WO2009080443A1 - Dispersion comprising cerium oxide and colloidal silicon dioxide - Google Patents
Dispersion comprising cerium oxide and colloidal silicon dioxide Download PDFInfo
- Publication number
- WO2009080443A1 WO2009080443A1 PCT/EP2008/066496 EP2008066496W WO2009080443A1 WO 2009080443 A1 WO2009080443 A1 WO 2009080443A1 EP 2008066496 W EP2008066496 W EP 2008066496W WO 2009080443 A1 WO2009080443 A1 WO 2009080443A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- dispersion
- cerium oxide
- particles
- silicon dioxide
- oxide particles
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/1454—Abrasive powders, suspensions and pastes for polishing
- C09K3/1463—Aqueous liquid suspensions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/02—Polishing compositions containing abrasives or grinding agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/1409—Abrasive particles per se
Definitions
- Dispersion comprising cerium oxide and colloidal silicon dioxide
- the invention relates to a dispersion comprising cerium oxide and silicon dioxide, and to its production and use .
- cerium oxide dispersions can be used to polish glass surfaces, metal surfaces and dielectric surfaces, both for coarse polishing (high material removal, irregular profile, scratches) and for fine polishing (low material removal, smooth surfaces, few scratches, if any) .
- a disadvantage is often found to be that cerium oxide particles and the surface to be polished bear different electrical charges and attract one another as a result. As a consequence, it is difficult to remove the cerium oxide particles from the polished surface again.
- US 7112123 discloses a dispersion for polishing glass surfaces, metal surfaces and dielectric surfaces, which comprises, as an abrasive, from 0.1 to 50% by weight of cerium oxide particles and from 0.1 to 10% by weight of clay abrasive particles, 90% of the clay abrasive particles having a particle diameter of from 10 nm to 10 ⁇ m and 90% of the cerium oxide particles having a particle diameter of from 100 nm to 10 ⁇ m.
- Cerium oxide particles, clay abrasive particles and glass as the surface to be polished have a negative surface charge.
- Such a dispersion enables significantly higher material removal than a dispersion based only on cerium oxide particles. However, such a dispersion causes a high defect rate.
- US 5891205 discloses an alkaline dispersion which comprises silicon dioxide and cerium oxide.
- the particle size of the cerium oxide particles is less than or equal to the size of the silicon dioxide particles.
- the cerium oxide particles present in the dispersion stem from a gas phase process, are not aggregated and have a particle size which is less than or equal to 100 nm.
- the presence of cerium oxide particles and silicon dioxide particles allows the removal rate to be increased drastically.
- the silicon dioxide/cerium oxide weight ratio should be from 7.5:1 to 1:1.
- the silicon dioxide preferably has a particle size of less than 50 nm and the cerium oxide one of less than 40 nm.
- the proportion a) of silicon dioxide is greater than the proportion of cerium oxide and b) the silicon dioxide particles are larger than the cerium oxide particles.
- the dispersion disclosed in US 5891205 enables significantly higher removal than a dispersion based only on cerium oxide particles. However, such a dispersion causes a high defect rate.
- US 6491843 discloses an aqueous dispersion which is said to have a high selectivity with regard to the removal rate of Si ⁇ 2 and Si3N 4 .
- This dispersion comprises abrasive particles and an organic compound which has both a carboxyl group and a second chloride- or amine-containing functional group. Suitable organic compounds mentioned are amino acids.
- all abrasive particles are said to be suitable, preference being given especially to aluminum oxide, cerium oxide, copper oxide, iron oxide, nickel oxide, manganese oxide, silicon dioxide, silicon carbide, silicon nitride, tin oxide, titanium dioxide, titanium carbide, tungsten oxide, yttrium oxide, zirconium oxide or mixtures of the aforementioned compounds.
- cerium oxide is specified as abrasive particles. What are desired are dispersions which afford a high material removal rate with a low defect rate and high selectivity. After the polishing and cleaning of the wafers, only a small amount of deposits, if any, should be present on the surface.
- a dispersion which comprises particles of cerium oxide and colloidal silicon dioxide, where the zeta potential of the silicon dioxide particles is negative and that of the cerium oxide particles is positive or equal to zero, and the zeta potential of the dispersion is negative overall, the mean diameter of the
- cerium oxide particles is not more than 200 nm
- silicon dioxide particles is less than 100 nm, the proportion, based in each case on the total amount of the dispersion, of
- cerium oxide particles is from 0.01 to 50% by weight
- silicon dioxide particles is from 0.01 to 10% by weight and the pH of the dispersion is from 3.5 to ⁇ 7.5.
