WO2009114263A2 - Process for production of ethylbenzene from toluene and methane - Google Patents
Process for production of ethylbenzene from toluene and methane Download PDFInfo
- Publication number
- WO2009114263A2 WO2009114263A2 PCT/US2009/035002 US2009035002W WO2009114263A2 WO 2009114263 A2 WO2009114263 A2 WO 2009114263A2 US 2009035002 W US2009035002 W US 2009035002W WO 2009114263 A2 WO2009114263 A2 WO 2009114263A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- methane
- product stream
- styrene
- ethylbenzene
- toluene
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
- C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
- C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
- C07C15/46—Styrene; Ring-alkylated styrenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
- C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/919—Apparatus considerations
- Y10S585/921—Apparatus considerations using recited apparatus structure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/929—Special chemical considerations
- Y10S585/943—Synthesis from methane or inorganic carbon source, e.g. coal
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010550729A JP2011513487A (en) | 2008-03-13 | 2009-02-24 | Process for producing ethylbenzene from toluene and methane |
CA2718250A CA2718250A1 (en) | 2008-03-13 | 2009-02-24 | Process for production of ethylbenzene from toluene and methane |
EP09718868A EP2252565A4 (en) | 2008-03-13 | 2009-02-24 | Process for production of ethylbenzene from toluene and methane |
CN2009801088750A CN101970384A (en) | 2008-03-13 | 2009-02-24 | Process for production of ethylbenzene from toluene and methane |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/047,953 | 2008-03-13 | ||
US12/047,953 US8076527B2 (en) | 2008-03-13 | 2008-03-13 | Process for production of ethylbenzene from toluene and methane |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2009114263A2 true WO2009114263A2 (en) | 2009-09-17 |
WO2009114263A3 WO2009114263A3 (en) | 2010-01-07 |
Family
ID=41063777
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2009/035002 WO2009114263A2 (en) | 2008-03-13 | 2009-02-24 | Process for production of ethylbenzene from toluene and methane |
Country Status (7)
Country | Link |
---|---|
US (3) | US8076527B2 (en) |
EP (1) | EP2252565A4 (en) |
JP (1) | JP2011513487A (en) |
KR (1) | KR20100123719A (en) |
CN (1) | CN101970384A (en) |
CA (1) | CA2718250A1 (en) |
WO (1) | WO2009114263A2 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120215045A1 (en) * | 2011-02-22 | 2012-08-23 | Fina Technology, Inc. | Staged Injection of Oxygen for Oxidative Coupling or Dehydrogenation Reactions |
EP2691496A2 (en) | 2011-03-29 | 2014-02-05 | Fuelina, Inc. | Hybrid fuel and method of making the same |
US20120296131A1 (en) * | 2011-05-22 | 2012-11-22 | Fina Technology, Inc. | Method for alkylation of toluene in a pre-existing dehydrogenation plant |
US10308885B2 (en) | 2014-12-03 | 2019-06-04 | Drexel University | Direct incorporation of natural gas into hydrocarbon liquid fuels |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1238602A (en) | 1968-11-21 | 1971-07-07 | ||
SU358928A1 (en) * | 1970-04-27 | 1974-08-25 | ||
US3904484A (en) * | 1972-09-07 | 1975-09-09 | Badger Co | Ethylbenzene-styrene separation |
US4113787A (en) * | 1977-01-10 | 1978-09-12 | Uop Inc. | Aromatic hydrocarbon dehydrogenation process |
US4982038A (en) | 1985-03-19 | 1991-01-01 | Phillips Petroleum Company | Oxidative methylation of organic compounds |
US4950836A (en) | 1985-06-07 | 1990-08-21 | Phillips Petroleum Company | Oxidative methylation of organic compounds |
GB8802731D0 (en) * | 1988-02-06 | 1988-03-09 | British Petroleum Co Plc | Chemical process |
US4956327A (en) * | 1989-05-31 | 1990-09-11 | Institute Of Gas Technology | Mixed basic metal oxide/sulfide catalyst |
EP0335130A1 (en) * | 1988-03-28 | 1989-10-04 | Institute of Gas Technology | Mixed basic metal oxide catalyst |
US4950827A (en) | 1988-03-28 | 1990-08-21 | Institute Of Gas Technology | Oxidative coupling of aliphatic and alicyclic hydrocarbons with aliphatic and alicyclic substituted aromatic hydrocarbons |
JPH0822825B2 (en) * | 1989-01-26 | 1996-03-06 | 日本鋼管株式会社 | Method for producing ethylbenzene and styrene |
US5026937A (en) * | 1989-12-29 | 1991-06-25 | Uop | Aromatization of methane using zeolite incorporated in a phosphorus-containing alumina |
CN1050071C (en) * | 1995-08-16 | 2000-03-08 | 南开大学 | Catalyst for preparing styrene and ethylbenzene |
