WO2009072073A1

WO2009072073A1 - Plastic pipe made of cross-linked polyolefin further comprising stabilizer (s)

Info

Publication number: WO2009072073A1
Application number: PCT/IB2008/055089
Authority: WO
Inventors: Jan Ericsson; Jacob John; Lucas Brickweg
Original assignee: Uponor Innovation Ab
Priority date: 2007-12-05
Filing date: 2008-12-04
Publication date: 2009-06-11
Also published as: CA2707478A1; CA2707478C; DK2220155T3; US7855246B2; EP2220155B1; EP2220155A4; PT2220155E; EP2220155A1; ES2537204T3; US20090149588A1

Abstract

A plastic pipe is made of a cross-linked poiyolefin to be utilized in, but not limited to, potabie water applications. Certain antioxidants and stabilizers are added to a process for producing the plastic pipe. The added antioxidants and stabilizers remain as key components in the final plastic pipes, providing superior long term stability and resistance to oxidative degradation, the latter being caused by but not limited to, chlorinated water environments, At least a primary stabilizer is used in the material.

Description

Plastic pipe made of cross-linked polyolefin further comprising stabilizer (s) .

BACKGROUND OF THE INVENTION

[0001] The invention relates to a plastic pipe used for potable water applications, which is made from a cross-linked polyolefin, preferably but not limited to, polyethylene.

[00023 It is advantageous and state-of-the-art to use polyoiefiπs, preferably but not limited to, polyethylene, for making piastic pipes applicable to potable water systems and applications. A further advantage is to use cross- linked polyethylene PEX for making pipes for potable water applications. Such advantages include, but are not limited to, long term stability including oxidation resistance to meet current codes and standards for potable water applications, flexibility in installation including a "memory effect", etc.

[0003] In many countries, potable water is typically more or ϊess chlorinated, chlorine primarily acting as a disinfectant. Chlorinated water environments exhibit additional challenges to plastic pipe systems. It is well known that extensive exposure to chlorine, and/or any of its water-soluble derivatives, at elevated temperatures and pressures, eventually leads to increased failure rates for piastic piping systems through catalyzed oxidation. It is fundamentally established that chlorine, hypochlorite, etc. reacts with polyethylene in an oxidative type of reaction, resulting in undesired and accelerated polymer (pipe} degradation. Typically, antioxidants are used to overcome the degradative effect of chlorine and/or its derivatives. However, St has been discovered that conventional antioxidants, such as Naugard 76 (supplied by Chemtura), which is equal to Irganox 1076 (supplied by Ciba Specialty Chemicals), typically applied with resins currently being used in the manufacture of piastic pipes, may be rapidly consumed through catalyzed oxidation promoted e.g. by chlorinated water, typically being utilized by an end-user in potable water applications. This effect is highly undesirable and may occur in a relatively short period of time. Thus, an immediate need exists for new types of plastic pipe polymer matrix formulations to address the extractabiiity of antioxidants and stabilizers. This may logically be achieved by lowering the rate of diffusion and_s consequently, extraction and depletion of said entities.

[0004] US 2007/0092675 discloses stabilized polyethylene materials which maintain the physical properties in chlorinated water environments. The disclosure suggests adding antioxidants, such as hindered phenols, phos- phates and metal deactivators, to a polyethylene resin. However, the disclosure states that for many applications it is preferred that the resins not be cross-linked. Thus, a need exists for a new type of solution.

DESCRIPTION OF THE INVENTION

[QOQS] An objective of the present invention is to provide new poly- otefin formuiations suitable for manufacture of plastic pipe systems, which further provide increased iong term stability in residential and commercial potable water applications, particularly when exposed Io oxidative environments such as, but not limited to, chlorinated water environments,

[0006] in the present invention, plastic pipes are made from a cross- linked pofyolefin to be utilized in, but not limited to, potable water applications. Certain antioxidants and stabilizers are added to the process for producing the plastic pipes. Furthermore, the added antioxidants and stabilizers remain as key components in the final plastic pipes, then providing superior long term stability and resistance to oxidative degradation, the latter being caused by but not limited to, chlorinated water environments. At least a primary stabilizer is used in the material.