- the zeta potential is a measure of the surface charge of the particles.
- the zeta potential is understood to mean the potential at the shear level within the electrochemical double layer of particle/electrolyte in the dispersion.
- An important parameter in connection with the zeta potential is the isoelectric point (IEP) for a particle.
- the IEP specifies the pH at which the zeta potential is zero. The greater the zeta potential, the more stable is the dispersion.
- the charge density at the surface can be influenced by changing the concentration of the potential-determining ions in the surrounding electrolyte.
- Particles of the same material will have the same sign of the surface charges and thus repel one another.
- the repulsive force cannot compensate for the van der Waals attraction of the particles, and there is flocculation and possibly sedimentation of the particles.
- the zeta potential can, for example, be determined by measuring the colloidal vibration current (CVI) of the dispersion or by determining the electrophoretic mobility.
- CVI colloidal vibration current
- the zeta potential can be determined by means of the electrokinetic sound amplitude (ESA) .
- the inventive dispersion preferably has a zeta potential of from -10 to -100 mV and more preferably one of from -25 to -50 mV.
- the inventive dispersion also features a pH of 3.5 to ⁇ 7.5. It allows, for example, the polishing of dielectric surfaces in the alkaline range. Preference may be given to a dispersion which has a pH of 5.5. to 7.4.
- the proportion of cerium oxide in the inventive dispersion can be varied over a range from 0.01 to 50% by weight based on the dispersion.
- High cerium oxide contents are desired when the intention is, for example, to minimize transport costs.
- the content of cerium oxide is preferably from 0.1 to 5% by weight and more preferably from 0.2 to 1% by weight, based on the dispersion .
- the proportion of colloidal silicon dioxide in the inventive dispersion is from 0.01 to 10% by weight, based on the dispersion.
- a range from 0.05 to 0.5% by weight is preferred.
- the cerium oxide/silicon dioxide weight ratio in the inventive dispersion is preferably from 1.1:1 to 100:1. It has been found to be advantageous in polishing processes when the cerium oxide/silicon dioxide weight ratio is from 1.25:1 to 5:1.
- the mean particle diameter of the cerium oxide particles in the inventive dispersion is not more than 200 nm. Preference is given to a range from 40 to 90 nm. Within this range, the best results arise in polishing processes with regard to material removal, selectivity and defect rate.
- the cerium oxide particles may be present as isolated individual particles, or else in the form of aggregated primary particles.
- the inventive dispersion preferably comprises aggregated cerium oxide particles, or the cerium oxide particles are present predominantly or completely in aggregated form.
- cerium oxide particles have been found to be those which contain carbonate groups on their surface and in layers close to the surface, especially those as disclosed in DE-A-102005038136.
- cerium oxide particles which have a BET surface area of from 25 to 150 m 2 /g, the primary particles have a mean diameter of from
- the layer of the primary particles close to the surface has a depth of approx. 5 nm, in the layer close to the surface, the carbonate concentration, proceeding from the surface at which the carbonate concentration is at its highest, decreases toward the interior, the carbon content on the surface which stems from the carbonate groups is from 5 to 50 area percent and, in the layer close to the surface, is from 0 to 30 area percent in a depth of approx. 5 nm the content of cerium oxide, calculated as Ce ⁇ 2 and based on the powder, is at least 99.5% by weight and the content of carbon, comprising organic and inorganic carbon, is from 0.01 to 0.3% by weight, based on the powder.
- the carbonate groups can be detected both at the surface and in a depth up to approx. 5 nm of the cerium oxide particles.
- the carbonate groups are chemically bonded and may, for example, be arranged as in the structures a-c.
- the carbonate groups can be detected, for example, by XPS/ESCA analysis.
- XPS X-ray Photoelectron Spectroscopy
- ESCA Electron Spectroscopy for Chemical Analysis
- the content of sodium is generally not more than 5 ppm and that of chlorine not more than 20 ppm.
- the elements mentioned are generally tolerable only in small amounts in chemical-mechanical polishing.
- the cerium oxide particles used preferably have a BET surface area oof from 30 to 100 m 2 /g and more preferably of 40 to 80 m 2 /g.
