WO2010090653A1 - Conversion of combined cycle power plant to compressed air energy storage power plant - Google Patents
Conversion of combined cycle power plant to compressed air energy storage power plant Download PDFInfo
- Publication number
- WO2010090653A1 WO2010090653A1 PCT/US2009/048082 US2009048082W WO2010090653A1 WO 2010090653 A1 WO2010090653 A1 WO 2010090653A1 US 2009048082 W US2009048082 W US 2009048082W WO 2010090653 A1 WO2010090653 A1 WO 2010090653A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- compressed air
- hrsg
- power plant
- steam turbine
- air
- Prior art date
Links
- 238000004146 energy storage Methods 0.000 title claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 title description 10
- 238000002485 combustion reaction Methods 0.000 claims abstract description 41
- 238000003860 storage Methods 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 19
- 238000011084 recovery Methods 0.000 claims abstract description 7
- 230000003416 augmentation Effects 0.000 claims description 9
- 230000002708 enhancing effect Effects 0.000 claims description 3
- 238000010248 power generation Methods 0.000 abstract description 4
- 239000003570 air Substances 0.000 description 62
- 238000002347 injection Methods 0.000 description 9
- 239000007924 injection Substances 0.000 description 9
- 230000004048 modification Effects 0.000 description 6
- 238000012986 modification Methods 0.000 description 6
- 238000005457 optimization Methods 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- 230000006978 adaptation Effects 0.000 description 2
- 239000012080 ambient air Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
- F02C6/18—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
- F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
- F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
- F01K23/10—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle with exhaust fluid of one cycle heating the fluid in another cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49716—Converting
Definitions
- the embodiments relate to compressed air energy storage (CAES) power plants and, more particularly, to the conversion of a power producing combined cycle (CC) power plant to a load management CAES power plant.
- CAES compressed air energy storage
- U. S. Patents No. 7389644 and No. 7406828 disclose CAES plant concepts with a power generation section including a combustion turbine as a prime power generation component, with a recuperator recovering the combustion turbine exhaust heat to preheat stored compressed air, withdrawn from a storage, to be expanded through a bottoming cycle expander driving an electric generator that generates the bottoming cycle additional power with additional power being generated by the air injection into combustion turbine assembly with associated power augmentation of combustion turbine.
- These CAES plants could be built based on existing combustion turbines.
- An object of the present invention is to fulfill the needs referred to above.
- this objective is obtained by a method of converting a CC power plant to CAES power plant.
- the CC power plant includes at least one combustion turbine, a HRSG constructed and arranged to receive exhaust heat from an associated combustion turbine for steam generation to be expanded through the bottoming cycle power generating a steam turbine associated with the HRSG, and an electric generator associated with the steam turbine.
- the method provides additional external components needed for the conversion in a CAES plant.
- an air storage is provided to store compressed air.
- At least one motor-driven compressor is constructed and arranged to supply, during off-peak hours, the compressed air into the air storage.
- the method ensures that compressed air from the storage can be received by the HRSG with corresponding parameters.
- the HRSG provides heat to compressed air received from the air storage.
- the steam turbine receives heated compressed air from the HRSG to expand the heated compressed air to atmospheric pressure to produce power.
- An electric generator is associated with the steam turbine.
- a portion of airflow expanded by the steam turbine can be injected, under certain conditions, into the combustion turbine assembly for additional power due to the power augmentation of the combustion turbine.
- the HRSG and the steam turbine can be used as is, but are preferably modified, with heat transfer components being added to the HRSG for enhancing the compressed air preheating, and the steam turbine being converted to an air expander.
- a CAES power plant includes at least one combustion turbine.
- a HRSG is constructed and arranged to receive exhaust heat from an associated combustion turbine.
- the HRSG is used as is or is modified to be able to provide heat to compressed air.
- a steam turbine is associated with the HRSG.
- the steam turbine is used as is or is modified to be able to expand heated compressed air to atmospheric pressure to produce power.
