WO2011013689A1 - 積層型圧電素子およびこれを用いた噴射装置ならびに燃料噴射システム - Google Patents
積層型圧電素子およびこれを用いた噴射装置ならびに燃料噴射システム Download PDFInfo
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- WO2011013689A1 WO2011013689A1 PCT/JP2010/062662 JP2010062662W WO2011013689A1 WO 2011013689 A1 WO2011013689 A1 WO 2011013689A1 JP 2010062662 W JP2010062662 W JP 2010062662W WO 2011013689 A1 WO2011013689 A1 WO 2011013689A1
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- internal electrode
- stress relaxation
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- piezoelectric element
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Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/50—Piezoelectric or electrostrictive devices having a stacked or multilayer structure
- H10N30/508—Piezoelectric or electrostrictive devices having a stacked or multilayer structure adapted for alleviating internal stress, e.g. cracking control layers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M51/00—Fuel-injection apparatus characterised by being operated electrically
- F02M51/06—Injectors peculiar thereto with means directly operating the valve needle
- F02M51/0603—Injectors peculiar thereto with means directly operating the valve needle using piezoelectric or magnetostrictive operating means
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/01—Manufacture or treatment
- H10N30/05—Manufacture of multilayered piezoelectric or electrostrictive devices, or parts thereof, e.g. by stacking piezoelectric bodies and electrodes
- H10N30/053—Manufacture of multilayered piezoelectric or electrostrictive devices, or parts thereof, e.g. by stacking piezoelectric bodies and electrodes by integrally sintering piezoelectric or electrostrictive bodies and electrodes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/80—Constructional details
- H10N30/87—Electrodes or interconnections, e.g. leads or terminals
- H10N30/872—Interconnections, e.g. connection electrodes of multilayer piezoelectric or electrostrictive devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M63/00—Other fuel-injection apparatus having pertinent characteristics not provided for in groups F02M39/00 - F02M57/00 or F02M67/00; Details, component parts, or accessories of fuel-injection apparatus, not provided for in, or of interest apart from, the apparatus of groups F02M39/00 - F02M61/00 or F02M67/00; Combination of fuel pump with other devices, e.g. lubricating oil pump
- F02M63/02—Fuel-injection apparatus having several injectors fed by a common pumping element, or having several pumping elements feeding a common injector; Fuel-injection apparatus having provisions for cutting-out pumps, pumping elements, or injectors; Fuel-injection apparatus having provisions for variably interconnecting pumping elements and injectors alternatively
- F02M63/0225—Fuel-injection apparatus having a common rail feeding several injectors ; Means for varying pressure in common rails; Pumps feeding common rails
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/42—Piezoelectric device making
Definitions
- the present invention relates to a laminated piezoelectric element used as, for example, a piezoelectric driving element (piezoelectric actuator), a pressure sensor element, a piezoelectric circuit element, and the like.
- a conventional multilayer piezoelectric element includes, for example, a laminate in which piezoelectric layers and internal electrode layers are alternately laminated, and is bonded to the side surfaces of the laminate to have different polarities alternately. And a pair of external electrodes that are electrically connected to the internal electrode layer led out.
- an internal electrode layer that is set to have as large an area as possible across the piezoelectric layer is exposed on the side surface of the laminate without forming the external electrode. In this case, discharge on the side surface is prevented. Therefore, an insulating resin is coated on the side surface of the laminate so as to cover the exposed end portion of the internal electrode layer.
- the laminated piezoelectric element is used as a piezoelectric actuator in a fuel injection device (injector) such as an internal combustion engine of an automobile, that is, when used under severe conditions such as being continuously driven at a high temperature, a resin is used.
- the heat resistance is not always sufficient, and there is a problem in that there is a risk of discharge between the internal electrode layers on the side surface of the laminate.
- the present invention has been devised in view of the above-mentioned conventional problems, and the purpose thereof is a laminated type having high durability without cracks developing inside the laminated body even under a severe environment.
- the object is to provide a piezoelectric element.
- the laminated piezoelectric element according to the present invention includes a laminated body in which piezoelectric layers and internal electrode layers are alternately laminated and a stress relaxation layer is disposed in part between the piezoelectric layers, and a side surface of the laminated body.
- a laminated piezoelectric element including an external electrode joined and electrically connected to the internal electrode layer, wherein the internal electrode layer is not exposed on a side surface of the multilayer body, and the stress relaxation layer is It is exposed on the side surface of the laminate.
- An ejection device includes a container having an ejection hole and any one of the multilayer piezoelectric elements according to the present invention, and fluid stored in the container is driven from the ejection hole by driving the multilayer piezoelectric element. It is characterized by being discharged.
- the fuel injection system of the present invention includes a common rail that stores high-pressure fuel, the injection device of the present invention that injects the high-pressure fuel stored in the common rail, a pressure pump that supplies the high-pressure fuel to the common rail, and the injection And an injection control unit for supplying a drive signal to the apparatus.
- a first conductive paste serving as an internal electrode layer is applied to a central region of a main surface of a first piezoelectric ceramic green sheet, and the first conductive paste is applied to an outer peripheral region.
- a step of applying the conductive paste a step of producing a laminated molded body by laminating a predetermined number of the first and second piezoelectric ceramic green sheets, and firing the laminated molded body to thereby produce the piezoelectric
- the internal electrode layers surrounded by the body layers and the dummy internal electrode layers are alternately stacked, and the stress relaxation layer is disposed in a part between the piezoelectric layers.
- a step of producing a layer member and is characterized in that it comprises a step of removing the dummy inner electrode layers together with the outer peripheral region of the piezoelectric layer by grinding the side surfaces of the laminate.
- the multilayer body in which the piezoelectric layers and the internal electrode layers are alternately stacked and the stress relaxation layer is disposed in part between the piezoelectric layers, and the side surface of the multilayer body And an external electrode electrically connected to the internal electrode layer, wherein the internal electrode layer is not exposed on the side surface of the multilayer body, and the stress relaxation layer is formed of the multilayer body. Since the stress relaxation layer is exposed on the side surface of the laminate because it is exposed on the side surface, it is used in a fuel injection device (injector) of an automobile internal combustion engine, that is, a high electric field and high pressure are applied for a long time.
- the cracks generated in the stress relaxation layer reduce the stress caused by the elongation of the laminate, the displacement of the laminate is not restricted and a high displacement can be achieved.
