1 - Solar collecting panel of composite ceramic material and solar fluted air duct - Google Patents

Solar collecting panel of composite ceramic material and solar fluted air duct Download PDF

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Publication number
WO2011079527A1
WO2011079527A1 PCT/CN2010/002247 CN2010002247W WO2011079527A1 WO 2011079527 A1 WO2011079527 A1 WO 2011079527A1 CN 2010002247 W CN2010002247 W CN 2010002247W WO 2011079527 A1 WO2011079527 A1 WO 2011079527A1
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WO
WIPO (PCT)
Prior art keywords
plate
composite ceramic
heat collecting
ceramic solar
solar heat
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PCT/CN2010/002247
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French (fr)
Chinese (zh)
Inventor
曹树梁
许建华
蔡滨
王启春
石延岭
许建丽
杨玉国
修大鹏
谷胜利
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山东天虹弧板有限公司
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Application filed by 山东天虹弧板有限公司 filed Critical 山东天虹弧板有限公司
Publication of WO2011079527A1 publication Critical patent/WO2011079527A1/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S70/00Details of absorbing elements
    • F24S70/30Auxiliary coatings, e.g. anti-reflective coatings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00Integration of renewable energy sources in buildings
    • Y02B10/20Solar thermal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/40Solar thermal energy, e.g. solar towers

Definitions

  • the invention relates to a solar energy utilization technology, and is a composite ceramic solar heat collecting plate and a solar trough air duct. Specifically, it is a low-cost, long-life, solid-state ceramic solid plate or a common ceramic solid groove plate made of industrial waste, natural minerals and common ceramic raw materials rich in the fourth-period transition metal element.
  • the heat collecting plate generates a hot air by using a solar trough air duct manufactured by a solar heat collecting plate.
  • the hot air supplies heat to the building or is used to heat the air on a large scale on the slopes and deserts, and drives the turbine to generate electricity by the rising hot air flow.
  • the solar greenhouse chimney power generation system is mainly composed of a chimney, a greenhouse and a generator and an energy storage device.
  • the greenhouse is the same as the ordinary cultivated greenhouse, and the air heated by the greenhouse flows through the chimney in the center of the greenhouse to generate an air flow, which drives the air turbine to drive the generator. Power generation.
  • the "solar greenhouse chimney” has a large investment, the hot air temperature obtained by heating the greenhouse is relatively low, and the power generation system is not efficient.
  • Another black ceramic surface layer of the composite ceramic solar hollow heat collecting plate absorbs sunlight energy, heats the air in the cavity of the hollow plate, and uses the heat energy of the hot air and the kinetic energy of the hot air to provide heat energy to the building or drive the air turbine. Drive the generator to generate electricity.
  • composite ceramic solar hollow panels to make solar air ducts has many advantages, but it has been found through trial and error and continuous research by the inventors that it still lacks: When building ceramic solar wind tunnels in desert areas, it is necessary to build large-scale solar winds. Road, composite ceramic solar hollow board is limited by the ceramic production process. The height and width of the tunnel are generally between 20 and 50 mm, which cannot meet the requirements. The manufacturing process of manufacturing large-channel composite ceramic solar hollow board is very complicated and difficult in process. At the same time, the composite ceramic solar hollow plate has a large heat capacity, and absorbs a large amount of heat energy in the solar air channel, thereby consuming energy in the solar air channel and affecting the wind power of the solar air channel. The above-mentioned deficiencies make the production cost of the solar air duct relatively high, and the technical implementation scheme is quite complicated and low in efficiency.
  • One of the present inventions 1 provides a composite ceramic solar heat collecting plate, and the second object of the present invention is to provide A composite ceramic solar trough air duct, which can solve the deficiencies in the prior art, greatly reduce the manufacturing cost of the solar air duct, and make the solar air duct have a long service life and high efficiency.
  • a composite ceramic solar collector plate having a rectangular shape, the base of which is a solid ceramic solid plate, and a flat surface of a common ceramic solid plate covered with a sintered black porcelain layer.
  • the ordinary ceramic solid plate and the black ceramic layer sintered on the surface constitute a composite ceramic solar heat collecting solid plate.
  • the black ceramic layer covered by the ordinary ceramic solid plate is a vanadium titanium black porcelain layer with a rough surface, covered with tiny holes or black slag.
  • the layer is either a mineral black porcelain layer.
  • the composite ceramic solar collector solid plate has side plates on both sides in the longitudinal direction, and the composite ceramic solar heat collecting solid plate is integrated with the side plates on both sides in the longitudinal direction thereof, and the cross section is groove-shaped, and the composite ceramic solar heat collecting solid plate is integrated. And the side plates on both sides in the longitudinal direction thereof constitute a composite ceramic solar heat collecting solid groove plate. 5 ⁇ The thickness of the thickness of the ceramic layer is 0. 05-0. 5 mm.
  • the method for preparing the composite ceramic solar heat collecting plate comprises covering the vanadium tailings or other industrial wastes other than the vanadium tailings or the mixed slurry of the industrial minerals and the ceramic raw materials in a conventional ceramic forming method.
  • One side of the ceramic plate blank is dried and fired to form a base ceramic which is a common ceramic, and the surface layer is a vanadium-titanium black porcelain layer or a waste black ceramic layer or a mineral black ceramic layer composite ceramic solar heat collecting solid plate.
  • the composite ceramic solar trough air duct produced by the composite ceramic solar collector plate is provided with a non-ceramic material bottom plate under the bottom plane of the composite ceramic solar heat collecting solid plate, and the first side plate is respectively disposed on both sides of the bottom plate length direction.
  • a second side plate a transparent plate is mounted on the top of the first side plate and the second side plate, and the bottom plate, the first side plate, the second side plate and the transparent plate made of non-ceramic materials are connected to each other to form upper, lower, left and right closed, front and rear ends
  • the bottom plane of the composite ceramic solar heat collecting solid plate is in close contact with the bottom plate, and the two sides of the composite ceramic solar heat collecting solid plate are in close contact with the first side plate and the second side plate, respectively.
  • the front end opening and the rear end opening of the plurality of composite ceramic solar heat collecting trough channels are connected to each other to form a composite ceramic solar trough air duct.
  • a transparent plate is mounted on the top plates of the two sides of the composite ceramic solar heat collecting solid groove plate, and the composite ceramic solar heat collecting solid groove plate and the transparent plate are formed to be closed up and down and left and right, and the front and rear ends are open solar heat collecting trough channels, A plurality of composite ceramic solar heat collecting trough channel front end openings and rear end openings are connected to each other to form a composite ceramic solar trough air duct.
  • the bottom plate, the first side plate and the second side plate made of the non-ceramic material are integrated, and the cross section is groove-shaped, and the gold is used. The plate is pressed and formed.
  • the transparent plate is a tempered glass plate.
  • the composite ceramic solar trough air duct construction method of the composite ceramic solar heat collecting plate installs the composite ceramic solar trough air duct on the slope or the desert with a certain slope, and the sunlight passes through the transparent cover plate.
  • the dark or black underside and/or inner side of the composite ceramic solar collector plate absorbs sunlight and heats the air in the channel plate, propelling the turbine to generate electricity with a rising flow of hot air.
  • the composite ceramic solar trough air duct is installed on the roof of the building or the air is heated on the sunny wall to provide hot air into the building.
  • the slurry is sprayed on the dried green body to form a rough surface with irregularities, and the rough surface is covered with capillary pores, and is fired into a rough, surface layer covered with tiny holes, and the sunlight is irradiated on the rough surface and into the minute holes. It is difficult to escape, forming a sun trap and increasing the sun absorption ratio.
  • a transparent plate is installed on the top plates of the two sides of the composite ceramic solar heat collecting solid groove plate, and the composite ceramic solar heat collecting solid groove plate and the transparent plate are formed to be closed up and down, left and right, and the front and rear ends are open solar heat collecting channels, and the plurality of pieces are The front end opening and the rear end opening of the solar heat collecting channel are connected to each other to form a composite ceramic solar trough air duct, or a composite ceramic solar heat collecting solid flat plate is mounted on the inner bottom surface of the solid groove plate made of non-ceramic material.
  • the solid groove plate made of ceramic material is provided with a transparent plate at the top of both sides of the plate, a solid groove plate made of non-ceramic material, a composite ceramic solar heat collecting solid plate and a transparent plate are formed to be closed up and down, left and right, and the front and rear ends are open solar collectors.
  • the hot channel connects the front end openings and the rear end openings of the plurality of solar heat collecting channels to each other to form a composite ceramic solar trough air duct.
  • the solid concave groove plate made of the non-ceramic material is press-formed with a metal plate, especially by a corrosion-resistant color steel plate.
  • the residue remaining after extracting vanadium from the vanadium slag is the vanadium tailings, and the vanadium tailings are black or dark ceramics made of one of the raw materials or raw materials;
  • Black porcelain is all industrial wastes other than vanadium tailings, which are more than 5% of the total amount of Fe, Mn, Ti, V, Cr, Ni, Cu, Co, Zn, Zr, Nb, Mo, W compounds.
  • the mineral black porcelain is a total of 5 compounds of Fe, Mn, Ti, V, Cr, Ni, CLU CO, Zn, Zr, Nb, Mo, W % of the metal mineral is a black or dark ceramic made from one of the raw materials or raw materials.
  • the electric furnace copper slag contains FeO 26-34%
  • the copper blast furnace water quenching slag is commonly called black sand
  • the wet copper leaching slag contains Fe 50%, Cu 1. 13%, Pb 1.05%, Zn 0.2%, Bi 0.15%, Mn 0.04%
  • lead ashing furnace water quenching slag is a blast furnace that produces lead smelting Slag fuming furnace and then the recycling of lead, zinc spoil the contents of Fe 2 0 :, 38. 6- 38. 7 %, Pb 0. 06-0. 37%, Zn 0. 8-1.
  • the manufacturing difficulty of the composite ceramic solar heat collecting plate is reduced, so that it becomes a solid flat plate, and the manufacturing cost is greatly reduced, so that the base material blank of the composite ceramic solar heat collecting plate can be subjected to a dry pressing forming method or a pair of rolls.
  • the technical scheme of the composite ceramic solar trough air passage according to the present invention can also be large
  • the scale is used to heat the air on the barren slope or desert, and the generating heat is driven by the rising hot air.
  • the comprehensive performance of the solar trough air duct technical scheme of the invention is superior to various existing schemes, and its own structure consumes extremely low energy.
  • the price of ceramic flat products as ordinary ceramic wall and floor tiles is 400 yuan per ton, ordinary steel per Tonnes 4,000 yuan, copper material is 70,000 yuan per ton.
  • the solar energy absorption film used in existing solar technology is a film formed by tiny particles at normal temperature or relatively low temperature, between particles, particles.
  • the binding force formed between the substrate and the substrate is weak.
  • the molecular bond is weak.
  • the bond energy of the molecular bond is weak and the structure is unstable.
  • the sun absorption ratio is attenuated with the use time, and the effective use time is about 10 years. Generally less than 10 years.
  • the solar trough air duct technical scheme of the invention is simple to manufacture and convenient in construction, and provides an easy and safe and reliable technical guarantee for laying large-scale solar collectors in deserts, barren slopes and the like.
  • the technical solution of the invention can be made into a large-sized solar trough air duct, which can minimize the heat capacity of the composite ceramic solar collector panel and the composite ceramic solar collector trough panel in the solar air duct, and consume the energy drop in the air duct.
  • the area occupied by the air duct is minimized, the system structure is simplified to a minimum, and the indirect heating is changed to direct heating, so that the efficiency of the solar air duct is at a high level.
  • the solar greenhouse chimney power generation system mainly produces hot air from the greenhouse.
