WO2011004122A2 - Procédé de production d'hydrocarbures synthétiques à partir de matières carbonées - Google Patents
Procédé de production d'hydrocarbures synthétiques à partir de matières carbonées Download PDFInfo
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- WO2011004122A2 WO2011004122A2 PCT/FR2010/051436 FR2010051436W WO2011004122A2 WO 2011004122 A2 WO2011004122 A2 WO 2011004122A2 FR 2010051436 W FR2010051436 W FR 2010051436W WO 2011004122 A2 WO2011004122 A2 WO 2011004122A2
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- WIPO (PCT)
- Prior art keywords
- production
- elementary
- module
- carbonaceous material
- synthetic hydrocarbons
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Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/002—Removal of contaminants
- C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
- C10K1/005—Carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/026—Increasing the carbon monoxide content, e.g. reverse water-gas shift [RWGS]
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1656—Conversion of synthesis gas to chemicals
- C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1684—Integration of gasification processes with another plant or parts within the plant with electrolysis of water
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
Definitions
- the present invention generally relates to processes for producing synthetic hydrocarbons from carbonaceous materials.
- Such units must be installed next to a very large source of carbonaceous material, or must be supplied from many smaller sources spread over a large area.
- the invention aims to provide a synthetic hydrocarbon production process that can be implemented, among other things, far from the important sources of carbonaceous materials, with a low energy cost for supply.
- the invention relates to a process for producing synthetic hydrocarbons from at least one carbonaceous material, the process comprising the following steps:
- each basic production unit having an elementary production capacity of between 100 and 1000 barrels per day of synthetic hydrocarbons ; - construct the said number of elementary production units in the said territory;
- the territory has an area of less than 10 000 km 2 ;
- the resources of said carbonaceous material come from a plurality of localized sources, the elementary production units being constructed on the same site, said site being less than 200 km from each of the sources of said carbonaceous material;
- the resources of said carbonaceous material come from a plurality of localized sources, the elementary production units being built on the same site, said site being chosen such that the average distance of said sources of carbonaceous material at said site is less than 100; km;
- each elementary production unit has an elementary production capacity of between 100 and 500 barrels per day of synthetic hydrocarbons
- each basic production unit includes:
- An electrolyzer capable of supplying hydrogen to the conversion module and to the production module of the first hydrocarbon stream and possibly oxygen to the production module of the first gas stream; the conversion module and the production module of the first synthetic hydrocarbon stream are dedicated to the corresponding elementary production unit;
- the production module of the first gas stream is dedicated to the corresponding elementary production unit
- the production module of the first gas stream is common to at least two elementary production units
- each elementary production unit comprises a post-processing module designed to produce at least a second stream of synthetic hydrocarbons from the first stream of synthetic hydrocarbons, the post-treatment module being dedicated to the corresponding elementary production unit;
- each elementary production unit comprises a post-treatment module designed to produce at least a second stream of synthetic hydrocarbons from the first synthetic hydrocarbon stream, the post-treatment module being common to at least two elementary production units;
- the electrolyser is dedicated to the corresponding elementary production unit
- the electrolysers of the elementary production units are supplied with electricity from an electrical distribution network serving at least one electrical consumer other than the elementary production units, the method comprising the following steps:
- Figure 1 is a step diagram showing the main steps of the method of the invention.
- FIG. 2 is a schematic representation of the territories considered for the method of FIG. 1;
- FIG. 3 is a schematic representation of the sources of carbonaceous material in some territories of Figure 2;
- FIG. 4 is a schematic representation of the synthetic hydrocarbon production facilities of the territories of FIG. 3, showing that each installation consists of several modules;
- FIG. 5 is a schematic representation of the modules of the installations of FIG. 4, for a first embodiment of the invention
- FIG. 6 is a schematic representation similar to that of FIG. 5, for a second embodiment of FIG. the invention.
- the process shown schematically in FIG. 1 aims at optimizing the production of synthetic hydrocarbons from carbonaceous material in a geographical area, and in particular aims at optimizing the logistic operations of supplying carbonaceous material for the production facilities.