- the internal electrode layer is not exposed on the side surface of the laminate, it is used between the internal electrode layers on the side surface of the laminate even when used in a fuel injection device (injector) of an internal combustion engine of an automobile, that is, at a high temperature. There is no such thing as discharging. Similarly, even when used in water or in chemicals, there is no discharge between the internal electrode layers on the side of the laminate.
- the multilayer piezoelectric element of the present invention cracks do not develop inside the multilayer body even under a harsh environment, and the multilayer piezoelectric element has high durability.
- the container having the injection hole and the multilayer piezoelectric element of the present invention are provided, and the fluid stored in the container is discharged from the injection hole by driving the multilayer piezoelectric element.
- the multilayer piezoelectric element it is possible to prevent the internal electrode layer from being short-circuited due to a crack straddling the internal electrode layer inside the multilayer body, and to prevent the displacement of the multilayer body from being restrained.
- the desired injection can be stably performed over a long period of time.
- a common rail that stores high-pressure fuel
- an injection device of the present invention that injects high-pressure fuel stored in the common rail
- a pressure pump that supplies high-pressure fuel to the common rail
- a drive signal to the injection device Therefore, the desired injection of the high-pressure fuel can be stably performed over a long period of time.
- the multilayer piezoelectric element of the present invention can be reliably and stably manufactured.
- FIG. 2 is a cross-sectional view taken along a line A-A ′ parallel to the stacking direction of the multilayer body of the multilayer piezoelectric element illustrated in FIG. 1.
- FIG. 2 is a cross-sectional view of a portion including an internal electrode in a cross section perpendicular to the stacking direction of the multilayer body of the multilayer piezoelectric element illustrated in FIG. 1.
- FIG. 2 is a cross-sectional view of a portion including a stress relaxation layer in a cross section perpendicular to the stacking direction of the multilayer body of the multilayer piezoelectric element illustrated in FIG. 1.
- FIG. 1 is a cross-sectional view taken along a line A-A ′ parallel to the stacking direction of the multilayer body of the multilayer piezoelectric element illustrated in FIG. 1.
- FIG. 2 is a cross-sectional view of a portion including an internal electrode in a cross section perpendicular to the stacking direction of the multilayer body of the multilayer piezoelectric element illustrated
- 1 shows an example in which slits are formed in the external electrode in the multilayer piezoelectric element shown in FIG. 1, (a) is a side view and a plan view, and (b) to (d) are plan views.
- 1A is a cross-sectional view of a portion including a stress relaxation layer of another example in a cross section perpendicular to the stacking direction of the multilayer body of the multilayer piezoelectric element shown in FIG. 1, and FIG. It is sectional drawing of the site
- 1A is a cross-sectional view of a portion including a stress relaxation layer of another example in a cross section perpendicular to the stacking direction of the multilayer body of the multilayer piezoelectric element shown in FIG. 1, and FIG.
- FIG. 9 is a cross-sectional view taken along the line A-A ′ parallel to the stacking direction of the multilayer body of the multilayer piezoelectric element illustrated in FIG. 8.
- (A)-(d) is a top view which shows the example of the external lead member in the multilayer piezoelectric element of this invention, respectively.
- FIG. 1 is a perspective view showing an example of an embodiment of the multilayer piezoelectric element of the present invention
- FIG. 2 is a cross-sectional view taken along line AA ′ parallel to the stacking direction of the multilayer body of the multilayer piezoelectric element shown in FIG. It is sectional drawing in a cross section.
- 3 is a cross-sectional view of a portion including an internal electrode in a cross section perpendicular to the stacking direction of the multilayer body of the multilayer piezoelectric element shown in FIG. 1
- FIG. 4 is a cross-section of a portion including a stress relaxation layer similar to FIG. FIG. As shown in FIG. 1 to FIG.
- the piezoelectric layers 2 and the internal electrode layers 3 are alternately stacked, and the internal electrodes are formed in a part between the piezoelectric layers 2.
- the laminated body 5 in which the stress relaxation layer 4 that is lower in strength than the layer 3 and easily cracks due to stress is disposed, and is joined to the side surface of the laminated body 5 and electrically connected to the internal electrode layer 3
- the external electrode 6 is included, the internal electrode layer 3 is not exposed on the side surface of the multilayer body 5, and the stress relaxation layer 4 is exposed on the side surface of the multilayer body 5.
- the piezoelectric layer 2 constituting the multilayer body 5 is made of piezoelectric ceramics having piezoelectric characteristics, and is made of, for example, a perovskite oxide made of PbZrO 3 —PbTiO 3 or the like.
- the internal electrode layers 3 are alternately stacked with the piezoelectric layers 2 so as to sandwich the piezoelectric layers 2 from above and below, and a positive electrode and a negative electrode are arranged in the stacking order so that the piezoelectric body sandwiched between them.
- a driving voltage is applied to the layer 2.
- the internal electrode layer 3 is made of, for example, a metal such as silver palladium (Ag—Pd), and in this example, a pair of external electrodes in which the positive electrode and the negative electrode (or the ground electrode) are joined to the opposite side surfaces of the laminate 5, respectively. It is electrically connected to the electrode 6 via the electrode lead portion 3A. That is, the internal electrode layer 3 is not exposed on the side surface of the multilayer body 5 and is led out to the side surface of the multilayer body 5 by the electrode lead-out portion 3A.
- a metal such as silver palladium (Ag—Pd)
- the internal electrode layer 3 is not exposed on the side surface of the multilayer body 5 and is led out to the side surface of the multilayer body 5 by the electrode lead-out portion 3A.
- a stress relaxation layer 4 is disposed in part between the piezoelectric layers 2 of the multilayer body 5 instead of the internal electrode layer 3. Since the stress relaxation layer 4 has a lower strength than the internal electrode layer 3 and is likely to crack due to the stress, the stress relaxation layer 4 has a crack or the like ahead of the internal electrode layer 3 due to the stress generated in the laminated body 5 by driving. Breakage occurs, and the laminate 5 functions as a stress relaxation layer.
- the internal electrode layer 3 is not exposed on the side surface of the multilayer body 5 as in the multilayer piezoelectric element 1 of this example shown in FIGS. The layer 4 is exposed on the side surface of the laminated body 5.
- the multilayer piezoelectric element 1 can be used in a fuel injection device (injector) of an internal combustion engine of an automobile, That is, in use under severe conditions such as continuous driving with a high electric field and high pressure applied for a long time, a crack generated in the laminate 5 due to repeated stress caused by the expansion and contraction of the laminate 5 is exposed to the side surface.