- An electric generator is associated with the steam turbine. Also, a portion of airflow expanded by the steam turbine can be injected, under certain conditions, into the combustion turbine assembly for additional power due to the power augmentation of the combustion turbine.
- An air storage is constructed and arranged to store compressed air.
- the HRSG is associated with the air storage to receive compressed air from the air storage.
- At least one compressor is constructed and arranged to supply during off-peak hours the compressed air into air storage.
- the air storage is constructed to ensure that compressed air from the storage can be received by the HRSG with corresponding parameters.
- FIG. 1 is a schematic illustration of the conversion of a CC power plant (with typical combined cycle configuration based on two combustion turbines with HRSGs feeding the steam into the single bottoming cycle steam turbine) into a CAES power plant in accordance with an embodiment of the invention.
- the embodiment converts a CC power plant to a CAES power plant.
- the only additional components typical for a CAES plants that need to be added to CC power plants (converted to CAES plants) are external compressor(s) and an air storage such that the external compressor(s) will utilize off peak energy to convert it to the compressed air energy stored in the air storage.
- a CC power plant is converted to a CAES power plant, generally indicated at 10.
- the plant 10 includes at least one conventional combustion (e.g., gas) turbine (GT), generally indicated at 1 1 , having a main compressor 12; receiving, at inlet 13, a source of inlet air at ambient temperature and feeding a main fuel burning combustor 14 with the compressed air for preheating; a main expansion turbine 14 operatively associated with the main compressor 12, with the combustor 14 feeding the main expansion turbine 16; and an electric generator 17 for generating electric power.
- GT gas turbine
- Each heat recovery steam generator (HRSG) 18 is associated with each GT. More particularly, each HRSG 18 receives exhaust gas heat from the associated turbine 14. Since the HRSG 18 is a heat exchanger, it can be used as is or can be modified for stored compressed air preheating. In accordance with the embodiment, minor modifications of the HRSG 18 could be made to deliver compressed air preheating by adding heat transfer components to the HRSG 18. Alternatively, significant modifications/optimization of the HRSG 18 can be made by converting the HRSG 18 to define a recuperator optimized for the best and most efficient heat recovery. The approach for the HRSG modification is driven by economics and CAES plant operating requirements.
- the plant 10 also includes a steam turbine 20 that receives heated compressed air from each HRSG 18.
- An electric generator 22 is associated with the turbine 20 for producing electric power.
- the steam turbine 20 is used as is or is modified by converting it into an air expander based on properly optimized inlet compressed air mass flow and temperature parameters and exhaust to the atmospheric pressure without significant modification of steam turbine flow path. This type of conversion is typical and practical and there are a number of conventional steam turbines converted into air/gas expanders.
- a method of converting a CC power plant to CAES power plant provides an air storage 24 constructed and arranged to store compressed air. At least one compressor 26, driven by a motor 28, is provided to supply the air storage 24 with compressed air via piping 29. An outlet 30 of the air storage 24 is connected by piping 32 to each HRSG 18 so that compressed air can be received by each HRSG 18.
- Each HRSG 18 is used as is or modified, as noted above, to be able to provide heat to the compressed air received from the air storage.
- the steam turbine 20 is used as is or is modified, as noted above, to be able to receive heated compressed air from each HRSG 18 and to expand the heated compressed air to produce power.
- the airflow extracted from the steam turbine 20 is injected into the combustion turbine assembly 1 1 , preferably upstream of combustors 16 with injection flow parameters determined by combustion turbine limitations and optimization.
- structure 34 facilitates the injection of air into combustion turbine assembly.
- the structure 34 is preferably piping structures. Injection can be limited or restricted under certain conditions. For example, based on combustion turbine manufacturers published data, injection at low ambient temperatures may not be permitted or possible, or injection may not be permitted or possible due to accessibility to injection points, or injection may not occur due to operational judgments.
- the extracted airflow injected into the combustion turbine assembly 1 1 upstream of the combustors 14 provides a combustion turbine power augmentation of approximately up to 20-25%.