  • the indoor and outdoor temperature difference is about 30 degrees.
  • the solar trough air duct absorbs sunlight from the black porcelain layer, and generates hot air with the composite ceramic solar trough air duct.
  • the temperature difference between the inner and outer air ducts is 60 degrees. Above, the generated wind speed, wind pressure, and power generation efficiency are much higher than the solar greenhouse chimney power generation system.
  • FIG. 1 is a schematic structural view of a composite ceramic solar heat collecting solid plate
  • FIG. 2 is a structural schematic view of a composite ceramic solar heat collecting solid groove plate
  • FIG. 3 is one embodiment of the solar heat collecting trough channel according to the present invention
  • FIG. 4 is a schematic structural view of the second embodiment of the solar heat collecting trough channel according to the present invention
  • FIG. 5 is a schematic structural view of the solar heat collecting trough air duct according to the present invention.
  • the composite ceramic solar heat collecting plate of the present invention comprises two structures, one structure is as follows: as shown in FIG. 1, it is rectangular, and its base body is a common ceramic solid flat plate 1 on a flat surface of a common ceramic solid flat plate 1. Covering a layer of sintered black porcelain layer 2, the ordinary ceramic solid plate 1 and the black ceramic layer 2 sintered on the surface thereof constitute a composite ceramic solar heat collecting solid plate 3, and the black ceramic layer 2 covered on the ordinary ceramic solid plate 1 is rough surface, cloth
  • the vanadium-titanium black ceramic layer filled with tiny holes is either a black slag layer or a mineral black porcelain layer.
  • Another structure is as follows: As shown in FIG. 1, it is rectangular, and its base body is a common ceramic solid flat plate 1 on a flat surface of a common ceramic solid flat plate 1. Covering a layer of sintered black porcelain layer 2, the ordinary ceramic solid plate 1 and the black ceramic layer 2 sintered on the surface thereof constitute a composite ceramic solar heat collecting solid plate 3, and the black ceramic layer 2 covered on the ordinary ceramic solid plate 1 is
  • side plates are respectively disposed on both sides of the composite ceramic solar heat collecting solid plate 3 in the longitudinal direction, and the composite ceramic solar heat collecting solid plate 3 is integrated with the side plates on both sides in the longitudinal direction thereof.
  • the cross-section has a groove shape, and the composite ceramic solar heat collecting solid plate 3 and the side plates on both sides in the longitudinal direction thereof constitute a composite ceramic solar heat collecting solid groove plate 4.
  • the surface of the inner bottom surface and the inner side surface of the composite ceramic solar heat collecting solid groove plate 4 are covered with a sintered black porcelain layer 2, which is a vanadium titanium black ceramic layer having a rough surface, covered with minute holes or a black residue.
  • the porcelain layer is either a mineral black porcelain layer.
  • the thickness of the thickness of the black ceramic layer 2 is 0. 05 mm, and the thickness of the black ceramic layer 2 is 0. 05.
  • the thickness of the black ceramic layer 2 is preferably 0.5 mm, which is a solution capable of achieving the object of the present invention and achieving an optimum effect at a relatively inexpensive cost.
  • a further preferred embodiment of the thickness of the composite ceramic solar heat collecting solid plate 3 of the present invention is 3 mm.
  • the thickness of the composite ceramic solar collector solid groove plate 4 can also be 3-12 mm, which is a relatively cost-saving solution under the existing manufacturing process conditions, the composite ceramic solar collector solid
  • the thickness of the groove plate 4 is preferably 5 mm. When the thickness of the composite ceramic solar heat collecting solid plate 3 and the composite ceramic solar heat collecting solid groove plate 4 is larger, the manufacturing cost is relatively higher, and the thickness of the composite ceramic solar hollow heat collecting plate in the prior art is 25 More than a millimeter.
  • the composite ceramic solar heat collecting solid plate 3 and the black ceramic layer 2 on the surface of the composite ceramic solar heat collecting solid groove plate 4 of the invention are all made of industrial waste, and a scheme for reducing cost and better heat absorption effect is formed.
  • a composite ceramic solar trough air duct is fabricated by using a composite ceramic solar heat collecting solid plate 3 or a composite ceramic solar heat collecting solid groove plate 4.
  • the composite ceramic solar trough air duct is made by using the composite ceramic solar heat collecting solid flat plate 3: a bottom plate 5 made of non-ceramic material is installed under the bottom plane of the composite ceramic solar heat collecting solid flat plate 3,
  • the first side plate 6 and the second side plate 7 are respectively disposed on both sides of the bottom plate 5 in the longitudinal direction, the transparent plate 8 is mounted on the top of the first side plate 6 and the second side plate 7, and the bottom plate 5 and the first side plate are made of non-ceramic material.
  • the second side plate 7 and the transparent plate 8 are connected to each other to form a solar heat collecting trough channel which is closed up, down, left and right, and has an open front and rear end.
  • the bottom plane of the composite ceramic solar heat collecting solid plate 3 is in close contact with the bottom plate 5, and is composited.
  • the two sides of the ceramic solar heat collecting solid plate 3 are in close contact with the side 6 and the second side plate 7, respectively, and the front end opening and the rear end of the plurality of composite ceramic solar heat collecting trough channels are interconnected to form a composite ceramic solar trough.
  • sunlight energy is absorbed by black porcelain layer ⁇ heats air, provides hot air to the building or drives air turbine with rising hot air flow Drive generators ⁇
  • the composite ceramic solar trough air duct is made of the composite ceramic solar heat collecting solid groove plate 4: the transparent plate 8 is mounted on the top of the two sides of the composite ceramic solar heat collecting solid groove plate 4.
  • the composite ceramic solar heat collecting solid groove plate 4 and the transparent plate 8 are formed to be closed up and down and left and right, and the front and rear ends are open solar heat collecting trough channels, and the front end and the rear end of the multi-component composite ceramic solar heat collecting trough channel are opened.
  • the openings are connected to each other to form a composite ceramic solar channel, and the sunlight passes through the transparent plate 8.
  • the sunlight energy is absorbed by the black porcelain layer and heats the air, providing hot air to the building or driving the air turbine with the rising hot air to drive electricity. Machine power generation.
  • the technical solution described in the present invention has the advantages of low manufacturing cost, can be made into any size, long service life, easy to install, and easy to manufacture. Therefore, it can be laid in a large area, and the solar energy collected in a large area is used for indoor heating. , refrigeration, and various applications such as large-scale solar power generation in desert areas, can truly achieve the use of inexpensive devices to collect a large amount of solar energy to replace conventional energy sources.
  • the bottom plate 5, the first side plate 6 and the second side plate 7 made of the non-ceramic material according to the present invention are integrated, and have a groove shape in section, and are press-formed with a metal plate.
  • the use of color steel sheet press molding, which is easy to manufacture and install, and has a relatively long service life, is one of the preferred embodiments of the present invention, and of course, it can also be made of concrete.
  • the transparent plate 8 of the present invention is preferably a tempered glass plate.
  • the composite ceramic solar heat collecting plate according to the present invention is prepared by coating a vanadium tailings residue or other industrial waste residue other than the vanadium tailings residue or a slurry prepared by mixing industrial minerals and ceramic raw materials with a conventional ceramic forming method. Forming one side of the dried ceramic plate blank, and then drying it into a base material is a common ceramic, and the surface layer is a vanadium-titanium black porcelain layer or a waste black ceramic layer or a mineral black ceramic layer composite ceramic solar heat collecting solid.
  • the flat plate, this manufacturing method has the lowest cost, simple manufacturing process and easy implementation.
  • the present invention can cover the thermal insulation layer at the bottom and the outer side of the composite ceramic solar energy trough duct.
  • the composite ceramic solar trough air duct constructed by the composite ceramic solar collector board according to the present invention is constructed by installing a composite ceramic solar trough air duct on the roof of a building or heating the air on the sunny wall surface. Hot air is provided inside the building.
  • the composite ceramic solar trough air passage of the invention can be installed in the northwestern part of China to find a mountain range with a height of about 800 meters and a hillside with a wide slope.
  • the mountain ridge is extended to the top of the mountain to construct a wind tunnel with a diameter of 40 meters, and 80 square kilometers is installed on the hillside. That is, 80 million square meters of composite ceramic solar collector trough air duct, air duct installed in the air duct, under the sun, hot air pushes the air turbine to drive the generator to generate electricity with a power of about 500,000 kilowatts.
  • a "chimney” with a diameter of 50 meters and a height of 200 meters is built on the top of the mountain.
  • Several air passages with a diameter of 10-20 meters are connected to the "chimney” to trim the desert south of the mountain.
  • a simple factory was built on site, and a roll of color steel plate with a thickness of 1.5 mm was pressed into a width of 1000 mm and a height of 200 mm, 400 mm, and 600 mm by continuous roll forming.
  • a composite ceramic solar collector solid plate 3 with a length of 1000 mm, a width of 1000 mm and a thickness of 3 mm is mounted on the inner bottom surface of the concave groove plate, and is mounted on the top of both sides of the concave groove plate.
  • the tempered glass plate with a thickness of 4 mm forms a solar heat collecting channel, and the front end opening and the rear end opening of the solar heat collecting channel with the groove height of 200 mm, 400 mm and 600 mm are connected to each other to form a composite ceramic solar trough with a total length of 3000 m.
  • the air duct has a large cross-sectional area communicating with the air passage, and a plurality of such composite ceramic solar trough air passages are arranged in parallel and communicate with the air passage, with a total area of 300 square meters.
  • an air turbine is installed in the air duct and the bottom of the "chimney". Under the sunlight, the hot air pushes the air turbine to drive the generator to generate electricity with a power of about 2 million kilowatts.
  • the wind speed of hot air is determined by the temperature difference between the inside and outside of the air duct, and the power generation is proportional to the cube of the wind speed.
  • the Sahara Desert covers an area of 9.6 million square kilometers and is 15-30 degrees north latitude. It is extremely dry and is the most intense area on the earth.
  • a composite ceramic solar collector solid groove plate 4 with a length of 1200 mm, a width of 800 mm, a groove height of 150 mm and a wall thickness of 5 mm is used on both sides of the composite ceramic solar heat collecting solid groove plate 4.
  • a tempered glass plate with a thickness of 4 mm is installed on the top of the plate to form a solar heat collecting channel.
  • the channel is connected end to end to a length of 500 meters.
  • the air passages are arranged in parallel with the air passage, with a total area of 100 square kilometers.
  • An air turbine is installed in the air passage. Under the sunlight, the hot air drives the air turbine to drive the generator to generate electricity with a power of about 600,000 kilowatts.

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Abstract

A solar collecting panel of composite ceramic material and a solar fluted air duct are provided. The solar collecting panel has a rectangular shape and is constituted of a common ceramic solid flat plate and a sintered black ceramic layer covering the flat plate. The black ceramic layer is vanadium-titanium black ceramic layer, waste residue black ceramic layer or ores black ceramic layer, whose surface is coarse and distributed with tiny holes. Two sides along the longitude direction of the solar collecting panel are provided with side plates respectively to form a solar collecting fluted plate. The bottom and the outsides of lateral sides of the fluted plate are provided with a bottom plate and two side plates respectively, and a transparent plate is provided on the top of the two side plates to form a solar collecting fluted channel with a front and back end opened. The solar fluted air duct is formed of multiple solar collecting fluted channels, which are connected with one another end to end.