- the cracks that are selectively generated in the stress relaxation layer 4 reduce the stress generated by the expansion and contraction of the multilayer body 5, so that the displacement of the multilayer body 5 is not constrained over a long period of time. A long-term maintenance of high displacement can be achieved.
- the internal electrode layer 3 is not exposed on the side surface of the multilayer body 5, so that it can be used at a high temperature as used in a fuel injection device (injector) of an automobile internal combustion engine. Even when used in the above, no discharge occurs between the internal electrode layers 3 on the side surface of the laminate 5. Furthermore, no discharge occurs on the side surface of the laminate 5 even when used in water or in chemicals.
- the outer edge of the internal electrode layer is not exposed on the side surface of the multilayer body so that the internal electrode layer is not exposed on the side surface of the multilayer body. Since it is made to recede from the side toward the inside of the laminate (that is, the non-formation part of the internal electrode layer is provided around the internal electrode layer (between the outer edge of the piezoelectric layer that hits the side of the laminate))
- the portion functions as a portion that restrains the displacement of the laminated body because the driving voltage is not applied to the piezoelectric layer and the laminated body does not expand and contract.
- the receding distance from the side surface of the laminated body of the internal electrode layer is not uniform over the entire circumference in the direction perpendicular to the laminating direction of the laminated body (parallel to the piezoelectric layer and the internal electrode layer), the receding distance is large. Because the restraining force that restrains the displacement of the laminate is large on the side of the side and the restraining force is small on the side of the side with the smaller receding distance, the laminate does not extend straight in the stacking direction. There may be a problem that the film is inclined and elongated with respect to the stacking direction.
- the internal electrode layer 3 is not exposed on the side surface of the multilayer body 5, but the stress relaxation layer 4 is exposed on the side surface of the multilayer body 5. 1. Even if the receding distance of the internal electrode layer 3 is not uniform in the direction parallel to the internal electrode layer 3 around the internal electrode layer 3, the restraining force that restrains the displacement of the laminate 5 because the receding distance is large. Since cracks are generated in the stress relaxation layer 4 preferentially from the side surface side where a large retraction distance is applied, that is, from the side surface side having a larger receding distance, a greater stress relaxation effect can be obtained on the side surface side having a larger restraining force. As a result, the multilayer piezoelectric element 1 of this example can be displaced straight with respect to the stacking direction of the stacked body 5 by having the stress relaxation layer 4.
- the multilayer piezoelectric element 1 of the present example cracks do not develop inside the multilayer body 5 even under a harsh environment, and has high durability and high reliability over a long period of time. It becomes.
- the receding distance t from the side surface of the multilayer body 5 to the end of the internal electrode layer 3 shown in FIG.
- the thickness it is preferable to set the thickness to 5 ⁇ m to 500 ⁇ m. If the receding distance t is less than 5 ⁇ m, the insulation distance through the side surface of the multilayer body 5 between the adjacent internal electrode layers 3 is short so as not to cause discharge. There is a risk of discharge between the laminate 5 and the outside.
- the receding distance t exceeds 500 ⁇ m
- the area of the piezoelectrically inactive portion where no driving voltage is applied to the piezoelectric layer 2 in the multilayer body 5 increases.
- the discharge and the discharge between the laminated body 5 and the outside do not occur, the amount of displacement is reduced.
- the area of the piezoelectrically inactive portion in the stacked body 5 increases, the stress when the stacked body 5 expands also increases.
- the length of the electrode lead portion 3A that electrically connects the end portion of the internal electrode layer 3 and the external electrode 6 is the same length as the receding distance t, and is preferably in the above range.
- the stress relieving layer 4 having a stress relieving function in the laminate 5 is formed as a layer having a lower strength than the internal electrode layer 3 and susceptible to cracking due to stress.
- a stress relaxation layer 4 includes, for example, a piezoelectric layer that is not sufficiently sintered, a piezoelectric layer or metal layer with many holes, or a layer in which piezoelectric particles and metal particles are independently distributed.
- the stress relaxation layer 4 Since the stress relaxation layer 4 has lower rigidity than the internal electrode layer 3 and therefore lower rigidity than the piezoelectric layer 2, cracks generated from the side surfaces of the multilayer body 5 in the stress relaxation layer 4 are reduced. In other words, it does not progress toward the internal electrode layer 3 by bending. Therefore, since the crack generated in the stress relaxation layer 4 propagates along the stress relaxation layer 4, the crack progresses to the adjacent internal electrode layer 3 through the piezoelectric layer 2 sandwiching the stress relaxation layer 4, The internal electrode layer 3 is not short-circuited.
- the internal electrode layers 3 adjacent to the upper and lower sides of the stress relaxation layer 4 have the same polarity (positive electrodes or negative electrodes). This is because an electric field is not generated between the piezoelectric layers 3 adjacent to the upper and lower sides of the stress relaxation layer 4 (the piezoelectric layer 3 is not distorted).
- the stress relaxation layer 4 contains more holes than the internal electrode layer 3.
- the strength of the stress relaxation layer 4 is lower than the strength of the internal electrode layer 3, and is stably and preferentially selected. In particular, the stress relaxation layer 4 can be cracked.
- the porosity of the stress relaxation layer 4 (the ratio of the volume occupied by the holes in the volume of the stress relaxation layer 4) is The porosity of the internal electrode layer 3 is preferably twice or more than the porosity.
- the holes in the stress relaxation layer 4 are usually circular or a shape in which a plurality of circular ones are connected. In order to effectively lower the strength of the stress relaxation layer 4 so that cracks are selectively generated, it is preferable that the pores of the stress relaxation layer 4 have a shape in which a plurality of holes are connected to each other.
- the stress relaxation layer 4 includes metal portions independent of each other. Since the rigidity of the stress relaxation layer 4 can be lowered by distributing the metal parts softer than the piezoelectric body constituting the piezoelectric layer 2 in an independent state, it is excellent as a stress relaxation layer in the laminate 5. It can be assumed that no cracks develop inside the laminate 5. These metal portions are distributed in a so-called island shape in an independent state in the stress relaxation layer 4. Of course, these metal portions may be present together with pores, and in this case, the effects of both can be obtained synergistically. Since the metal parts are independent from each other in the stress relaxation layer 4, there is no electrical conduction by the metal parts.
- the metal portions independent of each other included in the stress relaxation layer 4 are partially bonded to the adjacent piezoelectric layer 2.
- the strength of the stress relaxation layer 4 can be kept lower, so that it is more effective as a stress relaxation layer in the laminate 5. Will be able to function.
- a plurality of stress relaxation layers 4 are arranged at predetermined intervals in the stacking direction of the stacked body 5.