- the colloidal silicon dioxide particles of the inventive dispersion have a mean particle diameter of less than 100 nm. Preference is given to the range from 3 to 50 nm and particular preference to the range from 10 to 35 nm.
- Colloidal silicon dioxide particles are understood to mean those which are present in the form of individual particles which are uncrosslinked with each other, are spherical or very substantially spherical and have hydroxyl groups on the surface.
- cerium oxide particles on their surface and in layers close to the surface, comprise carbonate groups and the pH of the dispersion is from 3.5 to ⁇ 7.5.
- the inventive dispersion may further comprise one or more aminocarboxylic acids with a proportion, in total, of from 0.01 to 5% by weight, based on the dispersion.
- aminocarboxylic acids with a proportion, in total, of from 0.01 to 5% by weight, based on the dispersion.
- These are preferably selected from the group consisting of alanine, 4-aminobutanecarboxylic acid, 6- aminohexanecarboxylic acid, 12-aminolauric acid, arginine, aspartic acid, glutamic acid, glycine, glycylglycine, lysine and proline. Particular preference is given to glutamic acid and proline.
- the proportion of amino acid or salt thereof in the dispersion is preferably from 0.1 to 0.6% by weight.
- the liquid phase of the inventive dispersion comprises water, organic solvents and mixtures of water with organic solvents.
- the main constituent with a content of > 90% by weight of the liquid phase, is water.
- inventive dispersion may also comprise acids, bases, salts.
- the pH can be adjusted by means of acids or bases.
- the acids used may be inorganic acids, organic acids or mixtures of the aforementioned.
- the inorganic acids used may in particular be phosphoric acid, phosphorous acid, nitric acid, sulfuric acid, mixtures thereof, and their acidic salts.
- the pH can be increased by adding ammonia, alkali metal hydroxides or amines.
- the inventive dispersion contains 0.3-20% by weight of an oxidizing agent.
- an oxidizing agent for this purpose, it is possible to use hydrogen peroxide, a hydrogen peroxide adduct, for example the urea adduct, an organic peracid, an inorganic peracid, an imino peracid, a persulfate, perborate, percarbonate, oxidizing metal salts and/or mixtures of the above.
- the inventive dispersion may further comprise oxidation activators .
- Suitable oxidation activators may be the metal salts of Ag, Co, Cr, Cu, Fe, Mo, Mn, Ni, Os, Pd, Ru, Sn, Ti, V and mixtures thereof. Also suitable are carboxylic acids, nitriles, ureas, amides and esters. Iron (II) nitrate may be particularly preferred.
- concentration of the oxidation catalyst may, depending on the oxidizing agent and the polishing task, be varied within a range between 0.001 and 2% by weight. More preferably, the range may be between 0.01 and 0.05% by weight.
- the corrosion inhibitors which are generally present in the inventive dispersion with a content of from 0.001 to 2% by weight, may be nitrogen-containing heterocycles such as benzotriazole, substituted benzimidazoles, substituted pyrazines, substituted pyrazoles and mixtures thereof.
- the invention further provides a process for producing the inventive dispersion in which cerium oxide particles in powder form are introduced and subsequently dispersed into a predispersion comprising colloidal silicon dioxide particles or a predispersion comprising cerium oxide particles and a predispersion comprising colloidal silicon dioxide particles are combined and subsequently dispersed, and then optionally one or more amino acids are added in solid, liquid or dissolved form and then optionally oxidizing agent, oxidation catalyst and/or corrosion inhibitor.
- Suitable dispersing units are especially those which bring about an energy input of at least 200 kJ/m 3 .
- These include systems operating by the rotor-stator principle, for example Ultra-Turrax machines, or stirred ball mills. Higher energy inputs are possible with a planetary kneader/mixer .
- the efficacy of this system is combined with a sufficiently high viscosity of the processed mixture in order to introduce the required high shear energies to divide the particles.
- High-pressure homogenizers are used to decompress two predispersed suspension streams under high pressure through a nozzle.
- the two dispersion jets meet one another exactly and the particles grind one another.
- the predispersion is likewise placed under high pressure, but the particles collide against armored wall regions. The operation can be repeated as often as desired in order to obtain smaller particle sizes.
- the energy input can also be effected by means of ultrasound.
- the dispersion and grinding apparatus can also be used in combination. Oxidizing agents and additives can be supplied at different times to the dispersion. It may also be advantageous, for example, not to incorporate oxidizing agents and oxidation activators until the end of the dispersion, if appropriate at lower energy input .
