WO2009121973A1 - Device for producing chocolate - Google Patents

Device for producing chocolate Download PDF

Info

Publication number
WO2009121973A1
WO2009121973A1 PCT/EP2009/054086 EP2009054086W WO2009121973A1 WO 2009121973 A1 WO2009121973 A1 WO 2009121973A1 EP 2009054086 W EP2009054086 W EP 2009054086W WO 2009121973 A1 WO2009121973 A1 WO 2009121973A1
Authority
WO
WIPO (PCT)
Prior art keywords
mixer
grinder
taste
mixing
changer
Prior art date
Application number
PCT/EP2009/054086
Other languages
French (fr)
Inventor
Simon Jakob Van Leverink
Original Assignee
Duyvis Wiener B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Duyvis Wiener B.V. filed Critical Duyvis Wiener B.V.
Priority to MX2010010925A priority Critical patent/MX2010010925A/en
Priority to CN200980118233.9A priority patent/CN102036743B/en
Priority to EP09726776A priority patent/EP2288436A1/en
Priority to AP2010005460A priority patent/AP3476A/en
Priority to US12/936,081 priority patent/US9004383B2/en
Priority to JP2011502396A priority patent/JP5639038B2/en
Priority to UAA201011964A priority patent/UA100881C2/en
Priority to RU2010143721/05A priority patent/RU2505350C2/en
Priority to BRPI0909492-0A priority patent/BRPI0909492B1/en
Publication of WO2009121973A1 publication Critical patent/WO2009121973A1/en
Priority to HK11111644.4A priority patent/HK1157273A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/04Apparatus specially adapted for manufacture or treatment of cocoa or cocoa products
    • A23G1/10Mixing apparatus; Roller mills for preparing chocolate
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/04Apparatus specially adapted for manufacture or treatment of cocoa or cocoa products
    • A23G1/10Mixing apparatus; Roller mills for preparing chocolate
    • A23G1/12Chocolate-refining mills, i.e. roll refiners
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/50Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle
    • B01F25/52Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle with a rotary stirrer in the recirculation tube
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • B01F27/95Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with stirrers having planetary motion, i.e. rotating about their own axis and about a sun axis
    • B01F27/953Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with stirrers having planetary motion, i.e. rotating about their own axis and about a sun axis using only helical stirrers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00Other mixers; Mixing plants; Combinations of mixers
    • B01F33/80Mixing plants; Combinations of mixers
    • B01F33/83Mixing plants specially adapted for mixing in combination with disintegrating operations
    • B01F33/831Devices with consecutive working receptacles, e.g. with two intermeshing tools in one of the receptacles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00Other mixers; Mixing plants; Combinations of mixers
    • B01F33/80Mixing plants; Combinations of mixers
    • B01F33/836Mixing plants; Combinations of mixers combining mixing with other treatments
    • B01F33/8361Mixing plants; Combinations of mixers combining mixing with other treatments with disintegrating
    • B01F33/83613Mixing plants; Combinations of mixers combining mixing with other treatments with disintegrating by grinding or milling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C17/00Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls
    • B02C17/16Mills in which a fixed container houses stirring means tumbling the charge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C17/00Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls
    • B02C17/18Details
    • B02C17/183Feeding or discharging devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2101/00Mixing characterised by the nature of the mixed materials or by the application field
    • B01F2101/06Mixing of food ingredients
    • B01F2101/12Mixing of chocolate ingredients
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/23Mixers with rotary stirring devices in fixed receptacles; Kneaders characterised by the orientation or disposition of the rotor axis
    • B01F27/232Mixers with rotary stirring devices in fixed receptacles; Kneaders characterised by the orientation or disposition of the rotor axis with two or more rotation axes
    • B01F27/2324Mixers with rotary stirring devices in fixed receptacles; Kneaders characterised by the orientation or disposition of the rotor axis with two or more rotation axes planetary

Definitions

  • the mixer defines a toroidal, preferably annular mixing chamber accommodating at least one mixing element, which is rotatable about its axis and/or about the central axis of the toroidal vessel.
  • the mixer, the grinder, and, if present, the taste-changer form a self-contained unit, i.e. are configured such that installation of the device requires no connection of pipes or pumps and is preferably reduced to positioning the unit and connecting the unit to a source of electricity.
  • the mixer 3, grinder 4, and taste-changer 5 form a compact and self-contained unit that can be configured such that installation requires no connection of pipes or pumps, i.e. is essentially reduced to positioning the unit and connecting the unit to a source of electricity.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Confectionery (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)
  • Crushing And Grinding (AREA)