- stress can be relieved in the entire layered body 5 almost uniformly in the stacking direction of the layered body 5. It is possible to effectively prevent cracks from being formed inside the formed internal electrode layer 3 and laminated body 5.
- the number of layers of the internal electrode layer 3 formed in large numbers is preferably 1/2 or less of the number of layers, preferably 1/8 or less of the number of internal electrode layers 3.
- an interval corresponding to the number of layers may be provided.
- the number of the stress relaxation layers 4 in the multilayer body 5 is reduced when the spacing between the stress relaxation layers 4 is more than half the total number of the internal electrode layers 3, the multilayer body It becomes difficult to relieve stress well over the entire stacking direction of 5.
- the vicinity of both ends in the stacking direction of the stacked body 5 is an inactive portion in which the piezoelectric layer 2 is not sandwiched between the internal electrode layers 3, and the piezoelectric layer 2 does not expand or contract, Since the stress does not occur, the arrangement of the stress relaxation layer 4 may be out of the regularity of the arrangement in the vicinity of the center of the stacked body 5.
- “with a predetermined interval” means not only that the interval between the stress relaxation layers 4 is constant, but also that the layers are laminated even if the intervals vary. This includes the case where the interval is approximated to such an extent that the stress can be relaxed substantially uniformly over the entire region of the body 5 in the stacking direction. Specifically, the interval may be within a range of ⁇ 20%, preferably within a range of ⁇ 15% with respect to the average value of the interval between the stress relaxation layers 4.
- the external electrode 6 includes another example of the external electrode 6 in the multilayer piezoelectric element 1 in a side view and a plan view in FIG. As shown in a plan view in FIG. 6D, it is preferable to form slits 7 at portions corresponding to each other between the piezoelectric layers 2 on which the stress relaxation layers 4 are disposed. In this case, by forming the slit 7 in the external electrode 6, the stress applied repeatedly to the external electrode 6 when the laminate 5 is expanded and contracted can be dispersed by the slit 7 in the external electrode 6. Therefore, it is possible to effectively prevent the external electrode 6 from peeling from the side surface of the multilayer body 5 by driving for a long period of time.
- the slit 7 formed in the external electrode 6 is printed with the conductive paste to be the external electrode 6. After baking, it can be formed by cutting a portion corresponding to the stress relaxation layer 4 with a dicing apparatus or the like.
- the slit 7 can be formed by processing a notch in a portion corresponding to the stress relaxation layer 4, and the position of the slit 7 can be formed on the metal plate. What is necessary is just to join the external electrode 6 to the side surface of the laminated body 5 according to the position of the stress relaxation layer 4. In FIG. 5, the laminated body 5 and the internal electrode layer 3 are not shown.
- the slits 7 formed in the external electrode 6 extend over the entire width of the external electrode 6 over the entire region in the width direction of the external electrode 6 (the direction perpendicular to the stacking direction of the multilayer body 5, that is, the direction along the internal electrode layer 3). It is preferable that the external electrode 6 is formed continuously without being divided up and down. In this case, specifically, as shown in a side view and a plan view of the external electrode 6 in the multilayer piezoelectric element 1 in FIG. 5A, the external electrode 6 extends in the width direction but in the thickness direction. It is preferable to form a slit 7 that does not penetrate through the slit 7. Further, as another structure, as shown in a plan view in FIG.
- FIG. 5 (b) it may be formed in a so-called comb-tooth shape on one of the left and right sides of the external electrode 6, or in FIG. 5 (c). As shown in FIG. 5, it may be formed alternately from the left and right sides, or a plurality of short slits 7 may be formed side by side along the corresponding internal electrode layer 3 as shown in FIG.
- the width of the slit 7 is preferably set to 30 ⁇ m or less in accordance with the thickness of the corresponding internal electrode layer 3 so as not to greatly reduce the strength of the external electrode 6 or increase the resistance. Further, the depth of the slit 7 penetrates the external electrode 6 through the entire thickness of the external electrode 6 when the external electrode 6 is not divided by the slit 7 as in the example shown in FIGS. Although it is preferable from the point of stress relaxation, even if it does not cover the entire thickness, it is preferable to form it at a half depth.
- the stress relaxation layer 4 preferably has a non-formation region between the piezoelectric layers 2. That is, in the example shown in FIG. 6 (a), the central portion of the stress relaxation layer 4 is shown in FIGS. 6 (a) and 6 (b). In the example shown in FIG. 6B, the circular non-forming region 4A is provided at the center of the stress relaxation layer 4 with an elliptical non-forming region 4A in which the direction perpendicular to the external electrodes 6 is the long axis. It is. Since the stress relaxation layer 4 has the non-formation region 4A between the piezoelectric layers 2, the upper and lower piezoelectric layers 2 can be bonded to each other in the non-formation region 4A.
- the force generated by the expansion and contraction of the stacked body 5 when the body 5 is driven can be reliably transmitted to the stacking direction of the stacked body 5 without using the stress relaxation layer 4 having a low strength. Further, even when the stress relaxation layer 4 is cracked and propagated as the multilayer piezoelectric element 1 is driven, the upper and lower piezoelectric layers 2 are connected to each other through the non-formation region 4A of the stress relaxation layer 4. Since the upper and lower piezoelectric layers 2 are not completely separated from each other, it is possible to prevent the laminated body 5 from being divided apart at the stress relaxation layer 4 portion. it can.
- the shape of the non-formation region 4A provided in the stress relaxation layer 4 can be various shapes such as a rectangular shape in addition to a circular shape and an elliptical shape as shown in FIG. Further, the number of the non-formation regions 4A may be plural as well as one at the center as shown in FIG. In addition, since the crack which arises in the stress relaxation layer 4 arises from the outer periphery exposed to the side surface of the laminated body 5 fundamentally, it is preferable to arrange
- FIGS. 7 (a) and 6 (b) are respectively shown in FIGS.
- the stress relaxation layer 4 is preferably divided between the piezoelectric layers 2 by the non-formation region 4 ⁇ / b> A.
- the stress relaxation layer 4 is divided by the non-formation region 4A between the positive electrode and the negative external electrode 6.
