WO2010043799A3 - Method for the pyrolysis and gasification of biomasses by means of thermochemical conversion - Google Patents

Method for the pyrolysis and gasification of biomasses by means of thermochemical conversion Download PDF

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Publication number
WO2010043799A3
WO2010043799A3 PCT/FR2009/051920 FR2009051920W WO2010043799A3 WO 2010043799 A3 WO2010043799 A3 WO 2010043799A3 FR 2009051920 W FR2009051920 W FR 2009051920W WO 2010043799 A3 WO2010043799 A3 WO 2010043799A3
Authority
WO
WIPO (PCT)
Prior art keywords
biomasses
pyrolysis
thermochemical
carbon dioxide
thermochemical conversion
Prior art date
Application number
PCT/FR2009/051920
Other languages
French (fr)
Other versions
WO2010043799A2 (en
Inventor
Jean-Xavier Morin
Original Assignee
Jean-Xavier Morin
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jean-Xavier Morin filed Critical Jean-Xavier Morin
Priority to EP09755991A priority Critical patent/EP2342309A2/en
Priority to CA2740501A priority patent/CA2740501A1/en
Publication of WO2010043799A2 publication Critical patent/WO2010043799A2/en
Publication of WO2010043799A3 publication Critical patent/WO2010043799A3/en

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26—DRYING
    • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B17/00—Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement
    • F26B17/12—Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement with movement performed solely by gravity, i.e. the material moving through a substantially vertical drying enclosure, e.g. shaft
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/725—Redox processes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26—DRYING
    • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B21/00—Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
    • F26B21/14—Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects using gases or vapours other than air or steam, e.g. inert gases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0969—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1606—Combustion processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1625—Integration of gasification processes with another plant or parts within the plant with solids treatment
    • C10J2300/1637—Char combustion
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
    • F23C2900/99008—Unmixed combustion, i.e. without direct mixing of oxygen gas and fuel, but using the oxygen from a metal oxide, e.g. FeO
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2900/00—Special arrangements for conducting or purifying combustion fumes; Treatment of fumes or ashes
    • F23J2900/15061—Deep cooling or freezing of flue gas rich of CO2 to deliver CO2-free emissions, or to deliver liquid CO2
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26—DRYING
    • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B2200/00—Drying processes and machines for solid materials characterised by the specific requirements of the drying good
    • F26B2200/02—Biomass, e.g. waste vegetative matter, straw
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Abstract

The invention relates to a method for extracting carbon dioxide from the atmosphere, said method comprising the thermochemical conversion of biomasses as a natural intermediate vector for storing carbon dioxide, the carbon dioxide being trapped by a thermochemical cycle (3) that comprises a combustion reactor (8) and an oxidation chamber (9) connected together, and in which flow metal oxides which are alternately oxidised and reduced and which ensure the oxygen supply for the combustion, wherein said thermochemical conversion is achieved using a pyrolysis reactor (2) and said thermochemical cycle (3). According to the invention, the biomasses are dried (1) by air-lean fumes (13) exiting from the oxidation chamber (9) of said thermochemical cycle before said pyrolysis.
PCT/FR2009/051920 2008-10-17 2009-10-08 Method and device for extracting carbon dioxide from the atmosphere WO2010043799A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP09755991A EP2342309A2 (en) 2008-10-17 2009-10-08 Method and device for extracting carbon dioxide from the atmosphere
CA2740501A CA2740501A1 (en) 2008-10-17 2009-10-08 Method for the pyrolysis and gasification of biomasses by means of thermochemical conversion

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR0857066 2008-10-17
FR0857066A FR2937334A1 (en) 2008-10-17 2008-10-17 DEVICE FOR EXTRACTING CO2 FROM THE ATMOSPHERE
FR0857903A FR2937333B1 (en) 2008-10-17 2008-11-21 METHOD AND DEVICE FOR EXTRACTING CARBON DIOXIDE FROM THE ATMOSPHERE
FR0857903 2008-11-21

Publications (2)