- the remaining airflow in the steam turbine 20 is expanded though low pressure stages to atmospheric pressure. Thus, when injection is possible or desired, not all airflow from the steam turbine 20 is exhausted to atmospheric pressure.
- the steam turbine 20 reduces the pressure of the preheated compressed air, the temperature of the compressed air is reduced.
- cold (lower than ambient temperature) air from the steam turbine 20 can be connected via structure 34' with the ambient air at main compressor inlet 13 so that ambient inlet air and the colder expander exhaust air are mixed, reducing the overall temperature of the inlet air prior to being received by the main compressor 12.
- the reduction of the overall temperature of the inlet air prior to being received by the main compressor 12 provides a combustion turbine power augmentation of approximately up to 20-25%.
- the structure 34' is piping connected between an exhaust stage of the steam turbine 20 and the inlet 13 to the main compressor 12, which is an alternative to piping 34.
- cold (lower than ambient temperature) air from the steam turbine 20 can be connected via structure 34' with the ambient air at main compressor inlet 13 so that the reduction of the overall temperature of the inlet air prior to being received by the main compressor 12 provides a combustion turbine power augmentation of approximately up to 20-25%.
- the bottoming cycle power of the conventional combined cycle plant is approximately 50-60% of the GT power.
- the bottoming cycle power is approximately 150-200% of the GT power. Therefore, in an optimized CAES plant 10, in addition to the modified steam turbine 20, an additional bottom cycle expander 36, as shown in dotted form in FIG. 1 , may be needed.
- the expander 36 also receives heated compressed air from the HRSG 18.
- a generator 38 can be associated with the expander 36 to produce electric power.
- the modification of the HRSG into a recuperator may require additional heat recovery heat exchanger surfaces and/or an additional parallel heat exchanger (not shown).
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
UAA201110641A UA98749C2 (en) | 2009-02-04 | 2009-06-22 | Conversion of combined cycle power plant to compressed air energy storage power plant and plant with compressed air energy storage |
CN2009801561439A CN102308065A (en) | 2009-02-04 | 2009-06-22 | Conversion of combined cycle power plant to compressed air energy storage power plant |
MX2011008198A MX2011008198A (en) | 2009-02-04 | 2009-06-22 | Conversion of combined cycle power plant to compressed air energy storage power plant. |
AU2009339444A AU2009339444B2 (en) | 2009-02-04 | 2009-06-22 | Conversion of combined cycle power plant to compressed air energy storage power plant |
EP09839812.6A EP2394038A4 (en) | 2009-02-04 | 2009-06-22 | Conversion of combined cycle power plant to compressed air energy storage power plant |
EA201170992A EA201170992A1 (en) | 2009-02-04 | 2009-06-22 | CONVERSION OF ENERGY INSTALLATION OF A COMBINED CYCLE INTO AN ENERGY INSTALLATION WITH A COMPRESSED AIR ENERGY DRIVE |
CA2751160A CA2751160C (en) | 2009-02-04 | 2009-06-22 | Conversion of combined cycle power plant to compressed air energy storage power plant |
JP2011547911A JP2012516963A (en) | 2009-02-04 | 2009-06-22 | Conversion of combined cycle power plant to compressed air energy storage power plant |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/320,751 | 2009-02-04 | ||
US12/320,751 US7640643B2 (en) | 2007-01-25 | 2009-02-04 | Conversion of combined cycle power plant to compressed air energy storage power plant |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2010090653A1 true WO2010090653A1 (en) | 2010-08-12 |
Family
ID=42542326