Description

复合陶瓷太阳能集热板及太阳能槽形风道  Composite ceramic solar collector plate and solar trough air duct
技术领域 Technical field
本发明涉及太阳能利用技术, 是一种复合陶瓷太阳能集热板及太阳能槽形风道。 具体说是以富含第四周期过渡金属元素的工业废弃物、 天然矿物和普通陶瓷原料制造 低成本、 长寿命的、 表面为深色或黑色的普通陶瓷实心平板或普通陶瓷实心槽板作为 太阳能集热板, 利用太阳能集热板制造的太阳能槽形风道产生热风, 热风为建筑提供 热能或用于在荒坡、 荒漠上大规模加热空气, 以上升的热气流带动涡轮进行发电。 背景技术  The invention relates to a solar energy utilization technology, and is a composite ceramic solar heat collecting plate and a solar trough air duct. Specifically, it is a low-cost, long-life, solid-state ceramic solid plate or a common ceramic solid groove plate made of industrial waste, natural minerals and common ceramic raw materials rich in the fourth-period transition metal element. The heat collecting plate generates a hot air by using a solar trough air duct manufactured by a solar heat collecting plate. The hot air supplies heat to the building or is used to heat the air on a large scale on the slopes and deserts, and drives the turbine to generate electricity by the rising hot air flow. Background technique
近年来一些国家幵展了一种称之为 "太阳能温室烟囱 " 的太阳能热发电方式的 研究试验。 太阳能温室烟囱发电系统, 主要由烟囱、 温室和发电机及储能装置组成, 所述温室与普通栽培温室相同, 由被温室加热的空气流经温室中心的烟囱产生气流, 带动空气涡轮机驱动发电机发电。 "太阳能温室烟囪"投资大、 由温室加热得到的热 空气温度比较低, 发电系统效率不高。  In recent years, some countries have developed a research experiment on solar thermal power generation called “solar greenhouse chimney”. The solar greenhouse chimney power generation system is mainly composed of a chimney, a greenhouse and a generator and an energy storage device. The greenhouse is the same as the ordinary cultivated greenhouse, and the air heated by the greenhouse flows through the chimney in the center of the greenhouse to generate an air flow, which drives the air turbine to drive the generator. Power generation. The "solar greenhouse chimney" has a large investment, the hot air temperature obtained by heating the greenhouse is relatively low, and the power generation system is not efficient.
另有一种以复合陶瓷太阳能中空集热板的黑瓷表面层吸收阳光能量, 加热中空板 内空腔中的空气, 利用热空气的热能和热空气上升时的动能为建筑提供热能或者带动 空气涡轮机驱动发电机发电。  Another black ceramic surface layer of the composite ceramic solar hollow heat collecting plate absorbs sunlight energy, heats the air in the cavity of the hollow plate, and uses the heat energy of the hot air and the kinetic energy of the hot air to provide heat energy to the building or drive the air turbine. Drive the generator to generate electricity.
用复合陶瓷太阳能中空板制作太阳能风道有较多优点,但经发明人反复试验及不 断研究中发现, 它仍存在不足: 当在沙漠地区建造陶瓷太阳能风道时, 需要建造大尺 寸的太阳能风道, 复合陶瓷太阳能中空板受陶瓷生产工艺的限制, 孔道的高度和宽度 一般为 20至 50毫米之间, 不能达到要求, 制造大孔道复合陶瓷太阳能中空板的制作 工艺十分复杂, 工艺上很难实现, 同时, 复合陶瓷太阳能中空板的热容量较大, 在太 阳能风道中吸收大量热能, 从而消耗太阳能风道中的能量, 影响太阳能风道的风力。 上述不足, 易使太阳能风道的制作成本相对较高, 并使技术实施方案相当复杂, 效率 较低。  The use of composite ceramic solar hollow panels to make solar air ducts has many advantages, but it has been found through trial and error and continuous research by the inventors that it still lacks: When building ceramic solar wind tunnels in desert areas, it is necessary to build large-scale solar winds. Road, composite ceramic solar hollow board is limited by the ceramic production process. The height and width of the tunnel are generally between 20 and 50 mm, which cannot meet the requirements. The manufacturing process of manufacturing large-channel composite ceramic solar hollow board is very complicated and difficult in process. At the same time, the composite ceramic solar hollow plate has a large heat capacity, and absorbs a large amount of heat energy in the solar air channel, thereby consuming energy in the solar air channel and affecting the wind power of the solar air channel. The above-mentioned deficiencies make the production cost of the solar air duct relatively high, and the technical implementation scheme is quite complicated and low in efficiency.
发明内容 Summary of the invention
本发明的 1 的之一是提供一种复合陶瓷太阳能集热板, 本发明的目的之二是提供 一-种复合陶瓷太阳能槽形风道, 它们能够解决现有技术中存在的不足, 大幅度降低太 阳能风道的制造成本, 并使太阳能风道使用寿命长并具有较高的效率。 One of the present inventions 1 provides a composite ceramic solar heat collecting plate, and the second object of the present invention is to provide A composite ceramic solar trough air duct, which can solve the deficiencies in the prior art, greatly reduce the manufacturing cost of the solar air duct, and make the solar air duct have a long service life and high efficiency.
本发明为实现上述目的, 通过以下技术方案实现: 复合陶瓷太阳能集热板, 它呈 矩形, 其基体是普通陶瓷实心平板, 普通陶瓷实心平板的一个平面的表面上覆盖一层 烧结的黑色瓷层, 普通陶瓷实心平板与其表面烧结的黑色瓷层构成复合陶瓷太阳能集 热实心平板, 普通陶瓷实心平板上覆盖的黑色瓷层是表面粗糙、 布满微小孔洞的钒钛 黑瓷层或者是废渣黑瓷层或者是矿物黑瓷层。 复合陶瓷太阳能集热实心平板的长度方 向两侧分别设置侧板, 复合陶瓷太阳能集热实心平板与其长度方向两侧的侧板为一体 结构, 其截面呈凹槽形, 复合陶瓷太阳能集热实心平板和其长度方向两侧的侧板构成 复合陶瓷太阳能集热实心凹槽板。 复合陶瓷太阳能集热实心平板或复合陶瓷太阳能集 热实心凹槽板的普通陶瓷实心平板的厚度为 2-8毫米, 黑色瓷层的厚度为 0. 05-0. 5 毫米。 所述的复合陶瓷太阳能集热板的制作方法, 将提钒尾渣或者除提钒尾渣以外的 其他工业废渣或者工业矿物与陶瓷原料混合磨制的泥浆覆盖在以传统陶瓷成型方法成 型干燥的陶瓷平板素坯的一面, 再经干燥、 烧制成为基体是普通陶瓷, 表面层是钒钛 黑瓷层或者是废渣黑瓷层或者是矿物黑瓷层的复合陶瓷太阳能集热实心平板。 所述的 复合陶瓷太阳能集热板制作的复合陶瓷太阳能槽形风道, 在复合陶瓷太阳能集热实心 平板的底平面下面安装非陶瓷材料制作的底板, 底板长度方向两侧分别设置第一侧板 和第二侧板, 第一侧板和第二侧板的顶部安装透明板, 非陶瓷材料制作的底板、 第一 侧板、 第二侧板和透明板相互连接, 形成上下左右封闭、 前后端为敞口的太阳能集热 槽形通道, 复合陶瓷太阳能集热实心平板的底平面与底板紧密接触, 复合陶瓷太阳能 集热实心平板的两侧面分别与第一侧板和第二侧板紧密接触, 将多件复合陶瓷太阳能 集热槽形通道的前端敞口和后端敞口相互连接形成复合陶瓷太阳能槽形风道。 在复合 陶瓷太阳能集热实心凹槽板的两侧板顶部安装透明板, 复合陶瓷太阳能集热实心凹槽 板与透明板形成上下左右封闭, 前后端为敞口的太阳能集热槽形通道, 将多件复合陶 瓷太阳能集热槽形通道前端敞口和后端敞口相互连接,形成复合陶瓷太阳能槽形风道。 所述的非陶瓷材料制作的底板、 第一侧板和第二侧板为一体, 其截面呈凹槽形, 用金 属板压制成型。 所述透明板是钢化玻璃板。 所述的复合陶瓷太阳能集热板制作的复合 陶瓷太阳能槽形风道的施工方法, 将复合陶瓷太阳能槽形风道以一定的坡度安装在荒 坡上或荒漠上, 阳光穿过透明盖板, 复合陶瓷太阳能集热槽板的深色或黑色底面和 / 或内侧面吸收阳光后加热槽形板内的空气, 以上升的热气流推动涡轮进行发电。 将复 合陶瓷太阳能槽形风道安装在建筑物房顶上或向阳墙面上加热空气, 向建筑物内提供 热空气。 In order to achieve the above object, the present invention is achieved by the following technical solutions: a composite ceramic solar collector plate having a rectangular shape, the base of which is a solid ceramic solid plate, and a flat surface of a common ceramic solid plate covered with a sintered black porcelain layer. The ordinary ceramic solid plate and the black ceramic layer sintered on the surface constitute a composite ceramic solar heat collecting solid plate. The black ceramic layer covered by the ordinary ceramic solid plate is a vanadium titanium black porcelain layer with a rough surface, covered with tiny holes or black slag. The layer is either a mineral black porcelain layer. The composite ceramic solar collector solid plate has side plates on both sides in the longitudinal direction, and the composite ceramic solar heat collecting solid plate is integrated with the side plates on both sides in the longitudinal direction thereof, and the cross section is groove-shaped, and the composite ceramic solar heat collecting solid plate is integrated. And the side plates on both sides in the longitudinal direction thereof constitute a composite ceramic solar heat collecting solid groove plate. 5毫米。 The thickness of the thickness of the ceramic layer is 0. 05-0. 5 mm. The method for preparing the composite ceramic solar heat collecting plate comprises covering the vanadium tailings or other industrial wastes other than the vanadium tailings or the mixed slurry of the industrial minerals and the ceramic raw materials in a conventional ceramic forming method. One side of the ceramic plate blank is dried and fired to form a base ceramic which is a common ceramic, and the surface layer is a vanadium-titanium black porcelain layer or a waste black ceramic layer or a mineral black ceramic layer composite ceramic solar heat collecting solid plate. The composite ceramic solar trough air duct produced by the composite ceramic solar collector plate is provided with a non-ceramic material bottom plate under the bottom plane of the composite ceramic solar heat collecting solid plate, and the first side plate is respectively disposed on both sides of the bottom plate length direction. And a second side plate, a transparent plate is mounted on the top of the first side plate and the second side plate, and the bottom plate, the first side plate, the second side plate and the transparent plate made of non-ceramic materials are connected to each other to form upper, lower, left and right closed, front and rear ends In the open solar heat collecting trough channel, the bottom plane of the composite ceramic solar heat collecting solid plate is in close contact with the bottom plate, and the two sides of the composite ceramic solar heat collecting solid plate are in close contact with the first side plate and the second side plate, respectively. The front end opening and the rear end opening of the plurality of composite ceramic solar heat collecting trough channels are connected to each other to form a composite ceramic solar trough air duct. A transparent plate is mounted on the top plates of the two sides of the composite ceramic solar heat collecting solid groove plate, and the composite ceramic solar heat collecting solid groove plate and the transparent plate are formed to be closed up and down and left and right, and the front and rear ends are open solar heat collecting trough channels, A plurality of composite ceramic solar heat collecting trough channel front end openings and rear end openings are connected to each other to form a composite ceramic solar trough air duct. The bottom plate, the first side plate and the second side plate made of the non-ceramic material are integrated, and the cross section is groove-shaped, and the gold is used. The plate is pressed and formed. The transparent plate is a tempered glass plate. The composite ceramic solar trough air duct construction method of the composite ceramic solar heat collecting plate installs the composite ceramic solar trough air duct on the slope or the desert with a certain slope, and the sunlight passes through the transparent cover plate. The dark or black underside and/or inner side of the composite ceramic solar collector plate absorbs sunlight and heats the air in the channel plate, propelling the turbine to generate electricity with a rising flow of hot air. The composite ceramic solar trough air duct is installed on the roof of the building or the air is heated on the sunny wall to provide hot air into the building.