- the method comprises the following steps:
- each unit of elementary production having an elementary production capacity of between 100 and 1000 barrels per day of synthetic hydrocarbons ;
- the geographical area considered in the present process may be an entire country. It can be, as illustrated in Figure 2, a country like France.
- the geographical area considered could also be only a part of a country or on the contrary could encompass several countries of small sizes.
- territories are selected for the supply of carbonaceous material, for example the territories T1 to T5 in Figure 2.
- a facility for the production of synthetic hydrocarbon will be installed in each territory.
- These territories can be selected on the basis of the following criteria:
- the sources of carbonaceous materials are of two kinds:
- non-renewable carbon sources for example of the coal type, combustion fumes from blast furnaces or cement plants,
- renewable carbon sources for example of the type of vegetable waste, animal waste, the organic part of the sorted municipal waste etc.
- Non-renewable carbon sources are generally concentrated (mines, factories). On the other hand, renewable carbon sources are rarely concentrated, they are rather spread over the territory.
- renewable carbon sources are more particularly considered.
- the carbonaceous material may therefore include one or more of the following:
- the available carbon resources are evaluated.
- one or more sources of carbonaceous material are identified in each territory, denoted R1 to R5 and R'1 to R'7 for the two territories T1 and T3 of FIG. source, the amount of carbonaceous material likely to be supplied to the facility for the production of synthetic hydrocarbon is evaluated. This quantity is for example a flow, in tons of carbon per year.
- the total production capacity of synthetic hydrocarbons that can be obtained from the resources of each territory is determined.
- This operation is a conventional sizing operation, which will not be detailed here. It will only be specified that the total production capacity is a function of the nature of the synthetic hydrocarbons to be produced and the production process chosen.
- the synthetic hydrocarbons can be chosen so that the installation produces essentially diesel, and / or kerosene, and / or any other type of hydrocarbon that can be envisaged.
- the elementary production units are standardized units, all identical to each other, having the same elementary production capacity. Only the module for preparing the raw material depends on the nature of the raw material.
- the elementary production capacity is typically between 100 and 1000 barrels per day of synthetic hydrocarbons, and is typically between 100 and 500 barrels per day of synthetic hydrocarbons. Each unit of elementary production thus has a low production capacity compared to the known installations to date for the manufacture of synthetic hydrocarbons.
- each territory there is built on each territory a number of elementary production units which may be different, and which is a function of the carbon resource resources available in said territory.
- the installation 11 for the production of hydrocarbons for the T1 territory can include five units of elementary production, while the facility 13 for the production of synthetic hydrocarbons for the territory T3 has only three units of elementary production.
- each unit of elementary production is represented as a rectangle.
- Each synthetic hydrocarbon production plant typically comprises between 1 and 20 elementary production units, typically between 1 and 10 elementary production units.
- the construction site of the synthetic hydrocarbon production facility is chosen for each territory. All the basic production units of the same facility are built on the same site.
- the site is chosen so that all sources of carbonaceous matter are separated from within 200 km of the site.
- the site is chosen such that the distance between said site and each source of carbonaceous material is less than 100 km.
- the site is chosen so that the average distance between the site and the sources of carbonaceous material is less than 100 km, preferably less than 50 km.
- the distance between the site and a given source of carbonaceous material can be calculated in many ways, including depending on the nature of the source. If the source is located, for example in the case of municipal waste from a waste sorting workshop, the distance chosen will correspond to the distance between the sorting workshop and the site. If the source is geographically extended, for example in the case of biomass produced in several fields spread over a certain area, one can for example consider the distance between the geographical center of said area and the site. Distances can be calculated in many other ways that will not be detailed here.
- the number of individual units of production determined for each territory is built on the site.
- each territory is carried out by transporting the carbonaceous material from the various sources of said territory to the basic production units, and producing the synthetic hydrocarbons in the various elementary production units from the transported carbonaceous material.
- the synthetic hydrocarbons are then distributed. They can be distributed only in the corresponding territory, or on the contrary be distributed in a wider geographical area.
- each elementary production unit is practically entirely independent of the other elementary production units of the same installation.
