WO2010072344A1 - Substrate material for high speed optical discs - Google Patents
Substrate material for high speed optical discs Download PDFInfo
- Publication number
- WO2010072344A1 WO2010072344A1 PCT/EP2009/008903 EP2009008903W WO2010072344A1 WO 2010072344 A1 WO2010072344 A1 WO 2010072344A1 EP 2009008903 W EP2009008903 W EP 2009008903W WO 2010072344 A1 WO2010072344 A1 WO 2010072344A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- polycarbonate
- disc
- bisphenol
- compounds
- relative solution
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/253—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
- G11B7/2533—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/253—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
- G11B7/2533—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins
- G11B7/2534—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins polycarbonates [PC]
Definitions
- the present invention describes the usage of special polycarbonates for the production of optical discs, which can be used safely without breakage in optical disc drives at high spinning speeds and exhibit a good transcripability.
- optical data storage is mainly characterized by the increase of the sorage capacity per disc from one generation to the next generation.
- This can be examplif ⁇ ed e.g. by the 0.7 GByte capacity per disc in the Compact Disc (CD) format, the 4.7 GByte capacity of a sin- gle layer Digital Versatile Disc (DVD) and the 25 GByte capacity of a single layer Blu-ray Disc (BD).
- CD Compact Disc
- DVD Digital Versatile Disc
- BD Blu-ray Disc
- those capacities can be increased by introducing e.g. double layer discs or discs with even more layers or double side accessible discs.
- JP 200-6318525-A that discloses special polycarbonate blends with special blend partners. Pure Bisphenol A polycarbonate is judged to be not suitable. Suitable materials are disclosed to be those with higher bending modulus than Bisphenol A polycarbonate.
- EP 1 130 587 A proposes sandwich discs comprising different polymers as core and shell mate- rials. This disc architecture is complicated and special processing equipment is needed to produce those sandwich type discs.
- KR 2003073242 describes optical discs with special fiber reinforcement in the inner part of the disc. These discs are said to able to sustain high spinning speed but are difficult to produce due to their complex non standard architecture. 3. PROBLEM TO BE SOLVED
- test discs made from standard optical disc grade Bisphenol A polycarbonate could not sustain a spinning speed of 24000 RPM for at least 30 minutes without failure due to disc breakage.
- Bisphenol A polycarbonate can solve the above described problem and at the same time can provide high pit and groove transcriptability.
- Bisphenol A polycarbonates with a relative solution viscosity (which corresponds to the molecular weight) in the range of 1.210 to 1.285, preferably of 1.220 to 1.285, more preferably in the range of 1.230 to 1.270. Additionaly the amount of release agent in said polycarbonate should be lower than 2000 ppm, preferably lower than 1000 ppm, most preferred lower than 500 ppm based on 100 parts by weight of polycarbonate.
- the polycarbonate resins are generally obtained by solution polymerization or melt polymerization of an aromatic dihydroxy compound and a carbonate precursor. Any aromatic dihydroxy compound is acceptable if discs made out of the respective polycarbonate satisfy the requirements of the high rotation speed test wherein said test is described in the experimental part of the specification and preferably the respective polycarbonate satisfies the above relative solution viscosity ranges
- Perferred aromatic dihydroxy compounds are compounds of formula (1) HO-Z-OH (1)
- R 1 and R 2 independently of each other represent H or Ci-Cg-alkyl, preferably H or Ci - C 4 -alkyl, in particular hydrogen or methyl and
- X represents a single bond, Ci - C 6 -alkylene, C 2 - Cs-alkylidene or C 5 - Ce- cycloalkylidene, which may be substituted by Ci - C 6 -alkyl, preferably methyl or ethyl, with the proviso that R 1 and R 2 represent hydrogen if X reperesents 3 ,3 ,5- trimethylcyclohexylidene.
- X represents isopropylidene and R 1 and R 2 represents hydrogen.
- Aromatic dihydroxy compounds are generally known or can be prepared according to generally known methods.
- the interfacial or melt polymerization of polycarbonate is also generally known and described in numerous publications e.g. WO 2004/063249 Al, WO 2001/05866 Al, WO 2000/105867, US-A 5,340,905, US 5,097,002, US-A 5,717,057.