将提钒尾渣或者除提钒尾渣以外的其他富含第四周期过渡金属元素的工业废渣 或者富含第四周期过渡金属元素的工业矿物与其它陶瓷原料的混合物磨制的泥浆喷涂 在干燥的普通陶瓷实心平板素坯的一面或者喷涂在干燥的普通陶瓷实心凹形槽板素坯 的内底面和内侧面上, 经干燥、 烧制, 成为基体是普通陶瓷, 表面层或槽内表面层是 粗糙、 布满微小孔洞的钒钛黑瓷层或者废渣黑瓷层或者矿物黑瓷层的复合陶瓷太阳能 集热实心平板或复合陶瓷太阳能集热实心凹槽板。 泥浆喷涂在干燥素坯上会形成凹凸 不平的粗糙表面, 并在粗糙表面上布满毛细孔, 经过烧制成为粗糙、 布满微小孔洞的 表面层, 阳光照射在粗糙表面、 进入微小孔洞中, 难以逃逸, 形成阳光陷阱, 提高阳 光吸收比。  Spraying a slurry of vanadium tailings or other industrial wastes rich in fourth-cycle transition metal elements or a mixture of industrial minerals rich in fourth-cycle transition metal elements and other ceramic raw materials in a dry state One side of the ordinary ceramic solid plate blank or sprayed on the inner bottom surface and the inner side surface of the dried ordinary ceramic solid concave groove plate blank, dried and fired, the base is ordinary ceramic, the surface layer or the inner surface layer of the groove It is a composite ceramic solar collector solid plate or composite ceramic solar collector solid groove plate which is rough, covered with tiny holes, vanadium-titanium black porcelain layer or waste black ceramic layer or mineral black porcelain layer. The slurry is sprayed on the dried green body to form a rough surface with irregularities, and the rough surface is covered with capillary pores, and is fired into a rough, surface layer covered with tiny holes, and the sunlight is irradiated on the rough surface and into the minute holes. It is difficult to escape, forming a sun trap and increasing the sun absorption ratio.
在复合陶瓷太阳能集热实心凹槽板的两侧板顶部安装透明板, 复合陶瓷太阳能集 热实心凹槽板与透明板形成上下左右封闭, 前后端为敞口的太阳能集热通道, 将多件 太阳能集热通道前端敞口和后端敞口相互连接, 形成复合陶瓷太阳能槽形风道, 或者 在非陶瓷材料制作的实心凹槽板的内底面上安装复合陶瓷太阳能集热实心平板, 在非 陶瓷材料制作的实心凹槽板的两侧板顶部安装透明板,非陶瓷材料制作的实心凹槽板、 复合陶瓷太阳能集热实心平板与透明板形成上下左右封闭, 前后端为敞口的太阳能集 热通道, 将多件太阳能集热通道前端敞口和后端敞口相互连接, 形成复合陶瓷太阳能 槽形风道。  A transparent plate is installed on the top plates of the two sides of the composite ceramic solar heat collecting solid groove plate, and the composite ceramic solar heat collecting solid groove plate and the transparent plate are formed to be closed up and down, left and right, and the front and rear ends are open solar heat collecting channels, and the plurality of pieces are The front end opening and the rear end opening of the solar heat collecting channel are connected to each other to form a composite ceramic solar trough air duct, or a composite ceramic solar heat collecting solid flat plate is mounted on the inner bottom surface of the solid groove plate made of non-ceramic material. The solid groove plate made of ceramic material is provided with a transparent plate at the top of both sides of the plate, a solid groove plate made of non-ceramic material, a composite ceramic solar heat collecting solid plate and a transparent plate are formed to be closed up and down, left and right, and the front and rear ends are open solar collectors. The hot channel connects the front end openings and the rear end openings of the plurality of solar heat collecting channels to each other to form a composite ceramic solar trough air duct.
所述的非陶瓷材料制作的实心凹形槽板是用金属板压制成型的, 尤其是用耐腐蚀 的彩钢板压制成型的。  The solid concave groove plate made of the non-ceramic material is press-formed with a metal plate, especially by a corrosion-resistant color steel plate.
所述透明板是玻璃板或钢化玻璃板或有机材料透明板。 将复合陶瓷太阳能槽形风道以一定的坡度安装在荒坡上或荒漠上, 阳光穿过透明 盖板,复合陶瓷太阳能集热槽板的深色或黑色底面和 /或内侧面吸收阳光后加热槽形板 内的空气, 以上升的热气流推动涡轮进行发电。 The transparent plate is a glass plate or a tempered glass plate or an organic material transparent plate. The composite ceramic solar trough air duct is installed on the slope or desert in a certain gradient, the sunlight passes through the transparent cover plate, and the dark or black bottom surface and/or the inner side of the composite ceramic solar heat collecting trough plate absorbs sunlight and is heated. The air in the trough plate drives the turbine to generate electricity with an elevated flow of hot air.
将复合陶瓷太阳能槽形风道安装在建筑物房顶上或向阳墙面上加热空气, 向建筑 物内提供热空气。 ·  A composite ceramic solar channel is installed on the roof of a building or heated on a sunny wall to provide hot air into the building. ·
本发明的复合陶瓷太阳能集热板采用钒钛黑瓷或者废渣黑瓷或者矿物黑瓷为阳光 吸收材料, 所述的钒钛黑瓷是以钒钛磁铁矿经熔炼得到含钒铁水, 含钒铁水经吹炼得 到钒渣, 从钒渣中提取钒后所剩余的残渣即为提钒尾渣, 以提钒尾渣为全部原料或原 料之一制造的黑色或深色陶瓷; 所述的废渣黑瓷是以 Fe、 Mn、 Ti、 V、 Cr、 Ni、 Cu、 Co、 Zn、 Zr、 Nb、 Mo、 W的化合物总量超过 5%的除提钒尾渣以外的其他工业废渣为全 部原料或原料之一制造的黑色或深色陶瓷; 所述的矿物黑瓷是以 Fe、 Mn、 Ti、 V、 Cr、 Ni、 CLU CO、 Zn、 Zr、 Nb、 Mo、 W的化合物总量超过 5%的金属矿物为全部原料或原料 之一制造的黑色或深色陶瓷。  The composite ceramic solar collector plate of the invention adopts vanadium-titanium black porcelain or waste slag black porcelain or mineral black porcelain as the sunlight absorbing material, and the vanadium-titanium black porcelain is smelted by vanadium-titanium magnetite to obtain vanadium-containing molten iron, containing vanadium. The molten iron is blown to obtain vanadium slag. The residue remaining after extracting vanadium from the vanadium slag is the vanadium tailings, and the vanadium tailings are black or dark ceramics made of one of the raw materials or raw materials; Black porcelain is all industrial wastes other than vanadium tailings, which are more than 5% of the total amount of Fe, Mn, Ti, V, Cr, Ni, Cu, Co, Zn, Zr, Nb, Mo, W compounds. Or a black or dark ceramic made of one of the raw materials; the mineral black porcelain is a total of 5 compounds of Fe, Mn, Ti, V, Cr, Ni, CLU CO, Zn, Zr, Nb, Mo, W % of the metal mineral is a black or dark ceramic made from one of the raw materials or raw materials.
本发明所述的除提钒尾渣以外的其他工业废渣包括铁合金工业废渣、钢铁业废渣、 有色冶金业废渣、 化工业废渣。 铁合金工业废渣中各种锰铁渣含 MnO 5-50%、 FeO 0.2-2.5%, 硅铬合金渣含 Cr20:, 0. 1-5%、 Cr 2-10.5%, SiC 4-22%、 Si 7-8%, 中、 低、 微碳铬铁渣含 CrA 2-7%、 FeO 1-3%, 硅铁渣含 FeO 3-7%, SiC 20-29%、 Si 7-10%, 钨铁渣含 MnO 20- 25%、 FeO 3-9%, 钼铁渣含 FeO 13-15%, 金属铬浸出渣含 Ci'A 2- 7%、 FeA8- 13%, 金属铬冶炼渣含 CrA 11-14%, 电解锰渣含 MnSO.,约 15%、 Fe (OH) 30%, 硅锰渣含 MnO 8-18%、 FeO 0.2-2%, 硅锰烟尘含 Mn02 20 24%, 镍铁炉渣含 FeO 40%、 CrA 40%。 钢铁业废渣中转炉钢渣含 FeA 1.4-11%、 FeO 7-21%、 MnO 0.9-4.5%, 平 炉钢渣含 Fe 0:11.7-7.4%、 FeO 7-36%, MnO 0.6 3.9%, 轧钢氧化铁皮含 Fe20:1接近 100%, 钒钛磁铁矿炼铁渣含 Ti0210- 17%、 FeA约 4%, 钒钛磁铁矿炼钢渣含氧化铁 11_13%、 MnO 1-1.2%、 V.A2.3-2.9%、 2-2.9%。 有色冶金业废渣中电炉铜渣含 FeO 26-34%, 铜鼓风炉水淬渣 俗称黑砂)含 Fe0+ Fe A 40-50%,湿法炼铜浸出渣含 Fe 50%、Cu 1. 13%、 Pb 1.05%、 Zn 0.2%、 Bi 0. 15%、 Mn 0.04%, 铅烟化炉水淬渣是将炼铅产出的鼓风炉炉 渣再经烟化炉回收铅、锌后的弃渣内含 Fe20:, 38. 6- 38. 7%、Pb 0. 06-0. 37%、Zn 0. 8-1. 3%, 炼铝厂制造 A1A时排出弃渣赤泥含 FeA 8-10%、 Ti02 2. 5%, 化工业废渣中以硫铁矿 制造硫酸时产出的硫铁矿烧渣含 Fe20:i 41- 49% , FeO 10-10. 4%、 TiO 0. 4-0. 5%、 MnO 0. 1-0. 5%、 CuO 2-4%。 Other industrial wastes other than vanadium tailings according to the present invention include ferroalloy industrial waste residue, steel industry waste residue, non-ferrous metallurgical industry waste residue, and chemical industry waste residue. The ferroalloy industrial waste slag contains MnO 5-50%, FeO 0.2-2.5%, and the silicon chromium alloy slag contains Cr 2 0 : , 0.1-5%, Cr 2-10.5%, SiC 4-22% , Si 7-8%, medium, low, micro carbon ferrochrome slag containing CrA 2-7%, FeO 1-3%, ferrosilicon slag containing FeO 3-7%, SiC 20-29%, Si 7-10% , tungsten iron slag contains MnO 20-25%, FeO 3-9%, molybdenum iron slag contains FeO 13-15%, metal chromium leaching slag contains Ci'A 2-7%, FeA8-13%, metal chromium smelting slag CrA 11-14%, electrolytic manganese slag containing MnSO., about 15%, Fe (OH) 30%, silicomanganese slag containing MnO 8-18%, FeO 0.2-2%, silicomanganese soot containing Mn0 2 20 24%, The nickel-iron slag contains 40% FeO and 40% CrA. Steel slag in steel industry contains FeA 1.4-11%, FeO 7-21%, MnO 0.9-4.5%, and flat furnace steel slag contains Fe 0 :1 1.7-7.4%, FeO 7-36%, MnO 0.6 3.9%, steel oxide oxidation The iron sheet contains Fe 2 0 :1 close to 100%, the vanadium-titanium magnetite iron slag contains Ti0 2 10- 17%, FeA about 4%, and the vanadium-titanium magnetite steelmaking slag contains 11_13% iron oxide, MnO 1-1.2 %, V.A2.3-2.9%, 2-2.9%. In the non-ferrous metallurgical industry, the electric furnace copper slag contains FeO 26-34%, the copper blast furnace water quenching slag is commonly called black sand) contains Fe0+ Fe A 40-50%, and the wet copper leaching slag contains Fe 50%, Cu 1. 13%, Pb 1.05%, Zn 0.2%, Bi 0.15%, Mn 0.04%, lead ashing furnace water quenching slag is a blast furnace that produces lead smelting Slag fuming furnace and then the recycling of lead, zinc spoil the contents of Fe 2 0 :, 38. 6- 38. 7 %, Pb 0. 06-0. 37%, Zn 0. 8-1. 3%, When the A1A is manufactured by the aluminum smelting plant, the waste sludge is discharged from the red mud containing FeA 8-10% and Ti0 2 2.5%. The pyrite slag produced by the pyrite produced in the chemical industry waste slag contains Fe 2 0 :i 41% to 49%, FeO 10-10. 4%, TiO 0. 4-0. 5%, MnO 0.1-1.5%, CuO 2-4%.