- each unit of elementary production is of the type described in the US patent application filed under No. US12 / 319861.
- each unit of elementary production can, as shown in Figure 5, include the following modules:
- a post-treatment module 22 intended to produce a second stream of synthetic hydrocarbons from the first stream of synthetic hydrocarbons
- each of the modules 10, 14, 16, 18, 20, 22, as well as the electrolyser 24, is dedicated to the corresponding elementary production unit.
- each elementary production unit comprises modules 10, 14, 16, 18, 20, 22 and an electrolyzer 24 of its own.
- the module 10 for producing the first gas stream is for example a gasifier.
- the gasifier may be of the partial oxidation type or a steam gasifier or a gasifier implementing both methods in combination (of the POS type).
- the module 10 is supplied with carbonaceous material via line 26, and with oxygen from electrolyser 24, via line 28.
- the conditioning module 14 separates the first gas stream into two streams, a second gas stream 30 comprising mainly CO2, and a third gas stream 32 comprising mainly CO.
- This conditioning module is of known type, and will not be described in more detail here.
- the conversion module 16 is of the type RWGS (Reverse Water Gas Shift).
- the water is for example recycled in the electrolyser 24.
- the CO leaves the conversion module via line 36.
- the CO 2 conversion module in CO 2 is for example of the WGS (Water Gas Shift) type. It is supplied with CO from the gas conditioning module via line 38. Line 38 is shunted by line 32. Conversion module 18 is also supplied with water via line 40. outside the module. Conversion module 18 converts CO to CO 2 , according to the following general chemical equation:
- the H 2 leaves the conversion module 18 via the line 42.
- the CO 2 leaves the conversion module 18 via the line 44.
- CO 2 leaving module 18 via line 44 is released into the atmosphere, or stored in any form, gaseous or liquid.
- the module 20 for producing the first stream of synthetic hydrocarbons operates for example according to the Fischer-Tropsch process. This process is known and will not be detailed here.
- the module 20 is supplied with CO by the line 32. It also receives the CO of the line 36, this line directly supplying the module 20 or supplying the module 20 via the line 32, as shown in FIG.
- the module 20 is also fed with hydrogen H 2 . It receives hydrogen H 2 from electrolyser 24 via line 46. It also receives hydrogen from line 42, from conversion module 18.
- the post-treatment module 22 produces from the first synthetic hydrocarbon stream a second stream of synthetic hydrocarbons and a third stream of synthetic hydrocarbons.
- the module 22 is a refining unit of a type known per se in the petroleum field.
- the second flow corresponds for example to the final product of the production facility.
- This second stream is, for example, diesel fuel or kerosene, etc.
- the third stream corresponds, for example, to the by-products of module 22 other than the desired end product. It includes, for example, naphthas or any other type of product.
- the second stream of synthetic hydrocarbons leaves module 22 via line 50 and the third stream through line 52.
- the second and third streams are collected in storage tanks or can be recycled in the facility.
- the electrolysis unit 24 of known type, is designed to produce oxygen and hydrogen from water and electricity supplied by the local electricity distribution network. Oxygen leaves the electrolyser via line 28 and hydrogen via line 54.
- the elementary production unit also comprises means for controlling the different modules 10, 14, 16, 18, 20 and 22 and driving the electrolyser 24. These means are not shown. They are especially designed to selectively distribute the flow of hydrogen leaving the electrolyser by the line 54 between the lines 34 and 46. These means are furthermore provided for selectively distributing the flow of CO leaving the gas conditioning module 14 to the production module 20 and / or to the conversion module 18.
- the control of the production unit can for example be performed in the following manner.
- the control means direct all the CO out of the module 14 to the module 20.
- the conversion module 18 is therefore at a standstill.
- the electrolyser is used to produce a large amount of hydrogen, partly directed to the conversion module 16 and partly to the production module 20.
- the control means direct a portion of the CO from the conditioning module 14 to the conversion module 18 and a portion of the CO to the module.
- the conversion module 16 is shut down. All the hydrogen leaving the electrolyser 24 is directed to the production module 20 via line 46.
- the electrolyser operates at a low capacity, and produces a smaller amount of hydrogen than in the first case.