- the polycarbonate resin may be a homopolycarbonate obtained by homopolymerizing the above aromatic dihydroxy compound or a copolycarbonate obtained by copolymerizing two or more aromatic dihydroxy compounds mentioned above.
- the polycarbonate based on bisphenol A as diphenol monomer may contain up to 20 wt.-%, preferably up to 10 wt.-%, more preferably up to 5 wt.-%, based on the amount of diphenols used for the production of polycarbonate, additional diphenol monomers selected from the group consisting of 1 , 1 -bis(4-hydroxyphenyl)- 3,3,5-trimethylcyclohexan, ⁇ , ⁇ '-bis(4-hydroxyphenyl)m-diisopropylbenzen or 4,4'-dihydroxy- biphenyl or 2-Phenyl-3,3-bis(4'-hydroxyphenyl)phthalimide.
- the reaction by the solution method is usually a reaction between the aromatic dihydroxy com- pound and phosgene, and is usually carried out in the presence of an acid coupling agent and an organic solvent.
- an acid coupling agent alkali metal hydroxides, such as sodium hydroxide or potassium hydroxide, or amine compounds, such as pyridine, are used.
- organic sol- vent halogenated hydrocarbons, such as methylene chloride or chlorobenzene or mixtures of such hydrocarbons, are used.
- a catalyst such as tertiary amines, quaternary ammonium compounds or quaternary phosphonium compounds which are exemplified by triethylamine, N-ethyl-piperidine, tetra-n-butylammonium bromide, or tetra-n- butylphosphonium bromide respectively may also be used.
- the reaction temperature is routinely 0 to 40° C, with a reaction time being 10 seconds to 5 hours and with a pH during the reaction being not less than 9.
- the reaction can be a batch process or a continuous process.
- terminal capping agents for adjusting the relative solution viscosity are usually also employed. These terminal capping agents used may be monofunctional phenols.
- the polycarbonate resin obtained has its terminal capped by a monofunctional phenol based group so that it is superior in thermal stability to polycarbonate resin not obtained as described above.
- the monofunctional phenols are generally phenols or lower alkyl substituted phenols like phenol, p-tert-butylphenol, p-cumylphenol, isooctylphenol or long-chain alkyl phenols like decyl phenol, dodecyl phenol, hexadecyl phenol, octadecyl phenol, eicosyl phenol, docosyl phenol and triacontyl phenol.
- Prefered terminal capping agents are phenol, p-tert- butylphenol, p-cumylphenol and 3-n-pentadecylphenol (CAS # 501-24-6).
- the terminal capping agent is introduced in an amount to achieve the appropriate relative solution viscosity.
- the terminal capping agent may be used alone or in combination with other above mentioned phenol compounds.
- the reaction by the melting method is usually an ester exchange reaction between an aromatic dihydroxy compound mentioned above and a carbonate ester, and is carried out by a method consisting in mixing the aromatic dihydroxy compound and the carbonate ester in the presence of an inert gas under heating and in distilling off the generated alcohol or phenol.
- the reaction temperature differs with e.g., the boiling point of the generated alcohol or phenol, it is usually 120 to 350° C.
- the reaction system is reduced in pressure to approximately 1.33> ⁇ 10 3 to 13.3 Pa to facilitate distillation of the generated alcohol or phenol.
- the reaction time is usually 1 to 6 hours.
- esters such as C6 to ClO aryl groups or aralkyl groups or C 1-4 alkyl groups, that may occasionally be substituted, specifically, diphenyl carbonate, bis(chlorophenyl) carbonate, dinaphtyl carbonate, bis(diphenyl) carbonate, dimethyl carbonate, diethyl carbonate and dibutyl carbonate. Of these, diphenyl carbonate is most preferred.
- polymerization catalysts may also be used.