Abstract

The invention relates to a device (1) for producing chocolate by mixing and grinding ingredients, such as cacao mass, cacao butter, sugar and/or milk powder, comprising a mixer (3), a grinder (4), and means for passing the mixture from the mixer (3) to the grinder (4). The mixer (3) comprises a toroidal, preferably annular vessel (6) for receiving and mixing the ingredients.

Description

Device for producing chocolate
The invention relates to a device for producing chocolate by mixing and grinding ingredients, such as cacao mass, cacao butter, sugar and/or milk powder, comprising a mixer, a grinder, and means for passing the obtained mixture 5 from the mixer to the grinder.
European patent application EP 442 544 relates to a method and device for mixing and grinding chocolate. The embodiment shown schematically in Figure 1 of EP 442 544 comprises a grinding device 1 in which the components of the
±\j process mass are ρrβ~iuiX6u sπu yrouπu . i-± pump ^, circu±αLcS the process mass to a ball mill 3 which is connected with its outlet via a taste-changer 4 to the intake of the grinding device 1.
GB 1 251 043 relates to a process wherein
15 constituents in a chocolate material are cyclically mixed and comminuted. The material is first premixed and then comminuted in a stirrer-type ball mill. Sugar, cocoa beans/liquor, milk powder and cocoa butter are premixed at 22 in Figure 4 of GB 1 251 043, pumped at 23 to mixer
20 vessels 24 or 25 where they are aerated, and pumps 26, 33 deliver the material to a mill 29. Aeration is effected by spreading the material over a spinning member 7 (Figure 5) so that it forms a film and feeding heated and/or irradiated air via a duct 8 on to the film. The mill is charged with 5 alloy steel, or ceramic balls of 1/4" to 3/8" diameter, which are retained by a mesh screen. The mixing and/or grinding vessels and pipe lines may be jacketed for heating or cooling. The mixer comprises a shaft 40 (Figure 5) carrying arms 42 and radial agitator members 43 which present an edge 0 44 to the material. A further vertical agitator 46 is mounted on the other side of the shaft and stirrer shaft 40 carries a screw 47 which is rotated by gearing in a radial arm 48 and produces vertical movement of the material. A second form of mixer includes a spiral scraper 49 and gear box arm 50 (Figure 6). A surface-tension controlling agent, e.g. lecithin, may be introduced by a metering valve.
It is an object of the present invention to provide a more compact device for producing chocolate.
To this end, the device according to the present invention is characterized in that the mixer comprises a toroidal, preferably annular vessel for receiving and mixing the ingredients. It is preferred that the grinder, preferably a ball mill, is located in the central space of the toroidal vessel.
It is further preferred that the mixer defines a toroidal, preferably annular mixing chamber accommodating at least one mixing element, which is rotatable about its axis and/or about the central axis of the toroidal vessel.
In a another aspect, the device comprises a taste- changer, preferably at least connected to an inlet of the mixer .
In yet a further aspect, the mixer, the grinder, and, if present, the taste-changer form a self-contained unit, i.e. are configured such that installation of the device requires no connection of pipes or pumps and is preferably reduced to positioning the unit and connecting the unit to a source of electricity. The invention will now be explained in more detail with reference to the drawings, which schematically show a preferred embodiment according to the present invention.
Figure 1 is a perspective view of a mixer grinder according to the present invention. Figure 2 is a cross-section of the mixer grinder shown in Figure 1.
Figures 1 and 2 show a device 1 for producing chocolate comprising a frame 2, a mixer 3, a grinder 4, a taste-changer 5, and means, such as pipes and pumps, for passing a mixture of ingredients from the mixer 3 to the grinder 4 and/or the taste-changer 5.
The mixer 3, in this field also referred to as "pre-mixer", comprises an annular vessel 6, defining a ring- shaped (endless) mixing chamber for receiving the ingredients and defining a central space 7. The outer wall of the vessel 6 comprises an inlet 8 for feeding the ingredients to the vessel 6. The top of the vessel 6 is closed by a removable lid 9 and its bottom communicates with an outlet valve 10. A plurality of mixing elements 11 is located inside the vessel 6, each rotatable about its axis and about the central axis of the annular vessel 6.