- the stress relaxation layer 4 is divided by the non-formation region 4A
- the upper and lower piezoelectric layers 2 are bonded to the non-formation region 4A across the opposite side surfaces or between the adjacent side surfaces of the laminate 5. Therefore, the above-described effects can be obtained more reliably. That is, it is possible to prevent the laminated body 5 from being divided apart at the stress relaxation layer 4 due to internal stress, and the generated force can be reliably transmitted when the laminated piezoelectric element is driven. Further, when divided between the positive electrode and the negative external electrode 6 by the non-formation region 4A, even when the multilayer piezoelectric element 1 is used in the liquid, the positive external electrode 6 and the negative external electrode 6 It is possible to reliably prevent the occurrence of a short circuit between them.
- FIG. 8 is a perspective view similar to FIG. 1, and FIG. 9 is a cross-sectional view taken along the line AA ′ similar to FIG. 2 in the multilayer piezoelectric element of the present invention.
- the external lead member 9 is preferably bonded to the surface of the external electrode 6 via a conductive bonding material 8. According to this, even when a large current is applied to the external electrode 6 to drive the multilayer piezoelectric element 1 at a high speed, the current supply to the external electrode is dispersed, and a large current is supplied to the conductive bonding member 8 and the external lead member 9. Therefore, local heat generation of the external electrode 6 can be suppressed.
- the external lead member 9 Since the external lead member 9 has a flexible structure with respect to the expansion / contraction direction of the laminate 5 as will be described later, even if the external electrode 6 is provided with the slit 7, the external lead member 9 is separated by the slit 7. Since current can be supplied to each external electrode 6, there is no possibility that power is not supplied to some of the piezoelectric layers 2. Further, since the external lead member 9 can follow the movement of the external electrode 6, even if the external electrode 6 is provided with a slit, the external electrode 6 is not disconnected.
- 10 is a lead wire
- 11 is a lead wire connecting material.
- the lead wire 10 is connected to the external lead member 9 using a lead wire connecting material 11.
- the lead wire 10 and the lead wire connecting material 11 replace the external lead member 9 and the conductive bonding member 8 in the example shown in FIGS. 1 and 2.
- the conductive bonding material 8 is made of conductive resin or solder.
- the conductive resin is preferable in that the material is flexible, and therefore can satisfactorily follow the deformation of the external electrode 6 accompanying the displacement of the laminate 5.
- a conductive resin it is preferable to use a metal such as silver (Ag), gold (Au), nickel (Ni) or copper (Cu) or an alloy thereof as a conductive material.
- silver powder that is excellent in oxidation resistance, low resistance, and relatively inexpensive.
- the conductive material in the conductive bonding material 8 made of a conductive resin is used as a powder, but the shape thereof is aspherical such as a needle shape or flake shape in order to lower the resistance value and increase the strength. Good.
- silicone, epoxy, polyimide, polyamide, or the like can be used, but it is preferable to use polyimide in consideration of use at a high temperature.
- the external lead member 9 can be used to expand and contract the laminate 5 as shown in plan views in FIGS. 10 (a) to 10 (d).
- a shape that follows is preferable. That is, wire rods as shown in FIG. 10 (a) arranged in a direction perpendicular to the stacking direction of the laminated body 5, metal mesh as shown in FIG. 10 (b), and FIG. 10 (c)
- a metal plate is processed so as to follow the expansion and contraction of the laminate 5 as shown, and a slit is provided, or the metal plate is processed so as to follow the extension and contraction of the laminate 5 as shown in FIG.
- a through hole provided can be used. Examples using these external lead members 9 are the examples shown in FIGS.
- the external lead member 9 is connected and fixed to the external electrode 6 by the conductive bonding material 8, but a part of the external lead member 9 is preferably embedded in the conductive bonding material 8. This is to increase the strength of attachment of the external lead member 9 to the external electrode 6.
- a piezoelectric ceramic green sheet to be the piezoelectric layer 2 is produced.
- a ceramic slurry is prepared by mixing a calcined powder of piezoelectric ceramic, a binder made of an organic polymer such as acrylic or butyral, and a plasticizer. Then, by using a tape molding method such as a doctor blade method or a calender roll method, a piezoelectric ceramic green sheet is produced using this ceramic slurry.
- any material having piezoelectric characteristics may be used.
- a perovskite oxide made of lead zirconate titanate (PZT: PbZrO 3 -PbTiO 3 ) can be used.
- a plasticizer dibutyl phthalate (DBP) or dioctyl phthalate (DOP) can be used.
- an internal electrode layer conductive paste to be the internal electrode layer 3 is prepared.
- a conductive paste for internal electrode layers is prepared by adding and mixing a binder and a plasticizer to a metal powder of a silver-palladium alloy.
- This internal electrode layer conductive paste is used not only for the formation of the internal electrode layer 3 but also for the formation of the electrode lead portion 3A.
- silver powder and palladium powder may be mixed.
- a stress relaxation layer paste to be the stress relaxation layer 4 is prepared.
- a stress relaxation layer paste is prepared by adding and mixing a binder and a plasticizer to a metal powder prepared so as to have a higher silver ratio than the internal electrode layer conductive paste.
- silver powder and palladium powder may be mixed, silver palladium alloy powder may be used, or silver powder may be further added to the internal electrode layer conductive paste.
- the stress relaxation layer 4 has a lower strength than the internal electrode layer 3 and is likely to crack due to stress, so that a layer having a large number of pores or a particle-like layer is relatively loosely bonded. Or a so-called brittle material.
- various pastes such as a mixture of acrylic beads as described later can be used.
- the internal electrode layer conductive paste is applied on the piezoelectric ceramic green sheet in the pattern of the internal electrode layer 3 by, for example, a screen printing method.
- the internal electrode layer conductive paste is applied to the pattern of the internal electrode layer 3, and at the same time, the internal electrode layer conductive paste is applied to the pattern of the electrode lead portion 3 ⁇ / b> A.
- a stress relaxation layer paste is applied on another piezoelectric ceramic green sheet in a pattern of the stress relaxation layer 4 by a screen printing method.
- the pattern of the stress relaxation layer 4 may be formed so as to be the entire surface with respect to a cross section perpendicular to the stacking direction of the stacked body 5, or a non-formed portion (a non-formed portion that becomes a non-formed region 4 ⁇ / b> A inside thereof). A portion where the stress relaxation layer paste is not printed) may be formed.
- the positive electrode and the negative electrode 6 be formed in a pattern in which the space between the external electrodes 6 is divided by the non-forming region 4A.
- a predetermined number of piezoelectric ceramic green sheets coated with the internal electrode layer conductive paste are laminated.
- the piezoelectric ceramic green sheets coated with the stress relaxation layer paste are laminated at a predetermined interval (the number of piezoelectric ceramic green sheets).
