WO2009108264A3 - Epoxidation catalyst - Google Patents

Epoxidation catalyst Download PDF

Info

Publication number
WO2009108264A3
WO2009108264A3 PCT/US2009/000599 US2009000599W WO2009108264A3 WO 2009108264 A3 WO2009108264 A3 WO 2009108264A3 US 2009000599 W US2009000599 W US 2009000599W WO 2009108264 A3 WO2009108264 A3 WO 2009108264A3
Authority
WO
WIPO (PCT)
Prior art keywords
titanium
epoxidation catalyst
catalyst
vanadium
reacting
Prior art date
Application number
PCT/US2009/000599
Other languages
French (fr)
Other versions
WO2009108264A2 (en
Inventor
Bi Le-Khac
Original Assignee
Lyondell Chemical Technology, L.P.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lyondell Chemical Technology, L.P. filed Critical Lyondell Chemical Technology, L.P.
Priority to CN2009801098108A priority Critical patent/CN101977687A/en
Priority to EP09714532A priority patent/EP2247380A2/en
Priority to JP2010548668A priority patent/JP2011513170A/en
Publication of WO2009108264A2 publication Critical patent/WO2009108264A2/en
Publication of WO2009108264A3 publication Critical patent/WO2009108264A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

Titanium or vanadium zeolite catalysts are prepared by reacting a titanium or vanadium compound, a silicon source, a templating agent, and a hydrophobic hydrocarbon wax at a temperature and for a time sufficient to form a molecular sieve. The catalyst is useful in olefin epoxidation with hydrogen peroxide.
PCT/US2009/000599 2008-02-27 2009-01-29 Epoxidation catalyst WO2009108264A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN2009801098108A CN101977687A (en) 2008-02-27 2009-01-29 Epoxidation catalyst
EP09714532A EP2247380A2 (en) 2008-02-27 2009-01-29 Epoxidation catalyst
JP2010548668A JP2011513170A (en) 2008-02-27 2009-01-29 Epoxidation catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/072,575 2008-02-27
US12/072,575 US20090216033A1 (en) 2008-02-27 2008-02-27 Epoxidation catalyst

Publications (2)

Publication Number Publication Date
WO2009108264A2 WO2009108264A2 (en) 2009-09-03
WO2009108264A3 true WO2009108264A3 (en) 2010-03-18

Family

ID=40935725

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/000599 WO2009108264A2 (en) 2008-02-27 2009-01-29 Epoxidation catalyst

Country Status (6)

Country Link
US (1) US20090216033A1 (en)
EP (1) EP2247380A2 (en)
JP (1) JP2011513170A (en)
KR (1) KR20100127766A (en)
CN (1) CN101977687A (en)
WO (1) WO2009108264A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100076207A1 (en) * 2008-09-24 2010-03-25 Bi Le-Khac Epoxidation catalyst
US8124555B2 (en) * 2010-02-01 2012-02-28 Lyondell Chemical Technology L.P. Process for making titanium-MWW zeolite
KR101214896B1 (en) 2010-04-07 2012-12-24 서강대학교산학협력단 Novel method of preparing vanadosilicate molecular sieves and novel vanadosilicate molecular sieves
WO2012010491A1 (en) * 2010-07-19 2012-01-26 Shell Internationale Research Maatschappij B.V. Epoxidation process
CN102755908B (en) * 2011-04-28 2014-05-14 中国科学院大连化学物理研究所 Alkene epoxidation method
CN102993130A (en) * 2012-12-14 2013-03-27 山东理工大学 Method for synthesizing styrene oxide by directly oxidizing styrene
KR102109788B1 (en) 2016-03-09 2020-05-12 주식회사 엘지화학 Organic zinc catalyst, preparation method of the catalyst and production method of poly(alkylene carbonate) resin over the catalyst
CN108339567B (en) * 2018-02-10 2020-05-12 浙江大学 Method for preparing hydrophobic zeolite catalytic material for encapsulating titanium dioxide
FI130830B1 (en) 2021-11-16 2024-04-15 Teknologian Tutkimuskeskus Vtt Oy Epoxidation of olefin mixture
CN115504482B (en) * 2022-08-12 2023-08-11 浙江师范大学 Titanium-silicon molecular sieve, preparation method and application thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002085513A2 (en) * 2001-03-02 2002-10-31 Basf Aktiengesellschaft Shaped body and method for producing the same
EP1314475A1 (en) * 2001-11-23 2003-05-28 Polimeri Europa S.p.A. Process for the preparation of MFI-Type zeolitic catalysts
WO2004026852A1 (en) * 2002-09-20 2004-04-01 Arco Chemical Technology, L.P. Process for direct oxidation of propylene to propylene oxide and large particle size titanium silicalite catalysts for use therein
WO2005092501A2 (en) * 2004-03-09 2005-10-06 Lyondell Chemical Technology, L.P. Polymer-encapsulated titanium zeolites for oxidation reactions
WO2006111584A1 (en) * 2005-04-22 2006-10-26 Basf Aktiengesellschaft Process for preparing a nanosized zeolitic material
WO2007058709A1 (en) * 2005-11-17 2007-05-24 Lyondell Chemical Technology, L.P. Epoxidation catalyst
WO2007058710A1 (en) * 2005-11-17 2007-05-24 Lyondell Chemical Technology, L.P. Epoxidation catalyst