本发明所述的金属矿物是指普通铁矿, 褐红色, 含 Fe 0:< 30- 70%, 铬铁矿, 暗红色, 含 Cr A 30-54%, FeO 12-17%,钛铁矿,黑紫色,含 TiO 50-60%、 FeO 22-35%、 Fe2037- 15%、 MnO 0. 5-4%, 锰矿, 黑褐色, MnO, 40-78%、 Mn:i0„ 4-32%、 Fe 1-18%, 含镍褐铁矿, 褐色, 含 Ni 1. 2-1. 4%、 Co 0. 1-0. 2%、 CrA 3%、 Fe 35-50%, 钒钛磁铁矿, 黑色,含 V 0. 4-1. 8%、 TiO, 9-34%、 Fe20:, 15- 50%、 FeO 9-34%. MnO 0. 2-6%、 Crz03 0. 1-0. 7%, 铌铁矿,黑色,含 NbA 9-68%、 TaA 1-15%、 TiO 1-3%、 MnO 1-3%、 SnO 2-5%、 FeO 12-20%, 黑钨矿、 黑褐色, 含 W0:, 65- 67%、 FeO 12- 15%、 MnO 8- 12%、 Sn 0. 17 0. 8%。 选用这些 富含过渡元素的工业废弃物和金属矿物的目的是为陶瓷太阳板坯体或表面层提供着色 的成分, 使坯体或表面层呈现深色或黑色, 使其吸收更多的阳光。 The metal mineral of the present invention refers to ordinary iron ore, maroon, containing Fe 0 : < 30- 70%, chromite, dark red, containing Cr A 30-54%, FeO 12-17%, ilmenite , black purple, containing TiO 50-60%, FeO 22-35%, Fe 2 0 3 7- 15%, MnO 0. 5-4%, manganese ore, dark brown, MnO, 40-78%, Mn : i 0 „ 4-32%, Fe 1-18%, nickel-containing limonite, brown, containing Ni 1. 2-1. 4%, Co 0. 1-0. 2%, CrA 3%, Fe 35-50% , vanadium-titanium magnetite, black, containing V 0. 4-1. 8%, TiO, 9-34%, Fe 2 0 : , 15- 50%, FeO 9-34%. MnO 0. 2-6% , Cr z 0 3 0. 1-0. 7%, coltan, black, containing NbA 9-68%, TaA 1-15%, TiO 1-3%, MnO 1-3%, SnO 2-5% FeO 12-20%, black tungsten ore, dark brown, containing W0 : , 65- 67%, FeO 12-15%, MnO 8- 12%, Sn 0. 17 0. 8%. Use these rich transition elements The purpose of industrial waste and metal minerals is to provide a colored component to the ceramic solar panel body or surface layer, rendering the body or surface layer dark or black, allowing it to absorb more sunlight.
本发明提供的复合陶瓷太阳能集热板和复合陶瓷太阳能槽形风道的目的在于降 低使用太阳能的成本,包括能源成本、 货币成本、 环境成本。 太阳能是否可以大规模使 用, 需要解决的关键问题是降低使用成本。 并且这种使用成本应当低于常规能源的使 用成本。 否则, 太阳能替代常规能源的一切技术方案都难于普及应用 。 为此, 本申请 发明人从复合陶瓷太阳能集热板的形状、 结构、 制造工艺、 使用原料及技术方案等多 方面做了更进一步的研究,提供的本发明技术方案能够解决现有技术存在的各种不足: 首先降低复合陶瓷太阳能集热板的制造难度, 使其成为实心平板, 大幅度降低制造成 本, 使复合陶瓷太阳能集热板的基体素坯能够采用干压成型方法或者采用对辊辊压法 成型方法, 在薄素坯板表面喷涂深色或黑瓷层原料, 经过烧结成为复合陶瓷太阳能集 热平板, 并且使用该方法可以制造尺寸很大的薄板, 其最薄的厚度可以达到 2毫米, 这种厚度是现有技术中所有复合陶瓷太阳能集热板均做不到的, 因此, 本发明所述的 复合陶瓷太阳能集热板的制作成本降至低水平极限; 由于太阳能是不稳定的低密度能 源, 需要大面积的铺设低成本、 长寿命的太阳能集热器, 才能将收集到的大量太阳能 转换成能够方便使用的能量, 成为大规模替代能源。 因此, 实现大面积铺设太阳能集 热器的前提是太阳能集热器必须具备制造成本低廉、 使用寿命长、 易于制造和安装等 特点, 而本发明所述的复合陶瓷太阳能集热槽形风道的技术方案恰能够完全具备制造 成本低廉、 使用寿命长、 原料易得、 易于制造和安装的优点, 因此, 本发明所述的太 阳能槽形风道的技术方案可以安装在建筑物房顶、 向阳墙面上收集太阳能, 将热空气 送入室内或用太阳能加热生活用水或将热空气通过制冷机组转换后用于夏季制冷等; 本发明所述的复合陶瓷太阳能槽形风道的技术方案还可以大规模应用于在荒坡或荒漠 上加热空气, 以上升的热气流带动发电机组发电。 本发明的太阳能槽形风道技术方案 的综合性能优于各种已有方案, 其自身结构耗能极低, 目前作为普通陶瓷墙地砖的陶 瓷平板制品售价每吨 400元人民币, 普通钢材每吨 4000元人民币, 铜材每吨 70000 元人民币, 普通陶瓷制品是己知成本最低、 寿命最长的工程材料之一, 工业废弃物成 本更低。 本技术方案设备制作成本仅为已有技术的几分之一至几十分之一, 使用寿命 高于现有技术 30-50倍, 使单位能量使用成本远远低于已有技术。 The composite ceramic solar collector plate and the composite ceramic solar trough air passage provided by the invention aim to reduce the cost of using solar energy, including energy cost, currency cost and environmental cost. Whether solar energy can be used on a large scale, the key problem to be solved is to reduce the cost of use. And this cost of use should be lower than the cost of using conventional energy. Otherwise, all technical solutions for solar energy to replace conventional energy sources are difficult to popularize. Therefore, the inventor of the present application has made further research from the aspects of the shape, structure, manufacturing process, raw materials and technical solutions of the composite ceramic solar heat collecting plate, and the technical solution of the present invention can solve the existing technology. Various shortcomings: Firstly, the manufacturing difficulty of the composite ceramic solar heat collecting plate is reduced, so that it becomes a solid flat plate, and the manufacturing cost is greatly reduced, so that the base material blank of the composite ceramic solar heat collecting plate can be subjected to a dry pressing forming method or a pair of rolls. The pressure forming method applies a dark or black ceramic layer material on the surface of the thin green sheet, and is sintered to form a composite ceramic solar heat collecting plate, and the thin plate having a large size can be manufactured by using the method, and the thinnest thickness can reach 2 Mm, this thickness is not available in all the composite ceramic solar collector plates in the prior art, therefore, the manufacturing cost of the composite ceramic solar collector plate according to the present invention is reduced to a low level limit; Low-density energy requires a large area of low-cost, long-life solar collectors. In order to collect a large amount of solar energy Converted into energy that is easy to use and becomes a large-scale alternative energy source. Therefore, the premise of realizing large-area solar collectors is that the solar collectors must have the characteristics of low manufacturing cost, long service life, easy manufacture and installation, and the composite ceramic solar heat collecting trough air duct of the present invention. The technical solution can fully possess the advantages of low manufacturing cost, long service life, easy availability of raw materials, easy manufacture and installation. Therefore, the technical scheme of the solar trough air duct of the present invention can be installed on the roof of the building and the sunny wall. Collecting solar energy on the surface, sending hot air into the room or heating the domestic water with solar energy or converting the hot air through the refrigeration unit for summer cooling, etc.; the technical scheme of the composite ceramic solar trough air passage according to the present invention can also be large The scale is used to heat the air on the barren slope or desert, and the generating heat is driven by the rising hot air. The comprehensive performance of the solar trough air duct technical scheme of the invention is superior to various existing schemes, and its own structure consumes extremely low energy. At present, the price of ceramic flat products as ordinary ceramic wall and floor tiles is 400 yuan per ton, ordinary steel per Tonnes 4,000 yuan, copper material is 70,000 yuan per ton. Ordinary ceramic products are one of the lowest cost and longest life engineering materials, and the cost of industrial waste is lower. The manufacturing cost of the device of the technical solution is only a fraction to a tens of the prior art, and the service life is 30-50 times higher than that of the prior art, so that the unit energy use cost is far lower than the prior art.
• 现有太阳能技术采用太阳能吸收膜吸收太阳光的能量, 现有太阳能技术采用的太 阳能吸收膜的制造工艺是由微小颗粒在常温下或比较低的温度下形成的膜层, 颗粒之 间、 颗粒与基体之间形成的结合力很弱, 充其量是分子键结合, 分子键的键能很弱, 结构不稳定, 在阳光长期照射下, 阳光吸收比随使用时间衰减, 有效使用时间 10年左 右,一般不足 10年。本发明所述的深色或黑色瓷层是在高温下与基体一起形成的陶瓷 材料, 是结合力最强的离子键或原子键结合的, 阳光吸收比不会衰减, 其有效使用时 间在几百年以上, 甚至具有更长的使用寿命。  • Existing solar technology uses solar absorption film to absorb sunlight energy. The solar energy absorption film used in existing solar technology is a film formed by tiny particles at normal temperature or relatively low temperature, between particles, particles. The binding force formed between the substrate and the substrate is weak. At most, the molecular bond is weak. The bond energy of the molecular bond is weak and the structure is unstable. Under long-term sunlight, the sun absorption ratio is attenuated with the use time, and the effective use time is about 10 years. Generally less than 10 years. The dark or black porcelain layer of the present invention is a ceramic material formed together with a matrix at a high temperature, and is the strongest bonding ionic bond or atomic bond, the sunlight absorption ratio is not attenuated, and the effective use time is several More than a hundred years, even with a longer service life.