- the CO 2 separated in the gas conditioning unit 14 is directed out of the unit of elemental production via the line 56.
- each unit of elementary production for the second embodiment, is substantially identical to that implemented for the first embodiment of the invention.
- certain modules are common to several elementary production units, and are therefore no longer dedicated to a specific unit, as in the first embodiment.
- the production module 10 of the first gas stream is common to at least two elementary production units. It can be common to several basic production units, or even be common to all elementary production units.
- the first gas stream is distributed among the different elementary production units sharing the production module 10.
- the post-processing module 22 is also shared between several elementary production units. It can be common to two basic production units, or even three, and can be common to all elementary production. As visible in FIG. 6, the first synthetic hydrocarbon stream 48 produced by each of the elementary production units is collected in a buffer storage 58, for example in a set of storage tanks. The post-processing module 22 is fed from this buffer storage 58. The second synthetic hydrocarbon stream 50, containing the final product, is collected at the output of the post-processing module 22 in a storage 60. Similarly, the third stream of synthetic hydrocarbons 52, comprising for example the other hydrocarbons, is collected at the outlet of the post-treatment module 22 in a storage 62.
- the process is particularly adapted to territories of small areas. It makes it possible to place the synthetic hydrocarbon production site at a moderate distance from the sources of carbonaceous matter in the territory.
- the transport needed to transport the carbonaceous material to the synthetic hydrocarbon production facility is short distances, which limits the fuel consumption associated with this transport as well as CO 2 emissions.
- transport for distribution of the final product is also limited distances, which saves fuel and limits CO 2 emissions.
- the installation is designed to be able to fade at least partially vis-à-vis the electrical distribution network.
- This partial erasure is achieved by stopping one or more elementary production units.
- the erasure can also be achieved by using CO 2 conversion unit CO 2 , which makes it possible to produce hydrogen from carbon monoxide. This relieves the electrolyser, whose electricity consumption and hydrogen production can be reduced accordingly.
- This also facilitates the management of the electricity grid at the local level, by making local demand quasi-constant electric. This operational flexibility makes it possible to take advantage of attractive rates on electricity by adapting the production load of the installation according to the price of electricity.
- the process for the production of synthetic hydrocarbons described above can have multiple variants.
- Each unit of elementary production can implement a process of hydrocarbon synthesis different from the Fischer-Tropsch process. It may for example implement a process known by the acronym MTG (Methanol To Gazoline).
- the modules that are common or dedicated to the different elementary production units may be different from what is shown in FIG. 6.
- the production module 10 of the first gas stream may be common while the post-processing module may be dedicated. Or vice versa.
- the electrolyser may be common, or any other module.
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- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/383,152 US9000055B2 (en) | 2009-07-09 | 2010-07-07 | Process for producing synthetic hydrocarbons from carbonaceous materials |
CN201080039848.5A CN102666370B (zh) | 2009-07-09 | 2010-07-07 | 由含碳材料生产合成烃的方法 |
EP10742220A EP2451742A2 (fr) | 2009-07-09 | 2010-07-07 | Procédé de production d'hydrocarbures synthétiques à partir de matières carbonées |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0954763A FR2947832B1 (fr) | 2009-07-09 | 2009-07-09 | Procede de production d'hydrocarbures synthetiques |
FR0954763 | 2009-07-09 |
Publications (2)
Publication Number | Publication Date |
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WO2011004122A2 true WO2011004122A2 (fr) | 2011-01-13 |