- the piezoelectric layers 2 and the internal electrode layers 3 and some of the piezoelectric layers are alternately laminated by firing at a temperature of 900 to 1200 ° C.
- positioned between 2 is produced.
- the silver component in the stress relaxation layer paste is piezoelectrically transferred to the internal electrode layer conductive paste. Since it diffuses through the ceramic green sheet, in the stress relaxation layer 4 after firing, the metal components remain as metal parts independent of each other and are distributed like islands. Becomes a layer with low rigidity. Further, the stress relaxation layer 4 has many voids (holes).
- the amount of silver diffusion due to the silver concentration gradient is reduced. It is preferable that a second conductive paste that becomes a dummy internal electrode layer after firing is applied in advance to the portion that is removed by the shape processing after firing.
- the internal electrode layer conductive paste as the first conductive paste that becomes the internal electrode layer 3 and the electrode lead portion 3A after firing in the pattern of the internal electrode layer 3 and the electrode lead portion 3A on the first piezoelectric ceramic green sheet Is applied by screen printing to surround the internal electrode layer conductive paste (first conductive paste) at a predetermined interval from the internal electrode layer conductive paste (first conductive paste). Then, a second conductive paste that becomes a dummy internal electrode layer after sintering is applied on the same first piezoelectric ceramic green sheet by a screen printing method.
- the internal electrode layer conductivity is obtained in a pattern of a plurality of internal electrode layers 3 and electrode lead-out portions 3A so as to form a plurality of stacked piezoelectric elements after being fired and divided.
- the paste first conductive paste
- the patterns of the internal electrode layer conductive paste are arranged between the patterns at a predetermined interval.
- the second conductive paste may be printed as described.
- first piezoelectric ceramic green sheets coated with the internal electrode layer conductive paste (first conductive paste) and the second conductive paste are laminated.
- second piezoelectric ceramic green sheet coated with the third conductive paste as the stress relaxation layer paste is laminated at a predetermined interval (the number of piezoelectric ceramic green sheets).
- the substrate is baked at a temperature of 900 to 1200 ° C., thereby the piezoelectric layers 2 and the internal electrode layers 3 surrounded by the dummy internal electrode layers are alternately laminated. And the laminated body 5 provided with the stress relaxation layer 4 arrange
- the stress relaxation layer paste (the third paste) corresponding to the portion where the internal electrode layer conductive paste (first conductive paste) is not applied across the first or second piezoelectric ceramic green sheet.
- the diffusion of silver is also promoted by the concentration gradient with respect to the second conductive paste applied along with the internal electrode layer conductive paste (first conductive paste) at a predetermined interval. Therefore, in the stress relaxation layer 4 after firing, the metal components remain as metal portions independent of each other and are distributed in an island shape. The rigidity is lower than that of the internal electrode layer 3, and voids (voids) ) Can be formed.
- the second conductive paste is the same paste as the internal electrode layer conductive paste (first conductive paste) or the internal electrode layer conductive paste (first conductive paste).
- a paste made of silver palladium having a low silver ratio in either case, the silver ratio is lower than the stress relaxation layer paste (third conductive paste)) may be used.
- the pattern of the internal electrode layer and the pattern of the dummy internal electrode layer are simultaneously applied at a predetermined interval. It is good in terms of paste pattern accuracy and paste application productivity.
- the formation of the stress relaxation layer 4 is not limited to the above manufacturing method.
- the stress relaxation layer paste may be a mixture of a material that disperses and disappears during firing (for example, acrylic beads) and silver palladium powder, a binder, and a plasticizer, or a material that disperses and disappears during firing (for example, acrylic Beads), calcined powder of piezoelectric ceramics, a binder and a plasticizer can be used.
- the amount of pores in the stress relaxation layer 4 can be adjusted by the amount of acrylic beads contained in the stress relaxation layer paste.
- the laminated body 5 obtained by firing is subjected to a grinding process on the side surface so as to have a predetermined shape using a surface grinder or the like.
- the portion where the dummy internal electrode layer is formed by applying the above-described second conductive paste is removed together with the outer peripheral portion of the piezoelectric layer 2 by this shape processing (grinding to the side surface).
- the laminated body 5 in which the piezoelectric layers 2 and the internal electrode layers 3 are alternately laminated and the stress relaxation layer 4 is disposed in a part between the piezoelectric layers 2 is produced.
- a silver glass conductive paste containing silver as a main component and containing glass is applied to the side surface from which the electrode lead-out portion 3A electrically connected to the internal electrode layer 3 of the multilayer body 5 in the pattern of the external electrode 6 is derived.
- Printing is performed and baking is performed at 650 to 750 ° C. to form the external electrode 6.
- slits 7 are formed on the external electrodes 6 corresponding to the stress relaxation layer 4 using a dicing apparatus or the like.
- the external lead member 9 is connected and fixed to the surface of the external electrode 6 via the conductive bonding material (solder) 8.
- the external lead member 9 is connected and fixed by the conductive bonding material 8 after the slit 7 is formed in the external electrode 6. To do.
- the multilayer piezoelectric element 1 connects each external electrode 6 and an external power source via an external lead member 9 and applies a driving voltage to the piezoelectric layer 2, thereby causing each piezoelectric layer 2 to have an inverse piezoelectric effect. Can be greatly displaced. This makes it possible to function as an automobile fuel injection valve that injects and supplies fuel to the engine, for example.
- FIG. 11 is a schematic cross-sectional view showing an example of an embodiment of an injection device of the present invention.
- the multilayer piezoelectric element 1 of the above example is accommodated inside a storage container (container) 23 having an injection hole 21 at one end.
- a needle valve 25 capable of opening and closing the injection hole 21 is disposed in the storage container 23 in the storage container 23 .
- a fluid passage 27 is disposed in the injection hole 21 so that it can communicate with the movement of the needle valve 25.
- the fluid passage 27 is connected to an external fluid supply source, and fluid is always supplied to the fluid passage 27 at a high pressure. Therefore, when the needle valve 25 opens the injection hole 21, the fluid supplied to the fluid passage 27 is discharged from the injection hole 21 to the outside or an adjacent container, for example, a fuel chamber (not shown) of the internal combustion engine. It is configured.
- the upper end portion of the needle valve 25 is a piston portion 31 having a larger inner diameter than other portions, and the piston portion 31 slides on the inner wall of the cylindrical storage container 23.
- the multilayer piezoelectric element 1 of the present invention of the above-described example is stored.
- the fluid passage 27 may be opened by applying a voltage to the multilayer piezoelectric element 1 and the fluid passage 27 may be closed by stopping the application of the voltage.