JPH1025257A (en) * | 1996-07-12 | 1998-01-27 | Toyota Motor Corp | Method for converting methyl group into vinyl group |
US5936135A (en) * | 1997-05-02 | 1999-08-10 | Council Of Scientific & Industrial Research | Process for the preparation of hydrocarbons |
US5880320A (en) * | 1997-08-05 | 1999-03-09 | Netzer; David | Combination process for manufacturing ethylene ethylbenzene and styrene |
ATE266614T1 (en) * | 2000-02-02 | 2004-05-15 | Dow Global Technologies Inc | INTEGRATED PROCESS FOR PRODUCING AN ALKENYL-SUBSTITUTED AROMATIC COMPOUND |
US6388155B1 (en) * | 2000-08-01 | 2002-05-14 | Abb Lummus Global Inc. | Styrene dehydrogenation reactor effluent treatment |
GB0129611D0 (en) * | 2001-12-11 | 2002-01-30 | Bp Chem Int Ltd | Process for production of styrene |
US7402719B2 (en) * | 2002-06-13 | 2008-07-22 | Velocys | Catalytic oxidative dehydrogenation, and microchannel reactors for catalytic oxidative dehydrogenation |
WO2004000767A1 (en) * | 2002-06-19 | 2003-12-31 | Exxonmobil Chemical Patents Inc. | Manufacture of xylenes from reformate |
US20040138511A1 (en) * | 2003-01-10 | 2004-07-15 | James Butler | Aromatic alkylation process with direct recycle |
US7220390B2 (en) * | 2003-05-16 | 2007-05-22 | Velocys, Inc. | Microchannel with internal fin support for catalyst or sorption medium |
TWI438187B (en) * | 2005-02-28 | 2014-05-21 | Evonik Degussa Gmbh | Acrylic and water-absorbing polymer structures based upon renewable raw materials and process for their preparation |
-
2008
- 2008-03-13 US US12/047,953 patent/US8076527B2/en not_active Expired - Fee Related
-
2009
- 2009-02-24 CA CA2718250A patent/CA2718250A1/en not_active Abandoned
- 2009-02-24 WO PCT/US2009/035002 patent/WO2009114263A2/en active Application Filing
- 2009-02-24 KR KR1020107020429A patent/KR20100123719A/en not_active Application Discontinuation
- 2009-02-24 EP EP09718868A patent/EP2252565A4/en not_active Withdrawn
- 2009-02-24 JP JP2010550729A patent/JP2011513487A/en active Pending
- 2009-02-24 CN CN2009801088750A patent/CN101970384A/en active Pending
-
2011
- 2011-11-07 US US13/290,211 patent/US8314282B2/en active Active
-
2012
- 2012-09-06 US US13/604,760 patent/US8734737B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of EP2252565A4 * |
Also Published As
Publication number | Publication date |
---|---|
CA2718250A1 (en) | 2009-09-17 |
WO2009114263A3 (en) | 2010-01-07 |
US8734737B2 (en) | 2014-05-27 |
US20090234168A1 (en) | 2009-09-17 |
JP2011513487A (en) | 2011-04-28 |
US20120328482A1 (en) | 2012-12-27 |
US20120059206A1 (en) | 2012-03-08 |
EP2252565A4 (en) | 2011-03-16 |
KR20100123719A (en) | 2010-11-24 |
EP2252565A2 (en) | 2010-11-24 |
CN101970384A (en) | 2011-02-09 |
US8076527B2 (en) | 2011-12-13 |
US8314282B2 (en) | 2012-11-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN108530256B (en) | Combined dealkylation-transalkylation process for maximizing xylene production from heavy reformate | |
KR20190120249A (en) | Recovering light alkyl mono-aromatic compounds from heavy alkyl aromatic and alkyl-bridged non-condensed alkyl aromatic compounds. | |
US8071836B2 (en) | Process for toluene and methane coupling in a microreactor | |
US9272962B2 (en) | Method for production of styrene from toluene and methanol | |
US20100041931A1 (en) | Method for Production of Styrene from Toluene Syngas | |
ZA200506862B (en) | Process for the production of alkylaromatics | |
US8734737B2 (en) | Production of EB from toluene and methane | |
US10065904B2 (en) | Process for producing alkylated aromatic hydrocarbons from a mixed hydrocarbon feedstream | |
KR102429204B1 (en) | Method and apparatus for methylation of aromatics in aromatic complexes | |
WO2015065629A1 (en) | Removal of light alkylated aromatics from the heavy alkylated aromatics stream | |
KR20220110550A (en) | Aromatic alkylation process | |
US20100022813A1 (en) | Process for Reducing Ethylbenzene Content from an Aromatic Stream |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200980108875.0 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 09718868 Country of ref document: EP Kind code of ref document: A2 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2718250 Country of ref document: CA |
|
ENP | Entry into the national phase |
Ref document number: 20107020429 Country of ref document: KR Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2010550729 Country of ref document: JP Ref document number: 2009718868 Country of ref document: EP |
|
NENP | Non-entry into the national phase |
Ref country code: DE |