- the zeta potential of the colloidal silicon dioxide particles used is preferably from -10 to -100 mV, at a pH of from 3.5 to 7.4.
- the zeta potential of the cerium oxide particles used is preferably from 0 to 60 mV, at a pH of from 3.5 to 7.4.
- the invention further provides for the use of the inventive dispersion for polishing dielectric surfaces.
- the inventive dispersion leads to a high Si ⁇ 2 :Si 3 N 4 selecitivity .
- the inventive dispersion contributes to this by virtue of its pH being 3.5 to ⁇ 7.5. At these pH values, the hydrolysis of Si3N 4 to Si ⁇ 2 is minimal or not present. The Si ⁇ 2 removal which is low at these pH values can be increased again by organic additives such as amino acids .
- the specific surface area is determined to DIN 66131.
- the surface properties are determined by large-area
- the zeta potential is determined in the pH range of 3-12 by means of the electrokinetic sound amplitude (ESA) .
- ESA electrokinetic sound amplitude
- a suspension comprising 1% cerium oxide is prepared.
- the dispersion is effected with an ultrasound probe (400 W) .
- the suspension is stirred with a magnetic stirrer and pumped by means of a peristaltic pump through the PPL-80 sensor of the Matec ESA-8000 instrument.
- the potentiometric titration with 5M NaOH commences up to pH 12.
- the back-titration to pH 4 is undertaken with 5M HNO3.
- the evaluation is effected by means of the instrument software version pcava 5.94.
- ⁇ zeta potential
- ⁇ volume fraction
- ⁇ p density difference between particles and liquid
- c speed of sound in the suspension
- ⁇ viscosity of the liquid
- ⁇ dielectric constant of the suspension
- G (CC) I correction for inertia.
- the mean aggregate diameters are determined with a Horiba LB-500 particle size analyzer.
- the feedstocks used to prepare dispersions are a pyrogenic cerium oxide as described in DE-A-102005038136, example 2.
- the colloidal silicon dioxides used are two Levasil ® grades from H. C. Starck. Important physicochemical parameters of these substances are reported in table 1.
- Wafer/pad Wafer/pad
- Silicon dioxide 200 mm, layer thickness 1000 nm, thermal oxide, from SiMat
- silicon nitride 200 mm, layer thickness 160 nm, LPCVD, from SiMat
- Rodel IC 1000-A3 pad
- Dl The dispersion is obtained by adding cerium oxide powder to water, and dispersing it by ultrasound treatment with an ultrasound finger (from Bandelin UW2200/DH13G, level 8, 100%; 5 minutes) . Subsequently, the pH is adjusted to 7.0 with aqueous ammonia.
- D2a-D3a The dispersions are obtained by mixing a predispersion consisting of cerium oxide and water and a predispersion consisting of colloidal silicon dioxide and water, dispersing it by ultrasound treatment with an ultrasound finger (from Bandelin UW2200/DH13G, level 8, 100%; 5 minutes) subsequently adding glutamic acid in the case of dispersions D2-lb, D2-2b and D3b, and adjusting the pH to 7.0.
- Table 2 shows important parameters of the resulting dispersions.
- Table 3 shows the polishing ablations and selectivities after makeup of the dispersion.
- the inventive dispersions As compared with dispersion Dl, which contains only cerium oxide, the inventive dispersions have a comparable removal of silicon dioxide and silicon nitride, but the number of scratches on the surface is significantly smaller.
- polishing residues are assessed visually (also by light microscope in the range of up to 64-fold magnification) .
- Dl is unstable and sediments as early as after a few minutes.
- the particle size measured is significantly above one micrometer.
- the inventive dispersions in contrast, are still stable even after polishing. This means that there is no formation of large agglomerates in the case of these dispersions.
- the polished wafers also exhibit a considerably lower level of residues.
- One possible mechanism comprises the outward screening of positively charged cerium oxide particles by negatively charged colloidal silicon dioxide particles, ensuring effective reversal of the charge of the cerium oxide particles.