- the injection device 19 of this example includes a container 23 having an injection hole 21 and the multilayer piezoelectric element 1 of the above example, and the fluid filled in the container 23 is ejected by driving the multilayer piezoelectric element 1. It may be configured to discharge from the hole 21.
- the multilayer piezoelectric element 1 does not necessarily have to be inside the container 23, as long as the multilayer piezoelectric element 1 is configured to apply pressure for controlling the ejection of fluid to the inside of the container 23 by driving the multilayer piezoelectric element 1. Good.
- the fluid includes various liquids and gases such as a conductive paste in addition to fuel, ink, and the like.
- the injection device 19 of this example that employs the multilayer piezoelectric element 1 of the above example is used for an internal combustion engine, the fuel is accurately injected into the combustion chamber of the internal combustion engine such as an engine over a longer period than the conventional injection device. Can be made.
- FIG. 12 is a schematic diagram showing an example of an embodiment of a fuel injection system of the present invention.
- the fuel injection system 35 of this example includes a common rail 37 that stores high-pressure fuel as a high-pressure fluid, and a plurality of injection devices 19 of the above-described examples that inject the high-pressure fluid stored in the common rail 37.
- a pressure pump 39 for supplying a high-pressure fluid to the common rail 37 and an injection control unit 41 for supplying a drive signal to the injection device 19 are provided.
- the injection control unit 41 controls the amount and timing of high-pressure fluid injection based on external information or an external signal. For example, if the fuel injection system 35 of this example is used for fuel injection of the engine, the amount and timing of fuel injection can be controlled while sensing the condition in the combustion chamber of the engine with a sensor or the like.
- the pressure pump 39 serves to supply fluid fuel from the fuel tank 43 to the common rail 37 at a high pressure. For example, in the case of an engine fuel injection system 35, fluid fuel is fed into the common rail 37 at a high pressure of about 1000 to 2000 atmospheres (about 101 MPa to about 203 MPa), preferably about 1500 to 1700 atmospheres (about 152 MPa to about 172 MPa).
- the high-pressure fuel sent from the pressure pump 39 is stored and sent to the injection device 19 as appropriate.
- the injection device 19 injects a certain fluid from the injection hole 21 to the outside or an adjacent container as described above.
- the target for injecting and supplying fuel is an engine
- high-pressure fuel is injected in a mist form from the injection hole 21 into the combustion chamber of the engine.
- the external electrodes 6 in the multilayer piezoelectric element 1 are formed one by one on the two opposite side surfaces of the multilayer body 5 in the above example, but the two external electrodes 6 are formed on adjacent side surfaces of the multilayer body 5. Alternatively, it may be formed on the same side surface of the stacked body 5.
- the cross-sectional shape in the direction orthogonal to the stacking direction of the stacked body 5 is not limited to the quadrangular shape that is an example of the above embodiment, but a polygonal shape such as a hexagonal shape or an octagonal shape, a circular shape, or a straight line and an arc. You may be the shape which combined.
- the multilayer piezoelectric element 1 of this example is used for, for example, a piezoelectric drive element (piezoelectric actuator), a pressure sensor element, a piezoelectric circuit element, and the like.
- the driving element include a fuel injection device for an automobile engine, a liquid injection device such as an inkjet, a precision positioning device such as an optical device, and a vibration prevention device.
- the sensor element include a combustion pressure sensor, a knock sensor, an acceleration sensor, a load sensor, an ultrasonic sensor, a pressure sensor, and a yaw rate sensor.
- Examples of the circuit element include a piezoelectric gyro, a piezoelectric switch, a piezoelectric transformer, and a piezoelectric breaker.
- a piezoelectric actuator provided with the multilayer piezoelectric element of the present invention was produced as follows. First, a ceramic slurry was prepared by mixing calcined powder of a piezoelectric ceramic mainly composed of lead zirconate titanate (PZT: PbZrO 3 —PbTiO 3 ) having an average particle size of 0.4 ⁇ m, a binder and a plasticizer. Using this ceramic slurry, a piezoelectric ceramic green sheet serving as a piezoelectric layer having a thickness of 100 ⁇ m was prepared by a doctor blade method.
- PZT lead zirconate titanate
- a binder was added to the silver-palladium alloy to produce an internal electrode layer and an internal electrode layer conductive paste (first conductive paste) to be an electrode lead portion.
- the silver-palladium ratio at this time was 95% by mass of silver and 5% of palladium.
- a binder was added to the silver-palladium alloy to produce a stress relaxation layer paste (third conductive paste) to be a stress relaxation layer.
- the silver-palladium ratio at this time was 99% by mass of silver and 1% of palladium.
- the internal electrode layer conductive paste (first conductive paste) was printed on one side of the first piezoelectric ceramic green sheet by the screen printing method in the pattern shown in FIG.
- first conductive paste the same composition as the conductive paste for the internal electrode layer (first conductive paste) is also applied to the first piezoelectric ceramic green sheet which is the outer peripheral portion of the laminate corresponding to the portion removed by the shape processing after firing.
- the pattern which becomes a dummy internal electrode layer was printed with the second conductive paste.
- a stress relaxation layer paste (third conductive paste) was printed on one side of another second piezoelectric ceramic green sheet by a screen printing method in the pattern shown in FIG.
- the stress relaxation layer paste (in proportion of 20 sheets of the first piezoelectric ceramic green sheet printed with the internal electrode layer conductive paste (first conductive paste) and the second conductive paste) A second piezoelectric ceramic green sheet printed with a third conductive paste) was laminated. A total of 300 first piezoelectric ceramic green sheets on which the internal electrode layer conductive paste (first conductive paste) and the second conductive paste are printed are used as stress relaxation layer paste (third conductive paste). A total of 15 second piezoelectric ceramic green sheets printed with the paste) were laminated.
- a silver glass paste prepared by adding glass, a binder, and a plasticizer to silver powder was printed on the side surface of the laminate with an external electrode pattern, and baked at 700 ° C. to form an external electrode. Then, a lead wire as an external lead member was connected and fixed to the external electrode using solder as a conductive bonding material.
- the multilayer piezoelectric element (sample number 1) of the example in which the internal electrode layer was not exposed on the side surface of the multilayer body and the stress relaxation layer was exposed on the side surface of the multilayer body was manufactured.
- metal parts mainly composed of silver were distributed in islands independently of each other.
- the size of the independent metal part was 2 ⁇ m on average.
- the porosity of the stress relaxation layer was 60%.