WO2011004122A3 WO2011004122A3 (fr) | 2011-04-07 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/FR2010/051436 WO2011004122A2 (fr) | 2009-07-09 | 2010-07-07 | Procédé de production d'hydrocarbures synthétiques à partir de matières carbonées |
Country Status (5)
Country | Link |
---|---|
US (1) | US9000055B2 (fr) |
EP (1) | EP2451742A2 (fr) |
CN (1) | CN102666370B (fr) |
FR (1) | FR2947832B1 (fr) |
WO (1) | WO2011004122A2 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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FR3029533A1 (fr) * | 2014-12-08 | 2016-06-10 | Commissariat Energie Atomique | Procede de gazeification de charge de matiere carbonee a rendement matiere et cout de production optimises |
WO2020101512A1 (fr) * | 2018-11-15 | 2020-05-22 | Wrzesinski Zbigniew | Procédé et système de production d'énergie électrique et de gaz de synthèse à partir d'un combustible de charbon au moyen d'une technologie en synergie nucléaire-charbon sans émissions et leurs utilisations pour produire un combustible liquide synthétique |
Families Citing this family (3)
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EP3196882A4 (fr) * | 2014-09-12 | 2018-05-16 | Sony Corporation | Dispositif de traitement d'information, procédé de traitement d'information, programme, et support d'enregistrement |
US11788022B1 (en) | 2022-03-22 | 2023-10-17 | Dioxycle | Augmenting syngas evolution processes using electrolysis |
US11965260B2 (en) | 2022-03-22 | 2024-04-23 | Dioxycle | Augmenting syngas evolution processes using electrolysis |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
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US20040265158A1 (en) * | 2003-06-30 | 2004-12-30 | Boyapati Krishna Rao | Co-producing hydrogen and power by biomass gasification |
DE20320020U1 (de) * | 2003-12-24 | 2004-05-06 | Geyer, Stefan, Dr.rer.nat. | Anlage zur Herstellung von Diesel und Zement |
WO2006012116A2 (fr) * | 2004-06-29 | 2006-02-02 | Van Dijk Technologies, L.L.C. | Procede de conversion de gaz naturel en gaz de synthese destine a etre converti ulterieurement en liquides organiques ou methanol et/ou dimethylether |
SG160406A1 (en) * | 2005-03-16 | 2010-04-29 | Fuelcor Llc | Systems, methods, and compositions for production of synthetic hydrocarbon compounds |
WO2007108014A1 (fr) * | 2006-03-20 | 2007-09-27 | Cri Ehf | Procédé de production de carburant liquide à partir de dioxyde de carbone et d'eau |
US8293805B2 (en) * | 2008-05-29 | 2012-10-23 | Schlumberger Technology Corporation | Tracking feedstock production with micro scale gas-to-liquid units |
US8184763B2 (en) | 2009-01-13 | 2012-05-22 | Areva Sa | System and a process for producing at least one hydrocarbon fuel from a carbonaceous material |
-
2009
- 2009-07-09 FR FR0954763A patent/FR2947832B1/fr not_active Expired - Fee Related
-
2010
- 2010-07-07 CN CN201080039848.5A patent/CN102666370B/zh not_active Expired - Fee Related
- 2010-07-07 WO PCT/FR2010/051436 patent/WO2011004122A2/fr active Application Filing
- 2010-07-07 US US13/383,152 patent/US9000055B2/en not_active Expired - Fee Related
- 2010-07-07 EP EP10742220A patent/EP2451742A2/fr not_active Withdrawn
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3029533A1 (fr) * | 2014-12-08 | 2016-06-10 | Commissariat Energie Atomique | Procede de gazeification de charge de matiere carbonee a rendement matiere et cout de production optimises |
EP3031884A1 (fr) * | 2014-12-08 | 2016-06-15 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Procédé de gazéification de charge de matière carbonée à rendement matière et coût de production optimisés |
WO2020101512A1 (fr) * | 2018-11-15 | 2020-05-22 | Wrzesinski Zbigniew | Procédé et système de production d'énergie électrique et de gaz de synthèse à partir d'un combustible de charbon au moyen d'une technologie en synergie nucléaire-charbon sans émissions et leurs utilisations pour produire un combustible liquide synthétique |
Also Published As
Publication number | Publication date |
---|---|
EP2451742A2 (fr) | 2012-05-16 |
CN102666370B (zh) | 2015-08-12 |
US20120172460A1 (en) | 2012-07-05 |
CN102666370A (zh) | 2012-09-12 |
FR2947832B1 (fr) | 2013-01-11 |
WO2011004122A3 (fr) | 2011-04-07 |
US9000055B2 (en) | 2015-04-07 |
FR2947832A1 (fr) | 2011-01-14 |
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