- alkali metal compounds e.g., sodium hydroxide, potassium hydroxide, or sodium or potassium salts of dihydric phenols
- alkali earth metal compounds such as calcium hydroxide, barium hydroxide or magnesium hydroxide
- nitrogen-containing basic compounds such as tetramethyl ammonium hydroxide, tetraethyl ammonium hydroxide, trimethylamine or triethyl- amine
- alkoxides of alkali metals or alkali earth metals phosphorous-containing basic compounds like tetraphenylphosphoniumphenolat or organic acid salts of alkali metals or alkali earth metals, zinc compounds, boron compounds, aluminum compounds, silicon compounds, germanium compounds, organotin compounds, lead compounds, osmium compounds, antimony compounds, manga
- These catalysts may be used alone or in combination. These catalysts are used in an amount preferably of 1 x 10 ⁇ 8 to 1 * 10 "3 equivalent, more preferably 1 x 10 "7 to 5x 10 "4 equivalent, to one mol of the dihydric phenol as the starting material.
- the aromatic polycarbonate resins may contain tri-or higher functional aromatic compounds or contain branched components in the polymer as a result of the isomerization reaction in polym- erization.
- the tri-or higher functional aromatic compounds preferably include phlorogrucin, phlorogrucide, tris phenols, such as 4,6-dimethyl-2, 4,6-tris(4-hydroxyphenyl) heptene-2,2,4,6-trimethyl-2,4,6-tris(4-hydroxyphenyl) heptane, 1 ,3,5-tris(4-hydroxyphenyl) benzene, l,l,l-tris(4-hydroxyphenyl) ethane, l,l,l-tris(3,5-dimethyI-4-hydroxyphenyl) ethane, 2, 6-bis(2-hydroxy-5-methylbenzyl)-4-methyl phenol, and 4-(4-[l,l-bis(4-hydroxyphenyl) ethy
- the polycarbonate or the copolycarbonate are characterized by the relative solution viscosity, determined in a polymer solution in dichloromethane, measured with an Ubbelhode capillary viscosimeter, capillary type OC.
- the polymer concentration is 5 g/1, the measurement is done at a temperature of 25°C.
- thermoplastic resin of the present invention As release agent higher fatty acid ester of a monohydric alcohol or polyhydric alcohol may be added to the thermoplastic resin of the present invention.
- a higher fatty acid ester of a monohydric or polyhydric alcohol By blending a higher fatty acid ester of a monohydric or polyhydric alcohol, releasability from a mold at the time of molding the thermoplastic resin is improved, and a release load in the molding of a disk substrate becomes small, thereby making it possible to prevent the deformation of the disk substrate and pit dislocation caused by a release failure.
- the melt fluidity of the thermoplastic resin is also improved.
- the positive amount of release agents is preferably less than 2000 ppm by weight of the resin, more preferably less than 1000 ppm by weight of the resin, especially prefered less than 500 ppm.
- Preferred higher fatty acid esters are glycerol monostrearate and glycerol monopalmitate as well as mixtures of them.
- Phosphorus-based thermal stabilizers may be added to the thermoplastic resin also.
- Suitable phosphorus-based thermal stabilizers are for example, phosphorous acid, phosphoric acid, phos- phonous acid, phosphonic acid and esters thereof.
- phosphite compounds such as triphenyl phosphite, tris nonylphenyl phosphite, tris(2,4-di-tert-butylphenyl) phosphite, tridecyl phosphite, trioctyl phosphite, trioctadecyl phosphite, didecyl monophenyl phosphite, dioctyl monophenyl phosphite, diisopropyl monophenyl phosphite, monobutyl diphenyl phosphite, monodecyl diphenyl phosphite, monooctyl diphenyl phosphite, bis(2,6-di-tert-butyl-4- methylphenyl) pentaerythritol diphosphite, 2,2-methylenebis(4,6-di-tert-butyl)
- Additional phosphorus-based thermal stabilizers are for example tetrakis(2,4-di-tert-butylphenyl)-4,4'-biphenylene diphos- phonite, tetrakis(2,4-di-tert-butylphenyl)-3,3'-biphenylene diphosphonite and bis(2,4-di-tert- butylphenyl)-4-biphenylene phosphonite.
- tris nonylphenylphosphonite distearyl pentaerythritol diphosphite, bis(2,4-di-tert-butylphenyl) pentaerythritol disphosphite, tris(2,4-di- tert-butylphenyl) phosphite, triphenyl phosphate, trimethyl phosphate, tetrakis(2,4-di-tert- butylphenyl)-4,4'-biphenylene diphosphonite and bis(2,4-di-tert-butylphenyl)-4-biphenylene phosphonite, are preferred.