- the porosity of the internal electrode was 10%. The porosity is determined by cutting the laminate with a cross section parallel to the stacking direction, mirror-finishing the cross section, photographing with a metallurgical microscope, and calculating the porosity from the ratio of the area of the pores in the field of view. Calculated.
- Comparative Example 1 a laminated body in which a stress relaxation layer was not laminated and an internal electrode layer was exposed on the side surface was produced, and a laminated piezoelectric element (sample number 2) in which the side surface of this laminated body was coated with a silicone resin. ) was produced.
- Comparative Example 2 a laminated body in which the stress relaxation layer was not laminated and the internal electrode layer was not exposed on the side surface was produced, and a laminated piezoelectric element (Sample No. 3) was produced.
- the piezoelectric layer was subjected to polarization treatment by applying a DC electric field of 3 kV / mm to the external electrode for 15 minutes via the external lead member.
- the laminated piezoelectric element (Sample No. 1) of the example of the present invention showed no abnormality even when continuously driven up to 1 ⁇ 10 7 times. This is because the internal electrode layer is not exposed on the side surface of the multilayer body, so that the occurrence of discharge on the side surface of the multilayer body can be prevented even when driven at a high temperature.
- the stress relaxation layer By providing the stress relaxation layer, cracks can be selectively generated in the stress relaxation layer with respect to the stress repeatedly generated by the extension and contraction of the laminate, thereby relaxing the stress of the laminate. This is because no cracks occurred in the piezoelectric layer and the internal electrode layer.
- sample number 4 the same laminated piezoelectric element (sample number 4) as that of sample number 1 was prepared except that a slit was provided in the external electrode corresponding to the stress relaxation layer. This slit was formed so as to extend over the entire width direction of the external electrode, the depth was from the surface of the external electrode to half the thickness direction, and the width of the slit was 30 ⁇ m.
- sample number 5 the same laminated piezoelectric element (sample number 5) as that of sample number 1 was prepared except that the stress relaxation layer was formed in the pattern shown in FIG.
- this multilayer piezoelectric element of sample number 5 was continuously driven up to 5 ⁇ 10 7 times by applying an AC voltage of 0 V to +160 V at a frequency of 150 Hz in an atmosphere of 150 ° C. The occurrence of was not observed.
- this multilayer piezoelectric element of sample number 6 was continuously driven up to 5 ⁇ 10 7 times by applying an AC voltage of 0 V to +160 V at a frequency of 150 Hz in an atmosphere of 150 ° C. The occurrence of was not observed.
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Abstract
Description
2・・・圧電体層
3・・・内部電極層
3A・・・電極引出部
4・・・応力緩和層
4A・・・非形成領域
5・・・積層体
6・・・外部電極
7・・・スリット
8・・・導電性接合材
9・・・外部リード部材
10・・・リード線
11・・・リード線接続材
19・・・噴射装置
21・・・噴射孔
23・・・収納容器(容器)
25・・・ニードルバルブ
27・・・流体通路
29・・・シリンダ
31・・・ピストン
33・・・皿バネ
35・・・燃料噴射システム
37・・・コモンレール
39・・・圧力ポンプ
41・・・噴射制御ユニット
43・・・燃料タンク
Claims (11)
- 圧電体層および内部電極層が交互に積層されているとともに前記圧電体層間の一部に応力緩和層が配置されている積層体と、該積層体の側面に接合されて前記内部電極層に電気的に接続された外部電極とを含む積層型圧電体素子であって、前記内部電極層は前記積層体の側面に露出しておらず、前記応力緩和層は前記積層体の側面に露出していることを特徴とする積層型圧電素子。
- 前記応力緩和層は、前記内部電極層よりも空孔を多く含んでいることを特徴とする請求項1に記載の積層型圧電素子。
- 前記応力緩和層は、互いに独立した金属部分を含んでいることを特徴とする請求項1または請求項2に記載の積層型圧電素子。
- 前記応力緩和層は、前記積層体の積層方向に所定の間隔をおいて複数配置されていることを特徴とする請求項1乃至請求項3のいずれかに記載の積層型圧電素子。
- 前記外部電極は、前記応力緩和層が配置されている前記圧電体層間に対応する部位にスリットが形成されていることを特徴とする請求項1乃至請求項4のいずれかに記載の積層型圧電素子。
- 前記応力緩和層は、前記圧電体層間において非形成領域を有していることを特徴とする請求項1乃至請求項5のいずれかに記載の積層型圧電素子。
- 前記応力緩和層は、前記圧電体層間において前記非形成領域によって分割されていることを特徴とする請求項6に記載の積層型圧電素子。
- 前記外部電極の表面に導電性接合材を介して外部リード部材が接合されていることを特徴とする請求項1乃至請求項7のいずれかに記載の積層型圧電素子。
- 噴射孔を有する容器と、請求項1乃至請求項8のいずれかに記載の積層型圧電素子とを備え、前記容器内に蓄えられた流体が前記積層型圧電素子の駆動により前記噴射孔から吐出されることを特徴とする噴射装置。
- 高圧燃料を蓄えるコモンレールと、該コモンレールに蓄えられた前記高圧燃料を噴射する請求項9に記載の噴射装置と、前記コモンレールに前記高圧燃料を供給する圧力ポンプと、前記噴射装置に駆動信号を与える噴射制御ユニットとを備えたことを特徴とする燃料噴射システム。
- 第1の圧電セラミックグリーンシートの主面の中央領域に内部電極層となる第1の導電性ペーストを塗布するとともに、外周領域に前記第1の導電性ペーストを所定の間隔をあけて取り囲んでダミー内部電極層となる第2の導電性ペーストを塗布する工程と、
第2の圧電セラミックグリーンシートの主面の全面に、応力緩和層となる第3の導電性ペーストを塗布する工程と、
前記第1および第2の圧電セラミックグリーンシートを所定の枚数積層することによって積層成形体を作製する工程と、
該積層成形体を焼成することによって、前記圧電体層および前記ダミー内部電極層に取り囲まれた前記内部電極層が交互に積層されているとともに前記圧電体層間の一部に前記応力緩和層が配置されている積層体を作製する工程と、
該積層体の側面を研削することによって前記圧電体層の外周領域とともに前記ダミー内部電極層を除去する工程と
を具備していることを特徴とする積層型圧電素子の製造方法。
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CN2010800327757A CN102473834A (zh) | 2009-07-28 | 2010-07-28 | 层叠型压电元件及使用该层叠型压电元件的喷射装置以及燃料喷射系统 |
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