[0007] Preferably, such a primary stabilizer comes from a specific class of sulphur containing hindered phenols, such as but not limited to, thiodi- ethylene-bis-[3-(3,5-di-tert-butyl-4-hydroxypheny]) propionate] (Irganox 1035 as supplied by Ciba Specialty Chemicals) and/or 2,2'-thiodiethylene bis[3-(3,5- di-f-butyl-4-hydroxypheny!)-propionate] (Anox 70 as supplied by Chemtura).

[0008] In an embodiment, a second stabilizer is utilized in the present invention, which second stabilizer comes from the classes of hindered amine light stabilizers (HALS), and/or nanoparticles, such as but not fimited to, metal oxides.

[0009] A large variety of hindered amine light stabilizers are com- merciatiy available on the market. Among many others, the present invenlion utilized Tinuvϊn 770 and Tinuvin 622 as supplied by Ciba Specialty Chemicals, but not limited thereto, as representative examples of this class of stabilizers. This was to demonstrate the innovative achievement within the framework of the present invention.

[0010] In the present invention, nanoparticles are represented by, but are not limited to, zinc oxide as supplied by BykChemie/NanoPhase.

[0011] It was concluded in the present invention that the primary stabilizer, provided considerably improved long term stability as demonstrated by, but not limited to, extended exposure to chlorinated water environments under elevated temperatures and pressures.

[0012] in addition, the primary stabilizer and the second stabilizers, when combined in the formulations, provided synergistic enhancement effects with regard to improved long term stability as demonstrated by, but not limited to, extended exposure to chlorinated water environments under elevated temperatures and pressures,

[0013j Further, it was demonstrated that the synergistic effects obtained by combining the primary stabilizer and the second stabilizer gave major improvements in the process design for the manufacture of PEΞX-A (polyethylene cross-linked by using peroxide) plastic pipes. This means in particular that new fundamental conditions were created for the design of ratios of all components in the plastic pipe formulations utilized for the manufacture of PEX-A plastic pipes. Ultimately, this gave a major contribution in order to achieve maximum performance for plastic pipes utilized in potable water applications. That is, as far as long term stability and enhanced resistance to oxidative polymer degradation are concerned, for example in chforinated potable water environments,

[0014] Thus, it is novel, advantageous, and innovative to produce cross-linked potyolefinic pipe products useful for potable water applications, providing major improvements in long-term stability and resistance to oxidation by applying the novel pipe formulations presented in this invention.

[0015] It wil! be obvious to a person skilled in the art that as technology advances, the inventive concept may be implemented in various ways. The invention and its embodiments are not limited to the examples described above but may vary within the scope of the claims.

Claims

1. A plastic pipe made of polyoiefin which is cross-linked to form a cross-finked polyoiefin, a material of the pipe further comprising a primary stabilizer.

2. A plastic pipe according to claim 1 , wherein the primary stabilizer comes from a specific class of sulphur containing hindered phenols, such as thiodi8thy!ene-bis-[3-(3,5-di-tert-butyi-4-hydroxypheny!) propionate] and/or 2,2'- ihiodieihylene bis[3-(3,5-di-f-butyl-4-hydroxyphenyl)-propioπate].

3. A plastic pipe according to claim 2, wherein in addition to the primary stabilizer, the material of the pipe further comprises a second stabilizer, which second stabilizer comprises hindered amine light stabilizers.

4. A plastic pipe according to claim 2» wherein in addition to the primary stabilizer, the material of the pipe further comprises a second stabilizer, which second stabilizer comprises nanoparticles.

5. A plastic pipe according to claim 2, wherein in addition to the primary stabiiizer, the material of the pipe further comprises a combination of second stabilizers including hindered amine light stabilizers and nanoparticles.

6. A plastic pipe according to claim 4, wherein the nanoparticles comprise zinc oxide.

7. A plastic pipe according to claim 5, wherein the nanoparticles comprise zinc oxide.