More specifically, in the example shown in the Figures, the mixing elements 11 are rotatably mounted on arms 12 connected to a first shaft 13 that coincides with the central axis of the annular vessel 6 and that is operatively coupled to a motor 14 mounted, e.g., on top of the vessel 6. The arms 12 have different lengths, such that a first (set of) mixing element (s) HA is located near the inner wall of the vessel 6 nearest the central axis and a second (set of) mixing element (s) HB is located near the inner wall farthest from the central axis of the vessel 6.
Each of the mixing elements 11 comprises a screw 15 extending over the greater part of the height of the vessel 6. A gear 16 is provided near the upper end of each of the mixing elements 11, which gear 16 meshes with a toothed ring 17 extending along the circumference of the inner wall of the vessel 6 nearest the central axis. In this example, the lead of the screw (s) 15 on the first mixing element (s) HA is opposite to that of the screw (s) 15 on the second mixing element (s) HB and a further gear 18 is provided between the second mixing element (s) HB and the toothed ring 17, such that, upon rotation of the mixing elements 11, upwards transport of the mixture is effected by all mixing elements 11. The grinder 4 comprises a stirrer-type ball mill 4, known in itself and m turn comprising a cylindrical vessel 19 filled with, e.g., hardened steel balls (not shown), and a central shaft 20 provided with radially extending stirring arms 21 and operatively coupled to a motor 22. The ball mill 4 is located in the central space 7 of the annular vessel 6 and connected, via a pump 23, pipes 24, and a cut-off valve 25, to an outlet of the mixer 3. The top of the grinder communicates with the top of the mixer. To further enhance the compact build of the device 1 according to the present invention, the shafts 13, 20 with which the mixer 3 and the grinder 4 are coupled to the respective motors 14, 22 are coaxial. Thermal insulation 26 is provided between the grinder 4 and the mixer 3. The taste-changer 5, also known in itself, comprises a central shaft 27 provided with radial pins and, at its lower end, a disc 28, and a ventilator (not shown) Suitable taste-changers are described m EP 294 876 and GB 1 251 044. The taste-changer 5 is connected, via the pump 23, pipes 29, and a cut-off valve 30, to an outlet of the mixer 3.
During operation, the mixer 3 is activated and ingredients, such as cacao mass (also referred to as liquor) , cacao butter, sugar, milk powder lecithin and/or vanalin, preferably having a total fat content of e.g. at least 30 wt%, are fed to the mixer 3 via the inlet 8. When the ingredients have been properly mixed, e.g. after half an hour, the grinder 4 is activated and the mixture is pumped to the grinder 4. The mixture flows through the grinder 4, over the top of the grinder 4, and back into the mixer in one or more cycles. When a desired particle size distribution has been accomplished, the cut-off valve 31 between the mixer 3 and the taste-changer 5 is opened. Subsequently, the cut-off valve 25 between the mixer 3 and the grinder 4 is closed, the taste-changer 5 and the associated ventilator and heating elements are activated in a manner known in itself, and the mixture is circulated through the mixer 3 and the taste-changer 5, e.g. for one and a half hours. The mixture leaving the taste-changer 5 flows back into the mixer 3, whereas the air leaving the taste-changer 5 and containing volatile components of the mixture, such as water and amino acids, is vented, e.g. to a flue. Samples are taken from the mixture and, once the desired properties have been achieved, the mixture is drained from the device 1.
The mixer 3, grinder 4, and taste-changer 5 form a compact and self-contained unit that can be configured such that installation requires no connection of pipes or pumps, i.e. is essentially reduced to positioning the unit and connecting the unit to a source of electricity.
The invention is not restricted to the above- described embodiments, which can be varied in a number of ways within the scope of the claims. For instance, the device can be provided with a first pump for passing mixture from the mixer to the grinder and a second pump for passing mixture from the mixer to the taste-changer. In that case, grinding and taste-changing can be performed simultaneously, reducing processing time.