本发明的太阳能槽形风道技术方案制造简单, 施工方便, 为在沙漠、 荒坡等地大 规模铺设太阳能集热器提供了易于实现的安全可靠技术保障。 本发明技术方案可以做 成较大尺寸的太阳能槽形风道, 能使复合陶瓷太阳能集热板和复合陶瓷太阳能集热槽 形板在太阳能风道中的热容量降至最小, 消耗风道中的能量降至最小, 占用风道中的 面积降至最小, 使系统结构简化至最低, 并使间接加热变为直接加热, 使太阳能风道 的效率达到很高水平。 太阳能温室烟囱发电系统主要由温室产生热空气, 温室内外温差约 30度; 太阳 能槽形风道由黑瓷层吸收阳光, 以复合陶瓷太阳能槽形风道产生热空气, 风道内外温 差在 60度以上, 所产生的风速、 风压、 发电效率远高于太阳能温室烟囱发电系统。 附图说明 The solar trough air duct technical scheme of the invention is simple to manufacture and convenient in construction, and provides an easy and safe and reliable technical guarantee for laying large-scale solar collectors in deserts, barren slopes and the like. The technical solution of the invention can be made into a large-sized solar trough air duct, which can minimize the heat capacity of the composite ceramic solar collector panel and the composite ceramic solar collector trough panel in the solar air duct, and consume the energy drop in the air duct. At the minimum, the area occupied by the air duct is minimized, the system structure is simplified to a minimum, and the indirect heating is changed to direct heating, so that the efficiency of the solar air duct is at a high level. The solar greenhouse chimney power generation system mainly produces hot air from the greenhouse. The indoor and outdoor temperature difference is about 30 degrees. The solar trough air duct absorbs sunlight from the black porcelain layer, and generates hot air with the composite ceramic solar trough air duct. The temperature difference between the inner and outer air ducts is 60 degrees. Above, the generated wind speed, wind pressure, and power generation efficiency are much higher than the solar greenhouse chimney power generation system. DRAWINGS
附图 1是复合陶瓷太阳能集热实心平板的结构示意图; 附图 2是复合陶瓷太阳能 集热实心凹槽板的结构示意图; 附图 3是本发明所述太阳能集热槽形通道实施例之一 的结构示意图; 附图 4是本发明所述太阳能集热槽形通道实施例之二结构示意图; 附 图 5是本发明所述太阳能集热槽形风道结构示意图。  1 is a schematic structural view of a composite ceramic solar heat collecting solid plate; FIG. 2 is a structural schematic view of a composite ceramic solar heat collecting solid groove plate; FIG. 3 is one embodiment of the solar heat collecting trough channel according to the present invention; FIG. 4 is a schematic structural view of the second embodiment of the solar heat collecting trough channel according to the present invention; and FIG. 5 is a schematic structural view of the solar heat collecting trough air duct according to the present invention.
具体实施方式 detailed description
本发明所述复合陶瓷太阳能集热板包括两种结构, 一种结构为: 如图 1所示, 它 呈矩形, 其基体是普通陶瓷实心平板 1, 普通陶瓷实心平板 1的一个平面的表面上覆 盖一层烧结的黑色瓷层 2, 普通陶瓷实心平板 1与其表面烧结的黑色瓷层 2构成复合 陶瓷太阳能集热实心平板 3, 普通陶瓷实心平板 1上覆盖的黑色瓷层 2是表面粗糙、 布满微小孔洞的钒钛黑瓷层或者是废渣黑瓷层或者是矿物黑瓷层。 另一种结构为: 如 图 2所示, 在复合陶瓷太阳能集热实心平板 3的长度方向两侧分别设置侧板, 复合陶 瓷太阳能集热实心平板 3与其长度方向两侧的侧板为一体结构, 其截面呈凹槽形, 复 合陶瓷太阳能集热实心平板 3和其长度方向两侧的侧板构成复合陶瓷太阳能集热实心 ra槽板 4。 复合陶瓷太阳能集热实心凹槽板 4的内底面的表面和内侧面的表面覆盖烧 结的黑色瓷层 2, 黑色瓷层 2是表面粗糙、 布满微小孔洞的钒钛黑瓷层或者是废渣黑 瓷层或者是矿物黑瓷层。  The composite ceramic solar heat collecting plate of the present invention comprises two structures, one structure is as follows: as shown in FIG. 1, it is rectangular, and its base body is a common ceramic solid flat plate 1 on a flat surface of a common ceramic solid flat plate 1. Covering a layer of sintered black porcelain layer 2, the ordinary ceramic solid plate 1 and the black ceramic layer 2 sintered on the surface thereof constitute a composite ceramic solar heat collecting solid plate 3, and the black ceramic layer 2 covered on the ordinary ceramic solid plate 1 is rough surface, cloth The vanadium-titanium black ceramic layer filled with tiny holes is either a black slag layer or a mineral black porcelain layer. Another structure is as follows: As shown in FIG. 2, side plates are respectively disposed on both sides of the composite ceramic solar heat collecting solid plate 3 in the longitudinal direction, and the composite ceramic solar heat collecting solid plate 3 is integrated with the side plates on both sides in the longitudinal direction thereof. The cross-section has a groove shape, and the composite ceramic solar heat collecting solid plate 3 and the side plates on both sides in the longitudinal direction thereof constitute a composite ceramic solar heat collecting solid groove plate 4. The surface of the inner bottom surface and the inner side surface of the composite ceramic solar heat collecting solid groove plate 4 are covered with a sintered black porcelain layer 2, which is a vanadium titanium black ceramic layer having a rough surface, covered with minute holes or a black residue. The porcelain layer is either a mineral black porcelain layer.
本发明所述的复合陶瓷太阳能集热实心平板 3和复合陶瓷太阳能集热实心凹槽板 的普通陶瓷实心平板 1的厚度优选的方案为 2-8毫米,黑色瓷层 2的厚度为 0. 05-0. 5 毫米, 黑色瓷层 2的厚度优选的方案为 0. 1毫米, 这是能够实现本发明目的、 以比较 廉价的成本达到最佳效果的方案。 本发明所述的复合陶瓷太阳能集热实心平板 3的厚 度进一步优选的方案为 3毫米。复合陶瓷太阳能集热实心凹槽板 4的厚度也可为 3-12 毫米, 这是在现有制作工艺条件下的比较节省成本的方案, 复合陶瓷太阳能集热实心 凹槽板 4的厚度优选的方案为 5毫米。 复合陶瓷太阳能集热实心平板 3和复合陶瓷太 阳能集热实心凹槽板 4的厚度尺寸越大时, 制造成本相对越高, 而现有技术中的复合 陶瓷太阳能中空集热板的厚度均在 25毫米以上。 The thickness of the thickness of the black ceramic layer 2 is 0. 05 mm, and the thickness of the black ceramic layer 2 is 0. 05. The thickness of the black ceramic layer 2 is preferably 0.5 mm, which is a solution capable of achieving the object of the present invention and achieving an optimum effect at a relatively inexpensive cost. A further preferred embodiment of the thickness of the composite ceramic solar heat collecting solid plate 3 of the present invention is 3 mm. The thickness of the composite ceramic solar collector solid groove plate 4 can also be 3-12 mm, which is a relatively cost-saving solution under the existing manufacturing process conditions, the composite ceramic solar collector solid The thickness of the groove plate 4 is preferably 5 mm. When the thickness of the composite ceramic solar heat collecting solid plate 3 and the composite ceramic solar heat collecting solid groove plate 4 is larger, the manufacturing cost is relatively higher, and the thickness of the composite ceramic solar hollow heat collecting plate in the prior art is 25 More than a millimeter.
本发明所述复合陶瓷太阳能集热实心平板 3和复合陶瓷太阳能集热实心凹槽板 4 表面的黑色瓷层 2均采用工业废料制作, 形成了降低成本且吸热效果较好的方案。  The composite ceramic solar heat collecting solid plate 3 and the black ceramic layer 2 on the surface of the composite ceramic solar heat collecting solid groove plate 4 of the invention are all made of industrial waste, and a scheme for reducing cost and better heat absorption effect is formed.
本发明为了完成第二发明目的, 采用复合陶瓷太阳能集热实心平板 3或复合陶瓷 太阳能集热实心凹槽板 4制作复合陶瓷太阳能槽形风道。  In order to accomplish the second object of the present invention, a composite ceramic solar trough air duct is fabricated by using a composite ceramic solar heat collecting solid plate 3 or a composite ceramic solar heat collecting solid groove plate 4.
如图 3和图 5所示, 采用复合陶瓷太阳能集热实心平板 3制作复合陶瓷太阳能槽 形风道是: 在复合陶瓷太阳能集热实心平板 3的底平面下面安装非陶瓷材料制作的底 板 5 ,底板 5长度方向两侧分别设置第一侧板 6和第二侧板 7, 第一侧板 6和第二侧板 7的顶部安装透明板 8, 非陶瓷材料制作的底板 5、 第一侧板 6、 第二侧板 7和透明板 8相互连接, 形成上下左右封闭、 前后端为敞口的太阳能集热槽形通道, 复合陶瓷太 阳能集热实心平板 3的底平面与底板 5紧密接触, 复合陶瓷太阳能集热实心平板 3的 两侧面分别与 侧 6和第二侧板 7紧密接触, 将多件复合陶瓷太阳能集热槽形通 道前端敞口和后端敞 相\互连接形成复合陶瓷太阳能槽形风道, 阳光穿过透明板 8 , 阳光能量被黑色瓷层吸收^加热空气, 向建筑物内提供热空气或以上升的热气流驱动 空气涡轮机带动发电机发 ΐ|  As shown in FIG. 3 and FIG. 5, the composite ceramic solar trough air duct is made by using the composite ceramic solar heat collecting solid flat plate 3: a bottom plate 5 made of non-ceramic material is installed under the bottom plane of the composite ceramic solar heat collecting solid flat plate 3, The first side plate 6 and the second side plate 7 are respectively disposed on both sides of the bottom plate 5 in the longitudinal direction, the transparent plate 8 is mounted on the top of the first side plate 6 and the second side plate 7, and the bottom plate 5 and the first side plate are made of non-ceramic material. 6. The second side plate 7 and the transparent plate 8 are connected to each other to form a solar heat collecting trough channel which is closed up, down, left and right, and has an open front and rear end. The bottom plane of the composite ceramic solar heat collecting solid plate 3 is in close contact with the bottom plate 5, and is composited. The two sides of the ceramic solar heat collecting solid plate 3 are in close contact with the side 6 and the second side plate 7, respectively, and the front end opening and the rear end of the plurality of composite ceramic solar heat collecting trough channels are interconnected to form a composite ceramic solar trough. Shaped airway, sunlight passes through transparent plate 8, sunlight energy is absorbed by black porcelain layer ^heats air, provides hot air to the building or drives air turbine with rising hot air flow Drive generators ΐ|
如图 4和图 5所示, 用复合陶瓷太阳能集热实心凹槽板 4制作复合陶瓷太阳能 槽形风道是: 在复合陶瓷太阳能集热实心凹槽板 4的两侧板顶部安装透明板 8, 复合 陶瓷太阳能集热实心凹槽板 4与透明板 8形成上下左右封闭, 前后端为敞口的太阳能 集热槽形通道, 将多件复合陶瓷太阳能集热槽形通道前端敞口和后端敞口相互连接, 形成复合陶瓷太阳能槽形风道, 阳光穿过透明板 8, 阳光能量被黑色瓷层吸收并加热 空气, 向建筑物内提供热空气或以上升的热气流驱动空气涡轮机带动发电机发电。  As shown in FIG. 4 and FIG. 5, the composite ceramic solar trough air duct is made of the composite ceramic solar heat collecting solid groove plate 4: the transparent plate 8 is mounted on the top of the two sides of the composite ceramic solar heat collecting solid groove plate 4. The composite ceramic solar heat collecting solid groove plate 4 and the transparent plate 8 are formed to be closed up and down and left and right, and the front and rear ends are open solar heat collecting trough channels, and the front end and the rear end of the multi-component composite ceramic solar heat collecting trough channel are opened. The openings are connected to each other to form a composite ceramic solar channel, and the sunlight passes through the transparent plate 8. The sunlight energy is absorbed by the black porcelain layer and heats the air, providing hot air to the building or driving the air turbine with the rising hot air to drive electricity. Machine power generation.