- the inventive dispersion offers, inter alia, the possibility of polishing at pH values close to the IEP of the pure cerium oxide. Since the interactions are electrostatic interactions, the colloidal silicon dioxide particles can be sheared off during the polishing operation, so that the polishing action of the cerium oxide is maintained. As a result of all particles always being outwardly negatively charged during the entire polishing operation, agglomerate formation is significantly reduced. Long-term analyses show that the stability and polishing properties are maintained even over prolonged periods.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Treatment Of Semiconductor (AREA)
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
- Silicon Compounds (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010538541A JP5300864B2 (en) | 2007-12-22 | 2008-12-01 | Dispersion containing cerium oxide and colloidal silicon dioxide |
CN2008801223495A CN101910352A (en) | 2007-12-22 | 2008-12-01 | Dispersion comprising cerium oxide and colloidal silicon dioxide |
EP08865512A EP2220188A1 (en) | 2007-12-22 | 2008-12-01 | Dispersion comprising cerium oxide and colloidal silicon dioxide |
KR1020107013667A KR101156824B1 (en) | 2007-12-22 | 2008-12-01 | Dispersion comprising cerium oxide and colloidal silicon dioxide |
US12/745,598 US20100307068A1 (en) | 2007-12-22 | 2008-12-01 | Dispersion comprising cerium oxide and colloidal silicon dioxide |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007062572.5 | 2007-12-22 | ||
DE102007062572A DE102007062572A1 (en) | 2007-12-22 | 2007-12-22 | Cerium oxide and colloidal silica containing dispersion |
Publications (1)
Publication Number | Publication Date |
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WO2009080443A1 true WO2009080443A1 (en) | 2009-07-02 |
Family
ID=40291136
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2008/066496 WO2009080443A1 (en) | 2007-12-22 | 2008-12-01 | Dispersion comprising cerium oxide and colloidal silicon dioxide |
Country Status (8)
Country | Link |
---|---|
US (1) | US20100307068A1 (en) |
EP (1) | EP2220188A1 (en) |
JP (1) | JP5300864B2 (en) |
KR (1) | KR101156824B1 (en) |
CN (1) | CN101910352A (en) |
DE (1) | DE102007062572A1 (en) |
TW (1) | TWI447214B (en) |
WO (1) | WO2009080443A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2927294A1 (en) * | 2014-04-04 | 2015-10-07 | Fujifilm Planar Solutions LLC | Polishing compositions and methods for selectively polishing silicon nitride over silicon oxide films |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009046849A1 (en) | 2009-11-18 | 2011-05-19 | Evonik Degussa Gmbh | Aqueous dispersion used in polishing silicon dioxide layers comprising cerium oxide and silicon dioxide is obtainable by mixing cerium oxide and silicon dioxide while stirring, and then dispersing at a specific shear rate |
KR20120024824A (en) * | 2009-06-25 | 2012-03-14 | 에보니크 데구사 게엠베하 | Dispersion comprising cerium oxide and silicon dioxide |
DE102009027211A1 (en) | 2009-06-25 | 2010-12-30 | Basf Se | Aqueous cerium oxide and silicon dioxide-containing dispersion, obtained by mixing cerium oxide-starting dispersion and silica-starting dispersion under stirring and dispersing at specified shear rate, useful to polish dielectric surface |
JPWO2013099142A1 (en) * | 2011-12-28 | 2015-04-30 | コニカミノルタ株式会社 | Substrate abrasive and substrate manufacturing method |
JPWO2014175397A1 (en) * | 2013-04-25 | 2017-02-23 | 日立化成株式会社 | Polishing liquid for CMP and polishing method using the same |
CN104694018B (en) * | 2015-03-23 | 2017-04-19 | 济南大学 | Preparing method for polishing powder used for polishing of zirconium dioxide ceramic |
JP6262836B1 (en) * | 2016-07-28 | 2018-01-17 | 株式会社バイコウスキージャパン | Polishing abrasive grains, method for producing the same, polishing slurry containing the same, and polishing method using the same |
US20180094166A1 (en) * | 2016-09-30 | 2018-04-05 | Rohm And Haas Electronic Materials Cmp Holdings, Inc. | Cmp polishing composition comprising positive and negative silica particles |