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3351635A (en) * 1966-03-14 1967-11-07 Halcon International Inc Epoxidation process
US4367342A (en) * 1969-04-02 1983-01-04 Shell Oil Company Olefin epoxidation
IT1127311B (en) * 1979-12-21 1986-05-21 Anic Spa SYNTHETIC, CRYSTALLINE, POROUS MATERIAL CONSTITUTED BY SILICON AND TITANIUM OXIDES, METHOD FOR ITS PREPARATION AND ITS USES
IT1152299B (en) * 1982-07-28 1986-12-31 Anic Spa PROCEDURE FOR THE EXPOSSIDATION OF HYDRAULIC COMPOUNDS
DE4425672A1 (en) * 1994-07-20 1996-01-25 Basf Ag Oxidation catalyst, process for its preparation and oxidation process using the oxidation catalyst
BE1011577A3 (en) * 1997-11-27 1999-11-09 Solvay Epoxidation catalyst, use and method epoxidation catalyst presence.

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002085513A2 (en) * 2001-03-02 2002-10-31 Basf Aktiengesellschaft Shaped body and method for producing the same
EP1314475A1 (en) * 2001-11-23 2003-05-28 Polimeri Europa S.p.A. Process for the preparation of MFI-Type zeolitic catalysts
WO2004026852A1 (en) * 2002-09-20 2004-04-01 Arco Chemical Technology, L.P. Process for direct oxidation of propylene to propylene oxide and large particle size titanium silicalite catalysts for use therein
WO2005092501A2 (en) * 2004-03-09 2005-10-06 Lyondell Chemical Technology, L.P. Polymer-encapsulated titanium zeolites for oxidation reactions
WO2006111584A1 (en) * 2005-04-22 2006-10-26 Basf Aktiengesellschaft Process for preparing a nanosized zeolitic material
WO2007058709A1 (en) * 2005-11-17 2007-05-24 Lyondell Chemical Technology, L.P. Epoxidation catalyst
WO2007058710A1 (en) * 2005-11-17 2007-05-24 Lyondell Chemical Technology, L.P. Epoxidation catalyst

Also Published As

Publication number Publication date
KR20100127766A (en) 2010-12-06
JP2011513170A (en) 2011-04-28
EP2247380A2 (en) 2010-11-10
US20090216033A1 (en) 2009-08-27
WO2009108264A2 (en) 2009-09-03
CN101977687A (en) 2011-02-16

Similar Documents

Publication Publication Date Title
WO2009108264A3 (en) Epoxidation catalyst
PL1764378T3 (en) Catalyst composition for polymerization of olefins, polymerization process using the same, and method for its preparation
DE602005011052D1 (en) EPOXIDATION PROCESS IN WHICH THE TITANIUM OR VANADIUM TOOLITE CATALYST IS PRE-TREATED WITH AN AMINOPOLYIC ACID
WO2010031076A3 (en) Conversion of prenyl derivatives to isoprene
EP2086678A4 (en) A method for preparing porous organic-inorganic hybrid materials, porous organic-inorganic hybrid materials obtained by the method and catalytic uses of the materials
EP2218725A4 (en) Bridged metallocene compound, olefin polymerization catalyst using the compound and ethylene polymer obtained by using the catalyst
WO2009005003A1 (en) Transition metal complex compound, olefin polymerization catalyst containing the compound, and method for producing olefin polymer performed in the presence of the catalyst
MX2012003525A (en) Silica-coated alumina activator-supports for metallocene catalyst compositions.
IL185683A (en) Dual specificity oligonucleotide and processes using the same
WO2006002185A8 (en) Chemical compounds
WO2012012495A3 (en) Functionalization of organic molecules using metal-organic frameworks (mofs) as catalysts
TW200720238A (en) Intramolecular prins reaction and catalysts suitable therefor (citronellall to isopulegol)
WO2009077443A3 (en) Azolylmethyloxiranes, use thereof and agents containing the same
WO2007061923A3 (en) Glucokinase activators
WO2006023189A3 (en) Treatment of air to a catalyst regenerator to maintain catalyst activity
WO2007057768A3 (en) Sulfonyl derivatives
EP2014685A3 (en) Polymerisation process
PL1947123T3 (en) Catalyst component for ethylene polymerization, preparation thereof and catalyst containing the same
ATE482941T1 (en) DIRECT EPOXIDATION PROCESS WITH IMPROVED CATALYST COMPOSITION
WO2010077537A3 (en) Fluid catalytic cracking system and process
WO2011010891A3 (en) Novel post metallocene-type transition metal compound
WO2004078336A3 (en) PROCESS FOR THE DEHYDRATION OF ALCOHOLS YIELDING α-OLEFINS
WO2008036591A3 (en) Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
WO2011056432A3 (en) Catalyst compounds and use thereof
WO2008135398A3 (en) A process for the preparation of an olefin oxide

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200980109810.8

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 09714532

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: 20107019001

Country of ref document: KR

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 2010548668

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2009714532

Country of ref document: EP