由于本发明所述太阳能集热槽形通道的尺寸受生产工艺的限制, 一般宽度可以做 成 0. 5米一 2米, 高度可以做成 0. 1米、 0. 5米、 1米、 1. 5米等等, 所以将太阳能集 热通道前后端相互连接形成复合陶瓷太阳能槽形风道, 如图 5所示, 这样就可以做成 几十米, 甚至几百米的长度, 将很多条复合陶瓷太阳能槽形风道平行、 并列在一起, 其总宽度可以达到几百米, 甚至几千米, 总之, 根据设计需要基本上没有限制。 本发 明所述的这种技术方案具有制造成本低、 可以做成任意尺寸、 使用寿命长、 易于安装、 易于制造等优点, 因此, 它可以大面积铺设, 将大面积收集的太阳能用于室内取暖、 制冷, 在荒漠地区实现大规模太阳能发电等各种用途, 能够真正实现用廉价的装置收 集了大量的太阳能用于替代常规能源。 The s. 5 meters and so on, so the front and rear ends of the solar heat collecting channel are connected to each other to form a composite ceramic solar trough air duct, as shown in Figure 5, so that it can be made A few tens of meters, even a few hundred meters in length, many composite ceramic solar trough air passages are parallel and juxtaposed, and their total width can reach several hundred meters, even several kilometers. In short, there is basically no limit according to design needs. . The technical solution described in the present invention has the advantages of low manufacturing cost, can be made into any size, long service life, easy to install, and easy to manufacture. Therefore, it can be laid in a large area, and the solar energy collected in a large area is used for indoor heating. , refrigeration, and various applications such as large-scale solar power generation in desert areas, can truly achieve the use of inexpensive devices to collect a large amount of solar energy to replace conventional energy sources.
本发明所述的所述的非陶瓷材料制作的底板 5、第一侧板 6和第二侧板 7为一体, 其截面呈凹槽形, 用金属板压制成型。 尤其釆用彩钢板压制成型, 这种方案易于制作 和安装, 且使用寿命相对较长, 是本发明优选方案之一, 当然, 也可以采用混凝土制 作。 本发明所述透明板 8优选采用钢化玻璃板。  The bottom plate 5, the first side plate 6 and the second side plate 7 made of the non-ceramic material according to the present invention are integrated, and have a groove shape in section, and are press-formed with a metal plate. In particular, the use of color steel sheet press molding, which is easy to manufacture and install, and has a relatively long service life, is one of the preferred embodiments of the present invention, and of course, it can also be made of concrete. The transparent plate 8 of the present invention is preferably a tempered glass plate.
本发明所述的复合陶瓷太阳能集热板的制作方法是, 将提钒尾渣或者除提钒尾渣 以外的其他工业废渣或者工业矿物与陶瓷原料混合磨制的泥浆覆盖在以传统陶瓷成型 方法成型干燥的陶瓷平板素坯的一面, 再经千燥、 烧制成为基体是普通陶瓷, 表面层 是钒钛黑瓷层或者是废渣黑瓷层或者是矿物黑瓷层的复合陶瓷太阳能集热实心平板, 这种制造方法成本最低, 制造工艺简单, 易于实施。  The composite ceramic solar heat collecting plate according to the present invention is prepared by coating a vanadium tailings residue or other industrial waste residue other than the vanadium tailings residue or a slurry prepared by mixing industrial minerals and ceramic raw materials with a conventional ceramic forming method. Forming one side of the dried ceramic plate blank, and then drying it into a base material is a common ceramic, and the surface layer is a vanadium-titanium black porcelain layer or a waste black ceramic layer or a mineral black ceramic layer composite ceramic solar heat collecting solid. The flat plate, this manufacturing method has the lowest cost, simple manufacturing process and easy implementation.
本发明为了降低复合陶瓷太阳能槽形风道内热量的散发速度, 可在复合陶瓷太阳 能槽形风道的底部和外侧包覆保温层。  In order to reduce the heat dissipation rate in the composite ceramic solar trough air duct, the present invention can cover the thermal insulation layer at the bottom and the outer side of the composite ceramic solar energy trough duct.
本发明所述的用复合陶瓷太阳能集热板制作的复合陶瓷太阳能槽形风道的施工方 法是, 将复合陶瓷太阳能槽形风道以一定的坡度安装在荒坡上或荒漠上, 阳光穿过透 明盖板,复合陶瓷太阳能集热槽板的深色或黑色底面和 /或内侧面吸收阳光后加热槽形 板内的空气, 以上升的热气流推动涡轮进行发电。  The construction method of the composite ceramic solar trough air duct made by the composite ceramic solar heat collecting plate of the invention is that the composite ceramic solar trough air duct is installed on the waste slope or the desert with a certain slope, and the sunlight passes through The transparent cover, the dark or black bottom surface and/or the inner side of the composite ceramic solar heat collecting trough plate absorbs sunlight and heats the air in the trough plate to drive the turbine to generate electricity with the rising hot air flow.
本发明所述的用复合陶瓷太阳能集热板制作的复合陶瓷太阳能槽形风道的施工方 法是, 将复合陶瓷太阳能槽形风道安装在建筑物房顶上或向阳墙面上加热空气, 向建 筑物内提供热空气。  The composite ceramic solar trough air duct constructed by the composite ceramic solar collector board according to the present invention is constructed by installing a composite ceramic solar trough air duct on the roof of a building or heating the air on the sunny wall surface. Hot air is provided inside the building.
本发明所述的复合陶瓷太阳能集热实心平板 3及复合陶瓷太阳能集热实心凹槽板 的基体均采用无白度要求的普通陶瓷原料, 用干压成型法按照设计尺寸压制成陶瓷 素坯平板,或用带槽的对辊辊压法制成陶瓷素坯槽板,再按重量百分比取提钒尾渣 65% 和普通瓷土 35%, 加水制成泥浆, 或按重量百分比取锰铁渣 45%、 硫铁矿烧渣 20%及普 通瓷土 35%, 加水磨成泥浆, 或按重量比取锰矿 50%、 黑钨矿 10%及普通瓷土 40%, 加 水磨成泥浆, 将泥浆喷涂在干燥的陶瓷平板素坯的上表面或陶瓷槽板素坯的底板上表 面和侧板内表面上, 经过干燥、 烧制成复合陶瓷太阳能集热实心平板或复合陶瓷太阳 能集热实心凹槽板 4。 The base body of the composite ceramic solar heat collecting solid plate 3 and the composite ceramic solar heat collecting solid groove plate according to the present invention adopts ordinary ceramic raw materials without whiteness requirement, and is pressed into ceramics according to design dimensions by dry pressing molding. The flat plate is made of ceramic, or the ceramic green plate is made by the grooved roll-to-roll method, and 65% of the vanadium tailings and 35% of the common porcelain are extracted by weight, and the slurry is added with water to obtain the ferromanganese. 45% of slag, 20% of pyrite cinder and 35% of ordinary china clay, add water to grind mud, or take 50% of manganese ore, 10% of black tungsten ore and 40% of ordinary china clay by weight ratio, add water to grind mud, spray mud On the upper surface of the dried ceramic slab blank or the upper surface of the bottom plate of the ceramic slab blank and the inner surface of the side plate, dried and fired to form a composite ceramic solar heat collecting solid plate or a composite ceramic solar collector solid groove plate 4.
本发明所述的复合陶瓷太阳能槽形风道,可以安装在中国西北地区寻找高度约 800 米具有幵阔山坡的山脉, 延山脊至山顶建造直径 40米的风道, 在山坡上安装 80平方 公里, 即 8000万平方米的复合陶瓷太阳能集热槽形风道, 风道中安装空气涡轮, 阳光 照射下, 热空气推动空气涡轮带动发电机发电, 功率约 50万千瓦。  The composite ceramic solar trough air passage of the invention can be installed in the northwestern part of China to find a mountain range with a height of about 800 meters and a hillside with a wide slope. The mountain ridge is extended to the top of the mountain to construct a wind tunnel with a diameter of 40 meters, and 80 square kilometers is installed on the hillside. That is, 80 million square meters of composite ceramic solar collector trough air duct, air duct installed in the air duct, under the sun, hot air pushes the air turbine to drive the generator to generate electricity with a power of about 500,000 kilowatts.
在撒哈拉沙漠寻找高度约 800米的山脉,在山顶上建设直径 50米、高 200米的 "烟 囱" , 建造多条直径 10- 20米的通风道与 "烟囱"相通, 将山下南面的沙漠修整成为 坡面, 在现场建设简易工厂, 将厚度 1. 5毫米的成卷的彩钢板用连续辊压成型的方法 压制成为宽度 1000毫米,槽高 200毫米、 400毫米、 600毫米三种高度,每件长度 1000 米的凹形槽板, 凹形槽板的内底面上安装长度 1000毫米, 宽度 1000毫米, 厚度 3毫 米的复合陶瓷太阳能集热实心平板 3 , 在凹形槽板两侧板顶部安装厚度 4毫米的钢化 玻璃板, 形成太阳能集热通道, 将槽高 200毫米、 400毫米、 600毫米的太阳能集热通 道前端敞口和后端敞口相互连接, 形成总长 3000米的复合陶瓷太阳能槽形风道,将截 面积大的一端与通风道相通, 很多条这样的复合陶瓷太阳能槽形风道平行排列, 与通 风道相通, 总面积 300平方公里, 通风道中和 "烟囱"底部安装空气涡轮, 阳光照射 下, 热空气推动空气涡轮带动发电机发电, 功率约 200万千瓦。 热空气的风速由风道 内外温差决定, 发电功率与风速的三次方成正比。 撒哈拉沙漠面积 960万平方公里, 北纬 15-30度, 极度干燥, 是地球上阳光最强烈的地区, 每平方米的阳光能量相当于 中国普通家庭户均耗能量。 沙漠地区非常干燥, 彩钢板不易腐蚀, 上述风道可以具有 很长的使用寿命。 北美洲的沙漠多山, 在北美沙漠寻找连成一片的荒滩、 荒坡、 山峰, 最低点到最 高点的高度差约 1200米, 建造直径 10米- 40米截面积逐步放大的通风道, 从荒滩直 达山顶, 釆用长度 1200毫米, 宽度 800毫米, 槽高 150毫米, 壁厚 5毫米的复合陶瓷 太阳能集热实心凹槽板 4,在复合陶瓷太阳能集热实心凹槽板 4两侧板顶部安装厚度 4 毫米的钢化玻璃板, 形成太阳能集热通道, 将通道首尾相连成为长度 500米的风道, 风道平行排列与通风道相通, 总面积 100平方公里, 通风道中安装空气涡轮, 阳光照 射下, 热空气推动空气涡轮带动发电机发电, 功率约 60万千瓦。 Looking for a mountain range of about 800 meters in the Sahara Desert, a "chimney" with a diameter of 50 meters and a height of 200 meters is built on the top of the mountain. Several air passages with a diameter of 10-20 meters are connected to the "chimney" to trim the desert south of the mountain. As a slope, a simple factory was built on site, and a roll of color steel plate with a thickness of 1.5 mm was pressed into a width of 1000 mm and a height of 200 mm, 400 mm, and 600 mm by continuous roll forming. A concave groove plate with a length of 1000 m. A composite ceramic solar collector solid plate 3 with a length of 1000 mm, a width of 1000 mm and a thickness of 3 mm is mounted on the inner bottom surface of the concave groove plate, and is mounted on the top of both sides of the concave groove plate. The tempered glass plate with a thickness of 4 mm forms a solar heat collecting channel, and the front end opening and the rear end opening of the solar heat collecting channel with the groove height of 200 mm, 400 mm and 600 mm are connected to each other to form a composite ceramic solar trough with a total length of 3000 m. The air duct has a large cross-sectional area communicating with the air passage, and a plurality of such composite ceramic solar trough air passages are arranged in parallel and communicate with the air passage, with a total area of 300 square meters. In the air duct and the bottom of the "chimney", an air turbine is installed. Under the sunlight, the hot air pushes the air turbine to drive the generator to generate electricity with a power of about 2 million kilowatts. The wind speed of hot air is determined by the temperature difference between the inside and outside of the air duct, and the power generation is proportional to the cube of the wind speed. The Sahara Desert covers an area of 9.6 million square kilometers and is 15-30 degrees north latitude. It is extremely dry and is the most intense area on the earth. The energy per square meter is equivalent to the average energy consumption of ordinary Chinese households. The desert area is very dry, and the color steel plate is not easily corroded. The above air duct can have a long service life. The deserts of North America are mountainous. In the North American desert, we look for a series of barren beaches, barren slopes and peaks. The height difference from the lowest point to the highest point is about 1200 meters. The air passages with a diameter of 10 meters to 40 meters are gradually enlarged. From the barren beach to the top of the mountain, a composite ceramic solar collector solid groove plate 4 with a length of 1200 mm, a width of 800 mm, a groove height of 150 mm and a wall thickness of 5 mm is used on both sides of the composite ceramic solar heat collecting solid groove plate 4. A tempered glass plate with a thickness of 4 mm is installed on the top of the plate to form a solar heat collecting channel. The channel is connected end to end to a length of 500 meters. The air passages are arranged in parallel with the air passage, with a total area of 100 square kilometers. An air turbine is installed in the air passage. Under the sunlight, the hot air drives the air turbine to drive the generator to generate electricity with a power of about 600,000 kilowatts.