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2009/048082 WO2010090653A1 (en) | 2009-02-04 | 2009-06-22 | Conversion of combined cycle power plant to compressed air energy storage power plant |
Country Status (10)
Country | Link |
---|---|
US (1) | US7640643B2 (en) |
EP (1) | EP2394038A4 (en) |
JP (1) | JP2012516963A (en) |
CN (1) | CN102308065A (en) |
AU (1) | AU2009339444B2 (en) |
CA (1) | CA2751160C (en) |
EA (1) | EA201170992A1 (en) |
MX (1) | MX2011008198A (en) |
UA (1) | UA98749C2 (en) |
WO (1) | WO2010090653A1 (en) |
Cited By (1)
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US8978380B2 (en) | 2010-08-10 | 2015-03-17 | Dresser-Rand Company | Adiabatic compressed air energy storage process |
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US7669423B2 (en) * | 2007-01-25 | 2010-03-02 | Michael Nakhamkin | Operating method for CAES plant using humidified air in a bottoming cycle expander |
US8196395B2 (en) | 2009-06-29 | 2012-06-12 | Lightsail Energy, Inc. | Compressed air energy storage system utilizing two-phase flow to facilitate heat exchange |
US8247915B2 (en) * | 2010-03-24 | 2012-08-21 | Lightsail Energy, Inc. | Energy storage system utilizing compressed gas |
US8436489B2 (en) * | 2009-06-29 | 2013-05-07 | Lightsail Energy, Inc. | Compressed air energy storage system utilizing two-phase flow to facilitate heat exchange |
US8146354B2 (en) | 2009-06-29 | 2012-04-03 | Lightsail Energy, Inc. | Compressed air energy storage system utilizing two-phase flow to facilitate heat exchange |
US8943836B2 (en) * | 2009-07-10 | 2015-02-03 | Nrg Energy, Inc. | Combined cycle power plant |
US8347628B2 (en) * | 2009-08-18 | 2013-01-08 | Gerard Henry M | Power generation directly from compressed air for exploiting wind and solar power |
US8572972B2 (en) * | 2009-11-13 | 2013-11-05 | General Electric Company | System and method for secondary energy production in a compressed air energy storage system |
US8453444B2 (en) * | 2010-01-11 | 2013-06-04 | David Haynes | Power plant using compressed or liquefied air for energy storage |
US8863492B2 (en) * | 2010-01-19 | 2014-10-21 | Siemens Energy, Inc. | Combined cycle power plant with split compressor |
US8161724B2 (en) * | 2010-03-31 | 2012-04-24 | Eif Nte Hybrid Intellectual Property Holding Company, Llc | Hybrid biomass process with reheat cycle |
US8965594B2 (en) | 2012-01-19 | 2015-02-24 | General Compression, Inc. | System and method for conserving energy resources through storage and delivery of renewable energy |
ITFI20120075A1 (en) | 2012-04-12 | 2013-10-13 | Nuovo Pignone Srl | "COMPRESSED-AIR ENERGY-STORAGE SYSTEM" |
WO2014055717A1 (en) | 2012-10-04 | 2014-04-10 | Kraft Robert J | Aero boost - gas turbine energy supplementing systems and efficient inlet cooling and heating, and methods of making and using the same |
US9388737B2 (en) | 2012-10-04 | 2016-07-12 | Powerphase Llc | Aero boost—gas turbine energy supplementing systems and efficient inlet cooling and heating, and methods of making and using the same |
US10119472B2 (en) | 2012-10-26 | 2018-11-06 | Powerphase Llc | Gas turbine energy supplementing systems and heating systems, and methods of making and using the same |
CN102878603B (en) * | 2012-10-30 | 2014-10-15 | 哈尔滨工业大学 | Gas-steam circulation combined double-stage coupling heat pump heat supply device |
US9938895B2 (en) | 2012-11-20 | 2018-04-10 | Dresser-Rand Company | Dual reheat topping cycle for improved energy efficiency for compressed air energy storage plants with high air storage pressure |
US9551279B2 (en) * | 2013-03-14 | 2017-01-24 | Dresser-Rand Company | CAES plant using steam injection and bottoming cycle expander |
US9145795B2 (en) | 2013-05-30 | 2015-09-29 | General Electric Company | System and method of waste heat recovery |