JP6985116B2 (en) * | 2017-11-17 | 2021-12-22 | 信越化学工業株式会社 | Abrasive for synthetic quartz glass substrate and polishing method for synthetic quartz glass substrate |
KR20220006277A (en) * | 2020-07-08 | 2022-01-17 | 성주경 | Vehicle oil film removal paste composition |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5891205A (en) | 1997-08-14 | 1999-04-06 | Ekc Technology, Inc. | Chemical mechanical polishing composition |
US6491843B1 (en) | 1999-12-08 | 2002-12-10 | Eastman Kodak Company | Slurry for chemical mechanical polishing silicon dioxide |
US20040006924A1 (en) * | 2002-02-11 | 2004-01-15 | Scott Brandon Shane | Free radical-forming activator attached to solid and used to enhance CMP formulations |
US20040209555A1 (en) * | 2003-04-21 | 2004-10-21 | Cabot Microelectronics Corporation | Coated metal oxide particles for CMP |
US20050037693A1 (en) * | 2003-07-04 | 2005-02-17 | Jsr Corporation | Chemical mechanical polishing aqueous dispersion and chemical mechanical polishing method |
US7112123B2 (en) | 2004-06-14 | 2006-09-26 | Amcol International Corporation | Chemical-mechanical polishing (CMP) slurry containing clay and CeO2 abrasive particles and method of planarizing surfaces |
US20060213126A1 (en) * | 2005-03-28 | 2006-09-28 | Cho Yun J | Method for preparing a polishing slurry having high dispersion stability |
WO2006132055A1 (en) * | 2005-06-06 | 2006-12-14 | Asahi Glass Company, Limited | Semiconductor abrasive |
JP2007012679A (en) * | 2005-06-28 | 2007-01-18 | Asahi Glass Co Ltd | Abrasive and manufacturing method of semiconductor integrated circuit device |
DE102005038136A1 (en) | 2005-08-12 | 2007-02-15 | Degussa Ag | Ceric oxide powder for catalyst, UV absorber, toner component, fuel cell constituent or chemical-mechanical polishing has crystalline primary particles with carbonate groups on and near surface produced by flame spray pyrolysis |
US20070232068A1 (en) | 2006-03-29 | 2007-10-04 | Gaku Minamihaba | Slurry for touch-up CMP and method of manufacturing semiconductor device |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5382272A (en) * | 1993-09-03 | 1995-01-17 | Rodel, Inc. | Activated polishing compositions |
US6022400A (en) * | 1997-05-22 | 2000-02-08 | Nippon Steel Corporation | Polishing abrasive grains, polishing agent and polishing method |
JP4113282B2 (en) * | 1998-05-07 | 2008-07-09 | スピードファム株式会社 | Polishing composition and edge polishing method using the same |
US20020019202A1 (en) * | 1998-06-10 | 2002-02-14 | Thomas Terence M. | Control of removal rates in CMP |
JP3895949B2 (en) * | 2001-07-18 | 2007-03-22 | 株式会社東芝 | CMP slurry and method for manufacturing semiconductor device using the same |
WO2003016424A1 (en) * | 2001-08-20 | 2003-02-27 | Samsung Corning Co., Ltd. | Polishing slurry comprising silica-coated ceria |
US20030211747A1 (en) * | 2001-09-13 | 2003-11-13 | Nyacol Nano Technologies, Inc | Shallow trench isolation polishing using mixed abrasive slurries |
JP2004079968A (en) * | 2002-08-22 | 2004-03-11 | Toshiba Corp | Polishing agent for semiconductor device and manufacturing method thereof using the same |
TWI307712B (en) * | 2002-08-28 | 2009-03-21 | Kao Corp | Polishing composition |
US20040065021A1 (en) * | 2002-10-04 | 2004-04-08 | Yasuhiro Yoneda | Polishing composition |
JP4574140B2 (en) * | 2003-08-27 | 2010-11-04 | 株式会社フジミインコーポレーテッド | Polishing composition and polishing method using the same |
TW200613485A (en) * | 2004-03-22 | 2006-05-01 | Kao Corp | Polishing composition |
US7056192B2 (en) * | 2004-09-14 | 2006-06-06 | International Business Machines Corporation | Ceria-based polish processes, and ceria-based slurries |
JP4451347B2 (en) * | 2005-04-26 | 2010-04-14 | 花王株式会社 | Polishing liquid composition |
US7553465B2 (en) * | 2005-08-12 | 2009-06-30 | Degussa Ag | Cerium oxide powder and cerium oxide dispersion |
DE102007008232A1 (en) * | 2007-02-20 | 2008-08-21 | Evonik Degussa Gmbh | Dispersion containing ceria and colloidal silica |