Publication Number Publication Date
WO2010043799A2 WO2010043799A2 (en) 2010-04-22
WO2010043799A3 true WO2010043799A3 (en) 2010-11-25

Family

ID=40677750

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2009/051920 WO2010043799A2 (en) 2008-10-17 2009-10-08 Method and device for extracting carbon dioxide from the atmosphere

Country Status (4)

Country Link
EP (1) EP2342309A2 (en)
CA (1) CA2740501A1 (en)
FR (2) FR2937334A1 (en)
WO (1) WO2010043799A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103113919A (en) * 2013-03-07 2013-05-22 华北电力大学（保定） Biomass pyrolysis system of three-stage reactor and working method thereof

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2395306A3 (en) * 2010-06-10 2013-03-06 PiEco GmbH Method and device for drying fibrous goods, in particular wood chips
DE102011051250A1 (en) * 2011-06-22 2013-04-04 Jan A. Meissner Processes and plants for greenhouse gas reduction of power and heating fuels
ITTO20120427A1 (en) * 2012-05-14 2013-11-15 Pierluigi Martini APPARATUS FOR THE GASIFICATION OF SOLID CARBONOSE SUBSTANCES CONTAINED IN VIRGIN BIOMASS AND WASTE.
DE102017005627A1 (en) 2016-10-07 2018-04-12 Lennart Feldmann Method and system for improving the greenhouse gas emission reduction performance of biogenic fuels, heating fuels and / or for enrichment of agricultural land with Humus-C
CN114958430B (en) * 2022-04-27 2023-02-07 广东工业大学 Carbon dioxide self-circulation type biomass high-temperature gasification system and method for byproduct hydrogen

Citations (5)

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Publication number Priority date Publication date Assignee Title
US20030024853A1 (en) * 2001-07-31 2003-02-06 Lyon Richard K. Method for efficient and environmentally clean utilization of solid fuels
US20030029088A1 (en) * 2001-07-31 2003-02-13 Lyon Richard K. Process for converting coal into fuel cell quality hydrogen and sequestration-ready carbon dioxide
WO2004072207A1 (en) * 2003-02-17 2004-08-26 Fortum Oyj Method for producing synthesis gas
US20050175533A1 (en) * 2003-12-11 2005-08-11 Thomas Theodore J. Combustion looping using composite oxygen carriers
EP1933087A2 (en) * 2006-12-11 2008-06-18 General Electric Company Systems and methods using an unmixed fuel processor

Family Cites Families (2)

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Publication number Priority date Publication date Assignee Title
US7819070B2 (en) * 2005-07-15 2010-10-26 Jc Enviro Enterprises Corp. Method and apparatus for generating combustible synthesis gas
WO2007081296A1 (en) * 2006-01-16 2007-07-19 Gep Yesil Enerji Uretim Teknolojileri Ltd. Sti. Downdraft/updraft gasifier for syngas production from solid waste

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030024853A1 (en) * 2001-07-31 2003-02-06 Lyon Richard K. Method for efficient and environmentally clean utilization of solid fuels
US20030029088A1 (en) * 2001-07-31 2003-02-13 Lyon Richard K. Process for converting coal into fuel cell quality hydrogen and sequestration-ready carbon dioxide
WO2004072207A1 (en) * 2003-02-17 2004-08-26 Fortum Oyj Method for producing synthesis gas
US20050175533A1 (en) * 2003-12-11 2005-08-11 Thomas Theodore J. Combustion looping using composite oxygen carriers
EP1933087A2 (en) * 2006-12-11 2008-06-18 General Electric Company Systems and methods using an unmixed fuel processor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103113919A (en) * 2013-03-07 2013-05-22 华北电力大学（保定） Biomass pyrolysis system of three-stage reactor and working method thereof

Also Published As

Publication number Publication date
CA2740501A1 (en) 2010-04-22
FR2937334A1 (en) 2010-04-23
FR2937333B1 (en) 2011-06-17
EP2342309A2 (en) 2011-07-13
FR2937333A1 (en) 2010-04-23
WO2010043799A2 (en) 2010-04-22

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