- These thermal stabilizers may be used alone or as a mixture.
- the amount of these thermal stabilizers, if added, is preferably 0.0001 to 0.05 weight part, more preferably 0.0005 to 0.02 weight part and most preferably 0.001 to 0.01 weight part to 100 parts by weight of the thermoplastic resin composition
- a generally known antioxidant may be added to the thermoplastic resin of the present invention to prevent oxidation.
- An example of the antioxidant is a phenol-based antioxidant.
- the amount of the antioxidant is preferably 0.0001 to 0.05 wt% based on the thermoplastic resin.
- additives as well as other additives like optical stabilizers, colorants, antistatic agents and lubricants may be added to the resin for an optical disk substrate of the present in- vention in such limits that discs made out of the respective polycarbonate resin composition satisfy the requirements of the high rotation speed test.
- Blends of polycarbonate with other thermopolastic resin may also be used as long as the discs made out of the respective blend satisfies the requirements of the high rotation speed test.
- Other thermoplastic resin may be selected from the group consisting of acrylic resin, preferably polymethylmethacrylate, polystyrene resins as homopolymer or as co- or blockpolymer with other monomers selected from the group comprising isoprene and butadiene or mixtures thereof, or polycyclooJefinic resins preferably polymerization products of olefins, such as moieties with a norbornene sructure.
- an injection molding machine (including an injection compression molding machine) equipped with a stamper having pits and grooves which satisfy specifications required for an optical recording medium and a surface accuracy is used to form an optical disk substrate by injection molding.
- the thickness of the disk substrate generally is 0.3 to 2.0 mm, preferably 0.6 to 1.2 mm, most preferred 1.0 to 1.15mm.
- This injection molding machine may be a generally used machine but preferably a machine made from a material whose cylinder and screws have low adhesion to resins, corro- sion resistance and abrasion resistance in order to suppress the production of carbide and improve the reliability of a disk substrate.
- the environment of the molding step is preferably as clean as possible in view of the object of the present invention. It is also important that the material to be molded should be fully dried to remove water and that residence which might cause the decomposition of a molten resin should be avoided.
- a disk substrate having a diameter of 120 mm and a thickness of 1.1 mm to 1.2 mm is injection molded from each pellet using an injection molding machine equipped with a mold and a stamper.
- the polycarbonate or the copolycarbonates are characterized by the relative solution viscosity of a polymer solution in dichloromethane with an Ubbelhode capillary viscosimeter, capillary type OC.
- the polymer concentration is 5 g/I, the measurement is done at a temperature of 25°C.
- the pit depth d R of the injection molded substrate with the replicated pit structure was measured with the Atomic Force Microscope in the tapping mode.
- the pit depth of the stamper d s was measured in the same way.
- the transeriptability t is then calculated via:
- the radial deviation measures the angular deviation of the disc surface from a reference plane. It is defined as the angle measured in radial direction, between incident light perpendicular to the reference plane and the reflected light.
- the radial deviation of the disc was measured using an offline optical disk scanner from Basler (Modell: Basler Reference 100). The maximum nominal value measured on the disc is taken.
- the high speed test is setup by a motor (LMT Lehner Motorentechnik, Typ 1525/17), a power supply (CL-Electronics, Typ DF-1730SL20A), a printed circuit board (YGE Young Generation Electronics, Typ 65 HV) for motor RPM setting equipped with an output to measure the motor RPM and which can be actuated by a potentiometer to set the RPM and an oscilloscope (Hewlett Packard, Typ Infinium 500 MHz) to measure the motor RPM.
- a clamp for the disc is boolted down. The details of the clamp and the disc fixture can be seen from figure 3.
- the disc itself is mounted on the clamp with the fixture and put into a casing.
- the geometry of the casing and the test setup can be seen from figure 1 to 2.
- the disc is accelerated to 24000 RPM within 30 seconds. From that point of time the disc spins at 24000 RPM for 30 minutes at the longest. For the test always three discs made form the same polycarbonate are taken. The test is passed if within the 30 minutes none of the three disc is broken. The test fails if disc breakage occurs within this 30 minutes for at least one disc. In table 3 the time to failure is shown if applicable.