US9593597B2 (en) | 2013-05-30 | 2017-03-14 | General Electric Company | System and method of waste heat recovery |
US9587520B2 (en) | 2013-05-30 | 2017-03-07 | General Electric Company | System and method of waste heat recovery |
KR102256476B1 (en) * | 2013-07-04 | 2021-05-27 | 한화에어로스페이스 주식회사 | Gas turbine system |
US10526966B2 (en) | 2014-11-06 | 2020-01-07 | Powerphase Llc | Gas turbine efficiency and power augmentation improvements utilizing heated compressed air and steam injection |
US9777630B2 (en) | 2014-11-06 | 2017-10-03 | Powerphase Llc | Gas turbine fast regulation and power augmentation using stored air |
US10215060B2 (en) | 2014-11-06 | 2019-02-26 | Powerphase Llc | Gas turbine efficiency and power augmentation improvements utilizing heated compressed air |
US9822705B2 (en) * | 2015-07-13 | 2017-11-21 | General Elecric Company | Power augmentation system for a gas turbine |
CN106401679B (en) * | 2016-09-28 | 2018-06-15 | 东莞市联洲知识产权运营管理有限公司 | A kind of thermoelectricity unit with peak regulation heat accumulation function |
CN110513277A (en) * | 2019-10-12 | 2019-11-29 | 贵州电网有限责任公司 | A kind of power plant's compressed-air energy-storage system and its control method |
CN110778442B (en) * | 2019-10-16 | 2021-01-05 | 华南理工大学 | Method and system for improving peak shaving power supply energy efficiency by using vertical pipe to charge and discharge seawater for energy storage |
CN113250775B (en) * | 2021-05-21 | 2024-06-25 | 中盐华能储能科技有限公司 | Large-capacity compressed air energy storage power generation system and method for segmented expansion work |
CN113623038B (en) * | 2021-09-17 | 2023-07-11 | 西安热工研究院有限公司 | Air-steam combined cycle power generation system and method |
BR102022016812A2 (en) | 2022-08-23 | 2024-02-27 | Aruanã Energia S/A | HOT EXHAUST GAS ENERGY RECOVERY SYSTEM |
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2009
- 2009-02-04 US US12/320,751 patent/US7640643B2/en not_active Expired - Fee Related
- 2009-06-22 UA UAA201110641A patent/UA98749C2/en unknown
- 2009-06-22 WO PCT/US2009/048082 patent/WO2010090653A1/en active Application Filing
- 2009-06-22 MX MX2011008198A patent/MX2011008198A/en not_active Application Discontinuation
- 2009-06-22 EA EA201170992A patent/EA201170992A1/en unknown
- 2009-06-22 JP JP2011547911A patent/JP2012516963A/en active Pending
- 2009-06-22 EP EP09839812.6A patent/EP2394038A4/en not_active Withdrawn
- 2009-06-22 AU AU2009339444A patent/AU2009339444B2/en not_active Ceased
- 2009-06-22 CA CA2751160A patent/CA2751160C/en not_active Expired - Fee Related
- 2009-06-22 CN CN2009801561439A patent/CN102308065A/en active Pending
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US7389644B1 (en) * | 2007-01-19 | 2008-06-24 | Michael Nakhamkin | Power augmentation of combustion turbines by injection of cold air upstream of compressor |
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Title |
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See also references of EP2394038A4 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8978380B2 (en) | 2010-08-10 | 2015-03-17 | Dresser-Rand Company | Adiabatic compressed air energy storage process |
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Publication number | Publication date |
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UA98749C2 (en) | 2012-06-11 |
EA201170992A1 (en) | 2011-12-30 |
US7640643B2 (en) | 2010-01-05 |
AU2009339444A1 (en) | 2011-08-25 |
AU2009339444B2 (en) | 2011-10-06 |
MX2011008198A (en) | 2011-08-17 |
JP2012516963A (en) | 2012-07-26 |
EP2394038A1 (en) | 2011-12-14 |
EP2394038A4 (en) | 2014-10-29 |
US20090145103A1 (en) | 2009-06-11 |
CN102308065A (en) | 2012-01-04 |
CA2751160A1 (en) | 2010-08-12 |
CA2751160C (en) | 2012-03-20 |
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