Claims

1. Device (1) for producing chocolate by mixing and grinding ingredients, such as cacao mass, cacao butter, sugar and/or milk powder, comprising a mixer (3), a grinder (4), and means for passing the mixture from the mixer (3) to the grinder (4), characterised in that the mixer (3) comprises a toroidal, preferably annular vessel (6) for receiving and mixing the ingredients.
2. Device (1) according to claim 1, wherein the grinder (4) is located in the central space (7) of the toroidal vessel (6) .
3. Device (1) according to claim 1 or 2, wherein the mixer (3) defines a toroidal, preferably annular mixing chamber accommodating at least one mixing element (11) which is rotatable about its axis and/or about the central axis of the toroidal vessel (6).
4. Device (1) according to any one of the preceding claims, wherein the mixer (3) and the grinder (4) are coupled to a motor or respective motors (14, 12) via coaxial shafts (13, 20) .
5. Device (1) according to any one of the preceding claims, wherein the grinder is a ball mill (4) .
6. Device (1) according to any one of the preceding claims, comprising a taste-changer (5), preferably connected to an inlet of the mixer (3) .
7. Device (1) according to any one of the preceding claims, wherein the mixer (3), the grinder (4), and, if present, the taste-changer (5) form a self-contained unit.
8. Device (1) according to claim 6 or 7, comprising a first pump for passing mixture from the mixer (3) to the grinder (4) and a second pump for passing mixture from the mixer (3) to the taste-changer (5).
PCT/EP2009/054086 2008-04-04 2009-04-06 Device for producing chocolate WO2009121973A1 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
MX2010010925A MX2010010925A (en) 2008-04-04 2009-04-06 Device for producing chocolate.
CN200980118233.9A CN102036743B (en) 2008-04-04 2009-04-06 Device for producing chocolate
EP09726776A EP2288436A1 (en) 2008-04-04 2009-04-06 Device for producing chocolate
AP2010005460A AP3476A (en) 2008-04-04 2009-04-06 Device for producing chocolate
US12/936,081 US9004383B2 (en) 2008-04-04 2009-04-06 Device for producing chocolate
JP2011502396A JP5639038B2 (en) 2008-04-04 2009-04-06 Chocolate production equipment
UAA201011964A UA100881C2 (en) 2008-04-04 2009-04-06 Device for producing chocolate
RU2010143721/05A RU2505350C2 (en) 2008-04-04 2009-04-06 Device for chocolate preparation
BRPI0909492-0A BRPI0909492B1 (en) 2008-04-04 2009-04-06 CHOCOLATE PRODUCTION DEVICE
HK11111644.4A HK1157273A1 (en) 2008-04-04 2011-10-27 Device for producing chocolate

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP08103382A EP2106845B1 (en) 2008-04-04 2008-04-04 Device for producing chocolate
EP08103382.1 2008-04-04

Publications (1)

Publication Number Publication Date
WO2009121973A1 true WO2009121973A1 (en) 2009-10-08

Family

ID=39739678

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/054086 WO2009121973A1 (en) 2008-04-04 2009-04-06 Device for producing chocolate

Country Status (17)

Country Link
US (1) US9004383B2 (en)
EP (2) EP2106845B1 (en)
JP (1) JP5639038B2 (en)
CN (1) CN102036743B (en)
AP (1) AP3476A (en)
AT (1) ATE525123T1 (en)
BR (1) BRPI0909492B1 (en)
CO (1) CO6310970A2 (en)
DK (1) DK2106845T3 (en)
ES (1) ES2373347T3 (en)
HK (1) HK1157273A1 (en)
MX (1) MX2010010925A (en)
MY (1) MY152423A (en)
PT (1) PT2106845E (en)
RU (1) RU2505350C2 (en)
UA (1) UA100881C2 (en)
WO (1) WO2009121973A1 (en)