DE102007035992A1 (en) * | 2007-05-25 | 2008-11-27 | Evonik Degussa Gmbh | Ceria, silica or phyllosilicate and amino acid-containing dispersion |
KR20120024824A (en) * | 2009-06-25 | 2012-03-14 | 에보니크 데구사 게엠베하 | Dispersion comprising cerium oxide and silicon dioxide |
-
2007
- 2007-12-22 DE DE102007062572A patent/DE102007062572A1/en not_active Withdrawn
-
2008
- 2008-12-01 US US12/745,598 patent/US20100307068A1/en not_active Abandoned
- 2008-12-01 KR KR1020107013667A patent/KR101156824B1/en not_active IP Right Cessation
- 2008-12-01 WO PCT/EP2008/066496 patent/WO2009080443A1/en active Application Filing
- 2008-12-01 EP EP08865512A patent/EP2220188A1/en not_active Withdrawn
- 2008-12-01 JP JP2010538541A patent/JP5300864B2/en not_active Expired - Fee Related
- 2008-12-01 CN CN2008801223495A patent/CN101910352A/en active Pending
- 2008-12-18 TW TW097149454A patent/TWI447214B/en not_active IP Right Cessation
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5891205A (en) | 1997-08-14 | 1999-04-06 | Ekc Technology, Inc. | Chemical mechanical polishing composition |
US6491843B1 (en) | 1999-12-08 | 2002-12-10 | Eastman Kodak Company | Slurry for chemical mechanical polishing silicon dioxide |
US20040006924A1 (en) * | 2002-02-11 | 2004-01-15 | Scott Brandon Shane | Free radical-forming activator attached to solid and used to enhance CMP formulations |
US20040209555A1 (en) * | 2003-04-21 | 2004-10-21 | Cabot Microelectronics Corporation | Coated metal oxide particles for CMP |
US20050037693A1 (en) * | 2003-07-04 | 2005-02-17 | Jsr Corporation | Chemical mechanical polishing aqueous dispersion and chemical mechanical polishing method |
US7112123B2 (en) | 2004-06-14 | 2006-09-26 | Amcol International Corporation | Chemical-mechanical polishing (CMP) slurry containing clay and CeO2 abrasive particles and method of planarizing surfaces |
US20060213126A1 (en) * | 2005-03-28 | 2006-09-28 | Cho Yun J | Method for preparing a polishing slurry having high dispersion stability |
WO2006132055A1 (en) * | 2005-06-06 | 2006-12-14 | Asahi Glass Company, Limited | Semiconductor abrasive |
EP1890321A1 (en) * | 2005-06-06 | 2008-02-20 | Asahi Glass Company, Limited | Semiconductor abrasive |
JP2007012679A (en) * | 2005-06-28 | 2007-01-18 | Asahi Glass Co Ltd | Abrasive and manufacturing method of semiconductor integrated circuit device |
EP1909312A1 (en) * | 2005-06-28 | 2008-04-09 | Asahi Glass Company, Limited | Abrasive and process for producing semiconductor integrated-circuit unit |
DE102005038136A1 (en) | 2005-08-12 | 2007-02-15 | Degussa Ag | Ceric oxide powder for catalyst, UV absorber, toner component, fuel cell constituent or chemical-mechanical polishing has crystalline primary particles with carbonate groups on and near surface produced by flame spray pyrolysis |
US20070232068A1 (en) | 2006-03-29 | 2007-10-04 | Gaku Minamihaba | Slurry for touch-up CMP and method of manufacturing semiconductor device |
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EP2927294A1 (en) * | 2014-04-04 | 2015-10-07 | Fujifilm Planar Solutions LLC | Polishing compositions and methods for selectively polishing silicon nitride over silicon oxide films |
US9558959B2 (en) | 2014-04-04 | 2017-01-31 | Fujifilm Planar Solutions, LLC | Polishing compositions and methods for selectively polishing silicon nitride over silicon oxide films |
US9583359B2 (en) | 2014-04-04 | 2017-02-28 | Fujifilm Planar Solutions, LLC | Polishing compositions and methods for selectively polishing silicon nitride over silicon oxide films |
Also Published As
Publication number | Publication date |
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JP5300864B2 (en) | 2013-09-25 |
US20100307068A1 (en) | 2010-12-09 |
JP2011507785A (en) | 2011-03-10 |
TWI447214B (en) | 2014-08-01 |
EP2220188A1 (en) | 2010-08-25 |
CN101910352A (en) | 2010-12-08 |
DE102007062572A1 (en) | 2009-06-25 |
KR20100084190A (en) | 2010-07-23 |
KR101156824B1 (en) | 2012-06-20 |
TW200946659A (en) | 2009-11-16 |
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