- Comparitive example 1 Dow Calibre ® 1080 DVD is an optical disc grade bisphenol A polycarbonate from DOW with a relative solution viscosity of 1.197.
- Comparitive example 2 Makrolon ® OD2015 is a optical disc grade Bisphenol A polycarbonate from Bayer MaterialScience AG with a relative solution viscosity of 1.210.
- Example 1 Is a bisphenol A polycarbonate with a relative solution viscosity of 1.227 and 400 ppm of glycerin mono stearate, prepared by interfacial polymerization and using p-tert- butylphenol as terminal capping agent
- Example 2 Is a bisphenol A polycarbonate with a relative solution viscosity of 1.261 and 400 ppm of glycerin mono stearate prepared by melt polymerization and using phenol as terminal capping agent.
- Example 3 Is a bisphenol A polycarbonate with a relative solution viscosity of 1.281 and 290 ppm of glycerin mono stearate prepared by interfacial polymerization and using phenol as terminal capping agent.
- Example 4 bisphenol A polycarbonate with a relative solution viscosity of 1.280 containing 3000 ppm pentaerythrit tetra stearate as release agent, prepared by interfacial polymerization and using phenol as terminal capping agent.
- Comparitive example 3 Is a bisphenol A polycarbonate with a relative solution viscosity of 1.300 containing 400 ppm of glycerin mono stearate, prepared by interfacial polymerization and phenol as terminal capping agent.
- a disk substrate having a diameter of 120 mm and a thickness of 1.1 mm is injection molded from above materials using a Sumitomo SD 4OE injection molding machine equipped with a mold AWM 5237 and a BD-ROM stamper. Following molding parameters were used, see table 1 : Table 1: Molding parameters according to disc molding process A used for the different examples
- T cy i is the melt temperature and T MO W is the mold temperature, whereas the left value respresents the mirror side of the mold and the right value the stamper side of the mold.
- a disk substrate having a diameter of 120 mm and a thickness of 1.15 mm is injection molded from above materials using a Netstal Diskjet 600 Hybrid injection molding machine using a screw with 32 mm diameter equipped with a mold AXX 1695 and a CD-Audio stamper. Following molding parameters were used, see table 2:
- Table 2 Molding parameters according to disc molding process B used for the different examples
- T cy i is the melt temperature and T MOM is the mold temperature, whereas the left value respresents the mirror side of the mold and the right value the stamper side of the mold.
- Table 3 summarizes the characteristics of the molded substrates.
- disc substrates made from BPA-PC with relative solution viscosities in between 1.210 and 1.285 provide secure high speed operation, good pit tran- scriptability and flat discs.
- Comparitive example 1 and 2 fail the high speed test as the relative viscosity is below 1.21 and by this do not fulfill our requirements. That means that in a short term test discs made from standard optical disc grade Bisphenol A polycarbonate could not sustain a spinning speed of 24000 RPM for at least 30 minutes without failure due to disc breakage.
- Comparitive example 3 has excellent high speed test performance but due to the high relative solution viscosity the transcriptability is not above 85% and also radial deviation becomes higher than in all other cases in which polycarbonates with lower relative solution viscosities were used.