图中 9是太阳能集热槽形通道前端敞口, 10是太阳能集热槽形通道后端敞口。 In the figure, 9 is the front end opening of the solar heat collecting trough channel, and 10 is the rear end opening of the solar heat collecting trough channel.

Claims

1、 复合陶瓷太阳能集热板, 其特征在于: 它呈矩形, 其基体是普通陶瓷实心平 板 (1), 普通陶瓷实心平板 (1) 的一个平面的表面上覆盖一层烧结的黑色瓷层 (2), 普通陶瓷实心平板 (1) 与其表面烧结的黑色瓷层 (2) 构成复合陶瓷太阳能集热实心 平板 (3), 普通陶瓷实心平板 (1) 上覆盖的黑色瓷层 (2) 是表面粗糙、 布满微小孔 洞的钒钛黑瓷层或者是废渣黑瓷层或者是矿物黑瓷层。 1. Composite ceramic solar collector plate, characterized in that: it is rectangular, the base is a common ceramic solid plate (1), and a flat surface of a common ceramic solid plate (1) is covered with a layer of sintered black porcelain ( 2), ordinary ceramic solid plate (1) black ceramic layer sintered on its surface (2) constitutes a composite ceramic solar collector solid plate (3), ordinary ceramic solid plate (1) covered with black porcelain layer (2) is the surface Rough, vanadium-titanium black ceramic layer covered with tiny holes or black slag layer or mineral black porcelain layer.
2、 根据权利要求 1所述的复合陶瓷太阳能集热板, 其特征在于: 复合陶瓷太阳能 集热实心平板(3) 的长度方向两侧分别设置侧板, 复合陶瓷太阳能集热实心平板(3) 与其长度方向两侧的侧板为一体结构, 其截面呈凹槽形, 复合陶瓷太阳能集热实心平 板 (3) 和其长度方向两侧的侧板构成复合陶瓷太阳能集热实心凹槽板 (4)。  2. The composite ceramic solar heat collecting plate according to claim 1, wherein: the composite ceramic solar heat collecting solid plate (3) is provided with side plates on both sides in the longitudinal direction, and a composite ceramic solar heat collecting solid plate (3) The side plate on both sides of the length direction is a unitary structure, and the cross section is groove-shaped. The composite ceramic solar heat collecting solid plate (3) and the side plates on both sides of the longitudinal direction form a composite ceramic solar heat collecting solid groove plate (4) ).
3、 根据权利要求 2所述的复合陶瓷太阳能集热板, 其特征在于: 复合陶瓷太阳 能集热实心平板(3)或复合陶瓷太阳能集热实心凹槽板(4)的普通陶瓷实心平板(1) 的厚度为 2-8毫米, 黑色瓷层 (2) 的厚度为 0.05-0.5毫米。  3. The composite ceramic solar collector plate according to claim 2, characterized in that: a composite ceramic solid plate (3) or a composite ceramic solar collector solid groove plate (4) of a common ceramic solid plate (1) The thickness of the black porcelain layer (2) is 0.05-0.5 mm.
4、 权利要求 1所述的复合陶瓷太阳能集热板的制作方法, 其特征在于: 将提钒 尾渣或者除提钒尾渣以外的其他工业废渣或者工业矿物与陶瓷原料混合磨制的泥浆覆 盖在以传统陶瓷成型方法成型干燥的陶瓷平板素坯的一而, 再经干燥、 烧制成为基体 是普通陶瓷, 表面层是钒钛黑瓷层或者是废渣黑瓷层或者是矿物黑瓷层的复合陶瓷太 阳能集热实心平板 (3)。  The method for manufacturing a composite ceramic solar heat collecting plate according to claim 1, characterized in that: the vanadium tailings or other industrial wastes other than the vanadium tailings or the slurry of industrial minerals and ceramic raw materials are mixed and ground. In the conventional ceramic molding method, the dried ceramic plate blank is molded, and then dried and fired to form a matrix which is a common ceramic, and the surface layer is a vanadium-titanium black porcelain layer or a waste black ceramic layer or a mineral black porcelain layer. Composite ceramic solar collector solid plate (3).
5、 权利要求 1-3任一项所述的复合陶瓷太阳能集热板制作的复合陶瓷太阳能槽 形风道, 其特征在于: 在复合陶瓷太阳能集热实心平板 (3) 的底平面下面安装非陶瓷 材料制作的底板(5), 底板(5)长度方向两侧分别设置第一侧板(6)和第二侧板(7), 第一侧板 (6) 和第二侧板 (7) 的顶部安装透明板 (8), 非陶瓷材料制作的底板 (5)、 第一侧板 (6)、 第二侧板 (7) 和透明板 (8) 相互连接, 形成上下左右封闭、 前后端 为敞口的太阳能集热槽形通道,复合陶瓷太阳能集热实心平板( 3 )的底平面与底板( 5 ) 紧密接触, 复合陶瓷太阳能集热实心平板 (3) 的两侧面分别与第一侧板 (6) 和第二 侧板(7)紧密接触, 将多件复合陶瓷太阳能集热槽形通道的前端敞口和后端敞口相互 连接形成复合陶瓷太阳能槽形风道。 The composite ceramic solar channel air duct produced by the composite ceramic solar heat collecting plate according to any one of claims 1 to 3, characterized in that: the non-installation of the bottom surface of the composite ceramic solar heat collecting solid plate (3) a bottom plate (5) made of a ceramic material, a first side plate (6) and a second side plate (7), a first side plate (6) and a second side plate (7) respectively disposed on both sides of the bottom plate (5) in the longitudinal direction The top is mounted with a transparent plate (8), the bottom plate (5) made of non-ceramic material, the first side plate (6), the second side plate (7) and the transparent plate (8) are connected to each other to form an upper, lower, left and right closed front and rear end. For the open solar heat collecting trough channel, the bottom plane of the composite ceramic solar heat collecting solid plate (3) is in close contact with the bottom plate (5), and the two sides of the composite ceramic solar heat collecting solid plate (3) are respectively separated from the first side The plate (6) and the second side plate (7) are in close contact, and the front end opening and the rear end opening of the plurality of composite ceramic solar heat collecting trough channels are connected to each other to form a composite ceramic solar trough air duct.
6、 权利要求 2所述的复合陶瓷太阳能集热实心槽形板制作的复合陶瓷太阳能槽 形风道, 其特征在于: 在复合陶瓷太阳能集热实心凹槽板 (4 ) 的两侧板顶部安装透明 板 (8 ), 复合陶瓷太阳能集热实心凹槽板 (4 ) 与透明板 (8 ) 形成上下左右封闭, 前 后端为敞口的太阳能集热槽形通道, 将多件复合陶瓷太阳能集热槽形通道前端敞口和 后端敞口相互连接, 形成复合陶瓷太阳能槽形风道。 6. The composite ceramic solar trough air duct produced by the composite ceramic solar heat collecting solid trough plate according to claim 2, characterized in that: the top of the two sides of the composite ceramic solar heat collecting solid groove plate (4) is installed. The transparent plate (8), the composite ceramic solar collector solid groove plate (4) and the transparent plate (8) are formed by upper and lower left and right sides, and the front and rear ends are open solar heat collecting trough channels, and the multiple composite ceramic solar collectors are collected. The front end opening and the rear end opening of the trough channel are connected to each other to form a composite ceramic solar trough air duct.
7、 根据权利要求 5所述的复合陶瓷太阳能集热板制作的复合陶瓷太阳能槽形风 道, 其特征在于: 所述的非陶瓷材料制作的底板 (5 )、 第一侧板 (6 ) 和第二侧板 (7 ) 为一体, 其截面呈凹槽形, 用金属板压制成型。  7. The composite ceramic solar trough air duct produced by the composite ceramic solar heat collecting plate according to claim 5, wherein: the non-ceramic material is made of a bottom plate (5), a first side plate (6), and The second side plate (7) is integrated and has a groove shape in section, and is press-formed with a metal plate.
8、 根据权利要求 5所述的复合陶瓷太阳能集热板制作的复合陶瓷太阳能槽形风 道, 其特征在于: 所述透明板 (8 ) 是钢化玻璃板。  The composite ceramic solar channel air duct produced by the composite ceramic solar heat collecting plate according to claim 5, wherein the transparent plate (8) is a tempered glass plate.
9、根据权利要求 5、 6、 7或 8任一项所述的复合陶瓷太阳能集热板制作的复合陶 瓷太阳能槽形风道的施工方法, 其特征在于: 将复合陶瓷太阳能槽形风道以一定的坡 度安装在荒坡上或荒漠上, 阳光穿过透明盖板, 复合陶瓷太阳能集热槽板的深色或黑 色底面和 /或内侧面吸收阳光后加热槽形板内的空气,以上升的热气流推动涡轮进行发 电。  The composite ceramic solar trough air duct construction method according to any one of claims 5, 6, 7 or 8, characterized in that: the composite ceramic solar trough air duct is A certain slope is installed on the slope or on the desert. The sunlight passes through the transparent cover. The dark or black bottom surface and/or the inner side of the composite ceramic solar collector plate absorbs sunlight and heats the air in the groove plate to rise. The hot air stream drives the turbine to generate electricity.
10、 根据权利要求 5、 6、 7或 8任一项所述的复合陶瓷太阳能集热板制作的复合 陶瓷太阳能槽形风道的施工方法, 其特征在于: 将复合陶瓷太阳能槽形风道安装在建 筑物房顶上或向阳墙面上加热空气, 向建筑物内提供热空气。  10. The method for constructing a composite ceramic solar trough air duct produced by the composite ceramic solar heat collecting plate according to any one of claims 5, 6, 7 or 8, characterized in that: the composite ceramic solar trough air duct is installed Heat the air on the roof of the building or on the sunny wall to provide hot air to the building.
PCT/CN2010/002247 2010-01-04 2010-12-31 Solar collecting panel of composite ceramic material and solar fluted air duct WO2011079527A1 (en)

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