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Publication number Priority date Publication date Assignee Title
DE102012001417A1 (en) * 2012-01-26 2013-08-01 Netzsch-Feinmahltechnik Gmbh Process for producing grease
KR101426504B1 (en) 2012-06-08 2014-08-06 주식회사 태환자동화산업 Conching device for cacao
NL2012088C2 (en) * 2014-01-15 2015-01-27 Caotech Beheer B V METHOD FOR OPERATING A BALL MILL AND A GRINDING SYSTEM FOR CARRYING OUT THE METHOD.
WO2016115557A1 (en) * 2015-01-16 2016-07-21 CocoTerra Company Chocolate processing system and method
MX2020000703A (en) * 2017-07-20 2020-08-17 Trade Secret Chocolate Methods and apparatus for processing chocolate.
CN107321449B (en) * 2017-08-02 2022-12-09 浙江艾领创矿业科技有限公司 Multi-shaft stirring mill
US11470853B2 (en) 2019-03-15 2022-10-18 CocoTerra Company Interface and application for designing a chocolate-making experience
CN110732279A (en) * 2019-11-08 2020-01-31 孙晓梅 automatic dyestuff grinds mixer
CN111744377A (en) * 2020-07-15 2020-10-09 袁静 Simple rock sugar processing device
CN112246144A (en) * 2020-10-28 2021-01-22 佛山市尊朗机械设备有限公司 Stirring machine
CN112808037A (en) * 2021-01-15 2021-05-18 孙红霞 Food and drug inspection dissolving device

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FR1031141A (en) * 1950-04-26 1953-06-19 Macchine Ind Dolciaria Carle & Roller machine for final crushing of chocolate
US3058413A (en) * 1959-09-26 1962-10-16 Carle & Montanari Spa Roller or trough machine for the final working up of chocolate
DE1167171B (en) * 1959-09-26 1964-04-02 Carle & Montanari Spa Conching machine for finishing chocolate mass
GB1251043A (en) * 1968-01-26 1971-10-27
JPS63214329A (en) * 1987-03-02 1988-09-07 Shinyou Sangyo Kk Vertical agitator with spiral blade

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SU644448A1 (en) * 1976-05-18 1979-03-06 Одесский технологический институт пищевой промышленности им.М.В.Ломоносова Machine for homogenisation pf semi-finished confectionery products
US2692124A (en) * 1952-09-05 1954-10-19 Mendoza Fausto Celorio Machine for kneading dough
GB1251044A (en) 1968-01-26 1971-10-27
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NL8701379A (en) 1987-06-12 1989-01-02 Wiener & Co Apparatenbouw Bv Breeding device.
NL9000105A (en) 1990-01-16 1991-08-16 Wiener & Co Apparatenbouw Bv METHOD AND APPARATUS FOR PROCESSING CHOCOLATE MASS
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Publication number Priority date Publication date Assignee Title
FR1031141A (en) * 1950-04-26 1953-06-19 Macchine Ind Dolciaria Carle & Roller machine for final crushing of chocolate
US3058413A (en) * 1959-09-26 1962-10-16 Carle & Montanari Spa Roller or trough machine for the final working up of chocolate
DE1167171B (en) * 1959-09-26 1964-04-02 Carle & Montanari Spa Conching machine for finishing chocolate mass
GB1251043A (en) * 1968-01-26 1971-10-27
JPS63214329A (en) * 1987-03-02 1988-09-07 Shinyou Sangyo Kk Vertical agitator with spiral blade

Also Published As

Publication number Publication date
EP2288436A1 (en) 2011-03-02
DK2106845T3 (en) 2012-01-16
US20110147507A1 (en) 2011-06-23
JP2011519269A (en) 2011-07-07
AP3476A (en) 2015-12-31
ES2373347T3 (en) 2012-02-02
CO6310970A2 (en) 2011-08-22
HK1157273A1 (en) 2012-06-29
CN102036743B (en) 2015-04-22
MY152423A (en) 2014-09-30
BRPI0909492A2 (en) 2015-12-22
AP2010005460A0 (en) 2010-12-31
RU2505350C2 (en) 2014-01-27
MX2010010925A (en) 2011-02-22
BRPI0909492B1 (en) 2019-04-09
US9004383B2 (en) 2015-04-14
EP2106845A1 (en) 2009-10-07
CN102036743A (en) 2011-04-27
PT2106845E (en) 2011-12-23
ATE525123T1 (en) 2011-10-15
EP2106845B1 (en) 2011-09-21
RU2010143721A (en) 2012-05-20
UA100881C2 (en) 2013-02-11
JP5639038B2 (en) 2014-12-10

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