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Optical Record Carriers And Manufacture Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200980152758.4A CN102265342B (en) | 2008-12-25 | 2009-12-12 | Substrate material for high-speed optical disk |
US13/142,097 US8436128B2 (en) | 2008-12-25 | 2009-12-12 | Substrate material for high speed optical discs |
PL09796622T PL2382629T3 (en) | 2008-12-25 | 2009-12-12 | Substrate material for high speed optical discs |
JP2011542698A JP5568094B2 (en) | 2008-12-25 | 2009-12-12 | High-speed optical disk substrate material |
EP09796622.0A EP2382629B1 (en) | 2008-12-25 | 2009-12-12 | Substrate material for high speed optical discs |
ES09796622.0T ES2437611T3 (en) | 2008-12-25 | 2009-12-12 | Substrate material for high speed optical discs |
HK12103548.7A HK1163335A1 (en) | 2008-12-25 | 2012-04-11 | Substrate material for high speed optical discs |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2008002083 | 2008-12-25 | ||
CNPCT/CN2008/002083 | 2008-12-25 |
Publications (2)
Publication Number | Publication Date |
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WO2010072344A1 true WO2010072344A1 (en) | 2010-07-01 |
WO2010072344A8 WO2010072344A8 (en) | 2011-06-23 |
Family
ID=41728153
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2009/008903 WO2010072344A1 (en) | 2008-12-25 | 2009-12-12 | Substrate material for high speed optical discs |
Country Status (9)
Country | Link |
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US (1) | US8436128B2 (en) |
EP (1) | EP2382629B1 (en) |
JP (1) | JP5568094B2 (en) |
KR (1) | KR101604156B1 (en) |
ES (1) | ES2437611T3 (en) |
HK (1) | HK1163335A1 (en) |
PL (1) | PL2382629T3 (en) |
TW (1) | TWI463491B (en) |
WO (1) | WO2010072344A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US20140221571A1 (en) * | 2011-10-04 | 2014-08-07 | Lg Chem, Ltd. | Resin composition and optical film formed using the same |
WO2017198808A1 (en) | 2016-05-19 | 2017-11-23 | Covestro Deutschland Ag | Polycarbonate compositions containing a carboxylic acid and their glycerol or diglycerol esters |
US11382431B2 (en) | 2018-04-19 | 2022-07-12 | Bertrand Gravlo | Retractable seat for a perched position |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6056402B2 (en) * | 2012-11-15 | 2017-01-11 | ソニー株式会社 | Manufacturing method of substrate for optical recording medium |
EP3131966B1 (en) | 2014-04-15 | 2020-07-08 | SABIC Global Technologies B.V. | High heat polycarbonate compositions |
EP3131967B1 (en) * | 2014-04-15 | 2021-04-14 | SHPP Global Technologies B.V. | High heat polycarbonate compositions |
CN106232717B (en) * | 2014-04-15 | 2018-06-01 | 沙特基础工业全球技术有限公司 | High heat polycarbonate compositions |
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JP2000195099A (en) * | 1998-12-25 | 2000-07-14 | Mitsubishi Engineering Plastics Corp | Substrate for information-recording medium |
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2009
- 2009-12-12 US US13/142,097 patent/US8436128B2/en not_active Expired - Fee Related
- 2009-12-12 EP EP09796622.0A patent/EP2382629B1/en not_active Not-in-force
- 2009-12-12 JP JP2011542698A patent/JP5568094B2/en not_active Expired - Fee Related
- 2009-12-12 KR KR1020117014596A patent/KR101604156B1/en not_active IP Right Cessation
- 2009-12-12 WO PCT/EP2009/008903 patent/WO2010072344A1/en active Application Filing
- 2009-12-12 PL PL09796622T patent/PL2382629T3/en unknown
- 2009-12-12 ES ES09796622.0T patent/ES2437611T3/en active Active
- 2009-12-15 TW TW098142810A patent/TWI463491B/en not_active IP Right Cessation
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2012
- 2012-04-11 HK HK12103548.7A patent/HK1163335A1/en not_active IP Right Cessation
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US20140221571A1 (en) * | 2011-10-04 | 2014-08-07 | Lg Chem, Ltd. | Resin composition and optical film formed using the same |
WO2017198808A1 (en) | 2016-05-19 | 2017-11-23 | Covestro Deutschland Ag | Polycarbonate compositions containing a carboxylic acid and their glycerol or diglycerol esters |
US11382431B2 (en) | 2018-04-19 | 2022-07-12 | Bertrand Gravlo | Retractable seat for a perched position |
Also Published As
Publication number | Publication date |
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KR20110099263A (en) | 2011-09-07 |
TWI463491B (en) | 2014-12-01 |
TW201040958A (en) | 2010-11-16 |
US8436128B2 (en) | 2013-05-07 |
EP2382629B1 (en) | 2013-10-02 |
EP2382629A1 (en) | 2011-11-02 |
US20120065354A1 (en) | 2012-03-15 |
HK1163335A1 (en) | 2012-09-07 |
PL2382629T3 (en) | 2014-03-31 |
JP2012514280A (en) | 2012-06-21 |
JP5568094B2 (en) | 2014-08-06 |
ES2437611T3 (en) | 2014-01-13 |
WO2010072344A8 (en) | 2011-06-23 |
KR101604156B1 (en) | 2016-03-16 |
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